CN112796099B - Production process of imitation Edley silk fabric - Google Patents
Production process of imitation Edley silk fabric Download PDFInfo
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- CN112796099B CN112796099B CN202110147403.9A CN202110147403A CN112796099B CN 112796099 B CN112796099 B CN 112796099B CN 202110147403 A CN202110147403 A CN 202110147403A CN 112796099 B CN112796099 B CN 112796099B
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- 239000004744 fabric Substances 0.000 title claims abstract description 99
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 38
- 150000001879 copper Chemical class 0.000 claims abstract description 37
- 238000010023 transfer printing Methods 0.000 claims abstract description 33
- 239000000839 emulsion Substances 0.000 claims abstract description 32
- 229920000297 Rayon Polymers 0.000 claims abstract description 23
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 22
- 238000002156 mixing Methods 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 9
- 238000007639 printing Methods 0.000 claims abstract description 8
- 238000012805 post-processing Methods 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- 238000010025 steaming Methods 0.000 claims description 30
- 238000007731 hot pressing Methods 0.000 claims description 20
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 16
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims description 12
- 229920002907 Guar gum Polymers 0.000 claims description 9
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 9
- 239000004202 carbamide Substances 0.000 claims description 9
- 235000013877 carbamide Nutrition 0.000 claims description 9
- 235000010417 guar gum Nutrition 0.000 claims description 9
- 239000000665 guar gum Substances 0.000 claims description 9
- 229960002154 guar gum Drugs 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 229940045136 urea Drugs 0.000 claims description 9
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 8
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 8
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 7
- 235000010413 sodium alginate Nutrition 0.000 claims description 7
- 239000000661 sodium alginate Substances 0.000 claims description 7
- 229940005550 sodium alginate Drugs 0.000 claims description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims description 7
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 claims description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 6
- 238000012546 transfer Methods 0.000 claims description 6
- 238000001132 ultrasonic dispersion Methods 0.000 claims description 6
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 5
- 230000005494 condensation Effects 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 238000004108 freeze drying Methods 0.000 claims description 5
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 238000003475 lamination Methods 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- 229960003010 sodium sulfate Drugs 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 229910000366 copper(II) sulfate Inorganic materials 0.000 claims description 4
- 238000007641 inkjet printing Methods 0.000 claims description 4
- 229960001407 sodium bicarbonate Drugs 0.000 claims description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- SJADIPTXQLOCGP-UHFFFAOYSA-M sodium;hydrogen carbonate;urea Chemical compound [Na+].NC(N)=O.OC([O-])=O SJADIPTXQLOCGP-UHFFFAOYSA-M 0.000 claims 2
- 238000005406 washing Methods 0.000 abstract description 8
- 238000007781 pre-processing Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 4
- 230000035699 permeability Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Images
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
- D06M13/21—Halogenated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/829—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of cellulose and animalized fibres
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
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- Engineering & Computer Science (AREA)
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- Chemical & Material Sciences (AREA)
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Abstract
The invention discloses a production process of an imitation Edley silk fabric, which is characterized by comprising the following steps of: (1) preparing a fabric: the silk/viscose blended fabric is used as a base material, and the blending proportion is 20-40% of silk fiber and 60-80% of viscose fiber; (2) preparing a modified paste: firstly, preparing modified copper/polyacrylate emulsion, and secondly, preparing modified paste; (3) the transfer printing process comprises the following steps: firstly, preprocessing transfer printing paper; secondly, a fabric transfer printing process; thirdly, post-processing the fabric; the invention improves the aspects of fabric selection, printing paste configuration, printing process parameters and the like, and finally obtains the process for producing the imitation Edley silk, the produced imitation Edley silk adopts silk/viscose blended fabric, the washing fastness and the rubbing fastness of the fabric are improved without changing the original performance, and the cost of the fabric is reduced at the same time, so that the imitation Edley silk can be used as the substitute fabric of the traditional Edley silk.
Description
Technical Field
The invention relates to a production process of a fabric, in particular to a production process of an imitation Edley silk fabric.
Background
By using the method for manufacturing the Edlas silk, the national patterns are fused with the modern printing process, the performances of different types of textile fabrics are compared, and the design and the manufacture of the simulated Edlas silk fabric are carried out through reactive dye transfer printing. The imitation Edlesi silk fabric with bright color, soft hand feeling and excellent wet processing fastness is manufactured.
The idelesi silk becomes the most popular clothing for Xinjiang minority nationality women, especially for Uygur women, and the skirt made of the idelesi silk by hands almost becomes the ceremony dress of the meetings and the festivals. In Xinjiang every festival and in other festive places, the bright colored skirt of young girls and the solemn gown of old women become unsettlable wearing decorations in social etiquette occasions of people, and more free wind begins to be blended with the Edles silk element. The traditional Edela silk fabric is made of real silk as a base material, the production process is complex, the time consumption is long, the production efficiency is low, and the traditional Edela silk fabric has the defects of easy fading, easy color change and the like.
Disclosure of Invention
The invention aims to provide a production process of an imitation Edley silk fabric, and the prepared imitation Edley silk fabric has excellent air permeability, washing fastness and rubbing fastness and can replace the traditional Edley silk fabric.
The technical scheme adopted by the invention for realizing the purpose is as follows:
a production process of an imitation Edley silk fabric is characterized by comprising the following steps:
(1) configured fabric
The silk/viscose blended fabric is used as a base material, and the blending proportion is 20-40% of silk fiber and 60-80% of viscose fiber;
(2) preparation of modified paste
Preparing modified copper/polyacrylate emulsion
Uniformly mixing modified copper ultrafine powder with butyl acrylate, methyl methacrylate and an emulsifier n-hexadecane, adding sodium dodecyl sulfate and deionized water, uniformly stirring, ultrasonically dispersing in a water bath at 0-4 ℃ for 200-300 s to obtain an emulsion, putting the emulsion into a flask, heating to 60-80 ℃, adding an initiator potassium persulfate, and continuously reacting for 3-5 hours to obtain a modified copper/polyacrylate emulsion;
② preparation of modified paste
The formula is as follows:
the preparation method comprises the following steps: firstly, mixing trichloroacetic acid with deionized water, then slowly adding modified copper/polyacrylate emulsion, sodium alginate, guar gum, urea, sodium bicarbonate and sodium sulfate, stirring for 0.5-1 hour at 25-30 ℃ under the condition of 400-800 r/min, and standing for 3-5 hours to obtain a modified paste;
(3) transfer printing process
Pretreatment of transfer printing paper
Uniformly coating the prepared modified paste on the surface of paper, drying the paper for 10-30 min at the temperature of 60-70 ℃, and finally extruding the paper on a small padder for 1-2 times to obtain treated transfer printing paper; ink-jet printing an idelese pattern onto the surface of the transfer printing paper;
② transfer printing process for face fabric
Carrying out hot-pressing lamination on the fabric and the treated transfer printing paper by adopting a dry transfer printing process, wherein the hot-pressing pressure is 1-7 MPa, the hot-pressing temperature is 100-140 ℃, and the time is 30-60 seconds;
thirdly, post-processing of the fabric
And after the hot pressing is finished, steaming the fabric, wherein the steaming temperature is 102-105 ℃, the steaming time is 5-20 min, after the steaming is finished, the fabric is firstly rinsed in cold water, then washed for 5min in hot water containing 2g/L of neutral soap chips at 95 ℃, and finally dried for 30min at 80 ℃.
The further setting is that:
the fabric weave structure of the silk/viscose blended fabric is 6 satins.
The modified copper superfine powder is prepared by the following method: weighing 7.50g of hydrazine hydrate and 6.00g of sodium hydroxide, adding into 50mL of ethylene glycol, fully stirring, and pouring into a 250mL flask; preparing 50mL of 0.15mol/L blue vitriol solution, placing the solution in a separating funnel after ultrasonic dispersion for 150-300 s, and slowly dripping the solution into a flask at the speed of 60-80 drops per minute; and after the copper sulfate pentahydrate solution is completely dripped, putting the copper sulfate pentahydrate solution into a microwave oven, heating the copper sulfate pentahydrate solution for 60 to 100 seconds by using a medium fire under the condition of circulating water condensation, and finally cooling and freeze-drying a reaction product to obtain the modified copper ultrafine powder.
The modified paste comprises the following components in percentage by mass:
a production process of an imitation Edley silk fabric is characterized by comprising the following steps:
(1) selection of fabrics
The silk/viscose blended fabric is used as a base material, the blending proportion is 20 percent of silk fiber and 80 percent of viscose fiber, and the weave structure of the fabric is 6 satin weaves;
(2) preparation of modified paste
Preparing modified copper/polyacrylate emulsion
Uniformly mixing 0.6g of modified copper ultrafine powder with 10g of butyl acrylate, 10g of methyl methacrylate and 0.68g of n-hexadecane serving as an emulsifier, adding 0.4g of sodium dodecyl benzene sulfonate and 78g of deionized water, uniformly stirring, ultrasonically dispersing in a water bath at 0-4 ℃ for 200-300 s to obtain corresponding emulsion, putting the emulsion into a flask, heating to 60-80 ℃, adding 0.4g of potassium persulfate serving as an initiator, and continuously reacting for 3-5 hours to obtain modified copper/polyacrylate emulsion;
the modified copper superfine powder is prepared by the following method: weighing 7.50g of hydrazine hydrate and 6.00g of sodium hydroxide, adding into 50mL of ethylene glycol, fully stirring, and pouring into a 250mL flask; preparing 50mL of 0.15mol/L blue vitriol solution, placing the solution in a separating funnel after ultrasonic dispersion for 150-300 s, and slowly dripping the solution into a flask at the speed of 60-80 drops per minute; after the copper sulfate pentahydrate solution is completely dripped, putting the copper sulfate pentahydrate solution into a microwave oven, heating the copper sulfate pentahydrate solution for 60-100 s with medium fire under the condition of circulating water condensation, and finally cooling and freeze-drying a reaction product to obtain modified copper ultrafine powder;
② preparation of modified paste
The formula is as follows:
the preparation method comprises the following steps: firstly, mixing trichloroacetic acid with deionized water, then slowly adding modified copper/polyacrylate emulsion, sodium alginate, guar gum, urea, sodium bicarbonate and sodium sulfate, stirring for 0.5-1 hour at 25-30 ℃ under the condition of 400-800 r/min, and standing for 3-5 hours to obtain a modified paste;
(3) transfer printing process
Pretreatment of transfer printing paper
Uniformly coating the prepared modified paste on the surface of paper, drying the paper for 10-30 min at the temperature of 60-70 ℃, and finally extruding the paper on a small padder for 1-2 times to obtain the treated transfer printing paper;
the inkjet treatment of paper comprises the following steps: cutting paper to a proper size, carrying out ink-jet printing on the Edley pattern on the surface of the transfer paper by using Epson printing software, and balancing the paper for 24 hours under the conditions of 20 ℃ of temperature and 60% of humidity after printing;
② transfer printing process for face fabric
Performing hot-pressing lamination on the fabric and the treated transfer paper under certain conditions by adopting a dry transfer printing process; the hot pressing pressure is 5MPa, the hot pressing temperature is 120 ℃, and the time is 60 seconds;
thirdly, post-processing of the fabric
And after the hot pressing is finished, steaming the fabric, wherein the steaming temperature is 105 ℃, the steaming time is 20min, after the steaming is finished, the fabric is firstly rinsed in cold water for 2 times, then washed in hot water containing 2g/L neutral soap chips for 5min at 95 ℃, and finally dried for 30min at 80 ℃.
The invention has the following beneficial effects:
the invention finally obtains the process for producing the imitation Edley silk by improving the aspects of fabric selection, printing paste configuration, printing process parameters and the like.
The present invention will be further described with reference to the following embodiments.
Drawings
FIG. 1 is a structural view of the tissue of silk/viscose blended fabric used in the present invention;
FIG. 2 is an Edeles pattern used in the present invention.
Detailed Description
Example 1:
a production process of an imitation Edley silk fabric comprises the following steps:
(1) selection of fabrics
The silk/viscose blended fabric is used as a base material, and the blending proportion of the silk/viscose blended fabric is 20% of silk fiber and 80% of viscose fiber. The weave structure is 6 satins, as shown in fig. 1.
(2) Preparation of modified paste
Preparing modified copper/polyacrylate emulsion
0.6g of modified copper ultrafine powder is uniformly mixed with 10g of Butyl Acrylate (BA), 10g of Methyl Methacrylate (MMA) and 0.68g of n-Hexadecane (HD) as an emulsifier, then 0.4g of sodium dodecyl benzene sulfonate and 78g of deionized water are added, ultrasonic dispersion is carried out in a water bath at 0 ℃ for 300s after uniform stirring to obtain corresponding emulsion, the emulsion is put into a flask and heated to 70 ℃, 0.4g of potassium persulfate as an initiator is added, and then the reaction is continued for 3 hours to obtain the modified copper/polyacrylate emulsion.
The modified copper superfine powder is prepared by the following method: weighing 7.50g of hydrazine hydrate and 6.00g of sodium hydroxide, adding into 50mL of ethylene glycol, fully stirring, and pouring into a 250mL flask; 50mL of 0.15mol/L copper sulfate pentahydrate solution is prepared, placed in a separating funnel after ultrasonic dispersion for 150s, and then slowly dripped into the flask at the speed of 60 drops per minute; and after the copper sulfate pentahydrate solution is completely dripped, putting the solution into a microwave oven, heating the solution for 90s with medium fire under the condition of circulating water condensation, and finally cooling and freeze-drying the reaction product to obtain the modified copper ultrafine powder.
② preparation of modified paste
The formula (mass percent):
the preparation method comprises the following steps: firstly, mixing trichloroacetic acid with deionized water, then slowly adding assistants such as modified copper/polyacrylate emulsion, sodium alginate, guar gum, urea, sodium bicarbonate, sodium sulfate and the like, stirring for 1 hour at 25 ℃ under the condition of 400 r/min, and standing for 3 hours to obtain the modified paste.
(3) Transfer printing process
Pretreatment of transfer printing paper
And uniformly coating the prepared modified paste on the surface of paper, drying the paper for 20min at the temperature of 60 ℃, and finally extruding the paper for 2 times on a small padder to obtain the treated transfer printing paper.
The inkjet treatment of paper comprises the following steps: the paper was cut to a suitable size, an idelesi pattern (shown in fig. 2) was ink-jet printed onto the surface of the transfer paper using Epson printing software, and after printing, the paper was equilibrated for 24 hours at 20 ℃ and 60% humidity.
② transfer printing process for face fabric
And (3) carrying out hot-pressing lamination on the fabric and the treated transfer paper under certain conditions by adopting a dry transfer printing process. The hot pressing pressure is 5MPa, the hot pressing temperature is 120 ℃, and the time is 60 seconds.
Thirdly, post-processing of the fabric
And after the hot pressing is finished, steaming the fabric, wherein the steaming temperature is 105 ℃, the steaming time is 20min, after the steaming is finished, the fabric is firstly rinsed in cold water for 2 times, then washed in hot water containing 2g/L neutral soap chips for 5min at 95 ℃, and finally dried for 30min at 80 ℃.
And (3) product performance testing:
the process of example 1 was used to prepare different blend ratios of the silk-like edley silk fabric (with the silk/viscose blend ratio adjusted), and the fabric and the commercially available edley silk fabric were subjected to performance testing, respectively, to test the hand feel, air permeability, K/S value, color fastness to washing, and color fastness to rubbing, as shown in table 1.
TABLE 1 influence of different fabric configurations on the performance of the silk imitating Edley silk
As shown in table 1:
(1) the traditional Edela silk is silk fabric, the imitated Edela silk adopts silk/viscose blended fabric, the washing fastness and the rubbing fastness of the fabric are improved while the original performance is not changed, the cost of the fabric is reduced, and the fabric can be used as a substitute fabric of the traditional Edela silk.
(2) The proportion of the silk/viscose blended fabric has certain influence on the performance of the prepared imitation Edley silk, and the K/S value and the air permeability of the fabric are slightly reduced along with the increase of the content of the silk.
Example 2
The process of example 1 was used with the difference that: the content of the modified copper/polyacrylate emulsion and the guar gum was adjusted and the effect on the performance of the silk fabric like edley silk was tested, as shown in table 2.
TABLE 2 influence of modified copper/polyacrylate emulsion and guar gum content on the performance of the Idely silk-like fabrics
As shown in table 2:
the modified copper/polyacrylate emulsion has certain influence on the performance of the fabric, and after the modified copper/polyacrylate emulsion is added into the modified paste, the K/S value, the color fastness to washing and the color fastness to rubbing of the fabric are obviously improved.
Example 3
The process of example 1 was used with the difference that: the amounts of urea and sodium bicarbonate were adjusted and tested for their effect on the performance of the simulated edley silk fabric, as shown in table 3.
TABLE 3 Effect of Urea and sodium bicarbonate dosage on the Properties of the simulated Edley silk Fabric
As shown in table 3:
the urea has the functions of absorbing moisture and assisting dissolution, and the sodium bicarbonate is favorable for fixing the color of the dye. With the increase of the using amount of the sodium bicarbonate and the urea, the K/S value, the color fastness to washing and the color fastness to rubbing of the fabric are improved.
Example 4
The process of example 1 was used with the difference that: the steaming temperature and steaming time were adjusted and the effect on the properties of the imitation edley silk fabric was tested as shown in table 4.
TABLE 4 influence of steaming temperature and steaming time on the performance of the Idely silk-like fabric
As shown in table 4:
the steaming temperature and the steaming time have certain influence on the K/S value and the wet treatment fastness of the silk fabric imitating the Edley silk, and the K/S value, the color fastness to washing and the color fastness to rubbing of the fabric are improved to a certain extent along with the rising of the steaming temperature and the prolonging of the steaming time.
To summarize:
as can be seen from examples 1-4 and tables 1-4, the optimum process parameters were identified as follows:
(1) fabric preparation:
the silk/viscose blended fabric is used as a base material, and the blending proportion of the silk/viscose blended fabric is 20% of silk fiber and 80% of viscose fiber.
(2) The formula of the modified paste comprises the following components:
(3) and (3) steaming treatment process:
steaming at 105 deg.C for 20min, rinsing the steamed material in cold water for 2 times, washing in hot water containing 2g/L neutral soap flakes at 95 deg.C for 5min, and oven drying at 80 deg.C for 30 min.
Claims (4)
1. A production process of an imitation Edley silk fabric is characterized by comprising the following steps:
(1) configured fabric
The silk/viscose blended fabric is used as a base material, and the blending proportion is 20-40% of silk fiber and 60-80% of viscose fiber;
(2) preparation of modified paste
Preparing modified copper/polyacrylate emulsion
Uniformly mixing modified copper ultrafine powder with butyl acrylate, methyl methacrylate and an emulsifier n-hexadecane, adding sodium dodecyl sulfate and deionized water, uniformly stirring, ultrasonically dispersing in a water bath at 0-4 ℃ for 200-300 s to obtain an emulsion, putting the emulsion into a flask, heating to 60-80 ℃, adding an initiator potassium persulfate, and continuously reacting for 3-5 hours to obtain a modified copper/polyacrylate emulsion;
② preparation of modified paste
The modified paste comprises the following components in percentage by mass:
modified copper/polyacrylate emulsion 10%
Sodium alginate 3%
Guar gum 3%
6 percent of urea
Sodium bicarbonate 5%
Sodium sulfate 4%
Trichloroacetic acid 3%
The balance of deionized water;
the preparation method comprises the following steps: firstly, mixing trichloroacetic acid with deionized water, then slowly adding modified copper/polyacrylate emulsion, sodium alginate, guar gum, urea, sodium bicarbonate and sodium sulfate, stirring for 0.5-1 hour at 25-30 ℃ under the condition of 400-800 r/min, and standing for 3-5 hours to obtain a modified paste;
(3) transfer printing process
Pretreatment of transfer printing paper
Uniformly coating the prepared modified paste on the surface of paper, drying the paper for 10-30 min at the temperature of 60-70 ℃, and finally extruding the paper on a small padder for 1-2 times to obtain treated transfer printing paper; ink-jet printing an Edelais pattern on the surface of the transfer printing paper;
② transfer printing process for face fabric
Carrying out hot-pressing lamination on the fabric and the treated transfer printing paper by adopting a dry transfer printing process, wherein the hot-pressing pressure is 1-7 MPa, the hot-pressing temperature is 100-140 ℃, and the time is 30-60 seconds;
thirdly, post-processing of the fabric
And after the hot pressing is finished, steaming the fabric, wherein the steaming temperature is 102-105 ℃, the steaming time is 5-20 min, after the steaming is finished, the fabric is firstly rinsed in cold water, then washed in hot water for 3-5 min, and finally dried for 10-30 min at the temperature of 80 ℃.
2. The process for producing the imitation edleshi silk fabric according to claim 1, wherein the process comprises the following steps: the fabric weave structure of the silk/viscose blended fabric is 6 satins.
3. The process for producing the imitation edleshi silk fabric according to claim 1, wherein the process comprises the following steps: the modified copper ultrafine powder is prepared by the following method: weighing 7.50g of hydrazine hydrate and 6.00g of sodium hydroxide, adding into 50mL of ethylene glycol, fully stirring, and pouring into a 250mL flask; preparing 50mL of 0.15mol/L blue vitriol solution, placing the solution in a separating funnel after ultrasonic dispersion for 150-300 s, and slowly dripping the solution into a flask at the speed of 60-80 drops per minute; and after the copper sulfate pentahydrate solution is completely dripped, putting the solution into a microwave oven, heating the solution for 60-100 s with medium fire under the condition of circulating water condensation, and finally cooling and freeze-drying the reaction product to obtain the modified copper ultrafine powder.
4. The production process of the imitation Edrley silk fabric according to claim 1, characterized by comprising the following steps:
(1) selection of fabrics
The silk/viscose blended fabric is used as a base material, the blending proportion is 20 percent of silk fiber and 80 percent of viscose fiber, and the weave structure of the fabric is 6 satin weaves;
(2) preparation of modified paste
Preparing modified copper/polyacrylate emulsion
Uniformly mixing 0.6g of modified copper ultrafine powder with 10g of butyl acrylate, 10g of methyl methacrylate and 0.68g of n-hexadecane serving as an emulsifier, adding 0.4g of sodium dodecyl benzene sulfonate and 78g of deionized water, uniformly stirring, ultrasonically dispersing in a water bath at 0-4 ℃ for 200-300 s to obtain corresponding emulsion, putting the emulsion into a flask, heating to 60-80 ℃, adding 0.4g of potassium persulfate serving as an initiator, and continuously reacting for 3-5 hours to obtain modified copper/polyacrylate emulsion;
the modified copper superfine powder is prepared by the following method: weighing 7.50g of hydrazine hydrate and 6.00g of sodium hydroxide, adding into 50mL of ethylene glycol, fully stirring, and pouring into a 250mL flask; preparing 50mL of 0.15mol/L blue vitriol solution, placing the solution in a separating funnel after ultrasonic dispersion for 150-300 s, and slowly dripping the solution into a flask at the speed of 60-80 drops per minute; after the copper sulfate pentahydrate solution is completely dripped, putting the copper sulfate pentahydrate solution into a microwave oven, heating the copper sulfate pentahydrate solution for 60-100 s with medium fire under the condition of circulating water condensation, and finally cooling and freeze-drying a reaction product to obtain modified copper ultrafine powder;
② preparation of modified paste
The formula is as follows:
modified copper/polyacrylate emulsion 10%
Sodium alginate 3%
Guar gum 3%
6 percent of urea
Sodium bicarbonate 5%
Sodium sulfate 4%
Trichloroacetic acid 3%
The balance of deionized water;
the preparation method comprises the following steps: firstly, mixing trichloroacetic acid with deionized water, then slowly adding modified copper/polyacrylate emulsion, sodium alginate, guar gum, urea, sodium bicarbonate and sodium sulfate, stirring for 0.5-1 hour at 25-30 ℃ under the condition of 400-800 r/min, and standing for 3-5 hours to obtain a modified paste;
(3) transfer printing process
Pretreatment of transfer printing paper
Uniformly coating the prepared modified paste on the surface of paper, drying the paper for 10-30 min at 60-70 ℃, and finally extruding the paper on a small padder for 1-2 times to obtain treated transfer printing paper;
the inkjet treatment of paper comprises the following steps: cutting paper to a proper size, carrying out ink-jet printing on the Edles pattern on the surface of the transfer paper by using Epson printing software, and balancing the paper for 24 hours at the temperature of 20 ℃ and the humidity of 60 percent after printing;
② transfer printing process for face fabric
Performing hot-pressing lamination on the fabric and the treated transfer paper under certain conditions by adopting a dry transfer printing process; the hot pressing pressure is 5MPa, the hot pressing temperature is 120 ℃, and the time is 60 seconds;
thirdly, post-processing of the fabric
And after the hot pressing is finished, steaming the fabric, wherein the steaming temperature is 105 ℃, the steaming time is 20min, after the steaming is finished, the fabric is firstly rinsed in cold water for 2 times, then washed in hot water containing 2g/L neutral soap chips for 5min at 95 ℃, and finally dried for 30min at 80 ℃.
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CN103774469A (en) * | 2013-12-06 | 2014-05-07 | 苏州大学 | Dry-type transfer-printed textile and preparation method thereof |
CN108914657A (en) * | 2018-07-19 | 2018-11-30 | 苏州大学 | The method for improving silk PRINTED FABRIC printing performance |
CN112080954A (en) * | 2020-09-17 | 2020-12-15 | 南通纺织丝绸产业技术研究院 | Dry heat transfer printing process for polyester blended fabric |
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CN103774469A (en) * | 2013-12-06 | 2014-05-07 | 苏州大学 | Dry-type transfer-printed textile and preparation method thereof |
CN108914657A (en) * | 2018-07-19 | 2018-11-30 | 苏州大学 | The method for improving silk PRINTED FABRIC printing performance |
CN112080954A (en) * | 2020-09-17 | 2020-12-15 | 南通纺织丝绸产业技术研究院 | Dry heat transfer printing process for polyester blended fabric |
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