CN113508482A - 固体电解质材料及使用了该固体电解质材料的电池 - Google Patents

固体电解质材料及使用了该固体电解质材料的电池 Download PDF

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Publication number
CN113508482A
CN113508482A CN201980093443.0A CN201980093443A CN113508482A CN 113508482 A CN113508482 A CN 113508482A CN 201980093443 A CN201980093443 A CN 201980093443A CN 113508482 A CN113508482 A CN 113508482A
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solid electrolyte
electrolyte material
examples
powder
battery
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CN201980093443.0A
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Chinese (zh)
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上野航辉
酒井章裕
宫崎晃畅
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Panasonic Intellectual Property Management Co Ltd
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Panasonic Intellectual Property Management Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562Solid materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00Compounds of rare earth metals
    • C01F17/30Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6
    • C01F17/36Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6 halogen being the only anion, e.g. NaYF4
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00Compounds of aluminium
    • C01F7/48Halides, with or without other cations besides aluminium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G15/00Compounds of gallium, indium or thallium
    • C01G15/006Compounds containing, besides gallium, indium, or thallium, two or more other elements, with the exception of oxygen or hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G29/00Compounds of bismuth
    • C01G29/006Compounds containing, besides bismuth, two or more other elements, with the exception of oxygen or hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00Compounds of zinc
    • C01G9/006Compounds containing, besides zinc, two ore more other elements, with the exception of oxygen or hydrogen
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0402Methods of deposition of the material
    • H01M4/0407Methods of deposition of the material by coating on an electrolyte layer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/30Three-dimensional structures
    • C01P2002/32Three-dimensional structures spinel-type (AB2O4)
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/62Submicrometer sized, i.e. from 0.1-1 micrometer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • H01M2300/008Halides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Secondary Cells (AREA)
  • Conductive Materials (AREA)
CN201980093443.0A 2019-03-26 2019-12-10 固体电解质材料及使用了该固体电解质材料的电池 Pending CN113508482A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2019-058334 2019-03-26
JP2019058334 2019-03-26
PCT/JP2019/048207 WO2020194897A1 (ja) 2019-03-26 2019-12-10 固体電解質材料およびそれを用いた電池

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Publication Number Publication Date
CN113508482A true CN113508482A (zh) 2021-10-15

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CN201980093443.0A Pending CN113508482A (zh) 2019-03-26 2019-12-10 固体电解质材料及使用了该固体电解质材料的电池

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US (1) US12009476B2 (de)
EP (1) EP3951973A4 (de)
JP (1) JP7445876B2 (de)
CN (1) CN113508482A (de)
WO (1) WO2020194897A1 (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11641029B2 (en) 2020-06-23 2023-05-02 Toyota Motor Engineering & Manufacturing North America, Inc. Metal lithium chloride derivatives in the space group of P21/c as Li super-ionic conductor, solid electrolyte, and coating layer for Li metal battery and Li-ion battery
WO2021260584A1 (en) * 2020-06-23 2021-12-30 Toyota Jidosha Kabushiki Kaisha Li zn cl4 derivatives in the space group of pmn2_1 as li super-ionic conductor, solid electrolyte, and coating layer for li metal battery and li-ion battery
US11462766B2 (en) * 2020-06-23 2022-10-04 Toyota Motor Engineering & Manufacturing North America, Inc. LiAlC14 derivatives in the space group of Pnma as Li super-ionic conductor, solid electrolyte, and coating layer for Li metal battery and Li-ion battery
CN116615813A (zh) * 2020-12-25 2023-08-18 松下知识产权经营株式会社 固体电解质材料及电池
JPWO2022259749A1 (de) * 2021-06-10 2022-12-15
CN114006051B (zh) * 2021-10-26 2022-12-09 西安交通大学 一种氯化物全无机复合固态电解质及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016134294A (ja) * 2015-01-20 2016-07-25 株式会社クラレ リチウムイオン二次電池及びこれを用いた電気機器
KR101684127B1 (ko) * 2015-06-15 2016-12-07 현대자동차주식회사 스피넬계 고체전해질 및 이를 이용한 전고체 전지
WO2017024023A1 (en) * 2015-08-04 2017-02-09 The Regents Of The University Of California Novel high voltage 10 and 12-vertex carborane and borane electrolytes, their use in rechargable batteries, and processes for their preparation
CN107615556A (zh) * 2015-03-26 2018-01-19 巴斯夫公司 电解质和金属氢化物电池
CN109565047A (zh) * 2016-11-15 2019-04-02 松下知识产权经营株式会社 电池用正极活性物质和电池

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5141675B2 (ja) 2009-12-16 2013-02-13 トヨタ自動車株式会社 硫化物固体電解質材料の製造方法、硫化物固体電解質材料およびリチウム電池
CN102244257B (zh) * 2011-06-15 2014-02-05 清华大学深圳研究生院 一种高温型锰酸锂正极材料及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016134294A (ja) * 2015-01-20 2016-07-25 株式会社クラレ リチウムイオン二次電池及びこれを用いた電気機器
CN107615556A (zh) * 2015-03-26 2018-01-19 巴斯夫公司 电解质和金属氢化物电池
KR101684127B1 (ko) * 2015-06-15 2016-12-07 현대자동차주식회사 스피넬계 고체전해질 및 이를 이용한 전고체 전지
WO2017024023A1 (en) * 2015-08-04 2017-02-09 The Regents Of The University Of California Novel high voltage 10 and 12-vertex carborane and borane electrolytes, their use in rechargable batteries, and processes for their preparation
CN109565047A (zh) * 2016-11-15 2019-04-02 松下知识产权经营株式会社 电池用正极活性物质和电池

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
TOMITA等: "Li ion conductivity of solid electrolyte,Li3-2xMxInBr6 (M=Mg, Ca, Sr, Ba)", 《SOLID STATE IONICS》, vol. 174, no. 1, 29 October 2004 (2004-10-29), pages 35 - 39 *

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EP3951973A4 (de) 2022-04-27
US12009476B2 (en) 2024-06-11
WO2020194897A1 (ja) 2020-10-01
EP3951973A1 (de) 2022-02-09
JP7445876B2 (ja) 2024-03-08
US20210408586A1 (en) 2021-12-30
JPWO2020194897A1 (de) 2020-10-01

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