CN117925333A - Cleaning agent for farms and preparation method thereof - Google Patents
Cleaning agent for farms and preparation method thereof Download PDFInfo
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- CN117925333A CN117925333A CN202410104454.7A CN202410104454A CN117925333A CN 117925333 A CN117925333 A CN 117925333A CN 202410104454 A CN202410104454 A CN 202410104454A CN 117925333 A CN117925333 A CN 117925333A
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- CN
- China
- Prior art keywords
- cleaning agent
- sodium
- alkyl glycoside
- gemini
- betaine
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 61
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 229930182470 glycoside Natural products 0.000 claims abstract description 71
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 52
- 150000002338 glycosides Chemical class 0.000 claims abstract description 41
- -1 alkyl glycoside sulfosuccinate salt Chemical class 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004088 foaming agent Substances 0.000 claims abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 66
- 239000011734 sodium Substances 0.000 claims description 30
- 229910052708 sodium Inorganic materials 0.000 claims description 28
- 239000002738 chelating agent Substances 0.000 claims description 26
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 26
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 25
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 21
- 229960003237 betaine Drugs 0.000 claims description 19
- 239000004094 surface-active agent Substances 0.000 claims description 15
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000004115 Sodium Silicate Substances 0.000 claims description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 239000001509 sodium citrate Substances 0.000 claims description 5
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 4
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 229940075468 lauramidopropyl betaine Drugs 0.000 claims description 3
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 239000000706 filtrate Substances 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 235000019794 sodium silicate Nutrition 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000006260 foam Substances 0.000 abstract description 30
- 230000000694 effects Effects 0.000 abstract description 15
- 239000010865 sewage Substances 0.000 abstract description 11
- 238000004140 cleaning Methods 0.000 abstract description 9
- 238000005187 foaming Methods 0.000 abstract description 7
- 238000011010 flushing procedure Methods 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 35
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 25
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 21
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 19
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 15
- 229960001484 edetic acid Drugs 0.000 description 15
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 10
- 239000003599 detergent Substances 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 229930182478 glucoside Natural products 0.000 description 4
- 150000008131 glucosides Chemical class 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- COCZYVIRPAUEIY-UHFFFAOYSA-N 2-(sulfomethyl)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)CS(O)(=O)=O COCZYVIRPAUEIY-UHFFFAOYSA-N 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- XFLNVMPCPRLYBE-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;tetrahydrate Chemical compound O.O.O.O.[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XFLNVMPCPRLYBE-UHFFFAOYSA-J 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 239000010794 food waste Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000006277 sulfonation reaction Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- 125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- QKZIVVMOMKTVIK-UHFFFAOYSA-M anilinomethanesulfonate Chemical compound [O-]S(=O)(=O)CNC1=CC=CC=C1 QKZIVVMOMKTVIK-UHFFFAOYSA-M 0.000 description 1
- 239000010828 animal waste Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 150000002646 long chain fatty acid esters Chemical class 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 150000003365 short chain fatty acid esters Chemical class 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a cleaning agent for a farm and a preparation method thereof, and belongs to the technical field of cleaning agents. At least comprises Gemini alkyl glycoside sulfosuccinate and foaming agent; the structural formula of the Gemini alkyl glycoside sulfosuccinate salt is as follows: X-R1-N (R3) 2-R-N(R4)2 -R2-X; wherein R is a C2-C4 alkyl group; r1 and R2 are alkyl glycoside sulfosuccinate groups; r3 and R4 are the same or different alkyl groups; x is Na +, K +, or NH 4 +. According to the Gemini alkyl glycoside sulfosuccinate with the amphoteric high surface activity, more hydrophilic groups are introduced, so that the foamability, wettability and foam wall-hanging property of the whole cleaning agent are improved, the foaming property is good, the generated foam is rich and fine, the foam is attached to the surface of the sewage, the contact area with the sewage is increased, the three are combined, and the high foamability, wettability and long-acting wall-hanging property are mutually matched, so that the intractable sewage can be removed quickly, the water flushing is facilitated, and the cleaning efficiency of the cleaning agent is improved.
Description
Technical Field
The invention relates to the technical field of cleaning agents, in particular to a cleaning agent containing Gemini alkyl glycoside sulfosuccinate for farms and a preparation method thereof.
Background
The breeding industry is greatly developed, and in the breeding process, food residues, animal wastes and the like need to be cleaned in order to keep the environment and ensure the growth health of animals. Most of the existing cleaning agents use surfactants such as alkylphenol ethoxylates, alkylaryl sulfonates or nonylphenol ethoxylates as main components and phosphate and other builders as auxiliary components. However, the production process of these conventional cleaning agents is harmful to the environment, the washing wastewater is difficult to biodegrade, and the use of phosphate can also lead to eutrophication of water. The alkyl glycoside sulfosuccinate has more hydrophilic groups in water, so that the solubility is better, and the alkyl glycoside sulfosuccinate has higher surface activity and better wettability and foaming performance, so that the alkyl glycoside sulfosuccinate is widely applied to daily cleaning. The alkyl glycoside sulfomethylsuccinate surfactant disclosed in publication No. CN106459121A, which is mainly used for daily use; the alkyl glycoside-based micelle thickening for surfactant systems disclosed in publication number CN104411289a, wherein rheology modifiers are disclosed comprising alkyl glycoside fatty acid ester mixtures comprising long chain fatty acid esters of alkyl glycosides and short chain fatty acid esters of alkyl glycosides. It is also mainly used for personal care such as shampoo, bath lotion, liquid soap, facial cleanser, hand soap, etc.; the technical scheme of the composition for reducing the irritation of the detergent disclosed in the publication No. CN115141691A is that the detergent is obtained by combining C12-C16 alkyl glycoside sulfosuccinate, glycereth and sodium lactate, and the composition mainly solves the problems of reducing the irritation to human skin and facilitating water flushing. The mask cleaning agent for the OLED disclosed in publication No. CN113862088A comprises organic acid, a chelating agent and a surfactant, wherein the surfactant is a surfactant compounded by alkyl glycoside APG and alkyl glycoside sulfosuccinate salt APG-SS. The technical problem that it solves is to the washing of mask after production, promotes the product percent of pass.
In summary, the alkyl glycoside sulfomethylsuccinate surfactant is mainly applied to personal daily care and washing of precision parts in the prior art, but the alkyl glycoside sulfomethylsuccinate surfactant is used for achieving the effects of disinfection and easy flushing, and has less cleaning effect on solid pollutants. The sewage in the farm is mainly food residues and excreta, the solid content of the sewage is high, and the adhesion is high, so that the farm equipment, the ground, the wall surface and the like are not thoroughly cleaned.
Disclosure of Invention
In order to solve the problems, the invention provides the cleaning agent for the farm and the preparation method thereof, and the cleaning agent is mainly applied to the farm, can clean the residual sewage with larger viscosity and more solids in the farm, has good cleaning effect, has no irritation to animals, and is environment-friendly.
In order to achieve the above object, the present invention is achieved by the following technical scheme:
a cleaning agent for farms, comprising at least: gemini alkyl glycoside sulfosuccinate salt and foaming agent;
The structural formula of the Gemini alkyl glycoside sulfosuccinate salt is as follows:
X-R1-N(R3)2-R-N(R4)2-R2-X；
Wherein R is a C2-C4 alkyl group; r1 and R2 are alkyl glycoside sulfosuccinate groups; r3 and R4 are the same or different alkyl groups; x is Na +, K + or NH 4 +;
The foaming agent comprises sulfonate and/or betaine.
Further, R3 and R4 are the same or different C2-C4 alkyl groups.
Further, R1 and R2 are C8-C16 alkyl glycoside sulfosuccinate groups.
Further, the sulfonate comprises one or more of alpha-sodium alkenyl sulfonate, sodium dodecyl benzene sulfonate and sodium dodecyl sulfate.
Further, one or more of betaine dodecyl dimethyl betaine, tetradecyl dimethyl betaine, octadecyl dimethyl betaine, dodecyl dihydroxyethyl betaine, lauramidopropyl betaine and cocoamidopropyl betaine.
Further, the cleaning agent for the farms comprises the following components in percentage by mass: 1-10% of Gemini alkyl glycoside sulfosuccinate, 0.1-5% of sulfonate, 1-10% of betaine, 0-20% of auxiliary agent and the balance of water.
Further, the auxiliary agent comprises any one or more of alkali, chelating agent and corrosion inhibitor.
Further, the alkali comprises sodium hydroxide or one or more of aqueous solution thereof, sodium bicarbonate, sodium silicate and sodium metasilicate.
Further, the chelating agent comprises one or more of tetra sodium ethylenediamine tetraacetate, sodium citrate, sodium polyacrylate and derivatives thereof.
Further, the corrosion inhibitor comprises one or more of sodium tripolyphosphate, sodium citrate and benzotriazole.
The invention also provides a preparation method of the cleaning agent for the farm, which comprises the following steps: adding Gemini alkyl glycoside sulfosuccinate salt, sulfonate, betaine, an auxiliary agent and water into a reaction kettle, uniformly stirring, and filtering to obtain filtrate, namely the cleaning agent for the farm.
The cleaning agent for the farms and the preparation method thereof have the beneficial effects that:
(1) According to the Gemini alkyl glycoside sulfosuccinate added in the invention, the cationic quaternary ammonium salt is used for modifying the alkyl glycoside sulfosuccinate to obtain the amphoteric high-surfactant, more hydrophilic groups are introduced into the surfactant, the foamability, wettability and foam wall-hanging property of the whole cleaning agent are improved, the foaming performance is good, the generated foam is rich and fine, the foam is attached to the surface of the sewage, and the contact area between the foam and the sewage is increased; the wetting property can enable the cleaning agent to quickly enter the solid content, so that the cohesiveness of the cleaning agent is reduced; the wall built-up performance can prolong the contact time of the foam and the sewage, and the foam is kept for a long time and stabilizes the wall built-up, so that the foam is further combined with the sewage. The three are combined, matched, so that refractory pollutants can be removed quickly, water flushing is facilitated, and the cleaning efficiency of the cleaning agent is improved.
(2) The invention has good foaming performance, rich foam and good foam stabilizing effect under the condition of 10-120 times dilution by compounding Gemini alkyl glycoside sulfosuccinate, alpha-alkenyl sodium sulfonate and cocamidopropyl betaine.
(3) The Gemini alkyl glycoside sulfosuccinate salt disclosed by the invention is introduced with quaternary ammonium salt, has bactericidal property, can achieve a good bactericidal effect without adding bactericide or antibacterial agent, and is small in use amount and good in bactericidal effect.
(4) The cleaning agent disclosed by the invention has the advantages of strong hydrophilicity, good compatibility with environment and good biodegradability, and the cleaned sewage is not harmful to the environment and the water body is not eutrophicated.
Drawings
In order to more clearly illustrate the embodiments of the invention or the technical solutions of the prior art, the drawings which are used in the description of the embodiments or the prior art will be briefly described, it being obvious that the drawings in the description below are only some embodiments of the invention, and that other drawings can be obtained according to these drawings without inventive faculty for a person skilled in the art.
FIG. 1 is a schematic view of the wall built-up of a glass surface at various times in example 5 of the present invention;
FIG. 2 is a schematic representation of the foam effect after 88-fold dilution of comparative example 8 and example 5, respectively;
fig. 3 is a schematic diagram of the foam effect after 100-fold dilution of comparative example 8 and example 5, respectively.
Detailed Description
In order that the manner in which the invention may be better understood, a more particular description of the invention will be rendered by reference to specific embodiments thereof which are illustrated in the appended drawings. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The cleaning agent for the farm comprises the following components in percentage by mass: 1-10% of Gemini alkyl glycoside sulfosuccinate, 0.1-5% of sulfonate, 1-10% of betaine, 0-20% of auxiliary agent and the balance of water.
The preparation method of the Gemini alkyl glycoside sulfosuccinate salt comprises the following steps:
(1) Carrying out chlorination reaction on alkyl glycoside and hydrochloric acid according to the mol ratio of 1:1.2 at the temperature of 55 ℃ to obtain chloro glycoside; reacting the chloro-glycoside with diethylamine to obtain glycosyl tertiary amine;
(2) Adding 1, 2-dibromoethane into the glycosyl tertiary amine, and reacting the glycosyl tertiary amine and the 1, 2-dibromoethane according to the mol ratio of 2:1 at the temperature of 55 ℃ to obtain Gemini alkyl glycoside;
(3) Sulfonation reaction is carried out on Gemini alkyl glycoside and sulfurous acid, maleic anhydride under the catalysis of p-toluenesulfonic acid, so as to obtain Gemini alkyl glycoside sulfosuccinate; gemini alkyl glycoside sulfosuccinate salt is a compound of formula (I):
The sulfonation reaction in this step is a routine operation by a person skilled in the art, and the proportion and conditions of each component are common general knowledge and are not described in detail herein.
Example 1
The cleaning agent for the farm comprises the following components in percentage by mass: 1% of Gemini alkyl glycoside sulfosuccinate sodium, 0.6% of alpha-alkenyl sodium sulfonate, 1% of cocamidopropyl betaine, 1% of sodium hydroxide and the balance of water.
Example 2
The cleaning agent for the farm comprises the following components in percentage by mass: 2% of Gemini alkyl glycoside sulfosuccinate sodium, 1.2% of alpha-alkenyl sodium sulfonate, 2% of cocamidopropyl betaine, 2% of sodium hydroxide and the balance of water.
Example 3
The cleaning agent for the farm comprises the following components in percentage by mass: 3% of Gemini alkyl glycoside sulfosuccinate sodium, 1.8% of alpha-alkenyl sodium sulfonate, 3% of cocamidopropyl betaine, 3% of sodium hydroxide, 0.1% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Example 4
The cleaning agent for the farm comprises the following components in percentage by mass: 4% of Gemini alkyl glycoside sulfosuccinate sodium, 2.4% of alpha-alkenyl sodium sulfonate, 5% of cocamidopropyl betaine, 5% of sodium hydroxide, 0.1% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Example 5
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glycoside sulfosuccinate sodium, 3% of alpha-alkenyl sodium sulfonate, 7% of cocamidopropyl betaine, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Example 6
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glycoside sulfosuccinate sodium, 3% of sodium dodecyl benzene sulfonate, 7% of cocamidopropyl betaine, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Example 7
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glycoside sodium sulfosuccinate, 3% of sodium dodecyl sulfate, 7% of cocamidopropyl betaine, 5% of sodium bicarbonate, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Example 8
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glycoside sulfosuccinate sodium, 3% of alpha-alkenyl sodium sulfonate, 7% of dodecyl dimethyl betaine, 5% of sodium silicate, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Example 9
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glucoside sulfosuccinate sodium, 3% of alpha-alkenyl sodium sulfonate, 7% of tetradecyl dimethyl betaine, 5% of sodium metasilicate, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Example 10
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glycoside sodium sulfosuccinate, 3% of alpha-alkenyl sodium sulfonate, 7% of octadecyl dimethyl betaine, 5% of sodium hydroxide, 0.2% of chelating agent sodium citrate, 0.2% of benzotriazole and the balance of water.
Example 11
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glycoside sulfosuccinate sodium, 3% of alpha-alkenyl sodium sulfonate, 7% of dodecyl dihydroxyethyl betaine, 5% of sodium hydroxide, 0.2% of chelating agent sodium polyacrylate, 0.2% of sodium tripolyphosphate and the balance of water.
Example 12
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glycoside sulfosuccinate sodium, 3% of alpha-alkenyl sodium sulfonate, 7% of lauramidopropyl betaine, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid tetrasodium salt, 0.2% of sodium citrate and the balance of water.
Comparative example 1
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glycoside sodium sulfosuccinate, 7% of cocamidopropyl betaine, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Comparative example 2
The cleaning agent for the farm comprises the following components in percentage by mass: 8% of Gemini alkyl glycoside sodium sulfosuccinate, 7% of cocamidopropyl betaine, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Comparative example 3
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glucoside sulfosuccinate sodium, 3% of alpha-alkenyl sodium sulfonate, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid tetrasodium and the balance of water.
Comparative example 4
The cleaning agent for the farm comprises the following components in percentage by mass: 12% of Gemini alkyl glucoside sulfosuccinate sodium, 3% of alpha-alkenyl sodium sulfonate, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid tetrasodium and the balance of water.
Comparative example 5
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glucoside sulfosuccinate sodium, 10% of alpha-alkenyl sodium sulfonate, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid tetrasodium and the balance of water.
Comparative example 6
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glycoside sodium sulfosuccinate, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Comparative example 7
The cleaning agent for the farm comprises the following components in percentage by mass: 15% of Gemini alkyl glycoside sodium sulfosuccinate, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Comparative example 8
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of C12 alkyl glycoside sulfosuccinate sodium, 3% of alpha-alkenyl sodium sulfonate, 7% of cocamidopropyl betaine, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water. The sodium alkyl glycoside sulfosuccinate of this comparative example was purchased from chemical plant in sea-ampere, jiangsu province.
Comparative example 9
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of Gemini alkyl glycoside, 3% of alpha-alkenyl sodium sulfonate, 7% of cocamidopropyl betaine, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water. Gemini alkyl glycoside in this comparative example was purchased.
Comparative example 10
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of ester group-containing gemini quaternary ammonium salt, 3% of alpha-alkenyl sodium sulfonate, 7% of cocamidopropyl betaine, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water. The quaternary ammonium salt containing ester group in this comparative example was produced by the company of rayo surfactant, inc.
Comparative example 11
The cleaning agent for the farm comprises the following components in percentage by mass: 5% of nonionic alkyl glycoside, 3% of alpha-sodium alkenyl sulfonate, 7% of cocamidopropyl betaine, 5% of sodium hydroxide, 0.2% of chelating agent ethylene diamine tetraacetic acid and the balance of water.
Determination of foam Properties
The cleaning agents obtained in examples 1 to 12 and comparative examples 1 to 11 were experimentally examined. Determination methods reference GB/T7462-1994 improved Ross-Miles method for determination of foaming Capacity of surfactants
The data obtained are shown in table 1:
TABLE 1 foaming Properties
As can be seen from table 1, the foam height of example 1 is the same as that of comparative example 4 and comparative example 7, because the concentration of Gemini alkyl glycoside sulfosuccinate salt in example 1 is smaller, while the concentration of Gemini alkyl glycoside sulfosuccinate salt in comparative example 4 and comparative example 7 is higher, and even if the betaine component is reduced, the foam performance is still better, indicating that Gemini alkyl glycoside sulfosuccinate salt has an excellent effect in enhancing foam performance.
As can be seen from examples 5 and comparative examples 1-7, comparative examples 1-2 have better foam performance in the absence of the sodium alpha-alkenyl sulfonate and comparative examples 3-5 in the absence of the cocamidopropyl betaine, and the liquid separation time is longer, which indicates that the synergistic effect of Gemini alkyl glycoside sulfosuccinate, sodium alpha-alkenyl sulfonate and cocamidopropyl betaine can greatly improve the foam performance and improve the cleaning effect.
Whereas the cleaners of comparative examples 8-10, lacking the Gemini alkyl glycoside sulfosuccinate component, used the conventional Gemini surfactant first, the foam performance was lower than that of example 5 of the present invention, while comparative example 11 used the conventional nonionic surfactant, which still had foam performance lower than that of example 5, demonstrating that the Gemini alkyl glycoside sulfosuccinate of the present invention had a decisive role in enhancing foam performance.
Cleaning effect test
The detergents obtained in examples 1 to 12 and comparative examples 1 to 11 were subjected to detergency tests as samples, the detergency was one of the detergency tests in annex a in QBT4314-2012 alkaline cleaners for food tools and industrial equipments, and the results are shown in table 2:
Table 2 cleaning effect
As can be seen from Table 2, the detergency of the detergents of examples 1 to 12 and comparative examples 1 to 11 were measured as shown in Table 2, and it can be seen from the tables that the detergents of examples 4 and 5 were high in detergency. Comparing example 5 with comparative examples 1-6, comparative examples 1-6 showed a greatly reduced detergency performance compared with example 5 in the absence of the sodium alpha-alkenyl sulfonate, cocamidopropyl betaine component, demonstrating that sodium alpha-alkenyl sulfonate, cocamidopropyl betaine of the present invention has an important effect in improving detergency. Example 5 in comparison with comparative examples 8-11, comparative examples 8-11 use conventional Gemini surfactants and nonionic surfactants, and lack sodium Gemini alkyl glycoside sulfosuccinate, which also has lower detergency than example 5, indicating that sodium Gemini alkyl glycoside sulfosuccinate has some effect on detergency. The combination of example 5 and comparative examples 1-11 shows that the detergency of example 5 is significantly higher than that of comparative examples 1-11, the detergency is higher than 98%, the detergency is strong, and the detergency is significantly improved by the synergistic effect of Gemini alkyl glycoside sulfosuccinate sodium, alpha-alkenyl sodium sulfonate and cocamidopropyl betaine.
Wall built-up performance test
The cleaning agent obtained in example 5 was applied to the surface of glass by a foam gun (ambient temperature: 30.+ -. 2 ℃ C., surface temperature: 26.+ -. 2 ℃ C.) and observed in time periods of 0min, 3min, 5min, 10in and 30min, respectively, and the obtained effects were shown in FIG. 1.
As can be seen from FIG. 1, the foam produced by the foam cleaning agent of the invention has wall built-up property at 30min and lasting wall built-up property. It can be seen from the figure that the foam begins to expand and collapse to form a large number of rich foams, giving itself flow and wetting characteristics.
Meanwhile, the results obtained by diluting example 5 and comparative example 8 88 times and 120 times, respectively, and foaming were carried out are shown in FIGS. 2 and 3.
As can be seen from fig. 2 and 3, the foam of the embodiment 5 of the present invention is richer and finer, and the richer and finer foam can improve the cleaning effect.
Reference herein to "an embodiment" means that a particular feature, structure, or characteristic described in connection with the embodiment may be included in at least one embodiment of the invention. The appearances of such phrases in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments. Those of skill in the art will explicitly and implicitly appreciate that the embodiments described herein may be combined with other embodiments.
Finally, it should be noted that: the embodiment of the invention is disclosed only as a preferred embodiment of the invention, and is only used for illustrating the technical scheme of the invention, but not limiting the technical scheme; although the invention has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art will understand that; the technical scheme recorded in the various embodiments can be modified or part of technical features in the technical scheme can be replaced equivalently; such modifications and substitutions do not depart from the spirit and scope of the corresponding technical solutions.
Claims (10)
1. A cleaning agent for farms is characterized in that: at least comprises: gemini alkyl glycoside sulfosuccinate salt and foaming agent;
The structural formula of the Gemini alkyl glycoside sulfosuccinate salt is as follows:
X-R1-N(R3)2-R-N(R4)2-R2-X；
Wherein R is a C2-C4 alkyl group; r1 and R2 are alkyl glycoside sulfosuccinate groups; r3 and R4 are the same or different alkyl groups; x is Na +, K + or NH 4 +;
The foaming agent comprises sulfonate and/or betaine surfactant.
2. The cleaning agent for farms according to claim 1, wherein: r3 and R4 are the same or different C2-C4 alkyl groups.
3. The cleaning agent for farms according to claim 1, wherein: the R1 and R2 are C8-C16 alkyl glycoside sulfosuccinate groups.
4. The cleaning agent for farms according to claim 1, wherein: the sulfonate comprises one or more of alpha-sodium alkenyl sulfonate, sodium dodecyl benzene sulfonate and sodium dodecyl sulfate.
5. The cleaning agent for farms according to claim 1, wherein: the betaine comprises one or more of dodecyl dimethyl betaine, tetradecyl dimethyl betaine, octadecyl dimethyl betaine, dodecyl dihydroxyethyl betaine, lauramidopropyl betaine and cocoamidopropyl betaine.
6. The cleaning agent for farms according to claim 1, wherein: comprises the following components in percentage by mass of 100 percent: 1-10% of Gemini alkyl glycoside sulfosuccinate, 0.1-5% of sulfonate, 1-10% of betaine, 0-20% of auxiliary agent and the balance of water.
7. The cleaning agent for farms according to claim 6, wherein: the auxiliary agent comprises one or more of alkali, chelating agent and corrosion inhibitor.
8. The cleaning agent for farms according to claim 7, wherein: the alkali comprises sodium hydroxide or one or more of aqueous solution thereof, sodium bicarbonate, sodium silicate and sodium metasilicate.
9. The cleaning agent for farms according to claim 7, wherein: the chelating agent comprises one or more of tetra sodium ethylenediamine tetraacetate, sodium citrate, sodium polyacrylate and derivatives thereof.
10. A method for preparing a cleaning agent for farms according to any one of claims 1 to 9, characterized in that: the method comprises the following steps: adding Gemini alkyl glycoside sulfosuccinate salt, sulfonate, betaine, an auxiliary agent and water into a reaction kettle, uniformly stirring, and filtering to obtain filtrate, namely the cleaning agent for the farm.
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| CN202410104454.7A CN117925333A (en) | 2024-01-25 | 2024-01-25 | Cleaning agent for farms and preparation method thereof |
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