CN113561595A - 一种厌氧发酵复合降解纸袋及制备方法 - Google Patents
一种厌氧发酵复合降解纸袋及制备方法 Download PDFInfo
- Publication number
- CN113561595A CN113561595A CN202010354943.XA CN202010354943A CN113561595A CN 113561595 A CN113561595 A CN 113561595A CN 202010354943 A CN202010354943 A CN 202010354943A CN 113561595 A CN113561595 A CN 113561595A
- Authority
- CN
- China
- Prior art keywords
- paper
- anaerobic fermentation
- outer layer
- composite degradation
- plastic inner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000855 fermentation Methods 0.000 title claims abstract description 29
- 230000015556 catabolic process Effects 0.000 title claims abstract description 15
- 239000002131 composite material Substances 0.000 title claims abstract description 15
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000000123 paper Substances 0.000 claims abstract description 50
- 229920003023 plastic Polymers 0.000 claims abstract description 21
- 239000004033 plastic Substances 0.000 claims abstract description 21
- 229920001971 elastomer Polymers 0.000 claims abstract description 18
- 239000000806 elastomer Substances 0.000 claims abstract description 18
- 229920001526 metallocene linear low density polyethylene Polymers 0.000 claims abstract description 17
- 239000002655 kraft paper Substances 0.000 claims abstract description 3
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000001125 extrusion Methods 0.000 claims description 9
- 238000010096 film blowing Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 238000009941 weaving Methods 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 238000007789 sealing Methods 0.000 abstract description 7
- 238000013461 design Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/327—Layered products comprising a layer of synthetic resin comprising polyolefins comprising polyolefins obtained by a metallocene or single-site catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0017—Combinations of extrusion moulding with other shaping operations combined with blow-moulding or thermoforming
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31B—MAKING CONTAINERS OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31B70/00—Making flexible containers, e.g. envelopes or bags
- B31B70/60—Uniting opposed surfaces or edges; Taping
- B31B70/62—Uniting opposed surfaces or edges; Taping by adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31B—MAKING CONTAINERS OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31B70/00—Making flexible containers, e.g. envelopes or bags
- B31B70/60—Uniting opposed surfaces or edges; Taping
- B31B70/64—Uniting opposed surfaces or edges; Taping by applying heat or pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31B—MAKING CONTAINERS OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31B70/00—Making flexible containers, e.g. envelopes or bags
- B31B70/74—Auxiliary operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31B—MAKING CONTAINERS OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31B70/00—Making flexible containers, e.g. envelopes or bags
- B31B70/74—Auxiliary operations
- B31B70/79—Coating; Impregnating; Waterproofing; Decoating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a general shape other than plane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/31—Heat sealable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/716—Degradable
- B32B2307/7163—Biodegradable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
Abstract
本发明公开了一种厌氧发酵复合降解纸袋及制备方法,所述厌氧发酵复合降解纸袋包括纸质外层和塑料内层,其中,塑料内层由POE弹性体和茂金属线性低密度聚乙烯按重量份配比分别为10‑20份和80‑90份制备,所述纸质外层为牛皮纸。本发明有较好的封温性能和可降解性能,在袋子破碎后在厌氧条件下可短期内被厌氧发酵降解,设计简便,绿色环保。
Description
技术领域
本发明涉纸袋技术领域,尤其涉及一种厌氧发酵复合降解纸袋及制备方法。
背景技术
随着经济的发展,科技的进步,人类社会对社会资源的利用越来 越深入,纸塑袋因为便于装运小宗款装粉粒状物料,获得广泛使用。 但是,现有的纸塑袋热封性较差,常常会导致热封处破裂,同时现有 的纸塑袋降解性差。
发明内容
为了实现上述目的,本发明采用了如下技术方案:
一种厌氧发酵复合降解纸袋,所述厌氧发酵复合降解纸袋包括纸 质外层和塑料内层,其中,塑料内层由POE弹性体和茂金属线性低密 度聚乙烯按一定的重量份配比制备,所述纸质外层为本色牛皮纸构成。
优选地,所述POE弹性体和所述茂金属线性低密度聚乙烯重量份 配比为:茂金属线性低密度聚乙烯80-90份,POE弹性体10-20份。
优选地,所述POE弹性体密度为0.86-0.92g/cm3,熔融指数为 1.0-2.0g/10min;所述茂金属线性低密度聚乙烯密度为 0.91-0.93g/cm3,熔融指数为1.0-2.0g/10min。
优选地,所述纸质外层厚度为0.080-0.120mm,所述塑料内层厚 度为纸质外层厚度的5%。
本发明还提供了一种厌氧发酵复合降解纸袋的制备方法,包括以 下步骤:
S1.将POE弹性体与茂金属线性低密度聚乙烯经高速搅拌机加热搅拌 8min,混合均匀后出料,当混合料的温度为某一温度时,将混合料通 过挤出吹膜机制得薄膜;
S2.将所述薄膜进行加热涂覆于纸质外层的内表面上形成塑料内层, 或者将薄膜切割、拉丝和编织成塑料内层,将所述塑料内层通过粘合 剂粘合在纸质外层的内表面以制得厌氧发酵可降解纸。
S3.将所述厌氧发酵可降解纸加工成厌氧发酵可降解袋。
优选地,步骤S1中混合料的温度为15-25℃,挤出吹膜成型的 温度为160℃-180℃。
本发明具有如下有益效果:
本发明有较好的封温性能和可降解性能,在袋子破碎后在厌氧条 件下可短期内被厌氧发酵降解,设计简便,绿色环保。
附图说明
图1为本发明提供的厌氧发酵复合降解纸袋的热封性能实验数据表。
具体实施方式
下面将结合本发明实施例中的附图,对本发明实施例中的技术方 案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部 分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普 通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例, 都属于本发明保护的范围。实例一:
将90份POE弹性体与10份茂金属线性低密度聚乙烯经高速搅拌 机加热搅拌8min,混合均匀后以混合料的温度为35℃、挤出吹膜成 型温度为180℃通过挤出吹膜机制得薄膜,薄膜层厚度为纸质外层厚 度的5%,其中纸质外层为厚度为0.100mm的本色牛皮纸,将薄膜进 行加热涂覆于纸质外层的内表面上形成塑料内层以制得厌氧发酵可 降解纸,其中POE弹性体密度为0.86-0.92g/cm3,熔融指数为 1.0-2.0g/10min,茂金属线性低密度聚乙烯密度为0.91-0.93g/cm3, 熔融指数为1.0-2.0g/10min。
实例二:
将85份POE弹性体与15份茂金属线性低密度聚乙烯经高速搅拌机加 热搅拌8min,混合均匀后以混合料的温度为40℃、挤出成型温度为 170℃通过挤出吹膜机制得薄膜,薄膜层厚度为纸质外层厚度的5%, 其中纸质外层为厚度为0.100mm的本色牛皮纸,将薄膜进行加热涂覆 于纸质外层的内表面上形成塑料内层以制得厌氧发酵可降解纸,其中 POE弹性体密度为0.86-0.92g/cm3,熔融指数为1.0-2.0g/10min, 茂金属线性低密度聚乙烯密度为0.91-0.93g/cm3,熔融指数为 1.0-2.0g/10min。
实例三:
将80份POE弹性体与20份茂金属线性低密度聚乙烯经高速搅拌机加 热搅拌8min,混合均匀后以混合料的温度为45℃、挤出成型温度为 160℃通过挤出吹膜机制得薄膜,薄膜层厚度为纸质外层厚度的5%, 其中纸质外层为厚度为0.100mm的本色牛皮纸,将薄膜进行加热涂覆 于纸质外层的内表面上形成塑料内层以制得厌氧发酵可降解纸,其中 POE弹性体密度为0.86-0.92g/cm3,熔融指数为1.0-2.0g/10min, 茂金属线性低密度聚乙烯密度为0.91-0.93g/cm3,熔融指数为 1.0-2.0g/10min。
本发明通过调节塑料内层中POE弹性体与茂金属线性低密度聚乙烯的比 例可调节可降解纸袋的热封性能(如图1),纸质外层与塑料内层厚度占比使 厌氧发酵可降解纸袋有较好的封温性能和可降解性能,在袋子破碎后在厌氧 条件下可短期内被厌氧发酵降解,设计简便,绿色环保。
最后应说明的是:以上所述仅为本发明的优选实施例而已,并不 用于限制本发明,尽管参照前述实施例对本发明进行了详细的说明, 对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技 术方案进行修改,或者对其中部分技术特征进行等同替换,凡在本发 明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包 含在本发明的保护范围之内。
Claims (6)
1.一种厌氧发酵复合降解纸袋,其特征在于:所述厌氧发酵复合降解纸袋包括纸质外层和塑料内层,其中,塑料内层由POE弹性体和茂金属线性低密度聚乙烯按一定的重量份配比制备,所述纸质外层由牛皮纸构成。
2.根据权利要求1所述的一种厌氧发酵复合降解纸袋,其特征在于:所述POE弹性体和所述茂金属线性低密度聚乙烯重量份配比为:POE弹性体10-20份,茂金属线性低密度聚乙烯80-90份。
3.根据权利要求1或2所述的一种厌氧发酵复合降解纸袋,其特征在于:所述POE弹性体密度为0.86-0.92g/cm3,熔融指数为1.0-2.0g/10min;所述茂金属线性低密度聚乙烯密度为0.91-0.93g/cm3,熔融指数为1.0-2.0g/10min。
4.根据权利要求1所述的一种厌氧发酵复合降解纸袋,其特征在于:所述纸质外层厚度为0.080-0.120mm,所述塑料内层厚度为纸质外层厚度的5%。
5.一种厌氧发酵复合降解纸袋的制备方法,包括以下步骤:
S1.将POE弹性体与茂金属线性低密度聚乙烯经高速搅拌机加热搅拌,混合均匀后出料,当混合料的温度为某一温度时,将混合料通过挤出吹膜机制得薄膜;
S2.将所述薄膜进行加热涂覆于纸质外层的内表面上形成塑料内层,以制得厌氧发酵可降解纸;或者将薄膜切割、拉丝和编织成塑料内层,再将所述塑料内层通过粘合剂粘合在纸质外层的内表面,以制得厌氧发酵可降解纸;
S3.将所述厌氧发酵可降解纸加工成厌氧发酵可降解袋。
6.根据权利要求5所述的制备方法,其特征在于:步骤S1中混合料的温度为15-25℃,挤出吹膜成型温度为160℃-180℃。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010354943.XA CN113561595A (zh) | 2020-04-29 | 2020-04-29 | 一种厌氧发酵复合降解纸袋及制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010354943.XA CN113561595A (zh) | 2020-04-29 | 2020-04-29 | 一种厌氧发酵复合降解纸袋及制备方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN113561595A true CN113561595A (zh) | 2021-10-29 |
Family
ID=78158426
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010354943.XA Pending CN113561595A (zh) | 2020-04-29 | 2020-04-29 | 一种厌氧发酵复合降解纸袋及制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113561595A (zh) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101022951A (zh) * | 2004-08-17 | 2007-08-22 | 日本聚乙烯株式会社 | 层压材料 |
CN107696623A (zh) * | 2017-10-19 | 2018-02-16 | 江阴升辉包装材料有限公司 | 一种适用于生产线自动快速包装的热收缩膜 |
CN107856384A (zh) * | 2017-10-19 | 2018-03-30 | 合肥朗胜新材料有限公司 | 一种易降解环保纸塑袋及其制备方法 |
CN107921767A (zh) * | 2015-08-31 | 2018-04-17 | 普瑞曼聚合物株式会社 | 叠层体及其制造方法、以及密封膜 |
CN110229416A (zh) * | 2019-06-21 | 2019-09-13 | 广州惠豪包装新材料有限公司 | 一种高强度抗紫外缓冲气垫聚乙烯薄膜及其制备方法 |
-
2020
- 2020-04-29 CN CN202010354943.XA patent/CN113561595A/zh active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101022951A (zh) * | 2004-08-17 | 2007-08-22 | 日本聚乙烯株式会社 | 层压材料 |
CN107921767A (zh) * | 2015-08-31 | 2018-04-17 | 普瑞曼聚合物株式会社 | 叠层体及其制造方法、以及密封膜 |
CN107696623A (zh) * | 2017-10-19 | 2018-02-16 | 江阴升辉包装材料有限公司 | 一种适用于生产线自动快速包装的热收缩膜 |
CN107856384A (zh) * | 2017-10-19 | 2018-03-30 | 合肥朗胜新材料有限公司 | 一种易降解环保纸塑袋及其制备方法 |
CN110229416A (zh) * | 2019-06-21 | 2019-09-13 | 广州惠豪包装新材料有限公司 | 一种高强度抗紫外缓冲气垫聚乙烯薄膜及其制备方法 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107629285A (zh) | 一种epe珍珠棉包装材料制备方法 | |
CN107856384A (zh) | 一种易降解环保纸塑袋及其制备方法 | |
CN102653601A (zh) | 可完全生物降解塑料树脂及其薄膜类制品的方法 | |
CN106117704A (zh) | 一种高性能环保密实塑料包装袋及其制备方法 | |
CN113561595A (zh) | 一种厌氧发酵复合降解纸袋及制备方法 | |
CN113462132A (zh) | 一种可生物降解复合材料及其制备方法和可生物降解透气膜 | |
CN113561590A (zh) | 一种厌氧发酵共挤降解袋及制备方法 | |
CN103724674B (zh) | 一种淀粉透明填充母料及其制备方法 | |
CN112063084A (zh) | 水溶性膜及其制备方法、水溶性环保袋 | |
CN110818989A (zh) | 一种可降解塑料包装袋及其制备方法 | |
CN112848588B (zh) | 抗介质低迁移的易撕聚烯烃膜、制备方法、易撕包装结构 | |
CN105238088A (zh) | 一种纤维素基生物质片材及其制备方法 | |
CN112959782B (zh) | 一种加工性能优异的完全可降解阻气气垫膜及其制备方法 | |
CN111647204A (zh) | 一种含铝箔的可降解袋及其制备方法 | |
CN107298787A (zh) | 一种可降解的复合薄膜及其制备方法 | |
CN112759800A (zh) | 一种薄壁注塑用生物基复合材料及其制备方法 | |
CN215620652U (zh) | 一种降密度片材 | |
CN110628072A (zh) | 一种聚乳酸微孔发泡材料和制作方法以及拼图玩具 | |
CN110804216A (zh) | 一种薄膜级淀粉基复合材料及其制备方法 | |
CN108641124A (zh) | 一种高生物碳含量、低密度的生物基薄膜及其制备方法 | |
CN114801362B (zh) | 一种抗菌防雾高阻隔双向拉伸聚乳酸薄膜及其制备方法 | |
CN101619144A (zh) | 多功能生物降解淀粉基母料及其生产方法 | |
CN219446378U (zh) | 透明高阻隔聚酯复合膜及包装袋 | |
CN101735517A (zh) | 等规聚丙烯发泡材料的制备方法 | |
CN113500836A (zh) | 生物基环保片材、制备方法及利用其制备的餐盒 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20211029 |
|
WD01 | Invention patent application deemed withdrawn after publication |