CN112999397A - Environment-friendly deodorization medicament and preparation method thereof - Google Patents
Environment-friendly deodorization medicament and preparation method thereof Download PDFInfo
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- CN112999397A CN112999397A CN202110309526.8A CN202110309526A CN112999397A CN 112999397 A CN112999397 A CN 112999397A CN 202110309526 A CN202110309526 A CN 202110309526A CN 112999397 A CN112999397 A CN 112999397A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
Abstract
The invention discloses an environment-friendly deodorant agent which comprises the following raw materials in parts by weight: 5-8 parts of ferric citrate, 3-5 parts of dodecyl benzene sulfonic acid, 1-3 parts of fatty alcohol-polyoxyethylene ether, 2-6 parts of zinc chloride, 1-3 parts of EDTA-2Na, 2-5 parts of propylene glycol, 1-3 parts of a corrosion inhibitor, 10-15 parts of a plant extract and 30-40 parts of ethanol. The environment-friendly deodorant agent is prepared by compounding the chemical deodorant and the plant deodorant, active molecules in the deodorant contain active ingredients, peculiar smell molecules can be effectively captured, the active ingredients can perform chemical reactions such as polymerization, decomposition, substitution, replacement and addition with the peculiar smell molecules, the aim of removing peculiar smell is fulfilled, and the final product of the reaction is a harmless molecule without the problems of secondary pollution and the like.
Description
Technical Field
The invention relates to the field of deodorizers, in particular to an environment-friendly deodorizing medicament and a preparation method thereof.
Background
In recent years, the demand of the domestic market for the deodorant is continuously increased, and the market potential is huge. The deodorant relates to various types of deodorants in daily life of people, such as refrigerator deodorizers, automobile and airplane deodorants, room, toilet and restaurant deodorants and the like, and is quite widely applied. Deodorants are mainly of the following types: physical deodorant, chemical deodorant, microbial deodorant, plant deodorant, composite deodorant, etc.
The physical deodorant is a deodorant by a physical method, and only the local concentration of the malodor is changed as a result of not changing the malodor components by using the physical properties of the deodorant or malodor. The chemical deodorant is a deodorant that is produced by converting a generated malodorous substance into a non-malodorous substance by oxidation, reductive decomposition, neutralization reaction, addition reaction, condensation reaction, ion exchange reaction, or the like. The microbial deodorant is characterized in that malodorous substances in dissolved water are absorbed in the microorganisms by the microorganisms, and the malodorous substances are degraded by the metabolic activity of the microorganisms. The plant deodorant is prepared from natural plant extractive solution or natural plant extract as main raw material.
The physical deodorant cannot fundamentally remove odor simply by adsorption or dilution. The chemical deodorant has strong pertinence, has good deodorization effect on a single odor source, but has small application range, a plurality of components are corrosive, and have certain harm to human bodies, so the chemical deodorant is not suitable for indoor deodorization. The biological deodorant needs to be metabolized and decomposed by microorganisms to meet the requirements on the microbial environment, and the biological deodorant takes longer time. The plant deodorant is harmless and nontoxic to human bodies and animals, has no harm to soil and plants, does not contain Freon and ozone, and is safe to use, but the plant deodorant is not ideal in deodorizing effect generally, and particularly the covering plant deodorant has no decomposition effect on odor sources. Therefore, a compound deodorant is in demand.
Disclosure of Invention
In order to solve the defects mentioned in the background technology, the invention aims to provide an environment-friendly deodorant and a preparation method thereof, the environment-friendly deodorant is prepared by compounding a chemical deodorant and a plant deodorant, active molecules in the deodorant contain active ingredients, atomized plant liquid enters air or is adsorbed to the surface of a treated object in a fine mist form, peculiar smell molecules can be effectively captured, once the peculiar smell molecules are absorbed or enter the fine mist of the plant liquid, the active ingredients and the peculiar smell molecules can perform chemical reactions such as polymerization, decomposition, substitution, replacement, addition and the like to achieve the aim of removing peculiar smell, and final products of the reactions are harmless molecules such as water, oxygen, nitrogen and the like, so that the aim of effectively removing smell is achieved, and the problems of secondary pollution and the like do not exist.
The purpose of the invention can be realized by the following technical scheme:
an environment-friendly deodorant agent comprises the following raw materials in parts by weight: 5-8 parts of ferric citrate, 3-5 parts of dodecyl benzene sulfonic acid, 1-3 parts of fatty alcohol-polyoxyethylene ether, 2-6 parts of zinc chloride, 1-3 parts of EDTA-2Na, 2-5 parts of propylene glycol, 1-3 parts of a corrosion inhibitor, 10-15 parts of a plant extract and 30-40 parts of ethanol.
Further preferably, the corrosion inhibitor is benzotriazole and polyaspartic acid in a weight ratio of 1: 1-2, and mixing.
Further preferably, the plant extract comprises the following components in percentage by mass: 25-40% of camphor tree extract, 15-30% of ginkgo leaf extract, 10-20% of yucca extract, 10-15% of tea polyphenol, 3-5% of plant essence and 1-3% of gel.
Preferably, the plant essence is one or more of lavender essence, rose essence, lemon essence and clove essence
Further preferably, the gelling agent is prepared from polyvinyl alcohol, polyvinylpyrrolidone and polyacrylamide in a weight ratio of 1: 1: 1 and mixing.
A preparation method of an environment-friendly deodorant medicament comprises the following steps:
s1, adding ferric citrate, dodecyl benzene sulfonic acid, fatty alcohol-polyoxyethylene ether and ethanol into a reaction kettle, and heating and stirring for 1-3h at the temperature of 45-55 ℃;
s2, adding zinc chloride, EDTA-2Na and propylene glycol into the reaction kettle of S1, continuing to keep the temperature and stir for 0.5-1h, and then cooling;
s3, adding the corrosion inhibitor into the reaction kettle of S2, and then stirring until the corrosion inhibitor is fully dissolved and mixed;
and S4, finally adding the plant extract into the reaction kettle, stirring until the plant extract is mixed repeatedly, and standing, settling and filtering the solution to obtain the environment-friendly deodorant.
The invention has the beneficial effects that:
the invention prepares the environment-friendly deodorant agent by compounding the chemical deodorant and the plant deodorant, effective molecules in the deodorant contain active ingredients, the atomized plant liquid enters the air or is adsorbed on the surface of an object to be treated in the form of fine mist, peculiar smell molecules can be effectively captured, once the peculiar smell molecules are absorbed or enter the fine mist of the plant liquid, the active ingredients can perform chemical reactions such as polymerization, decomposition, substitution, replacement, addition and the like with the peculiar smell molecules to achieve the aim of removing peculiar smell, and the final products of the reactions are harmless molecules such as water, oxygen, nitrogen and the like, thereby achieving the aim of effectively removing smell without the problems of secondary pollution and the like.
The ferric citrate provides citrate with chelation and bivalent and trivalent ferric ions with neutralization and oxidation, and the oxidation reaction is irreversible, so that the final removal of the sulfide ions can be ensured, and the neutralization, complexation, oxidation and chelation reaction can be carried out on the ferric citrate and hydrogen sulfide and ammonia nitrogen in the solution under the combined action of the ferric ions and a zinc catalyst to generate a stable, nontoxic, harmless and tasteless substance, so that the hydrogen sulfide and the ammonia nitrogen in the solution can be thoroughly removed.
The plant extract comprises camphor tree extract, ginkgo leaf extract, yucca extract and tea polyphenol, the camphor tree extract has the function of inhibiting the growth of microorganisms such as aspergillus flavus, escherichia coli and the like, the yucca extract has strong adsorption capacity on harmful gases and can reduce the concentration of gases such as ammonia gas, hydrogen sulfide and the like in a livestock house, the ginkgo leaf extract can absorb and decompose the hydrogen sulfide, the tea polyphenol can absorb and decompose ammonia and organic amine, and odor source molecules can be rapidly and effectively removed through the compounding of several plant extracts.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it is to be understood that the terms "opening," "upper," "lower," "thickness," "top," "middle," "length," "inner," "peripheral," and the like are used in an orientation or positional relationship that is merely for convenience in describing and simplifying the description, and do not indicate or imply that the referenced component or element must have a particular orientation, be constructed and operated in a particular orientation, and thus should not be considered as limiting the present invention.
Example 1
An environment-friendly deodorant agent comprises the following raw materials in parts by weight: 5 parts of ferric citrate, 3 parts of dodecyl benzene sulfonic acid, 1 part of fatty alcohol-polyoxyethylene ether, 2 parts of zinc chloride, 1 part of EDTA-2Na, 2 parts of propylene glycol, 1 part of benzotriazole, 1 part of polyaspartic acid, 12 parts of plant extract and 30 parts of ethanol.
The plant extract comprises the following components in percentage by mass: 40% of camphor tree extract, 25% of ginkgo leaf extract, 15% of yucca extract, 14% of tea polyphenol, 1% of lavender essence, 2% of rose essence, 1% of polyvinyl alcohol, 1% of polyvinylpyrrolidone and 1% of polyacrylamide.
A preparation method of an environment-friendly deodorant medicament comprises the following steps:
s1, adding ferric citrate, dodecyl benzene sulfonic acid, fatty alcohol-polyoxyethylene ether and ethanol into a reaction kettle, and heating and stirring for 2 hours at 50 ℃;
s2, adding zinc chloride, EDTA-2Na and propylene glycol into the reaction kettle of S1, continuing to keep the temperature and stir for 0.5h, and then cooling;
s3, adding the corrosion inhibitor into the reaction kettle of S2, and then stirring until the corrosion inhibitor is fully dissolved and mixed;
and S4, finally adding the plant extract into the reaction kettle, stirring until the plant extract is mixed repeatedly, and standing, settling and filtering the solution to obtain the environment-friendly deodorant.
Example 2
An environment-friendly deodorant agent comprises the following raw materials in parts by weight: 8 parts of ferric citrate, 5 parts of dodecyl benzene sulfonic acid, 3 parts of fatty alcohol-polyoxyethylene ether, 5 parts of zinc chloride, 2 parts of EDTA-2Na, 4 parts of propylene glycol, 1 part of benzotriazole, 1 part of polyaspartic acid, 15 parts of plant extract and 40 parts of ethanol.
The plant extract comprises the following components in percentage by mass: 35% of camphor tree extract, 25% of ginkgo leaf extract, 20% of yucca extract, 15% of tea polyphenol, 3.5% of lavender essence, 0.5% of polyvinyl alcohol, 0.5% of polyvinylpyrrolidone and 0.5% of polyacrylamide.
A preparation method of an environment-friendly deodorant medicament comprises the following steps:
s1, adding ferric citrate, dodecyl benzene sulfonic acid, fatty alcohol-polyoxyethylene ether and ethanol into a reaction kettle, and heating and stirring for 1h at the temperature of 55 ℃;
s2, adding zinc chloride, EDTA-2Na and propylene glycol into the reaction kettle of S1, continuing to keep the temperature and stir for 1 hour, and then cooling;
s3, adding the corrosion inhibitor into the reaction kettle of S2, and then stirring until the corrosion inhibitor is fully dissolved and mixed;
and S4, finally adding the plant extract into the reaction kettle, stirring until the plant extract is mixed repeatedly, and standing, settling and filtering the solution to obtain the environment-friendly deodorant.
Example 3
An environment-friendly deodorant agent comprises the following raw materials in parts by weight: 6 parts of ferric citrate, 4 parts of dodecyl benzene sulfonic acid, 2 parts of fatty alcohol-polyoxyethylene ether, 5 parts of zinc chloride, 2 parts of EDTA-2Na, 4 parts of propylene glycol, 1 part of benzotriazole, 1 part of polyaspartic acid, 12 parts of plant extract and 35 parts of ethanol.
The plant extract comprises the following components in percentage by mass: 50% of camphor tree extract, 15% of ginkgo leaf extract, 15% of yucca extract, 12% of tea polyphenol, 2% of lavender essence, 1% of lemon essence, 2% of clove essence, 1% of polyvinyl alcohol, 1% of polyvinylpyrrolidone and 1% of polyacrylamide.
A preparation method of an environment-friendly deodorant medicament comprises the following steps:
s1, adding ferric citrate, dodecyl benzene sulfonic acid, fatty alcohol-polyoxyethylene ether and ethanol into a reaction kettle, and heating and stirring for 3 hours at the temperature of 45 ℃;
s2, adding zinc chloride, EDTA-2Na and propylene glycol into the reaction kettle of S1, continuing to keep the temperature and stir for 1 hour, and then cooling;
s3, adding the corrosion inhibitor into the reaction kettle of S2, and then stirring until the corrosion inhibitor is fully dissolved and mixed;
and S4, finally adding the plant extract into the reaction kettle, stirring until the plant extract is mixed repeatedly, and standing, settling and filtering the solution to obtain the environment-friendly deodorant.
In the description herein, references to the description of "one embodiment," "an example," "a specific example" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed.
Claims (6)
1. An environment-friendly deodorant medicament is characterized by comprising the following raw materials in parts by weight: 5-8 parts of ferric citrate, 3-5 parts of dodecyl benzene sulfonic acid, 1-3 parts of fatty alcohol-polyoxyethylene ether, 2-6 parts of zinc chloride, 2-3 parts of EDTA-2Na1, 2-5 parts of propylene glycol, 1-3 parts of a corrosion inhibitor, 10-15 parts of a plant extract and 30-40 parts of ethanol.
2. The environment-friendly deodorant agent according to claim 1, wherein the corrosion inhibitor is benzotriazole and polyaspartic acid in a weight ratio of 1: 1-2, and mixing.
3. The environment-friendly deodorant medicament as claimed in claim 1, wherein the plant extract comprises the following components in percentage by mass: 20-50% of camphor tree extract, 10-40% of ginkgo leaf extract, 15-25% of yucca extract, 5-20% of tea polyphenol, 3-5% of plant essence and 1-3% of gel.
4. The environment-friendly deodorant agent according to claim 3, wherein the plant essence is one or a mixture of lavender essence, rose essence, lemon essence and clove essence.
5. The environmentally friendly deodorant agent of claim 3 wherein said gelling agent is a mixture of polyvinyl alcohol, polyvinylpyrrolidone and polyacrylamide in a weight ratio of 1: 1: 1 and mixing.
6. A method for preparing the environmentally friendly deodorant agent of any one of claims 1 to 5, comprising the steps of:
s1, adding ferric citrate, dodecyl benzene sulfonic acid, fatty alcohol-polyoxyethylene ether and ethanol into a reaction kettle, and heating and stirring for 1-3h at the temperature of 45-55 ℃;
s2, adding zinc chloride, EDTA-2Na and propylene glycol into the reaction kettle of S1, continuing to keep the temperature and stir for 0.5-1h, and then cooling;
s3, adding the corrosion inhibitor into the reaction kettle of S2, and then stirring until the corrosion inhibitor is fully dissolved and mixed;
and S4, finally adding the plant extract into the reaction kettle, stirring until the plant extract is mixed repeatedly, and standing, settling and filtering the solution to obtain the environment-friendly deodorant.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114176101A (en) * | 2021-12-17 | 2022-03-15 | 富思特新材料科技发展股份有限公司 | Antibacterial deodorant and preparation method and application thereof |
CN115920106A (en) * | 2023-03-10 | 2023-04-07 | 广州市拓瑞科技有限公司 | High-energy long-acting deodorant for bio-based technology and preparation method thereof |
Citations (3)
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CN102030379A (en) * | 2009-09-24 | 2011-04-27 | 中国石油化工股份有限公司 | Oil refining device deodorant and preparation method thereof |
CN106345261A (en) * | 2016-08-23 | 2017-01-25 | 南京南炼宏泰技术开发有限公司 | Environmental-friendly high-efficacy deodorant and method for preparing same |
CN110339693A (en) * | 2019-07-16 | 2019-10-18 | 河南碳索新材料科技有限公司 | A kind of plant type air deodorization agent of farm and preparation method thereof |
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2021
- 2021-03-23 CN CN202110309526.8A patent/CN112999397A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102030379A (en) * | 2009-09-24 | 2011-04-27 | 中国石油化工股份有限公司 | Oil refining device deodorant and preparation method thereof |
CN106345261A (en) * | 2016-08-23 | 2017-01-25 | 南京南炼宏泰技术开发有限公司 | Environmental-friendly high-efficacy deodorant and method for preparing same |
CN110339693A (en) * | 2019-07-16 | 2019-10-18 | 河南碳索新材料科技有限公司 | A kind of plant type air deodorization agent of farm and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114176101A (en) * | 2021-12-17 | 2022-03-15 | 富思特新材料科技发展股份有限公司 | Antibacterial deodorant and preparation method and application thereof |
CN115920106A (en) * | 2023-03-10 | 2023-04-07 | 广州市拓瑞科技有限公司 | High-energy long-acting deodorant for bio-based technology and preparation method thereof |
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Application publication date: 20210622 |