JP2001239300A - Sludge treating method - Google Patents

Sludge treating method

Info

Publication number
JP2001239300A
JP2001239300A JP2000053389A JP2000053389A JP2001239300A JP 2001239300 A JP2001239300 A JP 2001239300A JP 2000053389 A JP2000053389 A JP 2000053389A JP 2000053389 A JP2000053389 A JP 2000053389A JP 2001239300 A JP2001239300 A JP 2001239300A
Authority
JP
Japan
Prior art keywords
sludge
charcoal powder
charcoal
tank
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000053389A
Other languages
Japanese (ja)
Inventor
Fumio Yorinobu
文夫 頼信
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FURUMOTO HIROKI
Original Assignee
FURUMOTO HIROKI
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FURUMOTO HIROKI filed Critical FURUMOTO HIROKI
Priority to JP2000053389A priority Critical patent/JP2001239300A/en
Publication of JP2001239300A publication Critical patent/JP2001239300A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Abstract

PROBLEM TO BE SOLVED: To separate sludge from water by perfectly floating the sludge for a short time at the most important solid-liquid separation step in the continuous steps and to reduce the moisture content, which is 75% in the present state, of the cake-shaped sludge after dehydration. SOLUTION: At first, charcoal powder and chitosan in the natural field is added to liquid sludge by about half of the liquid sludge or smaller based on measurement weight without using chemicals for making the sludge apt to flocculate and float. Next, the power of bubbles, which are generated when the pressurized oxygen solution prepared beforehand is purged into the liquid of atmospheric pressure, is used as assistance for floating the sludge for a short time in a floating tank where the concentrated sludge is gathered by pumping it up. The floated sludge is dehydrated to obtain cake-shaped sludge that has 800% moisture content and about one-tenth volume of the concentrated sludge. The cake-shaped sludge contains the charcoal powder of 100% or more amount of the total solid content and can be dried at accelerated drying speed by making good use of air permeability being the characteristic of the charcoal powder and generating cracks in the sludge having viscosity. The obtained sludge is used as not only a nonpolluting soil reducing material but also a good agricultural material by composting it into fertilizer.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】木炭粉とキトサン溶液を注入
した汚泥に微細気泡を付着させた、固液分離の廃水、下
水汚泥処理に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to solid-liquid separation wastewater and sewage sludge treatment in which fine bubbles are attached to sludge into which charcoal powder and a chitosan solution have been injected.

【0002】[0002]

【従来の技術】処理量の増大、ならびに汚泥の性質が多
様化し処理技術に困難を来たしたので、化学薬品である
高分子凝集剤、又は同じく無機系塩化第二鉄、消石灰等
を凝集のために使用し、しかる後に脱水工程を経て乾
燥、焼却えの方向に進めているのが現状である。ところ
がこの方法ではリサイクル方面に全体の1割程度しか利
用されずにいる。その理由は化学薬品剤の使用のため塩
類過多となり、土壌還元に適さないことである。従って
焼却方向に向ける数量が多く、最近の環境問題から排ガ
ス処理の技術の問題もあり、合せて処理汚泥の粘性が高
く、含水量平均75%の焼却のため、焼却設備に模大な
費用が掛り又ランニングコストも高く、さりとて場外委
託も過大な処理費を支払っているのが現状である。
2. Description of the Related Art Due to an increase in the treatment amount and diversification of sludge properties, it has become difficult to treat the technology. Therefore, a polymer flocculant, which is a chemical, or an inorganic ferric chloride, slaked lime, etc. At present, they are used for drying and then dehydration and drying and incineration. However, in this method, only about 10% of the whole is used for recycling. The reason is that the use of chemical agents causes excessive salt and is not suitable for soil reduction. Therefore, there is a large amount of waste in the incineration direction, and there are also problems with the technology of exhaust gas treatment due to recent environmental problems. In addition, the sludge has a high viscosity and incineration with an average water content of 75% requires a huge cost for incineration equipment. At present, running costs are high, and outsourcing is also paying excessive processing costs.

【0003】[0003]

【発明が解決しようとする課題】汚泥が浮上槽に入って
から短時間で浮上させることと、汚泥の悪臭を無くすこ
とにある。前記時間の問題は原水の量と比例するので、
工程上処理場のスペースに限度があるからである。そし
て連続工程である以上、全体の流れにマッチした時間と
いうことになるから、脱水工程までは短時間処理が必要
である。以上を技術上の課題とし、次の処理のための添
加材料の組合せからくる処理により、リサイクル化そし
て無公害の土壌還元化という大きな目標を課題としなけ
ればならない。又当面脱水工程を終えたケーキ状のもの
が土壌還元としての受入体制が満ぱいの場合は、現状の
焼却方法に向ける必要から、その方向として最終的に含
水量を少くすることが最大の課題である。そしてトータ
ルとして下水処理の処理コストを大幅に下げることが課
題である。又将来に向ってリサイクル資材として、安心
して継続的に使える農業資材として課題がある。
SUMMARY OF THE INVENTION An object of the present invention is to make the sludge float in a short time after entering the floating tank, and to eliminate the bad smell of the sludge. Since the problem of time is proportional to the amount of raw water,
This is because there is a limit to the space of the treatment plant in the process. Since the process is a continuous process, the time matches the entire flow. Therefore, a short process is required until the dehydration process. The above should be considered as a technical issue, and the major goal of recycling and non-polluting soil reduction should be achieved by the treatment that comes from the combination of additive materials for the next treatment. In addition, if the cake-like product after the dehydration process has a sufficient receiving system for soil reduction, it is necessary to turn to the current incineration method. is there. The challenge is to significantly reduce the cost of sewage treatment as a whole. In addition, there is a problem as an agricultural material that can be used safely and continuously as a recycled material for the future.

【0004】[0004]

【課題を解決するための手段】技術上の解決の手段とし
て、木炭粉とキトサン溶液を使うことである。木炭粉は
特長である、比表面積大なる微細孔が容積重を逆に小さ
くしているので、水の中では浮力としての要素を持ち、
又キトサン溶液は木炭と同じ自然界の産物であるから成
分的に公害性のないこと、そして凝集力に優れているこ
とは多くの排水処理に知られているものである。この前
者の比重の軽さと後者の凝集力で汚泥に浮力をつけたと
ころへ、浮上槽内で更にし、微細気泡の加勢を得て短時
間で完全に浮上分離させるのである。又木炭粉の細孔は
悪臭を吸着取することは、実績として既に知られてい
る。又木炭粉は通気性に優れているので、汚泥の脱水後
は粘性ある汚泥のひび割れ状態を起し乾燥速度を早める
のである。従ってこのメカニズムを利用し、機械装置に
取り組めは大幅に含水量を減らす乾燥効率が上るのであ
る。特に脱水後、焼却に向けず土壌還元に向ける場合は
成分上障害はなく向後の方向である。又コンポスト用に
する場合は単なる堆積を1週間位の日数を掛けることに
より、放線菌の働きで団粒構造形成に強い堆肥となるの
である。
The technical solution is to use charcoal powder and a chitosan solution. Charcoal powder is characterized by micropores with a large specific surface area, which makes it smaller in volume, so it has an element of buoyancy in water,
In addition, chitosan solution is a natural product similar to charcoal, so it is known in many wastewater treatments that it has no pollution and is excellent in cohesion. When the buoyancy is given to the sludge by the lightness of the specific gravity of the former and the cohesive force of the latter, the sludge is further raised in the flotation tank to obtain the energization of the fine bubbles and completely float and separate in a short time. It is already known that the pores of charcoal powder adsorb and remove odors. In addition, since charcoal powder is excellent in air permeability, after the sludge is dewatered, a viscous sludge is cracked and the drying speed is increased. Therefore, using this mechanism to tackle the machinery and equipment will greatly increase the drying efficiency by greatly reducing the water content. In particular, after dehydration, in the case of turning to soil reduction instead of incineration, there is no obstacle in terms of components, and it is the direction in the direction of return. In addition, when composting is used, by simply multiplying the number of days by about one week, actinobacteria function to make the compost strong against the formation of the aggregate structure.

【0005】[0005]

【発明の実施の形態】発明者は木炭粉による下水汚泥の
浮上分離を先に試みている。ところが難点として完全浮
上まで3日〜5日掛るので、都市から離れた処理上でな
ければスペースが既になく、都市のものとならないの
で、短時間浮上の解決課題に取組んできた。そんな中で
うなぎ養食場で餌に木炭粉を混ぜてあたえたところ、短
日で低床より座ブトンが浮くが如く低床汚泥が浮いてき
た事を聞くに及び、片方既に加圧浮上方式があることを
知っていたので、組み合せての効果を考え、直ちに実施
したところ好結果を得たことにはじまる。
BEST MODE FOR CARRYING OUT THE INVENTION The inventor has previously attempted to float and separate sewage sludge using charcoal powder. However, since it takes three to five days to completely ascend as a result, the space is not already available unless the processing is performed away from the city, and it does not become an urban one. Under such circumstances, when charcoal powder was mixed with the feed at the eel eating place, it was heard that low bed sludge floated as if the seat buton floated from the low floor in a short day, and one of them was already pressurized flotation method I knew that there was a problem, so I thought about the effect of the combination and immediately implemented it.

【0006】[0006]

【実施例1】木炭粉は樹種は問わないが、針葉樹が容積
重が小さく有利である。又木炭粉の粒度は容積重にも関
係があるので、実験の結果から2ミリメートルアンダー
のものとしている。粒子を細かくすると木炭の生産性か
らコスト高になると同時に、飛び散り原因となり作業性
を悪くするからである。又2ミリメートルより大きくす
れば嵩比重に影響するからである。次に木炭の製造温度
が重要である。木炭は製造温度即ち処理温度によって物
性が大きく異るからである。 以上の如くであるが、本発明には物性の中の容積重が最
も影響するので低温炭の使用が最も有利である。従って
杉、桧、カラマツ等の針葉樹低温炭が本発明に最も相応
しい資材である。木炭粉自身の含水率は15%〜25%
が適率で、15%以下は微粉と同じく飛び散りが出て作
業性を悪くする。撹拌装置は全面的に汚泥との馴染みを
良くするためであり、凝集のためである。
Example 1 Charcoal flour is not limited to wood species, but softwood is advantageous because it has a low bulk density. In addition, since the particle size of the charcoal powder is also related to the bulk density, it is determined to be less than 2 mm from the experimental results. This is because if the particles are made finer, the cost increases due to the charcoal productivity, and at the same time, it causes scattering and deteriorates the workability. Also, if it is larger than 2 mm, the bulk specific gravity is affected. Next, the production temperature of charcoal is important. This is because the properties of charcoal vary greatly depending on the production temperature, that is, the treatment temperature. As described above, the use of low-temperature coal is most advantageous in the present invention because the bulk weight in the physical properties has the most influence. Therefore, softwood low-temperature coal such as cedar, cypress, and larch is the most suitable material for the present invention. The moisture content of the charcoal powder itself is 15% to 25%
Is an appropriate rate, and when it is 15% or less, splatters appear as in the case of fine powder, resulting in poor workability. The stirrer is for improving the familiarity with the sludge on the whole and for coagulation.

【0007】[0007]

【実施例2】本発明の木炭粉の役割は下水汚泥濃縮液の
比重1の液体の中で、固型物を比重1.0以下にして浮
上させることにあるから、木炭粉の中でも比較的に疎水
性の持主、即ち揮発分の多い低温炭がよく、且つ容積重
の小さいものが望まれるのである。木炭粉の最終濃縮液
に注入する比率は最終濃縮液の含水率平均98%に対し
0.2%を基準とする。多いのは良いが処理コストに影
響するからである。
Embodiment 2 The role of the charcoal powder of the present invention is to raise a solid product to a specific gravity of 1.0 or less in a liquid having a specific gravity of 1 of the concentrated sewage sludge, and therefore, the charcoal powder is relatively small in the charcoal powder. It is desirable to use a low-temperature coal having a high hydrophobicity, that is, a high volatile content, and to have a low volumetric gravity. The ratio of the charcoal powder injected into the final concentrate is 0.2% based on an average water content of 98% of the final concentrate. Many are good because they affect the processing cost.

【0008】[0008]

【実施例3】キトサン溶液は1%のキトサン液をつくる
のである。1%溶液とは水50ccの中にキトサン1g
を入れ約15分据置き水と馴染ませる。次に1規定の有
機酸(錯酸)10ccを加え撹拌する。そして100c
cになるまで水を加えたものである。以上の比率で造っ
た溶液を木炭粉と同じ汚泥に対し10ppmの比率基準
をもって汚泥に対し混入するのである。このキトサン溶
液は汚泥を凝集する役目を果たすのである。木炭粉は後
の乾燥工程その他で活躍するが、浮上分離までは木炭粉
のみでは浮上に時間が掛り、所定の連続工程ベースにの
らないので、同じ自然界の凝集剤として選んだものであ
る。この取組みで木炭粉を入れた撹拌装置づき注入槽に
引続きこのキトサン1%溶液を注入撹拌するのである。
撹拌が終るや次の加圧浮上槽に進み、其処で予め準備さ
れた加圧タンクの酸素溶液を大気化の中で導入されるの
で直ちに微細気泡が前記汚泥に付着し同時に全面浮上
し、固液分離を果すのである。
Embodiment 3 The chitosan solution makes a 1% chitosan solution. 1% solution means 1g of chitosan in 50cc of water
And mix with standing water for about 15 minutes. Next, 10 cc of 1N organic acid (complex acid) is added and stirred. And 100c
Water was added until it became c. The solution prepared in the above ratio is mixed into the sludge with the same 10 ppm as the sludge as the charcoal powder. This chitosan solution serves to coagulate the sludge. The charcoal powder plays an active role in the subsequent drying step and the like, but it takes a long time to float with the charcoal powder alone until flotation and separation, so that it is not based on a predetermined continuous process. Therefore, it was selected as the same natural coagulant. In this approach, the 1% chitosan solution is subsequently injected and stirred into an injection tank with a stirring device containing charcoal powder.
When the stirring is completed, the process proceeds to the next pressurized flotation tank, where the oxygen solution in the previously prepared pressurized tank is introduced in the atmosphere, so that fine bubbles immediately adhere to the sludge and simultaneously float on the entire surface, and solidify. It performs liquid separation.

【0009】[0009]

【発明の効果】廃水処理、下水処理の分野は今日環境問
題として、焼却方向に処理方法が大多数向いて進んでい
ることに警鐘を鳴らしている。そんな中で自然界に還元
する、土壌還元を最終目的に化学薬品を使用せず、この
目的達成のために自然界の産物である木炭粉ならびにキ
トサンを使うということは社会的に貢献することであっ
て、他にデメリットは全くない。然もすぐはじめられる
有意義なものである。
In the field of wastewater treatment and sewage treatment, it is now an alarm that the majority of treatment methods are proceeding in the incineration direction as an environmental problem. Under such circumstances, it is social contribution to use charcoal powder and chitosan, which are natural products, to achieve this purpose without using chemicals for the ultimate purpose of reducing the soil and reducing the soil. There are no other disadvantages. It is a meaningful thing that can be started immediately.

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Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 汚泥原水から初沈工程を経て活性汚泥法
工程えと進んだ段階、或いは再度消化槽を経て、濃縮汚
泥の段階から次工程の加圧浮上槽との中間に撹拌装置づ
き木炭粉ならびにキトサン溶液の注入槽を設置する。其
処で所定の木炭粉は粉状のまま、キトサン溶液は定量注
入器をもって注入撹拌する。続いて加圧浮上槽に進み予
め造られた加圧タンクから導入された酸素溶液によって
大気下で発生する微細気泡の加勢を得て、短時間で全面
的に汚泥を水と分離浮上させる、木炭粉ならびにキトサ
ン溶液による加圧浮上方式と組み合わせた処理方法。
1. Charcoal powder from a raw sludge raw water through an initial settling process to an activated sludge process, or from a concentrated sludge stage through a digestion tank to a halfway point between a pressurized flotation tank and a next step. In addition, a chitosan solution injection tank is installed. Then, the chitosan solution is injected and stirred with a metering injector while the predetermined charcoal powder remains powdery. Subsequently, the charcoal is advanced to a pressurized flotation tank to obtain the energization of fine bubbles generated in the atmosphere by an oxygen solution introduced from a pre-formed pressurized tank, and to completely separate and float the sludge from water in a short time, charcoal. Processing method combined with pressure flotation method using powder and chitosan solution.
【請求項2】 気泡発生については、加圧浮上方式に限
らず他の微細気泡発生装置による処理方法。
2. The method of generating bubbles is not limited to the pressure-floating method, and is a processing method using another fine bubble generator.
JP2000053389A 2000-02-29 2000-02-29 Sludge treating method Pending JP2001239300A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000053389A JP2001239300A (en) 2000-02-29 2000-02-29 Sludge treating method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000053389A JP2001239300A (en) 2000-02-29 2000-02-29 Sludge treating method

Publications (1)

Publication Number Publication Date
JP2001239300A true JP2001239300A (en) 2001-09-04

Family

ID=18574782

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000053389A Pending JP2001239300A (en) 2000-02-29 2000-02-29 Sludge treating method

Country Status (1)

Country Link
JP (1) JP2001239300A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009087921A1 (en) * 2008-01-11 2009-07-16 Asahi Organic Chemicals Industry Co., Ltd. Method for treating oil-containing waste water and apparatus for treating oil-containing waste water
CN101979328A (en) * 2010-10-28 2011-02-23 浙江省医学科学院 Chitosan composite gel water purifying agent and preparation method thereof
WO2020211321A1 (en) * 2019-04-15 2020-10-22 华南理工大学 Sludge dewatering method
CN113088949A (en) * 2021-04-03 2021-07-09 季茂远 High-corrosion-resistance workpiece surface treating agent and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009087921A1 (en) * 2008-01-11 2009-07-16 Asahi Organic Chemicals Industry Co., Ltd. Method for treating oil-containing waste water and apparatus for treating oil-containing waste water
CN101979328A (en) * 2010-10-28 2011-02-23 浙江省医学科学院 Chitosan composite gel water purifying agent and preparation method thereof
CN101979328B (en) * 2010-10-28 2012-06-06 浙江省医学科学院 Chitosan composite gel water purifying agent, preparation method and uses thereof
WO2020211321A1 (en) * 2019-04-15 2020-10-22 华南理工大学 Sludge dewatering method
CN113088949A (en) * 2021-04-03 2021-07-09 季茂远 High-corrosion-resistance workpiece surface treating agent and preparation method thereof

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