CN113679081A - Spice essential oil for cigarettes and preparation method thereof - Google Patents
Spice essential oil for cigarettes and preparation method thereof Download PDFInfo
- Publication number
- CN113679081A CN113679081A CN202111048536.7A CN202111048536A CN113679081A CN 113679081 A CN113679081 A CN 113679081A CN 202111048536 A CN202111048536 A CN 202111048536A CN 113679081 A CN113679081 A CN 113679081A
- Authority
- CN
- China
- Prior art keywords
- essential oil
- coating
- hesperidin
- eugenol
- spice
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 53
- 235000013599 spices Nutrition 0.000 title claims abstract description 39
- 239000000341 volatile oil Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims abstract description 74
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims abstract description 52
- 239000011248 coating agent Substances 0.000 claims abstract description 49
- 238000000576 coating method Methods 0.000 claims abstract description 49
- QUQPHWDTPGMPEX-QJBIFVCTSA-N hesperidin Chemical compound C1=C(O)C(OC)=CC=C1[C@H]1OC2=CC(O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@@H](CO[C@H]4[C@@H]([C@H](O)[C@@H](O)[C@H](C)O4)O)O3)O)=CC(O)=C2C(=O)C1 QUQPHWDTPGMPEX-QJBIFVCTSA-N 0.000 claims abstract description 44
- 239000001100 (2S)-5,7-dihydroxy-2-(3-hydroxy-4-methoxyphenyl)chroman-4-one Substances 0.000 claims abstract description 43
- QUQPHWDTPGMPEX-UHFFFAOYSA-N Hesperidine Natural products C1=C(O)C(OC)=CC=C1C1OC2=CC(OC3C(C(O)C(O)C(COC4C(C(O)C(O)C(C)O4)O)O3)O)=CC(O)=C2C(=O)C1 QUQPHWDTPGMPEX-UHFFFAOYSA-N 0.000 claims abstract description 43
- QUQPHWDTPGMPEX-UTWYECKDSA-N aurantiamarin Natural products COc1ccc(cc1O)[C@H]1CC(=O)c2c(O)cc(O[C@@H]3O[C@H](CO[C@@H]4O[C@@H](C)[C@H](O)[C@@H](O)[C@H]4O)[C@@H](O)[C@H](O)[C@H]3O)cc2O1 QUQPHWDTPGMPEX-UTWYECKDSA-N 0.000 claims abstract description 43
- APSNPMVGBGZYAJ-GLOOOPAXSA-N clematine Natural products COc1cc(ccc1O)[C@@H]2CC(=O)c3c(O)cc(O[C@@H]4O[C@H](CO[C@H]5O[C@@H](C)[C@H](O)[C@@H](O)[C@H]5O)[C@@H](O)[C@H](O)[C@H]4O)cc3O2 APSNPMVGBGZYAJ-GLOOOPAXSA-N 0.000 claims abstract description 43
- VUYDGVRIQRPHFX-UHFFFAOYSA-N hesperidin Natural products COc1cc(ccc1O)C2CC(=O)c3c(O)cc(OC4OC(COC5OC(O)C(O)C(O)C5O)C(O)C(O)C4O)cc3O2 VUYDGVRIQRPHFX-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229940025878 hesperidin Drugs 0.000 claims abstract description 43
- ARGKVCXINMKCAZ-UHFFFAOYSA-N neohesperidine Natural products C1=C(O)C(OC)=CC=C1C1OC2=CC(OC3C(C(O)C(O)C(CO)O3)OC3C(C(O)C(O)C(C)O3)O)=CC(O)=C2C(=O)C1 ARGKVCXINMKCAZ-UHFFFAOYSA-N 0.000 claims abstract description 43
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000005770 Eugenol Substances 0.000 claims abstract description 36
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229960002217 eugenol Drugs 0.000 claims abstract description 36
- MXXWOMGUGJBKIW-YPCIICBESA-N piperine Chemical compound C=1C=C2OCOC2=CC=1/C=C/C=C/C(=O)N1CCCCC1 MXXWOMGUGJBKIW-YPCIICBESA-N 0.000 claims abstract description 34
- WVWHRXVVAYXKDE-UHFFFAOYSA-N piperine Natural products O=C(C=CC=Cc1ccc2OCOc2c1)C3CCCCN3 WVWHRXVVAYXKDE-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229940075559 piperine Drugs 0.000 claims abstract description 34
- 235000019100 piperine Nutrition 0.000 claims abstract description 34
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- 239000008103 glucose Substances 0.000 claims abstract description 27
- 229920001661 Chitosan Polymers 0.000 claims abstract description 26
- IYRMWMYZSQPJKC-UHFFFAOYSA-N kaempferol Chemical compound C1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 IYRMWMYZSQPJKC-UHFFFAOYSA-N 0.000 claims abstract description 18
- UBSCDKPKWHYZNX-UHFFFAOYSA-N Demethoxycapillarisin Natural products C1=CC(O)=CC=C1OC1=CC(=O)C2=C(O)C=C(O)C=C2O1 UBSCDKPKWHYZNX-UHFFFAOYSA-N 0.000 claims abstract description 9
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000008777 kaempferol Nutrition 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 claims abstract description 9
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 26
- 238000002156 mixing Methods 0.000 claims description 23
- 239000011162 core material Substances 0.000 claims description 19
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
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- 244000062241 Kaempferia galanga Species 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 8
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- 238000003756 stirring Methods 0.000 claims description 8
- 235000013421 Kaempferia galanga Nutrition 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 5
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- 230000002441 reversible effect Effects 0.000 claims description 2
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- 244000061176 Nicotiana tabacum Species 0.000 claims 1
- 238000000889 atomisation Methods 0.000 claims 1
- 241000208125 Nicotiana Species 0.000 abstract description 51
- 239000000796 flavoring agent Substances 0.000 abstract description 39
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- 230000000391 smoking effect Effects 0.000 abstract description 24
- 230000001681 protective effect Effects 0.000 abstract description 13
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- 230000000694 effects Effects 0.000 abstract description 4
- 230000007774 longterm Effects 0.000 abstract description 4
- 230000003111 delayed effect Effects 0.000 abstract description 3
- 239000003085 diluting agent Substances 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 21
- 239000003205 fragrance Substances 0.000 description 20
- 238000009792 diffusion process Methods 0.000 description 14
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 12
- 239000000686 essence Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- GLZPCOQZEFWAFX-JXMROGBWSA-N Nerol Natural products CC(C)=CCC\C(C)=C\CO GLZPCOQZEFWAFX-JXMROGBWSA-N 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000011259 mixed solution Substances 0.000 description 5
- 235000006886 Zingiber officinale Nutrition 0.000 description 4
- 244000273928 Zingiber officinale Species 0.000 description 4
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical compound CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 235000008397 ginger Nutrition 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 238000007873 sieving Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000628997 Flos Species 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 235000013355 food flavoring agent Nutrition 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- 241000243827 Nereis Species 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000010619 basil oil Substances 0.000 description 2
- 229940018006 basil oil Drugs 0.000 description 2
- 229960000846 camphor Drugs 0.000 description 2
- 229930008380 camphor Natural products 0.000 description 2
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 2
- 229940117916 cinnamic aldehyde Drugs 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
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- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
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- 238000005303 weighing Methods 0.000 description 2
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- 239000001169 1-methyl-4-propan-2-ylcyclohexa-1,4-diene Substances 0.000 description 1
- BGTBFNDXYDYBEY-FNORWQNLSA-N 4-(2,6,6-Trimethylcyclohex-1-enyl)but-2-en-4-one Chemical compound C\C=C\C(=O)C1=C(C)CCCC1(C)C BGTBFNDXYDYBEY-FNORWQNLSA-N 0.000 description 1
- -1 4-pentadienyl Chemical group 0.000 description 1
- NVEQFIOZRFFVFW-UHFFFAOYSA-N 9-epi-beta-caryophyllene oxide Natural products C=C1CCC2OC2(C)CCC2C(C)(C)CC21 NVEQFIOZRFFVFW-UHFFFAOYSA-N 0.000 description 1
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- 235000007129 Cuminum cyminum Nutrition 0.000 description 1
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- 235000009355 Dianthus caryophyllus Nutrition 0.000 description 1
- 240000006497 Dianthus caryophyllus Species 0.000 description 1
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 1
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- 240000000783 Origanum majorana Species 0.000 description 1
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- 239000006002 Pepper Substances 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 240000003889 Piper guineense Species 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/12—Steaming, curing, or flavouring tobacco
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/24—Treatment of tobacco products or tobacco substitutes by extraction; Tobacco extracts
- A24B15/26—Use of organic solvents for extraction
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0061—Essential oils; Perfumes compounds containing a six-membered aromatic ring not condensed with another ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention relates to the technical field of tobacco essence and spice, in particular to tobacco spice essential oil and a preparation method thereof. The spice essential oil for the cigarettes is used in tobacco shreds and comprises piperine, eugenol, kaempferol, hesperidin, glucose and chitosan. According to the application, the glucose and the chitosan are added into the essential oil, so that firstly, the glucose and the chitosan are used as diluents of the flavor components, the problem of overlarge irritation during smoking due to overhigh concentration of the flavor components is avoided, and the flavor components reach a proper degree of flavor; secondly, the problem of deterioration of the cigarette spice essential oil in the long-term storage process is prevented by taking glucose and chitosan as protective shells of the flavor components; thirdly, the protective shell is required to be broken to release the flavor components in the process of smoking the cut tobacco through the coating effect, so that the release of the flavor components is delayed.
Description
Technical Field
The invention relates to the technical field of tobacco essence and spice, in particular to tobacco spice essential oil and a preparation method thereof.
Background
As a novel tobacco product, the heating cigarette has great difference from the traditional cigarette in the aspects of material use, structural composition, smoking mode and the like. This makes the smoking experience of heated cigarettes as much different from that of conventional cigarettes, especially in terms of smoking comfort. At present, the tastes of the cigarettes sold and heated on the market are mainly divided into three categories: tobacco, mint, and various flavors. Heating cigarette is because its unique suction mode for some essences and low concentration essence commonly used in traditional cigarette are not applicable to the heating cigarette, and the essence in the heating cigarette often needs high concentration spices, causes like this that different types of products all have certain problem: tobacco is often irritating due to its high stiffness; mints tend to be bitter; the flavor also has the problems of certain bitter taste and poor comfort due to higher concentration of the essence. In view of these problems, there is a need to find a perfume that can better improve the smoking experience of the product.
At present, the research direction is more about spicy flavor tobacco essence, for example, the cigarette essence which is disclosed by a patent document with the publication number of CN111849637A and is heated without burning and is used for increasing the sweet taste of the oral cavity is characterized by comprising the following components in parts by weight: 9.3 to 25.5 portions of spicy flavoring agent, 3.4 to 16.5 portions of mouthfeel regulator, 12.9 to 33.7 portions of spicy flavoring agent and 24.3 to 74.4 portions of solvent. Each part of the spicy flavoring agent comprises the following components in parts by weight: 5-10 parts of clove bud oil; 0.5-3 parts of clove basil oil; 0.2-0.8 part of artemisia annua oil; 2-5 parts of patchouli oil; 1-5 parts of vetiver oil; 0.1-0.5 part of dill seed oil; 0.5-1.2 parts of damascone. For another example, a spicy base for improving smoking comfort of a heated cigarette disclosed in patent publication No. CN112457914A is characterized by comprising: according to the weight percentage, the main body of the spice is 10 to 90 percent, the solvent is 10 to 90 percent, and the sum of the two raw materials is 100 percent. The spice main body is at least one of natural spice extracts or spice composites; the natural spicy extract comprises at least one of star anise oil, cinnamon leaf oil, cinnamon bark oil, anise oil, sweet fennel oil, basil oil, cumin oil, caraway oil, nutmeg skin oil, celery seed oil or sweet marjoram oil; the spice composition comprises at least one of anethole, anisic aldehyde, methyl anisate, trans-anethole, anisic aldehyde, cinnamaldehyde, benzyl laurate, phellandrene, linalool, cinnamic aldehyde, cinnamic acetate, ethyl laurate, eugenol, cinnamic alcohol, ethyl laurate, caryophyllene, limonene or cineole.
Therefore, in the existing spicy flavor tobacco essence, most of different types of spices are simply combined together and then added into tobacco shreds, so that the various types of spices are mixed together and emitted when the tobacco shreds are used for smoking, and the irritation is large; and the fragrance amount of the first half section of the cigarette is still sufficient during smoking, but the fragrance amount is obviously reduced when the second half section of the cigarette is smoked, the fragrance amount before and after smoking is inconsistent, and the sensory experience of consumers is seriously influenced.
Disclosure of Invention
The invention aims to solve the problems and provides spice essential oil for cigarettes and a preparation method thereof.
The technical scheme for solving the problems is to provide the spice essential oil for the cigarettes, which is used in tobacco shreds and comprises piperine, eugenol, kaempferol, hesperidin, glucose and chitosan.
The invention also aims to provide a preparation method of the spice essential oil for the cigarettes, which comprises the following steps: the mixture of the piperine, the eugenol, the kaempferia galangal brain and the hesperidin is used as a core material, the mixture of the glucose and the chitosan is used as a wall material, and the core material is coated by the wall material to prepare the spice for the cigarette.
Piperine is a natural alkaloid isolated from pepper, also called 1- (5- (1, 3-benzodioxo-5-yl) -1-oxo-2, 4-pentadienyl (- (E, E) -piperidine, having pungent taste, eugenol is a component found in clove, also called 4-allyl-2-methoxyphenol, has the smell of carnation and the fragrance similar to clove oil, has strong vigor, is powerful and lasting, and has warm and pungent flavor, and the nereis brain is a component extracted from nereis, also called trans-p-methoxycinnamic acid ethyl ester, has unique aromatic smell, hesperidin is a flavonoid substance widely existing in citrus fruits, and has a chemical structure of dihydroflavodoxin structure. The flavors of the various flavor components are cooperated with each other, and the flavor components are used in the tobacco shreds and can bring good spicy smoking flavor to the tobacco shreds.
However, the fragrance components are easy to oxidize and deteriorate, so that glucose and chitosan are added into the essential oil, and firstly, the problem of overlarge irritation during smoking due to overhigh concentration of the fragrance components is avoided by using the glucose and the chitosan as diluents of the fragrance components, so that the fragrance components reach a proper degree; secondly, the problem of deterioration of the cigarette spice essential oil in the long-term storage process is prevented by taking glucose and chitosan as the protective shells of the components; thirdly, the protective shell is required to be broken to release the flavor components in the process of smoking the cut tobacco through the coating effect, so that the release of the flavor components is delayed. In the present application, the mechanism of the rupture of the protective sheath is that the pumping process is exothermic and the glucose is thermally decomposed, causing the protective sheath to rupture, so that the higher the temperature, the faster the protective sheath will rupture. During smoking, the temperature of the tobacco shred at the burning section is higher than that of the tobacco shred at the non-burning section, so that the fragrance component in the tobacco shred at the non-burning section can be prevented from being released in advance, and the fragrance quantity when the tobacco shred is smoked to the second half section of the cigarette is ensured. Furthermore, protective shells with different thicknesses can be designed by controlling the proportion of glucose and chitosan, the essential oil with the thicker protective shell is sprayed on the tobacco shreds in the rear half section of the cigarette, and the essential oil with the thinner protective shell is sprayed on the tobacco shreds in the front half section of the cigarette. Preferably, the mixing mass ratio of the chitosan to the glucose is 1: (5-10).
The mode of coating the core material with the wall material is not limited in the present application, and as a preferred aspect of the present invention, the step of coating the core material with the wall material comprises: adding glucose into a glacial acetic acid solution of chitosan, and stirring to obtain a viscous wall material; after the core material is added into the viscous wall material, the system is heated to 70-80 ℃ and stirred for 6-8 h. By this operation, the Maillard reaction between glucose and chitosan can be carried out to some extent, and the Maillard reaction product obtained not only has sugar flavor and can improve smoking flavor, but also has oxidation resistance and can further prevent flavor components from deteriorating.
In order to further slowly release the flavor components, the core material is preferably prepared by coating the mixture of the piperine, the eugenol and the alpinia galanga brain with the hesperidin. Further preferably, the mixture of piperine, eugenol and kaempferol is prepared by the following steps: coating the eugenol with another two parts of hesperidin to obtain a coating body 1; coating the coating body 1 with the piperine to obtain a coating body 2; coating the coating body 2 with another part of hesperidin to obtain a coating body 3; and coating the coating body 3 with the Kaempferia galangal brain to obtain a coating body 4.
The smoke released by the cut tobacco in the smoking process contains ammonia, and the hesperidin is dissolved in dilute alkali, so that other fragrance components are coated layer by taking the hesperidin as a coating material, different types of fragrance components can be released step by step, and the problem of large irritation caused by the simultaneous release of various fragrance components is avoided.
Hesperidin, piperine, eugenol and kaempferol have different dissolution characteristics: hesperidin is very slightly soluble in acetone and chloroform, but piperine, eugenol and kaempferine are all easily soluble in acetone and chloroform. Therefore, as a preferable mode of the invention, during coating, the hesperidin is atomized and sprayed in a solid form, and the piperine, the eugenol and the kaempferine are atomized and sprayed in a solution form. Preferably, the piperine, the eugenol and the kaempferine are dissolved by chloroform or acetone.
In the present invention, the amount of atomized spray of the coating material is preferably 3 to 7 times the amount of atomized spray of the material to be coated.
Preferably, in the coating of the present invention, the coating material is in reverse contact with the material to be coated.
The invention has the beneficial effects that:
1. according to the application, the hesperidin, the eugenol and the kaempferia galanga brain seed flavor components are creatively combined to form the tobacco essential oil, the flavors of the flavor components are mutually cooperated, and the essential oil is used in tobacco shreds and can bring good spicy smoking flavor to the tobacco shreds.
2. Glucose and chitosan are added into the essential oil, so that firstly, the problem of overlarge irritation during smoking due to overhigh concentration of the fragrance components is avoided by taking the glucose and the chitosan as diluents of the fragrance components, and the fragrance components reach the fragrance with proper degree; secondly, the problem of deterioration of the cigarette spice essential oil in the long-term storage process is prevented by taking glucose and chitosan as protective shells of the flavor components; thirdly, the protective shell is required to be broken to release the flavor components in the process of smoking the cut tobacco through the coating effect, so that the release of the flavor components is delayed.
Detailed Description
The following are specific embodiments of the present invention and further describe the technical solutions of the present invention, but the present invention is not limited to these examples.
Example 1
A preparation method of spice essential oil for cigarettes comprises the following steps:
preparing 1 part of piperine, 1 part of eugenol, 1 part of kaempferol, 15 parts of hesperidin, 30 parts of chitosan and 200 parts of glucose according to parts by mass.
Wherein the piperine is prepared by the following steps: pulverizing fructus Piperis powder, sieving with 40 mesh sieve, extracting with 95% ethanol at 55 deg.C under 200W microwave power for 25min at a solid-to-liquid ratio of 1: 8. Vacuum filtering the extract, and vacuum concentrating the filtrate until ethanol is evaporated to dryness.
Eugenol is prepared by the following steps: drying clean flos Caryophylli in oven at 75 deg.C for 2-4h, pulverizing, and sieving with 40 mesh sieve to obtain flos Caryophylli powder. Weighing flos Caryophylli powder, extracting with 85% ethanol at solid-to-liquid ratio = 1: 7 at 45 deg.C under microwave power of 200W for 10min for 3 times.
The Kaempferia galanga brain is prepared by the following steps: crushing the sand ginger, sieving the crushed sand ginger by a 40-mesh sieve, taking 95% ethanol as an extracting agent, extracting the sand ginger at the temperature of 45 ℃, with the microwave power of 200- & lt 250 & gt W, the extraction solid-liquid ratio = 1: 7, and extracting for 3 times within 10min each time.
The hesperidin is prepared by the following steps: weighing 25g of tangerine peel powder, and performing microwave extraction for 10min with 95% ethanol for 3 times at 60 ℃ with microwave power of 200W. Then Ca (OH) with a concentration of 10 g/L2Extracting pericarpium Citri Tangerinae powder residue with alkali extraction method (pH = 11.5) for 30min at 55 deg.C under 200W solid-liquid ratio of 1: 15), and adding Na 1 wt% of pericarpium Citri Tangerinae powder before microwave2SO3And after suction filtration, dropwise adding concentrated HCl into the filtrate at 50 ℃ in a water bath under stirring to ensure that the pH of an acid precipitation system is =4.5, quickly stirring for 45min under the condition, refrigerating overnight at 5 ℃, then performing suction filtration to obtain a precipitate, washing the precipitate for 2-3 times with distilled water, and performing vacuum drying on the dried precipitate at 55 ℃ for 3.5-4 hours to obtain the hesperidin product.
(1) Adding piperine, eugenol, rhizoma Kaempferiae brain, and hesperidin into ethanol solution, and mixing to obtain core material.
(2) Dissolving chitosan in 1% glacial acetic acid solution, and mixing with glucose aqueous solution to obtain the wall material.
(3) Preparing a Venturi ejector, and firstly enabling a wall material to enter from a nozzle of the ejector and to be ejected from a diffusion pipe after passing through a mixing pipe; then the core material enters from the suction chamber of the ejector and contacts with the wall material, and the core material and the wall material form the spice for the cigarettes through the mixing pipe and then are sprayed out from the diffusion pipe.
(4) Spraying the obtained spice for the cigarette onto the cut tobacco, wherein the mixing mass ratio of the spice for the cigarette to the cut tobacco is 3: 100, then delivering the cut tobacco into an environment with the temperature of 25 ℃ and the humidity of 60 percent for balancing for 24 hours, and packaging to obtain the cigarette.
Example 2
This embodiment is substantially the same as embodiment 1, except that:
and (3) directly dropwise adding the core material into the wall material at 75 ℃, stirring while dropwise adding, and continuously stirring for 7 hours after dropwise adding is finished to obtain the cigarette spice.
Example 3
This embodiment is substantially the same as embodiment 1, except that:
in the step (1), piperine, eugenol and kaempferol are added into 300 parts of acetone together to be dissolved to obtain a solution 1, and the hesperidin is sieved by a 500-mesh sieve. Preparing a Venturi ejector, and firstly enabling hesperidin and air to enter from a nozzle of the ejector together and to be ejected from a diffusion pipe after passing through a mixing pipe; then the solution 1 enters from the suction chamber of the ejector and contacts with hesperidin, and then the solution is sprayed out from the diffusion pipe after passing through a mixing pipe to form a core material.
Example 4
This embodiment is substantially the same as embodiment 1, except that:
in the step (1): sieving 15 parts of hesperidin by a 500-mesh sieve, and dividing into 3 parts, 5 parts and 7 parts; the piperine, the eugenol and the kaempferia galanga camphor are respectively added into 100 parts of acetone to be dissolved to obtain the piperine solution, the eugenol solution and the kaempferia galanga camphor solution.
Preparing a Venturi ejector, and firstly enabling 3 parts of hesperidin and air to enter from a nozzle of the ejector together and to be ejected from a diffusion pipe after passing through a mixing pipe; then the eugenol solution enters from the suction chamber of the ejector and contacts with the hesperidin, and then the eugenol solution passes through the mixing pipe to form a coating body 1 and then is ejected from the diffusion pipe.
Leading the piperine solution to enter from a nozzle of the ejector and be sprayed out from the diffusion pipe after passing through the mixing pipe; then the coating body 1 and air enter from the suction chamber of the ejector together, contact with piperine and form a coating body 2 through a mixing pipe together, and then are ejected from the diffusion pipe.
Enabling 5 parts of hesperidin and air to enter from a nozzle of a jet device together and to be sprayed out from a diffusion pipe after passing through a mixing pipe; then the coating body 2 enters from the suction chamber of the ejector and contacts with hesperidin, and then the coating body is sprayed out from the diffusion pipe after passing through a mixing pipe to form the coating body 3.
So that the Kaempferia galangal brain solution enters from a nozzle of the ejector, passes through the mixing pipe and is sprayed out from the diffusion pipe; then the coating body 3 and air enter from the suction chamber of the ejector together, contact with the sand ginger brain, pass through the mixing pipe together to form the coating body 4, and then are ejected from the diffusion pipe.
Enabling 7 parts of hesperidin and air to enter from a nozzle of a jet device together and to be sprayed out from a diffusion pipe after passing through a mixing pipe; then the coating body 4 enters from the suction chamber of the ejector and contacts with hesperidin, and then the coating body and the hesperidin form a core material through a mixing pipe and then the core material is ejected from a diffusion pipe.
In the step (3): directly adding the core material into the wall material at 70 ℃, stirring while dropwise adding, and continuously stirring for 8 hours after dropwise adding is finished to obtain the spice for cigarettes.
Example 5
This embodiment is substantially the same as embodiment 1, except that:
in the step (1), piperine, eugenol and kaempferol are added into 300 parts of acetone together to be dissolved to obtain a solution 1, and the hesperidin is sieved by a 500-mesh sieve. In the closed space, the hesperidin is sprayed from the top to the bottom, and then the solution 1 is sprayed from the bottom to the top, so that the solution 1 and the hesperidin reversely contact to form a core material.
Example 6
This embodiment is substantially the same as embodiment 1, except that:
preparing 1 part of piperine, 1 part of eugenol, 1 part of kaempferol, 15 parts of hesperidin, 30 parts of chitosan and 300 parts of glucose according to parts by mass.
In the step (4), the obtained spicery for the cigarette is sprayed on the cut tobacco, and the mixing mass ratio of the spicery for the cigarette to the cut tobacco is 3: 100, then sending the cut tobacco into an environment with the temperature of 25 ℃ and the humidity of 60 percent for balancing for 24 hours.
The tobacco shreds obtained in the embodiment and the tobacco shreds obtained in the embodiment 1 are mixed with equal mass to be made into cigarettes.
Comparative example 1
The piperine, the eugenol, the nerol and the hesperidin prepared in the embodiment 1 are selected, and 1 part of the piperine, 1 part of the eugenol, 1 part of the nerol and 15 parts of the hesperidin are added into 230 parts of absolute ethyl alcohol and uniformly mixed according to the parts by mass.
Spraying the obtained mixed solution on tobacco shreds, wherein the mixing mass ratio of the spicery for the tobacco to the tobacco shreds is 3: 100, then delivering the cut tobacco into an environment with the temperature of 25 ℃ and the humidity of 60 percent for balancing for 24 hours, and packaging to obtain the cigarette.
Comparative example 2
The piperine, the eugenol, the nerol and the hesperidin prepared in the embodiment 1 are selected, and 1 part of the piperine, 1 part of the eugenol, 1 part of the nerol and 15 parts of the hesperidin are added into 200 parts of absolute ethyl alcohol to be uniformly mixed according to the parts by mass, so that a mixed solution is obtained. And (3) dissolving 30 parts of chitosan in 1% glacial acetic acid solution, and dropwise adding the mixed solution into the chitosan solution to obtain the essence.
Spraying the obtained essence onto tobacco shreds, wherein the mixing mass ratio of the spicery for the tobacco to the tobacco shreds is 3: 100, then delivering the cut tobacco into an environment with the temperature of 25 ℃ and the humidity of 60 percent for balancing for 24 hours, and packaging to obtain the cigarette.
Comparative example 3
The piperine, the eugenol, the nerol and the hesperidin prepared in the embodiment 1 are selected, and 1 part of the piperine, 1 part of the eugenol, 1 part of the nerol and 15 parts of the hesperidin are added into 30 parts of absolute ethyl alcohol to be uniformly mixed according to the parts by mass, so that a mixed solution is obtained. And (3) after 200 parts of glucose solution is added into water, dropwise adding the mixed solution into the glucose solution to obtain the essence.
Spraying the obtained essence onto tobacco shreds, wherein the mixing mass ratio of the spicery for the tobacco to the tobacco shreds is 3: 100, then delivering the cut tobacco into an environment with the temperature of 25 ℃ and the humidity of 60 percent for balancing for 24 hours, and packaging to obtain the cigarette.
[ evaluation by aspiration ]
The tobacco shreds which are just balanced in the embodiment and the comparative example are respectively made into cigarettes, the cigarettes are divided into two batches, one batch is immediately subjected to smoking evaluation, the other batch is placed in the same environment and is kept stand for 10 days, the smoking evaluation is carried out by the sensory evaluation method of YC/T530-.
Table 1.
As shown in table 1, the cigarette manufactured in the examples of the present application showed no significant change in the amount of aroma before and after smoking, and also showed little change in the smoking aroma even after storage for a certain period of time, which was consistent. In comparative example 1, the flavor component is not coated, but is directly used in the tobacco shreds, which not only brings strong irritation, but also causes the problem of inconsistent flavor amount in the front and rear sections during smoking, and also causes the problem of reduced miscellaneous flavor and flavor amount due to loss and deterioration of flavor substances after the tobacco shreds are stored for a long time. In comparative example 2, the fragrance component was coated only with chitosan, and the protective shell thereof was not easily broken, which caused the fragrance component to hardly permeate out, so that the overall fragrance was not noticeable. In comparative example 3, only glucose was used to coat the flavor components, which resulted in poor coating effect and some loss of flavor substances after long-term storage of the tobacco shreds.
The specific embodiments described herein are merely illustrative of the spirit of the invention. Various modifications or additions may be made to the described embodiments or alternatives may be employed by those skilled in the art without departing from the spirit or ambit of the invention as defined in the appended claims.
Claims (10)
1. The cigarette spice essential oil is used in tobacco shreds, and is characterized in that: comprises piperine, eugenol, rhizoma Kaempferiae brain, hesperidin, glucose and chitosan.
2. The preparation method of the spice essential oil for the cigarettes according to claim 1, which is characterized by comprising the following steps: the method comprises the following steps: the mixture of the piperine, the eugenol, the kaempferia galangal brain and the hesperidin is used as a core material, the mixture of the glucose and the chitosan is used as a wall material, and the core material is coated by the wall material to prepare the spice for the cigarette.
3. The preparation method of the spice essential oil for the cigarettes according to claim 2, which is characterized by comprising the following steps: adding glucose into a glacial acetic acid solution of chitosan, and stirring to obtain a viscous wall material; after the core material is added into the viscous wall material, the system is heated to 70-80 ℃ and stirred for 6-8 h.
4. The preparation method of the spice essential oil for the cigarettes according to claim 2, which is characterized by comprising the following steps: the mixing mass ratio of the chitosan to the glucose is 1: (5-10).
5. The preparation method of the spice essential oil for the cigarettes according to claim 2, which is characterized by comprising the following steps: the core material is prepared by coating the mixture of the piperine, the eugenol and the galangal with the hesperidin.
6. The preparation method of the spice essential oil for the cigarettes according to claim 5, which is characterized by comprising the following steps: the mixture of piperine, eugenol and kaempferol is prepared by the following steps: coating the eugenol with another two parts of hesperidin to obtain a coating body 1; coating the coating body 1 with the piperine to obtain a coating body 2; coating the coating body 2 with another part of hesperidin to obtain a coating body 3; and coating the coating body 3 with the Kaempferia galangal brain to obtain a coating body 4.
7. The preparation method of the spice essential oil for the cigarettes according to claim 5 or 6, which is characterized by comprising the following steps of: during coating, the hesperidin is sprayed in a solid form in an atomizing mode, and the piperine, the eugenol and the kaempferine are sprayed in a solution form in an atomizing mode.
8. The preparation method of the spice essential oil for the cigarettes according to claim 7, which is characterized by comprising the following steps: the piperine, eugenol and kaempferia galanga brain are all dissolved by chloroform or acetone.
9. The preparation method of the spice essential oil for the cigarettes according to claim 7, which is characterized by comprising the following steps: the atomization spraying amount of the coating material is 3-7 times of that of the coated material.
10. The preparation method of the spice essential oil for the cigarettes according to claim 7, which is characterized by comprising the following steps: when coating, the coating material and the coated material are in reverse contact.
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| CN112457914A (en) * | 2020-10-27 | 2021-03-09 | 四川三联新材料有限公司 | Spicy base for improving smoking comfort of heated cigarettes and application thereof |
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