CN113718523A - 一种防水阻燃服装材料及其制备方法 - Google Patents

一种防水阻燃服装材料及其制备方法 Download PDF

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CN113718523A
CN113718523A CN202110929205.8A CN202110929205A CN113718523A CN 113718523 A CN113718523 A CN 113718523A CN 202110929205 A CN202110929205 A CN 202110929205A CN 113718523 A CN113718523 A CN 113718523A
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garment material
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陶文娟
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Guangdong Vocational and Technical College
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Abstract

本发明公开了一种防水阻燃服装材料及其制备方法,包括聚酯纤维与改性助剂;所述改性助剂包括邻苯二甲酸二辛酯、水溶性树脂、石墨烯微、纳米铝粉和聚乙烯二醇。本发明制备方法的生产工艺简单,易于操作,且产量较高,制备的上述防水阻燃服装材料防水、阻燃性能优越。

Description

一种防水阻燃服装材料及其制备方法
技术领域
本发明属于服装材料技术领域,具体涉及一种防水阻燃服装材料及其制备方法。
背景技术
面料就是用来制作服装的材料。作为服装三要素之一,面料不仅可以诠释服装的风格和特性,而且直接左右着服装的色彩、造型的表现效果。
功能性面料是指具有某种特殊性能和用途的面料,比如防水、防风、透气、透湿、保暖、防油、易去污、防菌除臭、防紫外线、防静电、防辐射、防阻燃、耐高温、耐酸碱等功能。市场上的功能性面料以服装面料为主,多用于户外运动服、高档休闲服中。功能性面料主要采用功能纤维织造法和功能助剂浸轧法两种途径得到。功能纤维织造法是指在纱纺阶段采用具有特种功能的高性能纤维,如在《国家重点新产品计划支持领域(2012)》中提到的“碳纤维、芳纶、芳砜纶、高强维纶、高强高模聚乙烯、聚苯硫醚(PPS)、聚苯并双恶唑(PBO)等高性能纤维”,其中芳纶纤维具有耐高温、阻燃和高韧性,可制成各种防护服、消防服和防弹服等。功能助剂浸轧法是指采用先进的涂层技术在布面上涂上不同的化工原料使其具有防水、阻燃、抗静电、增强强度等特殊功能。常用的涂层材质有聚氨基甲酸涂层、聚氯乙)涂层和聚丙烯酸酯涂层等。
相关技术中,服装面料功能单一,无防水阻燃的作用,穿着舒适感差。
发明内容
本发明所要解决的第一个技术问题是:
提供一种防水阻燃服装材料。
本发明所要解决的第二个技术问题是:
提供一种上述防水阻燃服装材料的制备方法。
为了解决上述第一个技术问题,本发明采用的技术方案为:
一种防水阻燃服装材料,
包括聚酯纤维与改性助剂;
所述改性助剂包括邻苯二甲酸二辛酯、水溶性树脂、石墨烯微、纳米铝粉和聚乙烯二醇。
上述改性助剂中所用的邻苯二甲酸二辛酯环境友好且具有一定抗菌效果与防静电效果,因此使得服装面料无需再额外添加防菌剂和防静电剂。
所述的水溶性树脂包括丙烯酸系列树脂或聚乙烯醇或其混合物以及交联体。
此外,上述石墨烯微使得上述防水阻燃服装材料具有优良的抗菌性、抗紫外等性能,可大幅减少服装上细菌,还提高了面料抗紫外性能,保护人体健康。
上述纳米铝粉可以提高上述防水阻燃服装材料的导电性能,从而提高防尘抗静电效果。
根据本发明的一种实施方式,上述聚酯纤维为对苯二甲酸、乙二醇、至少一种二酸及至少一种二醇共聚合而成的聚酯纤维。
根据本发明的一种实施方式,上述二元酸包括己二酸、癸二酸和邻苯二甲酸酐中的至少一种。
根据本发明的一种实施方式,上述二元醇包括乙氧化-2-甲基-1,3-丙二醇、乙二醇、1,4-环己烷二甲醇和2,2,4,4-四甲基-1,3-环丁烷二甲醇中的至少一种。
上述聚酯纤维具有较低的起始熔点及结晶熔点,受热时候会软化,从而发生粘性流动,使得织品中的其他纤维可藉由本发明的聚酯纤维粘合在一起,从而提升织品的结构强度,且使织品不易发生形变,同时各组分紧密结合提升了上述防水阻燃服装材料的防水性能。
根据本发明的一种实施方式,上述防水阻燃服装材料包括以下质量份的材料:
200-300份聚酯纤维与4-6份改性助剂;
所述改性助剂包括0.7-1.2份邻苯二甲酸二辛酯、1.5-2.5份水溶性树脂、0.8-1.8份石墨烯微、0.2-0.5份纳米铝粉和0.3-0.5份聚乙烯二醇。
根据本发明的一种实施方式,上述防水阻燃服装材料包括以下质量份的材料:
250份聚酯纤维与5份改性助剂;
所述改性助剂包括1.0份邻苯二甲酸二辛酯、1.8份水溶性树脂、1.1份石墨烯微、0.3份纳米铝粉和0.8份聚乙烯二醇。
为了解决上述第二个技术问题,本发明采用的技术方案为:
一种制备上述防水阻燃服装材料的方法,包括以下步骤:
S1将所述聚酯纤维进行织造加工,得到服装面料;
S2所述服装面料置于所述改性助剂中,15-30分钟后取出进行烘干;
S3将烘干后的所述服装面料在低温下冷冻3-5小时,取出烘干,得到所述防水阻燃服装材料。
根据本发明的一种实施方式,上述S2中还包括预烘烤的步骤。
根据本发明的一种实施方式,上述低温为-20℃到-23℃。
上述技术方案中的一个技术方案至少具有如下优点或有益效果之一:
1.上述改性助剂中所用的邻苯二甲酸二辛酯环境友好且具有一定抗菌效果与防静电效果,因此使得服装面料无需再额外添加防菌剂和防静电剂;
2.述石墨烯微使得上述防水阻燃服装材料具有优良的抗菌性、抗紫外等性能,可大幅减少服装上细菌,还提高了面料抗紫外性能,保护人体健康;
3.上述纳米铝粉可以提高上述防水阻燃服装材料的导电性能,从而提高防尘抗静电效果;
4.上述聚酯纤维具有较低的起始熔点及结晶熔点,受热时候会软化,从而发生粘性流动,使得织品中的其他组分可藉由本发明的聚酯纤维粘合在一起,从而提升织品的结构强度,使织品不易发生形变,同时各组分紧密结合提升了上述防水阻燃服装材料的防水性能;
5.本发明制备方法的生产工艺简单,易于操作,且产量较高,制备的上述防水阻燃服装材料防水、阻燃性能优越。
具体实施方式
为详细说明本发明的技术内容、所实现目的及效果,以下结合实施方式予以说明。
实施例1
一种制备上述的一种防水阻燃服装材料的方法,包括以下步骤:
S1将所述250g聚酯纤维进行织造加工,得到服装面料;
S2所述服装面料置于所述改性助剂中,30分钟后取出,先进行3分钟预烘干,然后再进行烘干;
S3将烘干后的所述服装面料在-22℃下冷冻3小时,取出烘干,得到所述防水阻燃服装材料。
上述改性助剂包括0.7份邻苯二甲酸二辛酯、1.5份水溶性树脂、0.8份石墨烯微、0.2份纳米铝粉和0.3份聚乙烯二醇。
上述250g聚酯纤维为70g对苯二甲酸、60g乙二醇、35g己二酸及42g乙二醇和43g1,4-环己烷二甲醇共聚合而成的聚酯纤维。
实施例2
一种制备上述的一种防水阻燃服装材料的方法,包括以下步骤:
S1将所述250g聚酯纤维进行织造加工,得到服装面料;
S2所述服装面料置于所述改性助剂中,30分钟后取出,先进行3分钟预烘干,然后再进行烘干;
S3将烘干后的所述服装面料在-22℃下冷冻3小时,取出烘干,得到所述防水阻燃服装材料。
上述改性助剂包括1.2份邻苯二甲酸二辛酯、2.5份水溶性树脂、1.8份石墨烯微、0.5份纳米铝粉和0.5份聚乙烯二醇。
上述250g聚酯纤维为70g对苯二甲酸、60g乙二醇、35g己二酸及42g乙二醇和43g1,4-环己烷二甲醇共聚合而成的聚酯纤维。
实施例3
一种制备上述的一种防水阻燃服装材料的方法,包括以下步骤:
S1将所述250g聚酯纤维进行织造加工,得到服装面料;
S2所述服装面料置于所述改性助剂中,30分钟后取出,先进行3分钟预烘干,然后再进行烘干;
S3将烘干后的所述服装面料在-22℃下冷冻3小时,取出烘干,得到所述防水阻燃服装材料。
上述改性助剂包括1.0份邻苯二甲酸二辛酯、1.8份水溶性树脂、1.1份石墨烯微、0.3份纳米铝粉和0.8份聚乙烯二醇。
上述250g聚酯纤维为70g对苯二甲酸、60g乙二醇、35g己二酸及42g乙二醇和43g1,4-环己烷二甲醇共聚合而成的聚酯纤维。
对比例1
一种制备上述的一种防水阻燃服装材料的方法,包括以下步骤:
S1将所述250g聚酯纤维进行织造加工,得到服装面料;
S2所述服装面料置于所述改性助剂中,30分钟后取出,先进行3分钟预烘干,然后再进行烘干;
S3将烘干后的所述服装面料在-22℃下冷冻3小时,取出烘干,得到所述防水阻燃服装材料。
上述改性助剂包括1.0份邻苯二甲酸二辛酯、1.8份水溶性树脂、1.1份石墨烯微、0.3份纳米铝粉和0.8份聚乙烯二醇。
上述聚酯纤维为聚对苯二甲酸丁二酯。
对比例2
一种制备上述的一种防水阻燃服装材料的方法,包括以下步骤:
S1将所述250g聚酯纤维进行织造加工,得到服装面料;
S2所述服装面料置于所述改性助剂中,30分钟后取出,先进行3分钟预烘干,然后再进行烘干;
S3将烘干后的所述服装面料在-22℃下冷冻3小时,取出烘干,得到所述防水阻燃服装材料。
上述改性助剂包括1.8份水溶性树脂。
上述250g聚酯纤维为70g对苯二甲酸、60g乙二醇、35g己二酸及42g乙二醇和43g1,4-环己烷二甲醇共聚合而成的聚酯纤维。
性能测试:
表1
Figure BDA0003210614860000061
由表一所得的实验数据,可以得出,本发明的制备的防水阻燃服装材料的防水阻燃性能显著优异于现有技术中的普通产品。
以上仅为本发明的实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书内容所作的等同变换,或直接或间接运用在相关的技术领域,均同理包括在本发明的专利保护范围内。

Claims (9)

1.一种防水阻燃服装材料,其特征在于:
包括聚酯纤维与改性助剂;
所述改性助剂包括邻苯二甲酸二辛酯、水溶性树脂、石墨烯微、纳米铝粉和聚乙烯二醇。
2.根据权利要求1所述的一种防水阻燃服装材料,其特征在于:
所述聚酯纤维为对苯二甲酸、乙二醇、二元酸及二元醇共聚合而成的聚酯纤维。
3.根据权利要求2所述的一种防水阻燃服装材料,其特征在于:
所述二元酸包括己二酸、癸二酸和邻苯二甲酸酐中的至少一种。
4.根据权利要求2所述的一种防水阻燃服装材料,其特征在于:
所述二元醇包括乙氧化-2-甲基-1,3-丙二醇、乙二醇、1,4-环己烷二甲醇和2,2,4,4-四甲基-1,3-环丁烷二甲醇中的至少一种。
5.根据权利要求1所述的一种防水阻燃服装材料,其特征在于:
所述防水阻燃服装材料包括以下质量份的材料:
200-300份聚酯纤维与4-6份改性助剂;
所述改性助剂包括0.7-1.2份邻苯二甲酸二辛酯、1.5-2.5份水溶性树脂、0.8-1.8份石墨烯微、0.2-0.5份纳米铝粉和0.3-0.5份聚乙烯二醇。
6.根据权利要求1所述的一种防水阻燃服装材料,其特征在于:
所述防水阻燃服装材料包括以下质量份的材料:
250份聚酯纤维与5份改性助剂;
所述改性助剂包括1.0份邻苯二甲酸二辛酯、1.8份水溶性树脂、1.1份石墨烯微、0.3份纳米铝粉和0.8份聚乙烯二醇。
7.一种制备如权利要求1至6任一项所述的一种防水阻燃服装材料的方法,其特征在于:包括以下步骤:
S1将所述聚酯纤维进行织造加工,得到服装面料;
S2所述服装面料置于所述改性助剂中,15-30分钟后取出进行烘干;
S3将烘干后的所述服装面料在低温下冷冻3-5小时,取出烘干,得到所述防水阻燃服装材料。
8.根据权利要求7所述的方法,其特征在于:
S2中还包括预烘烤的步骤。
9.根据权利要求7所述的方法,其特征在于:
所述低温为-20℃到-23℃。
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