CN105860744A - High-salt spray resistance one-component quick-drying grey epoxy primer and preparation method thereof - Google Patents
High-salt spray resistance one-component quick-drying grey epoxy primer and preparation method thereof Download PDFInfo
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- CN105860744A CN105860744A CN201610223033.1A CN201610223033A CN105860744A CN 105860744 A CN105860744 A CN 105860744A CN 201610223033 A CN201610223033 A CN 201610223033A CN 105860744 A CN105860744 A CN 105860744A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention relates to a one-component modified grey epoxy primer and a preparation method thereof, especially relates to a high-salt spray resistance quick-drying grey epoxy primer and a preparation method thereof, and belongs to the technical field of preparation technologies of chemical engineering coatings. The one-component quick-drying grey epoxy primer comprises, by weight, 35-45 parts of epoxy resin, 5-15 parts of amino resin, 20-30 parts of an epoxy system grey slurry, 1-5 parts of a cellulose acetate butyrate a dispersion, 3-10 parts of a cellulose acetate butyrate b dispersion, 0.1-1 part of an adhesion promoter, 5-15 parts of xylene and 4-10 parts of butanone. The grey epoxy primer prepared in the invention has good adhesion, high salt spray corrosion resistance and high acid and alkali resistance, and can be massively used in coating anticorrosion processes of metal products without matching with a curing agent; and the primer also has a characteristic of normal temperature quick drying, so the wet-on-wet assembling speed of the primer and a floating coat is accelerated, and the construction period is shortened.
Description
Technical field
The present invention relates to a kind of one-component modified epoxy ash priming paint and preparation method thereof, especially relate to a kind of high salt spray resistance
Quick setting epoxy ash priming paint and preparation method, belong to chemistry painting industry fabricating technology field.
Background technology
Along with the application of paint is increasingly wider, use environment more and more harsher, to the performance requirement painted increasingly
High.Priming paint is direct spraying coating on metal base, and its Main Function is anticorrosive metal and fills and leads up the thin of metal base
Microdefect and rust staining etc..Epoxy resin is good due to itself Corrosion Protection, so being largely used to the anticorrosion of metal primer
Painting is loaded onto, and can optimize the adhesive force of finish paint, richness, anti-corrosion function etc., makes paint system play optimum efficiency.
The patent of invention of application number 201510129565.4 discloses the preparation of a kind of two component fast dry type epoxy coating and does
Method, coating resin part consists of epoxy resin 50-60 part, multi-arm mercaptan 30-40 part, nano silicon 1-3 part, solidification
Agent part contains the solidification of 1-2 part polyamine urges into agent, and after the paint spraying of preparation, low-temp reaction is fast, intensity is high, good toughness, especially
It is applicable to heavy antisepsis field, but dual-component coating technique is longer for hardening time more complicated, required, is not appropriate for not possessing baking
Condition and the cycle urgent condition of production.
The patent of invention of application number 201510581618.6, discloses a kind of corrosion-resistant heat-resistant paint, including following components
Epoxy resin, acrylic resin, multiple filler, diethylene glycol dibenzoate, polyvinyl alcohol, silane coupler, defoamer, film forming
Helping and solvent, prepared corrosion-resistant heat-resistant paint has good adhesion performance, has acid and alkali-resistance, salt fog resistance simultaneously
Can, but the actually prepared paint salt spray resistance result of only 96 hours is really the most undesirable, and this is likely due to formula
In filler, heat-resistant filler component is far more than anticorrosive packing, and heat resistance lays particular stress on caused.
The patent of invention of application number 201510264194.0, discloses a kind of one-component height antiseptical epoxy coating combination
Thing, with bisphenol A modified epoxy resin as matrix resin, adds zinc sulfate anticorrosive packing, titanium white powder pigment and auxiliary agent, preparation
Obtain epoxy coating composition, can in 15-20 minute surface drying, and salt spray resistance 240-480 hour on multiple metal material,
But while performance relatively comparative example increases, but such salt spray resistance result can not fully meet market to corrosion resistant coating
Increasingly strict requirements.
Summary of the invention
The invention provides one-component quick setting epoxy ash priming paint and preparation method, the epoxy of preparation of a kind of high salt spray resistance
Ash priming paint, without coordinating firming agent, has good adhesive force, high salt fog resistance, resistance to acids and bases, and this coating and also has
The characteristic of normal temperature quick-drying, can make the wet on wet assembling speed quickening of priming paint and middle painting, shorten construction period, can be widely applied
In the painting anticorrosion operation of metallic article.
For achieving the above object, the one-component quick setting epoxy ash priming paint of a kind of high salt spray resistance that the present invention provides is by following
Raw material forms by weight: epoxy resin 35-45 part, amino resins 5-15 part, epoxy systems ash mill base 20-30 part, vinegar
Acid cellulose butyrate a dispersion liquid 1-5 part, acetylbutyrylcellulose b dispersion liquid 3-10 part, adhesion promoter 0.1-1 part, diformazan
Benzene 5-15 part, butanone 4-10 part.
Wherein, described epoxy systems ash mill base is made up of by weight following raw material: acrylic resin 45-55 part,
Wetting dispersing agent a 0.2-0.5 part, wetting dispersing agent b 2-4 part, carbon black 2-6 part, titanium dioxide 22-28 part, propylene glycol monomethyl ether vinegar
Acid esters 7-10 part, dimethylbenzene 7-10 part, aluminium triphosphate 1.5-2.5 part, fumed silica 0.1-0.3 part.
Described acetylbutyrylcellulose a dispersion liquid is made up of by weight following raw material: acetylbutyrylcellulose a
15%, butyl ester 85%;Acetylbutyrylcellulose b dispersion liquid is made up of by weight following raw material: acetylbutyrylcellulose b
25%, butyl ester 75%;
Described epoxy resin is the quick-dry type modified epoxy of high reaction activity, has the characteristic of normal temperature quick-drying.
Described amino resins uses with modified epoxy collocation, and basic proportioning is 1:3-1:5.
Described acetylbutyrylcellulose a has the high full-bodied characteristic of bytyry content, and acetylbutyrylcellulose b has
There is the high low viscous characteristic of bytyry content.
Described adhesion promoter is with a kind of specialty polyesters resin for strengthening the composition of attachment.
Described wetting dispersing agent a is the wetting dispersing agent that special acid mixes with silicone, can prevent pink colour, grow dim, deposits
The phenomenons such as caking, wetting dispersing agent b is a kind of urethanes, can shorten pigment jitter time and prevent pigment flocculation
Occur.
Described carbon black is high blackness gas method carbon black, and particle diameter is 17nm;Titanium dioxide is rutile-type, has the weather-proof of excellence
Property and chalking resistance;Aluminium triphosphate fineness is 1250 mesh, improves the corrosion-resistant salt fog performance of solvent type epoxy anticorrosive paint
Effect is obvious;Fumed silica, a size of 10-20nm, act primarily as the effect of thickening, thixotroping and anti-settling.
Detailed description of the invention
Embodiment 1:
In clean standard compliant container, it is sequentially added into acrylic resin 46 parts, wetting dispersing agent a 0.3 part, profit in proportion
Hygroscopic water powder b 2 parts and propylene glycol methyl ether acetate 7 parts and dimethylbenzene 9 parts, start dispersion machine, at rotating speed 500-800r/min
The lower dispersed 5min of moderate-speed mixer, is subsequently adding carbon black 6 parts, titanium dioxide 27 parts, aluminium triphosphate 2.4 parts, vapor phase method dioxy
SiClx 0.3 part, under rotating speed 700-800r/min, moderate-speed mixer dispersion 0.5-1.5h, i.e. obtains epoxy systems stock white, standby
With;In another clean standard compliant container, it is sequentially added into epoxy resin 35 parts, 8 parts of amino resins, acetic acid fourth in proportion
Acid cellulose a dispersion liquid 3 parts, acetylbutyrylcellulose b dispersion liquid 6 parts, dimethylbenzene 9.5 parts, butanone 6 parts, start dispersion machine,
The dispersed 5min of moderate-speed mixer under rotating speed 500-800r/min, is subsequently adding epoxy systems ash mill base 27.1 parts and adhesive force
Accelerator 0.9 part, moderate-speed mixer dispersion 0.5-1.5h under rotating speed 700-800r/min, the preparation of epoxy ash priming paint completes.
In use, being mixed homogeneously by weight 1:0.9 with diluent by paint, diluent is pressed weight by following raw material
Amount part is than composition: toluene 40 parts, propylene glycol methyl ether acetate 25 parts, butanone 10 parts, butyl ester 25 parts.Spray is used after Paint dilution
Painting, brushing, any one mode of showering are constructed.
Embodiment 2:
In clean standard compliant container, it is sequentially added into acrylic resin 49 parts, wetting dispersing agent a 0.4 part, profit in proportion
Hygroscopic water powder b 3 parts and propylene glycol methyl ether acetate 8.5 parts and dimethylbenzene 8 parts, start dispersion machine, at rotating speed 500-800r/min
The lower dispersed 5min of moderate-speed mixer, is subsequently adding carbon black 5 parts, titanium dioxide 24 parts, aluminium triphosphate 1.9 parts, vapor phase method dioxy
SiClx 0.2 part, under rotating speed 700-800r/min, moderate-speed mixer dispersion 0.5-1.5h, i.e. obtains epoxy systems stock white, standby
With;In another clean standard compliant container, it is sequentially added into epoxy resin 40 parts, 10 parts of amino resins, acetic acid in proportion
Cellulose butyrate a dispersion liquid 3 parts, acetylbutyrylcellulose b dispersion liquid 6 parts, dimethylbenzene 9.5 parts, butanone 6 parts, start dispersion machine,
At the rotating speed dispersed 5min of 500-800r/min moderate-speed mixer, it is subsequently adding epoxy systems ash mill base 25 parts and attachment is made every effort to promote
Entering agent 0.5 part, moderate-speed mixer dispersion 0.5-1.5h under rotating speed 700-800r/min, the preparation of epoxy ash priming paint completes.
In use, being mixed homogeneously by weight 1:0.9 with diluent by paint, diluent is pressed weight by following raw material
Amount part is than composition: toluene 40 parts, propylene glycol methyl ether acetate 25 parts, butanone 10 parts, butyl ester 25 parts.Spray is used after Paint dilution
Painting, brushing, any one mode of showering are constructed.
Embodiment 3:
In clean standard compliant container, it is sequentially added into acrylic resin 53 parts, wetting dispersing agent a 0.5 part, profit in proportion
Hygroscopic water powder b 3.9 parts and propylene glycol methyl ether acetate 9 parts and dimethylbenzene 7 parts, start dispersion machine, at rotating speed 500-800r/min
The lower dispersed 5min of moderate-speed mixer, is subsequently adding carbon black 3 parts, titanium dioxide 22 parts, aluminium triphosphate 1.5 parts, vapor phase method dioxy
SiClx 0.1 part, under rotating speed 700-800r/min, moderate-speed mixer dispersion 0.5-1.5h, i.e. obtains epoxy systems stock white, standby
With;In another clean standard compliant container, it is sequentially added into epoxy resin 45 parts, 12 parts of amino resins, acetic acid in proportion
Cellulose butyrate a dispersion liquid 2 parts, acetylbutyrylcellulose b dispersion liquid 5 parts, dimethylbenzene 8 parts, butanone 7.7 parts, start dispersion machine,
At the rotating speed dispersed 5min of 500-800r/min moderate-speed mixer, it is subsequently adding epoxy systems ash mill base 20 parts and attachment is made every effort to promote
Entering agent 0.3 part, moderate-speed mixer dispersion 0.5-1.5h under rotating speed 700-800r/min, the preparation of epoxy ash priming paint completes.
In use, being mixed homogeneously by weight 1:0.9 with diluent by paint, diluent is pressed weight by following raw material
Amount part is than composition: toluene 40 parts, propylene glycol methyl ether acetate 25 parts, butanone 10 parts, butyl ester 25 parts.Spray is used after Paint dilution
Painting, brushing, any one mode of showering are constructed.
The one-component quick setting epoxy ash priming paint prepared according to above-described embodiment, all has good adhesive force, high salt spray resistance
Corrosivity, resistance to acids and bases, normal temperature quick-drying performance, performance is coated with application number 201510264194.0 one-component high anticorrosion rapid-curing cutback epoxy
Feed composition contrasts, and specific performance data are as follows:
Embodiment 1-3 and comparative example performance comparison test result comparative example:
Wherein, drying time tests according to GB/T1728-1979 (1989), and adhesive force is tested according to GB/T5210-2006, resistance to
Soda acid performance is tested according to GB/T9274-1988, and resistance to neutral salt spray does not carry out drawing lattice and processes according to GB/T10125-2012() survey
Examination, the salt spray resistance of comparative example has carried out stroke lattice according to GB/T1771(and has processed) test.
Embodiment of the present invention is only the description carrying out the preferred embodiment of the present invention, not to the present invention
Spirit and scope are defined, and on the premise of without departing from design philosophy of the present invention, in this area, engineers and technicians are to this
Various modification that bright technical scheme is made and improvement, all should fall into protection scope of the present invention, the skill that the present invention is claimed
Art content, all records in detail in the claims.
Claims (6)
1. the one-component quick setting epoxy ash priming paint of a high salt spray resistance, it is characterised in that it is by following raw material by weight
Than composition:
Epoxy resin 35-45 part
Amino resins 5-15 part
Epoxy systems ash mill base 20-30 part
Acetylbutyrylcellulose a dispersion liquid 1-5 part
Acetylbutyrylcellulose b dispersion liquid 3-10 part
Adhesion promoter 0.1-1 part
Dimethylbenzene 5-15 part
Butanone 4-10 part.
The one-component quick setting epoxy ash priming paint of a kind of high salt spray resistance the most according to claim 1, it is characterised in that epoxy body
System's ash mill base is made up of by weight following raw material:
Acrylic resin 45-55 part
Wetting dispersing agent a 0.2-0.5 part
Wetting dispersing agent b 2-4 part
Carbon black 2-6 part
Titanium dioxide 22-28 part
Propylene glycol methyl ether acetate 7-10 part
Dimethylbenzene 7-10 part
Aluminium triphosphate 1.5-2.5 part
Fumed silica 0.1-0.3 part.
The one-component quick setting epoxy ash priming paint of a kind of high salt spray resistance the most according to claim 1, it is characterised in that:
(1) acetylbutyrylcellulose a dispersion liquid is made up of by weight following raw material: acetylbutyrylcellulose a 15%, fourth
Ester 85%;Acetylbutyrylcellulose b dispersion liquid is made up of following weight part ratio: acetylbutyrylcellulose b 25%, butyl ester 75%;
(2) epoxy resin is the quick-dry type modified epoxy of high reaction activity, has the characteristic of normal temperature quick-drying;
(3) amino resins uses with modified epoxy collocation, and basic proportioning is 1:3-1:5;
(4) acetylbutyrylcellulose a has the high full-bodied characteristic of bytyry content, and acetylbutyrylcellulose b has Gao Ding
The low viscous characteristic of acyl group content;
(5) adhesion promoter is with a kind of specialty polyesters resin for strengthening the composition of attachment.
Epoxy systems ash mill base the most according to claim 2, it is characterised in that wetting dispersing agent a is special acid and silicone
The wetting dispersing agent of mixing, can prevent pink colour, grow dim, deposit the phenomenons such as caking, and wetting dispersing agent b is one polyurethane chemical combination
Thing, can shorten pigment jitter time and the generation of anti-pigment flocculation.
Epoxy systems ash mill base the most according to claim 2, it is characterised in that carbon black is high blackness gas method carbon black, particle diameter
For 17nm;Titanium dioxide is rutile-type, has weatherability and the chalking resistance of excellence;Aluminium triphosphate fineness is 1250 mesh, right
The corrosion-resistant salt fog performance enhancing effects of solvent type epoxy anticorrosive paint is obvious;Fumed silica, a size of 10-20nm,
Act primarily as the effect of thickening, thixotroping and anti-settling.
6., according to the one-component quick setting epoxy ash priming paint of a kind of high salt spray resistance described in claim 1-5, its preparation method is as follows:
In clean standard compliant container, it is sequentially added into acrylic resin, wetting dispersing agent a, wetting dispersing agent b and the third two in proportion
Alcohol methyl ether acetate and xylene solvent, start dispersion machine, and under rotating speed 500-800r/min, moderate-speed mixer is dispersed
5min, is subsequently adding carbon black, titanium dioxide, aluminium triphosphate, fumed silica, middling speed under rotating speed 700-800r/min
Dispersed with stirring 0.5-1.5h, i.e. obtains epoxy systems stock white, standby;In another clean standard compliant container, by than
Example is sequentially added into epoxy resin, amino resins, acetylbutyrylcellulose a dispersion liquid, acetylbutyrylcellulose b dispersion liquid, diformazan
Benzene, butanone, start dispersion machine, and under rotating speed 500-800r/min, the dispersed 5min of moderate-speed mixer, is subsequently adding epoxy systems
Ash mill base and adhesion promoter, moderate-speed mixer dispersion 0.5-1.5h under rotating speed 700-800r/min, preparation completes.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106978018A (en) * | 2017-04-12 | 2017-07-25 | 湖南中智优库科技有限公司 | A kind of epoxy resin metal heavy anticorrosion paint and preparation method thereof |
CN113088949A (en) * | 2021-04-03 | 2021-07-09 | 季茂远 | High-corrosion-resistance workpiece surface treating agent and preparation method thereof |
CN115820070A (en) * | 2021-12-29 | 2023-03-21 | 郑州格莱菲高铁新材料科技有限公司 | Persistent corrosion-resistant zinc-olefin primer composition and preparation method thereof |
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CN104293047A (en) * | 2014-10-31 | 2015-01-21 | 成都锦汇科技有限公司 | Acrylic acid amino stoving varnish |
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CN1583912A (en) * | 2004-05-27 | 2005-02-23 | 解居会 | Coiled material priming paint coating and preparing method thereof |
CN101735714A (en) * | 2009-11-27 | 2010-06-16 | 深圳市威凯士化工涂料有限公司 | Environmentally-friendly low-temperature curing metallic gold coating, manufacturing process and application of coating serving as iron printed tank coating in directly coating roll |
CN104059511A (en) * | 2013-03-18 | 2014-09-24 | 福建省腾龙工业公司 | Quick-drying primer-topcoat two-in-one steel member paint and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106978018A (en) * | 2017-04-12 | 2017-07-25 | 湖南中智优库科技有限公司 | A kind of epoxy resin metal heavy anticorrosion paint and preparation method thereof |
CN113088949A (en) * | 2021-04-03 | 2021-07-09 | 季茂远 | High-corrosion-resistance workpiece surface treating agent and preparation method thereof |
CN115820070A (en) * | 2021-12-29 | 2023-03-21 | 郑州格莱菲高铁新材料科技有限公司 | Persistent corrosion-resistant zinc-olefin primer composition and preparation method thereof |
CN115820070B (en) * | 2021-12-29 | 2024-03-12 | 郑州格莱菲高铁新材料科技有限公司 | Persistent corrosion-resistant zincate primer composition and preparation method thereof |
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