CN113832628B - Method for producing composite material capable of simultaneously dyeing and laminating - Google Patents
Method for producing composite material capable of simultaneously dyeing and laminating Download PDFInfo
- Publication number
- CN113832628B CN113832628B CN202010586051.2A CN202010586051A CN113832628B CN 113832628 B CN113832628 B CN 113832628B CN 202010586051 A CN202010586051 A CN 202010586051A CN 113832628 B CN113832628 B CN 113832628B
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- elastic material
- woven sheet
- elastic
- materials
- pore
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- 239000002131 composite material Substances 0.000 title claims abstract description 29
- 238000004043 dyeing Methods 0.000 title claims description 31
- 238000004519 manufacturing process Methods 0.000 title claims description 17
- 238000010030 laminating Methods 0.000 title description 2
- 239000013013 elastic material Substances 0.000 claims abstract description 91
- 239000011148 porous material Substances 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 31
- 238000010438 heat treatment Methods 0.000 claims abstract description 14
- 239000003086 colorant Substances 0.000 claims abstract description 9
- 239000011248 coating agent Substances 0.000 claims abstract description 5
- 238000000576 coating method Methods 0.000 claims abstract description 5
- 235000011837 pasties Nutrition 0.000 claims abstract description 4
- 230000000149 penetrating effect Effects 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000012466 permeate Substances 0.000 claims description 12
- 230000002209 hydrophobic effect Effects 0.000 claims description 10
- 230000000694 effects Effects 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 2
- 238000005096 rolling process Methods 0.000 claims description 2
- 238000009954 braiding Methods 0.000 claims 2
- 238000003825 pressing Methods 0.000 claims 1
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- 238000010586 diagram Methods 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 239000012459 cleaning agent Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 238000003911 water pollution Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
- D06B1/10—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material
- D06B1/12—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material by rubbing contact, e.g. with brushes or pads
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C7/00—Heating or cooling textile fabrics
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
- Coloring (AREA)
Abstract
The invention provides a method for preparing a composite material capable of being simultaneously dyed and bonded, which comprises the steps of firstly preparing a plurality of elastic materials and a woven sheet, wherein the elastic materials are pasty with proper viscosity and have preset colors, and the woven sheet is provided with a first surface, a second surface and a plurality of pores communicated with the first surface and the second surface. And coating the elastic material on the first surface of the woven sheet, penetrating the elastic material into each pore from the first surface by a control means, attaching the elastic material to the woven sheet, forming a plurality of color-dyed areas on the second surface by the elastic material, and finally, heating and forming the attached elastic material and the woven sheet into a composite material.
Description
Technical Field
The present invention relates to a method for manufacturing a composite material, and more particularly, to a method for manufacturing a composite material capable of simultaneously dyeing and bonding.
Background
The prior elastic composite material (such as insoles, exercise mats and the like) is formed by attaching an elastic layer to a surface material (such as a plastic film or cloth and the like), and the manufacturing method is that the surface material is printed or dyed by ink at first, so that the beautiful appearance of the product can be improved, then the surface material is attached to the elastic layer by using adhesive, adhesive or glue-free attaching technology, and finally the product is heated and molded.
That is, in the existing elastic composite material manufacturing process, the process cannot be simplified due to different manufacturing steps of dyeing the surface material and attaching the surface material to the elastic layer, and the environment-friendly problems such as waste water, water pollution or air pollution can be caused by using solvents, cleaning agents and adhesives in the dyeing and attaching process, so that the process has obvious improvement.
Disclosure of Invention
The main purpose of the present invention is to provide a method for manufacturing a composite material capable of simultaneously dyeing and bonding and forming, which can complete dyeing and bonding and forming of cloth and an elastic layer at one time, has no problems of pollution of waste water, water and air caused by using solvents, cleaning agents and adhesives, has environment-friendly process, rapid manufacturing mode and various dyeing effects, and has practical value.
The present invention provides a method for manufacturing a composite material capable of being simultaneously dyed and bonded, comprising the steps of a) providing a plurality of elastic materials and a woven sheet, wherein the elastic materials are in a pasty state with proper viscosity and have a predetermined color, and the woven sheet has a first surface, a second surface and a plurality of pores communicated with the first surface and the second surface; step b) coating the elastic material on the first surface of the woven sheet; step c) penetrating the elastic material into each pore from the first surface by a control means, attaching the elastic material to the woven sheet, and forming a plurality of dyed areas on the second surface by the elastic material; and d) heating and forming the bonded elastic material and the woven sheet into a composite material.
Further, in step b), the elastic material is continuously coated on the first surface of the woven sheet by using a doctor blade.
Further, in step b), several kinds of elastic materials with different colors are continuously coated on the first surface of the woven sheet by using a doctor blade.
Further, various different colored elastic materials are fed in parallel between the doctor blade and the woven sheet.
Further, various different colored elastic materials are fed in overlapping between the doctor blade and the woven sheet.
Further, in step c), the control means applies pressure to cause the elastic material to infiltrate into the pores from the first surface.
Further, the pressure is applied to the surface of the elastic material by rolling with a roller or air pressure, so that the elastic material is pressed to permeate into the pores of the woven sheet.
Further, in step c), the control means changes the flowing state of the elastic material or the pore size of the woven sheet by means of heating, so that the elastic material naturally infiltrates into each pore.
Further, different parts of the woven sheet are heated by using different temperatures, so that the pore expansion degree of the different parts of the woven sheet is different, and the state that the elastic material permeates into each pore can be changed, so that the dyeing effect of the dyeing area is changed.
Further, in step c), after the elastic material is made to permeate into each pore from the first surface, a plurality of water drops may be further disposed on the surface of the elastic material.
Further, the water source from which the droplets are output more rapidly mixes the hydrophilic material with the hydrophobic material in a predetermined ratio.
Further, after the elastic material permeates into each pore from the first surface, a plurality of hydrophilic materials or hydrophobic materials can be arranged on the surface of the elastic material.
Drawings
FIG. 1 is a flow chart of a preferred embodiment of the present invention.
FIG. 2 is a general diagram of a preferred embodiment of the present invention.
FIG. 3 is a schematic illustration of a composite made in accordance with a preferred embodiment of the present invention.
FIG. 4 is a schematic diagram of a different control means (air pressure) according to another preferred embodiment of the present invention.
FIG. 5 is a schematic diagram of a different control means (temperature) according to another embodiment of the present invention.
FIG. 6 is a schematic diagram of a method for simultaneously feeding different color elastomeric materials in parallel between a doctor blade and a woven sheet according to another preferred embodiment of the invention.
FIG. 7 is a schematic illustration of the process of feeding different color elastomeric materials in an overlapping manner between a doctor blade and a woven sheet according to another preferred embodiment of the invention.
FIG. 8 is a schematic diagram illustrating a method for forming a plurality of water droplets on a surface of an elastic material according to another embodiment of the present invention.
Detailed Description
The present invention will be further described with reference to the accompanying drawings and specific examples, which are not intended to limit the invention, so that those skilled in the art may better understand the invention and practice it.
First, as shown in fig. 1 to 3, a first step 110 of a composite material manufacturing method 100 capable of simultaneously dyeing and bonding and molding according to a preferred embodiment of the present invention is to prepare an elastic material 1 and a woven sheet 2. The elastic material 1 is a pasty latex with proper viscosity, and of course, the invention is not limited to latex, and other elastic materials can be adopted, and the raw materials can be added with pigment to form a preset color. The woven sheet 2 is a sheet-like fabric woven or spun from fiber wires (such as nylon, cotton or plastic wires) and has a first surface 22, a second surface 24 and a plurality of holes 26 communicating the first and second surfaces 22, 24, and the woven sheet 2 is pre-wound for pulling out in a subsequent process.
The second step 120 of the present invention: the elastic material 1 is applied to the first surface 22 of the woven sheet 2. In detail, one end of the woven sheet 2 is continuously extended and moved toward the other end by a conveyor belt (not shown), a strip-shaped scraper 3 (extending direction is perpendicular to the moving direction of the conveyor belt) is disposed above one end of the woven sheet 2 which is input into the conveyor belt, the scraper 3 is spaced apart from the woven sheet 2 by a predetermined distance, the elastic material 1 is input into the surface of the woven sheet 2 at the front side of the scraper 3 (the side facing the winding portion of the woven sheet 2), the elastic material 1 can be continuously coated on the first surface 22 of the woven sheet 2 by the scraper 3 along with the moving process of the woven sheet 2, and the distance between the scraper 3 and the woven sheet 2 substantially forms the coating thickness of the elastic material 1.
The third step 130 of the present invention: by a control means, the elastic material 1 is made to permeate into each hole 26 from the first surface 22, so that the elastic material 1 is attached to the woven sheet 2, and the elastic material 1 forms a color-dyed area 28 on the second surface 24. The control means uses a conventional roller 4 to roll the elastic material 1 and the woven sheet 2, so that the elastic material 1 can infiltrate into each hole 26 (or even properly penetrate out of the second surface 24) from the first surface 22 by using pressure, so that not only the elastic material 1 can be attached to the woven sheet 2, but also the elastic material 1 in each hole 26 can be used to present a colored dyeing area 28 on the second surface 24.
A fourth step 140 of the present invention: the bonded elastic material 1 and the woven sheet 2 are heated and formed into a composite material 30. The heating mode utilizes the existing oven 5, and the mode of adopting the oven or other heating devices (such as a vulcanizing and foaming box) is selected according to the requirements of the characteristics of the product.
Finally, the composite material 30 finished product with the dyed woven layer on one side and the elastic layer (emulsion curing) on the other side is obtained by cooling at normal temperature.
Therefore, the method 100 for manufacturing a composite material capable of being simultaneously dyed and bonded and formed according to the present invention uses the control means (the aforementioned embodiment applies pressure to the elastic material 1 and the woven sheet 2 by using the roller), so that the elastic material 1 infiltrates into the pores 26 of the woven sheet 2 and is then heated and formed, the dyeing of the composite material 30 (the dyed areas 28 are made to have a predetermined color by the elastic material 1 infiltrated into each pore 26) and the bonding and forming of the elastic material 1 and the woven sheet 2 can be completed once, and the method does not need to bond the cloth with the elastic layer by using the adhesive after dyeing the cloth ink as in the conventional manufacturing of the elastic composite material, so that the problems of water pollution, wastewater and air pollution caused by using the solvent, the cleaning agent and the adhesive of the conventional elastic composite material can not occur, and the process is environment-friendly and the manufacturing method is faster.
In particular, the elastic material 1 is penetrated into the pores 26 of the woven sheet 2 for shaping, so that the original hand feeling, touch feeling and even physical and chemical characteristics of the woven sheet 2 can be changed, and the composite material 30 manufactured by using the woven sheet 2 made of different materials can also cause the dyeing area 28 to present different dyeing effects, and even if the composite material 30 is manufactured by using the woven sheet 2 made of the same material and woven wires and formed by different weaving modes, twist degrees or tightness degrees, the dyeing area 28 can also cause different dyeing effects, and the composite material 30 manufactured by the invention can have various changes due to different materials (woven sheet 2).
Next, the control means in the third step 130 of the present invention is not limited to the pressure applied by the roller 4, as shown in fig. 4, the air pressure may be applied to the surface of the elastic material 1, so that the elastic material 1 is pressed and permeates into the pores 26 of the woven sheet 2, and the value of the air pressure may be adjusted according to the actual state of the elastic material 1 permeated into the pores 26.
In addition, the control means of the present invention may be heating, as shown in fig. 5, by heating the elastic material 1 or the woven sheet 2, the flowing state of the elastic material 1 or the size of the pores 26 of the woven sheet 2 is changed, so that the elastic material 1 can naturally infiltrate into each pore 26. In detail, the elastic material 1 has better fluidity after heating, and is easy to permeate into each pore 26, and each pore 26 can be slightly expanded after heating the woven sheet 2, and the elastic material 1 can also be easier to permeate into each pore 26 (the thermal expansion numbers of different woven wires are different, so the heating temperature of the woven sheet 2 can be adjusted according to the selection of materials). Furthermore, the heating control means can heat different portions of the woven sheet 2 at different temperatures to make the expansion degree of the pores 26 of different portions of the woven sheet 2 different, so that the state of the elastic material 1 penetrating into each pore 26 will not be uniform, and the dyeing effect (such as the change of the shade of the color or the change of the visual effect of the gradient layer) of the dyeing region 28 can be changed.
In the step of coating the elastic material 1 on the surface of the woven sheet 2 by using the doctor blade 3, the elastic materials 1 with different colors may be fed in parallel between the doctor blade 3 and the woven sheet 2, as shown in fig. 6, so that the doctor blade 3 can simultaneously coat the elastic materials 1 with different colors on the first surface 22 of the woven sheet 2, and the dyed area 28 after being formed has multiple colors.
In addition, as shown in fig. 7, the present invention can also input several kinds of elastic materials 1 with different colors between the doctor blade 3 and the woven sheet 2 in an overlapped manner, so that the elastic materials 1 with different colors can be mixed and smeared on the surface of the woven sheet 2 by the doctor blade 3, and the dyeing area 28 has the effects of color mixing and camouflage.
Therefore, the invention can not only utilize the change of the control means to change the visual effect of the dyeing area 28 of the woven sheet 2, but also can adjust the input mode of the elastic material 1 to change the color of the dyeing area 28.
Furthermore, as shown in fig. 8, after the elastic material 1 is pressed by the roller 4 to permeate into each hole 26 from the first surface 22, a plurality of water droplets 6 (or hydrophilic material, hydrophobic material, etc. or a predetermined ratio of hydrophilic material and hydrophobic material may be quickly mixed in the water source outputting the water droplets 6, so that the water droplets 6 may be affected by the hydrophobic material to be in a pseudo-dispersed state) may be sprayed on the surface of the elastic material 1 by the roller 1 by adding a water pipe 41 to the roller 4 and providing a plurality of water inlets 42 on the surface, so that a proper amount of water may be output from each water inlet 42 to the surface of the elastic material 1 when the roller 4 presses the elastic material 1.
Accordingly, each water drop 6 can be evaporated by heating during the process of forming the elastic material 1 and the woven sheet 2, and the elastic material 1 can generate a bubble structure (hydrophilic or hydrophobic structure can be generated by using hydrophilic or hydrophobic material, so as to obtain the characteristics of affinity or rejection of moisture) or generate a camouflage effect on the color dyeing region 28. The hydrophilic material refers to a material having a property of being close to and attracting moisture, such as activated carbon, and the hydrophobic material refers to a material having a property of repelling moisture, such as glass particles or metal particles, which are not hydrophilic, and the respective detailed materials are not described herein.
In summary, the method for manufacturing the composite material capable of being simultaneously dyed and bonded and formed according to the present invention, by the control means, allows the elastic material to infiltrate into the pores of the woven sheet and then be heated and formed, so that dyeing and bonding and forming of the elastic material and the woven sheet can be completed at one time, and the problems of pollution of waste water, water and air caused by using solvents, cleaning agents and adhesives in the existing dyeing and bonding steps of the elastic composite material can be solved, thus the process is environment-friendly, the manufacturing mode is more rapid, the dyeing effect is more diverse, and the method has practical value; the present invention is, therefore, truly in accordance with the requirements of the patent application, and the present invention is filed by law.
The above-described embodiments are merely preferred embodiments for fully explaining the present invention, and the scope of the present invention is not limited thereto. Equivalent substitutions and modifications will occur to those skilled in the art based on the present invention, and are intended to be within the scope of the present invention. The protection scope of the invention is subject to the claims.
Claims (11)
1. The composite material making process capable of being dyed and adhered to form simultaneously includes the following steps:
step a) preparing a plurality of elastic materials and a braiding sheet, wherein the elastic materials are pasty with proper viscosity and have color, and the braiding sheet is provided with a first surface, a second surface and a plurality of pores communicated with the first surface and the second surface;
step b) coating the elastic material on the first surface of the woven sheet;
step c) applying pressure to make the elastic material permeate into each pore from the first surface and properly permeate out of the second surface through a control means, so that the elastic material is attached to the woven sheet, and a plurality of color-dyed areas are formed on the second surface by utilizing the elastic material permeated into each pore; and
And d) heating and forming the bonded elastic material and the woven sheet, and cooling at normal temperature to obtain the composite material with the dyed woven layer on one side and the elastic layer on the other side.
2. The method of claim 1, wherein in step b), the elastic material is continuously coated on the first surface of the woven sheet by a doctor blade.
3. The method of claim 2, wherein in step b), a plurality of different color elastic materials are continuously coated on the first surface of the woven sheet by using a doctor blade.
4. A method of producing a composite material capable of simultaneous dyeing and bonding as claimed in claim 3, wherein the elastomeric materials of different colors are fed in parallel between the doctor blade and the woven sheet.
5. A method of producing a composite material capable of simultaneous dyeing and bonding as claimed in claim 3, wherein the elastic materials of different colors are fed between the doctor blade and the woven sheet in overlapping relation.
6. The method of claim 1, wherein the pressure is applied to the surface of the elastic material by rolling with a roller or by air pressure, so that the elastic material is pressed to penetrate into the pores of the woven sheet.
7. A method for producing a composite material capable of being simultaneously dyed and bonded to form according to claim 1, 2 or 3, wherein in the step c), the control means changes the flow state of the elastic material or the pore size of the woven sheet by heating so that the elastic material naturally infiltrates into each pore.
8. The method of claim 7, wherein the different portions of the woven sheet are heated at different temperatures to cause different portions of the woven sheet to have different degrees of pore expansion, thereby changing the state of the elastic material penetrating into the pores and causing the dyeing effect of the dyeing region to change.
9. The method of claim 1, wherein in step c), after the elastic material is made to permeate into each hole from the first surface, a plurality of water drops can be further provided on the surface of the elastic material.
10. The method of claim 9, wherein the water source from which the water droplets are delivered mixes the hydrophilic material and the hydrophobic material in a predetermined ratio more rapidly.
11. The method according to claim 1, wherein in step c), after the elastic material is infiltrated into each pore from the first surface, a plurality of hydrophilic materials or hydrophobic materials can be further disposed on the surface of the elastic material.
Priority Applications (1)
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CN202010586051.2A CN113832628B (en) | 2020-06-24 | 2020-06-24 | Method for producing composite material capable of simultaneously dyeing and laminating |
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CN202010586051.2A CN113832628B (en) | 2020-06-24 | 2020-06-24 | Method for producing composite material capable of simultaneously dyeing and laminating |
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CN113832628B true CN113832628B (en) | 2024-02-20 |
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GB236345A (en) * | 1924-05-24 | 1925-07-09 | Walter Everitt | Porous coloured covering for hard tennis courts |
US5198073A (en) * | 1990-07-24 | 1993-03-30 | Digital Equipment Corporation | Methods for treating the surface of a solid body |
TW200846051A (en) * | 2007-05-17 | 2008-12-01 | See Green Ind Co Ltd | Anti-slip exercise pad and manufacturing method thereof |
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TW200950969A (en) * | 2008-06-06 | 2009-12-16 | See Green Ind Co Ltd | Method of producing continuous elastic pads |
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TW201406838A (en) * | 2012-08-06 | 2014-02-16 | Univ Nat Yunlin Sci & Tech | The method for fabrication of polymeric porous film with large area |
TW201540514A (en) * | 2014-04-23 | 2015-11-01 | See Green Ind Co Ltd | Continuous solid material printing method |
CN205814961U (en) * | 2016-05-24 | 2016-12-21 | 简单绿能股份有限公司 | Cushion structure |
CN106698966A (en) * | 2016-11-18 | 2017-05-24 | 常州大学 | Technology for preparing TiO2/SiO2 thin film based on water droplet templating method |
CN107839135A (en) * | 2016-09-20 | 2018-03-27 | 简单绿能股份有限公司 | Method for manufacturing continuous mixed-color elastic cushion |
TW201817935A (en) * | 2016-11-09 | 2018-05-16 | 簡單綠能股份有限公司 | Method for manufacturing a component with multicolor sides wherein high productivity is achieved by coloring the surfaces that corresponds to each other at the same time |
CN110283321A (en) * | 2019-06-20 | 2019-09-27 | 常州大学 | It is a kind of can self-contained hole configurations polymer preparation method |
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2020
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Patent Citations (13)
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GB236345A (en) * | 1924-05-24 | 1925-07-09 | Walter Everitt | Porous coloured covering for hard tennis courts |
US5198073A (en) * | 1990-07-24 | 1993-03-30 | Digital Equipment Corporation | Methods for treating the surface of a solid body |
TW200846051A (en) * | 2007-05-17 | 2008-12-01 | See Green Ind Co Ltd | Anti-slip exercise pad and manufacturing method thereof |
TW200916153A (en) * | 2007-10-02 | 2009-04-16 | See Green Ind Co Ltd | Resilient mat and manufacturing method thereof |
TW200950969A (en) * | 2008-06-06 | 2009-12-16 | See Green Ind Co Ltd | Method of producing continuous elastic pads |
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TW201817935A (en) * | 2016-11-09 | 2018-05-16 | 簡單綠能股份有限公司 | Method for manufacturing a component with multicolor sides wherein high productivity is achieved by coloring the surfaces that corresponds to each other at the same time |
CN106698966A (en) * | 2016-11-18 | 2017-05-24 | 常州大学 | Technology for preparing TiO2/SiO2 thin film based on water droplet templating method |
CN110283321A (en) * | 2019-06-20 | 2019-09-27 | 常州大学 | It is a kind of can self-contained hole configurations polymer preparation method |
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