CN113026354A - Plant type fabric degerming and odor removing aerosol and preparation method thereof - Google Patents

Plant type fabric degerming and odor removing aerosol and preparation method thereof Download PDF

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CN113026354A
CN113026354A CN202110301699.5A CN202110301699A CN113026354A CN 113026354 A CN113026354 A CN 113026354A CN 202110301699 A CN202110301699 A CN 202110301699A CN 113026354 A CN113026354 A CN 113026354A
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extract
plant
aerosol
group
odor
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CN113026354B (en
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骆建华
张龙来
廖国栋
刘文龙
吴鹰花
薛洪伟
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Zhongshan Lanju Daily Chemical Industries Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246Esters of unsaturated carboxylic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention provides a plant type fabric degerming and odor removing aerosol and a preparation method thereof, and relates to the technical field of cleaning agents. The invention discloses a plant type fabric degerming and odor removing aerosol which comprises the following raw materials in parts by weight: 0.01-0.1 part of botanical fungicide, 1-10 parts of deodorant, 0.2-2 parts of emulsifier, 5-20 parts of solvent, 0.1-0.5 part of corrosion inhibitor, 20-40 parts of propellant and 30-50 parts of deionized water. The plant type fabric degerming odor-removing aerosol can deeply penetrate into the interior of the fabric for degerming and removing odor, cannot cause fading or stain ring formation of the fabric, is quick in drying time, and is fresh and convenient to use.

Description

Plant type fabric degerming and odor removing aerosol and preparation method thereof
Technical Field
The invention relates to the technical field of cleaning agents, in particular to a plant type fabric degerming and odor removing aerosol and a preparation method thereof.
Background
With the continuous improvement of the living standard of people, the concern of people on health and cleaning is also increasing. The odor of the clothes in the aspect of life, such as the odor of the articles used on the bed, the odor in the bedroom, the sweat odor of the underwear and the like, often influences the life quality of people. In addition, with the arrival of aging society, the number of bed-ridden elderly people and home care people increases, and the demand for measures to prevent malodor also increases, so that fabric deodorant products become a focus of attention.
However, the degerming and odour-combating products for fabrics on the market have some drawbacks, such as: although the deodorant has the functions of degerming and deodorization, the way of covering essence is mainly adopted, and the peculiar smell molecules are not removed; secondly, the peculiar smell molecules on the surface can be eliminated, but the peculiar smell molecules cannot penetrate into the textile fiber, so that the effect is not durable enough; and thirdly, the fabric is not easy to volatilize after being used, the drying time of the fabric is long, the fabric is not fresh and cool enough, and the fading of the fabric or the formation of stain rings on the surface of the fabric are easy to cause.
Disclosure of Invention
Therefore, the plant type fabric degerming odor-removing aerosol is needed to solve the problems, can deeply penetrate into the fabric to degerming and remove odor, cannot cause fading or stain circles of the fabric, is quick in drying time, and is fresh and convenient to use.
A plant type fabric degerming and odor removing aerosol comprises the following raw materials in parts by weight:
Figure BDA0002986521850000011
the plant type fabric degerming and deodorizing aerosol achieves the degerming and deodorizing effects through the plant source bactericide and the deodorizing agent, and the feed liquid is enabled to quickly permeate into textile fibers in the form of the aerosol, so that the degerming and deodorizing effects are more lasting; the volatile agent is quick in volatilization, the fabric is not easy to fade, and a stain ring can not be formed on the surface of the fabric.
In one embodiment, the plant-derived fungicide is selected from: two or three of cortex Cinnamomi extract, semen glycines seed extract, herba Rosmarini officinalis extract, Mandarin orange pericarp extract, semen Cassiae seed extract, and herba Menthae extract. The botanical fungicide belongs to a plant extraction type fungicide, is mild, has no stimulation, is environment-friendly and is harmless to human bodies.
In one embodiment, the botanical fungicide is selected from a mixture of cinnamon bark extract, rosemary extract, cassia seed extract. Preferably, the mass ratio of the cinnamon bark extract to the rosemary extract to the cassia seed extract is 4:3: 3.
In one embodiment, the botanical fungicide is selected from the group consisting of cinnamon bark extract, soybean seed extract, citrus peel extract. Preferably, the mass ratio of the cinnamon bark extract to the soybean seed extract to the citrus peel extract is 5:4: 1.
In one embodiment, the botanical fungicide is selected from the group consisting of cinnamon bark extract, soybean seed extract, and peppermint extract. Preferably, the mass ratio of the cinnamon bark extract to the soybean seed extract to the mint extract is 4:4: 2.
In one embodiment, the odorant is selected from: one or two of zinc ricinoleate and zinc ricinoleate. The deodorant belongs to an odor chelating agent, and can completely remove odor molecules rather than only cover the odor.
In one embodiment, the solvent is selected from: one or more of ethanol, kerosene, acetone, ethyl acetate and propylene glycol. Among them, D60 kerosene is preferable.
In one embodiment, the emulsifier is selected from: one or two of acetylene glycol emulsifier and ethoxy alcohol emulsifier.
In one embodiment, the emulsifier is selected from: one or two of tetramethyl decyne glycol and ethoxy propanol. The emulsifier has the characteristics of low solid content and low residue, is easy to volatilize, is not easy to leave stain rings on fabrics, and can not cause the fading of the fabrics.
In one embodiment, the propellant is selected from: compressed air, inert gas, liquefied petroleum gas, propane and butane, dimethyl ether, tetrafluoroethane and tetrafluoropropene.
In one embodiment, the corrosion inhibitor is selected from: one or more than two of sodium benzoate, sodium nitrite, triethanolamine, morpholine and polyethoxylated ammonium.
The invention also provides a preparation method of the plant type fabric degerming and odor removing aerosol, which comprises the following steps:
1) weighing the bactericide, the deodorant, the emulsifier and the solvent, and uniformly mixing to obtain a group A material;
2) uniformly mixing the corrosion inhibitor and water to obtain a group B material;
3) adding the group B material into the group A material, uniformly mixing, and emulsifying uniformly to obtain a feed liquid;
4) and filling the feed liquid into an aerosol can, sealing a valve, and filling a propellant to obtain the plant type fabric degerming and deodorizing aerosol.
Compared with the prior art, the invention has the following beneficial effects:
the plant type fabric degerming and deodorizing aerosol disclosed by the invention achieves the degerming and deodorizing effects through the plant source bactericide and the deodorizing agent, and the feed liquid is enabled to quickly permeate into textile fibers in the form of the aerosol, so that the degerming and deodorizing effects are more durable; the volatile agent is quick in volatilization, the fabric is not easy to fade, and a stain ring can not be formed on the surface of the fabric. The preparation method is simple, easy to operate and low in cost.
Drawings
FIG. 1 shows the result of the test of the fading residue of cotton cloth in the experimental example.
Detailed Description
To facilitate an understanding of the invention, a more complete description of the invention will be given below in terms of preferred embodiments. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention.
In the following examples and comparative examples, all the starting materials were commercially available unless otherwise specified.
Example 1
The fabric degerming deodorant comprises the following raw materials in parts by weight:
0.04 part of cinnamon bark extract, 0.03 part of rosemary extract, 0.03 part of cassia seed extract, 5 parts of zinc ricinoleate, 1 part of tetramethyl decyndiol, 10 parts of ethanol, 0.27 part of sodium benzoate, 0.23 part of sodium nitrite, 20 parts of propane butane and 40 parts of deionized water.
The fabric degerming deodorant is prepared by the following method:
1) mixing cortex Cinnamomi extract, herba Rosmarini officinalis extract, semen Cassiae extract, zinc ricinoleate, tetramethyl decynediol, and ethanol;
2) mixing sodium benzoate, sodium nitrite and deionized water, and stirring uniformly;
3) slowly adding the solution obtained in the step 2) into the solution obtained in the step 1) for multiple times, stirring for 30min to obtain a uniform state, and obtaining a feed liquid;
4) filling the material liquid into an aerosol can, sealing the valve, and filling propane and butane to obtain the final product.
Example 2
The fabric degerming deodorant comprises the following raw materials in parts by weight:
0.025 parts of cinnamon bark extract, 0.02 parts of soybean seed extract, 0.005 parts of citrus peel extract, 5 parts of zinc ricinoleate, 1 part of tetramethyl decyndiol, 10 parts of propylene glycol, 0.33 part of sodium benzoate, 0.17 part of morpholine, 20 parts of propane butane and 45 parts of deionized water.
The fabric degerming deodorant is prepared by the following method:
1) mixing cortex Cinnamomi extract, semen glycines extract, Mandarin orange pericarp extract, zinc ricinoleate, tetramethyl decyndiol, and propylene glycol;
2) mixing sodium benzoate, morpholine and deionized water, and stirring uniformly;
3) slowly adding the solution obtained in the step 2) into the solution obtained in the step 1) for multiple times, stirring for 30min to obtain a uniform state, and obtaining a feed liquid;
4) filling the material liquid into an aerosol can, sealing the valve, and filling propane and butane to obtain the final product.
Example 3
The fabric degerming deodorant comprises the following raw materials in parts by weight:
0.02 part of cinnamon bark extract, 0.02 part of soybean seed extract, 0.01 part of mint extract, 5 parts of zinc ricinoleate, 2 parts of ethoxy propanol, 10 parts of propylene glycol, 0.27 part of sodium benzoate, 0.23 part of polyethoxylated ammonium, 20 parts of dimethyl ether and 30 parts of deionized water.
The fabric degerming deodorant is prepared by the following method:
1) mixing cortex Cinnamomi extract, semen glycines extract, herba Menthae extract, zinc ricinoleate, ethoxypropanol, and propylene glycol;
2) mixing sodium benzoate, polyethoxylated ammonium and deionized water, and stirring uniformly;
3) slowly adding the solution obtained in the step 2) into the solution obtained in the step 1) for multiple times, stirring for 30min to obtain a uniform state, and obtaining a feed liquid;
4) filling the material liquid into an aerosol can, sealing a valve, and filling dimethyl ether to obtain the product.
Comparative example 1
The commercial Fenx clear fabric degerming deodorant.
Comparative example 2
A fabric sterilizing deodorant differing from example 1 in that tetramethyldecyndiol was replaced with an equal amount of span 80 as the emulsifier.
Experimental example 1
Fading residue test.
1) Cutting blue fabrics made of different fabric materials such as cotton cloth, polyester fabric, polyester and cotton combined fabric into a circle with the diameter of 6cm by using scissors, washing the circle by using standard clothes, and airing the circle for later use.
2) A certain amount of sample to be tested is transferred by a liquid transfer machine and dripped into the center of the circular cloth (dripping 100 mu l), and whether the dripping part has visible color spots and stain rings after the circular cloth is naturally dried by air is observed.
3) A blank control is set in the experiment at the same time, and deionized water with the same amount is dripped into the blank control.
The test results are as follows, and some of the results are shown in FIG. 1
TABLE 1 sample formation of stain circles on fabrics of different materials
Comparative example 1 Comparative example 2 Example 1 Example 2 Example 3 CK
Cotton cloth Is more obvious Is more obvious Is not significant Is not significant Is not significant Is not significant
Terylene fabric Is remarkable in that Is more obvious Is not significant Is not significant Is not significant Is not significant
Combined cloth Is remarkable in that Is more obvious Is not significant Is not significant Is not significant Is not significant
Wherein, the 'significant' means that clear stain circle boundaries can be observed by naked eyes; "not significant" means that the boundaries of the spot rings are not visible to the naked eye; by "more visible" is meant that the irregular, lighter colored ring boundaries are visible to the naked eye.
The degerming deodorant of the examples and the comparative examples is found to have no fading on cotton cloth, polyester and cotton combined cloth (polyester: cotton is 1: 1). The cotton cloth test result is shown in figure 1, the obvious stain ring residue and situation exist in comparative example 1, the obvious stain ring residue situation also exists in comparative example 2, and the stain rings and color spots can not be seen by naked eyes in examples 1-3.
Experimental example 2
And (4) ammonia gas removal experiments.
The method selects common peculiar smell molecule ammonia as an evaluation object, and comprises the following experimental methods:
1) the method comprises the steps of cleaning and airing a 2500mL wide-mouth bottle, covering a half of the bottle mouth with a preservative film, cutting 2cm × 5cm filter paper, tying one end of the filter paper with a rope, hanging the filter paper in the wide-mouth bottle, transferring 10 μ L ammonia water (with the concentration of 25% -28%) with a 50 μ L microsyringe, injecting the ammonia water into the cut filter paper, and completely sealing the bottle mouth with the preservative film.
2) After 4h, slowly pulling out the rope, taking out the filter paper (without uncovering the sealed preservative film), opening a small hole in the preservative film by using a pointed-end tweezers, transferring a certain amount (10mL, 5mL, 0.5mL) of the degerming aerosol liquid medicine from the experimental sample (the liquid medicine of the embodiment 1, the comparative example 1 and the comparative example 2) by using a liquid transfer machine, injecting the degerming aerosol liquid medicine into the bottle from the opened small hole, sealing the bottle by using a new preservative film, fastening the bottle by using the rope, injecting the same amount of negative control liquid into the blank group of bottles, wherein the negative control liquid is deionized water or ethanol water solution.
3) After 24h, ammonia gas concentration in the experimental group and the blank group of bottles is measured by an ammonia gas test tube, and the clearance rate is calculated according to the following formula. W1The calculation method is as follows:
W1=(K1-K2)/K1×100%
in the formula, W1For clearance, K1The ammonia gas concentration is blank group (mg/m)3),K2For the experimental group, the ammonia concentration (mg/m)3)。
The results are shown in table 2:
TABLE 2 test results of ammonia removal effect of samples
Figure BDA0002986521850000051
Tests show that when 10mL of sample is used, the degerming odor-removing aerosol of the example and the comparative example has better odor-removing effect in both the example 1 and the comparative example 2, but the comparative example 1 has only 60% ammonia gas removal rate. Both example 1 and comparative example 2 had a more pronounced amine removal effect when 0.5mL of sample was used, with comparative example 1 having substantially no amine removal effect, presumably because comparative example 1 deodorized primarily in a masked manner.
Experimental example 3
And (5) performing a sterilization experiment.
1) Collecting and culturing strains: firstly, placing a sterile culture medium in the air for a certain time, collecting bacterial colonies in the air, culturing for 48 hours in an incubator at 37 ℃, then respectively picking out the air by using inoculating loops to collect the bacterial colonies, and further collecting and culturing target strains by adopting a plate marking method.
2) Control group medium inoculation: respectively inoculating 30 strains on each sterile culture medium by using a self-made inoculating needle in an inoculating mode;
test group medium inoculation: taking 0.1mL of degerming and deodorizing aerosol liquid medicine by using a liquid transfer gun, coating the liquid medicine on the surface of a sterile culture medium by using a coating rod, uniformly coating the liquid medicine, and then respectively inoculating 30 strains on each sterile culture medium by using an inoculating needle;
negative control: no colony inoculation was performed.
3) Culturing and detecting: placing the samples of the test group, the control group and the negative control group in an incubator, culturing for 48h in the incubator at 37 ℃, counting colonies, and calculating the bacteriostasis rate (P) according to the following formula:
P=((a-b)/b×100%
wherein, P is the bacteriostasis rate, a is the colony number in the culture medium of a control group, and b is the colony number in the culture medium of a test group.
Test results are shown in table 2:
TABLE 3 test results of bacteriostatic effect of samples
Figure BDA0002986521850000061
Tests show that the products of the examples and the comparative examples have good sterilization effect on colonies collected in the air.
The technical features of the embodiments described above may be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.

Claims (10)

1. A plant type fabric degerming and odor removing aerosol is characterized by comprising the following raw materials in parts by weight:
Figure FDA0002986521840000011
2. the plant-based fabric sterilization and odor elimination aerosol according to claim 1, wherein the plant-derived bactericide is selected from the group consisting of: two or three of cortex Cinnamomi extract, semen glycines seed extract, herba Rosmarini officinalis extract, Mandarin orange pericarp extract, semen Cassiae seed extract, and herba Menthae extract.
3. The plant-based fabric sterilization and odor removal aerosol as claimed in claim 2, wherein the plant-derived bactericide is a mixture of cinnamon bark extract, rosemary extract and cassia seed extract; or a mixture of cinnamon bark extract, soybean seed extract, citrus peel extract; or a mixture of cinnamon bark extract, soybean seed extract, and mint extract.
4. The plant-based fabric sterilization and odor elimination aerosol according to claim 1, wherein the odor elimination agent is selected from the group consisting of: one or two of zinc ricinoleate and zinc ricinoleate.
5. The plant-based fabric sterilization and odor elimination aerosol according to claim 1, wherein the solvent is selected from the group consisting of: one or more of ethanol, kerosene, acetone, ethyl acetate and propylene glycol.
6. The plant-based fabric sterilization and odor removal aerosol as claimed in any one of claims 1 to 5, wherein the emulsifier is selected from the group consisting of: one or two of acetylene glycol emulsifier and ethoxy alcohol emulsifier.
7. The plant-based fabric sterilization and odor elimination aerosol according to claim 6, wherein the emulsifier is selected from the group consisting of: one or two of tetramethyl decyne glycol and ethoxy propanol.
8. The plant-based fabric sterilization and odor elimination aerosol according to claim 1, wherein the propellant is selected from the group consisting of: compressed air, inert gas, liquefied petroleum gas, propane and butane, dimethyl ether, tetrafluoroethane and tetrafluoropropene.
9. The plant-based fabric sterilization and odor removal aerosol as claimed in claim 1, wherein the corrosion inhibitor is selected from the group consisting of: one or more than two of sodium benzoate, sodium nitrite, triethanolamine, morpholine and polyethoxylated ammonium.
10. A method for preparing the plant-based fabric sterilization and odor removal aerosol as claimed in any one of claims 1 to 9, which comprises the following steps:
1) weighing the bactericide, the deodorant, the emulsifier and the solvent, and uniformly mixing to obtain a group A material;
2) uniformly mixing the corrosion inhibitor and water to obtain a group B material;
3) adding the group B material into the group A material, uniformly mixing, and emulsifying uniformly to obtain a feed liquid;
4) and filling the feed liquid into an aerosol can, sealing a valve, and filling a propellant to obtain the plant type fabric degerming and deodorizing aerosol.
CN202110301699.5A 2021-03-22 2021-03-22 Plant type fabric degerming and odor removing aerosol and preparation method thereof Active CN113026354B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113678846A (en) * 2021-08-12 2021-11-23 广东莱雅新化工科技有限公司 Dry and comfortable type degerming and odor-removing carpet cleaning agent as well as preparation method and using method thereof

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CN106942305A (en) * 2017-03-09 2017-07-14 深圳市寰保化工科技有限公司 A kind of lawn plant deodorization smell removal liquid and its preparation method and application
CN110732036A (en) * 2019-11-26 2020-01-31 浙江绿岛科技有限公司 deodorizing plant extract fragrance spray and preparation method thereof
JP2021040701A (en) * 2019-09-06 2021-03-18 ライオン株式会社 Deodorant composition

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Publication number Priority date Publication date Assignee Title
CN106942305A (en) * 2017-03-09 2017-07-14 深圳市寰保化工科技有限公司 A kind of lawn plant deodorization smell removal liquid and its preparation method and application
CN106860895A (en) * 2017-04-01 2017-06-20 江苏大学 A kind of in-car cooling sterilizing environmental protection aerosol and preparation method thereof
JP2021040701A (en) * 2019-09-06 2021-03-18 ライオン株式会社 Deodorant composition
CN110732036A (en) * 2019-11-26 2020-01-31 浙江绿岛科技有限公司 deodorizing plant extract fragrance spray and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113678846A (en) * 2021-08-12 2021-11-23 广东莱雅新化工科技有限公司 Dry and comfortable type degerming and odor-removing carpet cleaning agent as well as preparation method and using method thereof

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