CN101993258B - Quick-acting organic liquid-molybdenum-boron fertilizer and preparation method thereof - Google Patents
Quick-acting organic liquid-molybdenum-boron fertilizer and preparation method thereof Download PDFInfo
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- CN101993258B CN101993258B CN 200910164273 CN200910164273A CN101993258B CN 101993258 B CN101993258 B CN 101993258B CN 200910164273 CN200910164273 CN 200910164273 CN 200910164273 A CN200910164273 A CN 200910164273A CN 101993258 B CN101993258 B CN 101993258B
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- molybdenum
- boron
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- boric acid
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 30
- 229910052796 boron Inorganic materials 0.000 title abstract description 22
- 238000002360 preparation method Methods 0.000 title description 3
- LGLOITKZTDVGOE-UHFFFAOYSA-N boranylidynemolybdenum Chemical compound [Mo]#B LGLOITKZTDVGOE-UHFFFAOYSA-N 0.000 claims abstract description 12
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 11
- 239000004327 boric acid Substances 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 8
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 5
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 5
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 4
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 4
- 239000011609 ammonium molybdate Substances 0.000 claims description 4
- 229940010552 ammonium molybdate Drugs 0.000 claims description 4
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical group [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 claims description 2
- ZUHZZVMEUAUWHY-UHFFFAOYSA-N n,n-dimethylpropan-1-amine Chemical compound CCCN(C)C ZUHZZVMEUAUWHY-UHFFFAOYSA-N 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 229960004418 trolamine Drugs 0.000 claims description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims 2
- 235000011164 potassium chloride Nutrition 0.000 claims 2
- 239000001103 potassium chloride Substances 0.000 claims 2
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical group [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract description 20
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 11
- 239000011733 molybdenum Substances 0.000 abstract description 11
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 230000002262 irrigation Effects 0.000 abstract description 4
- 238000003973 irrigation Methods 0.000 abstract description 4
- 238000011161 development Methods 0.000 abstract description 3
- 229910002651 NO3 Inorganic materials 0.000 abstract description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract description 2
- 150000001413 amino acids Chemical class 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 230000037081 physical activity Effects 0.000 abstract description 2
- 108090000623 proteins and genes Proteins 0.000 abstract description 2
- 102000004169 proteins and genes Human genes 0.000 abstract description 2
- 230000009467 reduction Effects 0.000 abstract description 2
- 239000003895 organic fertilizer Substances 0.000 abstract 3
- 150000001720 carbohydrates Chemical class 0.000 abstract 1
- 235000014633 carbohydrates Nutrition 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- 239000007921 spray Substances 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000003756 stirring Methods 0.000 description 9
- 235000013399 edible fruits Nutrition 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000002689 soil Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000011573 trace mineral Substances 0.000 description 4
- 235000013619 trace mineral Nutrition 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- -1 alkyl compound Chemical class 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 244000241235 Citrullus lanatus Species 0.000 description 2
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 241000270666 Testudines Species 0.000 description 2
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical class CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 150000001638 boron Chemical class 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002751 molybdenum Chemical class 0.000 description 2
- 239000000618 nitrogen fertilizer Substances 0.000 description 2
- 230000035790 physiological processes and functions Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 1
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010058314 Dysplasia Diseases 0.000 description 1
- 206010023126 Jaundice Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 108090000913 Nitrate Reductases Proteins 0.000 description 1
- 108010020943 Nitrogenase Proteins 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000005089 fruit drop Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000036244 malformation Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000007198 pollen germination Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004162 soil erosion Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a molybdenum-boron organic fertilizer which is chelated by chemical reaction between boron and molybdenum which are both inorganic and an organic compound. The fertilizer contains 6% of pure boron, more than 0.1% of pure molybdenum and 30% of organic matters. The molybdenum-boron organic fertilizer can be spayed on leaves and applied during irrigation and trickle irrigation, can be easily dissolved in water and absorbed by crops, can quickly participate in many important physical activities of plants, can promote the synthesis of amino acids and proteins and the transformation and circulation of carbohydrates, can accelerate the growth and development of crops and can quickly participate in nitrate reduction and azotification of leguminous plants; and therefore, the molybdenum-boron organic fertilizer is a quick-acting organic microelement chemical fertilizer.
Description
Technical field
The present invention relates to a kind of quick-acting organic liquid molybdenum boron fertilizer and preparation method.Boron that this fertilizer is necessary with crop and molybdenum element become a kind of organic chelate through amino-complex and alkyl compound equi-potential chelating.This inner complex good water solubility, crop are prone to absorption, nontoxic noresidue, cost trace element fertilizer low, easy to use; Boron-containing quantity is up to 12% in this fertilizer; Contain the molybdenum amount and be up to 2%, not only National standard also can satisfy the needs of agriculture prodn.The preparing method's energy consumption that realizes this fertilizer is low, technical process simple, non-environmental-pollution, and quality product is controlled easily.
Background technology
Boron plays crucial effect in whole vital processes of plant.It has not replaceable physiological function, promotes pollen germination, stimulates pollen tube growth, and plant fertilization is had special influence, is beneficial to fruit, seed formation; The many important physical activities of involved in plant can promote amino acid and proteinic synthetic, and promote the conversion and the running of glucide, accelerate crop growth.The boron element is under-supply, and plant strain growth is bad, can not form or form abnormal floral organ, and pollen tube forms difficulty, hinders spermatization, and the pollen granule dysplasia forms phenomenons such as " colored and unreal ", " real and fruitless ", " fruit and bad ".During serious boron deficiency, even No kernels or seeds are gathered, as in a year of scarcity.In agriculture prodn; Rape occur " colored and unreal ", " real and fruitless ", " fruit and meciless ", the oranges and tangerines " stone fruit " of weak, the peanut of rice and wheat " not twisting with the fingers disease ", cotton " flower bud and do not spend ", " flower and not bell ", beet " heartrot ", grape " big fruitlet ", " stuffed fruit ", crudefiber crop growing way, fiber, apple " fruit contracts "; And fruit tree fruit drop, fruit-setting rate are low, malformed fruit or the like, all are directly or indirectly because due to the boron deficiency.China is through the soil lacking boron of soil investigation more than 86%, and the boron fertilizer that uses at present is inorganic boric acid or boric acid sodium salt mostly, like borax, polymerization boron etc.; They are indissoluble or insoluble in cold water usually, needs heating for dissolving, and crystallization after use, can occur; Stop up shower nozzle or condense upon on the plant leaf surface; Borate combines to form not dissolved salt with inorganic metal ions such as calcium, magnesium, zinc, iron easily in soil simultaneously, and the crop assimilation effect is extremely low, has seriously restricted " three height " Agricultural Development.
Molybdenum is the main nitrogen fixation of participating in nitrate reduction and pulse family in plant materials, is pulse family fixed nitrogen trace elements necessary, is one of composition of Mo-Fe protein in the nitrogenase.Molybdenum ion is the metal ingredient of nitrate reductase, in nitrogen form transforms, plays the electron transport effect, and its physiological function and nitrogen metabolism are closely related, and when molybdenum lacked, the metabolism of nitrogen promptly was obstructed, so the shortage symptom of the molybdenum shortage of nitrogen quite seemingly.Plant leaf look light when lacking molybdenum, jaundice, and when serious, spot appears in blade, and the edge is shrivelled to curl, leaf malformation, it is irregular to grow.Concerning Cauliflower, leaf wrinkle volume even dead is not bloomed or is spent caducous.
Lack molybdenum at the soil of China more than 98%,, belong to expensive noble metal because the reserves of metal molybdenum are very rare; Usually the molybdenum salt that uses in the agriculture prodn is ammonium molybdate, and owing to cost an arm and a leg, generally all at 200,000 yuan/ton; Be up to 480,000 yuan per ton, these inorganic molybdenum salt crop assimilated efficiencies are low, are prone to again run off; So the use that China's agriculture prodn for a long time can't penetration and promotion molybdenum element fertilizer causes the specific absorption of many crop N elements extremely low, a large amount of nitrogenous fertilizer major parts of using of agriculture prodn are through soil erosion; Peasant's fertilizer input strengthens every year on the one hand, and on the other hand, a large amount of nitrogenous fertilizer forms the water body oxygen enrichmentization among flowing into rivers, lake; The water quality in severe contamination rivers and lake; How to capture these great realistic problems,, do not have that a kind of crop absorbs, can make crop nutrition content to coordinate easily, capital goods in the agricultural sector supply agriculture prodn to use efficiently if not from the dealing with problems in essence of agriculture prodn about national economy; To a kind of great restriction of agricultural sustainable development and the waste of scarce resource, also can't fundamentally solve the pollution problem that agriculture production environment brings beyond doubt
The boracic that uses in the agriculture prodn at present, the fertilizer of molybdenum element are a lot; The technology of this respect is also comparatively flourishing; But the product of all technological manufacturings all is boric acid or borate, molybdate to be done some according to a certain percentage be mixed and made into simply that to contain composite fertilizer or compound that multiple trace unit calculates fertile; Also have boron is processed organic liquid boron, but just contain single element boron.
After the present invention also aims to the mechanism of all trace elements in crop studied comprehensively, can find a kind of new technological approaches and method to provide that a kind of crop is prone to absorb, two kinds of ions of boron molybdenum can symbiotic chelating attitude compounds.
This boron molydbenum fertilizer that the present invention also aims to manufacturing can be miscible with arbitrary proportion and water, can be through foliage-spray, dash execute, drip irrigation etc., crop is prone to absorb, cost is low, easy to use.Use the 50-100 gram for general every mu through field experiment, cost is 4.5-10 yuan, and effect of increasing production is about 7-30%.
The method that the present invention also aims to make this fertilizer is simple, low, the non-environmental-pollution of energy consumption, and it is harmless to human non-toxic that crop absorbs the back.
Summary of the invention
The present invention has effectively overcome the defective of employed boron fertilizer and molydbenum fertilizer in the present agriculture prodn, has practiced thrift resource, has reduced the pollution to environment of agriculture input and traditional product, has also improved yield and quality simultaneously.
The boracic that uses in the agriculture prodn at present, the fertilizer of molybdenum element are a lot; The technology of this respect is also comparatively flourishing, but the product of all technological manufacturings all be boric acid or boron salt, molybdate to be done some according to a certain percentage simply be mixed and made into and contain composite fertilizer or the compound fertilizer that multiple trace unit calculates.Also have boron is processed organic liquid boron, but just contain single element boron.
A kind of quick-acting organic liquid molybdenum boron fertilizers of the present invention, it contains B:6-12, Mo:0.1-2, organic cpds: 10-30; Overall weight percent with this fertilizer is a benchmark, and its B element derives from a kind of in boric acid, borate, the boron trioxide, and the Mo element derives from molybdic acid or molybdate; Said organic cpds is a kind of in Monoethanolamine MEA BASF, diethylolamine, trolamine, quadrol, NSC 446, dimethyl propylamine, terepthaloyl moietie, USP Kosher, the YD 30 or the mixture more than two kinds that cooperates by arbitrary proportion.
Beneficial effect of the present invention is: after the present invention studies the mechanism of all trace elements in crop comprehensively; Can find a kind of new technological approaches and method to provide the easy absorption of a kind of crop, two kinds of ions of boron molybdenum to close the attitude compound by symbiotic huge legendary turtles; Boron-containing quantity is up to 12% in this boron molybdenum huge legendary turtle compound; Contain the molybdenum amount and be up to more than 2%, not only National standard also can satisfy the needs of agriculture prodn.It can be miscible with arbitrary proportion and water, can be through foliage-spray, dash execute, drip irrigation etc., crop is prone to absorb, becomes wood low, easy to use.Use the 50-100 gram for general every mu through field experiment, cost is 4.5-10 yuan, and effect of increasing production is about 7-30%; The method of making this fertilizer simultaneously is simple, low, the non-environmental-pollution of energy consumption, and it is harmless to human non-toxic that crop absorbs the back.
Embodiment
Embodiment 1:
At normal temperatures and pressures, 10 kilograms triethylamines are joined in 20 kilograms the water and stir, the boric acid that adds 70 kilograms then continues to stir, and react to add 50 after 20 minutes and restrain molybdic acids, continues stirring reaction again.Postcooling got product in 15 minutes.
Pengzhou City, Sichuan soil and fertilizer stands in Cao Qiao village, Li Chun town, Pengzhou City and makes an experiment, and gets this product 20 grams and converts 15 kilograms in water, on rape, sprays; Spray to be selected in season and spend preceding 2 days and just go out with pod; Spray twice, than borax that sprays equivalent separately and ammonium molybdate, rape yield increasing is 9.8%.
Embodiment 2:
At normal temperatures and pressures, the monoethylamine of 10 kilograms triethylamines and 10 kilograms is added to respectively in 20 kilograms the water and stirs, the boric acid that adds 60 kilograms then continues to stir, and react to add 20 after 20 minutes and restrain molybdic acids, continues stirring reaction again.Postcooling to normal temperature got product in 15 minutes.
Qu County, Sichuan Province soil and fertilizer stands in the test of San Hui town, Qu County deep bid village 1 society, gets this product 20 grams and converts 15 kilograms in water, on soybean, sprays; Spray to be selected in season and spend preceding 2 days and just go out with pod; Spray twice, than the polymerization boron and the ammonium molybdate that spray equivalent separately, soybean yield-increasing is 10.3%.
Embodiment 3:
At normal temperatures and pressures, the monoethylamine of 10 kilograms terepthaloyl moietie and 10 kilograms is added to respectively in 20 kilograms the water and stirs, the boric acid that adds 60 kilograms then continues to stir, and react to add 20 after 20 minutes and restrain molybdic acids, continues stirring reaction again.Postcooling to normal temperature got product in 15 minutes.
Chongqing City agricultural technology extension master station gets this product 20 grams and converts 15 kilograms in water in the test of five town newly-built village 5 societies of Yongchuan District, on watermelon, sprays three times; Than the boric acid and the Potassium orthomolybdate that spray equivalent separately; 338 kilograms of watermelon mu raising the output, stimulation ratio is 12.75%, abridged edition increases income 318.2 yuan.
Claims (3)
1. quick-acting organic liquid molybdenum boron fertilizer, it is characterized in that: it contains B:6-12, Mo:0.1-2, organic cpds: 10-30; Overall weight percent with this fertilizer is a benchmark, and its B element derives from a kind of in boric acid, borate, the boron trioxide, and the Mo element derives from molybdic acid or molybdate; Said organic cpds is a kind of in Monoethanolamine MEA BASF, diethylolamine, trolamine, quadrol, NSC 446, dimethyl propylamine, terepthaloyl moietie, USP Kosher, the YD 30 or the mixture more than two kinds that cooperates by arbitrary proportion.
2. quick-acting organic liquid molybdenum boron fertilizer according to claim 1 is characterized in that: said borate is boric acid sodium salt, boric acid sylvite, polymerization boric acid sodium salt, polymerization boric acid sylvite.
3. quick-acting organic liquid molybdenum boron fertilizer according to claim 1, it is characterized in that: said molybdate is Sodium orthomolybdate, Potassium orthomolybdate, ammonium molybdate.
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| CN 200910164273 CN101993258B (en) | 2009-08-27 | 2009-08-27 | Quick-acting organic liquid-molybdenum-boron fertilizer and preparation method thereof |
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| CN 200910164273 CN101993258B (en) | 2009-08-27 | 2009-08-27 | Quick-acting organic liquid-molybdenum-boron fertilizer and preparation method thereof |
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| CN101993258B true CN101993258B (en) | 2012-12-05 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102603400B (en) * | 2012-03-06 | 2014-01-15 | 北京雷力农用化学有限公司 | Liquid boron-molybdenum fertilizer and preparation method thereof |
| CN102731194B (en) * | 2012-07-13 | 2014-07-09 | 合肥绿农肥业有限责任公司 | Liquid organic boron-zinc water-soluble fertilizer and preparation method thereof |
| CN104151081B (en) * | 2014-08-26 | 2016-08-17 | 成都新朝阳作物科学有限公司 | High nitrogen clear liquid type foliage fertilizer and its preparation method and application |
| CN113860947A (en) * | 2021-09-29 | 2021-12-31 | 河北昊德生物科技有限公司 | Liquid boron-molybdenum fertilizer and preparation method thereof |
| CN113816800A (en) * | 2021-10-30 | 2021-12-21 | 史丹利农业集团股份有限公司 | Medium trace element fertilizer for regulating alkaline soil and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1076685A (en) * | 1993-05-24 | 1993-09-29 | 李连忠 | A kind of leaf fertilizer special for vegetable |
| CN1103393A (en) * | 1993-12-04 | 1995-06-07 | 龚信田 | Chelate multicomponent mixed microfertilizer and its preparing method |
| CN1199726A (en) * | 1997-09-04 | 1998-11-25 | 陈良玉 | Efficient foliage fertilizer |
-
2009
- 2009-08-27 CN CN 200910164273 patent/CN101993258B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1076685A (en) * | 1993-05-24 | 1993-09-29 | 李连忠 | A kind of leaf fertilizer special for vegetable |
| CN1103393A (en) * | 1993-12-04 | 1995-06-07 | 龚信田 | Chelate multicomponent mixed microfertilizer and its preparing method |
| CN1199726A (en) * | 1997-09-04 | 1998-11-25 | 陈良玉 | Efficient foliage fertilizer |
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| Publication number | Publication date |
|---|---|
| CN101993258A (en) | 2011-03-30 |
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Effective date of registration: 20170406 Address after: 610091 the Yellow River Road, Qingyang Industrial Park, Qingyang District, Sichuan,, block A1 Patentee after: Chengdu Jie Jie Organic Agriculture Development Co., Ltd. Address before: High tech Zone Chengdu city Sichuan province 610041 Bauhinia Road No. 96 Garden 1 building 4 unit 502 Patentee before: Zhang Xiaochuan |
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