CN112835242B - Multifunctional colorful electrochromic display screen capable of detecting ambient electromagnetic radiation and its application - Google Patents

Abstract

The invention discloses a multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation and its application. The multi-color electrochromic display screen includes a display screen body, a collector unit, a detector unit, a processor unit, a multi-color electrochromic display unit with a multi-color electrochromic structure, and a digital display unit. The colorful electrochromic structure includes a working electrode, an electrolyte and a counter electrode, the working electrode includes a first optical structure layer and a second optical structure layer which are opposite to each other and are arranged in parallel, and a dielectric layer is arranged between them. The dielectric layer is composed of electrochromic materials, and the bonding interface between the dielectric layer and the first optical structure layer and the second optical structure layer is the first surface and the second surface of the dielectric layer, respectively. The first surface and the second surface The optical cavity is formed with the dielectric layer. The colorful electrochromic display screen of the present invention can realize the detection of electromagnetic radiation in the environment, display colorful color changes, and display electromagnetic radiation information to users.

Description

Multifunctional colorful electrochromic display screen capable of detecting ambient electromagnetic radiation and its application

technical field

The invention relates to a display screen, in particular to a multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation and its application, belonging to the field of optoelectronic technology.

Background technique

With the advancement and development of science and technology, the popularization of household appliances, and the rapid development of communication electronic products, it has brought great convenience to people's life style, but the accompanying electromagnetic radiation pollution is also becoming more and more serious. Electromagnetic radiation is another important source of pollution after air pollution/water pollution and noise pollution. Electromagnetic radiation is also known as electronic mist pollution/electromagnetic pollution. Because electromagnetic radiation is colorless, odorless, and invisible, it can penetrate a variety of substances including the human body. , people cannot detect this invisible pollution through the sense organs. In the past ten years, the rapid development of mobile communication has led to the popularization of communication towers. In addition, high-voltage power lines and substations are gradually approaching residential areas, including the popularity of microwave ovens, hair dryers and other household appliances in daily life. Electromagnetic radiation is gradually eroding. people's living space. Studies have shown that electromagnetic radiation exceeding a certain level and for a certain period of time will have different degrees of impact on people's lives. Therefore, scientific and intuitive measurement of electromagnetic radiation is crucial and urgent.

SUMMARY OF THE INVENTION

The main purpose of the present invention is to provide a multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation, so as to overcome the deficiencies in the prior art.

Another object of the present invention is to provide an application of the multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation, for example, in the field of ambient electromagnetic radiation detection.

In order to realize the foregoing invention purpose, the technical scheme adopted in the present invention includes:

The embodiment of the present invention provides a multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation, which includes: a display screen main body;

a collector unit, at least for collecting ambient electromagnetic radiation;

A detector unit, at least for converting electromagnetic radiation energy into chemical energy or electrical energy;

a processor unit, at least used to process the converted chemical energy or electrical energy signal to calculate the intensity of electromagnetic radiation;

A multi-color electrochromic display unit, which includes a multi-color electrochromic structure, at least used to produce discoloration under the control of the processor unit according to the change of the electrical signal transmitted by the processor unit;

A digital display unit, at least for displaying electromagnetic radiation intensity information;

d为所述介质层的厚度，

为所述介质层的折射率，λ为所述入射光的波长，

为所述入射光在透过所述第一表面或第二表面时的折射角。Wherein, the colorful electrochromic structure includes a working electrode, an electrolyte and a counter electrode, the electrolyte is distributed between the working electrode and the counter electrode, and the working electrode includes a first optical structure layer and a second optical structure layer opposite and parallel to each other Optical structure layer, the first optical structure layer and the second optical structure layer are optically reflective and/or optically transmissive, and a medium layer is arranged between the first optical structure layer and the second optical structure layer, so The dielectric layer is composed of electrochromic materials, and the bonding interface between the dielectric layer and the first optical structure layer and the second optical structure layer is the first surface and the second surface of the dielectric layer, respectively. The second surface and the dielectric layer form an optical cavity; when incident light enters the optical cavity from the first optical structure layer or the second optical structure layer, the reflected light formed on the first surface and the reflected light formed on the second surface The phase shift of the reflected light

d is the thickness of the dielectric layer,

is the refractive index of the dielectric layer, λ is the wavelength of the incident light,

is the refraction angle of the incident light when it passes through the first surface or the second surface.

In some embodiments, the dielectric layer consists essentially of an electrochromic material, such as an organic material or an inorganic material.

In some implementations, the multi-color electrochromic display unit and the digital display unit are at least partially covered on the front surface of the display screen body, and the collector unit, the detector unit and the processor unit are respectively arranged on the multi-colored electrochromic display unit and the digital display unit. Color TV electrochromic display unit.

The embodiment of the present invention also provides a device capable of detecting environmental electromagnetic radiation, and the device is provided with the aforementioned multifunctional multi-color electrochromic display screen capable of detecting environmental electromagnetic radiation.

The embodiments of the present invention also provide the application of the aforementioned multifunctional colorful electrochromic display screen or device capable of detecting ambient electromagnetic radiation in the field of ambient electromagnetic radiation detection.

The embodiment of the present invention also provides a method for detecting electromagnetic radiation, the method is mainly implemented based on the aforementioned multi-functional multi-color electrochromic display screen or device capable of detecting environmental electromagnetic radiation, and the method includes:

Connect the working electrode, the counter electrode and the power source to form a working circuit;

A collector unit is used to collect ambient electromagnetic radiation, a detector unit is used to convert the electromagnetic radiation energy into chemical energy or electrical energy, and then a processor is used to process the converted chemical energy or electrical energy signal, calculate the electromagnetic radiation intensity, and calculate the electromagnetic radiation intensity according to the processor unit. The change of the transmitted electrical signal adjusts the light transmittance of the multi-color electrochromic structure in the multi-color electrochromic display unit to make the multi-color electrochromic structure change color;

The digital display unit displays electromagnetic radiation intensity information.

Compared with the prior art, the advantages of the present invention are:

In the present invention, the front surface of the multi-color electrochromic layer display panel is arranged on the main body of the display screen, and the collector unit senses the electromagnetic radiation in the environment, and the detector unit converts the collected electromagnetic radiation energy into chemical energy or electrical energy, The processor unit processes the converted signal, calculates the electromagnetic radiation intensity, controls the colorful electrochromic display panel to change the corresponding color, controls the temperature sensor unit to sense the ambient temperature, and controls the digital display panel to display the specific electromagnetic radiation intensity Or level and ambient temperature, it can detect electromagnetic radiation in the environment and display a variety of color changes, showing users the electromagnetic radiation information of their environment, convenient and time-saving operation, can be widely used in mobile phone shells, tablet shells Body, home appliance shell, wall outer body and other occasions.

Description of drawings

FIG. 1 is a schematic front view of a multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation according to a typical embodiment of the present invention.

2 is a schematic structural diagram of a multi-color electrochromic structure in a multi-functional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation according to a typical embodiment of the present invention.

FIG. 3 is a schematic structural diagram of a working electrode of a multi-color electrochromic structure in an exemplary embodiment of the present invention.

4 is a schematic structural diagram of a multi-color electrochromic structure in a multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation according to another exemplary embodiment of the present invention.

5 is a schematic structural diagram of a multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation according to another embodiment of the present invention.

FIG. 6 is a schematic structural diagram of a novel colorful electrochromic structure in an exemplary embodiment of the present invention.

7 is a schematic diagram of a novel reflective/transmissive dual-mode multicolor electrochromic structure in an exemplary embodiment of the present invention.

FIG. 8 is a schematic structural diagram of the electrochromic working electrode in FIG. 7 .

FIG. 9 is a schematic structural diagram of a novel colorful electrochromic structure in an exemplary embodiment of the present invention.

Figure 10 is a photograph of the reflected color from the side of the first optical structure of the novel multi-colored electrochromic structure at different tungsten oxide thicknesses in an exemplary embodiment of the present invention.

Figure 11 is a photograph of the reflected color from the direction of the PET substrate of the novel multi-colored electrochromic structure at different tungsten oxide thicknesses in an exemplary embodiment of the present invention.

Figure 12 is a photograph of the transmission color of the novel multi-colored electrochromic structures at different tungsten oxide thicknesses in an exemplary embodiment of the present invention.

13 is a schematic structural diagram of a novel multi-colored electrochromic structure in an exemplary embodiment of the present invention.

Figure 14 is a photograph of the reflected color from the side of the first optical structure of the novel multi-colored electrochromic structure at different tungsten oxide thicknesses in an exemplary embodiment of the present invention.

Figure 15 is a photograph of the reflected color from the direction of the PET substrate for the novel multi-colored electrochromic structure at various tungsten oxide thicknesses in an exemplary embodiment of the present invention.

Figure 16 is a photograph of the transmission color of the novel multi-colored electrochromic structures at various tungsten oxide thicknesses in an exemplary embodiment of the present invention.

FIG. 17 is a schematic structural diagram of a working electrode of a novel reflection/transmission dual-mode multi-color electrochromic device in an exemplary embodiment of the present invention.

Figure 18 is a photograph of the working electrodes (taken from the first optical structure and the sides of the substrate) at different voltages in a multi-color electrochromic device with different tungsten oxide thicknesses according to an exemplary embodiment of the present invention.

Detailed ways

In view of the many defects of the prior art, the inventor of the present application has been able to propose the technical solution of the present invention after long-term research and extensive practice. The technical solution, its implementation process and principle will be further explained as follows. However, it should be understood that within the scope of the present invention, the above-mentioned technical features of the present invention and the technical features specifically described in the following (embodiments) can be combined with each other to form new or preferred technical solutions. Due to space limitations, they will not be repeated here.

In order to explain the embodiments of the present invention or the technical solutions in the prior art more clearly, the following briefly introduces the accompanying drawings that need to be used in the description of the embodiments or the prior art. Obviously, the accompanying drawings in the following description are only These are some embodiments described in the present invention, but not all examples. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work fall within the protection scope of the present invention. The implementation conditions adopted in the following examples can be further adjusted according to actual needs, and the unremarked implementation conditions are usually the conditions in routine experiments.

Also, it should be noted that in this specification, relational terms such as first and second, etc. are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply these There is no such actual relationship or sequence between entities or operations. Moreover, the terms "comprising", "comprising" or any other variation thereof are intended to encompass a non-exclusive inclusion such that a process, method, article or device that includes a list of elements includes not only those elements, but also includes not explicitly listed or other elements inherent to such a process, method, article or apparatus. Without further limitation, an element qualified by the phrase "comprising a..." does not preclude the presence of additional identical elements in a process, method, article or apparatus that includes the element.

An aspect of the embodiments of the present invention provides a multifunctional multi-colored electrochromic display screen capable of detecting ambient electromagnetic radiation, comprising:

Display main body;

a collector unit, at least for collecting ambient electromagnetic radiation;

A detector unit, at least for converting electromagnetic radiation energy into chemical energy or electrical energy;

a processor unit, at least used to process the converted chemical energy or electrical energy signal to calculate the intensity of electromagnetic radiation;

A multi-color electrochromic display unit, which includes a multi-color electrochromic structure, at least used to produce discoloration under the control of the processor unit according to the change of the electrical signal transmitted by the processor unit;

A digital display unit, at least for displaying electromagnetic radiation intensity information;

d为所述介质层的厚度，

为所述介质层的折射率，λ为所述入射光的波长，

为所述入射光在透过所述第一表面或第二表面时的折射角。Wherein, the colorful electrochromic structure includes a working electrode, an electrolyte and a counter electrode, the electrolyte is distributed between the working electrode and the counter electrode, and the working electrode includes a first optical structure layer and a second optical structure layer opposite and parallel to each other Optical structure layer, the first optical structure layer and the second optical structure layer are optically reflective and/or optically transmissive, and a medium layer is arranged between the first optical structure layer and the second optical structure layer, so The dielectric layer is composed of electrochromic materials, and the bonding interface between the dielectric layer and the first optical structure layer and the second optical structure layer is the first surface and the second surface of the dielectric layer, respectively. The second surface and the dielectric layer form an optical cavity; when incident light enters the optical cavity from the first optical structure layer or the second optical structure layer, the reflected light formed on the first surface and the reflected light formed on the second surface The phase shift of the reflected light

d is the thickness of the dielectric layer,

is the refractive index of the dielectric layer, λ is the wavelength of the incident light,

is the refraction angle of the incident light when it passes through the first surface or the second surface.

Further, for the working electrode, the reflection light formed on the first surface by the incident light incident from the first optical structure layer and the reflection formed on the second surface by the incident light passing through the dielectric layer Light interference superposition. Vice versa, that is, the reflected light formed on the second surface by the incident light incident from the second optical structure layer interferes with the reflected light formed on the first surface by the incident light transmitted through the dielectric layer.

d为所述介质层的厚度，

为所述介质层的折射率，λ为所述入射光的波长，

为所述入射光在透过所述第一表面或第二表面时的折射角。Further, when incident light enters the optical cavity from the first optical structure layer or the second optical structure layer, the phase shift of the reflected light formed on the first surface and the reflected light formed on the second surface

d is the thickness of the dielectric layer,

is the refractive index of the dielectric layer, λ is the wavelength of the incident light,

is the refraction angle of the incident light when it passes through the first surface or the second surface.

则所述第一表面的反射系数

其中

为入射光于第一表面的入射角。In some embodiments, if the refractive index of the first optical structure layer is defined as

Then the reflection coefficient of the first surface

in

is the incident angle of the incident light on the first surface.

则所述第二表面的反射系数

其中

为入射光在透过第二表面时的折射角。In some implementations, if the refractive index of the second optical structure layer is defined as

Then the reflection coefficient of the second surface

in

is the refraction angle of the incident light when it passes through the second surface.

反射率表示为：

In some embodiments, the reflection coefficient of the working electrode is expressed as:

The reflectance is expressed as:

Further, the reflection coefficient and reflectivity of the working electrode are also applicable to the case where the incident light enters the optical cavity from the second optical structure layer.

则所述第一光学结构层的透射系数

其中

为入射光于第一表面的入射角。In some embodiments, if the refractive index of the first optical structure layer is defined as

Then the transmission coefficient of the first optical structure layer

in

is the incident angle of the incident light on the first surface.

则所述第二光学结构层的透射系数

其中

为入射光在透过第二表面时的折射角。In some implementations, if the refractive index of the second optical structure layer is defined as

Then the transmission coefficient of the second optical structure layer

in

is the refraction angle of the incident light when it passes through the second surface.

透过率表示为：

In some embodiments, the transmittance of the working electrode is expressed as:

The transmittance is expressed as:

Further, the transmittance and transmittance of the working electrode are also applicable to the case where the incident light enters the optical cavity from the second optical structure layer.

Further, the working electrode has an optical transmission working mode, an optical reflection working mode or an optical transmission and reflection working mode.

Wherein, in the optical reflection working mode, the working electrode has a double-sided asymmetric structural color.

Wherein, in the optical transmission working mode, the working electrode has a transparent structural color.

In some embodiments, the working electrode includes one or more layers of a first optical structure, one or more layers of a dielectric, and one or more layers of a second optical structure.

In some embodiments, the working electrode includes a plurality of first optical structure layers and/or a plurality of second optical structure layers and a plurality of dielectric layers.

In some implementations, the material of at least one of the first optical structure layer and the second optical structure layer includes a metal material.

In some embodiments, the first optical structure layer or the second optical structure layer is a metal layer.

In some embodiments, the first optical structure layer and the second optical structure layer are both metal layers.

In some embodiments, the first optical structure layer or the second optical structure layer is directly air.

In some embodiments, the first optical structure layer or the second optical structure layer is absent.

Further, the metal material includes tungsten, gold, silver, copper, titanium, aluminum, chromium, iron, cobalt, nickel, platinum, germanium, palladium, etc., but is not limited thereto.

Further, the thickness of the first optical structure layer or the second optical structure layer is preferably 0-2000 nm.

In some embodiments, the dielectric layer is mainly composed of electrochromic materials, and the material of the dielectric layer is selected from organic materials or inorganic materials.

Further, the metal layer and the dielectric layer constitute a metal-dielectric structure, which can produce optical interference to display multiple colors, and requires a color that is not affected by the thickness of the ion conductive layer. The different colors of the unit can be realized by selecting one or more combinations of different metal materials, different dielectric materials or different dielectric layer thicknesses.

Further, the inorganic material includes, but is not limited to, a combination of any one or more of simple metals or non-metals, inorganic salts, oxides, and the like.

Further, the non-metal element includes any one or a combination of single crystal silicon, polycrystalline silicon, and diamond, but is not limited thereto.

Further, the inorganic salt includes, but is not limited to, a combination of any one or more of fluoride, sulfide, selenide, chloride, bromide, iodide, arsenide or telluride.

Further, the oxides include WO ₃ , NiO, TiO ₂ , Nb ₂ O ₅ , Fe ₂ O ₃ , V ₂ O ₅ , Co ₂ O ₃ , Y ₂ O ₃ , Cr ₂ O ₃ , MoO ₃ , Al ₂ O ₃ , SiO ₂ , MgO, ZnO, MnO ₂ , CaO, ZrO ₂ , Ta ₂ O ₅ , Y ₃ Al ₅ O ₁₂ , Er ₂ O ₃ , IrO ₂ , etc. any one or a combination, but Not limited to this.

Further, the fluoride includes any one of MgF ₂ , CaF ₂ , GeF ₂ , YbF ₃ , YF ₃ , Na ₃ AlF ₆ , AlF ₃ , NdF ₃ , LaF ₃ , LiF , NaF , BaF ₂ , SrF ₂ , etc. One or more combinations, but not limited to this.

Further, the sulfide includes, but is not limited to, a combination of any one or more of ZnS, GeS, MoS ₂ , Bi ₂ S ₃ and the like.

Further, the selenide includes, but is not limited to, a combination of any one or more of ZnSe, GeSe, MoSe ₂ , PbSe, Ag ₂ Se and the like.

Further, the chloride includes any one or a combination of AgCl, NaCl, KCl, etc., but is not limited thereto.

Further, the bromide includes, but is not limited to, a combination of any one or more of AgBr, NaBr, KBr, TlBr, CsBr, and the like.

Further, the iodide includes any one or a combination of AgI, NaI, KI, RbI, CsI, etc., but is not limited thereto.

Further, the arsenide includes GaAs and the like, but is not limited thereto.

Further, the antimonide compound includes GdTe and the like, but is not limited thereto.

Further, the material of the dielectric layer includes SrTiO ₃ , Ba ₃ Ta ₄ O ₁₅ , Bi ₄ Ti ₃ O ₂ , CaCO ₃ , CaWO ₄ , CaMnO ₄ , LiNbO ₄ , Prussian blue, Prussian black, Prussian white, and Prussian green A combination of any one or more of the above, but not limited thereto.

Further, the material of the dielectric layer includes liquid crystal material or MOF material, but is not limited thereto.

Further, the organic material includes, but is not limited to, organic small molecule compounds, polymers, and the like.

Further, the organic materials include viologen, tetrathiafulvalene, polypyrrole, polyaniline, polythiophene, polycarbazole, phthalocyanine, terephthalate, dimethylbenzidine, tetrathief A combination of any one or more of alkenes, alkyl bipyridines, phenothiazoles, polyamides, epoxy resins, polydiynes, etc., but not limited thereto.

In some embodiments, the dielectric layer may consist essentially of an electrochromic material. The dielectric layer is the core layer of the working electrode, and also the generation layer of the color changing reaction. The material of the dielectric layer can be selected from inorganic electrochromic materials and/or organic electrochromic materials according to the type.

Further, the electrochromic material can be selected from inorganic, organic materials, liquid crystal materials, MOF materials, and the like. For example, the inorganic material may include tungsten trioxide (WO ₃ ), nickel oxide (NiO), TiO ₂ , Nb ₂ O ₅ , Fe ₂ O ₃ , V ₂ O ₅ , Co ₂ O ₃ , Y ₂ O ₃ , MoO ₃ , IrO ₂ , Prussian blue, Prussian black, Prussian white, Prussian green, etc., without limitation. The organic materials may include viologen compounds, polypyrrole, polyaniline, polythiophene compounds and their derivatives, polycarbazole, metal phthalocyanine compounds, terephthalate, dimethylbenzidine, Tetrathiafulvalene, alkyl bipyridine, phenothiazole, polydiyne, etc., but not limited thereto.

In some embodiments, the thickness of the dielectric layer is greater than 0 and less than or equal to 2000 nm, preferably 0.001-2000 nm, more preferably 50-2000 nm, more preferably 100-500 nm, so that the colorful electrochromic structure The color saturation is higher.

Further, an optimized dielectric layer can also be added between the first optical structure layer or the second optical structure layer and the dielectric layer to optimize the color of the electrochromic layer.

Further, an optimized medium layer can also be added on the first optical structure layer or the second optical structure layer, or, the first optical structure layer or the second optical structure layer can also be arranged on the optimized medium layer, to optimize the color of the electrochromic layer.

In some embodiments, the first optical structure layer or the second optical structure layer is bonded to the substrate.

Further, the substrate is transparent or translucent. Correspondingly, the material of the substrate can be transparent or translucent, for example, it can be selected from any one or a combination of glass, plexiglass, PET, PES, PEN, PC, PMMA, PDMS, etc., but not limited to this.

Further, the aforementioned optimized medium layer may be disposed between the first optical structure layer or the second optical structure layer and the substrate.

Further, the material of the optimized dielectric layer includes but is not limited to WO ₃ , NiO, TiO ₂ , Nb ₂ O ₅ , Fe ₂ O ₃ , V ₂ O ₅ , Co ₂ O ₃ , Y ₂ O ₃ , Cr ₂ O ₃ , MoO ₃ , Al ₂ O ₃ , SiO ₂ , MgO, ZnO, MnO ₂ , CaO, ZrO ₂ , Ta ₂ O ₅ , Y ₃ Al ₅ O ₁₂ , Er ₂ O ₃ , ZnS, MgF ₂ , SiN _x ( silicon nitride), etc., but not limited thereto.

Further, the thickness of the optimized dielectric layer is preferably 0-2000 nm, preferably 100-500 nm, so that the color saturation of the electrochromic structure is higher.

In a more typical embodiment, as shown in FIG. 6 , the multi-color electrochromic structure includes a second optical structure layer 2 , a dielectric layer 3 and a first optical structure layer 4 disposed on the substrate 1 . The first optical structure layer 4 and the second optical structure layer 2 are reflective/transmissive layers, which may be made of metal material.

Wherein, the first optical structure layer 4 can also be directly made of air.

Wherein, the second optical structure layer 2 may also not exist.

In this typical embodiment, the materials and thicknesses of the first optical structure layer, the second optical structure layer, and the dielectric layer can be as described above. Moreover, by adjusting the material and thickness of the first optical structure layer 4, the second optical structure layer 2, and the dielectric layer 3, etc., the reflection/transmission structure color, reflectivity and transmittance of the working electrode can be changed.

Another aspect of the embodiments of the present invention also provides a method for preparing the working electrode, which may include:

The first layer is formed by physical or chemical deposition methods, such as coating, printing, film casting, etc., or magnetron sputtering, electron beam evaporation, thermal evaporation, electrochemical deposition, chemical vapor deposition, atomic force deposition, sol-gel technology, etc. An optical structure layer or a second optical structure layer, a dielectric layer, etc., but not limited thereto.

In some embodiments, the first optical or second optical structure layer, the dielectric layer may be sequentially formed on the substrate.

Further, electrochromic devices made of electrochromic materials have been widely used in smart windows, smart indicators, imaging devices, and the like. The principle of electrochromism is a phenomenon in which the electronic structure and optical properties (reflectivity, transmittance, absorptivity, etc.) of inorganic or organic electrochromic materials undergo stable and reversible changes under the action of an external electric field or current. It appears to be a reversible change in color and transparency. Traditional electrochromism can be divided into two models, transmissive electrochromic devices and reflective electrochromic devices, and the color of electrochromic devices is only determined by the electronic structure and optical properties of the electrochromic itself. Therefore, the single mode and monotonic color modulation of electrochromism also become a bottleneck limiting its application range.

In some embodiments, the first optical structure layer or the second optical structure layer, the thickness and/or material of the dielectric layer, etc. may be adjusted during the preparation method, so as to adjust the reflection of the working electrode /Transmissive structural color.

Further, in the foregoing embodiments of the present invention, the type of the electrolyte is not particularly limited, and a liquid electrolyte, a gel polymer electrolyte, or an inorganic solid electrolyte may be used. In some embodiments, the electrolyte is in contact with the dielectric layer and provides a material for a mobile environment for ions, such as hydrogen ions or lithium ions, to discolor or decolorize the electrochromic material.

In some embodiments, the type of the electrolyte is not particularly limited, and the electrolyte may include one or more compounds such as H ⁺ , Li ⁺ , Al ³⁺ , Na ⁺ , K ⁺ , Rb ⁺ , Ca ²⁺ , a compound of Zn ²⁺ , Mg ²⁺ or Cs ⁺ . The electrolyte layer is composed of a special conductive material, such as a liquid electrolyte material containing a solution of lithium perchlorate, sodium perchlorate, etc., or a solid electrolyte or gel electrolyte material. In one embodiment, the electrolyte layer may contain a lithium salt compound such as LiClO ₄ , LiBF ₄ , LiAsF ₆ or LiPF ₆ . The ions contained in the electrolyte can contribute to the color change or light transmittance change of the colorful electrochromic structure when inserted into or removed from the dielectric layer according to the polarity of the applied voltage. In some embodiments, the electrolyte employed comprises a mixture of ions that can enrich the color change of the electrochromic structure compared to a single ion.

In some embodiments, the electrolyte may be a liquid electrolyte, such as aqueous LiCl, AlCl ₃ , HCl, H ₂ SO ₄ aqueous solution, and the like.

In some embodiments, the electrolyte may also include a carbonate compound. Since the carbonate-based compound has a high dielectric constant, the ionic conductivity provided by the lithium salt can be increased. As the carbonate-based compound, at least one of the following can be used: PC (propylene carbonate), EC (ethylene carbonate), DMC (dimethyl carbonate), DEC (diethyl carbonate), and EMC (carbonic acid) ethyl methyl ester). For example, an organic-based LiClO ₄ or Na(ClO ₄ ) ₃ propylene carbonate electrolyte solution or the like can be used.

In some embodiments, the electrolyte may be a gel electrolyte, such as PMMA-PEG-LiClO ₄ , PVDF-PC-LiPF ₆ , LiCl/PVA, H ₂ SO ₄ /PVA, etc., but not limited thereto.

In some preferred embodiments, when an inorganic solid electrolyte is used as the electrolyte, the electrolyte may comprise LiPON or Ta ₂ O ₅ . For example, the electrolyte may be, but is not limited to, a Li-containing metal oxide thin film, such as LiTaO or LiPO or the like. In addition, the inorganic solid electrolyte may be an electrolyte in which LiPON or Ta ₂ O ₅ is added with components such as B, S, and W, for example, may be LiBO ₂ +Li ₂ SO ₄ , LiAlF ₄ , LiNbO ₃ , Li ₂ OB ₂ O ₃ etc.

In some preferred embodiments, the electrolyte adopts an all-solid-state electrolyte, which can be combined with a solid-state dielectric layer, a metal reflective layer, a counter electrode, etc. to form an all-solid-state electrochromic structure.

Further, the colorful electrochromic structure further includes an ion conductive layer, an ion storage layer, a transparent conductive layer, and the like.

Further, the ion storage layer is in contact with the electrolyte.

For example, the working electrode may comprise a substrate.

For example, the counter electrode may include a substrate, a transparent conductive layer, and an ion storage layer.

The material of the substrate can be as described above, which will not be repeated here.

Further, the material of the ion storage layer can be selected from, but not limited to, NiO, Fe ₂ O ₃ , TiO ₂ , Prussian blue, IrO ₂ and the like. The ion storage layer plays the role of storing charges in the working electrode, that is, storing corresponding counter ions when the dielectric layer material undergoes a redox reaction, thereby ensuring the charge balance of the entire electrochromic layer.

In some specific embodiments, the all-solid-state electrolyte in the aforementioned all-solid-state multi-color electrochromic structure may be in the form of a solid-state ion conductive layer. The discoloration principle of this all-solid-state colorful electrochromic structure is as follows: the metal reflective layer and other layer materials form a metal-dielectric structure, which can produce optical interference to display multiple colors. It can also include other layers, such as ion conductive layer, ion storage layer and transparent conductive layer, etc. By adjusting the thickness of each layer material to an appropriate range, an electrochromic device with structural color can be prepared. Further, by applying The voltage can adjust the refractive index of the electrochromic material, and can further adjust the color of the all-solid-state colorful electrochromic device.

In some embodiments, the substrate is further provided with a conductive layer. Wherein, the conductive layer includes any one or a combination of FTO, ITO, Ag nanowires, Ag nanogrids, carbon nanotubes, and graphene, or may be a metal layer, Cu, W, etc., and not limited to this.

When a certain voltage is formed between the two transparent conductive layers, the material of the dielectric layer undergoes a redox reaction under the action of the voltage, thereby changing the color. This color change is a structural color change and will remain after the voltage is removed.

In some embodiments, the counter electrode comprises a transparent conductive electrode or a translucent conductive electrode.

In some embodiments, the counter electrode includes a transparent conductive electrode with an ion storage layer, the material of which can be selected from, but not limited to, NiO, Fe ₂ O ₃ , TiO ₂ and the like. The ion storage layer is in contact with the electrolyte. In the aforementioned embodiments of the present invention, the transparent conductive electrode may be formed by including a material with high light transmittance, low sheet resistance, etc., for example, may be formed by including any one of the following: selected from ITO (Indium Tin oxide), FTO (fluorine doped tin oxide), AZO (aluminum doped zinc oxide), GZO (gallium doped zinc oxide), ATO (antimony doped tin oxide), IZO ( Transparent conductive oxides of indium-doped zinc oxide), NTO (niobium-doped titanium oxide), ZnO, OMO (oxide/metal/oxide), and CTO; silver (Ag) nanowires; metal meshes; or OMO (Oxide Metal Oxide).

The method of forming the transparent conductive electrode is not particularly limited, and any known method can be used without limitation. For example, a thin film electrode layer comprising transparent conductive oxide particles can be formed on the glass base layer by methods such as sputtering or printing (screen printing, gravure printing, ink jet printing, etc.). In the case of the vacuum method, the thickness of the electrode layer thus prepared may be in the range of 10 nm to 500 nm, and in the case of the printing method, the thickness may be in the range of 0.1 μm to 20 μm. In one example, the visible light transmittance of the transparent conductive electrode layer may be 70% to 95%.

In some embodiments, a metal material layer, especially a thin layer of metal, can also be added on the dielectric layer to optimize the color of the colorful electrochromic structure. Specifically, for some materials or colorful electrochromic structures with a suitable thickness, adding a metal material with a suitable thickness can increase the intensity difference of the reflectivity curve, thereby improving the color saturation. Wherein, the metal may be selected from Ag, Al, Cu, Ni, etc., but is not limited thereto. The thickness of the metal layer may preferably be 0 to 30 nm, particularly preferably 1 to 10 nm.

In some embodiments, a semiconductor material can also be added on the dielectric layer to optimize the color of the multi-colored electrochromic structure. For some specific materials or colorful thin films of thickness, adding semiconductor materials of appropriate thickness can increase the intensity difference of the reflectivity curve, thereby improving the color saturation. Wherein, the semiconductor may be selected from Al ₂ O ₃ , SiO ₂ , ZnS, MgF ₂ , silicon nitride, etc., but is not limited thereto. The thickness of the semiconductor may preferably be 0 to 300 nm, particularly preferably 1 to 100 nm. Please refer to FIG. 4, which shows a multi-color electrochromic structure in a typical embodiment of the present invention, which includes a substrate, a metal layer, an electrochromic layer, an ion conductive layer, an ion storage layer and a transparent conductive layer. The photochromic structure is electrically coupled and connected to the voltage control circuit. The color of the colorful electrochromic structure is changed by adjusting the light transmittance of the colorful electrochromic structure.

Wherein, referring to the foregoing content, the metal layer and the dielectric layer (ie, the electrochromic layer, or called the working electrode) constitute a metal-dielectric structure, which can produce optical interference to display multicolor; the electrochromic layer Different colors of the layers can be achieved by selecting different metal materials, different dielectric materials or different dielectric layer thicknesses in one or more combinations.

The multi-color electrochromic structure provided by the foregoing embodiments of the present invention is a multi-color pattern obtained by the optical interference effect of a metal medium. Compared with the existing inorganic material electrochromic technology, it has the characteristics of various colors and a wide range of choices.

By adopting the above technical solutions, in the multi-functional multi-color electrochromic display screen capable of detecting environmental electromagnetic radiation, the multi-color electrochromic panel can change color following the change of the electrical signal, and the multi-color electrochromic panel includes the first A substrate, a first transparent conductive layer, a colorful electrochromic layer, an electrolyte layer, an ion storage layer, a second transparent conductive layer and a second substrate.

In some preferred embodiments, the colorful electrochromic display unit and the digital display unit are at least partially covered on the front surface of the display screen body, and the collector unit, the detector unit and the processor unit are respectively arranged on the on the multi-color electrochromic display unit.

Further, the multifunctional multi-colored electrochromic display screen capable of detecting ambient electromagnetic radiation further includes a temperature sensor unit, which is at least used to detect ambient temperature.

Further, the output end of the collector unit is connected with the input end of the detector unit, and the output end of the detector unit and the output end of the temperature sensor unit are respectively connected with the input end of the processor unit , the output end of the processor unit is respectively connected with the multi-color electrochromic display unit and the digital display unit.

In some preferred embodiments, the multi-color electrochromic display panel is half-covered on the front of the display screen body, and the collector unit, the detector unit and the processor unit are respectively embedded in the multi-color electrochromic display panel, so The temperature sensor unit is embedded in the colorful electrochromic display panel, the digital display panel is half-covered on the front of the display screen main body, the output end of the collector unit is connected to the detector unit, and the output end of the detector unit is The processor module is connected, the output end of the temperature sensor unit is connected to the processor module, and the processor unit is connected to the digital display panel and the colorful electrochromic display panel. The multi-color electrochromic layer display panel is disposed on the main body of the display screen on the front, and the collector unit senses electromagnetic radiation in the environment, and the detector unit converts the collected electromagnetic radiation energy into chemical energy or electrical energy, and passes through the processor unit. Process the converted signal, calculate the electromagnetic radiation intensity, control the colorful electrochromic display panel to change the corresponding color, control the temperature sensor unit to sense the ambient temperature, and control the digital display panel to display the specific electromagnetic radiation intensity or level and ambient temperature.

Further, the collector unit includes, but is not limited to, a lens group, a mirror group, an antenna, and the like.

Further, the detector units include, but are not limited to, photosensitive films, photocells, photosensitive and thermal detection elements, resonant cavity resonators, and the like.

Further, the processor unit performs various processing on the converted signal, such as developing, fixing, signal amplification, transformation, correction and encoding. The processor unit includes, but is not limited to, a photographic processing device and an electronic processing device. Another aspect of the embodiments of the present invention also provides a method for preparing the aforementioned multi-colored electrochromic structure, which includes the following steps: providing a substrate; using PVD deposition to first deposit and prepare different metals in different regions on the substrate , and then deposit the dielectric layer material on the different metals; or adopt the PVD deposition method, first sputter the metal layer material on the substrate, and then deposit and prepare different dielectric materials in different regions of the metal layer; or By PVD deposition, metal layer materials are first sputtered on the substrate, and then dielectric materials with different thicknesses are deposited in different regions of the metal layer; or by PVD deposition, different thicknesses are first deposited on the substrate Different metals are prepared by regional deposition, and then different dielectric materials are deposited in different regions of the metal layer; or PVD deposition is used to first deposit different metals in different regions on the substrate, and then deposit and prepare different metals in different regions of the substrate. Different regions of the layer are deposited to prepare dielectric materials of different thicknesses; the PVD deposition methods include evaporation plating, electron beam evaporation, magnetron sputtering or ion plating. The preparation methods of metal reflective layers (such as tungsten films) include electron beam evaporation, thermal evaporation, etc., while the preparation methods of electrochromic materials for dielectric layers (such as tungsten oxide) include electron beam evaporation, thermal evaporation, and electrochemical deposition. Two preparation methods, electron beam evaporation method and electrochemical deposition method, are mainly introduced below.

1. Electron beam evaporation method

Electron beam evaporation is a technology of vacuum evaporation coating, which is characterized by little or no coverage on both sides of the target three-dimensional structure, usually only deposited on the surface of the target, and the prepared film is of high purity and good quality , but also can accurately control the thickness. This method mainly refers to the use of electron beams to directly heat the evaporation material under vacuum conditions, so that the evaporation material is vaporized and transported to the substrate, condensed on the substrate to form a thin film, and finally forms the metal reflective layer required for the wristband.

2. Electrochemical deposition method

Electrochemical deposition means that under the action of an external electric field, a cathode and an anode form a circuit in a certain electrolyte solution, and through a redox reaction, the particles in the solution are precipitated on the surface of the cathode or anode to form a wristband. Color-changing material coating. This method can be uniformly deposited on various substrates with complex structures, and is usually carried out at room temperature or slightly higher than room temperature, so this method is also commonly used in the preparation of nanostructured materials.

The color of the colorful electrochromic film obtained by the optical interference of the metal medium in the embodiment of the present invention is the physical structural color, the initial color is controlled by changing the thickness of the metal layer and the electrochromic layer, and the color changes correspondingly after electrification. Compared with various pigment drawings in the prior art, it has the advantages of non-fading, environmental protection and iridescent effect, etc., and has broad application prospects in the fields of display, decoration, anti-counterfeiting and the like.

Another aspect of the embodiments of the present invention further provides a device capable of detecting ambient electromagnetic radiation, the device is provided with the aforementioned multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation.

Further, the device includes a mobile phone, a tablet computer, a home appliance or a wall, etc., but is not limited thereto.

Another aspect of the embodiments of the present invention also provides an application of the aforementioned multifunctional multi-color electrochromic display screen or device capable of detecting ambient electromagnetic radiation in the field of ambient electromagnetic radiation detection.

Another aspect of the embodiments of the present invention also provides a method for detecting electromagnetic radiation, the method is mainly implemented based on the foregoing multifunctional multi-color electrochromic display screen or device capable of detecting ambient electromagnetic radiation, and the method includes:

Connect the working electrode, the counter electrode and the power source to form a working circuit;

A collector unit is used to collect ambient electromagnetic radiation, a detector unit is used to convert the electromagnetic radiation energy into chemical energy or electrical energy, and then a processor is used to process the converted chemical energy or electrical energy signal, calculate the electromagnetic radiation intensity, and calculate the electromagnetic radiation intensity according to the processor unit. The change of the transmitted electrical signal adjusts the light transmittance of the multi-color electrochromic structure in the multi-color electrochromic display unit to make the multi-color electrochromic structure change color;

The digital display unit displays electromagnetic radiation intensity information.

The multi-functional colorful electrochromic display screen for environmental electromagnetic radiation detection of the present invention can realize the detection of electromagnetic radiation in the environment and display colorful color changes, and display the electromagnetic radiation information of the environment where the user is located, and the operation is convenient and time-saving. , can be widely used in mobile phone shells, tablet shells, home appliance shells, wall shells and other occasions.

Please refer to FIG. 7 , which shows a novel reflective/transmissive dual-mode multi-color electrochromic structure in a typical embodiment of the present invention, which includes a working electrode 5 , a counter electrode 7 and an electrolyte layer 6 , and the electrolyte layer 6 is disposed on the working electrode 5 and between the counter electrode 7.

Wherein, the electrolyte layer 6 can be selected from suitable aqueous electrolyte, organic phase electrolyte, gel electrolyte or solid electrolyte, preferably LiCl, AlCl ₃ , HCl, H ₂ SO ₄ aqueous solution, LiClO ₄ propylene carbonate Electrolyte, LiCl/PVA, H ₂ SO ₄ /PVA gel electrolyte, etc., but not limited thereto.

Referring to FIG. 8 again, the working electrode 5 may include an optical thin film structure, and the optical thin film structure may include a conductive substrate 10, a metal reflection/transmission layer 11 as a second optical structure layer, and a dielectric layer 12, while the dielectric The air layer above the layer 12 can serve as the first optical structure layer, and the dielectric layer 12 is composed of electrochromic material. Preferably, the thickness of the aforementioned second optical structure layer is greater than 0 and less than 20 nm.

Wherein, referring to the foregoing content, the present invention uses the collector unit to sense the electromagnetic radiation in the environment by arranging the front of the multi-color electrochromic layer display panel on the display screen body, and the detector unit converts the collected electromagnetic radiation energy into Chemical energy or electrical energy, the converted signal is processed by the processor unit, the electromagnetic radiation intensity is calculated, the colorful electrochromic display panel is controlled to change the corresponding color, the temperature sensor unit is controlled to sense the ambient temperature, and the digital display panel is controlled to display The specific electromagnetic radiation intensity or level and ambient temperature can be detected, and the electromagnetic radiation in the environment can be detected to show colorful color changes, and the electromagnetic radiation information of the environment in which they are located can be displayed to the user. The operation is convenient and time-saving, and can be widely used in Mobile phone case, tablet case, home appliance case, wall outer body, etc.

The technical solutions of the present invention are further described in detail below through several embodiments and in conjunction with the accompanying drawings. However, the selected embodiments are only intended to illustrate the present invention and not to limit the scope of the present invention.

Example 1

The embodiment of the present invention provides a multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation, including a display screen main substrate 100, a collector unit 200 for collecting environmental electromagnetic radiation, and for converting electromagnetic radiation energy into chemical Detector unit 300 for energy or electrical energy, processor unit 400 for processing converted signals, digital display panel 500 for information reception, and colorful electrochromic display panel 600 for changing color following changes in electrical signals , a temperature sensor unit 700 for detecting temperature. The multi-color electrochromic display panel 600 is half-covered on the front of the display screen main substrate 100 , the collector unit 200 , the detector unit 300 and the processor unit 400 are respectively embedded in the multi-color electrochromic display panel 600 and the temperature sensor unit 700 Inlaid on the multi-color electrochromic display panel 600, the digital display panel 500 is half-covered on the front of the display screen main substrate 100, the output end of the collector unit 200 is connected to the detector unit 300, the output end of the detector unit 300 is connected to the processor unit 400, and the temperature The output end of the sensor unit 700 is connected to the processor unit 400 , and the processor unit 400 is connected to the digital display panel 500 and the multi-color electrochromic display panel 600 .

As shown in FIG. 1 , in this embodiment, a multi-functional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation is applied to the outer casing of household appliances such as refrigerators and microwave ovens, and the front surface of the display screen main substrate 100 is provided with colorful electrochromic display screens. Layer display panel 600, the collector unit 200 senses electromagnetic radiation in the home environment, the detector unit 300 converts the collected electromagnetic radiation energy into chemical energy or electrical energy signals, and transmits the converted signals to the processor unit 400, through The processor unit 400 performs calculation processing on the converted signal, calculates the electromagnetic radiation intensity, divides it into many levels, and controls the power supply to output corresponding voltage, and the output voltage is applied to the multi-color electrochromic panel 600 . For example, level 1 electromagnetic radiation intensity output 1-1.5V, level 2 electromagnetic radiation intensity output 1.5-2V, level 3 electromagnetic radiation intensity output 2-2.5V, level 4 electromagnetic radiation intensity output 2.5-3V, level 5 electromagnetic radiation intensity output 3 -3.5V, 6-level electromagnetic radiation intensity output 3.5-4V. The multi-color electric-to-color-changing panel 600 of this embodiment is half-covered on the front surface of the display main body substrate 100 , and the receiving voltage port of the multi-color electric-to-color-changing panel 600 is connected to a power source. The schematic diagram of the multi-color electrochromic structure is shown in FIG. 2, including a first substrate, a first transparent conductive layer, a multi-colored electrochromic layer, an electrolyte layer, an ion storage layer, a second transparent conductive layer and a second substrate. The structure of the working electrode of the colorful electrochromic structure is shown in FIG. 3 , which is composed of a metal layer and a dielectric layer, and the dielectric layer is composed of an electrochromic material. Since the color change of the electrochromic layer is subject to the level of voltage, in this embodiment, when the level of electromagnetic radiation is different, the voltage output by the processor unit 400 to control the power supply to the multi-color electrochromic panel 600 is different. The panel 600 also presents colorful colors corresponding to it. When the electromagnetic radiation level is high enough to endanger human health, the processor unit 400 controls the power supply to output corresponding voltages to the colorful electrochromic layer panel 600. 600 presents another color, for example, the original red multi-colored electrochromic panel 600 becomes dark green to remind the user to pay attention to the electromagnetic radiation in the home environment, and to keep away or take corresponding measures. Of course, it should be noted that the digital display panel 500 in the display screen in this embodiment is also connected to the processor unit 400, and the processor unit 400 can simultaneously display the electromagnetic radiation intensity level on the digital display panel 500 in detail. In order to increase the use function of the display screen, a temperature sensor unit 700 is arranged on the colorful electrochromic panel 600 to sense the ambient temperature. The temperature sensor unit is connected to the sensor unit 400, and the temperature sensor transmits the sensed signal to the sensor unit. In 400, the sensor unit 400 transmits the information to the digital display panel 500 for display. The collector unit 200 , the detector unit 300 and the processor unit 400 are respectively embedded in the multi-color electrochromic display panel 600 , and the temperature sensor unit 700 is embedded in the multi-color electrochromic display panel 600 .

Example 2

The embodiment of the present invention provides another multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation, including a display screen main substrate 100, a collector unit 200 for collecting environmental electromagnetic radiation, and used for converting electromagnetic radiation energy into Detector unit 300 for chemical energy or electrical energy, processor unit 400 for processing converted signals, digital display panel 500 for information reception, and colorful electrochromic display panel for changing color following changes in electrical signals 600, a temperature sensor unit 700 for detecting temperature, an alarm unit 800 for sounding an alarm, and a power supply unit 900 for supplying voltage. The multi-color electrochromic display panel 600 is half covered on the front of the display screen main substrate 100 , the digital display panel 500 is half covered on the front of the display main substrate 100 , the collector unit 200 , the detector unit 300 , and the processor unit 400 , the temperature sensor unit 700, the alarm unit 800 and the power supply unit 900 are respectively embedded in the display screen main substrate 100, located above the electrochromic display panel 600 and the digital display panel 500, and the output end of the collector unit 200 is connected to the detector unit 300 to detect The output end of the processor unit 300 is connected to the processor unit 400 , the output end of the temperature sensor unit 700 is connected to the processor unit 400 , and the processor unit 400 is connected to the digital display panel 500 , the multicolor electrochromic display panel 600 and the alarm unit 800 . The collector unit 200 , the detector unit 300 , the processor unit 400 , the digital display panel 500 , the multi-color electrochromic display panel 600 , the temperature sensor unit 700 and the alarm unit 800 are connected to the power supply unit 900 .

As shown in FIG. 5 , in this embodiment, a multi-functional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation is applied to the outer casing of household appliances such as refrigerators and microwave ovens, and the front surface of the display screen main substrate 100 is provided with colorful electrochromic display Layer display panel 600, the collector unit 200 senses electromagnetic radiation in the home environment, the detector unit 300 converts the collected electromagnetic radiation energy into chemical energy or electrical energy signals, and transmits the converted signals to the processor unit 400, through The processor unit 400 performs calculation processing on the converted signal, calculates the electromagnetic radiation intensity, divides it into many levels, and controls the power supply to output corresponding voltage, and the output voltage is applied to the multi-color electrochromic panel 600 . For example, level 1 electromagnetic radiation intensity output 1-1.5V, level 2 electromagnetic radiation intensity output 1.5-2V, level 3 electromagnetic radiation intensity output 2-2.5V, level 4 electromagnetic radiation intensity output 2.5-3V, level 5 electromagnetic radiation intensity output 3 -3.5V, 6-level electromagnetic radiation intensity output 3.5-4V. The multi-color electric-to-color-changing panel 600 of this embodiment is half-covered on the front surface of the display screen main substrate 100 , and the receiving voltage port of the multi-color electric-to-color-changing panel 600 is connected to the power supply unit. The colorful electrochromic structure includes a first substrate, a first transparent conductive layer, a colorful electrochromic layer, an electrolyte layer, an ion storage layer, a second transparent conductive layer and a second substrate. The working electrode of the colorful electrochromic structure is composed of a metal layer and a dielectric layer, and the dielectric layer is composed of an electrochromic material. Since the color change of the electrochromic layer is subject to the level of voltage, in this embodiment, when the level of electromagnetic radiation is different, the voltage output by the processor unit 400 to control the power supply to the multi-color electrochromic panel 600 is different. The panel 600 also presents colorful colors corresponding to it. When the electromagnetic radiation level is high enough to endanger human health, the processor unit 400 controls the power supply to output corresponding voltages to the colorful electrochromic layer panel 600. 600 presents another color, for example, the original red multi-colored electrochromic panel 600 becomes dark green to remind the user to pay attention to the electromagnetic radiation in the home environment, and to keep away or take corresponding measures. Meanwhile, when the electromagnetic radiation level is high enough to endanger human health, the processor unit 400 can simultaneously control the alarm unit to issue an alarm to remind the user to stay away. Of course, it should be noted that the digital display panel 500 in the display screen in this embodiment is also connected to the processor unit 400, and the processor unit 400 can simultaneously display the electromagnetic radiation intensity level on the digital display panel 500 in detail. In order to increase the use function of the display screen, a temperature sensor unit 700 is arranged on the colorful electrochromic panel 600 to sense the ambient temperature. The temperature sensor unit is connected to the sensor unit 400, and the temperature sensor transmits the sensed signal to the sensor unit. In 400, the sensor unit 400 transmits the information to the digital display panel 500 for display. Among them, the collector unit 200, the detector unit 300, the processor unit 400, the temperature sensor unit 700, the alarm unit 800 and the power supply unit 900 are respectively embedded in the display screen main substrate 100, located on the electrochromic display panel 600 and the digital display panel. above 500.

Comparative Example 1

The comparative example provides a conventional display screen capable of detecting ambient electromagnetic radiation, comprising a display screen main body substrate, a collector unit for collecting ambient electromagnetic radiation, a detector unit for converting electromagnetic radiation energy into chemical energy or electrical energy, and a A processor unit for processing the converted signal, a digital display panel for information reception, a temperature sensor unit for detecting temperature, an alarm unit for sounding an alarm, and a power supply unit for supplying voltage. In this comparative example, a display screen that can detect environmental electromagnetic radiation is applied to the outer casing of household appliances such as refrigerators and microwave ovens, and a digital display panel is arranged on the front of the main substrate of the display screen to sense electromagnetic radiation in the home environment with a collector unit. The unit converts the collected electromagnetic radiation energy into chemical energy or electrical energy signals, and transmits the converted signals to the processor unit. The processor unit calculates and processes the converted signals to calculate the electromagnetic radiation intensity. When the level is high enough to endanger human health, the processor unit can simultaneously control the alarm unit to issue an alarm to remind the user to stay away. This control example lacks a colorful electrochromic display panel that changes color following the change of electrical signals. Users cannot actively observe the electromagnetic radiation intensity of the environment they are in, and can only passively remind them, showing poor human-computer interaction.

Comparative Example 2

The comparative example provides a conventional multifunctional electrochromic display screen capable of detecting ambient electromagnetic radiation, including a display screen main body substrate, a collector unit for collecting ambient electromagnetic radiation, and for converting electromagnetic radiation energy into chemical energy or electrical energy. Detector unit, processor unit for processing the converted signal, digital display panel for information reception, conventional electrochromic display panel for changing color following electrical signal changes, temperature sensor for temperature detection unit, an alarm unit for sounding an alarm, a power supply unit for supplying voltage. The conventional electrochromic structure includes a first substrate, a first transparent conductive layer, a conventional electrochromic layer, an electrolyte layer, an ion storage layer, a second transparent conductive layer and a second substrate. The working electrode of the conventional electrochromic structure is composed of tungsten oxide. Since the color change of the electrochromic layer is subject to the level of voltage, in this comparative example, when the level of electromagnetic radiation is different, the voltage output by the processor unit to control the power supply to the conventional electrochromic panel is different, and the conventional electrochromic panel also When the electromagnetic radiation level is high enough to endanger human health, the processor unit controls the power supply to output the corresponding voltage to the conventional electrochromic layer panel, and the conventional electrochromic panel appears dark blue to remind Users should pay attention to the electromagnetic radiation in the home environment, and keep away from it or take corresponding measures. The conventional electrochromic display panel described in this comparative example is made of pure tungsten oxide material, and its color change is only a single blue change, which is difficult for users to distinguish with naked eyes.

Example 3

A working electrode of a multi-color electrochromic structure provided by this embodiment includes a first optical structure layer, a second optical structure layer, a dielectric layer and a base layer, which can be referred to as shown in FIG. 6 .

The first optical structure layer is air, the second optical structure is a metal tungsten (W) layer, the dielectric layer is formed of tungsten oxide, and the base layer may be a PET film.

The preparation method of the working electrode of the colorful electrochromic structure is as follows: on a clean PET substrate, a layer of tungsten film is sputtered by magnetron sputtering method. Preferably, the thickness of the tungsten film is selected to be about 10 nm by sputtering. Then, a tungsten oxide layer is sputtered on the tungsten film by magnetron sputtering. Preferably, the thickness of the tungsten oxide layer is set at 100 nm˜400 nm.

Of course, the aforementioned tungsten film can also be prepared by methods known in the industry, such as electron beam evaporation and thermal evaporation. The aforementioned tungsten oxide layer can be prepared by methods known in the industry, such as electron beam evaporation, thermal evaporation, electrochemical deposition, and sol-gel technology. Referring to FIG. 8 , by controlling the thickness of the tungsten oxide layer to be different, an optical thin film structure reflecting rich and brilliant colors can be obtained when viewed from one side of the first optical structure layer.

Referring to Figure 9, under different tungsten oxide thicknesses (in Figure 8), from the direction of the base layer, the corresponding reflection color also presents rich and brilliant colors, and this color is different from the color seen from the direction of the first optical structure layer. very different.

Referring to FIG. 10 , under different thicknesses of tungsten oxide shown in FIG. 8 , through the optical film structure of this embodiment, a transmission structural color can be obtained, and the transmission structural color also presents rich and brilliant colors. Therefore, the transmittance of the transmitted color of the optical thin film structure of this embodiment is determined by the thickness of the metal tungsten layer and the tungsten oxide layer.

Example 4

The working electrode of a multi-color electrochromic structure provided by this embodiment includes a first optical structure layer, a second optical structure layer, a dielectric layer and a base layer, which can be referred to as shown in FIG. 8 .

The first optical structure layer is air, the second optical structure is a metallic silver (Ag) layer, the dielectric layer is formed of titanium dioxide, and the base layer may be a PET film.

The preparation method of the working electrode of the colorful electrochromic structure is as follows: on a clean PET substrate, a layer of silver film is sputtered by magnetron sputtering method. Preferably, the thickness of the silver film is selected to be about 2 nm by sputtering. Then, a layer of titanium dioxide is sputtered on the tungsten film by magnetron sputtering. Preferably, the thickness of the titanium dioxide layer is set at 100 nm˜400 nm.

Of course, the aforementioned silver film can also be prepared by methods known in the industry, such as electron beam evaporation and thermal evaporation. The aforementioned titanium dioxide layer can be prepared by means known in the industry, such as electron beam evaporation, thermal evaporation, electrochemical deposition, and sol-gel technology. The working electrode structure of this embodiment exhibits similar properties to the electrode structure working in Embodiment 3, that is, different colors are present when viewed from two sides. Also available in transmissive structural colors.

Example 5

The working electrode of the multi-color electrochromic structure provided by this embodiment includes a first dielectric layer, a second optical structure layer, a second dielectric layer, and a first optical structure layer formed on a substrate in sequence.

Wherein, the added second dielectric layer can improve the color brightness and saturation.

Referring to FIG. 13 , the first optical structure layer of the optical film structure is air, the second optical structure layer is metal tungsten (W), the first and second dielectric layers are formed of tungsten oxide, and the base layer can be PET membrane.

The preparation method of the working electrode of the colorful electrochromic structure is as follows: on a clean PET substrate, a tungsten oxide layer is first sputtered by a magnetron sputtering method. Preferably, the thickness of the tungsten oxide layer is set at 1 nm to 400 nm. . Then, a layer of tungsten film is sputtered by a magnetron sputtering method. Preferably, the thickness of the tungsten film is about 10 nm. Then, a tungsten oxide layer is sputtered on the tungsten film by magnetron sputtering. Preferably, the thickness of the tungsten oxide layer is set at 100 nm˜400 nm.

Of course, the aforementioned tungsten film can also be prepared by methods known in the industry, such as electron beam evaporation and thermal evaporation. The aforementioned tungsten oxide layer can be prepared by methods known in the industry, such as electron beam evaporation, thermal evaporation, electrochemical deposition, and sol-gel technology.

Referring to FIG. 14 , the thickness of the tungsten oxide layer between the control tungsten layer and the PET substrate is different. Viewed from the direction of the first optical structure layer, a working electrode structure reflecting rich and brilliant colors can be obtained.

Referring to Fig. 15, under the different thicknesses of tungsten oxide shown in Fig. 12, when viewed from the direction of the base layer, the corresponding reflection color also presents rich and brilliant colors, and this color is completely different from the color seen from the direction of the film. different.

Please refer to FIG. 16 again, under the different thicknesses of tungsten oxide shown in FIG. 14, through the working electrode structure, the transmission structural color can be obtained, and the transmission structural color also presents rich and brilliant colors. The transmittance of the transmitted color of the working electrode structure is determined by the thickness of the metal tungsten layer and the tungsten oxide layer.

Example 6:

The working electrode structure of a multi-color electrochromic structure provided by this embodiment includes a second optical structure layer, a dielectric layer, and a first optical structure layer formed on a substrate in sequence.

The first optical structure layer is a metal tungsten (W) film, the second optical structure layer is a metal aluminum (Al) film, the dielectric layer is formed of zinc sulfide (ZnS), and the base layer may be a PET film.

The preparation method of the working electrode structure of the colorful electrochromic structure is as follows: on a clean PET substrate, a layer of metal aluminum film is sputtered by magnetron sputtering method. Preferably, the thickness of the aluminum film is set at 15 nm. Then, a layer of zinc sulfide is sputtered by a magnetron sputtering method. Preferably, the thickness of the zinc sulfide is selected to be 100 nm˜400 nm by sputtering. Then, a layer of tungsten film is sputtered on the zinc sulfide layer by magnetron sputtering. Preferably, the thickness of the tungsten film is set at 0-50 nm.

Of course, the aforementioned tungsten film and aluminum film can also be prepared by methods known in the industry, such as electron beam evaporation and thermal evaporation. The aforementioned zinc sulfide layer can be prepared by methods known in the industry, such as electron beam evaporation, thermal evaporation, electrochemical deposition, and sol-gel technology.

The working electrode structure of the multi-color electrochromic structure in this embodiment will show different colors when viewed from two sides, and also has a transmissive structural color.

Example 7:

The working electrode structure of a multi-color electrochromic structure provided by this embodiment includes a second optical structure layer, a dielectric layer, and a first optical structure layer formed on a substrate in sequence.

Wherein, the first optical structure layer is air, the second optical structure layer is a metal aluminum (Al) film, the dielectric layer is formed of a single substance of silicon, and the base layer can be a PET film.

The preparation method of the working electrode structure of the colorful electrochromic structure is as follows: on a clean PET substrate, a layer of metal aluminum film is sputtered by magnetron sputtering method. Preferably, the thickness of the aluminum film is set at 5 nm. Then, a layer of silicon film is deposited by a magnetron sputtering method. Preferably, the thickness of the silicon film is selected to be 100 nm˜400 nm by sputtering.

Of course, the aforementioned aluminum film and silicon film can also be prepared by methods known in the industry, such as electron beam evaporation and thermal evaporation. The working electrode structure of this embodiment shows different colors when viewed from two sides, and also has a transmissive structural color.

Example 8:

The working electrode structure of a multi-color electrochromic structure provided by this embodiment includes a second optical structure layer, a dielectric layer, and a first optical structure layer formed on a substrate in sequence.

The first optical structure layer is a metallic silver (Ag) film, the second optical structure layer is a metallic aluminum (Al) film, the dielectric layer is formed of Prussian blue, and the base layer may be a PET/ITO film.

The preparation method of the working electrode structure of the colorful electrochromic structure is as follows: on a clean PET/ITO substrate, a layer of metal aluminum film is sputtered by a magnetron sputtering method. Preferably, the thickness of the aluminum film is set at 10 nm. . Then, a layer of Prussian blue is deposited by an electrodeposition method. Preferably, the thickness of the Prussian blue is selected to be 100 nm˜2000 nm. Then, a layer of silver film is sputtered on the Prussian blue layer by magnetron sputtering. Preferably, the thickness of the silver film is set at 0-50 nm.

Of course, the aforementioned silver film and aluminum film can also be prepared by methods known in the industry, such as electron beam evaporation and thermal evaporation. The aforementioned Prussian blue layer can be prepared by methods known in the industry, such as electrochemical deposition and sol-gel technology.

The working electrode structure of this embodiment shows different colors when viewed from two sides, and also has a transmissive structural color.

Example 9:

This embodiment provides a device, which can be considered as a reflection/transmission dual-mode multicolor electrochromic device, including a working electrode, an electrolyte layer and a counter electrode, and the electrolyte layer is provided between the working electrode and the counter electrode.

Referring to FIG. 17 , the working electrode includes an optical film structure disposed on a conductive substrate. The optical film structure includes first and second optical structure layers and a dielectric layer, wherein air is used as the first optical structure layer and the second optical structure layer. It is formed of metal tungsten (W), and the dielectric layer is formed of tungsten oxide. And the substrate can be PET/ITO or the like.

The preparation method of the working electrode is as follows: on the clean PET/ITO film, a layer of tungsten film is sputtered by magnetron sputtering method. Preferably, the thickness of the tungsten film is selected to be about 10 nm by sputtering. Then, a layer of tungsten oxide is sputtered on the tungsten film by magnetron sputtering. Preferably, the thickness of the tungsten oxide layer is set to 100 nm˜400 nm.

Of course, the aforementioned tungsten film can also be prepared by methods known in the industry, such as electron beam evaporation and thermal evaporation. The aforementioned tungsten oxide layer can be prepared by methods known in the industry, such as electron beam evaporation, thermal evaporation, and electrochemical deposition.

The working electrode of this embodiment shows different colors when viewed from two sides, and also has a transmissive structural color.

The aforementioned working electrode is then matched with a pair of electrodes (eg, NiO counter electrodes), and AlCl ₃ electrolyte is encapsulated therebetween, and then leads are drawn out to prepare the colorful electrochromic device of this embodiment. By applying voltage to the colorful electrochromic device, the color of the working electrode can be further modulated to change among more colors, especially the color changes on both sides of the working electrode are not exactly the same, see Fig. 18 shown.

Example 10:

This embodiment provides an optical device, which can be considered as a reflection/transmission dual-mode multicolor electrochromic device, including a working electrode, an electrolyte layer and a counter electrode, and the electrolyte layer is provided between the working electrode and the counter electrode.

The working electrode includes an optical thin film structure disposed on a conductive substrate, the optical thin film structure includes first and second optical structure layers and a dielectric layer, wherein the first optical structure layer is formed of metal tungsten (W), and the second optical structure layer is formed of Metal silver (Ag) is formed, and the dielectric layer is formed of titanium dioxide (TiO ₂ ). And the substrate can be PET/AgNWs.

The preparation method of the working electrode is as follows: on the clean PET/AgNWs film, a layer of silver film is sputtered by magnetron sputtering method. Preferably, the thickness of the silver film is selected to be about 10 nm by sputtering. Then, a layer of titanium oxide is sputtered on the silver film by magnetron sputtering. Preferably, the thickness of the titanium dioxide layer is set to be 100 nm˜400 nm. Then, a layer of tungsten film is sputtered by magnetron sputtering on the titanium dioxide layer. Preferably, the thickness of the tungsten film is selected to be about 5 nm by sputtering.

The optical device can be assembled and formed by referring to Embodiment 11.

Of course, the aforementioned silver film and tungsten film can also be prepared by methods known in the industry, such as electron beam evaporation and thermal evaporation. The aforementioned titanium oxide layer can be prepared by methods known in the industry, such as electron beam evaporation, thermal evaporation, and electrochemical deposition.

The working electrode of this embodiment shows different colors when viewed from two sides, and also has a transmissive structural color.

The aforementioned working electrode is then matched with a pair of electrodes (eg, NiO counter electrodes), and LiCl/PVA gel electrolyte is arranged between them, and then the wires are drawn out to prepare the colorful electrochromic device of this embodiment. By applying voltage to the colorful electrochromic device and adjusting the voltage range, the color of the working electrode can be further modulated to change between more colors, especially the color change on both sides of the working electrode is not complete same. The color change of the multi-colored electrochromic device of this example under voltage application shows similar properties to the color change of Example 9.

Example 11:

This embodiment provides an optical device, which can be considered as a reflection/transmission dual-mode multicolor electrochromic device, including a working electrode, an electrolyte layer and a counter electrode, and the electrolyte layer is provided between the working electrode and the counter electrode.

The working electrode includes an optical thin film structure disposed on a conductive substrate, the optical thin film structure includes first and second optical structure layers and a dielectric layer, wherein the first optical structure layer is air, and the second optical structure is a metal copper (Cu) layer , the dielectric layer is formed of vanadium oxide (V ₂ O ₅ ), and the base layer may be PET/ITO.

The preparation method of the optical thin film structure is as follows: on a clean PET substrate, a layer of copper film is sputtered by a magnetron sputtering method. Preferably, the thickness of the copper film is selected to be about 15 nm by sputtering. Then, a layer of vanadium oxide is sputtered on the copper film by magnetron sputtering. Preferably, the thickness of the vanadium oxide layer is set at 100 nm˜400 nm.

Of course, the aforementioned copper film can also be prepared by methods known in the industry, such as electron beam evaporation and thermal evaporation. The aforementioned vanadium oxide layer can be prepared by methods known in the industry, such as electron beam evaporation, thermal evaporation, electrochemical deposition, and sol-gel technology. The working electrode of this embodiment shows different colors when viewed from two sides, and also has a transmissive structural color.

The optical device can be assembled and formed by referring to Example 9.

The aforementioned working electrode is then matched with a pair of electrodes (for example, NiO counter electrodes), and a LiCl/HCl/AlCl ₃ /NaCl/PVA mixed ion gel electrolyte is arranged between them. By applying voltage to the colorful electrochromic device and adjusting the voltage range, the color of the working electrode can be further modulated, so that it can be changed between more colors, especially the color change on both sides of the working electrode is not complete. same. The color change of the multi-colored electrochromic device of this example under voltage application shows similar properties to the color change of Example 9.

Example 12:

This embodiment provides an optical device, which can be considered as a reflection/transmission dual-mode multicolor electrochromic device, including a working electrode, an electrolyte layer and a counter electrode, and the electrolyte layer is provided between the working electrode and the counter electrode.

The working electrode includes an optical thin film structure arranged on a conductive substrate, the optical thin film structure includes first and second optical structure layers and a dielectric layer, wherein air is used as the first optical structure layer, and the second optical structure layer is made of metal tungsten (W) formed, and the dielectric layer is formed of tungsten oxide (WO ₃ ). And the substrate can be PET/ITO.

The preparation method of the working electrode is as follows: on the clean PET/ITO film, a layer of silver film is sputtered by magnetron sputtering method. Preferably, the thickness of the tungsten film is selected to be about 10 nm by sputtering. Then, a layer of tungsten oxide layer is sputtered on the silver film by magnetron sputtering. Preferably, the thickness of the tungsten oxide layer is set to 100 nm˜400 nm.

Of course, the aforementioned tungsten film can also be prepared by methods known in the industry, such as electron beam evaporation and thermal evaporation. The aforementioned tungsten oxide layer can be prepared by methods known in the industry, such as electron beam evaporation, thermal evaporation, and electrochemical deposition.

The working electrode of this embodiment shows different colors when viewed from two sides, and also has a transmissive structural color.

A layer of lithium lanthanum titanate thin film is sputtered on the aforementioned working electrode as a solid electrolyte by a magnetron sputtering method, and the preferred thickness of the lithium lanthanum titanate thin film is 500 nm.

Then, the working electrode and the solid electrolyte are matched with a pair of electrodes (for example, IrO ₂ counter electrodes), and then lead wires are drawn out, and the colorful electrochromic device of this embodiment can be prepared. By applying voltage to the colorful electrochromic device, the color of the working electrode can be further modulated to change among more colors, especially the color changes on both sides of the working electrode are not completely the same. The color change of the multi-colored electrochromic device of this example under voltage application shows similar properties to the color change of Example 11.

Comparative Example 3:

An optical film structure provided by this comparative example includes a first optical structure layer, a second optical structure layer, a medium layer and a base layer.

The first optical structure layer is air, the second optical structure does not exist (no tungsten film), the dielectric layer is formed of tungsten oxide, and the base layer can be a PET film.

The preparation method of the optical thin film structure is as follows: on a clean PET substrate, a tungsten oxide layer is sputtered by magnetron sputtering. Preferably, the thickness of the tungsten oxide layer is set at 100nm-400nm.

By controlling the thickness of the tungsten oxide layer to be different, a transparent and colorless optical thin film structure is obtained when viewed from the side of the first optical structure layer.

Under different thicknesses of tungsten oxide, the corresponding color is also transparent and colorless when viewed from the direction of the base layer, and this color is exactly the same as the color viewed from the direction of the first optical structure layer.

Under different thicknesses of tungsten oxide, through the optical film structure of this control example, a transparent and colorless optical film structure is still obtained.

Comparative Example 4:

An optical film structure provided by this comparative example includes a first optical structure layer, a second optical structure layer, a medium layer and a base layer.

The first optical structure layer is air, the second optical structure is a metal tungsten (W) layer, the dielectric layer is formed of tungsten oxide, and the base layer may be a PET film.

The preparation method of the optical thin film structure is as follows: on a clean PET substrate, a layer of tungsten film is sputtered by magnetron sputtering method. Preferably, the thickness of the tungsten film is selected to be about 100 nm by sputtering. Then, a tungsten oxide layer is sputtered on the tungsten film by magnetron sputtering. Preferably, the thickness of the tungsten oxide layer is set at 100 nm˜400 nm.

Of course, the aforementioned tungsten film can also be prepared by methods known in the industry, such as electron beam evaporation and thermal evaporation. The aforementioned tungsten oxide layer can be prepared by methods known in the industry, such as electron beam evaporation, thermal evaporation, electrochemical deposition, and sol-gel technology. By controlling the thickness of the tungsten oxide layer to be different, an optical thin film structure reflecting rich and brilliant colors can be obtained when viewed from one side of the first optical structure layer.

Under different thicknesses of tungsten oxide, when viewed from the direction of the base layer, the corresponding reflection color only shows the color of the metal tungsten film (silver white). At different thicknesses of tungsten oxide, the optical film structure of this comparative example was found to be non-transmissive.

In addition, the inventors of the present application also conducted experiments with other dielectric materials, metal reflective materials, base materials, etc. listed in this specification instead of the corresponding materials in the foregoing embodiments, and found that the obtained electrochromic structure and detectable ambient gas All multi-function mobile phones have similar advantages.

By adopting the above technical solutions, the present invention arranges the front of the multi-color electrochromic layer display panel on the main body of the display screen, and uses the collector unit to sense electromagnetic radiation in the environment, and the detector unit converts the collected electromagnetic radiation energy into Chemical energy or electrical energy, the converted signal is processed by the processor unit, the electromagnetic radiation intensity is calculated, the colorful electrochromic display panel is controlled to change the corresponding color, the temperature sensor unit is controlled to sense the ambient temperature, and the digital display panel is controlled to display The specific electromagnetic radiation intensity or level and ambient temperature can be detected, and the electromagnetic radiation in the environment can be detected to display colorful color changes, and the electromagnetic radiation information of the environment in which they are located can be displayed to the user. The operation is convenient and time-saving, and can be widely used in Mobile phone case, tablet case, home appliance case, wall outer body, etc.

It should be understood that the above-mentioned embodiments are only intended to illustrate the technical concept and characteristics of the present invention, and the purpose thereof is to enable those who are familiar with the art to understand the content of the present invention and implement it accordingly, and cannot limit the protection scope of the present invention. All equivalent changes or modifications made according to the spirit of the present invention should be included within the protection scope of the present invention.

Claims (49)

1. a multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation, is characterized in that comprising: Display main body; a collector unit, at least for collecting ambient electromagnetic radiation; A detector unit, at least for converting electromagnetic radiation energy into chemical energy or electrical energy; a processor unit, at least used to process the converted chemical energy or electrical energy signal to calculate the intensity of electromagnetic radiation; A multi-color electrochromic display unit, which includes a multi-color electrochromic structure, at least used to produce discoloration under the control of the processor unit according to the change of the electrical signal transmitted by the processor unit; A digital display unit, at least for displaying electromagnetic radiation intensity information; Wherein, the colorful electrochromic structure includes a working electrode, an electrolyte and a counter electrode, the electrolyte is distributed between the working electrode and the counter electrode, and it is characterized in that: the working electrode includes a first optical structure that is opposite and parallel to each other layer and a second optical structure layer, the first optical structure layer and the second optical structure layer are optically reflective and/or optically transmissive, and the first optical structure layer and the second optical structure layer are provided with A dielectric layer, the dielectric layer is composed of electrochromic materials, and the bonding interface between the dielectric layer and the first optical structure layer and the second optical structure layer is the first surface and the second surface of the dielectric layer, respectively. The first surface, the second surface and the medium layer form an optical cavity; when incident light enters the optical cavity from the first optical structure layer or the second optical structure layer, the reflected light formed on the first surface and the Phase shift of reflected light from second surface

d is the thickness of the dielectric layer,

is the refractive index of the dielectric layer, λ is the wavelength of the incident light,

is the refraction angle of the incident light when it passes through the first surface or the second surface. 2. The multifunctional multi-color electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 1, wherein if the refractive index of the first optical structure layer is defined as

Then the reflection coefficient of the first surface

in

is the incident angle of the incident light on the first surface; And/or, if the refractive index of the second optical structure layer is defined as

Then the reflection coefficient of the second surface

in

is the refraction angle of the incident light when it passes through the second surface. 3. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 2, wherein the reflection coefficient of the working electrode is expressed as:

The reflectance is expressed as:

4. The multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation according to any one of claims 1-3, wherein if the refractive index of the first optical structure layer is defined as

Then the transmission coefficient of the first optical structure layer

in

is the incident angle of the incident light on the first surface; And/or, if the refractive index of the second optical structure layer is defined as

Then the transmission coefficient of the second optical structure layer

in

is the refraction angle of the incident light when it passes through the second surface. 5. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 4, wherein the transmission coefficient of the working electrode is expressed as:

The transmittance is expressed as:

6. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 1, wherein the working electrode has an optical transmission working mode, an optical reflection working mode or an optical transmission and reflection working mode; In the optical reflection operating mode, the working electrode has a double-sided asymmetric structural color, and in the optical transmission operating mode, the working electrode has a transparent structural color. 7. The multifunctional multi-colored electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 1, wherein any one of the first optical structure layer and the second optical structure layer is a metal layer, and the other is a metal layer. The first optical structure layer and the second optical structure layer are both metal layers. 8. The multifunctional multi-colored electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 1, wherein the working electrode comprises one or more first optical structure layers, one or more dielectric layers and One or more second optical structural layers. 9. The multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 8, wherein the working electrode comprises a plurality of first optical structure layers and/or a plurality of second optical structure layers and multiple dielectric layers. 10 . The multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 8 , wherein the material of at least one of the first optical structure layer and the second optical structure layer comprises a metal material. 11 . ; The metal material includes any one or a combination of any one or more of tungsten, gold, silver, copper, titanium, aluminum, chromium, iron, cobalt, nickel, platinum, germanium, and palladium; and/or, the first The thickness of at least one of the optical structure layer and the second optical structure layer is 0 to 2000 nm. 11 . The multifunctional multi-colored electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 1 , wherein the material of the medium layer is selected from organic materials or inorganic materials. 12 . 12. The multifunctional multi-color electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 11, wherein the inorganic material comprises any one of metal element or non-metal element, inorganic salt, oxide or various combinations. 13. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 12, wherein the non-metallic element comprises any one or a combination of monocrystalline silicon, polycrystalline silicon and diamond . 14. The multifunctional multi-colored electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 12, wherein the inorganic salt comprises fluoride, sulfide, selenide, chloride, bromide, iodide A combination of any one or more of arsenide, arsenide or telluride. 15. The multifunctional multi-colored electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 12, wherein the oxide comprises WO ₃ , NiO, TiO ₂ , Nb ₂ O ₅ , Fe ₂ O ₃ , V ₂ O ₅ , Co ₂ O ₃ , Y ₂ O ₃ , Cr ₂ O ₃ , MoO ₃ , Al ₂ O ₃ , SiO ₂ , MgO, ZnO, MnO ₂ , CaO, ZrO ₂ , Ta ₂ O ₅ , Y ₃ Al ₅ O ₁₂ , Er ₂ O ₃ , and IrO ₂ , any one or a combination of more than one. 16. The multifunctional multi-colored electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 14, wherein the fluoride comprises MgF ₂ , CaF ₂ , GeF ₂ , YbF ₃ , YF ₃ , Na ₃ A combination of any one or more of AlF ₆ , AlF ₃ , NdF ₃ , LaF ₃ , LiF, NaF, BaF ₂ , and SrF ₂ . 17. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 14, wherein the sulfide comprises any one or more of ZnS, GeS, MoS ₂ and Bi ₂ S ₃ . combination of species. 18. The multifunctional multi-colored electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 14, wherein the selenide comprises any one of ZnSe, GeSe, MoSe ₂ , PbSe, Ag ₂ Se or various combinations. 19. The multifunctional multi-color electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 14, wherein the chloride comprises any one or a combination of AgCl, NaCl and KCl. 20. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 14, wherein the bromide comprises any one or more of AgBr, NaBr, KBr, TlBr and CsBr. combination. 21. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 14, wherein the iodide comprises any one or more of AgI, NaI, KI, RbI, and CsI. combination. 22. The multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 14, wherein the arsenide comprises GaAs. 23. The multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 14, wherein the telluride comprises GdTe. 24. _The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim ₁ , wherein the material _of the dielectric layer comprises _SrTiO3 , _Ba3Ta4O15 , _{Bi4Ti3O 2.} Any one or a combination of CaCO ₃ , CaWO ₄ , CaMnO ₄ , LiNbO ₄ , Prussian blue, Prussian black, Prussian white, and Prussian green. 25. The multifunctional multi-colored electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 1, wherein the material of the medium layer comprises liquid crystal material or MOF material. 26. The multifunctional colorful electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 11, wherein the organic material comprises organic small molecular compounds and/or polymers. 27. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 11, wherein the organic material comprises viologen, polypyrrole, polyaniline, polythiophene, polycarbazole, A combination of any one or more of phthalocyanine, terephthalate, dimethylbenzidine, tetrathiefene, alkyl bipyridine, phenothiazole, polyamide, epoxy resin, and polydiyne. 28. The multifunctional multi-colored electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 1, wherein the thickness of the dielectric layer is 0.001-2000 nm. 29. The multifunctional multi-color electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 28, wherein the thickness of the dielectric layer is 100-500 nm. 30. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 1, wherein: An optimized medium layer is also distributed between the medium layer and the first optical structure layer or the second optical structure layer; Alternatively, an optimized medium layer is provided on the first optical structure layer or the second optical structure layer. 31. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 30, wherein the material of the optimized dielectric layer comprises WO ₃ , NiO, TiO ₂ , Nb ₂ O ₅ , Fe ₂ O ₃ , V ₂ O ₅ , Co ₂ O ₃ , Y ₂ O ₃ , Cr ₂ O ₃ , MoO ₃ , Al ₂ O ₃ , SiO ₂ , MgO, ZnO, MnO ₂ , CaO, ZrO ₂ , Ta ₂ O _5. Any one or a combination of Y ₃ Al ₅ O ₁₂ , Er ₂ O ₃ , ZnS, MgF ₂ , and silicon nitride. 32. The multifunctional multi-colored electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 30, wherein the thickness of the optimized dielectric layer is 0-2000 nm. 33. The multifunctional colorful electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 1, wherein the first optical structure layer or the second optical structure layer is further combined with a substrate, and the substrate is Transparent or translucent. 34. The multifunctional colorful electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 33, wherein the substrate comprises materials comprising glass, plexiglass, PET, PES, PEN, PC, PMMA, A combination of any one or more of PDMS. 35. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 33, wherein the substrate is further provided with a conductive layer, and the conductive layer comprises FTO, ITO, and Ag nanowires , Ag nanogrid, carbon nanotube, and any one or more combination of graphene. 36. The multifunctional colorful electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 1, wherein the colorful electrochromic structure further comprises an ion conductive layer, an ion storage layer and a transparent conductive layer. 37. The multifunctional colorful electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 1, wherein the counter electrode comprises a transparent conductive electrode or a semitransparent conductive electrode. 38. The multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 37, wherein an ion storage layer is further provided between the transparent conductive electrode and the dielectric layer. 39. The multifunctional colorful electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 1, wherein the electrolyte comprises a liquid electrolyte, a gel electrolyte or a solid electrolyte. 40. The multifunctional colorful electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 39, wherein the electrolyte is a solid electrolyte. 41. The multifunctional multi-color electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 40, wherein the multi-color electrochromic structure is an all-solid-state structure. 42. The multifunctional multi-color electrochromic display screen capable of detecting environmental electromagnetic radiation according to claim 1, wherein the multi-color electrochromic display unit and the digital display unit are at least partially covered on the display screen main body The collector unit, the detector unit and the processor unit are respectively arranged on the multi-color electrochromic display unit. 43. The multifunctional multi-colored electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 42, further comprising a temperature sensor unit, which is at least used to detect ambient temperature. 44. The multifunctional colorful electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 43, wherein the output end of the collector unit is connected to the input end of the detector unit, and the detection The output end of the temperature sensor unit and the output end of the temperature sensor unit are respectively connected to the input end of the processor unit, and the output end of the processor unit is respectively connected to the multi-color electrochromic display unit and the digital display unit. 45. The multifunctional colorful electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 1, wherein the collector unit comprises a lens group, a mirror group or an antenna; And/or, the detector unit includes a photosensitive film, a photocell, a photosensitive and thermal detection element or a resonant cavity resonator; And/or, the processor unit is at least used for developing, fixing, signal amplifying, transforming, correcting or encoding the converted chemical energy or electrical energy signal. 46. The multifunctional multi-colored electrochromic display screen capable of detecting ambient electromagnetic radiation according to claim 45, wherein the processor unit comprises a photographic processing device or an electronic processing device. 47. A device capable of detecting environmental electromagnetic radiation, characterized in that the device is provided with the multifunctional multi-colored electrochromic display screen capable of detecting environmental electromagnetic radiation according to any one of claims 1-46. 48. The device of claim 47, wherein the device comprises a mobile phone, a tablet computer, a home appliance or a wall. 49. A method for detecting electromagnetic radiation, characterized in that the method is mainly based on the multifunctional multi-color electrochromic display screen capable of detecting ambient electromagnetic radiation according to any one of claims 1-46 or claims 47-48 The apparatus of any one is implemented, and the method includes: Connect the working electrode and the counter electrode with the power supply to form a working circuit; A collector unit is used to collect ambient electromagnetic radiation, a detector unit is used to convert the electromagnetic radiation energy into chemical energy or electrical energy, and then a processor is used to process the converted chemical energy or electrical energy signal, calculate the electromagnetic radiation intensity, and calculate the electromagnetic radiation intensity according to the processor unit. The change of the transmitted electrical signal adjusts the light transmittance of the multi-color electrochromic structure in the multi-color electrochromic display unit to make the multi-color electrochromic structure change color; The digital display unit displays electromagnetic radiation intensity information.

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