CN113667549A - Herbal laundry detergent for infants and preparation method thereof - Google Patents
Herbal laundry detergent for infants and preparation method thereof Download PDFInfo
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- CN113667549A CN113667549A CN202111136993.1A CN202111136993A CN113667549A CN 113667549 A CN113667549 A CN 113667549A CN 202111136993 A CN202111136993 A CN 202111136993A CN 113667549 A CN113667549 A CN 113667549A
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- 239000003599 detergent Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title description 9
- 241000196324 Embryophyta Species 0.000 claims abstract description 51
- 239000000463 material Substances 0.000 claims abstract description 34
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 32
- 239000004094 surface-active agent Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 21
- 229930182470 glycoside Natural products 0.000 claims abstract description 21
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 21
- 244000303040 Glycyrrhiza glabra Species 0.000 claims abstract description 13
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 claims abstract description 13
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 13
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 claims abstract description 13
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 claims abstract description 13
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 claims abstract description 13
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 claims abstract description 13
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 claims abstract description 13
- 235000011477 liquorice Nutrition 0.000 claims abstract description 13
- 241000123835 Ampelopsis japonica Species 0.000 claims abstract description 12
- 241000213006 Angelica dahurica Species 0.000 claims abstract description 12
- 241000218158 Clematis Species 0.000 claims abstract description 12
- 235000006679 Mentha X verticillata Nutrition 0.000 claims abstract description 12
- 235000002899 Mentha suaveolens Nutrition 0.000 claims abstract description 12
- 235000001636 Mentha x rotundifolia Nutrition 0.000 claims abstract description 12
- 241001071795 Gentiana Species 0.000 claims abstract description 11
- 241001180876 Saposhnikovia Species 0.000 claims abstract description 11
- MFYSUUPKMDJYPF-UHFFFAOYSA-N 2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC1=CC=C(C)C=C1[N+]([O-])=O MFYSUUPKMDJYPF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 241000219784 Sophora Species 0.000 claims abstract description 9
- 241000972673 Phellodendron amurense Species 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims description 40
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 32
- 239000000706 filtrate Substances 0.000 claims description 24
- 238000005303 weighing Methods 0.000 claims description 24
- 238000001816 cooling Methods 0.000 claims description 12
- 238000009835 boiling Methods 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 10
- 238000007789 sealing Methods 0.000 claims description 9
- 238000011049 filling Methods 0.000 claims description 6
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 6
- 230000001376 precipitating effect Effects 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 3
- 244000301850 Cupressus sempervirens Species 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 13
- 239000004744 fabric Substances 0.000 abstract description 9
- 230000006378 damage Effects 0.000 abstract description 8
- 230000000840 anti-viral effect Effects 0.000 abstract description 5
- 239000000049 pigment Substances 0.000 abstract description 5
- 239000013543 active substance Substances 0.000 abstract description 2
- 239000002781 deodorant agent Substances 0.000 abstract 1
- 230000007794 irritation Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 208000003251 Pruritus Diseases 0.000 description 5
- 238000005202 decontamination Methods 0.000 description 5
- 230000003588 decontaminative effect Effects 0.000 description 5
- 238000004659 sterilization and disinfection Methods 0.000 description 5
- 241000191967 Staphylococcus aureus Species 0.000 description 4
- 244000052616 bacterial pathogen Species 0.000 description 4
- 238000005238 degreasing Methods 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 208000000509 infertility Diseases 0.000 description 4
- 230000036512 infertility Effects 0.000 description 4
- 208000021267 infertility disease Diseases 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 231100000344 non-irritating Toxicity 0.000 description 4
- 231100000252 nontoxic Toxicity 0.000 description 4
- 230000003000 nontoxic effect Effects 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 230000008719 thickening Effects 0.000 description 4
- 241001480043 Arthrodermataceae Species 0.000 description 3
- 241000193830 Bacillus <bacterium> Species 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- 241000218691 Cupressaceae Species 0.000 description 3
- 201000004624 Dermatitis Diseases 0.000 description 3
- 206010020751 Hypersensitivity Diseases 0.000 description 3
- 208000026935 allergic disease Diseases 0.000 description 3
- 230000007815 allergy Effects 0.000 description 3
- 208000010668 atopic eczema Diseases 0.000 description 3
- 230000037304 dermatophytes Effects 0.000 description 3
- 230000007803 itching Effects 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000255925 Diptera Species 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- 229930013930 alkaloid Natural products 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 208000001848 dysentery Diseases 0.000 description 2
- 230000001717 pathogenic effect Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- GWGNIPFKFKKFLB-UHFFFAOYSA-N 1,5,5-trichloro-2-(4,4,6-trichloro-6-hydroxycyclohex-2-en-1-yl)oxycyclohex-3-en-1-ol Chemical compound OC1(Cl)CC(Cl)(Cl)C=CC1OC1C(Cl)(O)CC(Cl)(Cl)C=C1 GWGNIPFKFKKFLB-UHFFFAOYSA-N 0.000 description 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- 206010063409 Acarodermatitis Diseases 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 235000016811 Biondella Nutrition 0.000 description 1
- 241001515917 Chaetomium globosum Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 206010021531 Impetigo Diseases 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 206010023126 Jaundice Diseases 0.000 description 1
- 206010024229 Leprosy Diseases 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- 241000447727 Scabies Species 0.000 description 1
- 241001530209 Swertia Species 0.000 description 1
- 241001136494 Talaromyces funiculosus Species 0.000 description 1
- 241000223261 Trichoderma viride Species 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000172 allergic effect Effects 0.000 description 1
- 230000003266 anti-allergic effect Effects 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229960005443 chloroxylenol Drugs 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 201000005404 rubella Diseases 0.000 description 1
- 208000005687 scabies Diseases 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to an infant herbal laundry detergent which comprises the following raw materials in parts by weight: 21% -27.5% of plant material, 15% -30% of surfactant, 0.1% of ethylparaben, auxiliary agent and the balance of water, wherein the plant material is prepared from the following components in parts by weight: 2 to 3 parts of gentian, 2 to 3 parts of clematis root, 4 to 5 parts of rhizoma atractylodis, 2 to 2.5 parts of ampelopsis japonica, 1 to 1.5 parts of divaricate saposhnikovia root, 0.5 part of liquorice, 1.5 parts of lightyellow sophora root, 3 to 4 parts of angelica dahurica, 1.5 to 2 parts of mint and 3.5 to 4.5 parts of amur corktree bark; the surfactant is prepared from the following raw materials in parts by weight: the antibacterial deodorant is prepared from 18-20 parts of imidazoline, 9-10 parts of alkyl glycoside, 2007-8 parts of ET, and 1-1.5 parts of sodium dodecyl sulfate by combining a flexible active agent with natural antibacterial and antiviral plant components, does not contain essence and pigment, does not irritate skin, does not damage fabrics, and is safe and environment-friendly.
Description
Technical Field
The invention relates to the technical field of laundry detergents, in particular to an infant herbal laundry detergent and a preparation method thereof.
Background
In spring and winter every year, sunlight is reduced, clothes are not dried thoroughly and are easy to breed various germs, most of germs cannot be eliminated after general clothes detergents are washed, so that the germs are left on the clothes, the clothes which are not dried thoroughly are easy to contact with germs, skin inflammation is caused, newborns are easy to be infected by staphylococcus aureus and grow impetigo, and mildew prevention and sterilization are the effects which are most expected by consumers.
At present, chemical bactericides such as 2,4, 4-trichloro-2-hydroxyphenyl ether, chloroxylenol, triclosan and triclocarban are mainly added into the degerming detergent in the market, most of the chemical bactericides have high irritation and are harmful to health after being used for a long time, the chemical additives can affect human skin to a certain degree, and the skin can be affected after being soaked in the laundry detergent, so that the skin is rough, carries bacteria or is allergic.
Disclosure of Invention
In order to overcome the technical defects in the prior art, the invention provides the herbal laundry detergent for the infants and the preparation method thereof, which combines a flexible active agent and natural antibacterial and antiviral plant components, does not contain essence and pigment, does not stimulate the skin, does not hurt the fabrics, and is safe and environment-friendly.
The technical solution adopted by the invention is as follows:
the herbal laundry detergent for infants comprises the following raw materials in parts by weight: 21 to 27.5 percent of plant material, 15 to 30 percent of surfactant, 0.1 percent of ethylparaben, auxiliary agent and the balance of water,
the plant material is prepared from the following components in parts by weight:
2 to 3 parts of gentian, 2 to 3 parts of clematis root, 4 to 5 parts of rhizoma atractylodis, 2 to 2.5 parts of ampelopsis japonica, 1 to 1.5 parts of divaricate saposhnikovia root, 0.5 part of liquorice, 1.5 parts of lightyellow sophora root, 3 to 4 parts of angelica dahurica, 1.5 to 2 parts of mint and 3.5 to 4.5 parts of amur corktree bark;
the surfactant is prepared from the following raw materials in parts by weight:
18-20 parts of imidazoline, 9-10 parts of alkyl glycoside, 2007-8 parts of ET, and 1-1.5 parts of sodium dodecyl sulfate.
Preferably, the plant material is prepared from the following components in parts by weight:
2 parts of gentian, 2 parts of clematis root, 4 parts of rhizoma atractylodis, 2 parts of ampelopsis japonica, 1 part of divaricate saposhnikovia root, 0.5 part of liquorice, 1.5 parts of radix sophorae flavescentis, 3 parts of angelica dahurica, 1.5 parts of mint and 3.5 parts of golden cypress.
Preferably, the plant material is prepared from the following components in parts by weight:
3 parts of gentian, 3 parts of clematis root, 5 parts of rhizoma atractylodis, 2.5 parts of ampelopsis japonica, 1.5 parts of divaricate saposhnikovia root, 0.5 part of liquorice, 1.5 parts of lightyellow sophora root, 4 parts of angelica dahurica, 2 parts of mint and 4.5 parts of amur corktree bark.
Preferably, the surfactant is prepared from the following raw materials in parts by weight:
imidazoline 18 parts, alkyl glycoside 9 parts, ET2007 part and sodium dodecyl sulfate 1 part.
Preferably, the surfactant is prepared from the following raw materials in parts by weight:
20 parts of imidazoline, 10 parts of alkyl glycoside, 2008 parts of ET and 1.5 parts of sodium dodecyl sulfate.
Preferably, the mass fraction of the surfactant is 15%.
The preparation method of the herbal laundry detergent for infants comprises the following steps:
s1: weighing the plant materials after the carefully selected impurities are removed according to the parts by weight, putting the plant materials into a sealing pot, putting 4-6 times of water into the sealing pot, and tightly covering the pot cover of the sealing pot;
s2: placing the stored sealed pot into a hot water kettle, stewing for ten hours in a waterproof way, and controlling the temperature in the sealed pot to be between 98 and 100 ℃;
s3: naturally cooling to room temperature, and separating juice and residues to obtain filtrate A;
s4: filtering and precipitating the filtrate A obtained in the step S3 to obtain a precipitated filtrate B;
s5: boiling and killing the filtrate B in the S4 again to obtain sterile liquid A;
s6: pouring the sterile liquid A into a stirring kettle heated in a water-proof way for stirring, wherein the stirring temperature is 40-60 ℃;
s7: weighing sodium dodecyl sulfate, dissolving to obtain a sodium dodecyl sulfate solution, weighing the sodium dodecyl sulfate solution, imidazoline, alkyl glycoside and ET200, and sequentially adding the sterile liquid A;
s8: the auxiliary agent is edible citric acid, the edible citric acid is poured into the sterile liquid A in S7, and the pH value of the sterile liquid A is controlled to be 6.8-7.5;
s9: weighing ethylparaben according to the weight parts, adding sterile liquid A in S8, and then stopping stirring;
s10: naturally cooling and filling.
Preferably, the stirring speed in the steps S6 to S9 is 15 revolutions per minute.
The invention has the beneficial effects that:
1. the invention adopts natural antiviral and antibacterial plant raw materials, does not contain pigment and essence, does not irritate skin, does not damage fabrics, is safe and environment-friendly, has obvious skin care and antibacterial effects and stable quality.
2. The laundry detergent is prepared by combining the natural plant extract and the surfactant, so that effective decontamination, bacteriostasis and no stimulation are realized.
3. Among the natural plants used in the present invention:
the felwort water-soaking agent has different degrees of inhibiting effects on various pathogenic dermatophytes, pseudomonas aeruginosa, dysentery bacillus, staphylococcus aureus, etc., can eliminate cold bacillus and jaundice, has bitter taste and cold property, can clear heat and eliminate dampness, and can be used for external application for diminishing inflammation and relieving itching.
Clematis root: and (4) mold repelling.
Rhizoma atractylodis: sterilizing, detoxicating and refreshing air.
Ampelopsis japonica: expelling dermatophytes.
Wind prevention: dispel dampness, repel mosquitoes.
The liquorice has the functions of resisting allergy and neutralizing cold and heat of plants.
The main extracted components of the lightyellow sophora root are alkaloids, and the alkaloids have obvious bacteriostatic action on escherichia coli, staphylococcus aureus, dysentery bacillus and various dermatophytes; meanwhile, because the medicine clears heat and dries dampness, the medicine can be used for treating and preventing eczema, skin itch, scabies, leprosy and the like, and has the functions of detoxifying and killing insects.
The angelica dahurica and the like have the effects of sterilizing escherichia coli and staphylococcus aureus, moistening skin and relieving itching, and have the mildew-proof effect on aspergillus niger, trichoderma viride, penicillium funiculosum and chaetomium globosum; and with the increase of the mildew-proof and bacteria-removing functional components, the mildew-proof and bacteria-removing effects are enhanced.
Mint is used for treating rubella and relieving itching and has the function of expelling mosquitoes.
Cortex Phellodendri has effects of clearing heat, eliminating dampness, purging pathogenic fire, removing steam, removing toxic substance and treating sore, and can be used for preventing and treating pyocutaneous disease, skin eczema and pruritus by washing with decoction.
Detailed Description
The invention is further illustrated below:
example 1
The embodiment provides an infant herbal laundry detergent which comprises the following raw materials in parts by weight: 21 percent of plant material, 15 percent of surfactant, 0.1 percent of ethylparaben, auxiliary agent and the balance of water,
the plant material is prepared from the following components in parts by weight:
2 parts of gentian, 2 parts of clematis root, 4 parts of rhizoma atractylodis, 2 parts of ampelopsis japonica, 1 part of divaricate saposhnikovia root, 0.5 part of liquorice, 1.5 parts of radix sophorae flavescentis, 3 parts of angelica dahurica, 1.5 parts of mint and 3.5 parts of golden cypress.
The surfactant is prepared from the following raw materials in parts by weight:
the laundry detergent is prepared by combining 18 parts of imidazoline, 9 parts of alkyl glycoside, 2007 parts of ET and 1 part of lauryl sodium sulfate by using a surfactant special for infants, does not irritate skin, does not damage fabrics, is safe and environment-friendly, and can effectively decontaminate and inhibit bacteria without irritation.
Imidazoline, has excellent foaming property and has the capability of sterilization and disinfection. More importantly, it is non-irritating to the skin and eyes. The alkyl glycoside is nontoxic, has little irritation to skin, is safe, and has remarkable thickening, viscosity increasing and detergency. Sodium dodecyl sulfate has strong degreasing capability.
The preparation method of the herbal laundry detergent for infants comprises the following steps:
s1: weighing the carefully-selected and impurity-removed plant materials in parts by weight, putting the plant materials into a sealing pot, putting 4 times of water into the sealing pot, and tightly covering the pot cover of the sealing pot;
s2: placing the sealed pot storing the materials into a hot water kettle, stewing for ten hours in a water-proof way, controlling the temperature in the sealed pot at 98 ℃, and stewing in the water-proof way, wherein the stewed liquid can be better kept clear, the filtering is easy, the natural plant components can be kept from being volatilized, the boiling water is utilized for heat energy conduction, the heating power is uniform and balanced, the natural plant components are not sticky and scorched, and the structure of the natural plant components is not damaged;
s3: naturally cooling to room temperature, and separating juice and residues to obtain filtrate A;
s4: filtering and precipitating the filtrate A obtained in the step S3 to obtain a precipitated filtrate B;
s5: boiling and killing the filtrate B in the S4 again to obtain sterile liquid A, and further ensuring the sterility;
s6: pouring the sterile liquid A into a stirring kettle heated in a water-proof way for stirring, wherein the stirring speed is 15 revolutions per minute, and the stirring temperature is 40 ℃;
s7: weighing sodium dodecyl sulfate, dissolving to obtain a sodium dodecyl sulfate solution, weighing the sodium dodecyl sulfate solution, imidazoline, alkyl glycoside and ET200, and sequentially adding sterile liquid A to prevent the high-concentration solution from mixing to generate precipitate;
s8: the auxiliary agent is edible citric acid, the edible citric acid is poured into sterile liquid A in S7, and the pH value of the sterile liquid A is controlled at 6.8;
s9: weighing ethylparaben according to the weight parts, adding sterile liquid A in S8 to prevent oxidation, and then stopping stirring;
s10: naturally cooling and filling.
Example 2
The embodiment provides an infant herbal laundry detergent which comprises the following raw materials in parts by weight: 25 percent of plant material, 20 percent of surfactant, 0.1 percent of ethylparaben, auxiliary agent and the balance of water,
the plant material is prepared from the following components in parts by weight:
3 parts of gentian, 3 parts of clematis root, 5 parts of rhizoma atractylodis, 2.5 parts of ampelopsis japonica, 1.5 parts of divaricate saposhnikovia root, 0.5 part of liquorice, 1.5 parts of lightyellow sophora root, 4 parts of angelica dahurica, 2 parts of mint and 4.5 parts of amur corktree bark, adopts natural antiviral and antibacterial plant raw materials, does not contain pigment and essence, does not stimulate the skin, does not damage fabrics, is safe and environment-friendly, has obvious skin-care and antibacterial effects and stable quality.
The surfactant is prepared from the following raw materials in parts by weight:
20 parts of imidazoline, 10 parts of alkyl glycoside, ET2008 parts and 1.5 parts of sodium dodecyl sulfate, and the laundry detergent prepared by combining the surfactants special for infants does not irritate skin, does not damage fabrics, is safe and environment-friendly, and realizes effective decontamination, bacteriostasis and no irritation.
Imidazoline, has excellent foaming property and has the capability of sterilization and disinfection. More importantly, it is non-irritating to the skin and eyes. The alkyl glycoside is nontoxic, has little irritation to skin, is safe, and has remarkable thickening, viscosity increasing and detergency. Sodium dodecyl sulfate has strong degreasing capability.
The preparation method of the herbal laundry detergent for infants comprises the following steps:
s1: weighing the carefully-selected and impurity-removed plant materials in parts by weight, putting the plant materials into a sealed pot, putting 5 times of water into the sealed pot, and tightly covering the pot cover of the sealed pot;
s2: placing the sealed pot storing the materials into a hot water kettle, stewing for ten hours in a water-proof way, controlling the temperature in the sealed pot at 99 ℃, and stewing in the water-proof way, wherein the stewed liquid can be better kept clear, the filtering is easy, the natural plant components can be kept from being volatilized, the boiling water is utilized for heat energy conduction, the heating power is uniform and balanced, the natural plant components are not sticky and scorched, and the structure of the natural plant components is not damaged;
s3: naturally cooling to room temperature, and separating juice and residues to obtain filtrate A;
s4: filtering and precipitating the filtrate A obtained in the step S3 to obtain a precipitated filtrate B;
s5: boiling and killing the filtrate B in the S4 again to obtain sterile liquid A, and further ensuring the sterility;
s6: pouring the sterile liquid A into a stirring kettle heated in a water-proof way for stirring, wherein the stirring temperature is 50 ℃, and the stirring speed is 15 revolutions per minute;
s7: weighing sodium dodecyl sulfate, dissolving to obtain a sodium dodecyl sulfate solution, weighing the sodium dodecyl sulfate solution, imidazoline, alkyl glycoside and ET200, and sequentially adding sterile liquid A to prevent the high-concentration solution from mixing to generate precipitate;
s8: the auxiliary agent is edible citric acid, the edible citric acid is poured into sterile liquid A in S7, and the pH value of the sterile liquid A is controlled at 7;
s9: weighing ethylparaben according to the weight parts, adding sterile liquid A in S8 to prevent oxidation, and then stopping stirring;
s10: naturally cooling and filling.
The stirring speed in steps S6 to S9 was 15 revolutions per minute.
Example 3
The embodiment provides an infant herbal laundry detergent which comprises the following raw materials in parts by weight: 27.5 percent of plant material, 30 percent of surfactant, 0.1 percent of ethylparaben, auxiliary agent and the balance of water,
the plant material is prepared from the following components in parts by weight:
3 parts of gentian, 3 parts of clematis root, 5 parts of rhizoma atractylodis, 2.5 parts of ampelopsis japonica, 1.5 parts of divaricate saposhnikovia root, 0.5 part of liquorice, 1.5 parts of lightyellow sophora root, 4 parts of angelica dahurica, 2 parts of mint and 4.5 parts of amur corktree bark, adopts natural antiviral and antibacterial plant raw materials, does not contain pigment and essence, does not stimulate the skin, does not damage fabrics, is safe and environment-friendly, has obvious skin-care and antibacterial effects and stable quality.
The surfactant is prepared from the following raw materials in parts by weight:
20 parts of imidazoline, 10 parts of alkyl glycoside, ET2008 parts and 1.5 parts of sodium dodecyl sulfate, and the laundry detergent prepared by combining the surfactants special for infants does not irritate skin, does not damage fabrics, is safe and environment-friendly, and realizes effective decontamination, bacteriostasis and no irritation.
Imidazoline, has excellent foaming property and has the capability of sterilization and disinfection. More importantly, it is non-irritating to the skin and eyes. The alkyl glycoside is nontoxic, has little irritation to skin, is safe, and has remarkable thickening, viscosity increasing and detergency. Sodium dodecyl sulfate has strong degreasing capability. .
The preparation method of the herbal laundry detergent for infants comprises the following steps:
s1: weighing the carefully-selected and impurity-removed plant materials in parts by weight, putting the plant materials into a sealed pot, putting 6 times of water into the sealed pot, and tightly covering the pot cover of the sealed pot;
s2: placing the sealed pot storing the materials into a hot water kettle, stewing for ten hours in a water-proof way, controlling the temperature in the sealed pot at 100 ℃, and stewing in the water-proof way, wherein the stewed liquid can be better kept clear, the filtering is easy, the natural plant components can be kept from being volatilized, the boiling water is utilized for heat energy conduction, the heating power is uniform and balanced, the natural plant components are not sticky and scorched, and the structure of the natural plant components is not damaged;
s3: naturally cooling to room temperature, and separating juice and residues to obtain filtrate A;
s4: filtering and precipitating the filtrate A obtained in the step S3 to obtain a precipitated filtrate B;
s5: boiling and killing the filtrate B in the S4 again to obtain sterile liquid A, and further ensuring the sterility;
s6: pouring the sterile liquid A into a stirring kettle heated in a water-proof way for stirring, wherein the stirring temperature is 60 ℃, and the stirring speed is 15 revolutions per minute;
s7: weighing sodium dodecyl sulfate, dissolving to obtain a sodium dodecyl sulfate solution, weighing the sodium dodecyl sulfate solution, imidazoline, alkyl glycoside and ET200, and sequentially adding sterile liquid A to prevent the high-concentration solution from mixing to generate precipitate;
s8: the auxiliary agent is edible citric acid, the edible citric acid is poured into sterile liquid A in S7, and the pH value of the sterile liquid A is controlled at 7.5;
s9: weighing ethylparaben according to the weight parts, adding sterile liquid A in S8 to prevent oxidation, and then stopping stirring;
s10: naturally cooling and filling.
Comparative example 1
The embodiment provides an infant herbal laundry detergent which comprises the following raw materials in parts by weight: 25 percent of plant material, 20 percent of surfactant, 0.1 percent of ethylparaben, auxiliary agent and the balance of water,
the plant material is prepared from the following components in parts by weight:
3 parts of gentian, 3 parts of clematis root, 5 parts of rhizoma atractylodis, 2.5 parts of ampelopsis japonica, 1.5 parts of divaricate saposhnikovia root, 1.5 parts of lightyellow sophora root, 4 parts of angelica dahurica, 2 parts of mint and 4.5 parts of golden cypress.
The surfactant is prepared from the following raw materials in parts by weight:
20 parts of imidazoline, 10 parts of alkyl glycoside, ET2008 parts and 1.5 parts of sodium dodecyl sulfate, and the laundry detergent prepared by combining the surfactants special for infants does not irritate skin, does not damage fabrics, is safe and environment-friendly, and realizes effective decontamination, bacteriostasis and no irritation.
Imidazoline, has excellent foaming property and has the capability of sterilization and disinfection. More importantly, it is non-irritating to the skin and eyes. The alkyl glycoside is nontoxic, has little irritation to skin, is safe, and has remarkable thickening, viscosity increasing and detergency. Sodium dodecyl sulfate has strong degreasing capability.
The preparation method of the herbal laundry detergent for infants comprises the following steps:
s1: weighing the carefully-selected and impurity-removed plant materials in parts by weight, putting the plant materials into a sealed pot, putting 5 times of water into the sealed pot, and tightly covering the pot cover of the sealed pot;
s2: placing the sealed pot storing the materials into a hot water kettle, stewing for ten hours in a water-proof way, controlling the temperature in the sealed pot at 99 ℃, and stewing in the water-proof way, wherein the stewed liquid can be better kept clear, the filtering is easy, the natural plant components can be kept from being volatilized, the boiling water is utilized for heat energy conduction, the heating power is uniform and balanced, the natural plant components are not sticky and scorched, and the structure of the natural plant components is not damaged;
s3: naturally cooling to room temperature, and separating juice and residues to obtain filtrate A;
s4: filtering and precipitating the filtrate A obtained in the step S3 to obtain a precipitated filtrate B;
s5: boiling and killing the filtrate B in the S4 again to obtain sterile liquid A, and further ensuring the sterility;
s6: pouring the sterile liquid A into a stirring kettle heated in a water-proof way for stirring, wherein the stirring temperature is 50 ℃, and the stirring speed is 15 revolutions per minute;
s7: weighing sodium dodecyl sulfate, dissolving to obtain a sodium dodecyl sulfate solution, weighing the sodium dodecyl sulfate solution, imidazoline, alkyl glycoside and ET200, and sequentially adding sterile liquid A to prevent the high-concentration solution from mixing to generate precipitate;
s8: the auxiliary agent is edible citric acid, the edible citric acid is poured into sterile liquid A in S7, and the pH value of the sterile liquid A is controlled at 7;
s9: weighing ethylparaben according to the weight parts, adding sterile liquid A in S8 to prevent oxidation, and then stopping stirring;
s10: naturally cooling and filling.
The stirring speed in steps S6 to S9 was 15 revolutions per minute.
Effects of use
The skin care laundry detergent prepared in the examples 1-3 is selected randomly to clean clothes, the skin of the experimenter before and after cleaning is observed, and the result shows that the laundry detergent has the antibacterial and decontamination effects, no allergy occurs to the skin of an infant, the skin of the experimenter 20 is selected randomly, the skin of the experimenter before and after cleaning is observed to clean the clothes, and the result shows that although bacteria and mould are well inhibited, two people have allergy symptoms, so that the effect that liquorice added into each antibacterial natural plant component has an antiallergic function, and the liquorice can neutralize the cold and heat of the plant.
While there have been shown and described what are at present considered the fundamental principles and essential features of the invention and its advantages, it will be understood by those skilled in the art that the invention is not limited by the embodiments described above, which are merely illustrative of the principles of the invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the invention as defined by the appended claims and their equivalents.
Claims (8)
1. The herbal laundry detergent for infants is characterized by comprising the following raw materials in parts by weight: 21 to 27.5 percent of plant material, 15 to 30 percent of surfactant, 0.1 percent of ethylparaben, auxiliary agent and the balance of water,
the plant material is prepared from the following components in parts by weight:
2 to 3 parts of gentian, 2 to 3 parts of clematis root, 4 to 5 parts of rhizoma atractylodis, 2 to 2.5 parts of ampelopsis japonica, 1 to 1.5 parts of divaricate saposhnikovia root, 0.5 part of liquorice, 1.5 parts of lightyellow sophora root, 3 to 4 parts of angelica dahurica, 1.5 to 2 parts of mint and 3.5 to 4.5 parts of amur corktree bark;
the surfactant is prepared from the following raw materials in parts by weight:
18-20 parts of imidazoline, 9-10 parts of alkyl glycoside, 2007-8 parts of ET, and 1-1.5 parts of sodium dodecyl sulfate.
2. The herbal infant laundry detergent of claim 1, wherein the plant material is prepared from the following components in parts by weight:
2 parts of gentian, 2 parts of clematis root, 4 parts of rhizoma atractylodis, 2 parts of ampelopsis japonica, 1 part of divaricate saposhnikovia root, 0.5 part of liquorice, 1.5 parts of radix sophorae flavescentis, 3 parts of angelica dahurica, 1.5 parts of mint and 3.5 parts of golden cypress.
3. The herbal infant laundry detergent of claim 1, wherein the plant material is prepared from the following components in parts by weight:
3 parts of gentian, 3 parts of clematis root, 5 parts of rhizoma atractylodis, 2.5 parts of ampelopsis japonica, 1.5 parts of divaricate saposhnikovia root, 0.5 part of liquorice, 1.5 parts of lightyellow sophora root, 4 parts of angelica dahurica, 2 parts of mint and 4.5 parts of amur corktree bark.
4. The herbal infant laundry detergent of claim 1, wherein the surfactant is prepared from the following raw materials in parts by weight:
imidazoline 18 parts, alkyl glycoside 9 parts, ET2007 part and sodium dodecyl sulfate 1 part.
5. The herbal infant laundry detergent of claim 1, wherein the surfactant is prepared from the following raw materials in parts by weight:
20 parts of imidazoline, 10 parts of alkyl glycoside, 2008 parts of ET and 1.5 parts of sodium dodecyl sulfate.
6. The herbal infant laundry detergent of claim 1, wherein the surfactant is 15% by mass.
7. The method for preparing herbal laundry detergent for infants according to any one of claims 1 to 6, characterized in that the method comprises the following steps:
s1: weighing the plant materials after the carefully selected impurities are removed according to the parts by weight, putting the plant materials into a sealing pot, putting 4-6 times of water into the sealing pot, and tightly covering the pot cover of the sealing pot;
s2: placing the stored sealed pot into a hot water kettle, stewing for ten hours in a waterproof way, and controlling the temperature in the sealed pot to be between 98 and 100 ℃;
s3: naturally cooling to room temperature, and separating juice and residues to obtain filtrate A;
s4: filtering and precipitating the filtrate A obtained in the step S3 to obtain a precipitated filtrate B;
s5: boiling and killing the filtrate B in the S4 again to obtain sterile liquid A;
s6: pouring the sterile liquid A into a stirring kettle heated in a water-proof way for stirring, wherein the stirring temperature is 40-60 ℃;
s7: weighing sodium dodecyl sulfate, dissolving to obtain a sodium dodecyl sulfate solution, weighing the sodium dodecyl sulfate solution, imidazoline, alkyl glycoside and ET200, and sequentially adding the sterile liquid A;
s8: the auxiliary agent is edible citric acid, the edible citric acid is poured into the sterile liquid A in S7, and the pH value of the sterile liquid A is controlled to be 6.8-7.5;
s9: weighing ethylparaben according to the weight parts, adding sterile liquid A in S8, and then stopping stirring;
s10: naturally cooling and filling.
8. The method of claim 7, wherein the stirring speed in steps S6-S9 is 15 rpm.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102559408A (en) * | 2011-12-30 | 2012-07-11 | 北京绿伞化学股份有限公司 | Pure plant type antibacterial cleanser and preparation method thereof |
| CN106377475A (en) * | 2016-10-14 | 2017-02-08 | 西安优派生物科技有限公司 | Completely-herbal skincare natural anti-bacterium hand sanitizer and preparation method thereof |
| CN107384624A (en) * | 2017-07-05 | 2017-11-24 | 芜湖慧宇商贸有限公司 | A kind of antimicrobial laundry liquid not hurt hands gently |
| CN107502458A (en) * | 2017-09-06 | 2017-12-22 | 南通优护优家卫生用品有限公司 | A kind of non-stimulated infant liquid laundry detergent |
| CN107760485A (en) * | 2016-08-23 | 2018-03-06 | 周国萍 | A kind of Antibacterial laundry detergent containing medicinal herb componentses |
-
2021
- 2021-09-27 CN CN202111136993.1A patent/CN113667549A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102559408A (en) * | 2011-12-30 | 2012-07-11 | 北京绿伞化学股份有限公司 | Pure plant type antibacterial cleanser and preparation method thereof |
| CN107760485A (en) * | 2016-08-23 | 2018-03-06 | 周国萍 | A kind of Antibacterial laundry detergent containing medicinal herb componentses |
| CN106377475A (en) * | 2016-10-14 | 2017-02-08 | 西安优派生物科技有限公司 | Completely-herbal skincare natural anti-bacterium hand sanitizer and preparation method thereof |
| CN107384624A (en) * | 2017-07-05 | 2017-11-24 | 芜湖慧宇商贸有限公司 | A kind of antimicrobial laundry liquid not hurt hands gently |
| CN107502458A (en) * | 2017-09-06 | 2017-12-22 | 南通优护优家卫生用品有限公司 | A kind of non-stimulated infant liquid laundry detergent |
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Application publication date: 20211119 |