CN117821176A

CN117821176A - Kitchen wet tissue compound liquid and preparation method thereof

Info

Publication number: CN117821176A
Application number: CN202311828519.4A
Authority: CN
Inventors: 黄凌; 刘荣; 严进; 吴杰
Original assignee: Nanjing Hechuang Material Technology Co ltd
Current assignee: Nanjing Hechuang Material Technology Co ltd
Priority date: 2023-12-27
Filing date: 2023-12-27
Publication date: 2024-04-05

Abstract

The invention provides a kitchen wet tissue compound liquid and a preparation method thereof, wherein the finished product of the compound liquid can remove hydrophilic and lipophilic stains, and the compatibility of the components is good; the main point is that the antibacterial and bactericidal agent has excellent antibacterial and bactericidal effects on bacteria, fungi, mould and the like, has the advantage of quick killing capability, can inhibit the formation of microorganisms under the condition of extremely low concentration, has long-acting antibacterial effect, is low in corrosion and nonirritant, does not damage the surface of kitchen ware, and is friendly to contact with skin.

Description

Kitchen wet tissue compound liquid and preparation method thereof

Technical Field

The invention belongs to the field of daily chemicals, and relates to a kitchen wet tissue compound liquid and a preparation method thereof.

Background

The kitchen environment is subjected to oil accumulation due to specific use conditions, on one hand, the visual cleanliness is affected, on the other hand, the kitchen residue is adhered to the greasy oil, or the freshness of the food is affected by contact friction when the food is treated, so that the oil treatment is an important step for kitchen cleaning; in addition, in the kitchen, common dirt accumulation, greasy dirt removal and food material blood dirt are adopted, and the purposes of neatness, such as wiping cloth wiping, are only achieved visually by adopting the traditional and common treatment and cleaning means, but the modern concept is clean and tidy, and besides the surface dirty cleaning, the deep sterilization requirement is also required. The common wiping rag is difficult to do and laborious, while the filled cleaning liquid is portable, but the residual stain needs to be washed and wiped; compared with the cleaning solution added after the cleaning cloth is soaked, the kitchen cleaning cloth is only required to be smeared lightly, and the kitchen cleaning cloth is suitable for the fast-paced life style of modern young people. In addition, the kitchen wet tissue can disinfect the surface of an object while cleaning oil stains, thereby creating a clean and clean kitchen environment.

At present, kitchen wet tissue cleaning products on the market are roughly divided into three types: (1) The first is strong cleaning force, for example, strong acid and strong alkali with large addition proportion are used for hydrolyzing grease, the cleaning product has good removing capability on heavy oil dirt, but the cleaning product has strong acidity or alkalinity and can cause great damage on the hand skin of a user, so the user can clean the hand skin by means of a protection device when using the cleaning product, and the cleaning product is very inconvenient; in addition, the strong cleaning kitchen cleaning products are easy to sacrifice the service life of the surface materials of kitchen ware and tableware, especially metals, the strong cleaning kitchen wet tissues generally have certain corrosiveness, the damage generated on the surfaces of the metal tools is easy to be discoloured and mottled, or the damage is easy to be influenced by smoothness and is visually represented, the phenomenon of poor beauty is generated, and the serious phenomenon is that residues infiltrate and mould. (2) The second is a solvent type, such as an ether type organic solvent added with ethylene glycol butyl ether, propylene glycol butyl ether and the like, and the solvent type kitchen cleaning product mainly wets and permeates oil dirt through the organic solvent and dissolves the oil dirt to remove and fall off, but the organic solvent has the probability of dissolving the surface decoration part of the kitchen appliance, such as paint surface or printing part, so as to destroy the pattern effect of the surface. In addition, the organic solvent is generally volatile low-toxic substances, and after being used, the organic solvent can cause a certain degree of air pollution to the household environment, and is not in line with the living concept of modern people pursuing safety and environmental protection. (3) The third is a pure surfactant formula, and the kitchen wet tissue fully plays roles of penetration, emulsification and solubilization of the surfactant, so that the greasy dirt is removed. However, such products are often poorly decontaminated, complex in formulation, costly, and the use of pure surfactant kitchen cleaning products produces a large amount of foam during use, which increases the number of rinses and wastes a large amount of water. 4) In addition, the kitchen wet tissues have a series of defects of skin rash, dry skin, contact dermatitis, skin surface injury and the like caused by sticky hand feeling and damage to cell membranes of contact surfaces of human bodies due to different kitchen wet tissue compound liquids.

Aiming at the defects: kitchen wipes make some changes in the formulation of the compound liquid, such as:

in the prior art, chinese patent number 202010800408.2 discloses an oil-removing environment-friendly kitchen wet tissue immersion liquid composition and a preparation method thereof, and the oil-removing environment-friendly kitchen wet tissue immersion liquid composition comprises: 0.01-1% of chelating agent; 0-1% of isomerism eight-carbon polyoxyethylene propylene ether; 0-1% of alkyl glycoside; 0.5-3% of cationic surfactant compound; 0.05-1% of high polymer film-forming brightening agent; 0-1% of humectant; natural low-foam inhibitor 0.01-0.1%; 1-10% of environment-friendly low-odor solvent; 0-1% of sterilizing preservative; 0-0.2% of other components; the balance of water. The kitchen wet tissue has good degreasing effect, and meanwhile, the foam amount is small, the irritation taste is small, but the antibacterial effect is poor.

CN114774214a discloses an environment-friendly wet towel for kitchen and restaurant and a preparation method thereof, wherein the soaking solution is prepared by dispersing decontamination microcapsules in deionized water; the decontamination microcapsule is prepared by coating decontamination solution with chitosan, the decontamination solution is prepared by mixing decontamination additive, N-lauryl-beta-iminodipropionate, sodium bicarbonate, deionized water and ethanol, the side chain of the decontamination additive contains a large amount of quaternary ammonium salt cationic structures, so that the self surface activity is higher, the decontamination microcapsule can well enter the interior of greasy dirt, the greasy dirt can be quickly emulsified when entering the interior of the greasy dirt, the adsorption force with a contact surface is reduced, multiple raw materials are compounded for use, the greasy dirt can be quickly removed, the environment-friendly wet towel does not use toxic solvents, the toxic gases are not released in the use process, the environment-friendly wet towel is greatly improved, and the safety of a user is ensured. However, the preparation method is complicated from the whole technical scheme, and the declared degreasing component is difficult to control from the practical point of view because the degreasing component is not directly contacted with the skin.

CN114292709a discloses a kitchen cleaning deodorizing wet tissue and a preparation method thereof, comprising (1) establishing an antiseptic sterilization system: adding quantitative propylene glycol into a reaction kettle, heating to 80+/-2 ℃, adding quantitative methyl nilate, continuously stirring until the methyl nilate is completely dissolved, reducing the temperature to 45+/-2 ℃, sequentially and quantitatively adding phenoxyethanol, ethylhexyl glycerol and didecyl dimethyl ammonium chloride, continuously and uniformly stirring to prepare an anti-corrosion and sterilization concentrated solution of the deodorizing kitchen wet tissues for later use; (2) construction of a deodorizing cleaning system: adding quantitative propylene glycol into a reaction kettle, heating to 70+/-2 ℃, adding quantitative zinc ricinoleate, continuously stirring until the quantitative zinc ricinoleate is completely dissolved, sequentially adding quantitative dodecyl glycoside and AEO-9, continuously stirring uniformly, adding quantitative deionized water, cooling to 40+/-2 ℃, adding quantitative zinc gluconate, continuously stirring uniformly, and preparing an odor-removing kitchen wet tissue odor-removing cleaning concentrated solution for later use; (3) construction of a pH buffer system: adding quantitative deionized water into a reaction kettle, respectively adding quantitative disodium hydrogen phosphate and potassium dihydrogen phosphate, and continuously and uniformly stirring to prepare a concentrated solution of the pH buffer system of the deodorizing kitchen wet tissue for later use; (4) Adding a certain amount of deionized water into a wet tissue liquid medicine dosing tank, adding EDTA-2Na, stirring until the mixture is completely dissolved, sequentially adding a certain amount of the pH buffer system concentrated solution, the deodorizing clean concentrated solution and the antiseptic sterilizing concentrated solution, and continuously and uniformly stirring to prepare the deodorizing kitchen wet tissue liquid medicine; (5) The deodorant kitchen wet tissue liquid medicine prepared in the step (4) is mixed with the spunlaced non-woven fabric according to the weight ratio of 3.4-3.8:1, uniformly applying the components into the spunlaced non-woven fabric to prepare the kitchen cleaning and deodorizing wet tissue. Similarly, the preparation is complicated, and the components are added with essence to remove the smell, so that the symptoms and the root causes are not treated, and the defect that the residual stain is not removed is easily covered.

That is, the above-mentioned problems may be accompanied by a large amount of cleaning agent or a strong corrosiveness, or the preparation is complicated, the production is difficult, the problems of sticky hand feeling, foam waste water and the like are difficult to solve, and there is a need in the art for a kitchen wet towel compound liquid which can balance various requirements, give consideration to cleaning force, continuously sterilize and is simple to prepare.

Disclosure of Invention

Aiming at the defects of the prior art, the invention provides a kitchen wet tissue compound liquid and a preparation method thereof.

In order to achieve the above purpose, the present invention adopts the following technical scheme: the kitchen wet tissue compound liquid comprises the following components in parts by weight:

benzethonium chloride: 0.1-3 parts

Benzalkonium salt compounds: 0.1-20 parts

Cationic surfactant: 0.1-5 parts

Isothiazolinone derivatives: 0.1-2 parts

Polyethylene glycol PEG:1-5 parts

Glycoside derivatives: 5-10 parts

Polyoxyethylene ether: 1-15 parts

Alcohols: 1-5 parts

Water softener: 0.1-0.5 part;

wherein the benzethonium chloride is 30% benzethonium chloride solution; the benzalkonium salt compound is a benzalkonium salt compound solution with the concentration of 50%; the cationic surfactant is a cationic surfactant solution with the concentration of 40%; the isothiazolinone derivative is an isothiazolinone derivative solution with the concentration of 10%.

By adopting the technical scheme, the compound has the functions of decontamination, sterilization and bacteriostasis, so that the source of peculiar smell is fundamentally solved, the addition of additional perfume is reduced, and the cost is reduced.

Preferably, the benzalkonium salt compound comprises pure matters or compound matters thereof, wherein the pure matters comprise C8 benzalkonium chloride, C10 benzalkonium chloride, C12 benzalkonium chloride, C14 benzalkonium chloride, C16 benzalkonium chloride and C18 benzalkonium chloride; at least one of C8 benzalkonium bromide, C10 benzalkonium bromide, C12 benzalkonium bromide, C14 benzalkonium bromide, C16 benzalkonium bromide, and C18 benzalkonium bromide.

By adopting the technical scheme, the quaternary ammonium salt compound is used, and the combination of the benzethonium chloride and the benzalkonium halide compound improves the broad spectrum performance of inhibiting bacteria, namely, compared with the independent use of the benzethonium chloride and the benzalkonium chloride, the total content of the benzethonium chloride and the benzalkonium chloride is smaller, the inhibition capability of the benzethonium chloride and the benzalkonium chloride on bacteria is stronger, and the use cost is reduced.

Preferably, the cationic surfactant comprises at least one of bis (octaalkyl) dimethyl ammonium chloride, bis (dodecyl) dimethyl ammonium chloride, bis (tetradecyl) dimethyl ammonium chloride, and bis (hexadecyl) dimethyl ammonium chloride.

By adopting the technical scheme, the preservative is also a detergent, the special effect of the cationic compound is utilized, the microbial watchcase can be effectively destroyed, so that the effects of killing and inhibiting microorganisms are achieved, the double-chain quaternary ammonium salt is used as the double-chain quaternary ammonium salt, the short plates with higher concentration are also compensated for when the single-chain quaternary ammonium salt is used for inhibiting fungi and moulds, and the system has high-efficiency inhibition on common bacteria, fungi and moulds in nature under the condition of lower concentration when being compounded for use.

Preferably, the isothiazolinone derivative comprises one of CIT, MIT, OIT, DCOIT, BIT or a complex thereof.

By adopting the technical scheme, the antibacterial and bactericidal agent has long-acting antibacterial and bactericidal capabilities and quick killing capabilities. The compound liquid has the capability of quickly killing the bacterial, the fungal and the mould, and simultaneously can continuously inhibit and kill the bacterial, the fungal and the mould for a long time.

Preferably, the PEG comprises at least one of PEG-7, PEG-8, PEG-9, PEG-200, PEG-400, PEG-600, and PEG-800.

Preferably, the glycoside derivative comprises at least one of decyl glucoside, dodecyl glucoside, tetradecyl glucoside and hexadecyl glucoside.

Preferably, the polyoxyethylene ether comprises at least one of isomeric dodecanol polyoxyethylene ether, isomeric tetradecanol polyoxyethylene ether and isomeric tridecanol polyoxyethylene ether.

By adopting the technical scheme, the compound liquid can remove hydrophilic stains and common oil stains, and can remove daily stains such as sludge, oil stains, oil sludge, blood and the like in the daily kitchen use process by adding decyl glucoside and polyvinyl ether.

Preferably, the humectant comprises at least one of propylene glycol, glycerin, butylene glycol, and ethanol.

Preferably, the water softener comprises at least one of disodium EDTA, citric acid, acetic acid, hydrochloric acid, sulfuric acid, or other organic acids.

The invention also provides a method for preparing the kitchen wet tissue compound liquid, which comprises the following steps:

1) Adding water into a stirring tank at room temperature, and starting stirring; adding 50% benzalkonium salt compound solution into a mixing stirring tank, and stirring until the benzalkonium salt compound solution is completely dissolved;

2) Slowly adding polyoxyethylene ether into the mixing stirring tank, and stirring until the polyoxyethylene ether is completely dissolved; slowly adding the glycoside derivative, and stirring uniformly until the glycoside derivative is completely dissolved; slowly adding 40% cationic surfactant compound solution, and stirring to dissolve completely;

3) Slowly adding the water softener after the cationic surfactant compound is completely dissolved, and uniformly stirring until the cationic surfactant compound is completely dissolved; slowly adding the humectant, and stirring uniformly until the humectant is completely dissolved; slowly adding the isothiazolinone derivative solution with the concentration of 10%, and uniformly stirring until the isothiazolinone derivative solution is completely dissolved;

4) Continuously and slowly adding 30% benzethonium chloride solution after the isothiazolinone derivative is dissolved, and uniformly stirring until the benzethonium chloride solution is completely dissolved; slowly adding polyethylene glycol PEG, and stirring until completely dissolving; after standing for 2 hours, the mixture can be injected and packaged.

The invention has the beneficial effects that:

1) The bacteria breeding is kitchen residue derived from micro-accumulation and cannot be decomposed by microorganisms, the compound liquid can inhibit microorganisms by extremely low liquid residue after being wiped by kitchen wet tissues, namely the compound liquid can sterilize and inhibit microorganisms under the condition of low concentration, and the low concentration condition means that the compound liquid has low corrosiveness, is not easy to damage the surfaces of kitchen ware, is not limited to be basically covered by the kitchen ware materials of fixed types, and has strong applicability;

2) The compound system with the antiseptic function in the components has small skin irritation, can be different from the common kitchen cleaner which needs to wear a latex glove for use, and can be directly contacted with skin; proper amount of the components are matched, so that the contact sticky feeling is further reduced, and the use comfort is improved;

3) The microbial killing and inhibiting effects are provided, and after the kitchen utensil is wiped, microbial pollution can be prevented for a certain time, so that the sanitary condition of the kitchen is improved, and the microbial formation can be inhibited under trace conditions. After the system is used, no residual trace is visible on the tabletop, and wiping is not needed again;

4) The hydrophilic and oleophilic adaptability is good, the compatibility of the components is good, no extra essence is added, the volatilization is reduced, and the environment is protected and safer;

5) After the kitchen wet tissue containing the compound liquid is used, no macroscopic residual trace exists on the surface of the wiped object, and secondary wiping is not needed; and the microbial agent is effective on bacteria and fungi, is fast in sterilization, can retain the antibacterial effect for a long time, and can inhibit the formation of microorganisms under trace conditions.

Drawings

Fig. 1 is a schematic diagram of a stock solution sample of kitchen wet wipe formulation.

Detailed Description

The invention is further described by the following specific examples, which are not intended to limit the scope of the invention.

The following reagents are commercially available except for the indicated manufacturer.

Benzethonium chloride, pharmaceutical grade, nanjing and wound materials science and technology limited company self-made;

c10 benzalkonium chloride, daily chemical grade, manufacturer, jingjiang green chemical company, inc;

bidecyldimethyl ammonium chloride DDAC, daily chemical grade, chengdu Cord;

decyl glucoside, daily chemical grade, shanghai He chemical Co., ltd;

the isomeric tridecanol polyoxyethylene ether 1305, daily chemical grade, is available in Yi city from Lvsen chemical industry Co., ltd;

isotridecyl alcohol polyoxyethylene ether 1307, daily chemical grade, linyi city, lvsen chemical Co., ltd;

propylene glycol, daily chemical grade, mountain east sea new source materials science and technology Co., ltd;

citric acid, food grade, weifang Yingxuan, inc.;

CIT/MIT, daily chemical grade, hezerun Xin biotechnology Co., ltd;

dodecyl glycoside, daily chemical grade, shanghai He chemical Co., ltd;

butanediol, analytically pure, nanjing chemical reagents, inc.;

disodium EDTA, food grade, shijia jack chemical company, inc;

PEG-400, daily chemical grade, shanghai He chemical Co., ltd;

glycerol, daily chemical grade, shanghai He chemical Co., ltd;

c8 benzalkonium bromide, daily chemical grade, chengdou family macro to chemical responsibility company;

tetradecyl glycoside, daily chemical grade, wuhan Ling, science and technology Co.

The testing method comprises the following steps:

(1) testing corrosiveness of the kitchen wet tissue compound liquid according to a standard GB/T27728-2011, and taking metal corrosiveness as a reference standard;

(2) according to the standard GB 15979-2002, the sterilization performance, the bacteriostasis performance and the stability are referenced;

(3) the killing and inhibiting effects on microorganisms under trace conditions of the components after wiping residues are simulated.

Example 1:

the following components are prepared in parts by weight:

1 part of benzethonium chloride

2 parts of C10 benzalkonium chloride

2 parts of bisdodecyl dimethyl ammonium chloride DDAC

2 parts of PEG-7

8 parts of decyl glucoside

1 part of isomeric tridecanol polyoxyethylene ether 1305

4.4 parts of isomeric tridecanol polyoxyethylene ether 1307

3 parts of propylene glycol

0.2 parts of citric acid;

the preparation method comprises the following steps:

1) Adding water into a stirring tank at room temperature, and starting stirring; adding C10 benzalkonium chloride into a mixing stirring tank, and uniformly stirring until the mixture is completely dissolved;

2) Slowly adding the isomeric tridecanol polyoxyethylene ether 1305 and the isomeric tridecanol polyoxyethylene ether 1307, and uniformly stirring until the isomeric tridecanol polyoxyethylene ether 1305 and the isomeric tridecanol polyoxyethylene ether 1307 are completely dissolved; slowly adding decyl glucoside, and stirring uniformly until completely dissolving; slowly adding DDAC, and stirring until completely dissolving;

3) Slowly adding citric acid, and stirring until completely dissolving; slowly adding propylene glycol, and stirring uniformly until the propylene glycol is completely dissolved; slowly adding MIT, and stirring until completely dissolving;

4) Slowly adding benzethonium chloride, and stirring uniformly until the benzethonium chloride is completely dissolved; slowly adding PEG-7, and stirring until completely dissolving; after standing for 2 hours, the mixture can be injected and packaged.

Example 2:

the following components are prepared in parts by weight:

2.5 parts of benzethonium chloride

15 parts of C8 benzalkonium bromide

0.5 part of bisdodecyl dimethyl ammonium chloride DDAC

0.5 part CIT/MIT

4 parts of PEG-200

10 parts of dodecyl glycoside

3 parts of isomeric tridecanol polyoxyethylene ether 1305

10 parts of isomeric tridecanol polyoxyethylene ether 1307

3 parts of butanediol

0.4 parts of disodium EDTA;

the preparation method comprises the following steps:

1) Adding water into a stirring tank at room temperature, and starting stirring; adding C8 benzalkonium bromide into a mixing stirring tank, and uniformly stirring until the mixture is completely dissolved;

2) Slowly adding the isomeric tridecanol polyoxyethylene ether 1305 and the isomeric tridecanol polyoxyethylene ether 1307, and uniformly stirring until the isomeric tridecanol polyoxyethylene ether 1305 and the isomeric tridecanol polyoxyethylene ether 1307 are completely dissolved; slowly adding dodecyl glucoside, and stirring until completely dissolving; slowly adding DDAC, and stirring until completely dissolving;

3) Slowly adding EDTA disodium, and stirring uniformly until the EDTA disodium is completely dissolved; slowly adding butanediol, and stirring uniformly until the butanediol is completely dissolved; slowly adding the CIT/MIT compound, and uniformly stirring until the CIT/MIT compound is completely dissolved;

4) Continuously and slowly adding benzethonium chloride, and uniformly stirring until the benzethonium chloride is completely dissolved; slowly adding PEG-200, and stirring until completely dissolving; after standing for 2 hours, the mixture can be injected and packaged.

Example 3:

the following components are prepared in parts by weight:

0.1 part of benzethonium chloride

10 parts of C12 benzalkonium bromide

5 parts of didodecyl dimethyl ammonium chloride

2 parts of DCOIT

4 parts of PEG-400

5 parts of tetradecyl glycoside

15 parts of isomeric dodecanol polyoxyethylene ether

4 parts of glycerol

0.5 part of acetic acid;

the preparation method comprises the following steps:

1) Adding water into a stirring tank at room temperature, and starting stirring; adding C12 benzalkonium bromide into a mixing stirring tank, and uniformly stirring until the mixture is completely dissolved;

2) Slowly adding the isomeric dodecanol polyoxyethylene ether, and uniformly stirring until the isomeric dodecanol polyoxyethylene ether is completely dissolved; slowly adding tetradecyl glycoside, and stirring until completely dissolving; slowly adding the didodecyl dimethyl ammonium chloride, and uniformly stirring until the didodecyl dimethyl ammonium chloride is completely dissolved;

3) Then slowly adding acetic acid, and stirring uniformly until the acetic acid is completely dissolved; slowly adding glycerol, and stirring until completely dissolving; slowly adding the DCOIT compound, and uniformly stirring until the DCOIT compound is completely dissolved;

4) Continuously and slowly adding benzethonium chloride, and uniformly stirring until the benzethonium chloride is completely dissolved; slowly adding PEG-400, and stirring uniformly until the PEG-400 is completely dissolved; after standing for 2 hours, the mixture can be injected and packaged.

Example 4:

the isothiazolinone derivative in example 1 was replaced with OIT, decyl glycoside with hexadecyl glycoside, polyoxyethylene ether with isotetradecyl polyoxyethylene ether, water softener with hydrochloric acid, and the rest was unchanged.

And the preparation operation step is replaced according to the addition sequence of the component types.

Example 5:

the isothiazolinone derivative in example 1 was replaced with BIT, the cationic surfactant with bis-octaalkyl dimethyl ammonium chloride, the water softener with sulfuric acid, the humectant with ethanol, PEG with PEG-9, the rest unchanged.

Example 6:

the component isothiazolinone derivatives in example 1 were substituted for the compound MIT/OIT, PEG was substituted for PEG-600, cationic surfactant was substituted for ditetradecyl dimethyl ammonium chloride, and the remainder was unchanged.

Example 7:

the component isothiazolinone derivatives in example 1 were substituted for the MIT/BIT complex, the cationic surfactant was substituted for dicetyl dimethyl ammonium chloride, PEG was substituted for PEG-800, and the rest was unchanged.

Example 8: the component isothiazolinone derivatives in example 1 were substituted for the MIT/DCOIT complex, PEG was substituted for PEG-8, and the remainder was unchanged.

Comparative example 1: the common kitchen wet tissues in the market are extracted to obtain the mixed solution stock solution.

Comparative example 2: the component benzalkonium halides of example 1 were removed, the remainder being unchanged.

Comparative example 3: the benzethonium chloride component of example 1 was removed, leaving the remainder unchanged.

(1) Comparative corrosiveness

	Corrosiveness of
		Example 1	Qualified product
Example 2	Qualified product
		Example 3	Qualified product
Example 4	Qualified product
		Example 5	Qualified product
Example 6	Qualified product
		Example 7	Qualified product
Example 8	Qualified product
		Comparative example 1	Failure to pass
Comparative example 2	Qualified product
		Comparative example 3	Qualified product

(2) The performance test was performed on example 1 as a preferred example and comparative example 1, and the results are shown in the following table:

(3) the performance test of example 1 as a preferred example and comparative example 1 was performed, the kitchen wet tissues in example 1 were subjected to high-power dilution, and the antibacterial effect under the condition of trace residue after wiping was simulated, and the results are shown in the following table:

comparing the performance test of example 1 with comparative examples 2 and 3 as a preferred example, it is verified that the combination of the individual components (benzethonium chloride, benzalkonium salt compound) and the components (benzethonium chloride and benzalkonium salt compound) inhibits the broad spectrum performance of bacteria, the test procedure is different in degerming group, the rest is referred to (3), and the results are shown in the following table:

the comparison of the test results shows that the kitchen wet tissue compound liquid has the effects of quick and effective killing and efficient inhibition on common bacteria, fungi and moulds in nature; under trace conditions, the invention can inhibit the formation of microorganisms, namely the invention can sterilize and inhibit bacteria under the condition of low concentration, and the low concentration condition means that the invention has lower corrosiveness, is not easy to damage the surface of kitchen ware, has lower corrosiveness, and is friendly to kitchen utensils; therefore, the skin irritation is tiny, and the kitchen cleaner is different from the common kitchen cleaner which needs to wear a latex glove for use, can be directly contacted with the skin, and is convenient for use.

Claims

1. The kitchen wet tissue compound liquid is characterized by comprising the following components in parts by weight:

benzethonium chloride: 0.1-3 parts

Benzalkonium salt compounds: 0.1-20 parts

Cationic surfactant: 0.1-5 parts

Isothiazolinone derivatives: 0.1-2 parts

Polyethylene glycol PEG:1-5 parts

Glycoside derivatives: 5-10 parts

Polyoxyethylene ether: 1-15 parts

Alcohols: 1-5 parts

Water softener: 0.1-0.5 part.

2. The kitchen wet wipe compound liquid according to claim 1, wherein the benzalkonium salt compound comprises pure substances or compound substances thereof, and the pure substances comprise C8 benzalkonium chloride, C10 benzalkonium chloride, C12 benzalkonium chloride, C14 benzalkonium chloride, C16 benzalkonium chloride and C18 benzalkonium chloride; at least one of C8 benzalkonium bromide, C10 benzalkonium bromide, C12 benzalkonium bromide, C14 benzalkonium bromide, C16 benzalkonium bromide, and C18 benzalkonium bromide.

3. The kitchen wet wipe compound liquid according to claim 1, wherein the cationic surfactant comprises at least one of bis-octaalkyl dimethyl ammonium chloride, bis-dodecyl dimethyl ammonium chloride, bis-tetradecyl dimethyl ammonium chloride, and bis-hexadecyl dimethyl ammonium chloride.

4. The kitchen wet wipe complex of claim 1, wherein the isothiazolinone derivative comprises one of CIT, MIT, OIT, DCOIT, BIT or a complex thereof.

5. The kitchen wet wipe complex formulation of claim 1, wherein the polyethylene glycol PEG comprises at least one of PEG-7, PEG-8, PEG-9, PEG-200, PEG-400, PEG-600, PEG-800.

6. The kitchen wet wipe compound liquid according to claim 1, wherein the glycoside derivative comprises at least one of decyl glycoside, dodecyl glycoside, tetradecyl glycoside and hexadecyl glycoside.

7. The kitchen wet wipe compound liquid according to claim 1, wherein the polyoxyethylene ether comprises at least one of isomeric dodecanol polyoxyethylene ether, isomeric tetradecanol polyoxyethylene ether and isomeric tridecanol polyoxyethylene ether.

8. The kitchen wet wipe complex formulation liquid according to claim 1, wherein the humectant comprises propylene glycol: at least one of glycerol, butanediol and ethanol.

9. The kitchen wet wipe complex formulation liquid according to claim 1, wherein the water softener comprises at least one of disodium EDTA, citric acid, acetic acid, hydrochloric acid, sulfuric acid, or other organic acids.

10. A method of preparing the kitchen wet wipe formulation according to any one of claims 1-9, comprising the steps of:

1) Adding water into a stirring tank at room temperature, and starting stirring; adding benzalkonium halide salt compounds into a mixing stirring tank, and uniformly stirring until the benzalkonium halide salt compounds are completely dissolved;

2) Slowly adding polyoxyethylene ether into the mixing stirring tank, and stirring until the polyoxyethylene ether is completely dissolved; slowly adding the glycoside derivative, and stirring uniformly until the glycoside derivative is completely dissolved; slowly adding the cationic surfactant compound solution, and uniformly stirring until the cationic surfactant compound solution is completely dissolved;

3) Slowly adding the water softener into the cationic surfactant compound solution after the cationic surfactant compound solution is completely dissolved, and uniformly stirring until the cationic surfactant compound solution is completely dissolved; slowly adding the humectant, and stirring uniformly until the humectant is completely dissolved; slowly adding the isothiazolinone derivative, and stirring uniformly until the isothiazolinone derivative is completely dissolved;

4) Continuously and slowly adding the benzethonium chloride solution after the isothiazolinone derivative solution is dissolved, and uniformly stirring until the benzethonium chloride solution is completely dissolved; slowly adding polyethylene glycol PEG, and stirring until completely dissolving; after standing for 2 hours, the mixture can be injected and packaged.