CN112845658B - Preparation method of UNS N08825 small-caliber precise seamless tube - Google Patents
Preparation method of UNS N08825 small-caliber precise seamless tube Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
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- B21C37/06—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
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Abstract
The invention discloses a preparation method of a UNS N08825 small-caliber precise seamless tube, belonging to the technical field of metal tube processing. The method comprises the following steps: circular forging stock UNS N08825 → blank processing → blank preheating → blank primary induction heating → blank hot reaming → blank secondary induction heating → pierced billet hot extrusion → solution annealing → finishing → 2-5 passes of cold rolling/cold drawing → small-caliber precision seamless pipe finished product physical and chemical inspection, and each index meets the 6-grade or finer grain size of the technical standard and special requirement of ASTM SB423 and GB/T30059-2013. The invention adopts a cold-drawing forming process, solves the problem of wall increasing by empty drawing according to the finished specification of the small-caliber precise seamless tube, the elongation of UNS N08825 material and the principle that the volume of the tube is not changed before and after deformation, and ensures that the wall thickness of the finished tube meets the design wall thickness.
Description
Technical Field
The invention belongs to the technical field of metal pipe processing, and particularly relates to a preparation method of a UNS N08825 small-caliber precise seamless pipe.
Background
UNS N08825 is a nickel-iron-chromium solid solution strengthening type corrosion-resistant alloy containing molybdenum, copper and titanium, has good pitting corrosion resistance, crevice corrosion resistance and chloride ion stress corrosion cracking resistance, can be used in oxidative environments (such as nitric acid, nitrate and the like) and reductive environments (such as sulfuric acid, phosphoric acid and the like), and is mainly applied to industrial equipment as a pipe.
At present, researches on manufacturing technologies of UNS N08825 seamless pipes are more related to two units of Long Steel company of Steel group and Wujin stainless Steel Limited company of Jiangsu, and specifically, the research on thermal piercing process of UNS N08825 alloy pipes is published in the journal of Special Steel technology of Deng Xingji, a piercing temperature interval and defect control are researched, and researches on small-size precise seamless pipes are not carried out. Wu Yougong has published a paper entitled "research and development of domestic NS1402(UNS N08825) alloy pipe" in journal of iron and steel research bulletin, and hot extrusion and multi-pass cold rolling process are adopted to manufacture seamless pipe with phi 19 x 2mm specification, and the outer diameter is larger than phi 15 mm. Chenjie published in the journal of Special Steel technology entitled "investigation on intergranular corrosion of UNS N08825 pipe finished products", carried out corrosion performance research on UNS N08825 alloy, and related to a minimum specification of phi 19 multiplied by 2mm, did not introduce a forming process of seamless pipes and an outer diameter of more than phi 15 mm. The research and development of the alloy pipe for the large-caliber thick-wall UNS N08825 petrochemical hydrogenation device is published in the journal of modern metallurgy by the highly-rainbow, and the large-caliber thick-wall pipe is developed by adopting a forming method combining oblique rolling perforation and cold rolling/cold drawing, and the specification with the outer diameter of less than phi 15mm is not involved. Generally, the smaller the outer diameter, the more difficult the deformation process, dimensional tolerance and physical and chemical property control.
Regarding the manufacture of UNS N08825, chemical compositions (Table 1), heat treatment temperature range (rapid water cooling after annealing at 960-1070 ℃), stretching performance range value, size and surface technical requirements of UNS N08825 seamless tubes are proposed in American standard ASTM SB423 and national standard GB/T30059-.
TABLE 1 main chemical composition
TABLE 2 tensile Properties
Disclosure of Invention
In order to overcome the problems in the prior art, the invention aims to provide a preparation method of UNS N08825 small-caliber precise seamless tube. By adopting the method, the UNS N08825 small-caliber precise seamless pipe with the diameter of 10-15 mm can be prepared.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
the technical route of the invention is as follows: circular forging stock UNS N08825 → blank processing → blank preheating → blank primary induction heating → blank hot reaming → blank secondary induction heating → pierced billet hot extrusion → solution annealing → finishing (straightening, flat end and acid pickling) → 3-5 cold rolling/cold drawing (degreasing and deoiling after each cold rolling/cold drawing) → 6-grade or finer grain size of the small-diameter precision seamless pipe finished product, all indexes of which meet the technical standards and special requirements of ASTM SB423 and GB/T30059-2013.
A preparation method of UNS N08825 small-caliber precise seamless tube comprises the following steps:
Further, a round billet UNS N08825 was cut into short pieces to a predetermined length and processed into a designed billet shape. The UNS N08825 round billet can be forged from a square billet by using a universal radial forging machine, and the forging ratio is not less than 4; cutting short sections from the forged blank according to a specified fixed length by using a band saw machine, and then processing a designed blank shape by adopting a deep hole drill and a lathe, wherein the outer diameter of the tube blank is phi 219-phi 277mm, and the deep hole is phi 40-60 mm.
Still further, the blank preheating of step 2 is to preheat the processed blank to 1000 ℃ ± 10 ℃ by using an annular gas furnace.
Further, the blank in the step 3 is subjected to primary induction heating, specifically, the preheated blank is heated to 1180 ℃ +/-10 ℃ in a vertical induction heating mode.
Further, the blank hot reaming in the step 4 is to ream the blank inner hole after the primary induction heating from the deep hole size to the inner hole size required by the hot extrusion by using a vertical reaming model, wherein the reaming cone used for reaming is phi 80-120 mm.
Further, the blank in the step 5 is subjected to secondary induction heating, specifically, the blank after hot hole expansion is quickly subjected to heat compensation to 1210 +/-10 ℃ by adopting an induction heating mode.
Further, the pierced billet hot extrusion in the step 6 is to adopt a horizontal extrusion model to hot extrude the tube blank after the secondary induction heating into a seamless tube with phi 57 mm-phi 168 mm; the outside diameter and inside diameter of the extruded tube during extrusion have shrinkage coefficients of 1.025 and 1.02, respectively, and the extrusion ratio is not more than 40.
Further, the solution annealing and finishing of step 7, wherein the finishing comprises straightening, flatting and pickling processes.
Further, the cold rolling treatment in the step 8 is specifically a pilger cold rolling mode, the diameter and the wall of the finished seamless pipe are reduced to phi 14-phi 22mm through 3-5 times of cold rolling, and degreasing are performed after each time of cold rolling, and then bright annealing is performed; the deformation ratio of the last pass of rolling, namely the ratio of the sectional areas before and after rolling is not less than 2, and the specification of the seamless tube formed by the last pass of cold rolling is calculated according to the specification of the finished seamless tube and the principle that the volume of the tube is not changed before and after deformation; the annealing target temperature of the seamless tube semi-finished product in the bright annealing is 1040 +/-10 ℃, and the annealing target temperature of the seamless tube finished product is 980 +/-10 ℃.
Further, the cold-drawing forming in the step 9 is to adopt a cold-drawing model, to make a small-caliber precise seamless pipe with phi 10mm to phi 15mm by cold-drawing for one time, and to perform degreasing and bright annealing after cold-drawing; the target temperature for annealing the seamless tube finished product in the bright annealing is 980 +/-10 ℃.
Compared with the prior art, the invention has the following beneficial effects:
1. the invention adopts a manufacturing method combining hot extrusion, annealing, acid pickling and cold rolling to manufacture UNS N08825 round solid blank into a small-caliber precise seamless tube, meets the technical standards of ASTM SB423 and GB/T30059-.
2. The invention adopts a method of combining hot extrusion and cold pilger rolling to manufacture a seamless tube which is made of UNS N08825 and has the diameter of phi 19 mm-phi 25 mm; and then the cold-drawing forming process is adopted to realize the manufacture of the small-caliber precise seamless pipe with the diameter of phi 10mm to phi 15 mm.
3. The invention adopts a cold-drawing forming process, solves the problem of wall increasing by empty drawing according to the finished specification of the small-caliber precise seamless tube, the elongation of UNS N08825 material and the principle that the volume of the tube is not changed before and after deformation, and ensures that the wall thickness of the finished tube meets the design wall thickness.
Drawings
FIG. 1 is a schematic structural diagram of a blank after the blank is processed in step 1 of the invention;
FIG. 2 is a schematic view of a vertical induction heating structure in the primary induction heating of the blank in step 3 of the present invention;
FIG. 3 is a schematic structural view of a vertical reaming model in step 4 blank hot reaming according to the invention;
FIG. 4 is a schematic structural diagram of a horizontal type extrusion model in the hot extrusion of the pierced billet in step 6 of the invention;
FIG. 5 is a schematic view showing the structure of a cold rolling model in the step 8 cold rolling process of the present invention.
FIG. 6 is a schematic structural diagram of a cold-drawn mold in the step 9 cold-drawing molding of the present invention.
Wherein, 1-blank, 2-coil, 3-reaming cone, 4-reaming cylinder, 5-glass powder, 6-shearing ring, 7-shearing ring seat, 8-extruding cylinder, 9-extruding rod, 10-extruding pad, 11-extruding die system, 12-seamless tube, 13-extruding needle, 14-glass pad, 15-roller, 16-conical core rod, 17-external die, 18-clamping plate and 19-welding drawing head.
Detailed Description
The technical scheme of the invention is further explained by combining the drawings and the specific embodiments. It should be understood by those skilled in the art that the specific embodiments described are merely to assist in understanding the invention and should not be construed as specifically limiting the invention.
Example 1
As shown in fig. 1 to 6, UNS N08825 small-caliber precision seamless tube (Φ 13.7 × 1.2mm) was prepared by the method of the present invention, comprising the steps of:
step 1.1 stock inspection
(1) The outer diameter phi 219 (-2-0) mm;
(2) the surface is not allowed to have obvious defects which can be seen by naked eyes, such as pits, grooves, cracks, scabs, black skin, steps, loose centers and the like.
Step 1.2 blank processing
(1) Cutting slope: the end face cutting slope is less than or equal to 2 mm;
(2) deep hole: phi is 40mm, no step is allowed, and the concentricity of the drill hole is less than or equal to 0.3 mm;
(3) a bell mouth: the diameter phi is 90mm, and the cone angle is 33.5 degrees;
(4) arc angle: r35 mm;
(5) machining surface roughness: r is less than or equal to 1.6 mu m;
(6) cleanliness: the inner surface and the outer surface are not allowed to have obvious visible impurities such as oil stains and the like.
TABLE 3 preheating process of annular furnace
Glass lubrication: the outer surface of the blank is lubricated by adopting W8 model glass powder, the inner surface of the blank is lubricated by adopting N26 model glass powder, and a D19 model glass pad is arranged between the extrusion die and the extrusion blank.
And (3) extruding a needle: phi 76.5 (considering the pipe inner diameter shrinkage factor is 1.02)
Extruding a rod: outside diameter phi 225/inside diameter phi 100 (load class 38MN)
Extrusion ratio: 19
Extrusion speed: 100 to 150mm/s
Extrusion force: burst force 35MN
And (3) cooling: and cooling the extruded product with water.
Inspecting an extruded tube:
(1) the tolerance of the outer diameter is +/-0.8 mm, and the tolerance of the wall thickness is +/-0.7 mm;
(2) the surface should have no defects such as cracks, scars, scratches, etc.
in order to improve the plasticity of the extruded tube, the extruded seamless tube 12 is subjected to solution annealing at the annealing temperature of 1120 ℃ in a rapid water cooling mode. Wherein the finishing comprises straightening, flatting and pickling processes.
The cold rolled phi 19 multiplied by 1.18mm is manufactured into phi 13.7 multiplied by 1.2mm by adopting a one-pass empty-drawing forming method. The wall thickness of the thin-wall seamless pipe with small caliber (less than or equal to phi 25mm) after drawing forming when the ratio of the diameter to the wall thickness exceeds 10 is considered to be increased, and the specification of the final cold rolling pass is inverted to be phi 19 x 1.18mm according to the principle that the specification of the finished product is phi 13.7 x 1.2mm, the elongation of the plastic property of the material is 40 percent (the elongation of UNS N08825 after bright annealing is in the range of 30-50 percent) and the volume of the pipe before and after deformation is unchanged.
And (3) annealing the subsequent cold-rolled or cold-drawn semi-finished products in the steps 8 and 9 by adopting a bright annealing process, wherein the furnace is heated in two sections to reach the target temperature in order to ensure that the temperature of the furnace is uniformly increased and the thermal inertia is reduced. The heating temperatures and soaking times of the finished and semi-finished products are shown in tables 4 and 5.
TABLE 4 target temperature for bright annealing of semi-finished products and finished products
TABLE 5 soaking time
TABLE 6 mechanical and grain size results
As is apparent from Table 6, the mechanics of the UNS N08825 small-caliber precision seamless pipe prepared by the method is far better than the technical standards of ASTM SB423 and GB/T30059-2013, and the grain size reaches more than grade 6.
Example 2
This example uses the method of the invention to prepare UNS N08825 small-caliber precision seamless tubes (Φ 10 × 1.2mm), differing from example 1 only in that:
and step 8, in the cold rolling treatment, reducing the diameter and the wall of the finished seamless pipe to phi 19-phi 25mm through 4 times of cold rolling, wherein the cold deformation process route is as follows: extruded mother pipe Φ 89 × 7mm → cold rolled Φ 57 × 4mm → cold rolled Φ 38 × 2.5mm → cold rolled Φ 21.7 × 1.8mm → cold rolled Φ 14 × 1.15 mm.
And 9, cold-drawing forming, namely manufacturing the cold-rolled phi 14 multiplied by 1.15mm into phi 10 multiplied by 1.2mm by adopting a one-pass empty-drawing forming method.
In the cold rolling treatment in step 8 of this embodiment, the finished seamless pipe may also be subjected to diameter reduction and wall reduction to Φ 14 × 1.15mm by 5-pass cold rolling, and the prepared pipe may have a higher grain size by 5-pass cold rolling treatment. In the embodiment, 4-pass cold rolling treatment is adopted, so that the method is economical, and the prepared pipe meets the technical index requirement.
Example 3
This example uses the method of the invention to produce UNS N08825 small-caliber precision seamless tubes (Φ 15 × 2mm), differing from example 1 only in that:
the outer diameter of the tube blank in the tube blank processing in the step 1 is phi 219 (-2-0) mm; deep hole: phi 40 mm;
and step 4, the concrete parameters in the blank hot reaming are as follows: 75mm phi of a reaming cone, 75.5mm of a shearing ring, 1.02 of reaming extension coefficient and over 300 ℃ of preheating temperature of a reaming cylinder.
And (3) extruding a needle: phi 70.38 (considering the shrinkage factor of the tube inner diameter is 1.02)
Extruding a rod: outside diameter phi 225/inside diameter phi 75 (load class 38MN)
Extrusion ratio: 14.2
Extrusion speed: 100 to 150mm/s
Extrusion force: burst force 32MN
And (3) cooling: and cooling the extruded product by water.
And step 8, in the cold rolling treatment, reducing the diameter and the wall of the finished seamless pipe to phi 19-phi 25mm through 3 times of cold rolling, wherein the cold deformation process route is as follows: extruded mother pipe Φ 89 × 10mm → cold rolled Φ 57 × 6mm → cold rolled Φ 38 × 3.5mm → cold rolled Φ 21.7 × 1.83 mm.
And 9, cold-drawing forming, namely manufacturing the cold-rolled phi 21.7 multiplied by 1.83mm into phi 15 multiplied by 2mm by adopting a one-pass empty-drawing forming method.
Claims (3)
1. A preparation method of UNS N08825 small-caliber precise seamless tube is characterized by comprising the following steps:
step 1, processing a tube blank: cutting a round forging stock UNS N08825 into short sections in a fixed length mode, and processing the short sections into a designed tube blank shape;
step 2, preheating the pipe blank: preheating the processed tube blank, specifically, preheating the processed tube blank to 1000 +/-10 ℃ by using an annular gas furnace, wherein the soaking time is 1.0 h;
step 3, primary induction heating of the tube blank: specifically, the preheated pipe blank is heated to 1180 +/-10 ℃ in a vertical induction heating mode;
step 4, hot hole expansion of the tube blank: reaming the inner hole of the tube blank after the primary induction heating from the deep hole size to the inner hole size required by the hot extrusion;
step 5, secondary induction heating of the tube blank: specifically, quickly heating the hot-reamed tube blank to 1210 +/-10 ℃ in an induction heating mode;
step 6, hot extrusion of the pierced billet: carrying out seamless tube hot forming on the tube blank subjected to secondary induction heating in an extrusion mode, specifically, carrying out hot extrusion forming on the tube blank subjected to secondary induction heating into a seamless tube with phi 57 mm-phi 168mm by adopting a horizontal extrusion model; the shrinkage coefficients of the outer diameter and the inner diameter of the extrusion pipe during extrusion are respectively 1.025 and 1.02, and the extrusion ratio is not more than 40;
step 7, solution annealing and finishing: carrying out solution treatment again on the extruded seamless pipe and finishing;
step 8, cold rolling treatment: performing diameter reduction and wall reduction treatment on the finished seamless pipe in a cold rolling mode, wherein the cold rolling treatment in the step 8 is specifically to perform diameter reduction and wall reduction on the finished seamless pipe to phi 14-phi 22mm through 3-5 times of cold rolling in a pilger cold rolling mode, and degreasing and deoiling the finished seamless pipe after each time of cold rolling and then performing bright annealing; the deformation ratio of the last rolling pass, namely the ratio of the sectional areas before and after rolling is not less than 2, and the specification of the seamless tube formed by the cold rolling of the last rolling pass is calculated according to the specification of the finished seamless tube and the material elongation rate in the range of 30-50% and according to the principle that the volume of the tube is unchanged before and after deformation; the target temperature for annealing the seamless tube semi-finished product during the bright annealing is 1040 +/-10 ℃, the target temperature for annealing the seamless tube finished product is 980 +/-10 ℃, and the bright annealing heat preservation time is 5-8 minutes;
step 9, cold-drawing forming: the method comprises the following steps of (1) manufacturing a small-caliber precise seamless pipe by adopting a cold-drawing forming method for the seamless pipe after reducing the diameter and reducing the wall, specifically, manufacturing the small-caliber precise seamless pipe with phi 10 mm-phi 15mm by adopting a cold-drawing model through one-time cold drawing, and performing bright annealing after degreasing and deoiling after cold drawing; the target temperature of annealing of the seamless tube finished product in the bright annealing is 980 +/-10 ℃;
step 10, physical and chemical inspection: and performing physical and chemical inspection on the manufactured small-caliber precise seamless pipe.
2. The method for preparing UNS N08825 small-caliber precise seamless tube according to claim 1,
the step 1 of processing into a designed tube blank shape specifically adopts a deep hole drill and a lathe to process into the designed tube blank shape, the outer diameter of the tube blank is phi 219-phi 277mm, and the deep hole is phi 40-60 mm.
3. The method for preparing the UNS N08825 small-caliber precise seamless tube according to claim 1, wherein the tube blank hot reaming of the step 4 is to ream the inner hole of the tube blank after one-time induction heating from the deep hole size to the inner hole size required by hot extrusion by using a vertical reaming model, wherein the reaming cone used for reaming is phi 80-120 mm.
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