CN112955332B - 氨基硅烷基官能化共轭二烯、其制备及在橡胶制造中的应用 - Google Patents

氨基硅烷基官能化共轭二烯、其制备及在橡胶制造中的应用 Download PDF

Info

Publication number
CN112955332B
CN112955332B CN201980072457.4A CN201980072457A CN112955332B CN 112955332 B CN112955332 B CN 112955332B CN 201980072457 A CN201980072457 A CN 201980072457A CN 112955332 B CN112955332 B CN 112955332B
Authority
CN
China
Prior art keywords
atoms
group
conjugated diene
copolymer
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201980072457.4A
Other languages
English (en)
Chinese (zh)
Other versions
CN112955332A (zh
Inventor
玛丽亚·西奥列克-科莫雷克
拉多斯劳·科扎克
帕韦尔·韦德
罗伯特·博加齐
托马什·斯科洛克
玛尔戈扎塔·瓦乐妮亚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sisso Dolly Seven
Synthos SA
Original Assignee
Sisso Dolly Seven
Synthos SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sisso Dolly Seven, Synthos SA filed Critical Sisso Dolly Seven
Publication of CN112955332A publication Critical patent/CN112955332A/zh
Application granted granted Critical
Publication of CN112955332B publication Critical patent/CN112955332B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/10Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06Butadiene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/14Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L19/00Compositions of rubbers not provided for in groups C08L7/00 - C08L17/00
    • C08L19/006Rubber characterised by functional groups, e.g. telechelic diene polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Tires In General (AREA)
  • Polymerization Catalysts (AREA)
CN201980072457.4A 2018-09-03 2019-09-02 氨基硅烷基官能化共轭二烯、其制备及在橡胶制造中的应用 Active CN112955332B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP18461604 2018-09-03
EP18461604.3 2018-09-03
PCT/EP2019/073369 WO2020048930A1 (en) 2018-09-03 2019-09-02 Aminosilyl-functionalized conjugated dienes, their preparation and their use in the production of rubbers

Publications (2)

Publication Number Publication Date
CN112955332A CN112955332A (zh) 2021-06-11
CN112955332B true CN112955332B (zh) 2023-02-21

Family

ID=63678590

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980072457.4A Active CN112955332B (zh) 2018-09-03 2019-09-02 氨基硅烷基官能化共轭二烯、其制备及在橡胶制造中的应用

Country Status (8)

Country Link
US (1) US11993620B2 (https=)
EP (1) EP3847042B1 (https=)
JP (2) JP7574179B2 (https=)
KR (1) KR20210057057A (https=)
CN (1) CN112955332B (https=)
EA (1) EA202190668A1 (https=)
PL (1) PL3847042T3 (https=)
WO (1) WO2020048930A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220164705A (ko) * 2020-04-07 2022-12-13 제트에스 엘라스토머 가부시키가이샤 공액 디엔계 중합체, 공액 디엔계 중합체 조성물, 고무 가교물, 및 타이어
CN115246899B (zh) * 2021-04-27 2023-10-10 中国石油化工股份有限公司 一种立构嵌段聚丁二烯及其制备方法
CN115246913B (zh) * 2021-04-27 2023-10-10 中国石油化工股份有限公司 一种立构嵌段聚异戊二烯及其制备方法
JP2024531349A (ja) * 2021-08-17 2024-08-29 アランセオ・ドイチュランド・ゲーエムベーハー 官能化ポリマー

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0767206B1 (fr) * 1995-10-04 2002-07-10 Compagnie Generale Des Etablissements Michelin-Michelin & Cie Composition de caoutchouc à base d'un polymère diénique comprenant un dérivé organosilane, utilisable pour la fabrication de bandes de roulement de pneumatiques
WO2002002576A1 (en) * 2000-06-30 2002-01-10 Exxonmobil Chemical Patents Inc. Bridged bis (indenyl) metallocene compounds
WO2003014248A2 (en) * 2001-08-07 2003-02-20 National Starch And Chemical Investment Holding Corporation Adhesion promoting resins with cross-linking properties
BRPI0604797A (pt) * 2005-11-30 2007-10-09 Goodyear Tire & Rubber polìmeros de borracha funcionalizados
TW201022301A (en) * 2008-08-27 2010-06-16 Sumitomo Chemical Co Conjugated diene polymer, conjugated diene polymer composition, and method for producing conjugated diene polymer
CN102549020B (zh) * 2009-09-09 2013-12-11 株式会社普利司通 改性剂、使用该改性剂的改性共轭二烯类聚合物的制造方法以及该改性共轭二烯类聚合物
TWI491619B (zh) * 2009-10-21 2015-07-11 Jsr Corp A method for producing a conjugated diene rubber, a modified conjugated diene rubber, and a rubber composition
WO2011082277A1 (en) * 2009-12-31 2011-07-07 Bridgestone Corporation Aminosilane initiators and functionalized polymers prepared therefrom
BR112013016433B1 (pt) * 2010-12-30 2021-02-23 Bridgestone Corporation processo para produzir polímeros funcionalizados com aminosilano, polímero telequélico produzido a partir deste processo e composição de borracha para uso em pneus
JP5956556B2 (ja) * 2011-03-29 2016-07-27 株式会社ブリヂストン シリル化アミノ基を含有するカルボン酸またはチオカルボン酸エステルで官能化されたポリマー
CN103502345B (zh) * 2011-04-28 2016-01-20 住友橡胶工业株式会社 橡胶组合物及充气轮胎
JP2012240924A (ja) * 2011-05-16 2012-12-10 Shin-Etsu Chemical Co Ltd 有機ケイ素化合物及びその製造方法、ゴム用配合剤、ゴム組成物並びにタイヤ
JP6173923B2 (ja) 2012-02-01 2017-08-02 住友ゴム工業株式会社 分枝共役ジエン共重合体、ゴム組成物および空気入りタイヤ
WO2013115011A1 (ja) 2012-02-02 2013-08-08 住友ゴム工業株式会社 分枝共役ジエン共重合体、ゴム組成物および空気入りタイヤ
WO2013183743A1 (ja) 2012-06-08 2013-12-12 住友ゴム工業株式会社 トレッド用ゴム組成物及び空気入りタイヤ
PL2895515T3 (pl) * 2012-09-14 2017-12-29 Trinseo Europe Gmbh Polimery modyfikowane przy użyciu aminosilanu
JP6181529B2 (ja) 2013-11-25 2017-08-16 住友ゴム工業株式会社 空気入りタイヤ
US9938305B2 (en) * 2014-07-14 2018-04-10 Trinseo Europe Gmbh Aminosilyl-substituted diarylethene compounds for anionic polymerisation
JP6562603B2 (ja) * 2014-08-11 2019-08-21 株式会社クラレ 変性ファルネセン重合体を含むゴム組成物及びタイヤ、並びに変性ファルネセン重合体の製造方法
KR101705947B1 (ko) * 2014-11-12 2017-02-10 한화토탈 주식회사 실릴음이온 개시제를 이용한 변성공액디엔계 중합체의 중합
KR101776391B1 (ko) * 2014-12-01 2017-09-07 주식회사 엘지화학 아민기를 포함하는 음이온 말단을 갖는 음이온 중합 개시제, 이를 이용한 변성 공역디엔계 공중합체의 제조방법, 및 이에 따라 제조한 변성 공역디엔계 공중합체를 포함하는 고무 조성물
JP2016117880A (ja) * 2014-12-17 2016-06-30 東洋ゴム工業株式会社 共重合体、ゴム組成物及び空気入りタイヤ
EP3059256B1 (en) * 2015-02-18 2017-11-15 Trinseo Europe GmbH A functionalized polymer blend for a tire
BR112017016522A2 (pt) * 2015-02-19 2018-04-10 Asahi Kasei Kabushiki Kaisha polímero com base em dieno conjugado modificado, método de fabricação do mesmo, e composição de polímero com base em dieno conjugado modificado
BR112017021159A2 (pt) 2015-04-10 2018-07-03 Synthos Sa copolímeros elastoméricos com base em estireno [bis(tri-hidrocarbilsilil)aminossilil]-funcionalizado e seu uso na preparação de borrachas
DK3280744T3 (en) 2015-04-10 2018-10-29 Synthos Sa [Bis (trihydrocarbylsilyl) aminosilyl] functionalized styrene and process for its preparation.
US10961327B2 (en) * 2015-09-14 2021-03-30 Jsr Corporation Method for producing hydrogenated conjugated diene-based polymer, hydrogenated conjugated diene-based polymer, polymer composition, cross-linked polymer, and tire
HUE039540T2 (hu) * 2015-10-21 2019-01-28 Trinseo Europe Gmbh Elasztomer polimerek funkcionalizálása során történõ alkalmazásra szolgáló aminoszilán-funkcionalizált diének
HUE042696T2 (hu) * 2016-06-17 2019-07-29 Trinseo Europe Gmbh A gumi tárolási stabilitásának szilán-mediált fokozása
KR102150526B1 (ko) * 2016-06-17 2020-09-01 주식회사 엘지화학 변성 공액디엔계 중합체의 제조방법 및 이를 이용하여 제조된 변성 공액디엔계 중합체
SG11201811355XA (en) * 2016-06-24 2019-01-30 Jsr Corp Method for producing modified conjugated diene-based polymer, modified conjugated diene-based polymer, polymer composition, crosslinked body, tire and compound
KR101997596B1 (ko) * 2016-07-04 2019-07-08 주식회사 엘지화학 변성제, 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물
BR112018016214A2 (pt) * 2016-10-06 2018-12-18 Synthos S.A. copolímeros elastoméricos baseados em [bis(tri-hidrocarbilsilil)aminosilil]-estireno funcionalizado e seu uso na preparação de borrachas
KR102123080B1 (ko) * 2016-10-07 2020-06-15 주식회사 엘지화학 아미노 실란계 화합물, 이의 제조방법 및 이를 포함하는 변성 공액디엔계 중합체
KR102122470B1 (ko) * 2016-12-08 2020-06-12 주식회사 엘지화학 변성제 및 이로부터 유래된 작용기를 포함하는 변성 공액디엔계 중합체

Also Published As

Publication number Publication date
US20210261575A1 (en) 2021-08-26
EP3847042A1 (en) 2021-07-14
US11993620B2 (en) 2024-05-28
CN112955332A (zh) 2021-06-11
JP2024167226A (ja) 2024-12-03
JP7812890B2 (ja) 2026-02-10
WO2020048930A1 (en) 2020-03-12
EA202190668A1 (ru) 2021-05-27
JP7574179B2 (ja) 2024-10-28
JP2021535172A (ja) 2021-12-16
EP3847042B1 (en) 2021-12-01
PL3847042T3 (pl) 2022-02-21
KR20210057057A (ko) 2021-05-20

Similar Documents

Publication Publication Date Title
CN101835807B (zh) 用含氨基的卤代硅烷官能化的聚合物
CN102143980B (zh) 用含被保护氨基的酰亚胺化合物官能化的聚合物
JP7812890B2 (ja) アミノシリル官能化共役ジエン、その調製、およびゴムの製造におけるその使用方法
CN113329890B (zh) 双甲硅烷基氨基官能化共轭二烯烃、其制备及在橡胶生产中的应用
CN104903358B (zh) 有机金属催化剂络合物及采用其的聚合方法
JP2017535621A (ja) 共役ジエン系重合体の製造方法
CN110382509B (zh) 双硅烷基氨基硅烷基官能化共轭二烯及其在橡胶制造中的使用
CN104364275A (zh) 具有有机膦官能的聚二烯和二烯共聚物
CN103459402A (zh) 镧系元素络合物催化剂以及使用其的聚合方法
CN111971316B (zh) 氨基硅烷基官能化苯乙烯的混合物、它们的制备及它们在弹性体共聚物生产中的使用
RU2812525C2 (ru) Функционализированные биссилиламином сопряженные диены, их получение и их применение при производстве каучуков
EA045508B1 (ru) Аминосилил-функционализованные сопряженные диены, их получение и их использование при производстве каучуков
BR112021013013B1 (pt) Dienos conjugados funcionalizados com bissililamino, usos, copolímero elastomérico, borracha, métodos de preparação, composição de borracha, componente de pneu e pneu

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant