CN1232488A - Cleaning compositions - Google Patents
Cleaning compositions Download PDFInfo
- Publication number
- CN1232488A CN1232488A CN97195199A CN97195199A CN1232488A CN 1232488 A CN1232488 A CN 1232488A CN 97195199 A CN97195199 A CN 97195199A CN 97195199 A CN97195199 A CN 97195199A CN 1232488 A CN1232488 A CN 1232488A
- Authority
- CN
- China
- Prior art keywords
- composition
- cleaning compositions
- glycine
- trimethyl
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000203 mixture Substances 0.000 title claims abstract description 131
- 238000004140 cleaning Methods 0.000 title claims abstract description 41
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000002904 solvent Substances 0.000 claims abstract description 20
- 229910021653 sulphate ion Inorganic materials 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- -1 alkyl sulphate Chemical compound 0.000 claims abstract description 13
- 239000013543 active substance Substances 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000007844 bleaching agent Substances 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical group CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 3
- CAFAOQIVXSSFSY-UHFFFAOYSA-N 1-ethoxyethanol Chemical class CCOC(C)O CAFAOQIVXSSFSY-UHFFFAOYSA-N 0.000 claims description 2
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 2
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 2
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 2
- 229960004217 benzyl alcohol Drugs 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000011010 flushing procedure Methods 0.000 claims 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 abstract 2
- IZWSFJTYBVKZNK-UHFFFAOYSA-O N-dodecyl-N,N-dimethyl-3-ammonio-1-propanesulfonic acid Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS(O)(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-O 0.000 abstract 2
- 229960003237 betaine Drugs 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 28
- 238000012360 testing method Methods 0.000 description 15
- 239000007788 liquid Substances 0.000 description 14
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 7
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 7
- 239000000645 desinfectant Substances 0.000 description 6
- 239000002932 luster Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000003352 sequestering agent Substances 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- ZEHLMSDXZOBLJS-UHFFFAOYSA-N P1(OCCCCCO1)=O.N Chemical class P1(OCCCCCO1)=O.N ZEHLMSDXZOBLJS-UHFFFAOYSA-N 0.000 description 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- BCXBKOQDEOJNRH-UHFFFAOYSA-N NOP(O)=O Chemical group NOP(O)=O BCXBKOQDEOJNRH-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- JHUXOSATQXGREM-UHFFFAOYSA-N dodecanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCCCC(=O)OO JHUXOSATQXGREM-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 229940094506 lauryl betaine Drugs 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 description 1
- JJJOZVFVARQUJV-UHFFFAOYSA-N 2-ethylhexylphosphonic acid Chemical compound CCCCC(CC)CP(O)(O)=O JJJOZVFVARQUJV-UHFFFAOYSA-N 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- UPNDZMLAOKOLQG-UHFFFAOYSA-N C(C)OC(C)O.[O] Chemical compound C(C)OC(C)O.[O] UPNDZMLAOKOLQG-UHFFFAOYSA-N 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- HMFHBZSHGGEWLO-SOOFDHNKSA-N D-ribofuranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H]1O HMFHBZSHGGEWLO-SOOFDHNKSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
- 206010021703 Indifference Diseases 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- PYMYPHUHKUWMLA-LMVFSUKVSA-N Ribose Natural products OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 description 1
- CWHJIJJSDGEHNS-MYLFLSLOSA-N Senegenin Chemical compound C1[C@H](O)[C@H](O)[C@@](C)(C(O)=O)[C@@H]2CC[C@@]3(C)C(CC[C@]4(CCC(C[C@H]44)(C)C)C(O)=O)=C4[C@@H](CCl)C[C@@H]3[C@]21C CWHJIJJSDGEHNS-MYLFLSLOSA-N 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical class OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- FAYZSSWSVMJVRQ-UHFFFAOYSA-N magnesium;phthalic acid Chemical compound [Mg].OC(=O)C1=CC=CC=C1C(O)=O FAYZSSWSVMJVRQ-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000006234 n-butoxy propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])OC([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000011012 sanitization Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 230000000392 somatic effect Effects 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 229920005613 synthetic organic polymer Polymers 0.000 description 1
- 239000009871 tenuigenin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2034—Monohydric alcohols aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
Abstract
A cleaning composition which provides effective cleaning and shine performance, said composition comprising a surfactant system comprising an alkyl sulphate and a betaine or sulphobetaine surfactant in a weight ratio of alkyl sulphate to betaine or sulphobetaine of 5.5:1 to 100:1, and wherein the pH of the composition is of at least 4. Preferably, the composition comprises a solvent for enhanced cleaning and shine performance of the composition.
Description
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a kind of cleaning compositions, said composition provides surface, the particularly effective cleaning and the luster performance of rigid surface.
Background of invention
The prescription of composition that the cleaning glossy surface can be provided is the problem of the formulator of the cleaning compositions known in this area.More specifically, the problem on surface of light is provided, and normally this lip-deep composition residues thing causes by staying, and these resistatess seem the streak that stays as after the water evaporation.When composition is used to clean the surface that lubricious material is made, as smooth ceramic tile, show window and mirror, or during as the pvc material of the widely used polyurethane-coated of North America, the problem of resistates is more remarkable.Furtherly, current a lot of products all are mixed with or can be used as no cleaning products.In this case or in these products, the problem of resistates becomes more serious.
So, needing a kind of composition, said composition can provide effective cleaning performance but provide the surface cleaned with gloss and there is not any resistates simultaneously.
For satisfying this needs, this area has proposed numerous solutions, comprises some solvent that uses acid, magnesium ion or use narration among WO 95/21229, EP 0,639,833 or the US 3,839,234.
The applicant is surprised to find that this needs also can be satisfied by compositions formulated, said composition comprises the alkyl sulfate surfactant that contains according to a certain ratio and the surfactant system of trimethyl-glycine or sultaine tensio-active agent, and the pH value of composition is at least 4.
This discovery makes us surprised especially, using when the alkyl sulfate surfactant of effective cleaning can be provided, finds can form crystal after the drying, forms the spot resistates on the surface after the cleaning; But then, when using the trimethyl-glycine be similarly effective cleaning component or sultaine tensio-active agent, can stay amorphous resistates, form sebaceous film from the teeth outwards.Unexpectedly, use alkyl-sulphate and trimethyl-glycine or sultaine tensio-active agent according to a certain ratio, effective cleaning on surface not only is provided, and above-mentioned resistates is occurred still less, or even no longer occur.
The applicant finds that further adding solvent in this surfactant system can provide enhanced cleaning function and useful to glossiness.
Therefore, advantage of the present invention is, composition is provided, and said composition can provide the effective cleaning and the surface luster performance on surface.
Another advantage of the present invention is that the composition with effective disinfectant properties is provided.
Another advantage of the present invention is that the composition to the skin gentleness is provided.
Invention is summed up
The present invention relates to a kind of cleaning compositions, said composition comprises the surfactant system that contains alkyl-sulphate and trimethyl-glycine or sultaine tensio-active agent, wherein the weight ratio of alkylsurfuric acid salt pair trimethyl-glycine or sultaine is 5.5: 1 to 100: 1, and the pH value of composition is at least 4.
In a preferred embodiment of the invention, composition includes the solvent of enhancing composition cleaning and luster performance.
In another preferred embodiment of the present invention, composition also includes the peroxygen bleach that can offer the effective disinfectant properties of composition.
The concrete statement of invention
Essential characteristic of the present invention is a surfactant system, and this system includes alkyl-sulphate and trimethyl-glycine or sultaine tensio-active agent, and wherein alkylsurfuric acid salt pair trimethyl-glycine or sultaine tensio-active agent have certain weight ratio.Alkyl sulfate surfactant
The alkyl sulfate surfactant that herein uses is that those molecular formula are ROSO
3 -M
+Material, wherein R representative contains 6 to 24 carbon atoms, more preferably 6 to 16 carbon atoms, the most preferably alkyl group of 8 to 14 carbon atoms.On behalf of water, M add dissolved cation.Alkyl group can be preferably linear configuration for the straight or branched configuration.
Alkyl-sulphate is commercial can be called EMPICOL from Albright﹠amp from Rhone Poulenc or with commodity by commodity Rhodapon by name; Wilson obtains.The preferred commercialization alkyl-sulphate that herein uses is EMPICOL 0137/A.Trimethyl-glycine or sultaine tensio-active agent
Composition among the present invention includes trimethyl-glycine or sultaine tensio-active agent, or derivatives thereof, or its mixture.Additional advantage of the present invention is the mild action of this trimethyl-glycine and/or sultaine tensio-active agent.Therefore, compositions herein is particularly suitable for cleaning responsive surface, as the laundry item or the surface of the sensitivity that contacts with food and/or baby.In addition, trimethyl-glycine and/or sultaine tensio-active agent are gentle equally especially to skin, therefore help the user that the convenient of the present composition used.
Use suitable trimethyl-glycine/sultaine tensio-active agent in the composition of the present invention, wherein contain alkalescence or acidic-group in the molecule, these groups form inner salt, make molecule have positively charged ion or anionic hydrophilic radical in wide ph range.At U.S.Pat.Nos.2, narrated some common embodiment of these sanitising agents in 082,275,2,702,279 and 2,255,082, quote as a reference herein.Preferred trimethyl-glycine or sultaine tensio-active agent have following structural formula
Wherein R1 is for containing from about 1 to about 24 carbon atoms; preferably from 8 to 18; the alkyl of from 12 to 14 carbon atoms more preferably, wherein R2 and R3 contain from 1 to 3 carbon atom, preferably 1 carbon atom; wherein n is from 1 to 10; preferably from 1 to 6, more preferably be 1 integer, Y is selected from carboxyl and alkylsulfonyl; and wherein the summation of R1, R2 and R3 group is from about 14 to about 24 carbon atoms, or its mixture.
The embodiment of Shi Yi beet alkali surface activator comprises C12-C18 alkyl dimethyl trimethyl-glycine especially, as coconut trimethyl-glycine and C10-C16 alkyl dimethyl trimethyl-glycine, as lauryl betaine.
Commercial Amonyl 265 can commodity by name of coconut trimethyl-glycine and lauryl betaine and Empigen BB/L are respectively from Seppic and Albright﹠amp; Wilson obtains.
Typically, compositions herein contains the above-mentioned trimethyl-glycine or the sultaine tensio-active agent of at least 0.005% weight of total composition, or derivatives thereof, or its mixture, preferably from 0.01% to 10%, more preferably from 0.1% to 5%.
A weight ratio that key character is alkylsurfuric acid salt pair trimethyl-glycine or sultaine of the present invention.Therefore, exceed the ratio of following ranges, than alkyl-sulphate higher ratio is arranged, can not provide and clean and the gloss effect, but have only cleanup action, and still can stay the grease-like resistates as trimethyl-glycine or sultaine tensio-active agent.On the other hand, the ratio of alkylsurfuric acid salt pair trimethyl-glycine or sultaine tensio-active agent will cause the surface crystalline form spot resistates to occur above 100: 1.Therefore, key character is that the scope that exists of alkyl-sulphate and trimethyl-glycine or sultaine tensio-active agent is that the weight ratio of alkylsurfuric acid salt pair trimethyl-glycine is 5.5: 1 to 100: 1 in the composition, preferably from 10: 1 to 50: 1.For having better cleaning and luster performance, the weight ratio of alkylsurfuric acid salt pair trimethyl-glycine is the most preferred from 15: 1 to 30: 1.The pH value
The pH value that another key character of the present invention is a composition.Finding to contain above-mentioned concrete surfactant system and pH value thus is lower than 4 composition produces precipitation in solution.The pH value of composition is to measure in the pure composition when 20 ℃ of following compositions are the aqueous solution or composition is measured in 1% the distilled water solution down at 20 ℃ when being solids composition.Thus, essential characteristic of the present invention is that the pH value of composition is at least 4.Preferably, composition of the present invention is liquid, aqueous cleaning compositions.This aqueous composition preferably has and is no more than 12.0 pH value, and more preferably from 4 to 10.Available organic or inorganic acidity of the pH value of composition or alkaline reagents are regulated.Annexing ingredient
The present composition can not necessarily contain annexing ingredient such as solvent, peroxygen bleach, sequestrant and composition thereof.Solvent
When using, solvent will advantageously be supplied with the composition enhanced and clean and luster performance.The The suitable solvent that adds in the present composition comprises propanediol derivative such as n-butoxy propyl alcohol or positive fourth oxygen propoxy-propyl alcohol, water-soluble CARBITOL solvent or water-soluble CELLOSOLVE solvent.Water-soluble CARBITOL solvent is 2-(2-alcoxyl oxyethyl group) alcohol compound, and wherein alkoxy base comes from ethyl, propyl group or butyl.Preferred water-soluble Trivalin SF is 2-(2-fourth oxygen oxyethyl group) ethanol, also is considered to diethylene glycol monobutyl ether.Water-soluble CELLOSOLVE solvent is a 2-alcoxyl ethoxy ethanol compounds, and 2-fourth oxygen ethoxy ethanol is preferred.Other suitable solvent has phenylcarbinol, ethanol, Virahol and glycol such as 2-ethyl-1,3-hexylene glycol and 2,2,4-trimethylammonium-1,3-pentanediol and composition thereof.The preferred solvent of Shi Yonging is positive fourth oxygen propoxy-propyl alcohol, diethylene glycol monobutyl ether and composition thereof herein.The most preferred solvent of herein using is diethylene glycol monobutyl ether .
The typical content of solvent is 0.01% to 10% weight of composition, preferably 3% to 7% weight in the undiluted present composition.Peroxygen bleach
The suitable annexing ingredient of another that uses is peroxygen bleach herein.Peroxygen bleach in the present composition, particularly hydrogen peroxide, persulphate or the like help the disinfectant properties of said composition.Therefore, be not bound by theory, think the somatic vital functions of this peroxygen bleach erodable microorganism, for example, it can suppress the combination of ribose body unit in the microbe tenuigenin.And this peroxygen bleach such as hydrogen peroxide are strong oxidizers, can produce the hydroxyl radical free radical that can attack protein and nucleic acid.In addition, the existence of this peroxygen bleach, especially hydrogen peroxide can provide strong soil-removing action, and this is remarkable especially in laundry item and rigid surface application.
The hydrogen peroxide source of herein using refers to any compound that can produce hydrogen peroxide that contacts with water.The suitable water-soluble hydrogen peroxide source of herein using comprises percarbonate, persilicate, persulphate such as single persulphate, and perborate and peroxy acid such as diperoxy dodecanedioic acid (DPDA) are crossed phthalic acid magnesium and composition thereof.
Preferred peroxygen bleach is a hydrogen peroxide, or its water-soluble source, or its mixture.Most preferred peroxygen bleach is a hydrogen peroxide.
Except that peroxygen bleach, available other class superoxide is used in combination as the surrogate in hydrogen peroxide and source thereof or with hydrogen peroxide and source thereof.Suitable kind comprises dialkyl peroxide, diacyl peroxide, preformed percarboxylic acids, organic and inorganic peroxide.
Typically, compositions herein contains this peroxygen bleach or its mixture of at least 0.01% weight of total composition, and preferably from 0.1% to 15%, more preferably from 1% to 10%.
Following sterilization testing method can be used for measuring the disinfectant properties of composition: the sterilization testing method
The disinfectant properties of composition can be measured by the fungicidal activity of said composition.In European standard, in CEN/TC 216 Ns 59 narrated the testing method of estimating composition fungicidal activity by the standard prEN 1276 of European Committee for Standardization (Bu Lusaier) issue November nineteen ninety-five.European standard prEN 1276, CEN/TC 216 N 59, the active requirement of minimum bactericidal of having stipulated measuring method and sanitizing composition.If bacterial colony forms unit (cfu) from 10
7Cfu (initial content) reduces to 10
2Cfu (with the final content after sterilized product contacts) promptly needs to reduce 10
5Vigor, test can be passed through.Sequestrant
Sequestrant also is the annexing ingredient that is suitable for using herein.Preferred chelating reagent is selected from amino phosphonates do.The suitable aminophosphonic acid salt compound that herein uses comprises amino alkylidenyl polyalkylene phosphonate, ethane 1-hydroxyl di 2 ethylhexyl phosphonic acid an alkali metal salt, nitrilo trimethylene phosphonic salt, ethylenediamine tetramethylene phosphonic acid salt and diethylidene three ammonia pentamethylene phosphonates.Phosphonate compounds can exist with their sour form or based on their form of various cationic salts of part or all of acid functional group.The preferred amino phosphonates do sequestrant that herein uses is diethylidene three ammonia pentamethylene phosphonates.This phosphine acid salt chelator is commercial can be obtained from Monsanto by commodity DEQUEST by name.
Have been found that this chelating reagent,, can further promote the disinfectant properties of hydrogen peroxide especially as the phosphine acid salt chelator of diethylidene three ammonia pentamethylene phosphonates, preferred especially in the present composition.
Typically, contain the sequestrant of 5% weight of total composition in the composition of the present invention, or its mixture, from 0.002% to 3% weight preferably is more preferably from 0.002% to 1.5% weight of composition.Nonessential compound
Compositions herein can contain various other nonessential compounds in addition, nonessential compound comprises the antimicrobial compound, as commercial can be from Eugenol, builder, buffer reagent, sterilant, enzyme, hydrotropic agent, tinting material, stablizer, bleach-activating agent, soil-suspending agent, dye-transfer, brightener, essence, dust-proofing agent, dispersion agent, dye transfer inhibitor, pigment, spices and dyestuff as Sigma, Systems-Bioindustries (SBI)-Manheimer company obtains.The formulation forms of composition
The present composition can be mixed with solid or liquid.When composition is mixed with solid, itself and appropriate solvent to typically be the water mixing before using.When being mixed with liquid form, composition preferably but be not mixed with aqueous composition not essentially.For ease of using, liquid composition is preferred herein.The packaged form of composition
Compositions herein can be packed with various suitable detergent package package materials well known to those skilled in the art.Liquid composition herein can be packed ideally with manually-operated spraying dispersion cup, and this container is normally made by synthetic organic polymer plastic material.So the present invention also comprises the packing of liquid cleansing composition in the spraying decollator among the present invention, preferably packs in triggering the spraying decollator.In fact, this spray-type decollator can be applied to the liquid cleansing composition that is suitable for using of the present invention on the relatively large area on surface to be cleaned equably, thereby helps the clean-up performance of said composition.This spray-type decollator is particularly suitable for cleaning vertical surface.
The suitable spray-type decollator that the present invention uses comprises by the manual operation foam flip-over type decollator as Specialty PackagingProducts company or the sale of Continental Sprayers company.The decollator of these types is published in, as authorizing the US-4 of Dunnining etc., and 701,311 and authorize the US-4 of Focarracci, 646,973 and US-4,538,745.That uses particularly preferredly is spray-type decollator such as commercial T 8500 or commercial T 8100 that can obtain from the Canyon in Northern Ireland that can obtain from Continental SprayInternational herein.In this decollator, liquid composition is divided into tiny drop and is directly injected on the processed surface.In fact, in this spray-type decollator, the composition in this decollator main body can be regulated direction by the energy of suction unit by the top of spray-type decollator by the user, and this suction unit is by this user's starting.More particularly,, force composition to break the barriers,, impact the power that impels the liquid composition atomizing, promptly impel the formation of drop to provide as grid or taperer or the like at this spray-type decollator top.
Composition of the present invention also can be made the form of wiping away paper, and the meaning of " wiping away paper " is with the discardable paper handkerchief that adds liquid composition of the present invention in back herein.So the present invention also comprises and wipes away paper, as with the discardable paper handkerchief that adds liquid composition of the present invention in back.Wipe away in the preferred making of paper dipping at this, more preferably with this liquid composition dipping.Preferably, this wipes away paper pack in plastics casing.The advantage of this making is, the user can use cleaning compositions quickly, even can use out of doors, promptly do not need liquid composition of the present invention is poured on the pending surface and with cloth it is dried.Even cleaning one step on surface is finished in other words.
The present invention includes the method for clean surface, composition wherein of the present invention is coated on this surface.
The meaning on " surface " is any surface that comprises rigid surface such as bathroom, kitchen, floor, desktop, refrigerator, wall, ceramic tile, clean surface or the like herein.
In the method for clean surface of the present invention, said composition can be coated on the surface to be sterilized with its pure form or its dilute form.
The meaning of " dilute form " is the composition that exists with the liquid or solid form that uses in the cleaning method herein herein, can dilute by the user, typically be diluted with water to 1000 times of its weight, preferably to 300 times, more preferably be diluted with water to 80 to 30 times of its weight, most preferably be diluted to 60 to 40 times.
In the embodiment preferred of the inventive method, said composition is coated in surface to be cleaned with its dilute form, and on rigid surface, composition does not need to wash this surface after applying; In fact, do not stay the visible resistates on this surface.
Be illustrated among the present invention unconfined embodiment below, wherein unless otherwise indicated, all percentage ratios all are based on weight.
The testing method that is used to measure cleaning and gloss effectiveness below is as follows: clean testing method
Grease/particulate matter on the porcelain dish of standard and making dirty cures this dish then.Then test composition is coated on the sponge, is placed on then on the Jia Dele instrument.The Jia Dele Instrument measuring reaches the required wiping number of times of 95-99% clean-up performance plate.So (promptly do not dilute) and dilute with water concentration is 1.5% to carry out performance measurement.The measurement of luster method
Five millimeters test products are applied to the one side of wetted sponge.The wetted sponge is pressed in the black ceramic tiles of cleaning with Virahol in advance from the top to the bottom with uniform pressure.Before expert statement people classification, dry 10 minutes of the ceramic tile that scribbles product.With the wetted sponge but repeat above-mentioned test, benchmark in contrast without test products.
Estimate the specific area of product film forming/one-tenth streak through expert statement.The numerical value of expression film forming/slivering trace is belonged to each product.For test result, used the grade of 0-4
Indifference, the i.e. film forming of test products/one-tenth streak poor performance between 0=test products and contrast benchmark.
4=test products and contrast have significant difference between benchmark, i.e. test products film forming/one-tenth streak not.
In an embodiment, abbreviation composition symbol has following implication:
Alkyl-sulphate: Empicol 0137/A
Trimethyl-glycine: can be called Empigen BB/L from Albright﹠amp by commodity; Wilson
The coconut alkyl dimethyl trimethyl-glycine that obtains.
Diethylene glycol monobutyl ether : 2-(2-fourth oxygen oxyethyl group) ethanol embodiment 1
Following composition of the present invention, by preparing with the following component of following mixed:
Embodiment 2
| ????A | ????B | ????C | ????E | |
| Alkyl-sulphate | ????1 | ????1 | ????1 | ????1 |
| Trimethyl-glycine | ???0.05 | ???0.05 | ???0.05 | ???0.05 |
| Diethylene glycol monobutyl ether | ????- | ????5 | ????- | ????5 |
| Hydrogen peroxide | ????- | ????- | ????2 | ????2 |
| Add water and minor component to 100 part | ||||
| Add H 2SO 4To the pH value be 4 | ||||
Following composition is prepared according to the present invention:
| ????F | ????G | ????H | ????I | |
| Alkyl-sulphate | ????1 | ????2 | ????8 | ????5 |
| Trimethyl-glycine | ???0.05 | ???0.1 | ???0.5 | ???0.2 |
| Diethylene glycol monobutyl ether | ????- | ????5 | ????- | ????5 |
| Hydrogen peroxide | ????- | ????- | ????1 | ????2 |
| Add water and minor component to 100 part | ||||
| Add H 2SO 4To the pH value be 5 | ||||
| ????J | ????K | ????L | ????M | |
| Alkyl-sulphate | ????1 | ????2 | ????8 | ????5 |
| Trimethyl-glycine | ???0.05 | ???0.1 | ???0.5 | ???0.2 |
| Diethylene glycol monobutyl ether | ????- | ????5 | ????- | ????5 |
| Hydrogen peroxide | ????- | ????- | ????1 | ????2 |
| Add water and minor component to 100 part | ||||
| Add H 2SO 4To the pH value be 9 | ||||
Claims (14)
1. cleaning compositions, comprise the surfactant system that contains alkyl-sulphate and trimethyl-glycine or sultaine tensio-active agent, wherein the weight ratio of alkylsurfuric acid salt pair trimethyl-glycine or sultaine is 5.5: 1 to 100: 1, and wherein the pH value of composition is at least 4.
2. according to the cleaning compositions of claim 1, wherein abovementioned alkyl vitriol is 10: 1 to 50: 1 to the ratio of trimethyl-glycine or sultaine, preferably 15: 1 to 30: 1.
3. according to each cleaning compositions in claim 1 and 2, wherein alkyl sulfate surfactant is that those molecular formula are ROSO
3 -M
+Material, wherein R representative contains 6 to 24 carbon atoms, 6 to 16 carbon atoms preferably, the alkyl group of 8 to 14 carbon atoms more preferably, and on behalf of water, M add dissolved cation.
4. according to each cleaning compositions among the claim 1-3, wherein this trimethyl-glycine or sultaine tensio-active agent have following structural formula
Wherein R1 is for containing from about 1 to about 24 carbon atoms; preferably from 8 to 18; the alkyl of from 12 to 14 carbon atoms more preferably, wherein R2 and R3 contain from 1 to 3 carbon atom, preferably 1 carbon atom; wherein n is from 1 to 10; preferably from 1 to 6, more preferably be 1 integer, Y is selected from carboxyl and alkylsulfonyl; and wherein the summation of R1, R2 and R3 group is from about 14 to about 24 carbon atoms, or its mixture.
5. according to each cleaning compositions among the claim 1-4, wherein said composition also comprises solvent in addition.
6. according to the cleaning compositions of claim 5, wherein this solvent is selected from propanediol derivative, 2-(2-alcoxyl oxyethyl group) alcohol compound, 2-alcoxyl ethoxy ethanol compounds, phenylcarbinol, ethanol, Virahol, glycol and composition thereof, preferably is selected from propanediol derivative and 2-(2-alcoxyl oxyethyl group) alcohol compound.
7. according to each cleaning compositions among the claim 1-6, wherein said composition also contains peroxygen bleach in addition.
8. add according among the claim 1-7 each cleaning compositions wipe away paper.
9. according to each cleaning compositions among the claim 1-7, wherein said composition is packaged in the spraying decollator, is preferably packaged in and triggers in the spraying decollator.
10. the method for clean surface is by coating the composition of each regulation among the claim 1-7 on this surface.
11. the method for clean surface according to Claim 8, wherein said composition is being coated in before this surface, is diluted with water to 1000 times of its weight, preferably to 300 times, more preferably be diluted with water to 80 to 40 times of its weight, most preferably be diluted to 60 to 30 times.
12. according to the method for claim 11, wherein should the surface after being coated with said composition, do not need flushing.
13. alkyl-sulphate and trimethyl-glycine or the application of sultaine surfactant system in cleaning compositions are to offer the surface cleaned with said composition with cleaning and gloss.
14. the application of each specified solvent in cleaning compositions among the claim 1-7 is to offer the surface cleaned with said composition with cleaning and gloss.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96870056A EP0805197A1 (en) | 1996-05-03 | 1996-05-03 | Cleaning compositions |
| EP96870056.7 | 1996-05-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1232488A true CN1232488A (en) | 1999-10-20 |
Family
ID=8226138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97195199A Pending CN1232488A (en) | 1996-05-03 | 1997-04-28 | Cleaning compositions |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0805197A1 (en) |
| JP (1) | JP2000514847A (en) |
| CN (1) | CN1232488A (en) |
| AR (1) | AR006940A1 (en) |
| AU (1) | AU2815997A (en) |
| BR (1) | BR9709584A (en) |
| CA (1) | CA2252716A1 (en) |
| CZ (1) | CZ351498A3 (en) |
| EG (1) | EG20926A (en) |
| HU (1) | HUP0002498A3 (en) |
| TR (1) | TR199802215T2 (en) |
| WO (1) | WO1997042278A1 (en) |
| ZA (1) | ZA973710B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2330279C (en) | 1998-05-22 | 2003-06-10 | The Procter & Gamble Company | Acidic cleaning compositions with c10 alkyl sulfate detergent surfactant |
| JP4744902B2 (en) * | 2005-03-18 | 2011-08-10 | 花王株式会社 | Bleach composition |
| DE102009002020A1 (en) * | 2009-03-31 | 2010-10-07 | Henkel Ag & Co. Kgaa | Cleaning agent for floors |
| ES2704084T3 (en) | 2015-07-13 | 2019-03-14 | Procter & Gamble | Cleaning product |
| EP3118290B1 (en) * | 2015-07-13 | 2019-02-20 | The Procter and Gamble Company | Cleaning product |
| ES2704087T3 (en) | 2015-07-13 | 2019-03-14 | Procter & Gamble | Cleaning product |
| ES2710253T3 (en) | 2015-07-13 | 2019-04-23 | Procter & Gamble | Cleaning product |
| ES2827229T3 (en) | 2015-07-13 | 2021-05-20 | Procter & Gamble | Cleaning product |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1084739A (en) * | 1963-06-25 | 1967-09-27 | Marchon Products Ltd | Surface-active compositions |
| JPS5089406A (en) * | 1973-12-11 | 1975-07-17 | ||
| US5540864A (en) * | 1990-12-21 | 1996-07-30 | The Procter & Gamble Company | Liquid hard surfce detergent compositions containing zwitterionic detergent surfactant and monoethanolamine and/or beta-aminoalkanol |
| GB9201519D0 (en) * | 1992-01-24 | 1992-03-11 | Unilever Plc | Detergent compositions |
| JPH08505424A (en) * | 1993-01-12 | 1996-06-11 | ヘンケル・コーポレイション | Dishwashing detergent |
| GB9307804D0 (en) * | 1993-04-15 | 1993-06-02 | Unilever Plc | Hygienic spray cleaner |
| ZA948477B (en) * | 1993-11-16 | 1996-04-29 | Colgate Palmolive Co | Gelled light duty liquid detergent |
| AU1178995A (en) * | 1993-11-22 | 1995-06-13 | Colgate-Palmolive Company, The | Liquid cleaning compositions |
| ES2153026T5 (en) * | 1994-02-18 | 2004-05-16 | Unilever N.V. | COMPOSITIONS OF PERSONAL WASHING. |
| US5529723A (en) * | 1994-12-15 | 1996-06-25 | Colgate-Palmolive Co. | Microemulsion light duty liquid cleaning compositions |
-
1996
- 1996-05-03 EP EP96870056A patent/EP0805197A1/en not_active Withdrawn
-
1997
- 1997-04-28 JP JP09539973A patent/JP2000514847A/en active Pending
- 1997-04-28 HU HU0002498A patent/HUP0002498A3/en unknown
- 1997-04-28 AU AU28159/97A patent/AU2815997A/en not_active Abandoned
- 1997-04-28 BR BR9709584-2A patent/BR9709584A/en unknown
- 1997-04-28 WO PCT/US1997/007080 patent/WO1997042278A1/en not_active Application Discontinuation
- 1997-04-28 CA CA002252716A patent/CA2252716A1/en not_active Abandoned
- 1997-04-28 TR TR1998/02215T patent/TR199802215T2/en unknown
- 1997-04-28 CZ CZ983514A patent/CZ351498A3/en unknown
- 1997-04-28 CN CN97195199A patent/CN1232488A/en active Pending
- 1997-04-29 ZA ZA9703710A patent/ZA973710B/en unknown
- 1997-05-02 AR ARP970101815A patent/AR006940A1/en unknown
- 1997-05-03 EG EG36897A patent/EG20926A/en active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2000514847A (en) | 2000-11-07 |
| HUP0002498A2 (en) | 2000-11-28 |
| EG20926A (en) | 2000-06-28 |
| AR006940A1 (en) | 1999-09-29 |
| HUP0002498A3 (en) | 2001-04-28 |
| TR199802215T2 (en) | 2001-06-21 |
| AU2815997A (en) | 1997-11-26 |
| ZA973710B (en) | 1997-11-25 |
| CZ351498A3 (en) | 1999-04-14 |
| BR9709584A (en) | 2000-05-02 |
| EP0805197A1 (en) | 1997-11-05 |
| WO1997042278A1 (en) | 1997-11-13 |
| CA2252716A1 (en) | 1997-11-13 |
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