CN113508482A - 固体电解质材料及使用了该固体电解质材料的电池 - Google Patents
固体电解质材料及使用了该固体电解质材料的电池 Download PDFInfo
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- CN113508482A CN113508482A CN201980093443.0A CN201980093443A CN113508482A CN 113508482 A CN113508482 A CN 113508482A CN 201980093443 A CN201980093443 A CN 201980093443A CN 113508482 A CN113508482 A CN 113508482A
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- 239000007784 solid electrolyte Substances 0.000 title claims abstract description 143
- 239000000463 material Substances 0.000 title claims abstract description 133
- 239000011029 spinel Substances 0.000 claims abstract description 12
- 229910052596 spinel Inorganic materials 0.000 claims abstract description 12
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 11
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 11
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 9
- 229910052738 indium Inorganic materials 0.000 claims abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 7
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 6
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 5
- 239000003792 electrolyte Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 15
- 229910052744 lithium Inorganic materials 0.000 claims description 7
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract description 24
- 229910001416 lithium ion Inorganic materials 0.000 abstract description 24
- 239000002245 particle Substances 0.000 description 59
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 56
- 239000000843 powder Substances 0.000 description 51
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 31
- 239000002994 raw material Substances 0.000 description 29
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 28
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium chloride Substances Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 26
- 150000002500 ions Chemical class 0.000 description 25
- 229910001629 magnesium chloride Inorganic materials 0.000 description 17
- -1 transition metal sulfides Chemical class 0.000 description 17
- 239000007773 negative electrode material Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 239000007774 positive electrode material Substances 0.000 description 14
- 239000002904 solvent Substances 0.000 description 13
- 229910003002 lithium salt Inorganic materials 0.000 description 11
- 159000000002 lithium salts Chemical class 0.000 description 10
- 238000002441 X-ray diffraction Methods 0.000 description 9
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- 229910001623 magnesium bromide Inorganic materials 0.000 description 8
- 150000001450 anions Chemical class 0.000 description 6
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
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- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 5
- 150000004820 halides Chemical class 0.000 description 5
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- PSCMQHVBLHHWTO-UHFFFAOYSA-K Indium trichloride Inorganic materials Cl[In](Cl)Cl PSCMQHVBLHHWTO-UHFFFAOYSA-K 0.000 description 3
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- UPWPDUACHOATKO-UHFFFAOYSA-K gallium trichloride Chemical compound Cl[Ga](Cl)Cl UPWPDUACHOATKO-UHFFFAOYSA-K 0.000 description 2
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- 229910052732 germanium Inorganic materials 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 229910001547 lithium hexafluoroantimonate(V) Inorganic materials 0.000 description 2
- 229910001540 lithium hexafluoroarsenate(V) Inorganic materials 0.000 description 2
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 2
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 2
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 description 2
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- 125000005497 tetraalkylphosphonium group Chemical group 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910021561 transition metal fluoride Inorganic materials 0.000 description 1
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 description 1
- PCMOZDDGXKIOLL-UHFFFAOYSA-K yttrium chloride Chemical compound [Cl-].[Cl-].[Cl-].[Y+3] PCMOZDDGXKIOLL-UHFFFAOYSA-K 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
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- C01F17/00—Compounds of rare earth metals
- C01F17/30—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6
- C01F17/36—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6 halogen being the only anion, e.g. NaYF4
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- C01G15/00—Compounds of gallium, indium or thallium
- C01G15/006—Compounds containing, besides gallium, indium, or thallium, two or more other elements, with the exception of oxygen or hydrogen
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- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
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- H01M10/052—Li-accumulators
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
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- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/008—Halides
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PCT/JP2019/048207 WO2020194897A1 (ja) | 2019-03-26 | 2019-12-10 | 固体電解質材料およびそれを用いた電池 |
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US11641029B2 (en) | 2020-06-23 | 2023-05-02 | Toyota Motor Engineering & Manufacturing North America, Inc. | Metal lithium chloride derivatives in the space group of P21/c as Li super-ionic conductor, solid electrolyte, and coating layer for Li metal battery and Li-ion battery |
WO2021260584A1 (en) * | 2020-06-23 | 2021-12-30 | Toyota Jidosha Kabushiki Kaisha | Li zn cl4 derivatives in the space group of pmn2_1 as li super-ionic conductor, solid electrolyte, and coating layer for li metal battery and li-ion battery |
US11462766B2 (en) * | 2020-06-23 | 2022-10-04 | Toyota Motor Engineering & Manufacturing North America, Inc. | LiAlC14 derivatives in the space group of Pnma as Li super-ionic conductor, solid electrolyte, and coating layer for Li metal battery and Li-ion battery |
CN116615813A (zh) * | 2020-12-25 | 2023-08-18 | 松下知识产权经营株式会社 | 固体电解质材料及电池 |
JPWO2022259749A1 (de) * | 2021-06-10 | 2022-12-15 | ||
CN114006051B (zh) * | 2021-10-26 | 2022-12-09 | 西安交通大学 | 一种氯化物全无机复合固态电解质及其制备方法 |
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JP2016134294A (ja) * | 2015-01-20 | 2016-07-25 | 株式会社クラレ | リチウムイオン二次電池及びこれを用いた電気機器 |
KR101684127B1 (ko) * | 2015-06-15 | 2016-12-07 | 현대자동차주식회사 | 스피넬계 고체전해질 및 이를 이용한 전고체 전지 |
WO2017024023A1 (en) * | 2015-08-04 | 2017-02-09 | The Regents Of The University Of California | Novel high voltage 10 and 12-vertex carborane and borane electrolytes, their use in rechargable batteries, and processes for their preparation |
CN107615556A (zh) * | 2015-03-26 | 2018-01-19 | 巴斯夫公司 | 电解质和金属氢化物电池 |
CN109565047A (zh) * | 2016-11-15 | 2019-04-02 | 松下知识产权经营株式会社 | 电池用正极活性物质和电池 |
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JP5141675B2 (ja) | 2009-12-16 | 2013-02-13 | トヨタ自動車株式会社 | 硫化物固体電解質材料の製造方法、硫化物固体電解質材料およびリチウム電池 |
CN102244257B (zh) * | 2011-06-15 | 2014-02-05 | 清华大学深圳研究生院 | 一种高温型锰酸锂正极材料及其制备方法 |
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JP2016134294A (ja) * | 2015-01-20 | 2016-07-25 | 株式会社クラレ | リチウムイオン二次電池及びこれを用いた電気機器 |
CN107615556A (zh) * | 2015-03-26 | 2018-01-19 | 巴斯夫公司 | 电解质和金属氢化物电池 |
KR101684127B1 (ko) * | 2015-06-15 | 2016-12-07 | 현대자동차주식회사 | 스피넬계 고체전해질 및 이를 이용한 전고체 전지 |
WO2017024023A1 (en) * | 2015-08-04 | 2017-02-09 | The Regents Of The University Of California | Novel high voltage 10 and 12-vertex carborane and borane electrolytes, their use in rechargable batteries, and processes for their preparation |
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US12009476B2 (en) | 2024-06-11 |
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JP7445876B2 (ja) | 2024-03-08 |
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