CN106047509A - Washing powder and preparation method thereof - Google Patents
Washing powder and preparation method thereof Download PDFInfo
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- CN106047509A CN106047509A CN201610387542.8A CN201610387542A CN106047509A CN 106047509 A CN106047509 A CN 106047509A CN 201610387542 A CN201610387542 A CN 201610387542A CN 106047509 A CN106047509 A CN 106047509A
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- Prior art keywords
- extracting solution
- tea
- fructus
- oil
- peel
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2027—Monohydric alcohols unsaturated
- C11D3/2031—Monohydric alcohols unsaturated fatty or with at least 8 carbon atoms in the alkenyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides washing powder and a preparation method thereof. The washing powder is mainly prepared from oil-tea-cake powder, a Chinese honeylocust fruit extracting solution, a Chinese soapberry fruit peel extracting solution, an aloe extracting solution, a jasmine flower extracting solution, sodium bicarbonate, alkaline protease, sodium silicate, carboxymethyl cellulose and linalool. The oil-tea-cake powder, the Chinese honeylocust fruit extracting solution and the Chinese soapberry fruit peel extracting solution serve as surfactant to mainly play the detergent action, alkaline protease is added, a special effect on washing dirt secreted by human bodies is achieved, the jasmine flower extracting solution serves as an auxiliary decontamination component, natural fragrant flavor can be emitted, the aloe extracting solution has a bactericidal effect, linalool is added, and the clothes can have a very good fragrance after being washed. According to the washing powder, all the components of the raw materials are carefully selected, the proportion is reasonable, and the decontamination capacity and the bactericidal effect are enhanced in an omni-directional and deep mode; the preparation method is simple, the material sources are wide, and the preparation cost is low.
Description
[technical field]
The present invention relates to washing technology field, be specifically related to a kind of detergent and preparation method thereof.
[background technology]
Along with improving constantly of people's health consciousness, the cleaning requirement to articles for use such as medicated clothings is increasingly stricter, and traditional washes
Clothing powder reaches decontamination purpose by interpolation chemicals mostly, and such detergent not only can remain on medicated clothing, to people
The skin of body has the side effect such as certain stimulation, and its waste liquid owing to containing chemicals, also having certain pollution to environment.
And detergent the most on the market simply lays particular emphasis on the appreciable spot of naked eyes, dirt, and have ignored human secretion, demodicid mite
The elimination of worm, antibacterial etc..Visible, that our detergent used in everyday can not be comprehensive, profound cleaning medicated clothing.So,
Need a safe and efficient Chinese medicine detergent.
[summary of the invention]
In view of problem above, the present invention provides a kind of natural detergent, and this detergent takes full advantage of Oil-tea-cake powder, Fructus Gleditsia
Really, the decontamination cleaning efficacy of Fructus Sapindi Mukouossi, the biocidal efficacies of Aloe, the delicate fragrance specially good effect of Flos Jasmini Sambac, and alkaline protease, silicic acid
The washing functions that sodium, carboxymethyl cellulose have, by extracting natural material active component, and combination collocation, rational proportion
Use, thus prepare natural harmless, the detergent of noresidue.
For reaching above-mentioned purpose, the present invention adopts the following technical scheme that a kind of detergent, mainly by Oil-tea-cake powder, Fructus Gleditsia
Really extracting solution, peel of Fructus Sapindi Mukouossi extracting solution, Aloe extraction solution, Flos Jasmini Sambac extracting solution, sodium bicarbonate, alkaline protease, sodium silicate,
Carboxymethyl cellulose, linalool are prepared from；
Described Oil-tea-cake powder is that acquisition is prepared as follows: after cake of camellia oleifera seeds smashing, grinding, cross 150-200 mesh sieve
Net, extracting screen underflow, obtain Oil-tea-cake powder；
Described Fructus Gleditsia fruit extracting solution is that acquisition is prepared as follows: taking Fructus Gleditsia fruit, Fructus Gleditsia is soaked in 1:4 ratio by fruit with water
2-3h in deionized water, is then heated up to 80 DEG C, decocts 1h～1.5h, crosses leaching filtrate, prepares Fructus Gleditsia fruit extracting solution；
Described peel of Fructus Sapindi Mukouossi extracting solution is that acquisition is prepared as follows: after peel of Fructus Sapindi Mukouossi is smashed into powder, add
The deionized water of 6-8 times of weight soaks 1-3 hour, ultrasonic extraction 10-15min, crosses leaching filtrate, centrifugal, takes supernatant, will
Supernatant is evaporated to solid content 12～18%, prepares peel of Fructus Sapindi Mukouossi extracting solution；
Described Aloe extraction solution is that acquisition is prepared as follows: the Folium Aloe taking maturation cleans peeling, carries out ultraviolet
Sterilize 30-45 minute, then grind pulping, serosity adds ethanol, is subsequently placed in high speed centrifuge and carries out solid-liquid and divide
From, centrifuging temperature is set as 4 DEG C, and the time is 20min, and rotating speed is 8000rpm/min, separates supernatant and precipitation, precipitates addition 6
The water of times weight, constant temperature 90 DEG C, it is stirred continuously, continues 60-90min, cross leaching filtrate, supernatant is mixed with filtrate, addition
Supernatant, the filtrate gross weight salicylic acid than 3% stir, and can be prepared by；
Described Flos Jasmini Sambac extracting solution is that acquisition is prepared as follows: take jasmine petal, irradiation-sterilize 0.5-under ultraviolet
1h, jasmine petal adds deionized water with water in 1:5 ratio, and by 2% addition of jasmine petal with deionized water gross weight ratio
Sorbic acid, soaks at least 30min, is subsequently poured in juice extractor and squeezes the juice, and crosses leaching filtrate, prepares Flos Jasmini Sambac extracting solution.
Preferably, each raw material preparing detergent forms as following weight percent: Oil-tea-cake powder 45-60%, Fructus Gleditsia fruit
Extracting solution 6-10%, peel of Fructus Sapindi Mukouossi extracting solution 6-10%, Aloe extraction solution 5-10%, Flos Jasmini Sambac extracting solution 5-10%, carbonic acid
Hydrogen sodium 3-5%, alkaline protease 5-10%, sodium silicate 2-4%, carboxymethyl cellulose 1-3%, linalool 1-2%.
Preferably, each raw material preparing detergent forms as following weight percent: Oil-tea-cake powder 52%, Fructus Gleditsia fruit are extracted
Liquid 8%, peel of Fructus Sapindi Mukouossi extracting solution 7%, Aloe extraction solution 8%, Flos Jasmini Sambac extracting solution 8%, sodium bicarbonate 4%, basic protein
Enzyme 7%, sodium silicate 3%, carboxymethyl cellulose 2%, linalool 1%.
Weigh each raw material in proportion, Oil-tea-cake powder, Fructus Gleditsia fruit extracting solution, peel of Fructus Sapindi Mukouossi extracting solution, Aloe are extracted
Liquid, Flos Jasmini Sambac extracting solution mixing post-heating, constant temperature 55 DEG C, constant temperature time is 20min, be subsequently adding alkaline protease, sodium silicate,
Carboxymethyl cellulose, then it is sufficiently stirred for 5-8min, it is eventually adding sodium bicarbonate, linalool, crosses homogenizer, concentrate, dry, grind
Rear prepared.
The method have the advantages that owing to prepared detergent mainly uses natural tea saponin powder, saponin, nothing
Suffer from sub-saponin, coordinate Aloe extraction solution, Flos Jasmini Sambac extracting solution, alkaline protease, sodium silicate, the synergism of sodium bicarbonate, because of
This can rapidly remove the spot on medicated clothing.It addition, described detergent not only environmentally safe, degradability are good, safety non-toxic,
To the advantage such as human body skin is non-stimulated, and wash rear noresidue, there is again the effect of bacteriostasis and sterilization, acaricide.
[detailed description of the invention]
The following examples can help those skilled in the art to be more completely understood by the present invention, but cannot be with any
Mode limits the present invention.
Embodiment 1:
Weigh Oil-tea-cake powder 45%, Fructus Gleditsia fruit extracting solution 6%, peel of Fructus Sapindi Mukouossi extracting solution 10%, reed by weight percentage
Luxuriant growth extracting solution 10%, Flos Jasmini Sambac extracting solution 10%, sodium bicarbonate 3%, alkaline protease 10%, sodium silicate 2%, carboxymethyl cellulose
Element 2%, linalool 2%.
By Oil-tea-cake powder, Fructus Gleditsia fruit extracting solution, peel of Fructus Sapindi Mukouossi extracting solution, Aloe extraction solution, the mixing of Flos Jasmini Sambac extracting solution
Uniformly post-heating, constant temperature 55 DEG C, the time is 20min, is subsequently adding alkaline protease, sodium silicate, carboxymethyl cellulose, more fully
Stirring 5-8min, is eventually adding sodium bicarbonate, linalool, crosses homogenizer, concentrates, and dries, and prepares after grinding.
Embodiment 2:
Weigh by weight percentage: Oil-tea-cake 52%, Fructus Gleditsia fruit extracting solution 8%, peel of Fructus Sapindi Mukouossi extracting solution 7%, Aloe
Extracting solution 8%, Flos Jasmini Sambac extracting solution 8%, sodium bicarbonate 4%, alkaline protease 7%, sodium silicate 3%, carboxymethyl cellulose
2%, linalool 1%.
By Oil-tea-cake powder, Fructus Gleditsia fruit extracting solution, peel of Fructus Sapindi Mukouossi extracting solution, Aloe extraction solution, the mixing of Flos Jasmini Sambac extracting solution
Post-heating, constant temperature 55 DEG C, add alkaline protease, sodium silicate, carboxymethyl cellulose, then be sufficiently stirred for 5-8min, be eventually adding
Sodium bicarbonate, linalool, cross homogenizer, concentrates, and dries, and prepares after grinding.
Embodiment 3:
Weigh by weight percentage: Oil-tea-cake powder 60%, Fructus Gleditsia fruit extracting solution 10%, peel of Fructus Sapindi Mukouossi extracting solution 6%, reed
Luxuriant growth extracting solution 5%, Flos Jasmini Sambac extracting solution 5%, sodium bicarbonate 5%, alkaline protease 5%, sodium silicate 2%, carboxymethyl cellulose
1%, linalool 1%.
Add after Oil-tea-cake powder, Fructus Gleditsia fruit extracting solution, Fructus Sapindi Mukouossi extracting solution, Aloe extraction solution, the mixing of Flos Jasmini Sambac extracting solution
Heat, constant temperature 55 DEG C, the time is 20min, is subsequently adding alkaline protease, sodium silicate, carboxymethyl cellulose, then is sufficiently stirred for 5-
8min, is eventually adding sodium bicarbonate, linalool, crosses homogenizer, concentrates, and dries, and prepares after grinding.
Embodiment 4:
Weigh by weight percentage: Oil-tea-cake powder 54%, Fructus Gleditsia fruit extracting solution 7%, peel of Fructus Sapindi Mukouossi extracting solution 7%, reed
Luxuriant growth extracting solution 7%, Flos Jasmini Sambac extracting solution 6%, sodium bicarbonate 4%, alkaline protease 6%, sodium silicate 4%, carboxymethyl cellulose
3%, linalool 2%.
Add after Oil-tea-cake powder, Fructus Gleditsia fruit extracting solution, Fructus Sapindi Mukouossi extracting solution, Aloe extraction solution, the mixing of Flos Jasmini Sambac extracting solution
Heat, constant temperature 55 DEG C, the time is 20min, is subsequently adding alkaline protease, sodium silicate, carboxymethyl cellulose, then is sufficiently stirred for 5-
8min, is eventually adding sodium bicarbonate, linalool, crosses homogenizer, concentrates, and dries, and prepares after grinding.
Although, the present invention is described in detail the most with a general description of the specific embodiments, but
On the basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Cause
This, these modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to the scope of protection of present invention.
Claims (4)
1. a detergent, it is characterised in that: described detergent is mainly made up of following raw material: Oil-tea-cake powder, Fructus Gleditsia fruit are extracted
Liquid, peel of Fructus Sapindi Mukouossi extracting solution, Aloe extraction solution, Flos Jasmini Sambac extracting solution, sodium bicarbonate, alkaline protease, sodium silicate, carboxymethyl
Cellulose, linalool；
Described Oil-tea-cake powder is that acquisition is prepared as follows: after cake of camellia oleifera seeds smashing, grinding, crosses 150-200 eye mesh screen, takes
Siftage, obtains Oil-tea-cake powder；
Described Fructus Gleditsia fruit extracting solution is that acquisition is prepared as follows: taking Fructus Gleditsia fruit, fruit is soaked in 1:4 ratio Fructus Gleditsia with water
2-3h in ionized water, is then heated up to 80 DEG C, decocts 1h～1.5h, crosses leaching filtrate, prepares Fructus Gleditsia fruit extracting solution；
Described peel of Fructus Sapindi Mukouossi extracting solution is that acquisition is prepared as follows: after peel of Fructus Sapindi Mukouossi is smashed into powder, add 6-8 times
The deionized water of weight soaks 1-3 hour, ultrasonic extraction 10-15min, crosses leaching filtrate, centrifugal, takes supernatant, by supernatant
Liquid is evaporated to solid content 12～18%, prepares peel of Fructus Sapindi Mukouossi extracting solution；
Described Aloe extraction solution is that acquisition is prepared as follows: the Folium Aloe taking maturation cleans peeling, carries out ultraviolet sterilization
30-45 minute, then grind pulping, serosity adds ethanol, is subsequently placed in high speed centrifuge and carries out solid-liquid separation, from
Heart temperature is set as 4 DEG C, and the time is 20min, and rotating speed is 8000rpm/min, separates supernatant and precipitation, and precipitation adds 6 times of weights
The water of amount, constant temperature 90 DEG C, it is stirred continuously, continues 60-90min, cross leaching filtrate, supernatant is mixed with filtrate, add supernatant
Liquid stirs with the filtrate gross weight salicylic acid than 3%, can be prepared by；
Described Flos Jasmini Sambac extracting solution is that acquisition is prepared as follows: take jasmine petal, ultraviolet irradiation-sterilize 0.5-1h, jasmine
Petal adds deionized water with water in 1:5 ratio, and by 2% addition sorbic acid of jasmine petal with deionized water gross weight ratio,
Soak at least 30min, be subsequently poured in juice extractor and squeeze the juice, cross leaching filtrate, prepare Flos Jasmini Sambac extracting solution.
A kind of detergent the most according to claim 1, it is characterised in that: following weight percent pressed by each raw material of described detergent
Than composition: Oil-tea-cake powder 45-60%, Fructus Gleditsia fruit extracting solution 6-10%, peel of Fructus Sapindi Mukouossi extracting solution 6-10%, Aloe extraction solution 5-
10%, Flos Jasmini Sambac extracting solution 5-10%, sodium bicarbonate 3-5%, alkaline protease 5-10%, sodium silicate 2-4%, carboxymethyl cellulose
Element 1-3%, linalool 1-2%.
A kind of detergent the most according to claim 2, it is characterised in that: following weight percent pressed by each raw material of described detergent
Than composition: Oil-tea-cake powder 52%, Fructus Gleditsia fruit extracting solution 8%, peel of Fructus Sapindi Mukouossi extracting solution 7%, Aloe extraction solution 8%, Flos Jasmini Sambac
Extracting solution 8%, sodium bicarbonate 4%, alkaline protease 7%, sodium silicate 3%, carboxymethyl cellulose 2%, linalool 1%.
4. according to a kind of detergent described in any one of claims 1 to 3, its preparation method is as follows: by Oil-tea-cake powder, Fructus Gleditsia fruit
Extracting solution, peel of Fructus Sapindi Mukouossi extracting solution, Aloe extraction solution, Flos Jasmini Sambac extracting solution mixing post-heating, constant temperature 55 DEG C, the time is
20min, is subsequently adding alkaline protease, sodium silicate, carboxymethyl cellulose, then is sufficiently stirred for 5-8min, be eventually adding bicarbonate
Sodium, linalool, cross homogenizer, concentrates, and dries, and prepares after grinding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610387542.8A CN106047509A (en) | 2016-06-03 | 2016-06-03 | Washing powder and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610387542.8A CN106047509A (en) | 2016-06-03 | 2016-06-03 | Washing powder and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106047509A true CN106047509A (en) | 2016-10-26 |
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| CN201610387542.8A Pending CN106047509A (en) | 2016-06-03 | 2016-06-03 | Washing powder and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107523447A (en) * | 2017-10-18 | 2017-12-29 | 桂林大创科技有限公司 | A kind of home-use washing powder and preparation method thereof |
| CN107699376A (en) * | 2017-11-27 | 2018-02-16 | 广西协成日用化工有限公司 | A kind of liquid detergent |
| CN107987989A (en) * | 2017-11-27 | 2018-05-04 | 广西协成日用化工有限公司 | A kind of washing powder |
| CN108913406A (en) * | 2018-08-30 | 2018-11-30 | 佛山市欧若拉生物科技有限公司 | A kind of liquid detergent and preparation method thereof effectively removing clothing peculiar smell |
| CN111662787A (en) * | 2020-06-11 | 2020-09-15 | 浙江施维康生物医学材料有限公司 | Peculiar smell-removing type washing gel bead and preparation method thereof |
| JP2021021060A (en) * | 2019-07-24 | 2021-02-18 | 趙華軍 | Detergent product |
-
2016
- 2016-06-03 CN CN201610387542.8A patent/CN106047509A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107523447A (en) * | 2017-10-18 | 2017-12-29 | 桂林大创科技有限公司 | A kind of home-use washing powder and preparation method thereof |
| CN107699376A (en) * | 2017-11-27 | 2018-02-16 | 广西协成日用化工有限公司 | A kind of liquid detergent |
| CN107987989A (en) * | 2017-11-27 | 2018-05-04 | 广西协成日用化工有限公司 | A kind of washing powder |
| CN108913406A (en) * | 2018-08-30 | 2018-11-30 | 佛山市欧若拉生物科技有限公司 | A kind of liquid detergent and preparation method thereof effectively removing clothing peculiar smell |
| JP2021021060A (en) * | 2019-07-24 | 2021-02-18 | 趙華軍 | Detergent product |
| CN111662787A (en) * | 2020-06-11 | 2020-09-15 | 浙江施维康生物医学材料有限公司 | Peculiar smell-removing type washing gel bead and preparation method thereof |
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Application publication date: 20161026 |