CN117778070A - Marine microorganism cleaning energy-saving agent and preparation method thereof - Google Patents
Marine microorganism cleaning energy-saving agent and preparation method thereof Download PDFInfo
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- CN117778070A CN117778070A CN202410026196.5A CN202410026196A CN117778070A CN 117778070 A CN117778070 A CN 117778070A CN 202410026196 A CN202410026196 A CN 202410026196A CN 117778070 A CN117778070 A CN 117778070A
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- marine microorganism
- saving agent
- mother liquor
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- 244000005700 microbiome Species 0.000 title claims abstract description 40
- 238000004140 cleaning Methods 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 239000012452 mother liquor Substances 0.000 claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 18
- 239000002699 waste material Substances 0.000 claims abstract description 18
- 239000003921 oil Substances 0.000 claims abstract description 12
- 239000003350 kerosene Substances 0.000 claims abstract description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 239000006228 supernatant Substances 0.000 claims description 9
- 230000000813 microbial effect Effects 0.000 claims description 8
- 239000000295 fuel oil Substances 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 241000222178 Candida tropicalis Species 0.000 claims description 6
- 102000004190 Enzymes Human genes 0.000 claims description 6
- 108090000790 Enzymes Proteins 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- LFKXWKGYHQXRQA-FDGPNNRMSA-N (z)-4-hydroxypent-3-en-2-one;iron Chemical compound [Fe].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O LFKXWKGYHQXRQA-FDGPNNRMSA-N 0.000 claims description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 125000005456 glyceride group Chemical group 0.000 claims description 4
- 238000007781 pre-processing Methods 0.000 claims description 4
- 239000000661 sodium alginate Substances 0.000 claims description 4
- 235000010413 sodium alginate Nutrition 0.000 claims description 4
- 229940005550 sodium alginate Drugs 0.000 claims description 4
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 229930182480 glucuronide Natural products 0.000 claims description 3
- 150000008134 glucuronides Chemical class 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 230000001376 precipitating effect Effects 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- GODZNYBQGNSJJN-UHFFFAOYSA-N 1-aminoethane-1,2-diol Chemical compound NC(O)CO GODZNYBQGNSJJN-UHFFFAOYSA-N 0.000 claims description 2
- 238000010008 shearing Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000003599 detergent Substances 0.000 claims 1
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 abstract description 6
- 230000029936 alkylation Effects 0.000 abstract description 4
- 238000005804 alkylation reaction Methods 0.000 abstract description 4
- -1 butyl cresol Chemical group 0.000 abstract description 4
- 229930003836 cresol Natural products 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000003208 petroleum Substances 0.000 abstract description 3
- 239000002816 fuel additive Substances 0.000 abstract description 2
- 239000003502 gasoline Substances 0.000 description 12
- 239000002283 diesel fuel Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- 230000001965 increasing effect Effects 0.000 description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 239000003344 environmental pollutant Substances 0.000 description 5
- 231100000719 pollutant Toxicity 0.000 description 5
- 239000000654 additive Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Landscapes
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
Abstract
The invention belongs to the field of fuel additives, and provides a marine microorganism cleaning energy-saving agent and a preparation method thereof, wherein the marine microorganism cleaning energy-saving agent comprises the following raw materials in parts by mass: 1-3 parts of marine microorganism active mother liquor, 100 parts of aviation kerosene and 10-20 parts of alkylated waste oil; the invention replaces methyl tertiary butyl ether and di tertiary butyl cresol by using the alkylation waste oil, which is a waste petroleum processing product, and can effectively utilize waste resources by taking the alkylation waste oil as one of raw materials, reduce the requirement for fresh raw materials, and contribute to environmental protection and sustainable development.
Description
Technical Field
The invention belongs to the field of fuel additives, and in particular relates to a marine microorganism cleaning energy-saving agent and a preparation method thereof.
Background
In recent years, automobiles are increasingly held due to the rapid development of the automobile industry. In the running process of the automobile, incomplete combustion of gasoline and diesel oil in the engine is easy to cause carbon deposition of the engine, the phenomenon reduces the fuel economy of the engine, the consumption of the fuel is increased continuously, the automobile is subjected to non-clean combustion, and meanwhile, the phenomenon is an important factor for increasing PM2.5 particulate pollutants and nitrogen oxides and other emissions in the urban overhead. In order to improve the combustion rate of gasoline and diesel oil and reduce the harm of automobile exhaust to the environment, people generally add gasoline and diesel oil additives into the gasoline and diesel oil to improve the combustion quality of the gasoline and diesel oil, improve the combustion efficiency of the gasoline and diesel oil, achieve the purposes of removing carbon deposit and saving fuel oil, and simultaneously reduce the emission of PM2.5 particulate matters, nitrogen oxides and other pollutants.
At present, various different types of gasoline and diesel additive chemical products exist in the market, but the functions are relatively single, some mainly improve the combustion efficiency of gasoline and diesel, and some mainly remove carbon deposition of an engine.
Therefore, it is necessary to develop a multifunctional additive which can improve the combustion efficiency of gasoline and diesel oil and remove carbon deposition of an engine, thereby reducing the emission of pollutants of an automobile and improving the utilization rate of fuel oil.
The marine microorganism clean energy-saving agent can be widely applied to various vehicles with gasoline engine as power and various vehicles with compression ignition type diesel engine as power, engineering machinery and transportation ships with engine head power for medium-speed compression ignition type ships by virtue of excellent functional characteristics.
The invention patent No. 201510392987.0 discloses a marine microorganism multifunctional fuel oil cleaning energy-saving agent and a preparation method thereof, wherein the marine microorganism multifunctional fuel oil cleaning energy-saving agent comprises the following raw materials in parts by weight: 1-3 parts of marine microorganism active mother liquor; aviation kerosene 100; 5-8 parts of methyl tertiary butyl ether; the di-tert-butyl cresol 2-6 can improve the fuel utilization rate and remove carbon deposition of an engine, thereby achieving the effects of saving energy, reducing the emission of automobile pollutants and protecting the engine.
However, the above patent uses methyl t-butyl ether and di-t-butyl cresol as raw materials, which are synthetic chemicals, increasing the production cost of the fuel cleaning and energy saving agent.
Therefore, a marine microorganism cleaning energy-saving agent and a preparation method thereof are provided by the person skilled in the art to solve the problems provided by the background art.
Disclosure of Invention
In order to solve the technical problems, the invention provides a marine microorganism cleaning energy-saving agent and a preparation method thereof, which are used for solving the problems that methyl tertiary butyl ether and di-tertiary butyl cresol are synthetic chemicals in the prior art, the production cost of the fuel cleaning energy-saving agent is increased, and the like.
The marine microorganism cleaning energy-saving agent comprises the following raw materials in parts by mass:
1-3 parts of marine microorganism active mother liquor, 100 parts of aviation kerosene and 10-20 parts of alkylated waste oil.
Preferably, the marine microorganism active mother liquor comprises the following raw materials in parts by weight:
2-6 parts of marine candida tropicalis biological enzyme, 10-15 parts of aviation kerosene, 1-3 parts of ethylene glycol monoethyl ether, 5 parts of tertiary butanol, 5 parts of a denitrogenation agent, 5 parts of glucuronide and 1 part of epoxy resin.
Preferably, the marine candida tropicalis biological enzyme comprises the following raw materials in parts by mass:
5-10 parts of gel cellulose, 3-5 parts of sodium alginate, 2-5 parts of fatty glyceride, 2-5 parts of glycol amine, 1-5 parts of propylene glycol amine and 2-6 parts of ferrous acetylacetonate.
Preferably, the use ratio of the marine microorganism cleaning energy-saving agent to the fuel oil is 1:700-1:5000.
A preparation method of a marine microorganism cleaning energy-saving agent comprises the following steps:
s1, preprocessing marine microorganism active mother liquor;
s2, mixing the marine microorganism active mother liquor, aviation kerosene and alkylated waste oil together to obtain mixed liquid;
s3, stirring the mixed liquid in the step S2 for 24 hours under magnetic shearing at 35 ℃.
Preferably, in the step S1, the method for pretreating the marine microorganism active mother liquor includes the following steps:
s11, centrifugally precipitating the microbial activity mother liquor to precipitate impurities at the bottom to obtain supernatant;
s12, adding sterile normal saline with the same volume as the supernatant for washing, and removing impurities in the centrifugal supernatant;
s13, re-suspending with normal saline to form the marine microorganism active mother liquor.
Compared with the prior art, the invention has the following beneficial effects:
1. the invention replaces methyl tertiary butyl ether and di tertiary butyl cresol by using the alkylation waste oil, which is a waste petroleum processing product, and can effectively utilize waste resources by taking the alkylation waste oil as one of raw materials, reduce the requirement for fresh raw materials, and contribute to environmental protection and sustainable development.
Drawings
FIG. 1 is a flow chart of a preparation method of the marine microorganism cleaning energy-saving agent.
Detailed Description
Embodiments of the present invention are described in further detail below with reference to the accompanying drawings and examples. The following examples are illustrative of the invention but are not intended to limit the scope of the invention.
Embodiment one: the invention provides a marine microorganism cleaning energy-saving agent, which comprises the following raw materials in parts by mass: 1-3 parts of marine microorganism active mother liquor, 100 parts of aviation kerosene and 10-20 parts of alkylated waste oil.
Wherein, the marine microorganism active mother liquor comprises the following raw materials in parts by weight: 2-6 parts of marine candida tropicalis biological enzyme, 10-15 parts of aviation kerosene, 1-3 parts of ethylene glycol monoethyl ether, 5 parts of tertiary butanol, 5 parts of a denitrogenation agent, 5 parts of glucuronide and 1 part of epoxy resin.
Wherein, the marine candida tropicalis biological enzyme comprises the following raw materials in parts by weight: 5-10 parts of gel cellulose, 3-5 parts of sodium alginate, 2-5 parts of fatty glyceride, 2-5 parts of ethylene glycol amine, 1-5 parts of propylene glycol amine, 2-6 parts of ferrous acetylacetonate, and the like, wherein the gel cellulose is used for increasing the gelation performance and viscosity, the sodium alginate is used for increasing the thickening effect, the fatty glyceride is used for improving the emulsifying performance and lubricating performance, the ethylene glycol amine is used for enhancing the stability and the oxidation resistance, and the ferrous acetylacetonate is used for providing a catalytic effect.
The marine microorganism clean energy-saving agent is mixed with fuel according to the proportion of 1:700-1:5000, so that carbon deposition of a gasoline engine can be effectively removed, the consumption of gasoline and diesel oil is reduced by about 5-10%, the pollutant emission is reduced by 80%, and the multiple purposes of saving energy, protecting environment, removing carbon deposition and protecting the engine are achieved.
By using an alkylated waste oil, which is a waste petroleum processing product, instead of methyl tertiary butyl ether and di tertiary butyl cresol, waste resources can be effectively utilized by using it as one of the raw materials, reducing the need for fresh raw materials, contributing to environmental protection and sustainable development.
Embodiment two: as shown in fig. 1: a preparation method of a marine microorganism cleaning energy-saving agent comprises the following steps:
pretreating marine microorganism active mother liquor;
mixing the marine microorganism active mother liquor, aviation kerosene and alkylated waste oil together to obtain mixed liquid;
the mixed liquid was stirred under magnetic shear at 35 ℃ for 24 hours.
Wherein, the method for preprocessing the marine microorganism active mother liquor comprises the following steps:
centrifugally precipitating the microbial active mother liquor to precipitate impurities at the bottom to obtain supernatant;
adding sterile normal saline with the same volume as the supernatant for washing, and removing impurities in the centrifugal supernatant;
resuspension is carried out by using normal saline to form microbial activity mother liquor.
The marine microorganism clean energy-saving agent prepared by the method has neutral pH value, less than or equal to 0.2 percent of sulfur content, no moisture, no mechanical impurity, no water-soluble acid-base and less than or equal to 1 corrosion of copper sheets, and is suitable for adding various fuel oils.
While embodiments of the present invention have been shown and described above for purposes of illustration and description, it will be understood that the above embodiments are illustrative and not to be construed as limiting the invention, and that variations, modifications, alternatives, and variations may be made to the above embodiments by one of ordinary skill in the art within the scope of the invention.
Claims (6)
1. The marine microorganism cleaning energy-saving agent is characterized by comprising the following raw materials in parts by mass:
1-3 parts of marine microorganism active mother liquor, 100 parts of aviation kerosene and 10-20 parts of alkylated waste oil.
2. The marine microbial cleaning energy saving agent as claimed in claim 1, wherein: the marine microorganism active mother liquor comprises the following raw materials in parts by mass:
2-6 parts of marine candida tropicalis biological enzyme, 10-15 parts of aviation kerosene, 1-3 parts of ethylene glycol monoethyl ether, 5 parts of tertiary butanol, 5 parts of a denitrogenation agent, 5 parts of glucuronide and 1 part of epoxy resin.
3. A marine microbial detergent energy saving agent as claimed in claim 2, wherein: the marine candida tropicalis biological enzyme comprises the following raw materials in parts by mass:
5-10 parts of gel cellulose, 3-5 parts of sodium alginate, 2-5 parts of fatty glyceride, 2-5 parts of glycol amine, 1-5 parts of propylene glycol amine and 2-6 parts of ferrous acetylacetonate.
4. The marine microbial cleaning energy saving agent as claimed in claim 1, wherein: the use ratio of the marine microorganism cleaning energy-saving agent to the fuel oil is 1:700-1:5000.
5. A preparation method of a marine microorganism cleaning energy-saving agent is characterized by comprising the following steps: the method comprises the following steps:
s1, preprocessing marine microorganism active mother liquor;
s2, mixing the marine microorganism active mother liquor, aviation kerosene and alkylated waste oil together to obtain mixed liquid;
s3, stirring the mixed liquid in the step S2 for 24 hours under magnetic shearing at 35 ℃.
6. The method for preparing the marine microbial cleaning energy-saving agent as claimed in claim 5, which is characterized in that:
in the step S1, the method for preprocessing the marine microorganism active mother liquor comprises the following steps:
s11, centrifugally precipitating the microbial activity mother liquor to precipitate impurities at the bottom to obtain supernatant;
s12, adding sterile normal saline with the same volume as the supernatant for washing, and removing impurities in the centrifugal supernatant;
s13, re-suspending with normal saline to form the marine microorganism active mother liquor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202410026196.5A CN117778070A (en) | 2024-01-08 | 2024-01-08 | Marine microorganism cleaning energy-saving agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202410026196.5A CN117778070A (en) | 2024-01-08 | 2024-01-08 | Marine microorganism cleaning energy-saving agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN117778070A true CN117778070A (en) | 2024-03-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202410026196.5A Pending CN117778070A (en) | 2024-01-08 | 2024-01-08 | Marine microorganism cleaning energy-saving agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN117778070A (en) |
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- 2024-01-08 CN CN202410026196.5A patent/CN117778070A/en active Pending
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