CN106860895A - A kind of in-car cooling sterilizing environmental protection aerosol and preparation method thereof - Google Patents

A kind of in-car cooling sterilizing environmental protection aerosol and preparation method thereof Download PDF

Info

Publication number
CN106860895A
CN106860895A CN201710211935.8A CN201710211935A CN106860895A CN 106860895 A CN106860895 A CN 106860895A CN 201710211935 A CN201710211935 A CN 201710211935A CN 106860895 A CN106860895 A CN 106860895A
Authority
CN
China
Prior art keywords
environmental protection
aerosol
dicotyledon
car cooling
hfc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710211935.8A
Other languages
Chinese (zh)
Inventor
李长生
朱丹宁
李剑锋
李川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu University
Original Assignee
Jiangsu University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu University filed Critical Jiangsu University
Priority to CN201710211935.8A priority Critical patent/CN106860895A/en
Publication of CN106860895A publication Critical patent/CN106860895A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06Aerosols
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02Amines; Quaternary ammonium compounds
    • A01N33/12Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/28Myrtaceae [Myrtle family], e.g. teatree or clove
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/012Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/013Deodorant compositions containing animal or plant extracts, or vegetable material
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/21Use of chemical compounds for treating air or the like
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/21Use of chemical compounds for treating air or the like
    • A61L2209/211Use of hydrogen peroxide, liquid and vaporous

Abstract

The invention discloses a kind of environment-friendly type aerosol lowered the temperature with sterilized dedusting suitable for in-car, the aerosol is prepared from by the component of following weight percentage:Dicotyledon 2~5wt% of bactericide, 9~23wt% of disinfectant, 0.5~5wt% of fire retardant, 0.5~1wt% of emulsifying agent, 0.5~1wt% of flavouring, 0.5~2wt% of excipient, 70~80wt% of propellant.The dicotyledon material of germicide includes the root of Dahurain angelica, the root of large-flowered skullcap, cloves, eucalyptus leaves, fan repeatedly grass.Solution, benzalkonium bromide of the disinfectant agent including hydrogen peroxide that concentration is 3%.The propellant is any two kinds in HFC 407C, HFC 410a, HFC 134a and HFA 227ea with 1:1 is mixed to prepare.The present invention compared with aerosol disinfectant product, possesses faster cooling rate, more powerful deodorization and sterilization effect, more environmentally friendly medicine component, smaller human body excitant with the existing cooling of in the market, and nontoxic non-combustible, using very high with the security of storage.

Description

A kind of in-car cooling sterilizing environmental protection aerosol and preparation method thereof
Technical field
It is special the present invention relates to a kind of environment-friendly type aerosol for in-car local cooling and deodorization and sterilization and preparation method thereof Be not be related to it is a kind of Chinese medicine is combined with chemical agent after obtain the production of aerosol of various practical functions.
Background technology
Under summer high temperature weather, it is Celsius that the outdoor temperature parked inside a period of time trunk of automobile can be up to 50 Degree, as long as such high temperature a dozen door openings just have blast of hot air and blow against one's face, sitting into in-car can feel vehicle-seat cushion and steering wheel Temperature boiling hot people high, even being lowered the temperature using on-board air conditioner is also required to even longer time more than ten minutes and could be down to in-car Comfort temperature:And the thermal balance of human body, water-electrolyte metabolism, digestive system and the circulatory system can all be affected in high temperature environments, For example there is water salt balance imbalance, pachyemia adverse reaction.On the other hand, under hot weather due in vehicle self-carrying jewelry dissipate The peculiar smell that sends and the peculiar smell that improper generation is cleaned after the frequent use of in-car air-conditioning, or under high temperature in-car bacteria breed with And human sweat's pollution can all cause the pollution of in-car air, people is allowed to feel that the impure and fresh initiation human body of air is uncomfortable.For above-mentioned Two kinds of problems, people would generally use existing some aerosol of cooling of in the market and air freshener products.
Common aerosol of cooling mainly uses some volatile heat absorptions under air such as water, ethanol, peppermint and borneol Material driven for automobile having carried out the disclosed one kind of such as CN1358818A of the local cooling in human body or enclosed environment Multiply the cooling agent of room, including water, fire retardant, propellant, ethanol and spices.Such as CN100453614C also discloses that one kind again Automobile cooling agent and its manufacture method, its component are also by spray including alcoholization white wine, ethyl acetate, dimethyl ether and essence etc. Spill the absorption heat energy such as alcohol and ethyl acetate and reach cooling purpose.But, the component in above-mentioned aerosol of cooling product is generally Flammable and explosive substance ethanol, dimethyl ether, ethyl acetate etc., have risk of explosion very high when depositing in high temperature environments, because This its security is further improved, and its local cooling's effect is also slightly not enough.
The air freshener that in the market is commonly used in the decomposition of sterilized and peculiar smell is broadly divided into industrial chemicals synthesis class, tradition Medical disinfecting category and natural product extraction class.Industrial chemicals synthesizes class aerosol while being carried out disinfection in being sprayed into air Easily cause secondary pollution and have that the duration is short, the low shortcoming of Disinfection Effect, or even some freshener products only add perfume (or spice) Smart composition carrys out covering smell without possessing disinfection effect.Conventional medical sterilization category aerosol disinfection effect is strong but past Toward with the intense irritation smell for being difficult to cover such as 84 thimerosals, glutaral disinfectant solution.Natural product extraction class aerosol Matter stabilization, safe and non-stimulating property but be limited to that unitary function, effect be common and extraction process cost and fail extensive production and application.
People are considered to the need for cooling in summer and deodorization and sterilization, and we are badly in need of developing and a kind of possess various functions Safety and environmental protection and the novel aerosol having no toxic side effect.
The content of the invention
For problem present in above-mentioned aerosol products, people's present invention lower the temperature to in-car under considering high temperature season With the demand of sterilizing, there is provided one kind had not only possessed fast cooling effect but also in-car peculiar smell and bacterium can be carried out at sterilizing Safe and efficient, the aerosol products that have no toxic side effect of reason.It is by have concurrently it is refrigerant cooling and suppress environment in common spoilage organisms The extracts of Chinese herbal medicine of effect, be aided with the nonirritant thimerosal of micro medical poisonless and can in atmosphere rapid vaporization heat absorption Non-combustible propellant mixture is made.
The technical solution adopted by the present invention is as follows:
A kind of in-car cooling sterilizing environmental protection aerosol, it is prepared from by weight percentage by following components:It is dicotyledonous 2~5wt% of bactericide, 9~23wt% of disinfectant, 0.5~5wt% of fire retardant, 0.5~1wt% of emulsifying agent, flavouring 0.5~1wt%, 0.5~2wt% of excipient, 70~80wt% of propellant;Wherein, the dicotyledon bactericide is by following The raw material of mass fraction is made:5~8 parts of the bark of official magnolia, 13~16 parts of the root of large-flowered skullcap, 8~12 parts of cloves, 22~24 parts of eucalyptus leaves, fan are repeatedly careless 14~20 parts.
The propellant is any two kinds in HFC-407C, HFC-410a, HFC-134a and HFA-227ea with 1:1 mixes Close.
The disinfectant be as obtained in 3% concentration of hydrogen peroxide aqueous solution mixing benzalkonium bromide, wherein, aquae hydrogenii dioxidi Solution accounts for the 80~90% of disinfectant gross mass, and benzalkonium bromide accounts for the 10~20% of the environment-friendly aerial fog agent gross mass.
The fire retardant is triphenylphosphine oxide.
The emulsifying agent is any one in Wool wax alcohols,ethoxylated, polyoxyethylene lanonol, monoglyceride.
The flavouring is Ergol.
The excipient is polyvinylpyrrolidone (pvp).
Technical scheme also includes a kind of preparation method of above-mentioned environment-friendly type aerosol, comprises the following steps:
(1) chopping is put into stainless cylinder of steel after each raw material in the dicotyledon bactericide is mixed by mass fraction In, ultrasound 2~3 hours, obtains first-time filtrate after the deionized water of 15 times of mixture quality of addition after filtering, adds compounding substances The deionized water of 5~10 times of amount obtains secondary filtrate to be cooked by slow fire 20~60 minutes after filtering;To addition phase homogeneity in raw material The deionized water of amount carries out 2 times and decocts 30~50 minutes, and filtering obtains three filtrates;
(2) three filtrates obtained by step (1) are mixed, concentration, solid dicotyledon is obtained after removing deionized water Bactericide;
(3) benzalkonium bromide of 1~2wt% is mixed into after the 8~21wt% of aqueous hydrogen peroxide solution for taking 3% concentration, according to Mass fraction adds solid dicotyledon bactericide, benzalkonium bromide, triphenylphosphine oxide, Wool wax alcohols,ethoxylated, polyoxyethylene Lanonol, monoglyceride, Ergol, polyvinylpyrrolidone, are fitted into tinplate inhalator jar after stirring, and are filled after sealing Load propellant and environment-friendly type aerosol is obtained.
Beneficial effects of the present invention are:
(1) rapid vaporization heat absorption makes together after the present invention mainly uses the propellant component in content to spurt into air The temperature of the content reclaimed water for ejecting is down to freezing point and is frozen and reaches the purpose of local cooling, and the extracts of Chinese herbal medicine for ejecting Prolonged overall cooling and sterilizing can be carried out to enclosed environment and human body.Existing cooling agent class product is contrasted, this Invention possess faster, duration longer cooling-down effect, and safety and environmental protection eliminates inflammable and explosive wind under hot environment Danger;The present invention existing air freshener class product of contrast, the toxic and side effect and excitant to human body is smaller, sterilizing, in Duration with peculiar smell is longer, and does not result in secondary pollution.
(2) present invention propellant mixture used is the nuisanceless refrigerant of safety and environmental protection, the propulsion refrigeration for possessing stabilization, It is lower in other propellant costs for using compared in the market.
Brief description of the drawings
Fig. 1 is internal pressure of the present invention and temperature profile;
Fig. 2 is agent material steam thermal conductivity factor under atmospheric pressure of the present invention.
Specific embodiment
The present invention is described in further details below in conjunction with specific embodiment, but protection scope of the present invention is not real Example is applied to be limited.
Embodiment 1
A kind of environment-friendly type aerosol for having in-car cooling and deodorization and sterilization effect concurrently, its composition is as follows with quality proportioning:
Wherein Chinese medicine sterilizing component is made up of the raw material of following mass fraction:
The preparation method of above-mentioned environment-friendly type aerosol is:
(1) 7 parts of the bark of official magnolia, 15 parts of the root of large-flowered skullcap, 12 parts of cloves, 22 parts of eucalyptus leaves, fan are changed to be shredded after 18 parts of grass mixes and is put into not In rust cylinder of steel, ultrasound 2~3 hours, obtains first-time filtrate after the deionized water of 15 times of mixture quality of addition after filtering, adds mixed The deionized water that 5~10 times of compound quality obtains secondary filtrate to be cooked by slow fire 30 minutes after filtering;It is identical to being added in raw material The deionized water of quality carries out 2 times and decocts 40 minutes, and filtering obtains three filtrates.
(2) three kinds of filtrates are mixed, concentration obtains solid dicotyledon bactericide after removing deionized water.
(3) the mixing such as benzalkonium bromide of 1wt% after the aqueous hydrogen peroxide solution 18wt% of 3% concentration is taken, is added wherein The solid dicotyledon bactericide of gained, and add triphenylphosphine oxide 1wt%, Wool wax alcohols,ethoxylated 1wt%, Benzyl Benzoate Ester 2wt%, polyvinylpyrrolidone 0.5wt%, are fitted into tinplate inhalator jar after stirring, and are filled into after sealing The propellant of 73.5wt% is obtained environment-friendly type aerosol.
Aerosol described in the present embodiment is more likely to effect of lowering the temperature.
Embodiment 2
A kind of environment-friendly type aerosol for having in-car cooling and deodorization and sterilization effect concurrently, its composition is as follows with quality proportioning:
Wherein Chinese medicine sterilizing component is made up of the raw material of following mass fraction:
The preparation method of above-mentioned environment-friendly type aerosol is:
(1) 8 parts of the bark of official magnolia, 15 parts of the root of large-flowered skullcap, 12 parts of cloves, 23 parts of eucalyptus leaves, fan are changed to be shredded after 16 parts of grass mixes and is put into not In rust cylinder of steel, ultrasound 2~3 hours, obtains first-time filtrate after the deionized water of 15 times of mixture quality of addition after filtering, adds mixed The deionized water that 5~10 times of compound quality obtains secondary filtrate to be cooked by slow fire 30 minutes after filtering;It is identical to being added in raw material The deionized water of quality carries out 2 times and decocts 40 minutes, and filtering obtains three filtrates.
(2) three kinds of filtrates are mixed, concentration obtains solid dicotyledon bactericide after removing deionized water.
(3) the mixing such as benzalkonium bromide of 2wt% after the aqueous hydrogen peroxide solution 21wt% of 3% concentration is taken, is added wherein The solid dicotyledon bactericide of gained, and add triphenylphosphine oxide 1wt%, Wool wax alcohols,ethoxylated 1wt%, Benzyl Benzoate Ester 1wt%, polyvinylpyrrolidone 2wt%, are fitted into tinplate inhalator jar after stirring, and are filled into 67wt%'s after sealing Propellant is obtained environment-friendly type aerosol.
Aerosol described in the present embodiment is more likely to sterilizing effect.
Security is tested with functional effect
Security is carried out for the environment-friendly type aerosol described in above-described embodiment 1-2 to be tested with functional effect, test event For five include internal pressure (25 DEG C/50 DEG C), Oral toxicity, skin irritatin, content flammability and venomous injurant quality detection.
(1) internal pressure test:Environment-friendly type aerosol sample described in above-described embodiment 1-2 is respectively placed in 25 DEG C and 50 DEG C In water bath with thermostatic control (temperature-controlled precision ± 1 DEG C), make water logging not have can body to soak 1 hour, put on pachydermia gloves, shake sample 5 times will be pressed Power table (band special joint) import alignment sample valve rod, the upright placement of sample is firmly compressed, and treats that gauge hand is stablized under postscript Pressure gauge reading, retest is averaged for three times.
Internal pressure is 0.69MPa at 25 DEG C of the environment-friendly type aerosol that test result shows described in above-described embodiment 1-2, at 50 DEG C It is 1.21MPa, pressure data is in the range of tinplate inhalator jar ultimate pressure capacity.
(2) Oral toxicity test:Aerosol sample contents are taken out, the carboxylic of 2 times of water of quality of content and 2wt% is added Methylcellulose is mixed and is made suspension.20 healthy adult mouse (18g~22g) are chosen, is divided into two groups every group each ten Male and female half and half.The sample suspension of phase homogenous quantities is once poured into oral administration by gavage, gavage capacity is 20mL/Kg (unit bodies The quality of reclosing test sample), observed and recorded contamination situation and the mouse in the observation period are poisoned and death condition.
Test result shows that the environment-friendly type aerosol described in above-described embodiment 1-2 is nontoxic.
(3) skin irritatin test:Only tested from healthy adult white rabbit 4, by white rabbit back backbone both sides before experiment Hair is cut, and does not damage epidermis, the left and right each about 3cm × 3cm of unhairing scope.Aerosol sample contents 0.5mL is taken directly to be applied to On any side skin in left and right, then covered with two layers of gauze and one layer of glassine paper, then fixed with bandage.Yarn is opened after 4 hours Cloth removes aerosol sample, smears position dermoreaction as controlled observation using opposite side skin behind 1 hour and 4 hours respectively And record.
Test result shows environment-friendly type aerosol described in above-described embodiment 1-2 without skin irritation.
(4) content flammability test:Using Cleveland opening agar diffusion method, take out aerosol sample contents 200mL and put In beaker, insert thermometer, light experiment flame heating sample, control programming rate be 14 (DEG C/min)~17 (DEG C/ min).Slow down firing rate when reaching 56 DEG C, control programming rate for 5 (DEG C/min)~6 (DEG C/min).Must not in process of the test Arbitrarily walk about or breathe near experiment beaker, in case disturbance sample steam.When temperature reaches 56 DEG C, start with experiment flame Swept above sample and drawn, swept with smooth, continuous action and drawn, temperature often raises 2 DEG C sweeps and draw one time, and flame passes through beaker institute every time Take time about 1s.When sample liquid level take up an official post what a little there is scintillation when, the reading of immediate record thermometer, as observation dodge Point.The speed for measuring and continuing after flash-point with 5 (DEG C/min)~6 (DEG C/min) heats up, and temperature often raises 2 DEG C sweeps and draw one time, until Sample energy sustained combustion of fighting no less than 5s, records burning-point of this temperature as sample.
Test result shows environment-friendly type aerosol described in above-described embodiment 1-2 without burning-point.
(5) venomous injurant quality detection:
Test result shows that the environment-friendly type aerosol described in above-described embodiment 1-2 is free of 1. chlorofluorocarbon compounds (CFCS) The class material 2. ODS such as methyl chloroform, carbon tetrachloride (ODS) class banned substance 3. benzene,toluene,xylene, formaldehyde And its polymer of formaldehyde.
Fig. 1 is internal pressure of the present invention and temperature profile;Fig. 2 is agent material steam thermal conductivity factor under atmospheric pressure of the present invention;By scheming 1st, Fig. 2 can be seen that HFC-134a pressure changes at different temperatures and steam thermal conductivity factor are all more stable, the liter of temperature It is high it is approximate with the change of pressure and steam thermal conductivity factor be directly proportional, without mutation.

Claims (8)

1. a kind of in-car cooling sterilizing environmental protection aerosol, it is characterised in that it be prepared by weight percentage by following components and Into:Dicotyledon 2~5wt% of bactericide, 9~23wt% of disinfectant, 0.5~5wt% of fire retardant, emulsifying agent 0.5~ 1wt%, 0.5~1wt% of flavouring, 0.5~2wt% of excipient, 70~80wt% of propellant;Wherein, the dicotyledon Bactericide is made up of the raw material of following mass fractions:5~8 parts of the bark of official magnolia, 13~16 parts of the root of large-flowered skullcap, 8~12 parts of cloves, eucalyptus leaves 22~ 24 parts, fan change grass 14~20 parts.
2. a kind of in-car cooling sterilizing environmental protection aerosol according to claim 1, it is characterised in that the propellant is Any two kinds in HFC-407C, HFC-410a, HFC-134a and HFA-227ea are with 1:1 mixing.
3. a kind of in-car cooling sterilizing environmental protection aerosol according to claim 1, it is characterised in that the disinfectant be by Obtained in 3% concentration of hydrogen peroxide aqueous solution mixing benzalkonium bromide, wherein, aqueous hydrogen peroxide solution accounts for the 80 of disinfectant gross mass ~90%, benzalkonium bromide accounts for the 10~20% of the environment-friendly aerial fog agent gross mass.
4. a kind of in-car cooling sterilizing environmental protection aerosol according to claim 1, it is characterised in that the fire retardant is three Phenyl phosphine oxide.
5. a kind of in-car cooling sterilizing environmental protection aerosol according to claim 1, it is characterised in that the emulsifying agent is poly- Any one in oxygen ethene lanolin, polyoxyethylene lanonol, monoglyceride.
6. a kind of in-car cooling sterilizing environmental protection aerosol according to claim 1, it is characterised in that the flavouring is benzene Benzyl formate.
7. a kind of in-car cooling sterilizing environmental protection aerosol according to claim 1, it is characterised in that the excipient is poly- Vinylpyrrolidone (pvp).
8. the preparation method of a kind of in-car cooling sterilizing environmental protection aerosol as described in claim 1~7, it is characterised in that bag Include following steps:
(1) shredded after each raw material in the dicotyledon bactericide is mixed by mass fraction and be put into stainless cylinder of steel, plus Enter ultrasound 2~3 hours after the deionized water of 15 times of mixture quality, after filtering first-time filtrate, add mixture quality 5~ 10 times of deionized water obtains secondary filtrate to be cooked by slow fire 20~60 minutes after filtering;To addition phase homogenous quantities in raw material Deionized water carries out 2 times and decocts 30~50 minutes, and filtering obtains three filtrates;
(2) three filtrates obtained by step (1) are mixed, concentration, the sterilization of solid dicotyledon is obtained after removing deionized water Agent;
(3) benzalkonium bromide of 1~2wt% is mixed into after the 8~21wt% of aqueous hydrogen peroxide solution for taking 3% concentration, according to quality Number adds solid dicotyledon bactericide, benzalkonium bromide, triphenylphosphine oxide, Wool wax alcohols,ethoxylated, polyoxyethylene wool Alcohol, monoglyceride, Ergol, polyvinylpyrrolidone, are fitted into tinplate inhalator jar after stirring, and are filled into after sealing Propellant is obtained environment-friendly type aerosol.
CN201710211935.8A 2017-04-01 2017-04-01 A kind of in-car cooling sterilizing environmental protection aerosol and preparation method thereof Pending CN106860895A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710211935.8A CN106860895A (en) 2017-04-01 2017-04-01 A kind of in-car cooling sterilizing environmental protection aerosol and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710211935.8A CN106860895A (en) 2017-04-01 2017-04-01 A kind of in-car cooling sterilizing environmental protection aerosol and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106860895A true CN106860895A (en) 2017-06-20

Family

ID=59159828

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710211935.8A Pending CN106860895A (en) 2017-04-01 2017-04-01 A kind of in-car cooling sterilizing environmental protection aerosol and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106860895A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109673639A (en) * 2018-12-20 2019-04-26 东元科技有限公司 A kind of interior sterilizing environmental protection aerosol and preparation method thereof that cools down
CN113026354A (en) * 2021-03-22 2021-06-25 中山榄菊日化实业有限公司 Plant type fabric degerming and odor removing aerosol and preparation method thereof
CN114027299A (en) * 2021-12-09 2022-02-11 江苏瑞安汽车实业有限公司 Atomizing and refreshing bactericide for internal circulation space of air conditioner and preparation method of bactericide

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101296710A (en) * 2005-11-01 2008-10-29 雷克特本克斯尔(英国)有限公司 Aerosol composition and method
CN104094977A (en) * 2013-04-15 2014-10-15 单宝华 Composition with insect-expelling sterilization disinfection effects and application thereof
CN105079100A (en) * 2015-07-08 2015-11-25 福建省雾精灵环境科技有限公司 Cooling spray
CN108849891A (en) * 2018-09-10 2018-11-23 美国太平洋大桥股份有限公司 A kind of air sterilizing disinfectant

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101296710A (en) * 2005-11-01 2008-10-29 雷克特本克斯尔(英国)有限公司 Aerosol composition and method
CN104094977A (en) * 2013-04-15 2014-10-15 单宝华 Composition with insect-expelling sterilization disinfection effects and application thereof
CN105079100A (en) * 2015-07-08 2015-11-25 福建省雾精灵环境科技有限公司 Cooling spray
CN108849891A (en) * 2018-09-10 2018-11-23 美国太平洋大桥股份有限公司 A kind of air sterilizing disinfectant

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘强等: "《中药新产品开发》", 31 March 2013 *
刘福昌等: "《天然药物化学》", 28 February 2013 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109673639A (en) * 2018-12-20 2019-04-26 东元科技有限公司 A kind of interior sterilizing environmental protection aerosol and preparation method thereof that cools down
CN113026354A (en) * 2021-03-22 2021-06-25 中山榄菊日化实业有限公司 Plant type fabric degerming and odor removing aerosol and preparation method thereof
CN114027299A (en) * 2021-12-09 2022-02-11 江苏瑞安汽车实业有限公司 Atomizing and refreshing bactericide for internal circulation space of air conditioner and preparation method of bactericide
CN114027299B (en) * 2021-12-09 2023-02-28 江苏瑞安汽车实业有限公司 Atomizing and refreshing bactericide for internal circulation space of air conditioner and preparation method of bactericide

Similar Documents

Publication Publication Date Title
CN106860895A (en) A kind of in-car cooling sterilizing environmental protection aerosol and preparation method thereof
CN106310326A (en) Air freshener and preparation method thereof
CN104094977B (en) A kind of composition and its application with expelling parasite sterilization and disinfection effect
CA2567601A1 (en) Production and use of a gaseous vapor disinfectant
CN105999342A (en) Water-based air freshening aerosol and preparation method thereof
CN101954107B (en) Solid aromatic sleep aid and preparation method thereof
CN107007863A (en) A kind of environmentally friendly air freshener of degerming smelly eliminating and preparation method thereof
CN109675081A (en) A kind of Fruity type natural plants Vehicular aromatherapy essential oil and preparation method thereof
CN101810203A (en) Solid mosquito repelling agent and preparation method thereof
AU691791B2 (en) Composition, apparatus and method for providing a supply of water-based cool mixture
CN107439611A (en) A kind of safety mosquito-repellent and its application method and mosquito repellent method
CN113710329A (en) Personal care compositions
CN108048047A (en) A kind of ice pellets type aerosol of cooling
US6060045A (en) Vitaminized air freshener and room deodorizer pad
TW460293B (en) External skin-care composition
EP3946223A1 (en) Antiperspirant and deodorant compositions
KR20140060424A (en) Aromatheraphy solution oil anti-bac composition and processing make the same
JP6099888B2 (en) Pest repellent aerosol agent for human body, and pest repellent and cooling method using the same.
CN106212462B (en) Herbal mixture air sanitizer and preparation method thereof and application method
CN104758218A (en) Rosemary perfume
JP2818777B2 (en) Full injection aerosol products
US20040071797A1 (en) Method and formulation for suppressing mold
CN108815547A (en) A kind of preparation method of agalloch eaglewood air freshener
CN102604595B (en) Environment-friendly self-disinfection money counting finger wetting agent and manufacturing method thereof
JP2012232921A (en) Smoking type insecticide, smoking type insecticidal device, and insecticidal method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170620