CN112796099B - Production process of imitation Edley silk fabric - Google Patents

Production process of imitation Edley silk fabric Download PDF

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CN112796099B
CN112796099B CN202110147403.9A CN202110147403A CN112796099B CN 112796099 B CN112796099 B CN 112796099B CN 202110147403 A CN202110147403 A CN 202110147403A CN 112796099 B CN112796099 B CN 112796099B
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fabric
silk
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paper
transfer printing
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CN112796099A (en
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杨宏林
孙婉儿
项伟
刘添涛
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Zhejiang Industry Polytechnic College
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
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    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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    • D06M13/402Amides imides, sulfamic acids
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/829Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of cellulose and animalized fibres
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    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
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    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
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    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40Reduced friction resistance, lubricant properties; Sizing compositions

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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a production process of an imitation Edley silk fabric, which is characterized by comprising the following steps of: (1) preparing a fabric: the silk/viscose blended fabric is used as a base material, and the blending proportion is 20-40% of silk fiber and 60-80% of viscose fiber; (2) preparing a modified paste: firstly, preparing modified copper/polyacrylate emulsion, and secondly, preparing modified paste; (3) the transfer printing process comprises the following steps: firstly, preprocessing transfer printing paper; secondly, a fabric transfer printing process; thirdly, post-processing the fabric; the invention improves the aspects of fabric selection, printing paste configuration, printing process parameters and the like, and finally obtains the process for producing the imitation Edley silk, the produced imitation Edley silk adopts silk/viscose blended fabric, the washing fastness and the rubbing fastness of the fabric are improved without changing the original performance, and the cost of the fabric is reduced at the same time, so that the imitation Edley silk can be used as the substitute fabric of the traditional Edley silk.

Description

Production process of imitation Edley silk fabric
Technical Field
The invention relates to a production process of a fabric, in particular to a production process of an imitation Edley silk fabric.
Background
By using the method for manufacturing the Edlas silk, the national patterns are fused with the modern printing process, the performances of different types of textile fabrics are compared, and the design and the manufacture of the simulated Edlas silk fabric are carried out through reactive dye transfer printing. The imitation Edlesi silk fabric with bright color, soft hand feeling and excellent wet processing fastness is manufactured.
The idelesi silk becomes the most popular clothing for Xinjiang minority nationality women, especially for Uygur women, and the skirt made of the idelesi silk by hands almost becomes the ceremony dress of the meetings and the festivals. In Xinjiang every festival and in other festive places, the bright colored skirt of young girls and the solemn gown of old women become unsettlable wearing decorations in social etiquette occasions of people, and more free wind begins to be blended with the Edles silk element. The traditional Edela silk fabric is made of real silk as a base material, the production process is complex, the time consumption is long, the production efficiency is low, and the traditional Edela silk fabric has the defects of easy fading, easy color change and the like.
Disclosure of Invention
The invention aims to provide a production process of an imitation Edley silk fabric, and the prepared imitation Edley silk fabric has excellent air permeability, washing fastness and rubbing fastness and can replace the traditional Edley silk fabric.
The technical scheme adopted by the invention for realizing the purpose is as follows:
a production process of an imitation Edley silk fabric is characterized by comprising the following steps:
(1) configured fabric
The silk/viscose blended fabric is used as a base material, and the blending proportion is 20-40% of silk fiber and 60-80% of viscose fiber;
(2) preparation of modified paste
Preparing modified copper/polyacrylate emulsion
Uniformly mixing modified copper ultrafine powder with butyl acrylate, methyl methacrylate and an emulsifier n-hexadecane, adding sodium dodecyl sulfate and deionized water, uniformly stirring, ultrasonically dispersing in a water bath at 0-4 ℃ for 200-300 s to obtain an emulsion, putting the emulsion into a flask, heating to 60-80 ℃, adding an initiator potassium persulfate, and continuously reacting for 3-5 hours to obtain a modified copper/polyacrylate emulsion;
② preparation of modified paste
The formula is as follows:
Figure BDA0002931122100000021
the preparation method comprises the following steps: firstly, mixing trichloroacetic acid with deionized water, then slowly adding modified copper/polyacrylate emulsion, sodium alginate, guar gum, urea, sodium bicarbonate and sodium sulfate, stirring for 0.5-1 hour at 25-30 ℃ under the condition of 400-800 r/min, and standing for 3-5 hours to obtain a modified paste;
(3) transfer printing process
Pretreatment of transfer printing paper
Uniformly coating the prepared modified paste on the surface of paper, drying the paper for 10-30 min at the temperature of 60-70 ℃, and finally extruding the paper on a small padder for 1-2 times to obtain treated transfer printing paper; ink-jet printing an idelese pattern onto the surface of the transfer printing paper;
② transfer printing process for face fabric
Carrying out hot-pressing lamination on the fabric and the treated transfer printing paper by adopting a dry transfer printing process, wherein the hot-pressing pressure is 1-7 MPa, the hot-pressing temperature is 100-140 ℃, and the time is 30-60 seconds;
thirdly, post-processing of the fabric
And after the hot pressing is finished, steaming the fabric, wherein the steaming temperature is 102-105 ℃, the steaming time is 5-20 min, after the steaming is finished, the fabric is firstly rinsed in cold water, then washed for 5min in hot water containing 2g/L of neutral soap chips at 95 ℃, and finally dried for 30min at 80 ℃.
The further setting is that:
the fabric weave structure of the silk/viscose blended fabric is 6 satins.
The modified copper superfine powder is prepared by the following method: weighing 7.50g of hydrazine hydrate and 6.00g of sodium hydroxide, adding into 50mL of ethylene glycol, fully stirring, and pouring into a 250mL flask; preparing 50mL of 0.15mol/L blue vitriol solution, placing the solution in a separating funnel after ultrasonic dispersion for 150-300 s, and slowly dripping the solution into a flask at the speed of 60-80 drops per minute; and after the copper sulfate pentahydrate solution is completely dripped, putting the copper sulfate pentahydrate solution into a microwave oven, heating the copper sulfate pentahydrate solution for 60 to 100 seconds by using a medium fire under the condition of circulating water condensation, and finally cooling and freeze-drying a reaction product to obtain the modified copper ultrafine powder.
The modified paste comprises the following components in percentage by mass:
Figure BDA0002931122100000031
a production process of an imitation Edley silk fabric is characterized by comprising the following steps:
(1) selection of fabrics
The silk/viscose blended fabric is used as a base material, the blending proportion is 20 percent of silk fiber and 80 percent of viscose fiber, and the weave structure of the fabric is 6 satin weaves;
(2) preparation of modified paste
Preparing modified copper/polyacrylate emulsion
Uniformly mixing 0.6g of modified copper ultrafine powder with 10g of butyl acrylate, 10g of methyl methacrylate and 0.68g of n-hexadecane serving as an emulsifier, adding 0.4g of sodium dodecyl benzene sulfonate and 78g of deionized water, uniformly stirring, ultrasonically dispersing in a water bath at 0-4 ℃ for 200-300 s to obtain corresponding emulsion, putting the emulsion into a flask, heating to 60-80 ℃, adding 0.4g of potassium persulfate serving as an initiator, and continuously reacting for 3-5 hours to obtain modified copper/polyacrylate emulsion;
the modified copper superfine powder is prepared by the following method: weighing 7.50g of hydrazine hydrate and 6.00g of sodium hydroxide, adding into 50mL of ethylene glycol, fully stirring, and pouring into a 250mL flask; preparing 50mL of 0.15mol/L blue vitriol solution, placing the solution in a separating funnel after ultrasonic dispersion for 150-300 s, and slowly dripping the solution into a flask at the speed of 60-80 drops per minute; after the copper sulfate pentahydrate solution is completely dripped, putting the copper sulfate pentahydrate solution into a microwave oven, heating the copper sulfate pentahydrate solution for 60-100 s with medium fire under the condition of circulating water condensation, and finally cooling and freeze-drying a reaction product to obtain modified copper ultrafine powder;
② preparation of modified paste
The formula is as follows:
Figure BDA0002931122100000032
Figure BDA0002931122100000041
the preparation method comprises the following steps: firstly, mixing trichloroacetic acid with deionized water, then slowly adding modified copper/polyacrylate emulsion, sodium alginate, guar gum, urea, sodium bicarbonate and sodium sulfate, stirring for 0.5-1 hour at 25-30 ℃ under the condition of 400-800 r/min, and standing for 3-5 hours to obtain a modified paste;
(3) transfer printing process
Pretreatment of transfer printing paper
Uniformly coating the prepared modified paste on the surface of paper, drying the paper for 10-30 min at the temperature of 60-70 ℃, and finally extruding the paper on a small padder for 1-2 times to obtain the treated transfer printing paper;
the inkjet treatment of paper comprises the following steps: cutting paper to a proper size, carrying out ink-jet printing on the Edley pattern on the surface of the transfer paper by using Epson printing software, and balancing the paper for 24 hours under the conditions of 20 ℃ of temperature and 60% of humidity after printing;
② transfer printing process for face fabric
Performing hot-pressing lamination on the fabric and the treated transfer paper under certain conditions by adopting a dry transfer printing process; the hot pressing pressure is 5MPa, the hot pressing temperature is 120 ℃, and the time is 60 seconds;
thirdly, post-processing of the fabric
And after the hot pressing is finished, steaming the fabric, wherein the steaming temperature is 105 ℃, the steaming time is 20min, after the steaming is finished, the fabric is firstly rinsed in cold water for 2 times, then washed in hot water containing 2g/L neutral soap chips for 5min at 95 ℃, and finally dried for 30min at 80 ℃.
The invention has the following beneficial effects:
the invention finally obtains the process for producing the imitation Edley silk by improving the aspects of fabric selection, printing paste configuration, printing process parameters and the like.
The present invention will be further described with reference to the following embodiments.
Drawings
FIG. 1 is a structural view of the tissue of silk/viscose blended fabric used in the present invention;
FIG. 2 is an Edeles pattern used in the present invention.
Detailed Description
Example 1:
a production process of an imitation Edley silk fabric comprises the following steps:
(1) selection of fabrics
The silk/viscose blended fabric is used as a base material, and the blending proportion of the silk/viscose blended fabric is 20% of silk fiber and 80% of viscose fiber. The weave structure is 6 satins, as shown in fig. 1.
(2) Preparation of modified paste
Preparing modified copper/polyacrylate emulsion
0.6g of modified copper ultrafine powder is uniformly mixed with 10g of Butyl Acrylate (BA), 10g of Methyl Methacrylate (MMA) and 0.68g of n-Hexadecane (HD) as an emulsifier, then 0.4g of sodium dodecyl benzene sulfonate and 78g of deionized water are added, ultrasonic dispersion is carried out in a water bath at 0 ℃ for 300s after uniform stirring to obtain corresponding emulsion, the emulsion is put into a flask and heated to 70 ℃, 0.4g of potassium persulfate as an initiator is added, and then the reaction is continued for 3 hours to obtain the modified copper/polyacrylate emulsion.
The modified copper superfine powder is prepared by the following method: weighing 7.50g of hydrazine hydrate and 6.00g of sodium hydroxide, adding into 50mL of ethylene glycol, fully stirring, and pouring into a 250mL flask; 50mL of 0.15mol/L copper sulfate pentahydrate solution is prepared, placed in a separating funnel after ultrasonic dispersion for 150s, and then slowly dripped into the flask at the speed of 60 drops per minute; and after the copper sulfate pentahydrate solution is completely dripped, putting the solution into a microwave oven, heating the solution for 90s with medium fire under the condition of circulating water condensation, and finally cooling and freeze-drying the reaction product to obtain the modified copper ultrafine powder.
② preparation of modified paste
The formula (mass percent):
Figure BDA0002931122100000051
the preparation method comprises the following steps: firstly, mixing trichloroacetic acid with deionized water, then slowly adding assistants such as modified copper/polyacrylate emulsion, sodium alginate, guar gum, urea, sodium bicarbonate, sodium sulfate and the like, stirring for 1 hour at 25 ℃ under the condition of 400 r/min, and standing for 3 hours to obtain the modified paste.
(3) Transfer printing process
Pretreatment of transfer printing paper
And uniformly coating the prepared modified paste on the surface of paper, drying the paper for 20min at the temperature of 60 ℃, and finally extruding the paper for 2 times on a small padder to obtain the treated transfer printing paper.
The inkjet treatment of paper comprises the following steps: the paper was cut to a suitable size, an idelesi pattern (shown in fig. 2) was ink-jet printed onto the surface of the transfer paper using Epson printing software, and after printing, the paper was equilibrated for 24 hours at 20 ℃ and 60% humidity.
② transfer printing process for face fabric
And (3) carrying out hot-pressing lamination on the fabric and the treated transfer paper under certain conditions by adopting a dry transfer printing process. The hot pressing pressure is 5MPa, the hot pressing temperature is 120 ℃, and the time is 60 seconds.
Thirdly, post-processing of the fabric
And after the hot pressing is finished, steaming the fabric, wherein the steaming temperature is 105 ℃, the steaming time is 20min, after the steaming is finished, the fabric is firstly rinsed in cold water for 2 times, then washed in hot water containing 2g/L neutral soap chips for 5min at 95 ℃, and finally dried for 30min at 80 ℃.
And (3) product performance testing:
the process of example 1 was used to prepare different blend ratios of the silk-like edley silk fabric (with the silk/viscose blend ratio adjusted), and the fabric and the commercially available edley silk fabric were subjected to performance testing, respectively, to test the hand feel, air permeability, K/S value, color fastness to washing, and color fastness to rubbing, as shown in table 1.
TABLE 1 influence of different fabric configurations on the performance of the silk imitating Edley silk
Figure BDA0002931122100000061
Figure BDA0002931122100000071
As shown in table 1:
(1) the traditional Edela silk is silk fabric, the imitated Edela silk adopts silk/viscose blended fabric, the washing fastness and the rubbing fastness of the fabric are improved while the original performance is not changed, the cost of the fabric is reduced, and the fabric can be used as a substitute fabric of the traditional Edela silk.
(2) The proportion of the silk/viscose blended fabric has certain influence on the performance of the prepared imitation Edley silk, and the K/S value and the air permeability of the fabric are slightly reduced along with the increase of the content of the silk.
Example 2
The process of example 1 was used with the difference that: the content of the modified copper/polyacrylate emulsion and the guar gum was adjusted and the effect on the performance of the silk fabric like edley silk was tested, as shown in table 2.
TABLE 2 influence of modified copper/polyacrylate emulsion and guar gum content on the performance of the Idely silk-like fabrics
Figure BDA0002931122100000072
As shown in table 2:
the modified copper/polyacrylate emulsion has certain influence on the performance of the fabric, and after the modified copper/polyacrylate emulsion is added into the modified paste, the K/S value, the color fastness to washing and the color fastness to rubbing of the fabric are obviously improved.
Example 3
The process of example 1 was used with the difference that: the amounts of urea and sodium bicarbonate were adjusted and tested for their effect on the performance of the simulated edley silk fabric, as shown in table 3.
TABLE 3 Effect of Urea and sodium bicarbonate dosage on the Properties of the simulated Edley silk Fabric
Figure BDA0002931122100000081
As shown in table 3:
the urea has the functions of absorbing moisture and assisting dissolution, and the sodium bicarbonate is favorable for fixing the color of the dye. With the increase of the using amount of the sodium bicarbonate and the urea, the K/S value, the color fastness to washing and the color fastness to rubbing of the fabric are improved.
Example 4
The process of example 1 was used with the difference that: the steaming temperature and steaming time were adjusted and the effect on the properties of the imitation edley silk fabric was tested as shown in table 4.
TABLE 4 influence of steaming temperature and steaming time on the performance of the Idely silk-like fabric
Figure BDA0002931122100000082
As shown in table 4:
the steaming temperature and the steaming time have certain influence on the K/S value and the wet treatment fastness of the silk fabric imitating the Edley silk, and the K/S value, the color fastness to washing and the color fastness to rubbing of the fabric are improved to a certain extent along with the rising of the steaming temperature and the prolonging of the steaming time.
To summarize:
as can be seen from examples 1-4 and tables 1-4, the optimum process parameters were identified as follows:
(1) fabric preparation:
the silk/viscose blended fabric is used as a base material, and the blending proportion of the silk/viscose blended fabric is 20% of silk fiber and 80% of viscose fiber.
(2) The formula of the modified paste comprises the following components:
Figure BDA0002931122100000091
(3) and (3) steaming treatment process:
steaming at 105 deg.C for 20min, rinsing the steamed material in cold water for 2 times, washing in hot water containing 2g/L neutral soap flakes at 95 deg.C for 5min, and oven drying at 80 deg.C for 30 min.

Claims (4)

1. A production process of an imitation Edley silk fabric is characterized by comprising the following steps:
(1) configured fabric
The silk/viscose blended fabric is used as a base material, and the blending proportion is 20-40% of silk fiber and 60-80% of viscose fiber;
(2) preparation of modified paste
Preparing modified copper/polyacrylate emulsion
Uniformly mixing modified copper ultrafine powder with butyl acrylate, methyl methacrylate and an emulsifier n-hexadecane, adding sodium dodecyl sulfate and deionized water, uniformly stirring, ultrasonically dispersing in a water bath at 0-4 ℃ for 200-300 s to obtain an emulsion, putting the emulsion into a flask, heating to 60-80 ℃, adding an initiator potassium persulfate, and continuously reacting for 3-5 hours to obtain a modified copper/polyacrylate emulsion;
② preparation of modified paste
The modified paste comprises the following components in percentage by mass:
modified copper/polyacrylate emulsion 10%
Sodium alginate 3%
Guar gum 3%
6 percent of urea
Sodium bicarbonate 5%
Sodium sulfate 4%
Trichloroacetic acid 3%
The balance of deionized water;
the preparation method comprises the following steps: firstly, mixing trichloroacetic acid with deionized water, then slowly adding modified copper/polyacrylate emulsion, sodium alginate, guar gum, urea, sodium bicarbonate and sodium sulfate, stirring for 0.5-1 hour at 25-30 ℃ under the condition of 400-800 r/min, and standing for 3-5 hours to obtain a modified paste;
(3) transfer printing process
Pretreatment of transfer printing paper
Uniformly coating the prepared modified paste on the surface of paper, drying the paper for 10-30 min at the temperature of 60-70 ℃, and finally extruding the paper on a small padder for 1-2 times to obtain treated transfer printing paper; ink-jet printing an Edelais pattern on the surface of the transfer printing paper;
② transfer printing process for face fabric
Carrying out hot-pressing lamination on the fabric and the treated transfer printing paper by adopting a dry transfer printing process, wherein the hot-pressing pressure is 1-7 MPa, the hot-pressing temperature is 100-140 ℃, and the time is 30-60 seconds;
thirdly, post-processing of the fabric
And after the hot pressing is finished, steaming the fabric, wherein the steaming temperature is 102-105 ℃, the steaming time is 5-20 min, after the steaming is finished, the fabric is firstly rinsed in cold water, then washed in hot water for 3-5 min, and finally dried for 10-30 min at the temperature of 80 ℃.
2. The process for producing the imitation edleshi silk fabric according to claim 1, wherein the process comprises the following steps: the fabric weave structure of the silk/viscose blended fabric is 6 satins.
3. The process for producing the imitation edleshi silk fabric according to claim 1, wherein the process comprises the following steps: the modified copper ultrafine powder is prepared by the following method: weighing 7.50g of hydrazine hydrate and 6.00g of sodium hydroxide, adding into 50mL of ethylene glycol, fully stirring, and pouring into a 250mL flask; preparing 50mL of 0.15mol/L blue vitriol solution, placing the solution in a separating funnel after ultrasonic dispersion for 150-300 s, and slowly dripping the solution into a flask at the speed of 60-80 drops per minute; and after the copper sulfate pentahydrate solution is completely dripped, putting the solution into a microwave oven, heating the solution for 60-100 s with medium fire under the condition of circulating water condensation, and finally cooling and freeze-drying the reaction product to obtain the modified copper ultrafine powder.
4. The production process of the imitation Edrley silk fabric according to claim 1, characterized by comprising the following steps:
(1) selection of fabrics
The silk/viscose blended fabric is used as a base material, the blending proportion is 20 percent of silk fiber and 80 percent of viscose fiber, and the weave structure of the fabric is 6 satin weaves;
(2) preparation of modified paste
Preparing modified copper/polyacrylate emulsion
Uniformly mixing 0.6g of modified copper ultrafine powder with 10g of butyl acrylate, 10g of methyl methacrylate and 0.68g of n-hexadecane serving as an emulsifier, adding 0.4g of sodium dodecyl benzene sulfonate and 78g of deionized water, uniformly stirring, ultrasonically dispersing in a water bath at 0-4 ℃ for 200-300 s to obtain corresponding emulsion, putting the emulsion into a flask, heating to 60-80 ℃, adding 0.4g of potassium persulfate serving as an initiator, and continuously reacting for 3-5 hours to obtain modified copper/polyacrylate emulsion;
the modified copper superfine powder is prepared by the following method: weighing 7.50g of hydrazine hydrate and 6.00g of sodium hydroxide, adding into 50mL of ethylene glycol, fully stirring, and pouring into a 250mL flask; preparing 50mL of 0.15mol/L blue vitriol solution, placing the solution in a separating funnel after ultrasonic dispersion for 150-300 s, and slowly dripping the solution into a flask at the speed of 60-80 drops per minute; after the copper sulfate pentahydrate solution is completely dripped, putting the copper sulfate pentahydrate solution into a microwave oven, heating the copper sulfate pentahydrate solution for 60-100 s with medium fire under the condition of circulating water condensation, and finally cooling and freeze-drying a reaction product to obtain modified copper ultrafine powder;
② preparation of modified paste
The formula is as follows:
modified copper/polyacrylate emulsion 10%
Sodium alginate 3%
Guar gum 3%
6 percent of urea
Sodium bicarbonate 5%
Sodium sulfate 4%
Trichloroacetic acid 3%
The balance of deionized water;
the preparation method comprises the following steps: firstly, mixing trichloroacetic acid with deionized water, then slowly adding modified copper/polyacrylate emulsion, sodium alginate, guar gum, urea, sodium bicarbonate and sodium sulfate, stirring for 0.5-1 hour at 25-30 ℃ under the condition of 400-800 r/min, and standing for 3-5 hours to obtain a modified paste;
(3) transfer printing process
Pretreatment of transfer printing paper
Uniformly coating the prepared modified paste on the surface of paper, drying the paper for 10-30 min at 60-70 ℃, and finally extruding the paper on a small padder for 1-2 times to obtain treated transfer printing paper;
the inkjet treatment of paper comprises the following steps: cutting paper to a proper size, carrying out ink-jet printing on the Edles pattern on the surface of the transfer paper by using Epson printing software, and balancing the paper for 24 hours at the temperature of 20 ℃ and the humidity of 60 percent after printing;
② transfer printing process for face fabric
Performing hot-pressing lamination on the fabric and the treated transfer paper under certain conditions by adopting a dry transfer printing process; the hot pressing pressure is 5MPa, the hot pressing temperature is 120 ℃, and the time is 60 seconds;
thirdly, post-processing of the fabric
And after the hot pressing is finished, steaming the fabric, wherein the steaming temperature is 105 ℃, the steaming time is 20min, after the steaming is finished, the fabric is firstly rinsed in cold water for 2 times, then washed in hot water containing 2g/L neutral soap chips for 5min at 95 ℃, and finally dried for 30min at 80 ℃.
CN202110147403.9A 2021-02-03 2021-02-03 Production process of imitation Edley silk fabric Active CN112796099B (en)

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Publication number Priority date Publication date Assignee Title
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CN108914657A (en) * 2018-07-19 2018-11-30 苏州大学 The method for improving silk PRINTED FABRIC printing performance
CN112080954A (en) * 2020-09-17 2020-12-15 南通纺织丝绸产业技术研究院 Dry heat transfer printing process for polyester blended fabric

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CN108914657A (en) * 2018-07-19 2018-11-30 苏州大学 The method for improving silk PRINTED FABRIC printing performance
CN112080954A (en) * 2020-09-17 2020-12-15 南通纺织丝绸产业技术研究院 Dry heat transfer printing process for polyester blended fabric

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