CN105949959A - General-purpose high-adhesion quick-drying primer and preparation method thereof - Google Patents

General-purpose high-adhesion quick-drying primer and preparation method thereof Download PDF

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Publication number
CN105949959A
CN105949959A CN201610456792.2A CN201610456792A CN105949959A CN 105949959 A CN105949959 A CN 105949959A CN 201610456792 A CN201610456792 A CN 201610456792A CN 105949959 A CN105949959 A CN 105949959A
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China
Prior art keywords
parts
diluent
drying
high adhesion
defoamer
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CN201610456792.2A
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Chinese (zh)
Inventor
张爱元
徐祥麟
王新华
汤杰
熊宽
吴志星
周赞
谢伦理
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CHANGSHA XIANGJIANG SHENGLI PAINT Co Ltd
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CHANGSHA XIANGJIANG SHENGLI PAINT Co Ltd
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Priority to CN201610456792.2A priority Critical patent/CN105949959A/en
Publication of CN105949959A publication Critical patent/CN105949959A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/002Priming paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a general-purpose high-adhesion quick-drying primer which comprises 31-33 parts of epoxy modified resin, 0-0.3 part of dispersing agent, 0.2-0.5 part of bentonite, 0.2-0.5 part of vapor-phase silicon dioxide, 9-11 parts of talcum powder, 7-11 parts of barium sulfate, 4-5.5 parts of wet-process sericite, 0-5 parts of composite zinc phosphate, 15-21 parts of pigment and filler, 0.1-0.3 part of part of defoaming agent, 0.05-0.2 part of leveling agent, 0-1.2 parts of adhesion promoter, 0.3-0.6 part of organic tin drying agent and 18-22 parts of diluter. The preparation method comprises the following steps: adding main materials into a reaction kettle, and stirring uniformly, wherein the diluter accounts for 2/3 of the total amount; grinding the uniformly stirred slurry until the fineness is 40 mu m or below; and adding the defoaming agent, leveling agent and organic tin drying agent, regulating the T-4-Cup viscosity of the system to 70-120s by using the rest 1/3 diluter, and discharging.

Description

A kind of universal high adhesion force quick-drying primer and preparation method thereof
Technical field
The present invention relates to chemistry painting industry and preparation method thereof, particularly relate to a kind of universal high adhesion force quick-drying primer and Preparation method.
Background technology
Priming paint is the first pass paint of brushing after mechanical material surface processes, and its Main Function is that protection material makes in processing Less by atmospheric corrosion during with.At present, engineering machinery and automobile manufacture industry use cold-rolled steel sheet to get more and more, some technique Not polishing in surface, only carries out oil removal treatment, and other metal substrates such as hot plate, galvanized sheet (pipe), aluminium alloy, rustless steel etc. there is also Not polishing the technique of an oil removing, the most even oil removal treatment is less than position.Additionally, the application condition letter of major part mechanical producer Plain, but the requirement to coating efficiency is more and more higher, in no matter winter or summer, sprayed priming paint, from dry several hours, at most every At night, with regard to topcoating, even " wet on wet " having, i.e. priming paint surface drying 10-20min, with regard to topcoating.
For above-mentioned substrate treatment situation and coating process, although conventional epoxy primer comprehensive anticorrosive better performances, but Being to meet above-mentioned technological requirement, spraying postadhesion power is poor, and easy embrittlement is the poorest with overcoatability, especially winter, Due to epoxy primer cold drying poor-performing own, in the environment below 5 DEG C, it is difficult between priming paint and firming agent two component Solidification, often occurs that paint is not done, do not had cohesive situation.
Summary of the invention
It is an object of the invention to solve the deficiencies in the prior art, it is provided that a kind of at the ground without grinding process Upper adhesive force is good, and rate of drying is fast, good with overcoatability, can meet " wet on wet " technological requirement, and comprehensive anticorrosive performance is good Universal high adhesion force quick-drying primer and preparation method thereof.
In order to achieve the above object, the technical scheme is that a kind of universal high adhesion force quick-drying primer, according to matter Amount number meter, including following component: epoxy modified resin 31-33 part, dispersant 0-0.3 part, bentonite 0.2-0.5 part, gas Aerosil 0.2-0.5 part, Pulvis Talci 9-11 part, barium sulfate 7-11 part, wet method sericite 4-5.5 part, composite zinc phosphate 0-5 Part, color stuffing 15-21 part, defoamer 0.1-0.3 part, levelling agent 0.05-0.2 part, adhesion promoter 0-1.2 part, organotin Drier 0.3-0.6 part, diluent 18-22 part.
Further preferred as technique scheme: described pigment total amount is 21 parts, by iron oxide black 20 parts and white carbon black 1 Part is constituted, epoxy modified resin 32 parts, dispersant 0.3 part, bentonite 0.3 part, aerosil 0.3 part, Pulvis Talci 10 parts, 10 parts of barium sulfate, wet method sericite 5.1 parts, composite zinc phosphate 0 part, defoamer 0.2 part, levelling agent 0.1 part, adhesion promoter 1 part, organotin drier 0.55 part, diluent 19.15 parts.
Further preferred as technique scheme: described pigment total amount is 15 parts, by 5 parts of ferrotitanium powder and titanium dioxide 10 Part is constituted, epoxy modified resin 31 parts, dispersant 0.3 part, bentonite 0.3 part, aerosil 0.3 part, Pulvis Talci 10 parts, 10.6 parts of barium sulfate, wet method sericite 4.8 parts, composite zinc phosphate 4 parts, defoamer 0.25 part, levelling agent 0.05 part, attachment is made every effort to promote Enter agent 0.9 part, organotin drier 0.5 part, diluent 22 parts.
Further preferred as technique scheme: described pigment total amount is 19 parts, is made up of iron oxide red, and epoxy changes Property resin 33 parts, dispersant 0 part, bentonite 0.2 part, aerosil 0.5 part, Pulvis Talci 9 parts, 7 parts of barium sulfate, wet method thin,tough silk 5.5 parts of Muscovitum, composite zinc phosphate 5 parts, defoamer 0.2 part, levelling agent 0.1 part, adhesion promoter 0 part, organotin drier 0.5 part, diluent 20 parts.
Further preferred as technique scheme: described pigment total amount is 21 parts, is made up of titanium dioxide, epoxide modified Resin 32 parts, dispersant 0 part, bentonite 0.5 part, aerosil 0.3 part, Pulvis Talci 11 parts, 10 parts of barium sulfate, wet method thin,tough silk 5.0 parts of Muscovitum, composite zinc phosphate 0 part, defoamer 0.3 part, levelling agent 0.1 part, adhesion promoter 0 part, organotin drier 0.6 part, diluent 19.2 parts.
The preparation method of a kind of above-mentioned universal high adhesion force quick-drying primer, comprises the following steps:
S1: after getting the raw materials ready, adds main material in reactor, stirs, and wherein diluent addition is the 2/3 of total amount;
S2: the slip after stirring is ground to fineness below 40 μm;
S3: add defoamer, levelling agent and organotin drier after having ground, adjusts system with remaining 1/3 diluent It is coated with-4-cup viscosity discharging after 70-120s.
Further preferred as technique scheme: in S1, mixing speed is 1200-2000r/min, and mixing time is 30min。
Compared with prior art, it is an advantage of the current invention that: universal high adhesion force quick-drying primer disclosed by the invention is done Dry speed is fast, and not temperature influence of constructing winter, under the conditions of ground is not polished, adhesive force is good, during " wet on wet " construction technology and face The matching of paint is good, and comprehensive anticorrosive performance can reach conventional common epoxy primer level.Modified epoxy disclosed by the invention The preparation method of priming paint, technique is simple, easy to operate, and production efficiency is high.
Detailed description of the invention
Below with reference to specific embodiment, the principle of the present invention is described further.
Embodiment one
The present embodiment is the universal high adhesion force quick-drying primer of black, and each raw material components is: iron oxide black 20 parts, white carbon black 1 part, Epoxy modified resin 32 parts, dispersant 0.3 part, bentonite 0.3 part, aerosil 0.3 part, Pulvis Talci 10 parts, barium sulfate 10 parts, wet method sericite 5.1 parts, composite zinc phosphate 0 part, defoamer 0.2 part, levelling agent 0.1 part, adhesion promoter 1 part, have Machine stannum drier 0.55 part, diluent 19.15 parts.Concrete preparation process is:
S1: after getting the raw materials ready, adds main material in reactor, stirs, and wherein diluent addition is the 2/3 of total amount;
S2: the slip after stirring is ground to fineness below 40 μm;
S3: add defoamer, levelling agent and organotin drier after having ground, adjusts system with remaining 1/3 diluent It is coated with-4-cup viscosity discharging after 70-120s.
Preferably, in step S1, mixing speed is 1200-2000r/min, and mixing time is 30min.
Embodiment two
The present embodiment is the universal high adhesion force quick-drying primer of Lycoperdon polymorphum Vitt, and each raw material components is: 5 parts of ferrotitanium powder, titanium dioxide 10 parts, Epoxy modified resin 31 parts, dispersant 0.3 part, bentonite 0.3 part, aerosil 0.3 part, Pulvis Talci 10 parts, barium sulfate 10.6 parts, wet method sericite 4.8 parts, composite zinc phosphate 4 parts, defoamer 0.25 part, levelling agent 0.05 part, adhesion promoter 0.9 part, organotin drier 0.5 part, diluent 22 parts.Concrete preparation process is with embodiment one.
Embodiment three
The present embodiment is the universal high adhesion force quick-drying primer of rust, and each raw material components is: iron oxide red 19, epoxide modified Resin 33 parts, dispersant 0 part, bentonite 0.2 part, aerosil 0.5 part, Pulvis Talci 9 parts, 7 parts of barium sulfate, wet method thin,tough silk cloud Female 5.5 parts, composite zinc phosphate 5 parts, defoamer 0.2 part, levelling agent 0.1 part, adhesion promoter 0 part, organotin drier 0.5 Part, diluent 20 parts.Concrete preparation process is with embodiment one.
Embodiment four
The present embodiment is the universal high adhesion force quick-drying primer of white, and each raw material components is: titanium dioxide 21, epoxy modified resin 32 parts, dispersant 0 part, bentonite 0.5 part, aerosil 0.3 part, Pulvis Talci 11 parts, 10 parts of barium sulfate, wet method sericite 5.0 parts, composite zinc phosphate 0 part, defoamer 0.3 part, levelling agent 0.1 part, adhesion promoter 0 part, organotin drier 0.6 Part, diluent 19.2 parts.Concrete preparation process is with embodiment one.
During use, add firming agent by priming paint mass ratio 5-4:1, spray after adjusting viscosity.
According to relevant national standard, above-described embodiment one to embodiment four is prepared the fast dry bottom of universal high adhesion force Paint and detect with epoxy primer main performance conventional on the market, contrast as follows:
Visible, the universal high adhesion force quick-drying primer of the present invention is faster than conventional epoxy primer rate of drying, and winter constructs not Temperature influence, under the conditions of not polishing, adhesive force substantially epoxy primer more common than routine is good.
Take iron oxide red universal high adhesion force quick-drying primer and Conventional epoxy ferrum on the market that above-described embodiment three prepares Red priming paint carries out salt spray test and compares, and result is as follows:
Visible, the iron oxide red universal high adhesion force quick-drying primer salt spray resistance of the present invention, can reach at the bottom of common epoxy iron red shop Paint level.
Now with epoxy primer conventional on the market, the present invention universal high adhesion force quick-drying primer respectively with bi-component third Olefin(e) acid polyurethane finish is supporting by the most universal " primer spray--→ surface drying 5min--→ spray bi-component acrylic 15min--→ test adhesive force is dried in polyurethane finish--→ surface drying 10min--→ 70 DEG C " technique do not polishing at the bottom of cold-rolled steel sheet Comparing on material, result is as follows:
Visible, the universal high adhesion force quick-drying primer of the present invention and the matching of bi-component acrylic polyurethane finish more than Under process conditions substantially good than conventional epoxy primer.
Principle and the embodiment of the present invention are set forth by specific embodiment used herein, above example Method and the core concept thereof being only intended to help to understand the present invention is described.The above is only the side of being preferable to carry out of the present invention Formula, it is noted that due to the finiteness of literal expression, and objectively there is unlimited concrete structure, for the art For those of ordinary skill, under the premise without departing from the principles of the invention, it is also possible to make some improvement, retouch or change, also Above-mentioned technical characteristic can be combined by rights;These improve retouching, change or combine, or the most improved general is sent out Bright design and technical scheme directly apply to other occasion, are regarded as protection scope of the present invention.

Claims (7)

1. a universal high adhesion force quick-drying primer, it is characterised in that: according to mass fraction meter, including following component: ring Oxygen modification resin 31-33 part, dispersant 0-0.3 part, bentonite 0.2-0.5 part, aerosil 0.2-0.5 part, Pulvis Talci 9-11 part, barium sulfate 7-11 part, wet method sericite 4-5.5 part, composite zinc phosphate 0-5 part, pigment 15-21 part, defoamer 0.1- 0.3 part, levelling agent 0.05-0.2 part, adhesion promoter 0-1.2 part, organotin drier 0.3-0.6 part, diluent 18-22 Part.
Universal high adhesion force quick-drying primer the most according to claim 1, it is characterised in that: described pigment total amount is 21 Part, it is made up of iron oxide black 20 parts and white carbon black 1 part, epoxy modified resin 32 parts, dispersant 0.3 part, bentonite 0.3 part, gas phase Silicon dioxide 0.3 part, Pulvis Talci 10 parts, 10 parts of barium sulfate, wet method sericite 5.1 parts, composite zinc phosphate 0 part, defoamer 0.2 Part, levelling agent 0.1 part, adhesion promoter 1 part, organotin drier 0.55 part, diluent 19.15 parts.
Universal high adhesion force quick-drying primer the most according to claim 1, it is characterised in that: described pigment total amount is 15 Part, it is made up of 5 parts of ferrotitanium powder and titanium dioxide 10 parts, epoxy modified resin 31 parts, dispersant 0.3 part, bentonite 0.3 part, gas phase Silicon dioxide 0.3 part, Pulvis Talci 10 parts, 10.6 parts of barium sulfate, wet method sericite 4.8 parts, composite zinc phosphate 4 parts, defoamer 0.25 part, levelling agent 0.05 part, adhesion promoter 0.9 part, organotin drier 0.5 part, diluent 22 parts.
Universal high adhesion force the most according to claim 1 quick-drying modified epoxy priming paint, it is characterised in that: described pigment is total Amount is 19 parts, is made up of iron oxide red, epoxy modified resin 33 parts, dispersant 0 part, bentonite 0.2 part, aerosil 0.5 part, Pulvis Talci 9 parts, 7 parts of barium sulfate, wet method sericite 5.5 parts, composite zinc phosphate 5 parts, defoamer 0.2 part, levelling agent 0.1 Part, adhesion promoter 0 part, organotin drier 0.5 part, diluent 20 parts.
Universal high adhesion force quick-drying primer the most according to claim 1, it is characterised in that: described pigment total amount is 21 Part, it is made up of titanium dioxide, epoxy modified resin 32 parts, dispersant 0 part, bentonite 0.5 part, aerosil 0.3 part, Talcum 11 parts of powder, 10 parts of barium sulfate, wet method sericite 5.0 parts, composite zinc phosphate 0 part, defoamer 0.3 part, levelling agent 0.1 part, attachment Power accelerator 0 part, organotin drier 0.6 part, diluent 19.2 parts.
6. a preparation method for the universal high adhesion force quick-drying primer according to any one of claim 1 to 5, its feature exists In: comprise the following steps:
S1: after getting the raw materials ready, adds main material in reactor, stirs, and wherein diluent addition is the 2/3 of total amount;
S2: the slip after stirring is ground to fineness below 40 μm;
S3: add defoamer, levelling agent and organotin drier after having ground, adjusts system with remaining 1/3 diluent It is coated with-4-cup viscosity discharging after 70-120s.
The preparation method of universal high adhesion force quick-drying primer the most according to claim 6, it is characterised in that: in S1, stir Mixing speed is 1200-2000r/min, and mixing time is 30min.
CN201610456792.2A 2016-06-22 2016-06-22 General-purpose high-adhesion quick-drying primer and preparation method thereof Pending CN105949959A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106675123A (en) * 2016-12-19 2017-05-17 钦州市钦南区科学技术情报研究所 Coating prepared from white clay waste and preparation method
CN106867378A (en) * 2016-12-22 2017-06-20 安徽易有墙纸有限公司 A kind of tack oil resistant wallpaper high and preparation method thereof
CN107177257A (en) * 2017-06-30 2017-09-19 苏州日新水性涂料有限公司 A kind of silver-colored sealing wax of wet on wet sudden strain of a muscle
CN112480783A (en) * 2020-11-30 2021-03-12 湖南中车弘辉科技有限公司 High-elasticity fan blade edge covering protective coating and construction method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102352171A (en) * 2011-09-16 2012-02-15 中华制漆(深圳)有限公司 Novel environment-friendly coating with superhigh marine environment corrosion resistance and preparation method and application thereof
CN103409037A (en) * 2013-08-06 2013-11-27 信和新材料股份有限公司 Solvent type double-composition epoxy coating material quick to solidify at low temperature and preparation method thereof
CN103980801A (en) * 2014-06-05 2014-08-13 唐山尼克涂料有限公司 Zinc-rich primer and preparation method thereof
CN104341912A (en) * 2014-10-12 2015-02-11 青岛文晟汽车零部件有限公司 Low-temperature-resistant primer

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102352171A (en) * 2011-09-16 2012-02-15 中华制漆(深圳)有限公司 Novel environment-friendly coating with superhigh marine environment corrosion resistance and preparation method and application thereof
CN103409037A (en) * 2013-08-06 2013-11-27 信和新材料股份有限公司 Solvent type double-composition epoxy coating material quick to solidify at low temperature and preparation method thereof
CN103980801A (en) * 2014-06-05 2014-08-13 唐山尼克涂料有限公司 Zinc-rich primer and preparation method thereof
CN104341912A (en) * 2014-10-12 2015-02-11 青岛文晟汽车零部件有限公司 Low-temperature-resistant primer

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106675123A (en) * 2016-12-19 2017-05-17 钦州市钦南区科学技术情报研究所 Coating prepared from white clay waste and preparation method
CN106867378A (en) * 2016-12-22 2017-06-20 安徽易有墙纸有限公司 A kind of tack oil resistant wallpaper high and preparation method thereof
CN107177257A (en) * 2017-06-30 2017-09-19 苏州日新水性涂料有限公司 A kind of silver-colored sealing wax of wet on wet sudden strain of a muscle
CN112480783A (en) * 2020-11-30 2021-03-12 湖南中车弘辉科技有限公司 High-elasticity fan blade edge covering protective coating and construction method thereof

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