CN105860744A - High-salt spray resistance one-component quick-drying grey epoxy primer and preparation method thereof - Google Patents

High-salt spray resistance one-component quick-drying grey epoxy primer and preparation method thereof Download PDF

Info

Publication number
CN105860744A
CN105860744A CN201610223033.1A CN201610223033A CN105860744A CN 105860744 A CN105860744 A CN 105860744A CN 201610223033 A CN201610223033 A CN 201610223033A CN 105860744 A CN105860744 A CN 105860744A
Authority
CN
China
Prior art keywords
epoxy
parts
acetylbutyrylcellulose
salt spray
ash
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610223033.1A
Other languages
Chinese (zh)
Other versions
CN105860744B (en
Inventor
刘立新
赵春波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Jinhai Technology Co Ltd
Original Assignee
Hunan Jinhai Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan Jinhai Technology Co Ltd filed Critical Hunan Jinhai Technology Co Ltd
Priority to CN201610223033.1A priority Critical patent/CN105860744B/en
Publication of CN105860744A publication Critical patent/CN105860744A/en
Application granted granted Critical
Publication of CN105860744B publication Critical patent/CN105860744B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a one-component modified grey epoxy primer and a preparation method thereof, especially relates to a high-salt spray resistance quick-drying grey epoxy primer and a preparation method thereof, and belongs to the technical field of preparation technologies of chemical engineering coatings. The one-component quick-drying grey epoxy primer comprises, by weight, 35-45 parts of epoxy resin, 5-15 parts of amino resin, 20-30 parts of an epoxy system grey slurry, 1-5 parts of a cellulose acetate butyrate a dispersion, 3-10 parts of a cellulose acetate butyrate b dispersion, 0.1-1 part of an adhesion promoter, 5-15 parts of xylene and 4-10 parts of butanone. The grey epoxy primer prepared in the invention has good adhesion, high salt spray corrosion resistance and high acid and alkali resistance, and can be massively used in coating anticorrosion processes of metal products without matching with a curing agent; and the primer also has a characteristic of normal temperature quick drying, so the wet-on-wet assembling speed of the primer and a floating coat is accelerated, and the construction period is shortened.

Description

A kind of one-component quick setting epoxy ash priming paint of high salt spray resistance and preparation method thereof
Technical field
The present invention relates to a kind of one-component modified epoxy ash priming paint and preparation method thereof, especially relate to a kind of high salt spray resistance Quick setting epoxy ash priming paint and preparation method, belong to chemistry painting industry fabricating technology field.
Background technology
Along with the application of paint is increasingly wider, use environment more and more harsher, to the performance requirement painted increasingly High.Priming paint is direct spraying coating on metal base, and its Main Function is anticorrosive metal and fills and leads up the thin of metal base Microdefect and rust staining etc..Epoxy resin is good due to itself Corrosion Protection, so being largely used to the anticorrosion of metal primer Painting is loaded onto, and can optimize the adhesive force of finish paint, richness, anti-corrosion function etc., makes paint system play optimum efficiency.
The patent of invention of application number 201510129565.4 discloses the preparation of a kind of two component fast dry type epoxy coating and does Method, coating resin part consists of epoxy resin 50-60 part, multi-arm mercaptan 30-40 part, nano silicon 1-3 part, solidification Agent part contains the solidification of 1-2 part polyamine urges into agent, and after the paint spraying of preparation, low-temp reaction is fast, intensity is high, good toughness, especially It is applicable to heavy antisepsis field, but dual-component coating technique is longer for hardening time more complicated, required, is not appropriate for not possessing baking Condition and the cycle urgent condition of production.
The patent of invention of application number 201510581618.6, discloses a kind of corrosion-resistant heat-resistant paint, including following components Epoxy resin, acrylic resin, multiple filler, diethylene glycol dibenzoate, polyvinyl alcohol, silane coupler, defoamer, film forming Helping and solvent, prepared corrosion-resistant heat-resistant paint has good adhesion performance, has acid and alkali-resistance, salt fog resistance simultaneously Can, but the actually prepared paint salt spray resistance result of only 96 hours is really the most undesirable, and this is likely due to formula In filler, heat-resistant filler component is far more than anticorrosive packing, and heat resistance lays particular stress on caused.
The patent of invention of application number 201510264194.0, discloses a kind of one-component height antiseptical epoxy coating combination Thing, with bisphenol A modified epoxy resin as matrix resin, adds zinc sulfate anticorrosive packing, titanium white powder pigment and auxiliary agent, preparation Obtain epoxy coating composition, can in 15-20 minute surface drying, and salt spray resistance 240-480 hour on multiple metal material, But while performance relatively comparative example increases, but such salt spray resistance result can not fully meet market to corrosion resistant coating Increasingly strict requirements.
Summary of the invention
The invention provides one-component quick setting epoxy ash priming paint and preparation method, the epoxy of preparation of a kind of high salt spray resistance Ash priming paint, without coordinating firming agent, has good adhesive force, high salt fog resistance, resistance to acids and bases, and this coating and also has The characteristic of normal temperature quick-drying, can make the wet on wet assembling speed quickening of priming paint and middle painting, shorten construction period, can be widely applied In the painting anticorrosion operation of metallic article.
For achieving the above object, the one-component quick setting epoxy ash priming paint of a kind of high salt spray resistance that the present invention provides is by following Raw material forms by weight: epoxy resin 35-45 part, amino resins 5-15 part, epoxy systems ash mill base 20-30 part, vinegar Acid cellulose butyrate a dispersion liquid 1-5 part, acetylbutyrylcellulose b dispersion liquid 3-10 part, adhesion promoter 0.1-1 part, diformazan Benzene 5-15 part, butanone 4-10 part.
Wherein, described epoxy systems ash mill base is made up of by weight following raw material: acrylic resin 45-55 part, Wetting dispersing agent a 0.2-0.5 part, wetting dispersing agent b 2-4 part, carbon black 2-6 part, titanium dioxide 22-28 part, propylene glycol monomethyl ether vinegar Acid esters 7-10 part, dimethylbenzene 7-10 part, aluminium triphosphate 1.5-2.5 part, fumed silica 0.1-0.3 part.
Described acetylbutyrylcellulose a dispersion liquid is made up of by weight following raw material: acetylbutyrylcellulose a 15%, butyl ester 85%;Acetylbutyrylcellulose b dispersion liquid is made up of by weight following raw material: acetylbutyrylcellulose b 25%, butyl ester 75%;
Described epoxy resin is the quick-dry type modified epoxy of high reaction activity, has the characteristic of normal temperature quick-drying.
Described amino resins uses with modified epoxy collocation, and basic proportioning is 1:3-1:5.
Described acetylbutyrylcellulose a has the high full-bodied characteristic of bytyry content, and acetylbutyrylcellulose b has There is the high low viscous characteristic of bytyry content.
Described adhesion promoter is with a kind of specialty polyesters resin for strengthening the composition of attachment.
Described wetting dispersing agent a is the wetting dispersing agent that special acid mixes with silicone, can prevent pink colour, grow dim, deposits The phenomenons such as caking, wetting dispersing agent b is a kind of urethanes, can shorten pigment jitter time and prevent pigment flocculation Occur.
Described carbon black is high blackness gas method carbon black, and particle diameter is 17nm;Titanium dioxide is rutile-type, has the weather-proof of excellence Property and chalking resistance;Aluminium triphosphate fineness is 1250 mesh, improves the corrosion-resistant salt fog performance of solvent type epoxy anticorrosive paint Effect is obvious;Fumed silica, a size of 10-20nm, act primarily as the effect of thickening, thixotroping and anti-settling.
Detailed description of the invention
Embodiment 1:
In clean standard compliant container, it is sequentially added into acrylic resin 46 parts, wetting dispersing agent a 0.3 part, profit in proportion Hygroscopic water powder b 2 parts and propylene glycol methyl ether acetate 7 parts and dimethylbenzene 9 parts, start dispersion machine, at rotating speed 500-800r/min The lower dispersed 5min of moderate-speed mixer, is subsequently adding carbon black 6 parts, titanium dioxide 27 parts, aluminium triphosphate 2.4 parts, vapor phase method dioxy SiClx 0.3 part, under rotating speed 700-800r/min, moderate-speed mixer dispersion 0.5-1.5h, i.e. obtains epoxy systems stock white, standby With;In another clean standard compliant container, it is sequentially added into epoxy resin 35 parts, 8 parts of amino resins, acetic acid fourth in proportion Acid cellulose a dispersion liquid 3 parts, acetylbutyrylcellulose b dispersion liquid 6 parts, dimethylbenzene 9.5 parts, butanone 6 parts, start dispersion machine, The dispersed 5min of moderate-speed mixer under rotating speed 500-800r/min, is subsequently adding epoxy systems ash mill base 27.1 parts and adhesive force Accelerator 0.9 part, moderate-speed mixer dispersion 0.5-1.5h under rotating speed 700-800r/min, the preparation of epoxy ash priming paint completes.
In use, being mixed homogeneously by weight 1:0.9 with diluent by paint, diluent is pressed weight by following raw material Amount part is than composition: toluene 40 parts, propylene glycol methyl ether acetate 25 parts, butanone 10 parts, butyl ester 25 parts.Spray is used after Paint dilution Painting, brushing, any one mode of showering are constructed.
Embodiment 2:
In clean standard compliant container, it is sequentially added into acrylic resin 49 parts, wetting dispersing agent a 0.4 part, profit in proportion Hygroscopic water powder b 3 parts and propylene glycol methyl ether acetate 8.5 parts and dimethylbenzene 8 parts, start dispersion machine, at rotating speed 500-800r/min The lower dispersed 5min of moderate-speed mixer, is subsequently adding carbon black 5 parts, titanium dioxide 24 parts, aluminium triphosphate 1.9 parts, vapor phase method dioxy SiClx 0.2 part, under rotating speed 700-800r/min, moderate-speed mixer dispersion 0.5-1.5h, i.e. obtains epoxy systems stock white, standby With;In another clean standard compliant container, it is sequentially added into epoxy resin 40 parts, 10 parts of amino resins, acetic acid in proportion Cellulose butyrate a dispersion liquid 3 parts, acetylbutyrylcellulose b dispersion liquid 6 parts, dimethylbenzene 9.5 parts, butanone 6 parts, start dispersion machine, At the rotating speed dispersed 5min of 500-800r/min moderate-speed mixer, it is subsequently adding epoxy systems ash mill base 25 parts and attachment is made every effort to promote Entering agent 0.5 part, moderate-speed mixer dispersion 0.5-1.5h under rotating speed 700-800r/min, the preparation of epoxy ash priming paint completes.
In use, being mixed homogeneously by weight 1:0.9 with diluent by paint, diluent is pressed weight by following raw material Amount part is than composition: toluene 40 parts, propylene glycol methyl ether acetate 25 parts, butanone 10 parts, butyl ester 25 parts.Spray is used after Paint dilution Painting, brushing, any one mode of showering are constructed.
Embodiment 3:
In clean standard compliant container, it is sequentially added into acrylic resin 53 parts, wetting dispersing agent a 0.5 part, profit in proportion Hygroscopic water powder b 3.9 parts and propylene glycol methyl ether acetate 9 parts and dimethylbenzene 7 parts, start dispersion machine, at rotating speed 500-800r/min The lower dispersed 5min of moderate-speed mixer, is subsequently adding carbon black 3 parts, titanium dioxide 22 parts, aluminium triphosphate 1.5 parts, vapor phase method dioxy SiClx 0.1 part, under rotating speed 700-800r/min, moderate-speed mixer dispersion 0.5-1.5h, i.e. obtains epoxy systems stock white, standby With;In another clean standard compliant container, it is sequentially added into epoxy resin 45 parts, 12 parts of amino resins, acetic acid in proportion Cellulose butyrate a dispersion liquid 2 parts, acetylbutyrylcellulose b dispersion liquid 5 parts, dimethylbenzene 8 parts, butanone 7.7 parts, start dispersion machine, At the rotating speed dispersed 5min of 500-800r/min moderate-speed mixer, it is subsequently adding epoxy systems ash mill base 20 parts and attachment is made every effort to promote Entering agent 0.3 part, moderate-speed mixer dispersion 0.5-1.5h under rotating speed 700-800r/min, the preparation of epoxy ash priming paint completes.
In use, being mixed homogeneously by weight 1:0.9 with diluent by paint, diluent is pressed weight by following raw material Amount part is than composition: toluene 40 parts, propylene glycol methyl ether acetate 25 parts, butanone 10 parts, butyl ester 25 parts.Spray is used after Paint dilution Painting, brushing, any one mode of showering are constructed.
The one-component quick setting epoxy ash priming paint prepared according to above-described embodiment, all has good adhesive force, high salt spray resistance Corrosivity, resistance to acids and bases, normal temperature quick-drying performance, performance is coated with application number 201510264194.0 one-component high anticorrosion rapid-curing cutback epoxy Feed composition contrasts, and specific performance data are as follows:
Embodiment 1-3 and comparative example performance comparison test result comparative example:
Wherein, drying time tests according to GB/T1728-1979 (1989), and adhesive force is tested according to GB/T5210-2006, resistance to Soda acid performance is tested according to GB/T9274-1988, and resistance to neutral salt spray does not carry out drawing lattice and processes according to GB/T10125-2012() survey Examination, the salt spray resistance of comparative example has carried out stroke lattice according to GB/T1771(and has processed) test.
Embodiment of the present invention is only the description carrying out the preferred embodiment of the present invention, not to the present invention Spirit and scope are defined, and on the premise of without departing from design philosophy of the present invention, in this area, engineers and technicians are to this Various modification that bright technical scheme is made and improvement, all should fall into protection scope of the present invention, the skill that the present invention is claimed Art content, all records in detail in the claims.

Claims (6)

1. the one-component quick setting epoxy ash priming paint of a high salt spray resistance, it is characterised in that it is by following raw material by weight Than composition:
Epoxy resin 35-45 part
Amino resins 5-15 part
Epoxy systems ash mill base 20-30 part
Acetylbutyrylcellulose a dispersion liquid 1-5 part
Acetylbutyrylcellulose b dispersion liquid 3-10 part
Adhesion promoter 0.1-1 part
Dimethylbenzene 5-15 part
Butanone 4-10 part.
The one-component quick setting epoxy ash priming paint of a kind of high salt spray resistance the most according to claim 1, it is characterised in that epoxy body System's ash mill base is made up of by weight following raw material:
Acrylic resin 45-55 part
Wetting dispersing agent a 0.2-0.5 part
Wetting dispersing agent b 2-4 part
Carbon black 2-6 part
Titanium dioxide 22-28 part
Propylene glycol methyl ether acetate 7-10 part
Dimethylbenzene 7-10 part
Aluminium triphosphate 1.5-2.5 part
Fumed silica 0.1-0.3 part.
The one-component quick setting epoxy ash priming paint of a kind of high salt spray resistance the most according to claim 1, it is characterised in that:
(1) acetylbutyrylcellulose a dispersion liquid is made up of by weight following raw material: acetylbutyrylcellulose a 15%, fourth Ester 85%;Acetylbutyrylcellulose b dispersion liquid is made up of following weight part ratio: acetylbutyrylcellulose b 25%, butyl ester 75%;
(2) epoxy resin is the quick-dry type modified epoxy of high reaction activity, has the characteristic of normal temperature quick-drying;
(3) amino resins uses with modified epoxy collocation, and basic proportioning is 1:3-1:5;
(4) acetylbutyrylcellulose a has the high full-bodied characteristic of bytyry content, and acetylbutyrylcellulose b has Gao Ding The low viscous characteristic of acyl group content;
(5) adhesion promoter is with a kind of specialty polyesters resin for strengthening the composition of attachment.
Epoxy systems ash mill base the most according to claim 2, it is characterised in that wetting dispersing agent a is special acid and silicone The wetting dispersing agent of mixing, can prevent pink colour, grow dim, deposit the phenomenons such as caking, and wetting dispersing agent b is one polyurethane chemical combination Thing, can shorten pigment jitter time and the generation of anti-pigment flocculation.
Epoxy systems ash mill base the most according to claim 2, it is characterised in that carbon black is high blackness gas method carbon black, particle diameter For 17nm;Titanium dioxide is rutile-type, has weatherability and the chalking resistance of excellence;Aluminium triphosphate fineness is 1250 mesh, right The corrosion-resistant salt fog performance enhancing effects of solvent type epoxy anticorrosive paint is obvious;Fumed silica, a size of 10-20nm, Act primarily as the effect of thickening, thixotroping and anti-settling.
6., according to the one-component quick setting epoxy ash priming paint of a kind of high salt spray resistance described in claim 1-5, its preparation method is as follows: In clean standard compliant container, it is sequentially added into acrylic resin, wetting dispersing agent a, wetting dispersing agent b and the third two in proportion Alcohol methyl ether acetate and xylene solvent, start dispersion machine, and under rotating speed 500-800r/min, moderate-speed mixer is dispersed 5min, is subsequently adding carbon black, titanium dioxide, aluminium triphosphate, fumed silica, middling speed under rotating speed 700-800r/min Dispersed with stirring 0.5-1.5h, i.e. obtains epoxy systems stock white, standby;In another clean standard compliant container, by than Example is sequentially added into epoxy resin, amino resins, acetylbutyrylcellulose a dispersion liquid, acetylbutyrylcellulose b dispersion liquid, diformazan Benzene, butanone, start dispersion machine, and under rotating speed 500-800r/min, the dispersed 5min of moderate-speed mixer, is subsequently adding epoxy systems Ash mill base and adhesion promoter, moderate-speed mixer dispersion 0.5-1.5h under rotating speed 700-800r/min, preparation completes.
CN201610223033.1A 2016-04-12 2016-04-12 A kind of one-component quick setting epoxy ash priming paint of high salt spray resistance and preparation method thereof Active CN105860744B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610223033.1A CN105860744B (en) 2016-04-12 2016-04-12 A kind of one-component quick setting epoxy ash priming paint of high salt spray resistance and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610223033.1A CN105860744B (en) 2016-04-12 2016-04-12 A kind of one-component quick setting epoxy ash priming paint of high salt spray resistance and preparation method thereof

Publications (2)

Publication Number Publication Date
CN105860744A true CN105860744A (en) 2016-08-17
CN105860744B CN105860744B (en) 2018-04-03

Family

ID=56637478

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610223033.1A Active CN105860744B (en) 2016-04-12 2016-04-12 A kind of one-component quick setting epoxy ash priming paint of high salt spray resistance and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105860744B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106978018A (en) * 2017-04-12 2017-07-25 湖南中智优库科技有限公司 A kind of epoxy resin metal heavy anticorrosion paint and preparation method thereof
CN113088949A (en) * 2021-04-03 2021-07-09 季茂远 High-corrosion-resistance workpiece surface treating agent and preparation method thereof
CN115820070A (en) * 2021-12-29 2023-03-21 郑州格莱菲高铁新材料科技有限公司 Persistent corrosion-resistant zinc-olefin primer composition and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1583912A (en) * 2004-05-27 2005-02-23 解居会 Coiled material priming paint coating and preparing method thereof
CN101735714A (en) * 2009-11-27 2010-06-16 深圳市威凯士化工涂料有限公司 Environmentally-friendly low-temperature curing metallic gold coating, manufacturing process and application of coating serving as iron printed tank coating in directly coating roll
CN103980800A (en) * 2014-06-05 2014-08-13 唐山尼克涂料有限公司 Baking varnish as well as preparation method and application method thereof
CN104059511A (en) * 2013-03-18 2014-09-24 福建省腾龙工业公司 Quick-drying primer-topcoat two-in-one steel member paint and preparation method thereof
CN104293047A (en) * 2014-10-31 2015-01-21 成都锦汇科技有限公司 Acrylic acid amino stoving varnish

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1583912A (en) * 2004-05-27 2005-02-23 解居会 Coiled material priming paint coating and preparing method thereof
CN101735714A (en) * 2009-11-27 2010-06-16 深圳市威凯士化工涂料有限公司 Environmentally-friendly low-temperature curing metallic gold coating, manufacturing process and application of coating serving as iron printed tank coating in directly coating roll
CN104059511A (en) * 2013-03-18 2014-09-24 福建省腾龙工业公司 Quick-drying primer-topcoat two-in-one steel member paint and preparation method thereof
CN103980800A (en) * 2014-06-05 2014-08-13 唐山尼克涂料有限公司 Baking varnish as well as preparation method and application method thereof
CN104293047A (en) * 2014-10-31 2015-01-21 成都锦汇科技有限公司 Acrylic acid amino stoving varnish

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106978018A (en) * 2017-04-12 2017-07-25 湖南中智优库科技有限公司 A kind of epoxy resin metal heavy anticorrosion paint and preparation method thereof
CN113088949A (en) * 2021-04-03 2021-07-09 季茂远 High-corrosion-resistance workpiece surface treating agent and preparation method thereof
CN115820070A (en) * 2021-12-29 2023-03-21 郑州格莱菲高铁新材料科技有限公司 Persistent corrosion-resistant zinc-olefin primer composition and preparation method thereof
CN115820070B (en) * 2021-12-29 2024-03-12 郑州格莱菲高铁新材料科技有限公司 Persistent corrosion-resistant zincate primer composition and preparation method thereof

Also Published As

Publication number Publication date
CN105860744B (en) 2018-04-03

Similar Documents

Publication Publication Date Title
CN101104764B (en) Double-anticorrosion paint for steel and preparing method thereof
CN105038424B (en) Water-based heavy-duty single-component on-rust primer, and preparation method and application thereof
CN105885644B (en) A kind of antirusting paint and preparation method thereof
CN105885690A (en) Water-borne acrylic resin anticorrosive coating and preparation method thereof
CN103788787A (en) Single-component water-based natural drying finishing coat for construction crane and preparation method thereof
CN106118295A (en) A kind of aqueous bottom surface unification Corrosion resisting paint without need of cleaning rust and preparation method thereof
CN106366851A (en) Epoxy ester dip-coating water based paint and preparation method thereof
CN101250372A (en) Metal inner surface anticorrosion paint and preparation method thereof
CN102558999B (en) Water-based environment-friendly electrostatic spraying baking paint and preparation method thereof
CN103666201A (en) Long-acting acid-base resistant solvent-free anticorrosive paint as well as preparation method and application thereof
CN106366870A (en) Compound waterborne metallic baking paint and coating method thereof
CN105860744B (en) A kind of one-component quick setting epoxy ash priming paint of high salt spray resistance and preparation method thereof
CN108003748A (en) A kind of engineering machinery epoxy primer and preparation method thereof
CN105109732A (en) Monocomponent workshop basecoat loading technology
CN103468092A (en) Water-based coating for surface of mechanical product
CN105111860A (en) Water-based double-component corrosion-resistant industrial paint and production method thereof
CN112745741A (en) Bottom-coating anti-corrosion powder coating for coating base material, base material capable of avoiding chemical pretreatment and coating system
CN101629045A (en) High solid metal inner cavity anticorrosive paint and production method thereof
CN104250512A (en) Water-based alcohol acid primer-topcoat antirust paint and preparation method thereof
CN104312425B (en) A kind of polyphenylene sulfide coil coating
CN104109428A (en) 3C1B-enabled wet-on-wet white primer surfacer and preparation method thereof
CN106433416A (en) High temperature-resistant primer, and preparation method and application thereof
CN105949959A (en) General-purpose high-adhesion quick-drying primer and preparation method thereof
CN103980799B (en) There is rusty scale convert and the epoxy selfreparing on rust paint of Stabilization
CN108912960A (en) A kind of selfreparing anticorrosive paint

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant