CN113088949A - High-corrosion-resistance workpiece surface treating agent and preparation method thereof - Google Patents

High-corrosion-resistance workpiece surface treating agent and preparation method thereof Download PDF

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Publication number
CN113088949A
CN113088949A CN202110363997.7A CN202110363997A CN113088949A CN 113088949 A CN113088949 A CN 113088949A CN 202110363997 A CN202110363997 A CN 202110363997A CN 113088949 A CN113088949 A CN 113088949A
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storage tank
side wall
fixedly connected
corrosion
rod
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季茂远
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/23Condensed phosphates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention belongs to the technical field of surface treating agents, and particularly relates to a high-corrosion-resistance workpiece surface treating agent and a preparation method thereof, wherein the high-corrosion-resistance workpiece surface treating agent is stored in a storage tank; the storage tank comprises an isolation cover; the isolation cover is arranged at the top of the storage tank; a motor is fixedly connected inside the isolation cover; the output end of the motor is fixedly connected with a rotating rod, penetrates through the isolation cover and extends into the storage tank; a plurality of groups of transmission rods are fixedly connected to the middle part of the rotating rod; the end part of the transmission rod is connected with a straight cylinder piston cylinder in a sliding way; a spring is connected between the end part of the transmission rod and the inner side wall of the straight cylinder piston cylinder; through at the inside quick-drying agent that increases of high corrosion resistant work piece surface treatment agent, can be quick when high corrosion resistant work piece surface treatment agent uses dry at the work piece surface, make the work piece receive the influence that there is moisture inside the high corrosion resistant work piece surface treatment agent less, make the work piece surface be difficult for leaving the water stain simultaneously.

Description

High-corrosion-resistance workpiece surface treating agent and preparation method thereof
Technical Field
The invention belongs to the technical field of surface treating agents, and particularly relates to a high-corrosion-resistance workpiece surface treating agent and a preparation method thereof.
Background
The surface treatment agent refers to a reagent used for treating the surface of a material to achieve a specific purpose, and includes a metal surface treatment agent, a polytetrafluoroethylene surface treatment agent, a silica gel surface treatment agent, and the like.
Some technical schemes related to surface treatment agents also appear in the prior art, for example, a Chinese patent with application number of 2020103216959 discloses a surface treatment agent for improving the corrosion resistance of electrolytic copper foil, which comprises 130-170g of potassium pyrophosphate, 3-8g of stannous sulfate, 18-27g of zinc sulfate, 1-5g of cerium sulfate and 3-9mg of an additive A; wherein, the additive A is one or more than two of SPS, formaldehyde or 1, 4-butynediol.
In the prior art, when the high-corrosion-resistance workpiece surface treating agent is coated on the surface of a workpiece, the drying speed is low, so that the moisture in the treating agent can influence the surface of the workpiece, and the problem that the water mark is remained on the surface of the workpiece due to long drying time is solved.
Disclosure of Invention
The invention provides a high-corrosion-resistance workpiece surface treating agent and a preparation method thereof, aiming at making up for the defects of the prior art and solving the problems that when the high-corrosion-resistance workpiece surface treating agent is coated on the surface of a workpiece, because the drying speed is slow, moisture existing in the treating agent can affect the surface of the workpiece, and the drying time is long, and water marks can be remained on the surface of the workpiece.
The technical scheme adopted by the invention for solving the technical problems is as follows: the high corrosion-resistant workpiece surface treating agent is stored in a storage tank and comprises the following raw materials in parts by weight:
10-15 parts of potassium pyrophosphate
1-3 parts of stannous sulfate
2-5 parts of zinc sulfate
1-3 parts of cerium sulfate
1-3 parts of quick drying agent; through at the inside quick-drying agent that increases of high corrosion resistant work piece surface treatment agent, can be quick when high corrosion resistant work piece surface treatment agent uses dry at the work piece surface, make the work piece receive the influence that there is moisture inside the high corrosion resistant work piece surface treatment agent less, make the work piece surface be difficult for leaving the water stain simultaneously.
Preferably, the quick-drying agent consists of the following raw materials in parts by weight:
10-15 parts of nano titanium dioxide
1-5 parts of charcoal ash
10-15 parts of potassium permanganate solution.
Preferably, the storage tank comprises a partition lid; the isolation cover is arranged at the top of the storage tank; a motor is fixedly connected inside the isolation cover; the output end of the motor is fixedly connected with a rotating rod, penetrates through the isolation cover and extends into the storage tank; a plurality of groups of transmission rods are fixedly connected to the middle part of the rotating rod; the end part of the transmission rod is connected with a straight cylinder piston cylinder in a sliding way; a spring is connected between the end part of the transmission rod and the inner side wall of the straight cylinder piston cylinder; a support rod is fixedly connected to one side, close to the inner side wall of the storage tank, of the straight-cylinder piston cylinder; the end part of the supporting rod is fixedly connected with a side wall scraper; when the high corrosion-resistant workpiece surface treating agent is used, firstly, the water in the storage tank is cleaned, the problem of water saturation caused by the fact that the high corrosion-resistant workpiece surface treating agent is placed in the storage tank due to the fact that water is remained in the storage tank is avoided, after the storage tank is treated, the high corrosion-resistant workpiece surface treating agent can be added into the storage tank, then, the isolation cover covers the top of the storage tank, the motor in the isolation cover is opened to drive the rotating rod to rotate, at the moment, the side wall scraper can stir the high corrosion-resistant workpiece surface treating agent in the storage tank, due to the fact that the side wall scraper is arc-shaped, when the high corrosion-resistant workpiece surface treating agent is impacted, a force close to the inner side wall of the storage tank is exerted, then, the straight cylinder piston cylinder can slide on the transmission rod, the side wall scraper can be attached to the inner side wall of the storage tank, and the high, meanwhile, the problem that the surface treating agent of the high-corrosion-resistance workpiece is adhered to the inner side wall of the storage tank can be avoided.
Preferably, a diversion trench is formed in the side wall scraper; a plurality of groups of flow guide grooves are arranged in the side wall scraper plate; the diversion trench is formed in the side wall scraper, so that when the side wall scraper impacts the high-corrosion-resistance workpiece surface treatment agent in the storage tank, part of the high-corrosion-resistance workpiece surface treatment agent flows through the diversion trench, and the problem that when the side wall scraper stirs the high-corrosion-resistance workpiece surface treatment agent in the storage tank, the flow direction of the high-corrosion-resistance workpiece surface treatment agent is too uniform, and the high-corrosion-resistance workpiece surface treatment agent in the storage tank is not fully stirred is solved.
Preferably, the middle part of the rotating rod is fixedly connected with a water storage tank; a first water guide pipe is communicated between the water storage tank and the rod cavity of the straight cylinder piston cylinder; the first water guide pipe is provided with a one-way valve; a second water guide pipe is communicated between the rod cavity of the straight cylinder piston cylinder and the side wall scraper plate; the middle part of the second water guide pipe is provided with a one-way valve; the second water guide pipe extends to the side wall of the diversion trench on the side wall scraper; the side wall of the diversion trench is fixedly connected with a guide film; when the straight cylinder piston cylinder is pulled by the side wall scraper plate towards the direction close to the inner side wall of the storage tank, water in a rod cavity of the straight cylinder piston cylinder is conveyed to the inside of the side wall scraper plate through the second water guide pipe and is sprayed out of the inside of the guide groove, and meanwhile, as the guide soft sheet is arranged in the guide groove, the high corrosion-resistant workpiece surface treating agent can impact the water spraying opening of the second water guide pipe through the guide of the guide soft sheet when passing through the inside of the guide groove, so that the high corrosion-resistant workpiece surface treating agent is fully mixed with the water, and after the water is added in the high corrosion-resistant workpiece surface treating agent, partial water is filled in the high corrosion-resistant workpiece surface treating agent, so that the problem of water shortage can not occur.
Preferably, the bottom end of the rotating rod is connected with a sleeve in a sliding manner; a limiting rod is fixedly connected to the side wall of the rotating rod; a stirring impeller is fixedly connected to the side wall of the sleeve; the bottom of the sleeve is fixedly connected with a sweeping plate; when the dwang was driven by the motor, impeller can rotate simultaneously in the inside of holding tank, then the sleeve will be promoted downwards by impeller, later clean the bottom inside wall that the board will contact the holding tank, scrape it, avoid the bottom of holding tank to have high corrosion-resistant work piece surface treatment agent to precipitate, and the quality problems appear in its processing agent that leads to.
Preferably, the bottom of the cleaning plate is fixedly connected with a friction elastic bag; a U-shaped piston cylinder is arranged in the sweeping plate at a position corresponding to the friction elastic bag; an ejector rod is connected to the port corresponding to the friction elastic bag in the U-shaped piston cylinder in a sliding manner; the other port of the U-shaped piston cylinder is connected with a soft wiping rod in a sliding manner; a soft air bag is arranged inside the U-shaped piston cylinder; when the cleaning plate contacts the inner side wall of the bottom of the storage tank, the friction elastic bag can be isolated between the cleaning plate and the storage tank, so that the problem that the tank body of the storage tank is scratched due to the fact that the cleaning plate directly contacts the inner side wall of the bottom of the storage tank is avoided; simultaneously the ejector pin can be pushed into to the U-shaped piston cylinder inside by the elastic bag of friction, then moves through the deformation of soft gasbag, can push out the U-shaped piston cylinder with soft pole of wiping, and then makes the bottom inside wall of soft pole contact holding vessel of wiping, makes it clean the tank bottoms of holding vessel, further promotes the effect of cleaning the board.
Preferably, the end part of the soft wiping rod is fixedly connected with a rubber head; a plurality of groups of slag guide grooves are formed in the rubber head; the end part of the soft wiping rod is fixedly connected with the rubber head, so that the soft wiping rod can deform when contacting with the inner side wall of the bottom of the storage tank, then the inner side wall of the bottom of the storage tank is wiped, the damage to the tank body at the bottom of the storage tank caused by the sweeping plate is further reduced, and meanwhile, the high-corrosion-resistant workpiece surface treating agent swept by the slag guide groove is thrown, so that the high-corrosion-resistant workpiece surface treating agent is mixed with the solution in the middle of the storage tank.
Preferably, a plurality of groups of guide grooves are formed in the cleaning plate; the inner side wall of the top of the guide groove is fixedly connected with a conical block; the cleaning plate is internally provided with a guide hole which is communicated with the guide groove; when the cleaning plate is close to the bottom of the inner side wall of the storage tank, part of the treating agent contacted with the cleaning plate flows through the guide groove and is then dispersed by the conical blocks, so that the treating agent in the storage tank can be better stirred and mixed by the cleaning plate.
A preparation method of a high corrosion-resistant workpiece surface treating agent is suitable for the high corrosion-resistant workpiece surface treating agent and comprises the following steps:
s1: firstly, adding potassium pyrophosphate, zinc sulfate and cerium sulfate into a container, preheating, adding stannous sulfate into the container when the temperature reaches 50 ℃, simultaneously stirring the mixture, and increasing the temperature to 60 ℃ to obtain a first solution;
s2: cooling the solution I in the S1 to 45 ℃, adding a nano titanium dioxide solution, charcoal ash solution and a potassium permanganate solution into the solution I, and then continuously stirring to obtain a solution II;
s3: and adding the solution II into a stirring device, adjusting the rotating speed of the stirring device to be 500-1000 r/min, standing the solution, and adding the solution into a storage tank to further finish the preparation of the high-corrosion-resistance workpiece surface treating agent.
The invention has the beneficial effects that:
1. the invention provides a high corrosion-resistant workpiece surface treating agent and a preparation method thereof.
2. According to the invention, the stirring impeller is additionally arranged at the bottom of the isolation cover in the high corrosion-resistant workpiece surface treating agent storage tank, so that the mixture of the high corrosion-resistant workpiece surface treating agent in the storage tank can be kept in a uniform state, the phenomenon of solid-liquid separation when the high corrosion-resistant workpiece surface treating agent is in the storage tank for a long time is avoided, and meanwhile, the water spray head is additionally arranged on the side wall scraper, so that the water in the high corrosion-resistant workpiece surface treating agent can be filled with partial water after the water is increased, and the problem of water shortage can be avoided.
3. According to the invention, the telescopic cleaning plate is additionally arranged at the bottom of the rotating rod, so that when the motor runs, the cleaning plate can be pushed to the bottom of the storage tank through the stirring impeller to clean the bottom of the storage tank, and meanwhile, the flexible rubber head is additionally arranged at the bottom of the cleaning plate, so that the problem that the cleaning plate scratches the bottom of the storage tank can be avoided, and meanwhile, the surface treating agent of a high-corrosion-resistant workpiece adhered to the bottom of the storage tank can be swept, and the waste of the treating agent is avoided.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this application, illustrate embodiment(s) of the invention and together with the description serve to explain the invention without limiting the invention. In the drawings:
FIG. 1 is a perspective view of the present invention;
FIG. 2 is a cross-sectional view of the present invention;
FIG. 3 is a cross-sectional view of the sidewall scraper;
FIG. 4 is a side cross-sectional view of the bottom sweeping shoe;
FIG. 5 is a partial cross-sectional view of a rubber soft wiping rod;
FIG. 6 is a front view of the bottom sweeping board;
FIG. 7 is a flow chart of a manufacturing process in the present invention.
Illustration of the drawings:
1. a storage tank; 11. an isolation cover; 2. a motor; 21. rotating the rod; 22. a transmission rod; 23. a straight cylinder piston cylinder; 24. a support bar; 25. a sidewall scraper; 3. a diversion trench; 4. a water storage tank; 41. a first water conduit; 42. a second water conduit; 5. a leader film; 6. a sleeve; 61. a stirring impeller; 62. cleaning the board; 63. rubbing the elastic bag; 64. a U-shaped piston cylinder; 65. a top rod; 66. a soft wiping rod; 67. a soft air bag; 68. a rubber head; 69. a slag guide groove; 7. a guide groove; 71. a conical block; 72. and (4) a guide hole.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Specific examples are given below.
Example one
A high-corrosion-resistance workpiece surface treating agent is composed of the following raw materials in parts by weight: 10 parts of potassium pyrophosphate, 1 part of stannous sulfate, 2 parts of zinc sulfate, 1 part of cerium sulfate and 1 part of quick-drying agent; the quick-drying agent consists of the following raw materials in parts by weight: 10 parts of nano titanium dioxide, 1 part of charcoal ash and 10 parts of potassium permanganate solution.
The high-corrosion-resistance workpiece surface treating agent prepared by the embodiment is used for spraying a workpiece, standing for 2H after spraying is finished, placing the workpiece at a position where air is smooth for 1 day after standing is finished, and measuring the drying degree of the surface of the workpiece after 1 day.
Example two
A high-corrosion-resistance workpiece surface treating agent is composed of the following raw materials in parts by weight: 13 parts of potassium pyrophosphate, 2 parts of stannous sulfate, 3 parts of zinc sulfate, 2 parts of cerium sulfate and 2 parts of quick-drying agent; the quick-drying agent consists of the following raw materials in parts by weight: 13 parts of nano titanium dioxide, 3 parts of charcoal ash and 13 parts of potassium permanganate solution.
The high-corrosion-resistance workpiece surface treating agent prepared by the embodiment is used for spraying a workpiece, standing for 2H after spraying is finished, placing the workpiece at a position where air is smooth for 1 day after standing is finished, and measuring the drying degree of the surface of the workpiece after 1 day.
EXAMPLE III
A high-corrosion-resistance workpiece surface treating agent is composed of the following raw materials in parts by weight: 15 parts of potassium pyrophosphate, 3 parts of stannous sulfate, 5 parts of zinc sulfate, 3 parts of cerium sulfate and 3 parts of quick-drying agent; the quick-drying agent consists of the following raw materials in parts by weight: 15 parts of nano titanium dioxide, 5 parts of charcoal ash and 15 parts of potassium permanganate solution.
The high-corrosion-resistance workpiece surface treating agent prepared by the embodiment is used for spraying a workpiece, standing for 2H after spraying is finished, placing the workpiece at a position where air is smooth for 1 day after standing is finished, and measuring the drying degree of the surface of the workpiece after 1 day.
The examples 1-3 show that the high corrosion-resistant workpiece surface treating agent disclosed by the invention can be quickly dried, and the problem that water stains are not easily left after the high corrosion-resistant workpiece surface treating agent is sprayed on a workpiece is fully avoided.
As shown in fig. 1 to 7, the present invention provides a high corrosion-resistant workpiece surface treating agent, the storage tank 1 comprises a separation cover 11; the isolation cover 11 is arranged on the top of the storage tank 1; the motor 2 is fixedly connected inside the isolation cover 11; the output end of the motor 2 is fixedly connected with a rotating rod 21, penetrates through the isolation cover 11 and extends into the storage tank 1; a plurality of groups of transmission rods 22 are fixedly connected to the middle part of the rotating rod 21; the end part of the transmission rod 22 is connected with a straight cylinder piston cylinder 23 in a sliding way; a spring is connected between the end part of the transmission rod 22 and the inner side wall of the straight cylinder piston cylinder 23; a support rod 24 is fixedly connected to one side of the straight cylinder piston cylinder 23 close to the inner side wall of the storage tank 1; the end part of the supporting rod 24 is fixedly connected with a side wall scraper 25; when the high corrosion-resistant workpiece surface treating agent stirring device is used, firstly, the water inside the storage tank 1 is cleaned, the problem of water saturation caused by the fact that the high corrosion-resistant workpiece surface treating agent is placed in the storage tank 1 is solved, after the storage tank 1 is treated, the high corrosion-resistant workpiece surface treating agent can be added into the storage tank, then the isolation cover 11 is covered on the top of the storage tank 1, the motor 2 inside the isolation cover 11 is opened to drive the rotating rod 21 to rotate, at the moment, the side wall scraper 25 can stir the high corrosion-resistant workpiece surface treating agent inside the storage tank 1, because the side wall scraper 25 is arc-shaped, when the high corrosion-resistant workpiece surface treating agent is impacted, a force close to the inner side wall of the storage tank 1 can be applied, then the straight cylinder piston cylinder 23 can slide on the driving rod 22, so that the side wall scraper 25 is attached to the inner side wall of the storage tank 1, and the high corrosion-resistant workpiece surface treating agent inside the storage tank 1, and simultaneously, the problem that the surface treating agent for the high-corrosion-resistant workpiece is adhered to the inner side wall of the storage tank 1 can be avoided.
In one embodiment of the present invention, the sidewall scraper 25 has a diversion trench 3 therein; a plurality of groups of the diversion trenches 3 are arranged in the side wall scraper 25; the diversion trench 3 is formed in the side wall scraper 25, so that when the side wall scraper 25 impacts the high corrosion-resistant workpiece surface treatment agent in the storage tank 1, part of the high corrosion-resistant workpiece surface treatment agent flows through the diversion trench 3, and the problem that when the side wall scraper 25 stirs the high corrosion-resistant workpiece surface treatment agent in the storage tank 1, the flow direction of the high corrosion-resistant workpiece surface treatment agent is too uniform, and the high corrosion-resistant workpiece surface treatment agent in the storage tank 1 is not fully stirred is solved.
As an embodiment of the present invention, the water storage tank 4 is fixedly connected to the middle of the rotating rod 21; a first water guide pipe 41 is communicated between the water storage tank 4 and the rod cavity of the straight cylinder piston cylinder 23; a check valve is arranged on the first water guide pipe 41; a second water guide pipe 42 is communicated between a rod cavity of the straight cylinder piston cylinder 23 and the side wall scraper 25; the middle part of the second water guide pipe 42 is provided with a one-way valve; the second water guide pipe 42 extends to the side wall of the diversion trench 3 on the side wall scraper 25; the side wall of the diversion trench 3 is fixedly connected with a guide film 5; when the cylinder 23 is pulled by the side wall scraper 25 in a direction approaching the inner side wall of the storage tank 1, the water in the rod cavity of the straight cylinder piston cylinder 23 is sent to the inner part of the side wall scraper 25 through the second water guide pipe 42 and is sprayed out from the inner part of the diversion trench 3, meanwhile, as the guide film 5 is arranged in the guide groove 3, when the surface treating agent of the high corrosion resistant workpiece passes through the guide groove 3, will impact the water jet of the second water guiding pipe 42 through the guiding of the guiding film 5, so that the high corrosion-resistant workpiece surface treating agent is fully mixed with the water content, after the water content in the high corrosion-resistant workpiece surface treating agent is increased, the water in the first water guide pipe 41 and the second water guide pipe 42 is filled with a part of water, so that the problem of water shortage can not occur, the water content can not flow freely when the transmission rod 22 and the straight cylinder piston 23 slide relatively.
As an embodiment of the present invention, a sleeve 6 is slidably connected to the bottom end of the rotating rod 21; a limiting rod is fixedly connected to the side wall of the rotating rod 21; a stirring impeller 61 is fixedly connected to the side wall of the sleeve 6; a sweeping plate 62 is fixedly connected to the bottom of the sleeve 6; when dwang 21 is driven by motor 2, impeller 61 can rotate simultaneously in the inside of holding tank 1, then sleeve 6 will be promoted downwards by impeller 61, later clean board 62 and will contact the bottom inside wall of holding tank 1, scrape it, avoid the bottom of holding tank 1 to have high corrosion-resistant work piece surface treatment agent to deposit, and the quality problems appear in its processing agent that leads to.
In one embodiment of the present invention, a friction elastic bag 63 is fixed to the bottom of the cleaning plate 62; a U-shaped piston cylinder 64 is arranged in the cleaning plate 62 at a position corresponding to the friction elastic bag 63; an ejector rod 65 is connected to the port corresponding to the friction elastic bag 63 in the U-shaped piston cylinder 64 in a sliding manner; the other end of the U-shaped piston cylinder 64 is connected with a soft wiping rod 66 in a sliding way; a soft air bag 67 is arranged in the U-shaped piston cylinder 64; when the cleaning plate 62 contacts the inner side wall of the bottom of the storage tank 1, the friction elastic bag 63 can isolate the cleaning plate 62 from the storage tank 1, so that the problem that the tank body of the storage tank 1 is scratched due to the fact that the cleaning plate 62 directly contacts the inner side wall of the bottom of the storage tank 1 is avoided; meanwhile, the ejector rod 65 can be pushed into the U-shaped piston cylinder 64 by the friction elastic bag 63, then the soft wiping rod 66 can be pushed out of the U-shaped piston cylinder 64 through the deformation movement of the soft air bag 67, and the soft wiping rod 66 is made to contact with the inner side wall of the bottom of the storage tank 1, so that the tank bottom of the storage tank 1 can be cleaned, and the cleaning effect of the cleaning plate 62 is further improved.
As an embodiment of the present invention, a rubber head 68 is fixed to an end of the soft wiping rod 66; a plurality of groups of slag guide grooves 69 are formed in the rubber head 68; through the tip rigid coupling at soft pole 66 of wiping there is the rubber head 68, can be when soft pole 66 of wiping will contact storage tank 1 bottom inside wall, carry out deformation, then wipe storage tank 1's bottom inside wall, further reduce the injury that cleaning plate 62 can cause storage tank 1 bottom jar body, lead slag chute 69 simultaneously and can throw the high corrosion-resistant work piece surface treatment agent who sweeps up, make its and storage tank 1 middle part's solution mix.
In one embodiment of the present invention, the cleaning plate 62 is provided with a plurality of sets of guide grooves 7; a conical block 71 is fixedly connected to the inner side wall of the top of the guide groove 7; a guide hole 72 is formed in the cleaning plate 62 and communicated with the guide groove 7; when the cleaning plate 62 is close to the bottom of the inner wall of the storage tank 1, part of the treating agent contacted with the cleaning plate 62 flows through the guide groove 7 and is then dispersed by the tapered block 71, so that the cleaning plate 62 can stir and mix the treating agent in the storage tank 1 better.
A preparation method of a high corrosion-resistant workpiece surface treating agent is suitable for the high corrosion-resistant workpiece surface treating agent, and the preparation process comprises the following steps:
s1: firstly, adding potassium pyrophosphate, zinc sulfate and cerium sulfate into a container, preheating, adding stannous sulfate into the container when the temperature reaches 50 ℃, simultaneously stirring the mixture, and increasing the temperature to 60 ℃ to obtain a first solution;
s2: cooling the solution I in the S1 to 45 ℃, adding a nano titanium dioxide solution, charcoal ash solution and a potassium permanganate solution into the solution I, and then continuously stirring to obtain a solution II;
s3: and adding the solution II into a stirring device, adjusting the rotating speed of the stirring device to be 500-1000 r/min, standing the solution, and adding the solution into a storage tank to further finish the preparation of the high-corrosion-resistance workpiece surface treating agent.
The working principle is as follows: when the high corrosion-resistant workpiece surface treating agent stirring device is used, firstly, the water inside the storage tank 1 is cleaned, the problem of water saturation caused by the fact that the high corrosion-resistant workpiece surface treating agent is placed in the storage tank 1 is solved, after the storage tank 1 is treated, the high corrosion-resistant workpiece surface treating agent can be added into the storage tank, then the isolation cover 11 is covered on the top of the storage tank 1, the motor 2 inside the isolation cover 11 is opened to drive the rotating rod 21 to rotate, at the moment, the side wall scraper 25 can stir the high corrosion-resistant workpiece surface treating agent inside the storage tank 1, because the side wall scraper 25 is arc-shaped, when the high corrosion-resistant workpiece surface treating agent is impacted, a force close to the inner side wall of the storage tank 1 can be applied, then the straight cylinder piston cylinder 23 can slide on the driving rod 22, so that the side wall scraper 25 is attached to the inner side wall of the storage tank 1, and the high corrosion-resistant workpiece surface treating agent inside the storage tank 1, meanwhile, the problem that the surface treating agent for the high-corrosion-resistance workpiece is adhered to the inner side wall of the storage tank 1 can be avoided; the diversion trench 3 is formed in the side wall scraper 25, so that when the side wall scraper 25 impacts the high corrosion-resistant workpiece surface treatment agent in the storage tank 1, part of the high corrosion-resistant workpiece surface treatment agent flows through the diversion trench 3, and the problem that when the side wall scraper 25 stirs the high corrosion-resistant workpiece surface treatment agent in the storage tank 1, the flow direction of the high corrosion-resistant workpiece surface treatment agent is too uniform, so that the high corrosion-resistant workpiece surface treatment agent in the storage tank 1 is not fully stirred is solved; when the cylinder 23 is pulled by the side wall scraper 25 in a direction approaching the inner side wall of the storage tank 1, the water in the rod cavity of the straight cylinder piston cylinder 23 is sent to the inner part of the side wall scraper 25 through the second water guide pipe 42 and is sprayed out from the inner part of the diversion trench 3, meanwhile, as the guide film 5 is arranged in the guide groove 3, when the surface treating agent of the high corrosion resistant workpiece passes through the guide groove 3, will impact the water jet of the second water guiding pipe 42 through the guiding of the guiding film 5, so that the high corrosion-resistant workpiece surface treating agent is fully mixed with the water content, after the water content in the high corrosion-resistant workpiece surface treating agent is increased, the water in the first water guide pipe 41 and the second water guide pipe 42 is filled with a part of water, so that the problem of water shortage can not occur, when the transmission rod 22 and the straight cylinder piston cylinder 23 slide relatively, the water content has the effect of not flowing randomly; when the rotating rod 21 is driven by the motor 2, the stirring impeller 61 can rotate in the storage tank 1 at the same time, then the sleeve 6 can be pushed downwards by the stirring impeller 61, and then the cleaning plate 62 can contact the inner side wall of the bottom of the storage tank 1 to scrape the inner side wall, so that the problem of quality of a treating agent caused by the fact that the treating agent is deposited on the surface of a high-corrosion-resistant workpiece at the bottom of the storage tank 1 is avoided; when the cleaning plate 62 contacts the inner side wall of the bottom of the storage tank 1, the friction elastic bag 63 can isolate the cleaning plate 62 from the storage tank 1, so that the problem that the tank body of the storage tank 1 is scratched due to the fact that the cleaning plate 62 directly contacts the inner side wall of the bottom of the storage tank 1 is avoided; meanwhile, the ejector rod 65 is pushed into the U-shaped piston cylinder 64 by the friction elastic bag 63, and then the soft wiping rod 66 is pushed out of the U-shaped piston cylinder 64 through the deformation movement of the soft air bag 67, so that the soft wiping rod 66 is in contact with the inner side wall of the bottom of the storage tank 1, the tank bottom of the storage tank 1 is cleaned by the soft wiping rod 66, and the cleaning effect of the cleaning plate 62 is further improved; the end part of the soft wiping rod 66 is fixedly connected with the rubber head 68, so that the soft wiping rod 66 can deform when contacting with the inner side wall of the bottom of the storage tank 1, then the inner side wall of the bottom of the storage tank 1 is wiped, the damage of the sweeping plate 62 to the tank body at the bottom of the storage tank 1 is further reduced, and meanwhile, the sweeping-up high-corrosion-resistance workpiece surface treating agent is thrown up by the slag guide groove 69 and is mixed with the solution in the middle of the storage tank 1; when the cleaning plate 62 is close to the bottom of the inner wall of the storage tank 1, part of the treating agent contacted with the cleaning plate 62 flows through the guide groove 7 and is then dispersed by the tapered block 71, so that the cleaning plate 62 can stir and mix the treating agent in the storage tank 1 better.
In the description herein, references to the description of "one embodiment," "an example," "a specific example" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed.

Claims (10)

1. A high corrosion-resistant workpiece surface treating agent is characterized in that: the high-corrosion-resistance workpiece surface treating agent is stored in a storage tank (1), and consists of the following raw materials in parts by weight:
10-15 parts of potassium pyrophosphate
1-3 parts of stannous sulfate
2-5 parts of zinc sulfate
1-3 parts of cerium sulfate
1-3 parts of quick drying agent.
2. The surface treatment agent for highly corrosion-resistant workpieces according to claim 1, wherein: the quick-drying agent is composed of the following raw materials in parts by weight:
10-15 parts of nano titanium dioxide
1-5 parts of charcoal ash
10-15 parts of potassium permanganate solution.
3. The surface treatment agent for highly corrosion-resistant workpieces according to claim 2, wherein: the storage tank (1) comprises an isolation cover (11); the isolation cover (11) is arranged at the top of the storage tank (1); a motor (2) is fixedly connected inside the isolation cover (11); the output end of the motor (2) is fixedly connected with a rotating rod (21) and penetrates through the isolation cover (11) to extend into the storage tank (1); a plurality of groups of transmission rods (22) are fixedly connected to the middle part of the rotating rod (21); the end part of the transmission rod (22) is connected with a straight cylinder piston cylinder (23) in a sliding way; a spring is connected between the end part of the transmission rod (22) and the inner side wall of the straight cylinder piston cylinder (23); a support rod (24) is fixedly connected to one side of the straight cylinder piston cylinder (23) close to the inner side wall of the storage tank (1); and the end part of the supporting rod (24) is fixedly connected with a side wall scraper (25).
4. The surface treatment agent for highly corrosion-resistant workpieces according to claim 3, wherein: a diversion trench (3) is formed in the side wall scraper (25); the diversion trench (3) is provided with a plurality of groups in the side wall scraper (25).
5. The surface treatment agent for highly corrosion-resistant workpieces according to claim 4, wherein: the middle part of the rotating rod (21) is fixedly connected with a water storage tank (4); a first water guide pipe (41) is communicated between the water storage tank (4) and the rod cavity of the straight cylinder piston cylinder (23); a one-way valve is arranged on the first water guide pipe (41); a second water guide pipe (42) is communicated between the rod cavity of the straight cylinder piston cylinder (23) and the side wall scraper (25); the middle part of the second water guide pipe (42) is provided with a one-way valve; the second water guide pipe (42) extends to the side wall of the diversion trench (3) on the side wall scraper (25); and the side wall of the flow guide groove (3) is fixedly connected with a guide film (5).
6. The surface treatment agent for highly corrosion-resistant workpieces according to claim 5, wherein: the bottom end of the rotating rod (21) is connected with a sleeve (6) in a sliding manner; a limiting rod is fixedly connected to the side wall of the rotating rod (21); a stirring impeller (61) is fixedly connected to the side wall of the sleeve (6); the bottom of the sleeve (6) is fixedly connected with a sweeping board (62).
7. The surface treatment agent for highly corrosion-resistant workpieces according to claim 6, wherein: a friction elastic bag (63) is fixedly connected to the bottom of the cleaning plate (62); a U-shaped piston cylinder (64) is arranged in the cleaning plate (62) at a position corresponding to the friction elastic bag (63); an ejector rod (65) is connected to the port corresponding to the friction elastic bag (63) in the U-shaped piston cylinder (64) in a sliding manner; the other port of the U-shaped piston cylinder (64) is connected with a soft wiping rod (66) in a sliding way; a soft air bag (67) is arranged in the U-shaped piston cylinder (64).
8. The surface treatment agent for highly corrosion-resistant workpieces according to claim 7, wherein: the end part of the soft wiping rod (66) is fixedly connected with a rubber head (68); a plurality of groups of slag guide grooves (69) are formed in the rubber head (68).
9. The surface treatment agent for highly corrosion-resistant workpieces according to claim 8, wherein: a plurality of groups of guide grooves (7) are formed in the cleaning plate (62); a conical block (71) is fixedly connected to the inner side wall of the top of the guide groove (7); the cleaning plate (62) is internally provided with a guide hole (72) which is communicated with the guide groove (7).
10. A preparation method of a high corrosion-resistant workpiece surface treating agent is characterized by comprising the following steps: the preparation method is suitable for the high corrosion-resistant workpiece surface treating agent as defined in any one of claims 1 to 9, and comprises the following steps:
s1: firstly, adding potassium pyrophosphate, zinc sulfate and cerium sulfate into a container, preheating, adding stannous sulfate into the container when the temperature reaches 50 ℃, simultaneously stirring the mixture, and increasing the temperature to 60 ℃ to obtain a first solution;
s2: cooling the solution I in the S1 to 45 ℃, adding a nano titanium dioxide solution, charcoal ash solution and a potassium permanganate solution into the solution I, and then continuously stirring to obtain a solution II;
s3: and adding the solution II into a stirring device, adjusting the rotating speed of the stirring device to be 500-1000 r/min, standing the solution, and adding the solution into a storage tank to further finish the preparation of the high-corrosion-resistance workpiece surface treating agent.
CN202110363997.7A 2021-04-03 2021-04-03 High-corrosion-resistance workpiece surface treating agent and preparation method thereof Pending CN113088949A (en)

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