CN1129249A - Method for preparing hydrogen diesel oil additive and application - Google Patents
Method for preparing hydrogen diesel oil additive and application Download PDFInfo
- Publication number
- CN1129249A CN1129249A CN 95101391 CN95101391A CN1129249A CN 1129249 A CN1129249 A CN 1129249A CN 95101391 CN95101391 CN 95101391 CN 95101391 A CN95101391 A CN 95101391A CN 1129249 A CN1129249 A CN 1129249A
- Authority
- CN
- China
- Prior art keywords
- diesel
- diesel oil
- oil
- additive
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002283 diesel fuel Substances 0.000 title claims abstract description 33
- 239000000654 additive Substances 0.000 title claims abstract description 26
- 230000000996 additive effect Effects 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 2
- 239000001257 hydrogen Substances 0.000 title abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 title abstract 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 14
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 230000003197 catalytic effect Effects 0.000 claims description 10
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 9
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000009775 high-speed stirring Methods 0.000 claims description 2
- 238000004945 emulsification Methods 0.000 claims 2
- 239000000446 fuel Substances 0.000 abstract description 8
- 239000000839 emulsion Substances 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- -1 alkyl naphthalene Chemical compound 0.000 abstract description 3
- 231100000957 no side effect Toxicity 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract description 2
- 239000007859 condensation product Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract 1
- 239000003502 gasoline Substances 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 3
- 230000000994 depressogenic effect Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000005526 G1 to G0 transition Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
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- Catalysts (AREA)
Abstract
The invention relates to a manufacturing method and application of a hydrogen diesel additive. The components by weight percentage are as follows: 75-85% of condensation product of alkyl acid and ethylene oxide, 8-12% of sodium dodecyl sulfate, 2-3% of alkyl naphthalene, 1-2% of alkyl aryl ammonium sulfonate, 1-2% of titanate, 2-4% of acetone and 3-5% of toluene. The preparation method comprises mixing the above materials at a certain proportion, and stirring to obtain emulsion. The additive is used for manufacturing water and diesel synthetic fuel. The physical index and chemical index of the synthetic fuel are similar to those of diesel oil, and the synthetic fuel has no side effect on the engine and has the oil saving rate of 35-40%.
Description
The present invention relates to a kind of hydro-diesel-oil additives production process and application.Belong to chemical field.
The synthol majority is the deficiency that solves the energy at present, the particularly shortage of petroleum resources,, but how to save for the production of the emulsion gasoline of gasoline, a lot of with water for this fuel of diesel oil with the test of alcohol gasoline replacing, whether can be with water for the diesel oil research of still needing.
For diesel oil, obtain water and diesel oil synthol, with water with energy-efficient.We call catalytic diesel oil to water and diesel oil synthol.
The objective of the invention is to propose a kind of two kinds of liquid of not bathing mutually of water and diesel oil that make additive and manufacture method and application that chemistry, physical change become New-type fuel (catalytic diesel oil) take place rapidly.
Additive of the present invention is a kind of nonionic surface active agent, is made up of by a certain percentage emulsifying agent, ignition dope, suspension agent, lubricant, pour point depressant etc.
Emulsifying agent is selected alkylphenol and ethylene oxide condensate (TX-18) for use, and sodium lauryl sulphate (SDS).Alkylphenol and ethylene oxide condensate have the good emulsifying performance, its structure of this promoting agent has hydrophilic, lipophilic two close atoms, hydrophilic group can make molecule introduce water, and oleophilic group can be introduced oil, under the effect of alkylphenol and ethylene oxide condensate, oil content is dispersed in forms oil-in-water emulsion in the water, the oleophilic group molecule also can form water-in-oil type emulsion.Sodium lauryl sulphate (SDS) is made the auxiliary agent of T-18, performance, the hydrophilic group that can improve hydrophilic and oleophilic in water, form micella be spherule be in spherome surface, can stable being dispersed in the water, micella is inner to be constituted the liquid carbon proton water is not precipitated in diesel oil and oleophilic group is in, be convenient to keeping, life-time service.
The pour point depressant alkylnaphthalene is used to prevent in additive solidify, improve the diesel oil number, increase rate of utilization because of the low diesel oil with water of temperature.
Lubricant alkyl aryl sulphonic acid ammonium and titanate mix use, can prevent to reduce the resistance of diesel oil in mechanical work, lubricate because of adding water.
Ignition dope is cooked the ignition dope of additive of acetone and benzene, make the artificial catalytic diesel oil burning that adds water thorough, improve ignition characteristic, above-mentioned each chemical industry preparation is proportioned, other adds carboxymethyl cellulose and does 80 ℃ of one-tenth paste solids behind stirring, the mould shape of packing into of parent heating, is convenient to transportation.
The present invention is a kind of hydro-diesel-oil additives production process and application, it is characterized in that its composition, is by weight percentage:
Alkyl acid and ethylene oxide condensate 75%-85%
Sodium lauryl sulphate 8%-12%
Alkylnaphthalene 2%-3%
Alkyl aryl sulphonic acid ammonium 1%-2%
Titanate 1%-2%
Acetone 2%-4%.
Toluene 3%-5%
Embodiment: the composition of additive is by weight percentage:
Alkyl acid and ethylene oxide condensate 79%
Sodium lauryl sulphate 11%
Alkylnaphthalene 2%
Alkyl aryl sulphonic acid ammonium 2%
Titanate 1%
Acetone 2%.
Toluene 3%
Additives production process of the present invention is alkyl acid and ethylene oxide condensate, sodium lauryl sulphate, alkylnaphthalene, alkyl aryl sulphonic acid ammonium, titanate, acetone, toluene to be mixed in proportion to stir be the emulsion liquid additive.
With 80 ℃ of the carboxymethyl cellulose Hybrid Heating of emulsion liquid additive and equivalent weight, stir, the mould shape of packing into becomes the paste solid additive.
Additive is applied to make catalytic diesel oil, and concrete steps are: by weight, water 40%-45%, diesel oil 60%-55%, every 1000kg adds fluid additive 1kg in addition, and it is catalytic diesel oil that mixing back high-speed stirring becomes uniform liquid.
Similar to natural diesel oil with the various physical indexs of catalytic diesel oil that this additive is made with chemical index, it is widely used in engineering machinery, generating set, vehicle and the boats and ships etc. that all are fuel with diesel oil, use its engine power performance of machinery of catalytic diesel oil constant substantially, to engine have no side effect, rate of economizing gasoline reaches 35%-40%, smoke intensity reduces 40%, the exhaust emissions obnoxious flavour reduces 30%, oil stationary phase is more than 30 days, and can dissolve each other generally with natural diesel oil, as taking place, precipitation can never scrap by the mechanical means regeneration.
It is as follows that the catalytic diesel oil made from additive of the present invention is used for the diesel motor trial sheet:
| S195 number of cylinders 1 cylinder diameter 95 | 14-17 ℃ of relative humidity 50-70% of barometric point 103.2KPa room temperature fuel trade mark DieseI+H 2O | ||||||
| Rotating speed | Load | Fuel consumption | Rate of economizing gasoline | Exhaust | |||
| N rev/min | The p kilogram | Δ g gram | T second | G gram KW hour | Dark brown | ||
| ????1000 | ????4.7 | ????30 | ????64.05 | ????488 | ??29.3％ | ????6.6 | |
| ????1200 | ???5.45 | ????30 | ????51.38 | ????437 | ??37.2％ | ????6.6 | |
| ????1400 | ????5.8 | ????40 | ????60.98 | ??395.5 | ?40.00％ | ????6.3 | |
| ????1600 | ????6.2 | ????40 | ????51.36 | ????384 | ?39.76％ | ????5.6 | |
| ????1800 | ????6.5 | ????40 | ????44.54 | ????376 | ?37.87％ | ????5.3 | |
| ????2000 | ????6.2 | ????50 | ????50.97 | ????387 | ??40.2％ | ????6.0 | |
Claims (3)
1, a kind of hydro-diesel-oil additives is characterized in that its composition being by weight percentage:
Alkyl acid and ethylene oxide condensate 75%-85%
Sodium lauryl sulphate 8%-12%
Alkylnaphthalene 2%-3%
Alkyl aryl sulphonic acid ammonium 1%-2%
Titanate 1%-2%
Acetone 2%-4%.
Toluene 3%-5%
2, by the manufacture method of the described hydro-diesel-oil additives of claim 1, it is characterized in that:
A, alkyl acid and ethylene oxide condensate, sodium lauryl sulphate, alkylnaphthalene, alkyl aryl sulphonic acid ammonium, titanate, acetone, toluene is mixed in proportion to stir is emulsification shape fluid additive;
B, with 80 ℃ of the carboxymethyl cellulose Hybrid Heating of emulsification shape fluid additive and equivalent weight, stir, the mould shape of packing into becomes the paste solid additive.
3, by the described hydro-diesel-oil additives of claim 1, it is characterized in that: make catalytic diesel oil, concrete steps are: by weight, and water 40%-45%, diesel oil 60%-55%, every 1000kg adds fluid additive 1kg in addition, and it is catalytic diesel oil that mixing back high-speed stirring becomes uniform liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95101391 CN1129249A (en) | 1995-02-15 | 1995-02-15 | Method for preparing hydrogen diesel oil additive and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95101391 CN1129249A (en) | 1995-02-15 | 1995-02-15 | Method for preparing hydrogen diesel oil additive and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1129249A true CN1129249A (en) | 1996-08-21 |
Family
ID=5073936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 95101391 Pending CN1129249A (en) | 1995-02-15 | 1995-02-15 | Method for preparing hydrogen diesel oil additive and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1129249A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101555426A (en) * | 2008-04-10 | 2009-10-14 | 张学纯 | Reproduced watery admiralty fuel oil additive refined by one-step method |
-
1995
- 1995-02-15 CN CN 95101391 patent/CN1129249A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101555426A (en) * | 2008-04-10 | 2009-10-14 | 张学纯 | Reproduced watery admiralty fuel oil additive refined by one-step method |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |