CN1129951A - Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants - Google Patents
Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants Download PDFInfo
- Publication number
- CN1129951A CN1129951A CN94193203A CN94193203A CN1129951A CN 1129951 A CN1129951 A CN 1129951A CN 94193203 A CN94193203 A CN 94193203A CN 94193203 A CN94193203 A CN 94193203A CN 1129951 A CN1129951 A CN 1129951A
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- Prior art keywords
- amine oxide
- composition
- alkyl
- detergent compositions
- mixture
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 116
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 33
- 239000003599 detergent Substances 0.000 title claims abstract description 19
- 238000004140 cleaning Methods 0.000 title abstract description 14
- 150000001412 amines Chemical class 0.000 claims abstract description 51
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 40
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- UZZYXUGECOQHPU-UHFFFAOYSA-N sulfuric acid monooctyl ester Natural products CCCCCCCCOS(O)(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-N 0.000 claims description 6
- 229940067739 octyl sulfate Drugs 0.000 claims description 3
- UZZYXUGECOQHPU-UHFFFAOYSA-M n-octyl sulfate Chemical compound CCCCCCCCOS([O-])(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-M 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- UQKAOOAFEFCDGT-UHFFFAOYSA-N n,n-dimethyloctan-1-amine Chemical compound CCCCCCCCN(C)C UQKAOOAFEFCDGT-UHFFFAOYSA-N 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 4
- 239000002689 soil Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 150000002632 lipids Chemical class 0.000 description 16
- 230000008719 thickening Effects 0.000 description 13
- 239000013543 active substance Substances 0.000 description 11
- -1 fatty acid alkali metal salt Chemical class 0.000 description 11
- 238000004061 bleaching Methods 0.000 description 7
- 235000013599 spices Nutrition 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000004851 dishwashing Methods 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 229910003202 NH4 Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000010480 babassu oil Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- LOKPKYSOCCPWIZ-UHFFFAOYSA-N cacodyl oxide Chemical compound C[As](C)O[As](C)C LOKPKYSOCCPWIZ-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical class CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- YZQBYALVHAANGI-UHFFFAOYSA-N magnesium;dihypochlorite Chemical compound [Mg+2].Cl[O-].Cl[O-] YZQBYALVHAANGI-UHFFFAOYSA-N 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- DGSDBJMBHCQYGN-UHFFFAOYSA-M sodium;2-ethylhexyl sulfate Chemical class [Na+].CCCCC(CC)COS([O-])(=O)=O DGSDBJMBHCQYGN-UHFFFAOYSA-M 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C11D2111/14—
Abstract
The present invention is an aqueous liquid detergent composition comprising a short chain surfactant for improved cleaning performance. Said composition further comprises a mixture of long chain amine oxides to restore viscosity. Said composition provides outstanding soil removal when used as a dish pretreatment composition as well as outstanding cleaning performance when used in hard-surface applications including toilet bowl cleaning.
Description
Technical field
The present invention relates to be suitable for the thickened aqueous detergent compositions of domestic use.More particularly, composition herein is applicable to the crust purposes that comprises that the washroom is cleaned, and the dishwashing detergent purposes, especially as pretreatment compositions.
Background of invention
The liquid detergent composition that comprises the combination of long chain amine oxide and lipid acid is well-known in the present technique field.
People wish that such composition has good cleaning character., it is found that long chain amine oxide does not provide best cleaning performance.Therefore first purpose of the present invention provides and has the cleaning composition that contains the long-chain tensio-active agent that has improved cleaning performance.
In order to reach this purpose, have been found that adding short chain surfactants is the useful purpose that strengthens cleaning performance that also reached thus.Yet, it should be noted that in such composition, to add the viscosity degradation that short chain surfactants causes composition.Said composition makes composition stick to vertical surface and on the surface of horizontal tilt, is considered to essential and should demonstrate high viscosity.
Therefore, another object of the present invention provides a kind of liquid composition that comprises long-chain tensio-active agent and short chain surfactants, and it remains with certain viscosity.
In order to reach this purpose, have been found that C more specifically says so by using the mixture of specific amine oxide
14Amine oxide and C
12Amine oxide, or C
16The mixture of amine oxide or the mixture of its mixture, even when adding short chain surfactants, still can keep viscosity.
Other advantage of the present invention is not need other thickening material.Another advantage of the present composition is that it has desirable whipability (suds ingprofile) so that do not need suds suppressor.
The thickening combination that comprises long chain amine oxide and fully saturated lipid acid is well-known in the present technique field.
US4282109 discloses a kind of long-chain C that comprises hypochlorite and straight chain and side chain
12-C
18Amine oxide is as the thickening bleaching composition of thickening material.But do not mention short chain C
6-C
8Tensio-active agent or lipid acid.
EP274885 discloses and has comprised alkaline metal hypochlorite and straight chain C
14Amine oxide and side chain and straight chain C
14The thickening bleaching composition of the mixture of amine oxide.But do not mention short chain surfactants.Said composition can randomly contain lipid acid as additional thickening auxiliary agent.
EP233666 discloses a kind of production and has comprised hypochlorite, is dissolved in the method for the thickening bleaching composition of the tensio-active agent of hypochlorite and fatty acid alkali metal salt.This detergent active comprises amine oxide, preferred lauryl dimethyl amine.But do not mention short chain surfactants.
DE2837880 discloses the bleaching composition of the mixture of the side chain that comprises alkaline metal hypochlorite and different chain length degree and straight chain amine oxide, (C
5-C
17) be used to increase viscosity.Said composition does not need the lipid acid thickening.
EP30401 discloses the thickening bleaching composition that comprises hypochlorite and some comprises the product performance of pH and viscosity.C
8-C
18The mixture of amine oxide and lipid acid are preferably as thickening material.But do not mention short chain surfactants.
The invention summary
Composition of the present invention comprises that having viscosity is that 50cps-2000cps contains according to formula R
1R
2R
3The mixture of the long chain amine oxide of NO and the aqueous composition of short chain surfactants, wherein R
2And R
3Be respectively C
1-C
3Alkyl.
Described short chain surfactants comprises a hydrophobic part and a hydrophilic segment, and the chain length of wherein said hydrophobic part is C
6-C
10
The mixture of described long chain amine oxide comprises wherein R
1Be C
14First amine oxide of alkyl and R wherein
1Be C
12Alkyl or C
16Alkyl, or second amine oxide of the mixture of its described amine oxide.
Described first amine oxide and described wherein R
1Be C
12The ratio of second amine oxide of alkyl is 0.3-10 and described first amine oxide and R wherein
1Be C
16The ratio of second amine oxide of alkyl is 0.2-4.5.
Unless otherwise indicated, all proportions that provides herein, percentage ratio and umber all are in the weight %'s of total composition.
The present invention also comprises the method for handling tableware, and wherein said tableware contacts with composition according to the present invention.
The detailed description of invention
Liquid detergent composition according to the present invention comprises hybrid long chain amine oxide and short chain surfactants.
Have been found that by adding short chain surfactants and can improve cleaning performance according to composition of the present invention.
Composition according to the present invention comprises at least a short chain surfactants, or its mixture.The something in common that all surface promoting agent has is that they all comprise a hydrophobic part and a hydrophilic segment.With regard to short chain surfactants, it is meant and comprises a C in this article
6-C
10Alkyl chain is as the tensio-active agent of its hydrophobic part.So such short chain surfactants is those tensio-active agents that are used for this field routinely, but have short alkyl chain, and can be any kind.Therefore, be applicable to that short chain surfactants herein comprises C
6-C
10Alkyl-sulphate (C
6-C
10SO
4), sulfated alkyl ether (C
6-C
10(OCH
2CH
2)
eSO
4), alkylsulfonate (C
6-C
10SO
3), alkyl succinate (C
6-C
10OOCCH
2CH
2COOZ), alkyl carboxylate (C
6-C
10COOM), alkyl ether carboxy acid salt (C
6-C
10(OCH
2CH
2)
eCOOM), alkyl sarcosine salt (C
6-C
10CON (CH
3) R), alkyl sulfosuccinate (C
6-C
10OOCCH (SO
3M) CH
2COOZ), amine oxide (C
6-C
10RR ' NO), glucose amide (C
6-C
10CONR " X), alkyl pyrrolidone (C
6-C
10(C
4H
6ON), alkyl polysaccharide (C
6-C
10OG
g), alkyl alkoxylates (C
6-C
10(OCH
2CH
2)
e(OCH
2CH
2CH
2)
pOH) and trimethyl-glycine (C
6-C
10N
+(CH
3)
2CH
2COO-).In the formula in bracket, e and p are respectively 0-20 and e+p＞0, and Z is M or R, M is H or any counter ion, and those ions for example known in the art comprise Na, K, Li, NH4, amine, X has the polyhydroxy alkyl that at least 3 hydroxyls are directly connected to the straight-chain alkyl on the chain, or its oxyalkylated derivative, R, R ' and R " are C
1-C
5Alkyl may be used hydroxy-functional, and R and R ' be C preferably
1-C
3, most preferable, R " preferably 2-hydroxyethyl or 2-hydroxypropyl, G is a carbohydrate, preferred glucose, and g is 1.5-8.All these tensio-active agents are known in this area.For example, in WO92-06154, can find comparatively complete the disclosing of conventional glucamide, in US4536319, can find comparatively complete the disclosing of conventional alkyl polysaccharide.Can comprise single arbitrary above-mentioned tensio-active agent according to composition of the present invention, or their arbitrary combination, this depends on the end-use of expection.
Preferred short chain nonionogenic tenside used herein is according to formula C
6-C
10(OCH
2CH
2)
e(OCH
2CH
2CH
2)
pThe alkyl alkoxylates of OH represents respectively that wherein the e of ethoxylation degree and propoxylation degree and p are 0-20 independently, and e+p＞0.Most preferably short chain nonionogenic tenside used herein be those wherein e and p be such alkyl alkoxylates, its e+p is 3-10, particularly preferred for p wherein be that 0 e is those alkyl alkoxylates of 3-8.In addition, most preferably short chain nonionogenic tenside used herein is that those wherein said short chains are the alkyl alkoxylates that comprise 7-10 carbon atom hydrocarbon chain.
Above-mentioned used herein preferred short chain nonionogenic tenside can be by method production well known to those of ordinary skill in the art, for example pass through corresponding pure and mild alkylene oxide condensation, but such short chain surfactants is to buy from the market more easily, for example from Sidobre with trade(brand)name Mergital
C
4(C
8E04), from Kolb with trade(brand)name Imbentin
AG/810/050 and AG/810/080 (are respectively C
8-10E05 and C
8-10E08) buy.
Preferred short chain anion surfactant used herein is C
6-C
10Alkyl-sulphate (C
6-C
10SO
4) and alkylsulfonate (C
6-C
10SO
3).C most preferably
6-C
8Alkyl-sulphate and sulfonate.Such short chain anion surfactant can by known sulfation or process for sulfonation then neutralization produce, but described negatively charged ion short chain surfactants is to buy from the market more easily, for example from Rhone Poulenc with trade(brand)name Rhodapon
OLS, or from witco with trade(brand)name Witconate
Buy.
Preferred short chain surfactants used herein is cacodyl oxide base octylame and octyl sulfate.Be applicable to that short chain surfactants herein is preferably compatible with hypochlorite.According to the present invention, the short chain surfactants that composition comprises is counted 0.5%-15% with the gross weight of composition, preferred 0.5%-10%, more preferably 1%-6%, most preferably 2%-4%.
Observed and in comprising the composition of described general amine oxide in the art, added the decline that short chain surfactants can cause described composition viscosity.Have been found that the viscosity that does not influence composition by the mixture that uses specific long chain amine oxide now.
The mixture that is applicable to long amine oxide herein according to the present invention is according to formula R
1R
2R
3NO comprises wherein R
1Be C
14First amine oxide of alkyl and R wherein
1Be C
12Alkyl or R wherein
1Be C
16The amine oxide mixture of second amine oxide of alkyl or its mixture.R in described first and second amine oxides
2And R
3Be C independently
1-C
3Alkyl.
Described first amine oxide and described wherein R
1Be C
12The ratio of second amine oxide of alkyl is 0.3-10, preferably 0.5-5 and wherein said first amine oxide and wherein R
1Be C
16The ratio of second amine oxide of alkyl is 0.2-4.5, preferred 0.5-2.
Preferred long chain amine oxide used herein can be Genaminox
RLA, Genaminox
RMY-X (can buy) from Hoechst, C
12-C
14Aromox
RDMMCO-W, (AKZO), Aromox DM14D-W, (AKZO) and Aromox
RDM14D-W (AKZO).Be applicable to that long-chain tensio-active agent herein is preferably compatible with hypochlorite.According to the present invention, the mixture of the long chain amine oxide of the present invention that described composition comprises is counted 1.5%-10% with the gross weight of composition, preferred 1.5%-7%, more preferably 2%-5% and most preferably 2.5%-4%.Composition according to the present invention comprises that the mixture of described long chain amine oxide makes composition comprise respectively with the gross weight of composition and counts 0.4%-6%, above-mentioned first amine oxide and the 0.5%-4% of preferred 0.5%-4%, above-mentioned second amine oxide of preferred 0.5%-3%.
Composition according to the present invention comprises the mixture and the above-mentioned short chain surfactants of above-mentioned long chain amine oxide, and its ratio is 0.25-3, preferred 0.5-2.
Long chain amine oxide of the present invention makes viscosity be increased to 50cps-2000cps, and preferred 100cps-700cps measures under revolution 50r.p.m or 100r.p.m condition with the number of axle 2 or 3 or 4 at 25 ℃ with Brookfield viscometer RVT.
Can further contain other long-chain tensio-active agent according to composition of the present invention as optional components.Suitable long-chain surface-active substance comprises the alkyl sarkosine, paraffin sulfonate, alkyl-sulphate and sulfated alkyl ether.
The preferred optional component that adds is C
12Alkyl-sulphate, short chain surfactants and C
12The weight ratio of alkyl-sulphate is 1: 4-4: 1.
Another optional components of the present invention is C
8-C
18An alkali metal salt of lipid acid.Be applicable to that lipid acid herein can be any C
8-C
18Lipid acid, preferred saturated lipid acid fully, preferred sodium, potassium or lithium salts, more preferably sodium salt.It is sad that suitable fatty acids can be selected from, capric acid, and lauric acid, tetradecanoic acid, palmitinic acid, stearic acid and suitably having hardened comes from for example tallow of natural origin, Oleum Cocois, the mixture of the lipid acid of peanut oil and babassu oil.
Composition according to the present invention comprises with composition total weight counts 0.2%-2%, the lipid acid of preferred 0.5%-1%.Described lipid acid can be as additional thickening auxiliary agent with as froth suppressor.
Another optional component that adds according to the present invention is a hypochlorite bleaching, preferably the alkaline metal hypochlorite.Although the alkaline metal hypochlorite is preferred, other hypochlorite compound also can be used for herein, and they can be selected from calcium and magnesium hypochlorite.The alkaline metal hypochlorite who preferably is used for herein is a clorox.The above-mentioned hypochlorite bleaching that composition according to the present invention comprises is such, and it makes that the amount of reactive chlorine in composition is 0.4%-4%, preferably 1%-2%.The component of thing combined according to the invention is chosen such that it makes that composition and hypochlorite are compatible.
What of thing combined according to the invention was non-imposed requires pH greater than 12, is preferably greater than 12.5, more preferably greater than 12.8.Can realize this point by adding caustic alkali.The suitable caustic alkali that is used for herein comprises sodium hydroxide and potassium hydroxide.
Can also comprise a certain amount of additional ingredients according to composition of the present invention, for example tinting material and spices.In addition, can comprise that according to composition of the present invention silicate is as corrosion inhibitor.
By the well-known method in present technique field, for example be set forth in the method among the GB1329086, prepare according to composition of the present invention.Can prepare by at room temperature in a nonmetallic device, mixing all components according to composition of the present invention.Preferably, at first, short chain surfactants prepares surfactant mixture by being joined in the long-chain component.Add spices then and the alkaline metal hypochlorite stirs simultaneously.All mix the back at other all components and added tinting material.
Composition of the present invention can be used for various cleaning purposes, makes that compare the time that sticks to the surface with non-thickening composition longer thereby for example clean described composition that crust has thickening character.Described composition is particularly suitable for cleaning the inclined surface that comprises water closet.
In another embodiment of the invention, composition herein is used for the dishwashing detergent purposes, comprises hand-washing and washing with automatic dishwasher.We find that described composition has good especially cleaning performance, are especially handling tableware, particularly plate when it as pretreatment compositions, pot, kitchen grid and/or any removal dirt aspect during by the food dirt/black kitchen utensils of crust.
Therefore, the present invention includes the method for handling tableware, it comprises these steps: described tableware is contacted with composition according to the present invention with dilution or pure form, allow described tableware and described composition keep in touch one period that is enough to handle described tableware then, preferred 2-15 minute, in water, wash described tableware then to remove described composition.Described herein method can be followed a subsequent step, and wherein said tableware is with comprising that a kind of dishwashing detergent product of the present invention or any other conventional dishwashing detergent product wash.In fact described subsequent step can be the hand washing operation or wash in automatic dish washer.
On the other hand, a step can be arranged before the method for described in this article processing tableware, wherein said tableware be immersed in the water before composition of the present invention contacts.
" with the form of its dilution " meaning in this article is meant can dilute with water according to composition of the present invention.General weaker concn is that composition of the present invention is 0.5%-3% (weight) in water.Described dilution can take place before composition of the present invention is used for described tableware or take place simultaneously.
As used at above-mentioned paragraph, " processing " speech comprises with the form of the composition that contains tensio-active agent according to the present invention and washs and bleach with the form that the present invention preferably contains the composition of hypochlorite.
Can illustrate by the following example according to composition of the present invention.Embodiment
A B C P EC
12Amine oxide 1.0 1.0 0.6 0.7 1.3C
14Amine oxide 1.8 2.3 2.2 2.0 3.1C
16Amine oxide-----octyl sulfate 1.5 2.0 2.0 1.0 3.0 lipid acid 0.5 0.5---hypochlorite 1.1 1.1 1.65 1.65 1.4 sodium hydroxide 0.8 0.8 1.3 1.3 1.1 spices 0.15 0.27-0.2 water+small powder (equal amount) viscosity, cps 450 620 446 1,600 1740
F G H I JC
12Amine oxide-----C
14Amine oxide 1.5 0.5 1.9 1 1.5C
16Amine oxide 1.5 2 1.6 1 1.1 octyl sulfates 33332 lipid acid 0.6 0.9 0.8 0.9 0.6 hypochlorites 1.6 1.7 1.5 1.6 1.7 sodium hydroxide 11 1.3 1.3 1.3 spices 0.2 0.2 0.2 0.2 0.2 water+small powder (equal amount) viscosity, cps 130 80 300 100 450
K LC
12Amine oxide--C
14Amine oxide 1.6 1.5C
16Amine oxide 1.5 1 octyl sulfates 33 lipid acid 0.9 0.9 lauryl sulfates 1.5 1 hypochlorites 1.5 1.70 sodium hydroxide 1.31 1.3 spices 0.2 0.2 water+small powder (equal amount) viscosity, cps 300 100
M NC
12Amine oxide--C
14Amine oxide 1.60 1.75C
16Amine oxide 1.50 1.50 octyl sulfates 3.00 3.00C
12Alkyl-sulphate 1.50-lipid acid 0.90 0.50 hypochlorite 1.73 1.73 sodium hydroxide 1.30 1.30 spices 0.275 0.275 water+small powder (equal amount) viscosity, cps 100-500 100-500
O PC
14Amine oxide 6 4.5C
16Amine oxide 43 octyl sulfates 7 5C
10Amine oxide 32 lipid acid 1.2 0.9 sodium hydroxide 0.6 4 spices-0.8 water+small powder (equal amount) viscosity, cps 62 282
Claims (11)
- One kind to have viscosity be that 50cps-2000cps contains according to formula R 1R 2R 3The aqueous composition of the mixture of the long chain amine oxide of NO, wherein R 2And R 3Be respectively C 1-C 3Alkyl is characterized in thatDescribed composition also contains the short chain surfactants that comprises a hydrophobic part and a hydrophilic segment, and the chain length of wherein said hydrophobic part is C 6-C 10Comprise with the mixture of described long chain amine oxide-R wherein 1Be C 14First amine oxide of alkylWith-R wherein 1Be C 12Alkyl or C 16Alkyl, or second amine oxide of its mixture andWherein, described first amine oxide and described wherein R 1Be C 12The ratio of second amine oxide of alkyl is 0.3-10 and wherein said first amine oxide and R wherein 1Be C 16The ratio of second amine oxide of alkyl is 0.2-4.5.
- 2. according to the aqueous detergent compositions of claim 1, it is further characterized in that the ratio of the mixture of described short chain surfactants and described long chain amine oxide is 3-0.25.
- 3. according to the aqueous detergent compositions of arbitrary aforementioned claim, comprise the mixture of counting the described long chain amine oxide of 1.5%-10% with composition total weight.
- 4. according to the aqueous detergent compositions of arbitrary aforementioned claim, comprise the described short chain surfactants of counting 0.5%-15% with composition total weight.
- 5. according to the aqueous detergent compositions of arbitrary aforementioned claim, the mixture of wherein said long chain amine oxide is selected from R 1R 2R 3NO, wherein R 2And R 3It is methyl.
- 6. according to the aqueous detergent compositions of arbitrary aforementioned claim, wherein preferred short chain surfactants is selected from octyl sulfate and oxidation octyldimethyl amine.
- 7. according to the aqueous detergent compositions of arbitrary aforementioned claim, it is further characterized in that described composition contains the alkaline metal hypochlorite.
- 8. according to the aqueous detergent compositions of claim 7, its pH is higher than 12.5.
- 9. according to the aqueous detergent compositions of arbitrary aforementioned claim, it also contains long chain alkyl sulfates, preferred C 12Alkyl-sulphate.
- 10. method of handling tableware comprises these steps:-the composition according to arbitrary aforementioned claim of described tableware with or dilute form pure with it contacted,-allow described tableware and described composition keep in touch one period that is enough to handle tableware then,-in water, wash described tableware then to remove described composition.
- 11. according to the composition of arbitrary claim of claim 1-9 in order to clean inclined surface, the preferably purposes of water closet.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP93202186 | 1993-07-23 | ||
| EP93202186.8 | 1993-07-23 | ||
| EP93870222.2 | 1993-11-22 | ||
| EP93870222 | 1993-11-22 | ||
| EP94870002 | 1994-01-10 | ||
| EP94870002.6 | 1994-01-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1129951A true CN1129951A (en) | 1996-08-28 |
| CN1057790C CN1057790C (en) | 2000-10-25 |
Family
ID=27235316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94193203A Expired - Fee Related CN1057790C (en) | 1993-07-23 | 1994-07-18 | Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0711335A4 (en) |
| JP (1) | JP3923074B2 (en) |
| CN (1) | CN1057790C (en) |
| AU (1) | AU7366294A (en) |
| CA (1) | CA2167482C (en) |
| CZ (1) | CZ20296A3 (en) |
| HU (1) | HU219162B (en) |
| MX (1) | MXPA94005640A (en) |
| WO (1) | WO1995003383A1 (en) |
| ZA (1) | ZA945410B (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0916719A3 (en) * | 1992-11-03 | 1999-07-14 | The Procter & Gamble Company | Cleaning with short-chain surfactants |
| WO1996007723A1 (en) * | 1994-09-06 | 1996-03-14 | S.C. Johnson & Son, Inc. | A cleaning composition comprising lipase and amylase enzymes |
| DE19621048C2 (en) * | 1996-05-24 | 2000-06-21 | Henkel Kgaa | Aqueous bleach and disinfectant |
| DE19626906C1 (en) * | 1996-07-04 | 1998-03-12 | Henkel Kgaa | Means for cleaning hard surfaces |
| US5922669A (en) * | 1997-09-10 | 1999-07-13 | Albemarle Corporation | No-rub hard surface cleaner comprising an alcohol ethoxylate-amine oxide surfactant mixture and a nitrogenous builder in aqueous solution |
| EP0916718A1 (en) | 1997-10-14 | 1999-05-19 | The Procter & Gamble Company | Cleaning and disinfecting compositions |
| GB2334722B (en) * | 1998-02-25 | 2002-04-24 | Reckitt & Colman Inc | Aqueous cleaning composition for removing soap scum |
| GB2334721B (en) * | 1998-02-25 | 2002-06-12 | Reckitt & Colman Inc | Cleansing composition |
| DE10343730A1 (en) * | 2003-09-22 | 2005-04-21 | Clariant Gmbh | Highly concentrated aqueous solution of amphoteric surfactants |
| CN101798551B (en) * | 2010-04-30 | 2012-01-18 | 北京绿伞化学股份有限公司 | Concentrated tableware detergent and preparation method thereof |
| EP2978357A1 (en) * | 2013-03-26 | 2016-02-03 | The Procter & Gamble Company | Articles for cleaning a hard surface |
| EP2978832A1 (en) * | 2013-03-26 | 2016-02-03 | The Procter & Gamble Company | Cleaning compositions for cleaning a hard surface |
| EP3034593B1 (en) | 2014-12-19 | 2019-06-12 | The Procter and Gamble Company | Liquid detergent composition |
| EP3078731A1 (en) * | 2015-04-10 | 2016-10-12 | Henkel AG & Co. KGaA | Cleaning composition comprising bleach |
| WO2016200343A1 (en) * | 2015-06-09 | 2016-12-15 | Hayat Kimya Sanayi Anonim Sirketi | Aqueous, thickened and transparent bleaching compositions |
| JP6585417B2 (en) * | 2015-08-04 | 2019-10-02 | 花王株式会社 | How to clean glass or ceramic tableware |
| EP3257926A1 (en) * | 2016-06-17 | 2017-12-20 | The Procter and Gamble Company | Liquid detergent composition |
| JP2019156929A (en) * | 2018-03-09 | 2019-09-19 | 株式会社ニイタカ | Foaming cleaner composition and cleaning method |
| EP3670637A1 (en) * | 2018-12-18 | 2020-06-24 | Henkel AG & Co. KGaA | Viscosity regulation in handwash agents |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3928249A (en) * | 1972-02-07 | 1975-12-23 | Procter & Gamble | Liquid detergent composition |
| US3892669A (en) * | 1972-10-27 | 1975-07-01 | Lever Brothers Ltd | Clear fabric-softening composition |
| US3953382A (en) * | 1973-05-30 | 1976-04-27 | Lever Brothers Company | Detergent compositions |
| ATE17595T1 (en) * | 1981-11-07 | 1986-02-15 | Procter & Gamble | DETERGENT COMPOSITIONS. |
| GB8630845D0 (en) * | 1986-12-24 | 1987-02-04 | Ici Plc | Bleaching compositions |
| GB8917626D0 (en) * | 1989-08-02 | 1989-09-20 | Quest Int | Perfumed bleach compositions |
-
1994
- 1994-07-18 CZ CZ96202A patent/CZ20296A3/en unknown
- 1994-07-18 HU HU9600139A patent/HU219162B/en not_active IP Right Cessation
- 1994-07-18 EP EP94922613A patent/EP0711335A4/en not_active Withdrawn
- 1994-07-18 WO PCT/US1994/008089 patent/WO1995003383A1/en not_active Application Discontinuation
- 1994-07-18 CN CN94193203A patent/CN1057790C/en not_active Expired - Fee Related
- 1994-07-18 JP JP50525395A patent/JP3923074B2/en not_active Expired - Fee Related
- 1994-07-18 CA CA002167482A patent/CA2167482C/en not_active Expired - Fee Related
- 1994-07-18 AU AU73662/94A patent/AU7366294A/en not_active Abandoned
- 1994-07-22 MX MXPA94005640A patent/MXPA94005640A/en not_active IP Right Cessation
- 1994-07-22 ZA ZA945410A patent/ZA945410B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HU219162B (en) | 2001-02-28 |
| AU7366294A (en) | 1995-02-20 |
| CZ20296A3 (en) | 1996-07-17 |
| CA2167482C (en) | 1999-12-28 |
| EP0711335A4 (en) | 1997-07-09 |
| CN1057790C (en) | 2000-10-25 |
| EP0711335A1 (en) | 1996-05-15 |
| JP3923074B2 (en) | 2007-05-30 |
| HUT73751A (en) | 1996-09-30 |
| MXPA94005640A (en) | 2005-08-19 |
| JPH09500680A (en) | 1997-01-21 |
| ZA945410B (en) | 1995-02-28 |
| HU9600139D0 (en) | 1996-03-28 |
| CA2167482A1 (en) | 1995-02-02 |
| WO1995003383A1 (en) | 1995-02-02 |
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