CN113025438B - Sterilization and virus killing toilet cleaner - Google Patents
Sterilization and virus killing toilet cleaner Download PDFInfo
- Publication number
- CN113025438B CN113025438B CN202110275557.6A CN202110275557A CN113025438B CN 113025438 B CN113025438 B CN 113025438B CN 202110275557 A CN202110275557 A CN 202110275557A CN 113025438 B CN113025438 B CN 113025438B
- Authority
- CN
- China
- Prior art keywords
- parts
- toilet cleaner
- slow release
- toilet
- active cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
- C11D3/323—Amides; Substituted amides urea or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a sterilizing and virus-killing toilet cleaner, and relates to the field of toilet cleaning products, wherein the toilet cleaner comprises a blue component and a white component; the blue component comprises anhydrous sodium sulphate, active cleaning factors, dyes, slow release agents and spices; the white component comprises anhydrous sodium sulphate, active cleaning factor, bactericide, slow release agent and perfume. The toilet cleaner has good visual sense, can keep the color of the water bloom bright for a long time, and optimizes the components and the content of the components, so that the toilet cleaner has the capacity of efficiently sterilizing, killing viruses and removing dirt.
Description
Technical Field
The invention relates to the field of toilet cleaning products, in particular to a sterilizing and virus-killing toilet cleaner.
Background
The toilet cleaner is a cleaning product which has cleaning, deodorizing and degerming effects on a toilet bowl, can effectively decompose stubborn dirt in a toilet basin, can kill hidden bacteria in the toilet basin simultaneously, achieves the purposes of deodorizing and sterilizing, only needs to put the toilet cleaner into a toilet water tank during use, and can achieve certain effects when flushing water every time, and is convenient and sanitary.
Chinese patent CN108300598A discloses a slow-release long-acting solid toilet cleaner and a preparation method thereof, wherein the toilet cleaner is prepared from the following components in parts by weight: 50-60 parts of anhydrous sodium sulphate, 5-10 parts of food-grade carboxymethyl cellulose, 3-6 parts of hydroxyethyl cellulose ether, 3-6 parts of PVA, 5-10 parts of baking soda, 5-10 parts of sodium dodecyl benzene sulfonate, 3-5 parts of surfactant AOS, 3-5 parts of pigment, 0.8-1 part of kasong, 0.05-0.1 part of essence, 0.05-0.1 part of terpineol and 9-10 parts of water.
Chinese patent CN105002025B discloses a long-acting biological toilet cleaner and a preparation method thereof, the toilet cleaner comprises a soap base, anhydrous sodium sulfate, sulfonic acid, sodium bicarbonate, fatty alcohol-polyoxyethylene ether sodium sulfate, carboxymethyl cellulose, modified starch, pigment, essence and biological deodorant bacteria, compared with the prior art, the toilet cleaner has the effects of deodorization, descaling, pipeline dredging and sterilization, and has a long service life which is as long as more than 45 days. The main purposes of the two patents are to improve the slow release effect of the toilet cleaner and prolong the service life, but various raw materials used in the toilet cleaner, such as sodium dodecyl benzene sulfonate, have poor hard water resistance, the dirt-removing capacity is reduced along with the hardness of water, and the toilet cleaner is difficult to reach higher concentration due to the slow release effect of the products for stubborn stains, bacteria, viruses and the like, so that a certain effect is realized in time. Meanwhile, the product also has the problems that the raw materials are complex, part of the raw materials are difficult to transport and store, and the raw materials are difficult to biodegrade, so that water pollution is caused after the product is used, and the like.
Aiming at the problems of poor sterilization and virus killing effects, complex raw materials, toxic and harmful substances contained in the toilet cleaning product in the prior art, subsequent water pollution and the like, an environment-friendly toilet cleaning product is urgently needed to be found, so that the product has the capability of efficiently sterilizing and killing viruses.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides a sterilizing and virus-killing toilet cleaner which has good visual sense and sense, can keep the color of water flowers bright for a long time, and ensures that the toilet cleaner has the capability of efficiently sterilizing and killing viruses through optimizing the components and the content.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
the invention provides a toilet cleaner, which comprises a blue component and a white component;
the blue component comprises anhydrous sodium sulphate, active cleaning factors, dyes, slow release agents and spices;
the white component comprises anhydrous sodium sulphate, active cleaning factor, bactericide, slow release agent and perfume.
Further, the toilet cleaner comprises, by weight, 50-65 parts of anhydrous sodium sulphate, 10-20 parts of active cleaning factors, 3-8 parts of dye, 12-16 parts of slow release agent and 0.5-2 parts of perfume; the white component comprises 52-68 parts of anhydrous sodium sulphate, 8-16 parts of active cleaning factor, 0.5-3 parts of bactericide, 10-18 parts of slow release agent and 0.5-2 parts of perfume.
Preferably, the toilet cleaner comprises, by weight, 60 parts of anhydrous sodium sulphate, 15 parts of active cleaning factors, 5 parts of dye, 15 parts of slow release agent and 1 part of spice; the white component comprises 58 parts of anhydrous sodium sulphate, 12 parts of active cleaning factor, 1 part of bactericide, 12 parts of slow release agent and 1 part of perfume.
Further, the weight ratio of the blue component to the white component is 2-3: 1-2; preferably 1: 1.
Further, the bactericide is triclocarban and/or sodium benzoate. Preferably, the bactericide is triclocarban and sodium benzoate in a weight ratio of 1: 1.
Further, the active cleaning factors are sodium dodecyl benzene sulfonate, alpha-olefin sulfonate and epicatechin.
Preferably, the weight ratio of the sodium dodecyl benzene sulfonate, the alpha-olefin sulfonate and the epicatechin is 3-5:4-8: 0.2-0.3; preferably 2:3: 0.1.
Further, the dye is blue powder, and the type of the perfume is adjusted according to actual requirements.
Further, the slow release agent is carboxymethyl cellulose.
Furthermore, the weight ratio of the total weight of the active cleaning factors in the blue component and the white component to the weight of the bactericide is 20-40: 0.5-3. Preferably 27: 1.
The invention also provides a preparation method of the toilet cleaner, which comprises the following steps: mixing materials, extruding and bonding, cutting into pieces, packaging by using a water-soluble film and sealing by using a roll film.
The technical effects obtained by the invention are as follows:
1. the toilet cleaner is divided into a blue component and a white component in appearance, has good visual sense, can keep the color of the water bloom bright for a long time, does not contain harmful substances, is more environment-friendly, and has the capability of efficiently sterilizing and killing viruses through optimization of the components and the content; researches find that the addition of trace epicatechin is beneficial to promoting the improvement of the sterilization rate and the urea removal rate, and besides a certain sterilization effect of the epicatechin, the epicatechin is matched with sodium dodecyl benzene sulfonate and alpha-olefin sulfonate to be used under a certain proportion condition, so that the integral cleaning effect of the product is also obviously enhanced in addition to the antibacterial effect; in addition, the cleaning factor and the bactericide are matched for use, so that the using amount of the bactericide can be effectively reduced, and higher antibacterial decontamination level can be kept to a certain extent and even realized.
2. The toilet cleaner has the advantages that the flushing frequency is 300 times, the concentration of high-concentration cleaning factors is greatly improved in 5-7 days, the dirt-removing capacity is higher, the flushed water can form a layer of lubricating protective film on the surface of a toilet, the long-acting antibacterial effect can be effectively realized, and urea, uric acid and the like are further degraded and decontaminated.
Detailed Description
It should be noted that the raw materials used in the present invention are all common commercial products, and thus the sources thereof are not particularly limited.
Example 1
A toilet cleaner comprises a blue component and a white component; the blue component comprises 50 parts of anhydrous sodium sulphate, 10 parts of active cleaning factor, 3 parts of dye, 12 parts of slow release agent and 0.5 part of perfume by weight; the white component comprises 52 parts of anhydrous sodium sulphate, 8 parts of active cleaning factor, 0.5 part of bactericide, 10 parts of slow release agent and 0.5 part of perfume. Wherein the weight ratio of the blue component to the white component is 2: 1. The active cleaning factors are sodium dodecyl benzene sulfonate, alpha-olefin sulfonate and epicatechin in a weight ratio of 3:4: 0.2; the bactericide is triclocarban and sodium benzoate with the weight ratio of 1: 1; the dye is blue powder; the slow release agent is carboxymethyl cellulose.
Example 2
A toilet cleaner comprises a blue component and a white component; the blue component comprises 65 parts of anhydrous sodium sulphate, 20 parts of active cleaning factors, 8 parts of dye, 16 parts of slow release agent and 2 parts of spice according to parts by weight; the white component comprises 68 parts of anhydrous sodium sulphate and 16 parts of
Active cleaning factor, 3 parts of bactericide, 18 parts of slow release agent and 2 parts of perfume. The weight ratio of the blue component to the white component was 3: 2. The active cleaning factors comprise sodium dodecyl benzene sulfonate, alpha-olefin sulfonate and epicatechin in a weight ratio of 5:8: 0.3; the bactericide is triclocarban and sodium benzoate with the weight ratio of 1: 1; the dye is blue powder; the slow release agent is carboxymethyl cellulose.
Example 3
A toilet cleaner comprises a blue component and a white component; the blue component comprises 60 parts of anhydrous sodium sulphate, 15 parts of active cleaning factor, 5 parts of dye, 15 parts of slow release agent and 1 part of perfume by weight; the white component comprises 58 parts of anhydrous sodium sulphate and 12 parts of sodium sulphate
Active cleaning factor, 1 part of bactericide, 12 parts of slow release agent and 1 part of perfume. The weight ratio of the blue component to the white component is 1: 1. The active cleaning factors comprise sodium dodecyl benzene sulfonate, alpha-alkenyl sulfonate and epicatechin with the weight ratio of 2:3: 0.1; the bactericide is triclocarban and sodium benzoate with the weight ratio of 1: 1; the dye is blue powder; the slow release agent is carboxymethyl cellulose.
Comparative example 1
The difference from the embodiment 1 is that the toilet cleaner comprises, by weight, 48 parts of anhydrous sodium sulphate, 22 parts of active cleaning factor, 2 parts of dye, 17 parts of slow release agent and 0.3 part of perfume; the white component comprises 50 parts of anhydrous sodium sulphate and 18 parts of
Active cleaning factor, 0.3 part of bactericide, 20 parts of slow release agent and 0.3 part of perfume.
Comparative example 2
The only difference from example 1 is that the weight ratio of sodium dodecylbenzenesulfonate, alpha-alkenylsulfonate and epicatechin is 2:9:0.1 (the total weight of the three is identical to example 1).
Comparative example 3
The only difference from example 1 is that the weight ratio of the total weight of active cleaning factor and biocide in the blue and white components was 9:2 (the total weight of both was identical to example 1).
Comparative example 4
The toilet cleaner prepared in example 2 in Chinese patent CN 108300598A.
The preparation methods and all parameters of the toilet cleaners in the above examples 1 to 3 and comparative examples 1 to 4 are all consistent, and the method specifically comprises the following steps: stirring, extruding and bonding, cutting into pieces, packaging with a water-soluble film and sealing with a roll film.
First, the sterilization capability test of the toilet cleaner
The test method comprises the following steps: after the toilet cleaners in examples 1-3 and comparative examples 1-4 which were washed for 100 times were immersed in water (the weight ratio of the total weight of the toilet cleaner to water was 1:100) for 1 hour, 5mL of the above-mentioned immersion liquid was taken, 0.5mL of suspension of escherichia coli and shigella dysenteriae bacteria was added thereto, after uniform mixing, after 30min, sampling was performed to determine the viable counts corresponding to the two strains in the mixed liquid, and a blank control group which was not immersed in the toilet cleaner was additionally provided with the bactericidal rate, and the viable counts corresponding to the two strains were determined, wherein the bactericidal rate was (the viable count of the blank control group-the viable count in each example)/the viable count of the blank control group x 100%, and the results were recorded in table 1.
TABLE 1
As can be seen from table 1, the bactericidal rate of the toilet cleaner of the present invention against escherichia coli and shigella can still be maintained at a high level after 100 times of use, and when the composition and the corresponding content of the toilet cleaner of the present invention are changed, the bactericidal rate of the final product will be reduced to a certain extent. In particular, in comparison, the toilet cleaner in comparative example 4 has a superior slow-release effect according to the description, but the antibacterial effect of the product is drastically reduced after 100 times of use, and is significantly inferior to the present invention.
Secondly, the urea degradation capability of the toilet cleaner
The products in normal human urine are mainly urea and a small amount of uric acid, and only the degradation capability of the toilet cleaner on the urea is examined at this time. The specific test method comprises the following steps: the percentage degradation of urea after the toilet cleaners in examples 1-3 and comparative examples 1-4 were used for the first time and after 200 times of flushing at 25 ℃ was measured, i.e. after the toilet cleaners were immersed in water (the weight ratio of the total weight of the toilet cleaners to the weight of water was 1:100) for 1 hour, the above-mentioned immersion liquid was used to prepare a solution with an initial urea concentration of 20mg/L, after standing for 2 hours, the change in urea content was detected, the urea degradation rate was calculated, and the results were counted in table 2.
TABLE 2
As can be seen from Table 2, the toilet cleaner of the present invention has excellent urea degrading ability, and the urea degrading ability is more than 60% when the toilet cleaner is used for the first time. After the toilet cleaner is washed 200 times, the degradation capability of the toilet cleaner for urea is reduced to a certain extent, but the level can be kept high overall. In contrast, the urea degradation capacity of the product of the comparative example was less than satisfactory after 200 flushes. The product in comparative example 4 has excellent urea degradation ability in the first use, but the degradation effect is obviously poor after 200 uses although the product still has certain effect.
In addition, experimental research shows that the frequency of using and flushing the toilet cleaner can reach 300 times, and the toilet cleaner is particularly influenced by water temperature, the number of using population, using habits and the like.
Finally, it should be noted that the above-mentioned contents are only used for illustrating the technical solutions of the present invention, and not for limiting the protection scope of the present invention, and that the simple modifications or equivalent substitutions of the technical solutions of the present invention by those of ordinary skill in the art can be made without departing from the spirit and scope of the technical solutions of the present invention.
Claims (5)
1. The utility model provides a clean lavatory is precious which characterized in that: comprises a blue component and a white component;
the blue component comprises 50-65 parts of anhydrous sodium sulphate, 10-20 parts of active cleaning factors, 3-8 parts of dye, 12-16 parts of slow release agent and 0.5-2 parts of perfume;
the white component comprises 52-68 parts of anhydrous sodium sulphate, 8-16 parts of active cleaning factor, 0.5-3 parts of bactericide, 10-18 parts of slow release agent and 0.5-2 parts of spice;
the active cleaning factors are sodium dodecyl benzene sulfonate, alpha-olefin sulfonate and epicatechin with the weight ratio of 3-5:4-8: 0.2-0.3; the weight ratio of the total weight of the active cleaning factors in the blue component and the white component to the bactericide is 20-40: 0.5-3.
2. The device of claim 1, wherein: the weight ratio of the blue component to the white component is 2-3: 1-2.
3. The device of claim 1, wherein: the bactericide is triclocarban and/or sodium benzoate.
4. The device of claim 1, wherein: the slow release agent is carboxymethyl cellulose.
5. The method for preparing a toilet cleaner according to any one of claims 1 to 4, wherein: the method comprises the following steps: mixing materials, extruding and bonding, cutting into pieces, packaging by using a water-soluble film and sealing by using a roll film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110275557.6A CN113025438B (en) | 2021-03-15 | 2021-03-15 | Sterilization and virus killing toilet cleaner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110275557.6A CN113025438B (en) | 2021-03-15 | 2021-03-15 | Sterilization and virus killing toilet cleaner |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113025438A CN113025438A (en) | 2021-06-25 |
| CN113025438B true CN113025438B (en) | 2022-06-10 |
Family
ID=76469087
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110275557.6A Active CN113025438B (en) | 2021-03-15 | 2021-03-15 | Sterilization and virus killing toilet cleaner |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113025438B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5759974A (en) * | 1994-11-07 | 1998-06-02 | Henkel Kommanditgesellschaft Auf Aktien | Block-form cleaners for flush toilets |
| CN102051274A (en) * | 2009-11-10 | 2011-05-11 | 上海卫安生物科技有限公司 | Solid water-saving toilet cleaner |
| CN106635485A (en) * | 2016-12-23 | 2017-05-10 | 叶宗瑞 | Toilet sterilizing deodorant and preparation method thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102260598B (en) * | 2011-06-24 | 2013-04-24 | 东莞爱屋氏日用品有限公司 | Sterilizing toilet cleaning block |
| CN102888294A (en) * | 2012-09-26 | 2013-01-23 | 启东市东洲仪表有限公司 | Solid detergent for water tank of toilet |
| CN104762141B (en) * | 2014-01-05 | 2018-10-23 | 上海弥乐化工新材料有限公司 | A kind of solid toilet cleaning agent and preparation method thereof |
| CN205170797U (en) * | 2015-12-03 | 2016-04-20 | 东莞爱屋氏日用品有限公司 | Not dirty hand cleaning toilet piece |
| CN108300598A (en) * | 2018-03-03 | 2018-07-20 | 上海弥乐化工新材料有限公司 | A kind of slow release long-acting solid toilet cleaning agent and preparation method thereof |
| CN110437940A (en) * | 2019-09-07 | 2019-11-12 | 阜阳洁平日化有限公司 | A kind of high-efficiency environment friendly deodorization agent for toilet and preparation method thereof |
| CN112175751A (en) * | 2020-01-20 | 2021-01-05 | 广州市晋康科技发展有限公司 | Solid toilet cleaning agent and preparation method thereof |
-
2021
- 2021-03-15 CN CN202110275557.6A patent/CN113025438B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5759974A (en) * | 1994-11-07 | 1998-06-02 | Henkel Kommanditgesellschaft Auf Aktien | Block-form cleaners for flush toilets |
| CN102051274A (en) * | 2009-11-10 | 2011-05-11 | 上海卫安生物科技有限公司 | Solid water-saving toilet cleaner |
| CN106635485A (en) * | 2016-12-23 | 2017-05-10 | 叶宗瑞 | Toilet sterilizing deodorant and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113025438A (en) | 2021-06-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1423497B1 (en) | Thickened toilet bowl cleaner | |
| AU2004213626B2 (en) | Hard surface cleaning compositions | |
| AU2002361849A1 (en) | Thickened toilet bowl cleaner | |
| CN109666545B (en) | Efficient toilet cleaning foam aerosol and preparation method thereof | |
| EP1539906A1 (en) | Acidic hard surface cleaners | |
| ZA200505343B (en) | Hard surface cleaning compositions | |
| EP1597346B1 (en) | Hard surface cleaning compositions | |
| JP2009173768A (en) | Sterilizing detergent composition for toilet seat, sterilizing cleaning material containing the same, and sterilizing cleaning method using them | |
| CN108739857A (en) | A kind of farm's foam-type disinfectant and the preparation method and application thereof | |
| CN105112182A (en) | Normal-pressure foam-type toilet cleaning agent and preparation method thereof | |
| WO2003083028A2 (en) | Cleaning and desinfecting herbal compositions and their preparation | |
| CN101120078A (en) | Aqueous liquid bleach compositions | |
| CN113025438B (en) | Sterilization and virus killing toilet cleaner | |
| EP1597345B1 (en) | Hard surface cleaning compositions | |
| EP0912705A1 (en) | Lavatory cleansing compositions | |
| WO2020234597A1 (en) | Detergent formulations having enhanced germ removal efficacy | |
| JP7436201B2 (en) | Disinfectant | |
| JP2012092320A (en) | Biofilm removing agent, composition for removing biofilm, and method for removing biofilm | |
| KR20110018201A (en) | Urinary calculus remover of toilet purposes | |
| JP6652484B2 (en) | Cleaning composition for hard surfaces | |
| CN107372627A (en) | A kind of drinking water barrel cleaning and sterilization agent of Environmental Safety | |
| WO2023180053A1 (en) | A solid hard surface cleaning composition | |
| JP2001200291A (en) | Solid agent for toilet cleaning | |
| JP2021107345A (en) | Disinfectant | |
| CN117821176A (en) | Kitchen wet tissue compound liquid and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |