JPH09500680A - Thickened aqueous detergent composition with improved cleaning performance containing short chain surfactants - Google Patents
Thickened aqueous detergent composition with improved cleaning performance containing short chain surfactantsInfo
- Publication number
- JPH09500680A JPH09500680A JP7505253A JP50525395A JPH09500680A JP H09500680 A JPH09500680 A JP H09500680A JP 7505253 A JP7505253 A JP 7505253A JP 50525395 A JP50525395 A JP 50525395A JP H09500680 A JPH09500680 A JP H09500680A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- chain
- mixture
- detergent composition
- aqueous detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 121
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 41
- 238000004140 cleaning Methods 0.000 title claims abstract description 15
- 239000003599 detergent Substances 0.000 title claims abstract description 15
- 150000001412 amines Chemical class 0.000 claims abstract description 42
- -1 alkali metal hypochlorite salt Chemical class 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- UZZYXUGECOQHPU-UHFFFAOYSA-N sulfuric acid monooctyl ester Natural products CCCCCCCCOS(O)(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-N 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 1
- RSVIRMFSJVHWJV-UHFFFAOYSA-N n,n-dimethyloctan-1-amine oxide Chemical compound CCCCCCCC[N+](C)(C)[O-] RSVIRMFSJVHWJV-UHFFFAOYSA-N 0.000 claims 1
- UZZYXUGECOQHPU-UHFFFAOYSA-M n-octyl sulfate Chemical group CCCCCCCCOS([O-])(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-M 0.000 claims 1
- 229940067739 octyl sulfate Drugs 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 4
- 230000002708 enhancing effect Effects 0.000 abstract description 2
- 239000002689 soil Substances 0.000 abstract description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 26
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
- 229930195729 fatty acid Natural products 0.000 description 12
- 150000004665 fatty acids Chemical class 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000004851 dishwashing Methods 0.000 description 7
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 6
- 239000007844 bleaching agent Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- 150000003335 secondary amines Chemical class 0.000 description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 description 3
- 238000000280 densification Methods 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229960002446 octanoic acid Drugs 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- CCGKOQOJPYTBIH-UHFFFAOYSA-N ethenone Chemical compound C=C=O CCGKOQOJPYTBIH-UHFFFAOYSA-N 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical class ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- YZQBYALVHAANGI-UHFFFAOYSA-N magnesium;dihypochlorite Chemical compound [Mg+2].Cl[O-].Cl[O-] YZQBYALVHAANGI-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- XMRPIOZXPHTSCE-UHFFFAOYSA-N n-methyltridecan-1-amine Chemical compound CCCCCCCCCCCCCNC XMRPIOZXPHTSCE-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical group [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
(57)【要約】 本発明は、洗浄性能を高めるための短鎖界面活性剤を含む、水性液体洗剤組成物である。前記組成物は、さらに粘度を回復するための長鎖アミンオキシドの混合物を含む。前記組成物は、食器前処理組成物として用いた場合に、顕著な汚れ除去を与え、ならびに便器の洗浄を含め、硬質表面への適用の場合、顕著な洗浄性を与える。 (57) [Summary] The present invention is an aqueous liquid detergent composition containing a short chain surfactant for enhancing cleaning performance. The composition further comprises a mixture of long chain amine oxides to restore viscosity. The composition provides significant soil removal when used as a dish pretreatment composition, as well as significant cleanability for hard surface applications, including toilet bowl cleaning.
Description
【発明の詳細な説明】 短鎖界面活性剤を含む改良された洗浄性能を有する濃密化水性洗剤組成物 技術分野 本発明は、家庭への適用に好適な濃密化水性洗剤組成物に関する。特に本発明 の組成物は、トイレ洗浄ならびに食器洗浄への適用を含めた、特に前処理組成物 としての硬質表面への適用に好適なものに関する。 背景技術 長鎖アミンオキシドと脂肪酸との組み合わせを含む液体洗剤組成物は周知の技 術である。 このような組成物は良い洗浄性能を有することが望まれている。しかしながら 、長鎖アミンオキシドは最適な洗浄性能を提供するものではないことが判明して いる。したがって、本発明の第１の目的は、改良された洗浄性を有する長鎖界面 活性剤を含む洗浄組成物を提供することである。 この課題に対して、短鎖界面活性剤を配合させることが有益であり、この目的 つまり洗浄性能を高めることに合致することが判明している。しかしながら、こ のような組成物中に短鎖界面活性剤を配合することは、組成物の粘度を低下させ る結果となることが観察されている。しかし、これら組成物は高度の粘度を示す べきであり、それによってその組成物が垂直面および水平面に対して傾斜した表 面に付着することが必須と考えられる。 したがって、さらに本発明の目的は、長鎖界面活性剤と短鎖界面活性剤とを含 む液体組成物であって、粘度を保持したものを提供することである。 この目的に対して、短鎖界面活性剤を添加した場合であっても、特定のアミン オキシドの混合物を用いることによって、より詳細にはＣ14鎖アミンオキシドと Ｃ12鎖アミンオキシドとのまたはＣ16鎖アミンオキシドまたはそれらの混合物に よって、粘度が保持され得ることが判明している。 さらに本発明の有利な点は、追加的な濃密化剤の必要がないことである。追加 的に本発明の組成物の有利な点は、望ましい泡特性を有しているので、抑泡剤を 必要としないことである。 長鎖アミンオキシドおよび完全飽和脂肪酸を含む濃密化組成物は周知の技術で ある。 米国特許第４，２８２，１０９号明細書には、次亜塩素酸塩および直鎖および 分枝長鎖Ｃ10−Ｃ18アミンオキシドを濃密化剤として含む濃密化漂白剤組成物が 開示されている。短鎖Ｃ6−Ｃ8界面活性剤または脂肪酸については述べられてい ない。 ＥＰ２７４８８５号明細書には、次亜塩素酸アルカリ金属塩および直鎖Ｃ14ア ミンオキシドと共に分枝および直鎖Ｃ15アミンオキシドの混合物を含む濃密化漂 白剤組成物が開示されている。この組成物は追加的濃密化助剤として任意に脂肪 酸を含むことができる。 ＥＰ２３３６６６号明細書には、次亜塩素酸塩、次亜塩素酸塩溶解性界面活性 剤および脂肪酸のアルカリ金属塩からなる濃密化漂白剤組成物の製法が開示され ている。この洗剤活性剤は、アミンオキシド好ましくは、ラウリルジメチルアミ ンを含有する。短鎖界面活性剤については述べられていない。 ＤＥ２８３７８８０号明細書には次亜塩素酸アルカリ金属塩および粘度を高め るための様々な鎖長（Ｃ5−Ｃ17）の分枝および直鎖アミンオキシドを含む漂白 剤組成物が開示されている。この組成物は濃密化のための脂肪酸を必要としない 。 ＥＰ３０４０１号明細書には、次亜塩素酸塩ならびにｐＨおよび粘度を含め特 有の特定数の生成物を含む濃密化漂白剤組成物が開示されている。Ｃ8−Ｃ18ア ミンオキシドの混合物、および脂肪酸は濃密化剤として好ましい。短鎖界面活性 剤については述べられていない。 発明の開示 本発明の組成物は、粘度が５０〜２０００ｃｐsであって、式Ｒ1Ｒ2Ｒ3ＮＯ（ 式中、Ｒ2およびＲ3は独立してＣ1−Ｃ3アルキル基である）で表される長鎖アミ ンオキシドの混合物および短鎖界面活性剤を含む水性組成物からなる。 前記短鎖界面活性剤は疎水性部分と親水性部分からなり、前記疎水性部分の鎖 長はＣ6−Ｃ10である。 前記長鎖アミンオキシドの混合物は、Ｒ1がＣ14アルキル基の第１のアミンオ キシド、Ｒ1がＣ12アルキル基もしくはＣ16アルキル基の第２のアミンオキシド 、またはそれらの前記アミンオキシドの混合物からなる。 前記第１アミンオキシドの、Ｒ1がＣ12アルキル基である前記第２のアミンオ キシドに対する比率は０．３〜１０、および前記第１アミンオキシドの、Ｒ1が Ｃ16アルキル基である前記第２のアミンオキシドの比率は０．２〜４．５である 。 全ての比率、パーセンテージおよび部は、ここでは特に断らない限り、全組成 物に対する重量％である。 さらに本発明は、本発明にかかる組成物と接触する食器の処理方法を包含する 。 発明を実施するための最良の形態 本発明の液体洗剤組成物は、長鎖アミンオキシド混合物および短鎖界面活性剤 を含む。 本発明の組成物の洗浄性能が、短鎖界面活性剤の配合によって向上できること が判明した。 本発明の組成物は、少なくとも１種の短鎖界面活性剤またはその混合物を含む 。全ての界面活性剤は、通常疎水性部分および親水性部分からなる。短鎖界面活 性剤とは、ここではその疎水性部分としてＣ6−Ｃ10アルキル鎖を含む界面活性 剤 を意味する。このような界面活性剤はこの分野において通常用いるものであるが 、より短いアルキル鎖も含め、どのような種類であることもできる。したがって 、本発明において用いる好適な短鎖界面活性剤は、Ｃ6−Ｃ10アルキルサルフェ ート（Ｃ6−Ｃ10ＳＯ4）、アルキルエーテルサルフェート（Ｃ6−Ｃ10（ＯＣＨ2 ＣＨ2）eＳＯ4）、アルキルスルホネート（Ｃ6−Ｃ10ＳＯ3）、アルキルスクシ ネート（Ｃ6−Ｃ10ＯＯＣＣＨ2ＣＨ2ＣＯＯＺ）、アルキルカルボキシレート（ Ｃ6−Ｃ10ＣＯＯＭ）、アルキルエーテルカルボキシレート（Ｃ6−Ｃ10（ＯＣＨ2 ＣＨ2）eＣＯＯＭ）、アルキノサルコシネート（Ｃ6−Ｃ10ＣＯＮ（ＣＨ3）Ｒ ）、アルキルスルホサクシネート（Ｃ6−Ｃ10ＯＯＣＣＨ（ＳＯ3Ｍ）ＣＨ2ＣＯ ＯＺ）、アミンオキシド（Ｃ6−Ｃ10ＲＲ’ＮＯ）、グルコースアミド（Ｃ6−Ｃ10 ＣＯＮＲ”Ｘ）、アルキルピロリドン（Ｃ6−Ｃ10（Ｃ4Ｈ6ＯＮ）、アルキル ポリサッカライド（Ｃ6−Ｃ10ＯＧｇ）、アルキルアルコキシレート（Ｃ6−Ｃ10 （ＯＣＨ2ＣＨ2）e（ＯＣＨ2ＣＨ2ＣＨ2）pＯＨ）およびベタイン（Ｃ6−Ｃ10Ｎ+ （ＣＨ3）2ＣＯＯ-）を含む。式中の同類部分ｅおよびｐは独立して０〜２０か つｅ＋ｐ＞０であり、ＺはＭまたはＲ、ＭはＨまたはＮａ、Ｋ、Ｌｉ、ＮＨ4、 アミンを含め公知のものなど、いかなるカウンターイオンであってよく、Ｘは少 なくとも３個のヒドロキシルが直接鎖に結合し、またはそのアルコキシ化された 誘導体を有する直鎖ヒドロカルビル鎖を有するポリヒドロキシヒドロカルビルで あり、Ｒ、Ｒ’およびＲ”はＣ1−Ｃ5アルキル基、可能ならばヒドロキシル基に よって機能化され、ＲおよびＲ’は好ましくはＣ1−Ｃ3最も好ましくはメチルで あり、Ｒ”は好ましくは２−ヒドロキシエチルまたは２−ヒドロキシプロピルで あり、Ｇはサッカライド、好ましくはグルコース、およびｇは１．５〜８である 。これらの全ての界面活性剤は周知のものである。通常のグルコースアミドのよ り完全な開示は、例えばＷＯ９２−０６１５４号明細書 に見いだすことができ、およびより完全な通常のアルキルポリサッカライドの開 示は例えば米国特許第４，５３６，３１９号明細書に見いだすことができる。本 発明の組成物は、最終用途によって上記のいかなる単独の界面活性剤またはそれ らのいかなる組み合わせをも含むことができる。 ここで用いるのに好ましい非イオン短鎖界面活性剤は、式Ｃ6−Ｃ10（ＯＣＨ2 ＣＨ2）e（ＯＣＨ2ＣＨ2ＣＨ2）pＯＨ（式中、ｅおよびｐはそれぞれエトキシ化 度およびプロポキシ化度を表し、独立して０〜２０であり、ｅ＋ｐ＞０である） によって表されるアルキルアルコキシレートである。ここで用いるのに最も好ま しい短鎖非イオン界面活性剤は、ｅ＋ｐが３〜１０、特にｐが０でｅが３〜８で あるｅおよびｐを有するものである。さらにここで用いるのに最も好ましい短鎖 非イオン界面活性剤は前記短鎖が炭素原子７〜１０個からなる炭化水素鎖である ものである。 ここで用いるのに好ましい前記短鎖非イオン界面活性剤は、対応するアルコー ルとアルキレンオキシドとの縮合などの当業者に周知な方法によって製造するこ とができるが、このような短鎖界面活性剤は、より好都合には、例えば、シドブ レから商品名マージタル（ＭｅｒｇｉｔａｌR）Ｃ４（Ｃ８ＥＯ４）、コルブか ら商品名インベンティン（ＩｍｂｅｎｔｉｎR）ＡＧ／８１０／０５０およびＡ Ｇ／８１０／０８０（それぞれ、Ｃ８−１０ＥＯ５およびＣ８−１０ＥＯ８）と して市販されている。 ここで用いるのに好ましい短鎖陰イオン界面活性剤は、Ｃ6−Ｃ10アルキルサ ルフェート（Ｃ6−Ｃ10ＳＯ4）およびアルキルスルホネート（Ｃ6−Ｃ10ＳＯ3） 最も好ましくは、Ｃ6−Ｃ8アルキルサルフェートおよびスルホネートである。こ のような短鎖陰イオン界面活性剤は、周知の硫酸化またはスルホン化およびそれ に引き続く中性化によって製造することができるが、前記陰イオン短鎖界面活性 剤はより好都合には、例えばローンポーレンから商品名ロウダポ ン（ＲｈｏｄａｐｏｎR）ＯＬＳまたはウィツコから商品名ウィツコネート（Ｗ ｉｔｃｏｎａｔｅR）として市販されている。 ここで用いるのに好ましい短鎖界面活性剤は、ジメチルオクチルアミンオキシ ドおよびオクチルサルフェートである。ここで用いるのに好適な短鎖界面活性剤 は、好ましくは次亜塩素酸塩相容性である。本発明によれば、組成物は全組成物 に対して０．５〜１５重量％、好ましくは０．５〜１０重量％、より好ましくは １〜６重量％、最も好ましくは２〜４重量％の短鎖界面活性剤を含む。 典型的にはアミンオキシドを含んでなる組成物に短鎖界面活性剤を配合すると 、前記組成物の粘度を低下させることが従来技術において記載されていることは 知られている。特定の長鎖アミンオキシドの混合物の使用によって、その組成物 の粘度が阻害されないことが今や判明した。 本発明によれば、ここで用いるのに好適な長鎖アミンオキシドの混合物は、式 Ｒ1Ｒ2Ｒ3ＮＯによって表され、第１アミンオキシドではＲ1がＣ14アルキル基で あり、第２アミンオキシドではＲ1がＣ12アルキル基またはＣ16アルキル基また はそれらの混合物である。Ｒ2およびＲ3は、共に前記第１および第２アミンオキ シド中の、独立したＣ1からＣ3アルキル基である。 前記第１アミンオキシドの第２アミンオキシドに対する比率は、Ｒ1がＣ12ア ルキル基である場合、０．３〜１０、好ましくは０．５〜５であり、前記第１ア ミンオキシドの前記第２アミンオキシドに対する比率は、前記第２アミンオキシ ドのＲ1がＣ16アルキル基の場合、０．２〜４．５、好ましくは０．５〜２であ る。 ここで用いるのに好ましい長鎖アミンオキシドはゲナミノックス（Ｇｅｎａｍ ｉｎｏｘR）ＬＡ、ゲナミノックス（ＧｅｎａｍｉｎｏｘR）ＭＹ−Ｘ、（ヘキス トから入手可能）、Ｃ12−Ｃ14アロモックス（ＡｒｏｍｏｘR）ＤＭＭＣＯ−Ｗ （ＡＫＺＯ）、アロモックス（ＡｒｏｍｏｘR）ＤＭ１４Ｄ−Ｗ（ＡＫＺＯ）、 およびアロモックス（ＡｒｏｍｏｘR）ＤＭ１４Ｄ−Ｗ（ＡＫＺＯ）であること ができる。ここで用いるのに好適な長鎖界面活性剤は好ましくは次亜塩素酸塩相 容性である。本発明によれば、前記組成物は、全組成物に対して１．５〜１０重 量％、好ましくは１．５〜７重量％、より好ましくは２〜５重量％、最も好まし くは２．５〜４重量％の前記本発明の長鎖アミンオキシドの混合物を含む。本発 明の組成物は前記長鎖アミンオキシドの混合物を含むので、組成物は独立して全 組成物に対して０．４〜６重量％、好ましくは０．５〜４重量％の前記第１アミ ンオキシドと、０．５〜４重量％、好ましくは０．５〜３重量％の前記第２アミ ンオキシドを含む。 本発明の組成物は、前記長鎖アミンオキシドの混合物と前記短鎖界面活性剤と を０．２５〜３、好ましくは０．５〜２の比率で含む。 本発明の長鎖アミンオキシドは、粘度を、ブッルクフィールド粘度計ＲＶＴに よって、温度２５℃で、スピンドル番号２または３または４を用い、５０ｒｐｍ または１００ｒｐｍにおいて測定し、５０〜２０００ｃｐｓ好ましくは１００〜 ７００ｃｐｓに回復させる。 本発明の組成物は、さらに、任意成分として他の長鎖界面活性剤を含むことが できる。好適な界面活性剤はアルキルサルコシネート、パラフィンスルホネート 、アルキルサルフェートおよびアルキルエーテルサルフェートを含む。 好適な任意成分は、Ｃ12アルキルサルフェートであり、短鎖界面活性剤とＣ12 アルキルスルホネートの重量比は、１：４から４：１である。 本発明の他の任意成分は、Ｃ8−Ｃ18脂肪酸のアルカリ金属塩である。ここで 用いるのに好適な脂肪酸は、いかなるＣ8−Ｃ18脂肪酸であることができるが、 好ましくは、完全飽和であり、好ましくはナトリウム、カリウム、リチウム塩で あり、より好ましくはナトリウム塩である。好適な脂肪酸はカプリル酸、カプリ ン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸および脂肪酸の 混合物、好適には硬化され、タロー、ココナッツオイル、グランドオイル、ババ スオイルなどの天然源から誘導されるものから選ばれることができる。 本発明の組成物は、全組成物に対して０．２〜２重量％、好ましくは０．５〜 １重量％の脂肪酸を含む。前記脂肪酸は追加的な濃密化助剤、および抑泡剤とし て用いることができる。 本発明の他の任意成分は、次亜塩素酸塩漂白剤、好ましくは次亜塩素酸アルカ リ金属塩である。次亜塩素酸アルカリ金属塩は好ましいが、次亜塩素酸カルシウ ム、および次亜塩素酸マグネシウムから選ぶことができる他の次亜塩素酸塩化合 物もさらにここで用いることができる。ここで用いるのに好適な次亜塩素酸塩は 次亜塩素酸ナトリウムである。本発明の組成物は、前記次亜塩素酸塩漂白剤を、 組成物中の活性塩素量を０．４〜４％好ましくは１〜２％含む。本発明によれば この組成物の成分は、この組成物が次亜塩素酸塩相容性であるように選ばれる。 本発明の組成物に任意に求められることは、ｐＨが１２より大きく、好ましく は１２．５より大きく、より好ましくは、１２．８より大きいことである。これ は、苛性アルカリを添加することにより達成される。ここで用いる好適な苛性ア ルカリには、水酸化ナトリウム、および水酸化カリウムが含まれる。 本発明の組成物は、さらにいくつもの追加的な成分、例えば着色剤および香料 を含むことができる。加えて、本発明の組成物は、腐食防止剤としてシリケート を含むことができる。 本発明の組成物は、ＧＢ１３２９０８６号明細書に記載の方法などの周知方法 によって調製される。本発明の組成物は、全成分を、非金属装置内で室温で混合 することによって調製することができる。好ましくは、界面活性剤混合物は第１ に長鎖成分に短鎖界面活性剤を加えることによって調製する。香料および次亜塩 素酸アルカリ金属塩は、ついで撹拌しながら加える。着色剤は他のすべての成分 を混合してから加える。 本発明の組成物は、硬質表面の洗浄など様々な洗浄目的に使用してもよく、そ のため前記組成物は濃密化した性質であり、非濃密化組成物よりも長時間表面に 付着する。前記組成物は、トイレットボールを含めて傾斜表面の洗浄に対して特 に好適である。 本発明の他の態様の組成物においては、この組成物は、手による食器洗浄なら びに自動食器洗浄機による洗浄を含めて食器洗浄への適用に用いられる。本発明 者らは、食品しみ／堆積物による食器（特に鍋、ポット、キッチングリル）およ び／またはいかなる台所用品の汚れであっても、前記組成物が、それらの処理の 前処理組成物として用いられた場合に、特に汚れ除去に関して、非常に優れた洗 浄性能を与えることを見いだした。 本発明によれば、前記食器に本発明の組成物を希釈または純粋（生の）形態で 接触させ、次いで前記食器を処理するのに十分な時間、好ましくは２〜１５分間 前記食器を前記組成物に接触させ続け、次いで前記組成物を除去するために前記 食器を水によってすすぐ工程からなる食器の処理を包含する。前記工程は、ここ では引き続き、前記食器が本発明の１つまたは他のいかなる通常の食器洗浄製品 を含む食器洗浄製品によって洗浄される工程を続けることができる。実際、前記 引き続き行う工程は手による食器洗浄操作または自動食器洗浄機によって行われ る食器洗浄のどちらであることもできる。 あるいは、ここで述べた前記食器処理方法の前工程として、本発明の組成物に よる接触の前に前記食器を水に浸すことができる。 「希釈した形態」とは、ここでは本発明の組成物が水によって希釈されること ができることを意味する。典型的には希釈量は、水中に本発明の組成物０．５〜 ３重量％である。前記希釈は、本発明の組成物を前記食器に適用する際または前 に行うことができる。 前述の段落に用いたように「処理」との表現は、界面活性剤および漂白剤から なる本発明の組成物と同様、次亜塩素酸塩を含む好適な本発明の組成物による洗 浄をも含む。 本発明の組成物は、以下の例によって説明することができる。 Detailed Description of the Invention Thickened aqueous detergent composition with improved cleaning performance containing short chain surfactants Technical field The present invention relates to concentrated aqueous detergent compositions suitable for household application. Especially the present invention Of the pretreatment composition, including its application in toilet cleaning as well as dishwashing. As a material suitable for application to a hard surface. Background technology Liquid detergent compositions containing a combination of long chain amine oxides and fatty acids are well known in the art. It is a technique. It is desired that such compositions have good cleaning performance. However Found that long-chain amine oxides do not provide optimum cleaning performance I have. Therefore, the first object of the present invention is to provide a long chain interface having improved detergency. It is to provide a cleaning composition comprising an active agent. To this end, it is beneficial to incorporate a short chain surfactant, In other words, it has been found that this is consistent with enhancing the cleaning performance. However, this Incorporating a short chain surfactant into a composition such as reduces the viscosity of the composition. Have been observed to result in However, these compositions show a high degree of viscosity The composition should be such that the composition is tilted with respect to the vertical and horizontal planes. It is considered essential to adhere to the surface. Therefore, a further object of the present invention is to include long chain surfactants and short chain surfactants. A liquid composition which retains its viscosity. To this end, even with the addition of short-chain surfactants, certain amines More specifically, by using a mixture of oxides, C14With chain amine oxide C12With chain amine oxide or C16Chain amine oxides or mixtures thereof Therefore, it has been found that the viscosity can be retained. A further advantage of the present invention is that no additional thickening agent is required. add to In general, the advantage of the composition of the present invention is that it possesses desirable foam properties, so It is not necessary. Thickening compositions containing long chain amine oxides and fully saturated fatty acids are well known in the art. is there. U.S. Pat. No. 4,282,109 describes hypochlorite and straight chain and Branched long chain CTen-C18A densified bleach composition containing amine oxide as a densifying agent It has been disclosed. Short chain C6-C8No mention of surfactants or fatty acids Absent. EP 274885 describes alkali metal hypochlorite and straight chain C14A Branched and straight chain C with minoxideFifteenThickening drift containing a mixture of amine oxides. A whitening agent composition is disclosed. This composition optionally contains fat as an additional densification aid. An acid can be included. EP 233666 describes hypochlorite, hypochlorite soluble surface active agents. A method of making a concentrated bleach composition comprising an agent and an alkali metal salt of a fatty acid is disclosed. ing. The detergent activator is an amine oxide, preferably lauryl dimethyl amide. Contains No mention is made of short-chain surfactants. DE 2837880 describes alkali metal hypochlorites and high viscosity Various chain lengths (CFive-C17) Bleaching containing branched and linear amine oxides An agent composition is disclosed. This composition does not require fatty acids for densification . EP 30401 describes specific characteristics including hypochlorite and pH and viscosity. A densified bleaching composition containing a certain number of products is disclosed. C8-C18A Mixtures of min oxides and fatty acids are preferred as thickening agents. Short chain surface activity No mention is made of agents. Disclosure of the invention The composition of the present invention has a viscosity of 50 to 2000 cps and has the formula R1R2RThreeNO ( Where R2And RThreeIs independently C1-CThreeLong-chain amino represented by (alkyl group) An aqueous composition comprising a mixture of oxides and a short chain surfactant. The short-chain surfactant is composed of a hydrophobic portion and a hydrophilic portion, and the chain of the hydrophobic portion is Length is C6-CTenIt is. The mixture of the long-chain amine oxide is R1Is C14The first amine of the alkyl group Kide, R1Is C12Alkyl group or C16Secondary amine oxide of alkyl group Or a mixture of these amine oxides. R of the primary amine oxide1Is C12The second amine which is an alkyl group The ratio to the xide is 0.3 to 10 and R of the primary amine oxide is1But C16The ratio of the second amine oxide that is an alkyl group is 0.2 to 4.5. . All ratios, percentages and parts are based on total composition unless otherwise specified herein. It is the weight% with respect to the thing. The invention further comprises a method of treating tableware in contact with the composition according to the invention. . BEST MODE FOR CARRYING OUT THE INVENTION The liquid detergent composition of the present invention comprises a long chain amine oxide mixture and a short chain surfactant. including. The cleaning performance of the composition of the present invention can be improved by blending a short-chain surfactant. There was found. The composition of the invention comprises at least one short chain surfactant or mixtures thereof. . All surfactants usually consist of a hydrophobic part and a hydrophilic part. Short-chain surface activity The sexing agent means here C as its hydrophobic portion.6-CTenSurfactant containing alkyl chains Agent Means Although such surfactants are commonly used in this field, , Any type, including shorter alkyl chains. Therefore A suitable short-chain surfactant used in the present invention is C6-CTenAlkyl sulphate (C6-CTenSOFour), Alkyl ether sulfate (C6-CTen(OCH2 CH2)eSOFour), Alkyl sulfonate (C6-CTenSOThree), Alkyl sushi Nate (C6-CTenOOCCH2CH2COOZ), alkyl carboxylate ( C6-CTenCOOM), alkyl ether carboxylate (C6-CTen(OCH2 CH2)eCOOM), alkino sarcosinate (C6-CTenCON (CHThree) R ), Alkyl sulfosuccinate (C6-CTenOOCCH (SOThreeM) CH2CO OZ), amine oxide (C6-CTenRR'NO), glucose amide (C6-CTen CONR "X), alkylpyrrolidone (C6-CTen(CFourH6ON), alkyl Polysaccharide (C6-CTenOGg), alkyl alkoxylate (C6-CTen (OCH2CH2)e(OCH2CH2CH2)pOH) and betaine (C6-CTenN+ (CHThree)2COO-)including. The like parts e and p in the formula are independently 0 to 20 E + p> 0, Z is M or R, M is H or Na, K, Li, NHFour, It can be any counterion, including known ones including amines, where X is At least 3 hydroxyls attached directly to the chain or its alkoxylated With a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with a derivative And R, R'and R "are C1-CFiveAlkyl group, hydroxyl group if possible Thus functionalized, R and R'are preferably C1-CThreeMost preferably methyl And R "is preferably 2-hydroxyethyl or 2-hydroxypropyl. Where G is a saccharide, preferably glucose, and g is 1.5-8 . All these surfactants are well known. Normal glucose amide For a more complete disclosure, see, for example, WO 92-06154. Can be found in, and more complete opening of the usual alkyl polysaccharides. Indications can be found, for example, in US Pat. No. 4,536,319. Book The composition of the invention may comprise any of the above single surfactants or any of the above depending on the end use. Any combination of these can be included. Preferred nonionic short chain surfactants for use herein have the formula C6-CTen(OCH2 CH2)e(OCH2CH2CH2)pOH (where e and p are ethoxylated Degree and propoxylation degree, independently 0 to 20 and e + p> 0) Is an alkylalkoxylate represented by Most preferred to use here New short-chain nonionic surfactants have e + p of 3 to 10, especially p of 0 and e of 3 to 8. With some e and p. Further preferred short chains for use herein The nonionic surfactant is a hydrocarbon chain whose short chain is composed of 7 to 10 carbon atoms. Things. Preferred short chain nonionic surfactants for use herein are the corresponding alcohols. Prepared by a method well known to those skilled in the art, such as condensation of alkylene oxide with alkylene oxide. However, such short chain surfactants are more conveniently Product name MarginalR) C4 (C8EO4), Korbu Product name InventinR) AG / 810/050 and A G / 810/080 (C8-10EO5 and C8-10EO8, respectively) It is commercially available. Preferred short chain anionic surfactants for use herein are C6-CTenAlkylsa Ruffate (C6-CTenSOFour) And alkyl sulfonate (C6-CTenSOThree) Most preferably C6-C8Alkyl sulphates and sulphonates. This Short-chain anionic surfactants such as the well known sulfated or sulfonated and The anionic short-chain surface active agent can be produced by the following neutralization. The agent is more conveniently, for example, from Loan Pollen under the trade name Rudapo (RhodaponR) Product name Witsuconate (W itconateR) Is commercially available. A preferred short chain surfactant for use herein is dimethyloctylamineoxy. And octyl sulphate. Short chain surfactant suitable for use herein Are preferably hypochlorite compatible. According to the invention, the composition is a whole composition 0.5 to 15% by weight, preferably 0.5 to 10% by weight, more preferably It comprises 1-6% by weight, most preferably 2-4% by weight of short chain surfactants. Incorporating a short chain surfactant into a composition typically comprising an amine oxide , It has been described in the prior art to reduce the viscosity of said composition. Are known. Compositions comprising the use of a mixture of specific long chain amine oxides It has now been found that the viscosity of the is not disturbed. According to the present invention, a mixture of long chain amine oxides suitable for use herein has the formula R1R2RThreeRepresented by NO, R in the primary amine oxide1Is C14With an alkyl group Yes, R in secondary amine oxide1Is C12Alkyl group or C16Alkyl group Is a mixture of them. R2And RThreeAre both said primary and secondary amine Independent C in sid1To CThreeIt is an alkyl group. The ratio of the primary amine oxide to the secondary amine oxide is R1Is C12A When it is a rukyl group, it is 0.3 to 10, preferably 0.5 to 5, and The ratio of min oxide to the secondary amine oxide is such that De R1Is C16In the case of an alkyl group, it is 0.2 to 4.5, preferably 0.5 to 2. You. Preferred long chain amine oxides for use herein are Genaminox (Genam). inoxR) LA, GenaminoxR) MY-X, (hex Available from C), C12-C14AromoxR) DMMCO-W (AKZO), AromoxR) DM14D-W (AKZO), And AromoxR) DM14D-W (AKZO) Can be. Long chain surfactants suitable for use herein are preferably hypochlorite phase It is tolerable. According to the invention, said composition is 1.5 to 10 times the total composition. %, Preferably 1.5-7% by weight, more preferably 2-5% by weight, most preferred Or 2.5 to 4% by weight of a mixture of the long-chain amine oxides according to the invention. Departure Since the light composition comprises a mixture of said long chain amine oxides, the composition is 0.4 to 6% by weight, preferably 0.5 to 4% by weight, of the first amine relative to the composition Oxide and 0.5 to 4% by weight, preferably 0.5 to 3% by weight, of said second amine. Oxides. The composition of the present invention comprises a mixture of the long-chain amine oxide and the short-chain surfactant. In a ratio of 0.25 to 3, preferably 0.5 to 2. The long-chain amine oxide of the present invention is capable of measuring viscosity on a Brookfield viscometer RVT. Therefore, at a temperature of 25 ° C., using spindle number 2 or 3 or 4, 50 rpm Alternatively, it is measured at 100 rpm and is 50 to 2000 cps, preferably 100 to Restore to 700 cps. The compositions of the present invention may further comprise other long chain surfactants as an optional ingredient. it can. Suitable surfactants are alkyl sarcosinates, paraffin sulfonates , Alkyl sulphates and alkyl ether sulphates. A preferred optional ingredient is C12Alkylsulfate, short-chain surfactant and C12 The weight ratio of alkyl sulfonate is 1: 4 to 4: 1. Another optional component of the present invention is C8-C18It is an alkali metal salt of fatty acid. here Suitable fatty acids for use are any C8-C18Can be fatty acids, Preferably it is fully saturated, preferably with sodium, potassium or lithium salts. Yes, and more preferably the sodium salt. Suitable fatty acids are caprylic acid, caprylic Acid, lauric acid, myristic acid, palmitic acid, stearic acid and fatty acids Mixture, preferably hardened, tallow, coconut oil, ground oil, bubba It can be selected from those derived from natural sources such as soya oil. The composition of the present invention comprises 0.2 to 2% by weight, preferably 0.5 to 2% by weight of the total composition. Contains 1% by weight of fatty acids. The fatty acid serves as an additional densification aid, and foam suppressor. Can be used. Another optional ingredient of this invention is a hypochlorite bleach, preferably an alkali hypochlorite. It is a metal salt. Alkali metal hypochlorite is preferred, but calcium hypochlorite And other hypochlorite compounds that can be selected from magnesium hypochlorite Objects can also be used here. Suitable hypochlorite for use herein is It is sodium hypochlorite. The composition of the present invention, the hypochlorite bleaching agent, The composition contains 0.4 to 4% of active chlorine, preferably 1 to 2%. According to the present invention The components of the composition are selected such that the composition is hypochlorite compatible. The composition of the present invention is optionally required to have a pH of more than 12. Is greater than 12.5, more preferably greater than 12.8. this Is achieved by adding caustic. The preferred caustic used here Lucari includes sodium hydroxide and potassium hydroxide. The composition of the present invention further comprises a number of additional ingredients such as colorants and fragrances. Can be included. In addition, the composition of the present invention comprises a silicate as a corrosion inhibitor. Can be included. The compositions of the present invention are well known in the art, such as those described in GB 1329086. Prepared by The composition of the present invention mixes all components at room temperature in a non-metallic apparatus. Can be prepared. Preferably, the surfactant mixture is first It is prepared by adding a short chain surfactant to the long chain component. Fragrance and hyposalt The alkali metal oxalate is then added with stirring. Colorants are all other ingredients Add after mixing. The composition of the present invention may be used for various cleaning purposes such as cleaning hard surfaces. Because of this, the composition has a thickened property, so that the surface of the composition has a longer time than the non-densified composition. Adhere to. The composition is particularly suitable for cleaning inclined surfaces, including toilet balls. Suitable for In a composition of another aspect of the invention, the composition is for hand dishwashing. And used in dishwashing applications, including washing in automatic dishwashers. The present invention They found that food stains / deposited dishes (especially pots, pots, kitchen grills) and And / or stains on any kitchen utensil, the composition When used as a pretreatment composition, it has excellent cleaning properties, especially with regard to soil removal. It was found that it gives cleanliness performance. According to the invention, the dishes are provided with the composition of the invention in diluted or pure (raw) form. Sufficient time to contact and then treat the dishes, preferably 2-15 minutes Continue to contact the tableware with the composition, and then remove the composition to remove the composition. It involves the treatment of tableware, which consists of rinsing the tableware with water. The process is here Continuing, said dish is one of the present invention or any other conventional dishwashing products. The process of being washed by a dishwashing product including can be continued. In fact, Subsequent steps may be performed by hand dishwashing or by an automatic dishwasher. It can be either dishwashing. Alternatively, the composition of the present invention may be used as a pre-step of the above-mentioned tableware treating method. The dishes can be soaked in water prior to contact by. "Diluted form" means here that the composition of the invention is diluted with water. Means you can do it. Typically, the amount of dilution is 0.5-0.5% of the composition of the invention in water. It is 3% by weight. Said dilution is prior to or before applying the composition of the invention to said dishes. Can be done. The expression "treatment" as used in the preceding paragraph refers to surfactants and bleaching agents. As well as a composition according to the invention which comprises washing with a suitable composition according to the invention comprising hypochlorite. Including Jiyo. The composition of the invention can be illustrated by the following examples.
───────────────────────────────────────────────────── フロントページの続き (31)優先権主張番号 ９４８７０００２．６ (32)優先日 1994年１月10日 (33)優先権主張国 欧州特許機構（ＥＰ） (81)指定国 ＥＰ(ＡＴ，ＢＥ，ＣＨ，ＤＥ， ＤＫ，ＥＳ，ＦＲ，ＧＢ，ＧＲ，ＩＥ，ＩＴ，ＬＵ，Ｍ Ｃ，ＮＬ，ＰＴ，ＳＥ)，ＯＡ(ＢＦ，ＢＪ，ＣＦ，ＣＧ ，ＣＩ，ＣＭ，ＧＡ，ＧＮ，ＭＬ，ＭＲ，ＮＥ，ＳＮ， ＴＤ，ＴＧ)，ＡＵ，ＢＢ，ＢＧ，ＢＲ，ＢＹ，ＣＡ， ＣＮ，ＣＺ，ＦＩ，ＧＥ，ＨＵ，ＪＰ，ＫＧ，ＫＰ，Ｋ Ｒ，ＫＺ，ＬＫ，ＬＶ，ＭＤ，ＭＧ，ＭＮ，ＭＷ，ＮＯ ，ＮＺ，ＰＬ，ＲＯ，ＲＵ，ＳＤ，ＳＩ，ＳＫ，ＴＪ， ＴＴ，ＵＡ，ＵＳ，ＵＺ，ＶＮ (72)発明者 ドラツィオ，アンナ ルチア イタリー国ローマ、ビア、タツィオ、ヌボ ラリ、53 (72)発明者 ソドウ，アンドレア ベルギー国ユークル、リュ、ド、ラ、フォ ベット、79────────────────────────────────────────────────── ─── Continuation of front page (31) Priority claim number 94870006. (32) Priority date January 10, 1994 (33) Countries claiming priority European Patent Organization (EP) (81) Designated countries EP (AT, BE, CH, DE, DK, ES, FR, GB, GR, IE, IT, LU, M C, NL, PT, SE), OA (BF, BJ, CF, CG , CI, CM, GA, GN, ML, MR, NE, SN, TD, TG), AU, BB, BG, BR, BY, CA, CN, CZ, FI, GE, HU, JP, KG, KP, K R, KZ, LK, LV, MD, MG, MN, MW, NO , NZ, PL, RO, RU, SD, SI, SK, TJ, TT, UA, US, UZ, VN (72) Inventor Drazio, Anna Lucia Italy Country Rome, Via, Tazio, Nubo Lari, 53 (72) Inventor Sodo, Andrea Belgium, Euclid, Ryu, De, La, Fo Bet, 79
Claims (1)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP93202186 | 1993-07-23 | ||
| EP93202186.8 | 1993-07-23 | ||
| EP93870222 | 1993-11-22 | ||
| EP93870222.2 | 1993-11-22 | ||
| EP94870002 | 1994-01-10 | ||
| EP94870002.6 | 1994-01-10 | ||
| PCT/US1994/008089 WO1995003383A1 (en) | 1993-07-23 | 1994-07-18 | Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH09500680A true JPH09500680A (en) | 1997-01-21 |
| JP3923074B2 JP3923074B2 (en) | 2007-05-30 |
Family
ID=27235316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50525395A Expired - Fee Related JP3923074B2 (en) | 1993-07-23 | 1994-07-18 | Concentrated aqueous detergent composition with improved detergency including short chain surfactants |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0711335A4 (en) |
| JP (1) | JP3923074B2 (en) |
| CN (1) | CN1057790C (en) |
| AU (1) | AU7366294A (en) |
| CA (1) | CA2167482C (en) |
| CZ (1) | CZ20296A3 (en) |
| HU (1) | HU219162B (en) |
| MX (1) | MXPA94005640A (en) |
| WO (1) | WO1995003383A1 (en) |
| ZA (1) | ZA945410B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017029519A (en) * | 2015-08-04 | 2017-02-09 | 花王株式会社 | Method of washing glass or ceramic made dish |
| JP2017538015A (en) * | 2014-12-19 | 2017-12-21 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition |
| JP2019156929A (en) * | 2018-03-09 | 2019-09-19 | 株式会社ニイタカ | Foaming cleaner composition and cleaning method |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0667892B1 (en) * | 1992-11-03 | 1999-07-07 | The Procter & Gamble Company | Cleaning with short-chain surfactants |
| CA2199260A1 (en) * | 1994-09-06 | 1996-03-14 | Ian C. Callaghan | A cleaning composition comprising lipase and amylase enzymes |
| DE19621048C2 (en) * | 1996-05-24 | 2000-06-21 | Henkel Kgaa | Aqueous bleach and disinfectant |
| DE19626906C1 (en) * | 1996-07-04 | 1998-03-12 | Henkel Kgaa | Means for cleaning hard surfaces |
| US5922669A (en) * | 1997-09-10 | 1999-07-13 | Albemarle Corporation | No-rub hard surface cleaner comprising an alcohol ethoxylate-amine oxide surfactant mixture and a nitrogenous builder in aqueous solution |
| EP0916718A1 (en) * | 1997-10-14 | 1999-05-19 | The Procter & Gamble Company | Cleaning and disinfecting compositions |
| GB2334721B (en) * | 1998-02-25 | 2002-06-12 | Reckitt & Colman Inc | Cleansing composition |
| GB2334722B (en) * | 1998-02-25 | 2002-04-24 | Reckitt & Colman Inc | Aqueous cleaning composition for removing soap scum |
| DE10343730A1 (en) * | 2003-09-22 | 2005-04-21 | Clariant Gmbh | Highly concentrated aqueous solution of amphoteric surfactants |
| CN101798551B (en) * | 2010-04-30 | 2012-01-18 | 北京绿伞化学股份有限公司 | Concentrated tableware detergent and preparation method thereof |
| US9757006B2 (en) | 2013-03-26 | 2017-09-12 | The Procter & Gamble Company | Articles for cleaning a hard surface |
| WO2014160590A1 (en) * | 2013-03-26 | 2014-10-02 | The Procter & Gamble Company | Cleaning compositions for cleaning a hard surface |
| EP3078731A1 (en) * | 2015-04-10 | 2016-10-12 | Henkel AG & Co. KGaA | Cleaning composition comprising bleach |
| WO2016200343A1 (en) * | 2015-06-09 | 2016-12-15 | Hayat Kimya Sanayi Anonim Sirketi | Aqueous, thickened and transparent bleaching compositions |
| EP3257926A1 (en) * | 2016-06-17 | 2017-12-20 | The Procter and Gamble Company | Liquid detergent composition |
| EP3670637A1 (en) * | 2018-12-18 | 2020-06-24 | Henkel AG & Co. KGaA | Viscosity regulation in handwash agents |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3928249A (en) * | 1972-02-07 | 1975-12-23 | Procter & Gamble | Liquid detergent composition |
| US3892669A (en) * | 1972-10-27 | 1975-07-01 | Lever Brothers Ltd | Clear fabric-softening composition |
| US3953382A (en) * | 1973-05-30 | 1976-04-27 | Lever Brothers Company | Detergent compositions |
| DE3268705D1 (en) * | 1981-11-07 | 1986-03-06 | Procter & Gamble | Cleaning compositions |
| GB8630845D0 (en) * | 1986-12-24 | 1987-02-04 | Ici Plc | Bleaching compositions |
| GB8917626D0 (en) * | 1989-08-02 | 1989-09-20 | Quest Int | Perfumed bleach compositions |
-
1994
- 1994-07-18 CZ CZ96202A patent/CZ20296A3/en unknown
- 1994-07-18 JP JP50525395A patent/JP3923074B2/en not_active Expired - Fee Related
- 1994-07-18 CN CN94193203A patent/CN1057790C/en not_active Expired - Fee Related
- 1994-07-18 CA CA002167482A patent/CA2167482C/en not_active Expired - Fee Related
- 1994-07-18 EP EP94922613A patent/EP0711335A4/en not_active Withdrawn
- 1994-07-18 AU AU73662/94A patent/AU7366294A/en not_active Abandoned
- 1994-07-18 HU HU9600139A patent/HU219162B/en not_active IP Right Cessation
- 1994-07-18 WO PCT/US1994/008089 patent/WO1995003383A1/en not_active Application Discontinuation
- 1994-07-22 ZA ZA945410A patent/ZA945410B/en unknown
- 1994-07-22 MX MXPA94005640A patent/MXPA94005640A/en not_active IP Right Cessation
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017538015A (en) * | 2014-12-19 | 2017-12-21 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition |
| JP2019199617A (en) * | 2014-12-19 | 2019-11-21 | ザ プロクター アンド ギャンブルカンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | Liquid detergent compositions |
| JP2022051765A (en) * | 2014-12-19 | 2022-04-01 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition |
| JP2017029519A (en) * | 2015-08-04 | 2017-02-09 | 花王株式会社 | Method of washing glass or ceramic made dish |
| JP2019156929A (en) * | 2018-03-09 | 2019-09-19 | 株式会社ニイタカ | Foaming cleaner composition and cleaning method |
Also Published As
| Publication number | Publication date |
|---|---|
| HU219162B (en) | 2001-02-28 |
| EP0711335A1 (en) | 1996-05-15 |
| CA2167482A1 (en) | 1995-02-02 |
| CZ20296A3 (en) | 1996-07-17 |
| WO1995003383A1 (en) | 1995-02-02 |
| MXPA94005640A (en) | 2005-08-19 |
| CN1057790C (en) | 2000-10-25 |
| CA2167482C (en) | 1999-12-28 |
| EP0711335A4 (en) | 1997-07-09 |
| ZA945410B (en) | 1995-02-28 |
| HU9600139D0 (en) | 1996-03-28 |
| JP3923074B2 (en) | 2007-05-30 |
| AU7366294A (en) | 1995-02-20 |
| HUT73751A (en) | 1996-09-30 |
| CN1129951A (en) | 1996-08-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH09500680A (en) | Thickened aqueous detergent composition with improved cleaning performance containing short chain surfactants | |
| JP2620228B2 (en) | Cleaning composition | |
| EP0013585A1 (en) | Light duty liquid detergent composition | |
| JPH0350299A (en) | Neutral liquid detergent composition | |
| CZ230194A3 (en) | COSMETIC CLEANSING STICK WITH NEUTRAL pH AND PROCESS FOR PREPARING THEREOF | |
| CZ53393A3 (en) | Liquid or jellylike cleansing agent and method of washing dishes therewith | |
| JP2010533234A (en) | Detergent composition containing foam promoting cosurfactant and foam stabilizing surfactant polymer | |
| JPH08505424A (en) | Dishwashing detergent | |
| EP0720642B1 (en) | Thickneded aqueous detergent compositions with improved cleaning performance | |
| RU2073700C1 (en) | Liquid detergent composition for washing dishes | |
| CA1231879A (en) | Liquid all-purpose cleaner | |
| JPH0699708B2 (en) | Neutral liquid detergent composition | |
| JPH05271690A (en) | Detergent composition | |
| CZ230294A3 (en) | SOLID, COSMETIC CLEANSING STICK WITH NEUTRAL pH AND PROCESS FOR PREPARING THEREOF | |
| US5693601A (en) | Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants | |
| JPH0726115B2 (en) | Detergent composition | |
| JP2530215B2 (en) | Detergent composition | |
| JP4877912B2 (en) | Liquid detergent composition | |
| JP2571117B2 (en) | Detergent composition | |
| NO127305B (en) | ||
| JPH04249599A (en) | Cleaning composition which gives improvement in reducing mash and/or improvement in mildness | |
| JPH08503236A (en) | Liquid dishwashing detergent composition | |
| EP0693548B1 (en) | A stable concentrated premix and its use for manufacturing aqueous detergent compositions | |
| JP2566821B2 (en) | Detergent composition | |
| JP2582626B2 (en) | Detergent composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20031120 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20040302 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20040419 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20040526 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20070123 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20070221 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| LAPS | Cancellation because of no payment of annual fees |