CN113403847A - 一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法 - Google Patents

一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法 Download PDF

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CN113403847A
CN113403847A CN202110782934.5A CN202110782934A CN113403847A CN 113403847 A CN113403847 A CN 113403847A CN 202110782934 A CN202110782934 A CN 202110782934A CN 113403847 A CN113403847 A CN 113403847A
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程贤生
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Abstract

本发明公开了一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法,包括以下步骤,取适量浓度为15%的乙醚溶液放入反应釜中,并将聚酯短纤维放入乙醚溶液中,搅拌浸泡2‑3h后,使用蒸馏水洗净,得到聚酯短纤维A,将聚酯短纤维A放入恒温水浴锅中,放入蒸馏水煮沸1‑1.5h后,在60℃‑80℃条件下烘干1‑2h,静置冷却至室温,得到聚酯短纤维B,取适量间甲酚溶液放入反应釜中,将聚酯短纤维B放进反应釜中,60℃‑70℃的恒温条件下,搅拌浸泡1.5‑2h,水洗风干,得到聚酯短纤维C。本发明利用乙醚对聚酯短纤维中的油剂进行处理,再次利用蒸馏水煮沸进行处理,能够较好的处理掉油剂,提高了聚酯短纤维与聚丙烯的接枝率,提高了后续聚酯短纤维接枝的良品率。

Description

一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法
技术领域
本发明涉及聚酯纤维技术领域,尤其涉及一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法。
背景技术
聚酯纤维,俗称“涤纶”,是由有机二元酸和二元醇缩聚而成的聚酯经纺丝所得的合成纤维,简称PET纤维,属于高分子化合物,于1941年发明,是当前合成纤维的第一大品种,聚酯纤维最大的优点是抗皱性和保形性很好,具有较高的强度与弹性恢复能力,具有坚牢耐用、抗皱免烫、不粘毛等优点接枝,是指大分子链上通过化学键结合适当的支链或功能性侧基的反应,所形成的产物称作接枝共聚物接枝共聚物的性能决定于主链和支链的组成,结构,长度以及支链数,长支链的接枝物类似共混物,支链短而多大接枝物则类似无规共聚物,通过共聚,可将两种性质不同的聚合物接枝在一起,形成性能特殊的接枝物。因此,聚合物的接枝改性,已成为扩大聚合物应用领域,改善高分子材料性能的一种简单又行之有效的方法。
等离子体是继固态、液态、气态之后的物质第四态,当外加电压达到击穿电压时,气体分子被电离,产生包括电子、离子、原子和原子团在内的混合体,等离子体辅助加工被用来制造特种优良性能的新材料、研制新的化学物质和化学过程,加工、改造和精制材料及其表面,具有极其广泛的工业应用--从薄膜沉积、等离子体聚合、微电路制造到焊接、工具硬化、超微粉的合成、等离子体喷涂、等离子体冶金、等离子体化工、微波源。
传统使用的聚酯短纤维接枝处理工艺存在一定缺陷,聚酯短纤维中含有油剂,不及时的处理油剂会导致聚酯短纤维的生产效果达不到要求,次品率较高。
发明内容
基于背景技术存在的技术问题,本发明提出了一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法。
本发明提出的一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法,包括以下步骤:
S1:取适量浓度为15%的乙醚溶液放入反应釜中,并将聚酯短纤维放入乙醚溶液中,搅拌浸泡2-3h后,使用蒸馏水洗净,得到聚酯短纤维A;
S2:将聚酯短纤维A放入恒温水浴锅中,放入蒸馏水煮沸1-1.5h后,在60℃-80℃条件下烘干1-2h,静置冷却至室温,得到聚酯短纤维B;
S3:取适量间甲酚溶液放入反应釜中,将聚酯短纤维B放进反应釜中,60℃-70℃的恒温条件下,搅拌浸泡1.5-2h,水洗风干,得到聚酯短纤维C;
S4:将聚酯短纤维C放进低温等离子接枝设备中,放入聚丙烯和引发剂,进行接枝处理,得到聚丙烯-聚酯短纤维初品;
S5:将聚丙烯-聚酯短纤维初品放进真空干燥箱内,烘干4-5h,得到聚丙烯-聚酯短纤维成品。
优选地,所述S1中浸泡条件为:浸泡温度为20℃,且反应釜内为无光环境。
优选地,所述S4中引发剂为过氧化二碳酸二异丙酯溶液、过氧化环己酮溶液、过氧化苯甲酸叔丁酯溶液和过氧化苯甲酰中一种,优选为过氧化二碳酸二异丙酯溶液。
优选地,所述S5中真空干燥条件为真空干燥箱腔内压强为-0.4MPa~-0.6MPa,温度为100℃-120℃,烘干时间为3-4h。
本发明的有益效果:
本发明利用乙醚对聚酯短纤维中的油剂进行初级处理,再次利用蒸馏水煮沸对聚酯短纤维中的进行再次处理,能够较好的将聚酯短纤维中的油剂处理掉,提高了聚酯短纤维与聚丙烯的接枝率,提高了后续聚酯短纤维接枝的良品率。
附图说明
图1为本发明提出的一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法的浸泡时间对接枝率的影响图。
具体实施方式
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。
实施例1:一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法,包括以下步骤:
S1:取适量浓度为15%的乙醚溶液放入反应釜中,并将聚酯短纤维放入乙醚溶液中,搅拌浸泡2h后,使用蒸馏水洗净,得到聚酯短纤维A,浸泡条件为:浸泡温度为20℃,且反应釜内为无光环境;
S2:将聚酯短纤维A放入恒温水浴锅中,放入蒸馏水煮沸1-1.5h后,在60℃-80℃条件下烘干1h,静置冷却至室温,得到聚酯短纤维B;
S3:取适量间甲酚溶液放入反应釜中,将聚酯短纤维B放进反应釜中,60℃-70℃的恒温条件下,搅拌浸泡1.5-2h,水洗风干,得到聚酯短纤维C;
S4:将聚酯短纤维C放进低温等离子接枝设备中,放入聚丙烯和引发剂,进行接枝处理,得到聚丙烯-聚酯短纤维初品,引发剂为过氧化二碳酸二异丙酯溶液、过氧化环己酮溶液、过氧化苯甲酸叔丁酯溶液和过氧化苯甲酰中一种,优选为过氧化二碳酸二异丙酯溶液;
S5:将聚丙烯-聚酯短纤维初品放进真空干燥箱内,烘干4-5h,得到聚丙烯-聚酯短纤维成品,真空干燥条件为真空干燥箱腔内压强为-0.4MPa~-0.6MPa,温度为100℃-120℃,烘干时间为3-4h。
实施例2:一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法,包括以下步骤:
S1:取适量浓度为15%的乙醚溶液放入反应釜中,并将聚酯短纤维放入乙醚溶液中,搅拌浸泡2.5h后,使用蒸馏水洗净,得到聚酯短纤维A,浸泡条件为:浸泡温度为20℃,且反应釜内为无光环境;
S2:将聚酯短纤维A放入恒温水浴锅中,放入蒸馏水煮沸1-1.5h后,在60℃-80℃条件下烘干1.5h,静置冷却至室温,得到聚酯短纤维B;
S3:取适量间甲酚溶液放入反应釜中,将聚酯短纤维B放进反应釜中,60℃-70℃的恒温条件下,搅拌浸泡1.5-2h,水洗风干,得到聚酯短纤维C;
S4:将聚酯短纤维C放进低温等离子接枝设备中,放入聚丙烯和引发剂,进行接枝处理,得到聚丙烯-聚酯短纤维初品,引发剂为过氧化二碳酸二异丙酯溶液、过氧化环己酮溶液、过氧化苯甲酸叔丁酯溶液和过氧化苯甲酰中一种,优选为过氧化二碳酸二异丙酯溶液;
S5:将聚丙烯-聚酯短纤维初品放进真空干燥箱内,烘干4-5h,得到聚丙烯-聚酯短纤维成品,真空干燥条件为真空干燥箱腔内压强为-0.4MPa~-0.6MPa,温度为100℃-120℃,烘干时间为3-4h。
实施例3:一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法,包括以下步骤:
S1:取适量浓度为15%的乙醚溶液放入反应釜中,并将聚酯短纤维放入乙醚溶液中,搅拌浸泡3h后,使用蒸馏水洗净,得到聚酯短纤维A,浸泡条件为:浸泡温度为20℃,且反应釜内为无光环境;
S2:将聚酯短纤维A放入恒温水浴锅中,放入蒸馏水煮沸1-1.5h后,在60℃-80℃条件下烘干2h,静置冷却至室温,得到聚酯短纤维B;
S3:取适量间甲酚溶液放入反应釜中,将聚酯短纤维B放进反应釜中,60℃-70℃的恒温条件下,搅拌浸泡1.5-2h,水洗风干,得到聚酯短纤维C;
S4:将聚酯短纤维C放进低温等离子接枝设备中,放入聚丙烯和引发剂,进行接枝处理,得到聚丙烯-聚酯短纤维初品,引发剂为过氧化二碳酸二异丙酯溶液、过氧化环己酮溶液、过氧化苯甲酸叔丁酯溶液和过氧化苯甲酰中一种,优选为过氧化二碳酸二异丙酯溶液;
S5:将聚丙烯-聚酯短纤维初品放进真空干燥箱内,烘干4-5h,得到聚丙烯-聚酯短纤维成品,真空干燥条件为真空干燥箱腔内压强为-0.4MPa~-0.6MPa,温度为100℃-120℃,烘干时间为3-4h。
红外光谱检测
利用红外光谱仪对三个实施例中的聚丙烯-聚酯短纤维成品进行检测,检测结果如图1所示。
综上所述,实施例2为本发明的最佳实施例。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。

Claims (4)

1.一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法,其特征在于,包括以下步骤:
S1:取适量浓度为15%的乙醚溶液放入反应釜中,并将聚酯短纤维放入乙醚溶液中,搅拌浸泡2-3h后,使用蒸馏水洗净,得到聚酯短纤维A;
S2:将聚酯短纤维A放入恒温水浴锅中,放入蒸馏水煮沸1-1.5h后,在60℃-80℃条件下烘干1-2h,静置冷却至室温,得到聚酯短纤维B;
S3:取适量间甲酚溶液放入反应釜中,将聚酯短纤维B放进反应釜中,60℃-70℃的恒温条件下,搅拌浸泡1.5-2h,水洗风干,得到聚酯短纤维C;
S4:将聚酯短纤维C放进低温等离子接枝设备中,放入聚丙烯和引发剂,进行接枝处理,得到聚丙烯-聚酯短纤维初品;
S5:将聚丙烯-聚酯短纤维初品放进真空干燥箱内,烘干4-5h,得到聚丙烯-聚酯短纤维成品。
2.根据权利要求1所述的一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法,其特征在于,所述S1中浸泡条件为:浸泡温度为20℃,且反应釜内为无光环境。
3.根据权利要求1所述的一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法,其特征在于,所述S4中引发剂为过氧化二碳酸二异丙酯溶液、过氧化环己酮溶液、过氧化苯甲酸叔丁酯溶液和过氧化苯甲酰中一种,优选为过氧化二碳酸二异丙酯溶液。
4.根据权利要求1所述的一种低温等离子处理聚酯短纤维接枝防油处理的工艺方法,其特征在于,所述S5中真空干燥条件为真空干燥箱腔内压强为-0.4MPa~-0.6MPa,温度为100℃-120℃,烘干时间为3-4h。
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