CN113575253A - Involucra calcium product for preventing sunscald and beautifying fruits and preparation method and application thereof - Google Patents

Involucra calcium product for preventing sunscald and beautifying fruits and preparation method and application thereof Download PDF

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Publication number
CN113575253A
CN113575253A CN202110857354.8A CN202110857354A CN113575253A CN 113575253 A CN113575253 A CN 113575253A CN 202110857354 A CN202110857354 A CN 202110857354A CN 113575253 A CN113575253 A CN 113575253A
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calcium
parts
product
water
fruit
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梁恩发
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Guangxi Taimei Biotechnology Co ltd
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Guangxi Taimei Biotechnology Co ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G17/00Cultivation of hops, vines, fruit trees, or like trees
    • A01G17/005Cultivation methods
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • A01G13/02Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • A01G13/0237Devices for protecting a specific part of a plant, e.g. roots, trunk or fruits
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Environmental Sciences (AREA)
  • Botany (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Cultivation Of Plants (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a leather membrane calcium product for preventing sunscald and beautifying fruits, which comprises 0.5-2 parts of pure acrylic emulsion, 0.05-0.5 part of dispersant, 2-5 parts of light calcium carbonate, 1-2 parts of ground calcium carbonate, 0.5-1 part of calcium citrate, 1-1.5 parts of titanium citrate, 0.1-0.5 part of ethyl cellulose, 0.2 part of antifreeze, 0.05 part of potassium sorbate and 1-2 parts of water. The product of the invention can continuously and stably release carbon dioxide in fruit cells, and optimize the quantity of available carbon dioxide of crops, thereby obviously coordinating and extending photosynthesis and being beneficial to the accumulation of organic substances; the product of the invention can meet the requirement of crops on calcium absorption, prevent fruit cracking and reduce the harm of bitter pox, fruit rust, navel rot, malformed fruit and the like; after the involucra calcium product is diluted and sprayed, a group of calcium-titanium protective films can be formed on the surface layers of fruits, so that the occurrence of sunfruits is effectively reduced, and other plant diseases and insect pests caused by suntan are effectively prevented.

Description

Involucra calcium product for preventing sunscald and beautifying fruits and preparation method and application thereof
Technical Field
The invention relates to the technical field of fruit protection, in particular to a film calcium product for preventing sunscald and beautifying fruits and a preparation method and application thereof.
Background
The high temperature and strong sunshine in the south cause serious sunburn damage to oranges, hot peppers and the like, and the appearance and the internal quality of fruits are affected.
The sunscald disease of the fruit is a common physiological disease of fruit trees, and brings great loss to the fruit production every year. . High temperature and strong light are the main causes of sunscald, and especially sudden high temperature and strong light are more likely to cause sunscald of fruits. Moisture stress and relative humidity are also factors in the occurrence of sunburn. Under the clamping of high temperature and drought, fruits in the fruit expansion period are easy to suntan, the fruits after suntan are easy to recover to a light degree, the suntan degree is moderate but the fruits do not damage the sponge layer, the fruit quality is not affected, but the commodity is very low. In the severely sunburned fruit, cells in the spongy layer die, and the juice is granulated and withered, so that the flavor is lost.
Therefore, the technical problems to be solved by the technical personnel in the field are to provide a suntan-proof skin calcium product capable of protecting fruits, and a preparation method and application thereof.
Disclosure of Invention
In view of the above, the invention provides a calcium involucra product for preventing sunscald and beautifying fruits, and a preparation method and application thereof
In order to achieve the purpose, the invention adopts the following technical scheme:
a involucra calcium product for preventing sunscald and beautifying fruits comprises the following raw materials in parts by weight: 0.5-2 parts of pure acrylic emulsion, 0.05-0.5 part of dispersant, 2-5 parts of light calcium carbonate, 1-2 parts of heavy calcium carbonate, 0.5-1 part of calcium citrate, 1-1.5 parts of titanium citrate, 0.1-0.5 part of ethyl cellulose, 0.2 part of antifreeze, 0.05 part of potassium sorbate and 1-2 parts of water.
Preferably, the anti-sunburn beautifying peel calcium product comprises the following raw materials in parts by weight: 1 part of pure acrylic emulsion, 0.05 part of dispersant, 3 parts of light calcium carbonate, 1 part of heavy calcium carbonate, 1 part of calcium citrate, 1.5 parts of titanium citrate, 0.3 part of ethyl cellulose, 0.2 part of antifreeze, 0.05 part of potassium sorbate and 2 parts of water.
Further, the dispersant is a C20 type dispersant.
The C20 type dispersant is polyacrylic acid dispersant.
The beneficial effect of adopting the further scheme is that: the invention adopts the dispersant to thoroughly disperse the nanoscale calcium.
Further, the antifreezing agent is ethylene glycol.
The beneficial effect of adopting the further scheme is that: the antifreezing agent can realize low-temperature condensation in winter.
The invention also provides a preparation method of the anti-sunscald involucra calcium product, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) dividing water into two parts, simultaneously mixing the first part of water with the pure acrylic emulsion, the dispersing agent, the light calcium carbonate, the heavy calcium carbonate, the calcium citrate and the titanium citrate, and then uniformly scattering the mixture by using a high-speed dispersion machine to obtain a mixture;
(3) dissolving ethyl cellulose, an antifreezing agent and potassium sorbate in the second part of water, adding the mixture into the mixed solution, uniformly stirring, and homogenizing to obtain the anti-sunburn skin calcium product.
Further, the rotating speed of the high-speed dispersion machine in the step (2) is 2500-.
Further, the stirring speed in the step (3) is 1200-1500r/min, and the stirring time is 20-50 min.
Furthermore, the homogenization time in the step (3) is 20-40 min.
The invention also provides an application method of the anti-sunscald skink calcium product, which comprises the following steps: diluting the involucra calcium product of the anti-sunburn fruit beautifying by 20-40 times with water, and then spraying the involucra calcium product on the fruit epidermis to quickly form a calcium-titanium film on the fruit epidermis so as to protect the fruit from being burnt.
The invention has the beneficial effects that: the product of the invention can continuously and stably release carbon dioxide in fruit cells, and optimize the quantity of available carbon dioxide of crops, thereby obviously coordinating and extending photosynthesis and being beneficial to the accumulation of organic substances;
the product of the invention can meet the requirement of crops on calcium absorption, prevent fruit cracking and reduce the harm of bitter pox, fruit rust, navel rot, malformed fruit and the like;
under the action of emulsion and cellulose, titanium dioxide and calcium carbonate in the product form an organic protective film on the surface of fruits, which is equivalent to sleeving a film bag and a paper bag to protect the growth of the fruits, prevent the invasion of pathogenic bacteria, reduce the occurrence of diseases, and reduce the occurrence of diseases such as sunburn, fruit rust, sand skin disease, lipid spot disease and the like. Protecting the brightness of the fruits, resisting storage and prolonging the harvesting period.
After the involucra calcium product is diluted and sprayed, a group of calcium-titanium protective films can be formed on the surface layers of fruits, so that the occurrence of sunfruits is effectively reduced, and other plant diseases and insect pests caused by suntan are effectively prevented.
Drawings
FIG. 1 is a graph showing the effect of the product of example 5 of the present invention after being sprayed on the surface of fruits for 2 minutes;
FIG. 2 is a graph showing the effect of the product of example 5 of the present invention after being sprayed on the surface of fruits for half an hour.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
Anti-sunscald skin calcium product for beautifying fruits
(1) Weighing 0.5kg of pure acrylic emulsion, 0.5kg of polyacrylic acid dispersant, 5kg of light calcium carbonate, 1kg of heavy calcium carbonate, 1kg of calcium citrate, 1kg of titanium citrate, 0.5kg of ethyl cellulose, 0.2kg of ethylene glycol, 0.05kg of potassium sorbate and 2kg of water;
(2) dividing water into two parts, wherein the weight of the first part of water is 1kg, mixing the first part of water with pure acrylic emulsion, a dispersing agent, light calcium carbonate, heavy calcium carbonate, calcium citrate and titanium citrate, and then dispersing for 50min by a high-speed dispersion machine 2500r/min to obtain a mixture;
(3) dissolving ethyl cellulose, an antifreezing agent and potassium sorbate in the second part of water, adding the mixture into the mixed solution at 1500r/min, stirring for 20min, and homogenizing for 40min to obtain the involucra calcium product for preventing sunscald fruits.
Example 2
Anti-sunscald skin calcium product for beautifying fruits
(1) Weighing 2kg of pure acrylic emulsion, 0.05kg of polyacrylic acid dispersant, 2kg of light calcium carbonate, 2kg of heavy calcium carbonate, 0.5kg of calcium citrate, 1.5kg of titanium citrate, 0.1kg of ethyl cellulose, 0.2kg of ethylene glycol, 0.05kg of potassium sorbate and 1.1kg of water;
(2) dividing water into two parts, wherein the weight of the first part of water is 1kg, mixing the first part of water with pure acrylic emulsion, a dispersing agent, light calcium carbonate, heavy calcium carbonate, calcium citrate and titanium citrate, and then dispersing for 20min by using a high-speed dispersion machine at 3000r/min to obtain a mixture;
(3) dissolving ethyl cellulose, an antifreezing agent and potassium sorbate in the second part of water, then adding the mixture into the mixed solution at a speed of 1200r/min, stirring for 50min, and homogenizing for 20min to obtain the involucra calcium product for preventing sunscald fruits.
Example 3
Anti-sunscald skin calcium product for beautifying fruits
(1) Weighing 1.2kg of pure acrylic emulsion, 0.2kg of polyacrylic acid dispersant, 3kg of light calcium carbonate, 1.5kg of heavy calcium carbonate, 0.7kg of calcium citrate, 1.2kg of titanium citrate, 0.3kg of ethyl cellulose, 0.2kg of ethylene glycol, 0.05kg of potassium sorbate and 1.5kg of water;
(2) dividing the water into two parts, wherein the weight of the first part of water is 1kg, mixing the first part of water with the pure acrylic emulsion, the dispersing agent, the light calcium carbonate, the heavy calcium carbonate, the calcium citrate and the titanium citrate, and then dispersing for 30min by using a high-speed dispersion machine 2700r/min to obtain a mixture;
(3) dissolving ethyl cellulose, an antifreezing agent and potassium sorbate in the second part of water, adding the mixture into the mixed solution at a speed of 1300r/min, stirring for 30min, and homogenizing for 30min to obtain the involucra calcium product for preventing sunscald fruits.
Example 4
Anti-sunscald skin calcium product for beautifying fruits
(1) Weighing 0.8kg of pure acrylic emulsion, 0.08kg of polyacrylic acid dispersant, 4kg of light calcium carbonate, 1.8kg of heavy calcium carbonate, 0.6kg of calcium citrate, 1.1kg of titanium citrate, 0.4kg of ethyl cellulose, 0.2kg of ethylene glycol, 0.05kg of potassium sorbate and 1.8kg of water;
(2) dividing the water into two parts, wherein the weight of the first part of water is 1kg, mixing the first part of water with the pure acrylic emulsion, the dispersing agent, the light calcium carbonate, the heavy calcium carbonate, the calcium citrate and the titanium citrate, and then dispersing for 25min by using a high-speed dispersion machine 2950r/min to obtain a mixture;
(3) dissolving ethyl cellulose, an antifreezing agent and potassium sorbate in the second part of water, adding the mixture into the mixed solution at a speed of 1400r/min, stirring for 45min, and homogenizing for 35min to obtain the involucra calcium product for preventing sunscald fruits.
Example 5
Anti-sunscald skin calcium product for beautifying fruits
(1) Weighing 1kg of pure acrylic emulsion, 0.05kg of polyacrylic acid dispersant, 3kg of light calcium carbonate, 1kg of heavy calcium carbonate, 1kg of calcium citrate, 1.5kg of titanium citrate, 0.3kg of ethyl cellulose, 0.2kg of ethylene glycol, 0.05kg of potassium sorbate and 2kg of water;
(2) dividing water into two parts, wherein the weight of the first part of water is 1kg, mixing the first part of water with pure acrylic emulsion, a dispersing agent, light calcium carbonate, heavy calcium carbonate, calcium citrate and titanium citrate, and then dispersing for 30min by a high-speed dispersion machine at 2880r/min to obtain a mixture;
(3) dissolving ethyl cellulose, an antifreezing agent and potassium sorbate in the second part of water, adding the mixture into the mixed solution at 1440r/min, stirring for 30min, and homogenizing for 20min to obtain the involucra calcium product for preventing sunscald fruits.
Test examples
At 23 days 7 months in 2020, the anti-sunscald skin calcium product prepared in example 5 was diluted 30 times with water in double bridge town orchard in Wuming district of Nanning, and then sprayed on the fruit skin to rapidly form a calcium-titanium film on the fruit skin, as shown in FIG. 1-2.
Although embodiments of the present invention have been shown and described above, it is understood that the above embodiments are exemplary and should not be construed as limiting the present invention, and that variations, modifications, substitutions and alterations can be made to the above embodiments by those of ordinary skill in the art within the scope of the present invention.

Claims (9)

1. The involucra calcium product for preventing sunscald and beautifying fruits is characterized by comprising the following raw materials in parts by weight: 0.5-2 parts of pure acrylic emulsion, 0.05-0.5 part of dispersant, 2-5 parts of light calcium carbonate, 1-2 parts of heavy calcium carbonate, 0.5-1 part of calcium citrate, 1-1.5 parts of titanium citrate, 0.1-0.5 part of ethyl cellulose, 0.2 part of antifreeze, 0.05 part of potassium sorbate and 1-2 parts of water.
2. The sunless beauty-preventing involucrata calcium product as recited in claim 1, comprising the following raw materials in parts by weight: 1 part of pure acrylic emulsion, 0.05 part of dispersant, 3 parts of light calcium carbonate, 1 part of heavy calcium carbonate, 1 part of calcium citrate, 1.5 parts of titanium citrate, 0.3 part of ethyl cellulose, 0.2 part of antifreeze, 0.05 part of potassium sorbate and 2 parts of water.
3. The sunless beauty peel calcium product as claimed in claim 2, wherein the dispersant is C20 type dispersant.
4. The sunless savory peel calcium product of claim 2, wherein the anti-freeze agent is ethylene glycol.
5. A preparation method of a involucra calcium product for preventing sunscald and beautifying fruits is characterized by comprising the following steps:
(1) weighing the raw materials according to the parts by weight of any one of claims 1 to 4;
(2) dividing water into two parts, simultaneously mixing the first part of water with the pure acrylic emulsion, the dispersing agent, the light calcium carbonate, the heavy calcium carbonate, the calcium citrate and the titanium citrate, and then uniformly scattering the mixture by using a high-speed dispersion machine to obtain a mixture;
(3) dissolving ethyl cellulose, an antifreezing agent and potassium sorbate in the second part of water, adding the mixture into the mixed solution, uniformly stirring, and homogenizing to obtain the anti-sunburn skin calcium product.
6. The method for preparing the anti-sunburn and fruit-beautifying coated calcium product as recited in claim 5, wherein the rotation speed of the high-speed disperser in step (2) is 2500-.
7. The method for preparing the anti-sunburn and fruit-beautifying coated calcium product as recited in claim 5, wherein the stirring rate in step (3) is 1200-1500r/min, and the stirring time is 20-50 min.
8. The method for preparing the sunless beauty preserved involucra calcium product according to claim 5, wherein the homogenization time in the step (3) is 20-40 min.
9. Method of application of the guacamole-protecting calcium film product according to any one of claims 1 to 4, characterized in that it comprises the following steps: diluting the involucra calcium product of the sunproof beauty fruit by 20-40 times with water, and then spraying the product on the fruit skin.
CN202110857354.8A 2021-07-28 2021-07-28 Involucra calcium product for preventing sunscald and beautifying fruits and preparation method and application thereof Pending CN113575253A (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1736218A (en) * 2005-05-13 2006-02-22 河北科技大学 Application of high molecular polymer emulsion film in protection film for fruit growth
CN102812958A (en) * 2012-09-03 2012-12-12 张军防 Plant sunscald controlling agent
CN105294176A (en) * 2015-10-20 2016-02-03 安庆市毕架山林业有限公司 Plant calcium
CN108207941A (en) * 2017-12-27 2018-06-29 深圳市隆戈尔生态技术有限公司 It is a kind of to mitigate bright preventing coating protection agent of plant day and preparation method thereof
CN109892330A (en) * 2017-12-08 2019-06-18 中国科学院大连化学物理研究所 A kind of crops sunscald control agent and its application
CN111066817A (en) * 2019-12-27 2020-04-28 河北萌帮水溶肥料股份有限公司 Protective agent for relieving sunscald of fruits and preparation process thereof
CN111574894A (en) * 2020-05-26 2020-08-25 南宁汉和生物科技股份有限公司 Biological sunscreen agent capable of promoting plant growth and preparation method thereof
CN112167266A (en) * 2020-10-30 2021-01-05 青岛帝保隆微碳农业技术有限公司 Micro-film calcium fruit suntan protective agent and preparation and application methods thereof
CN113016807A (en) * 2021-03-04 2021-06-25 广西合山市华纳新材料科技有限公司 Anti-sunburn agent for fruit trees and preparation method thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1736218A (en) * 2005-05-13 2006-02-22 河北科技大学 Application of high molecular polymer emulsion film in protection film for fruit growth
CN102812958A (en) * 2012-09-03 2012-12-12 张军防 Plant sunscald controlling agent
CN105294176A (en) * 2015-10-20 2016-02-03 安庆市毕架山林业有限公司 Plant calcium
CN109892330A (en) * 2017-12-08 2019-06-18 中国科学院大连化学物理研究所 A kind of crops sunscald control agent and its application
CN108207941A (en) * 2017-12-27 2018-06-29 深圳市隆戈尔生态技术有限公司 It is a kind of to mitigate bright preventing coating protection agent of plant day and preparation method thereof
CN111066817A (en) * 2019-12-27 2020-04-28 河北萌帮水溶肥料股份有限公司 Protective agent for relieving sunscald of fruits and preparation process thereof
CN111574894A (en) * 2020-05-26 2020-08-25 南宁汉和生物科技股份有限公司 Biological sunscreen agent capable of promoting plant growth and preparation method thereof
CN112167266A (en) * 2020-10-30 2021-01-05 青岛帝保隆微碳农业技术有限公司 Micro-film calcium fruit suntan protective agent and preparation and application methods thereof
CN113016807A (en) * 2021-03-04 2021-06-25 广西合山市华纳新材料科技有限公司 Anti-sunburn agent for fruit trees and preparation method thereof

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Application publication date: 20211102