CN112795776A - Method for co-processing waste incineration fly ash and copper-containing sludge - Google Patents
Method for co-processing waste incineration fly ash and copper-containing sludge Download PDFInfo
- Publication number
- CN112795776A CN112795776A CN202011567386.6A CN202011567386A CN112795776A CN 112795776 A CN112795776 A CN 112795776A CN 202011567386 A CN202011567386 A CN 202011567386A CN 112795776 A CN112795776 A CN 112795776A
- Authority
- CN
- China
- Prior art keywords
- copper
- content
- fly ash
- slag
- flue gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
- C22B1/2406—Binding; Briquetting ; Granulating pelletizing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/023—Fired or melted materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/0028—Smelting or converting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
- C22B7/002—Dry processes by treating with halogens, sulfur or compounds thereof; by carburising, by treating with hydrogen (hydriding)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
The invention relates to a method for the cooperative treatment of waste incineration fly ash and copper-containing sludge, which comprises the steps of uniformly mixing the waste incineration fly ash and the copper-containing sludge, pelletizing to obtain a pellet material; then mixing the ball material, the fluxing agent and the fuel to obtain a mixture; then smelting to obtain molten slag and flue gas; when the ball material is a high-chlorine material, performing water quenching on the molten slag to obtain vitreous body tailings; collecting soot in the flue gas, sequentially carrying out water washing and solid-liquid separation on the soot to obtain supernatant, and adding alkali into the supernatant to obtain a precipitate rich in copper and nickel; and when the ball material is a low-chlorine material, carrying out dilution treatment on the molten slag to obtain a slag phase and copper matte, and then carrying out water quenching on the slag phase to obtain vitreous body tailings. According to the invention, the waste incineration fly ash is treated without adding a binder for pelletizing, the copper-containing sludge is treated without adding extra drying equipment, and the two materials are treated in a synergistic manner, so that the process flow and the investment cost are greatly reduced.
Description
Technical Field
The invention relates to a method for cooperatively treating waste incineration fly ash and copper-containing sludge, belonging to the technical field of harmless and resource comprehensive treatment of hazardous waste.
Background
The current main disposal modes of the household garbage include three types: (1) cement solidification and landfill, (2) chemical agent stabilization technology, and (3) heat treatment technology. However, the heat treatment process of the domestic garbage gradually becomes the mainstream due to the problems of the continuous increase of the amount of the garbage, the increasing shortage of land resources, the ineffective recovery of valuable components in the domestic garbage and the like. However, a large amount of secondary pollutants, such as tail gas and fly ash, are also generated during the incineration of garbage. According to data, the generation amount of the fly ash accounts for about 3-5% of the amount of the incineration waste, the amount of the incineration fly ash generated every year reaches a non-negligible scale due to the large number of waste incineration bases, and dioxin and high chlorine content in the fly ash also become important obstacles for the effective treatment of the fly ash; in addition, the fly ash has low content of valuable metals such as copper, nickel and the like, difficult enrichment and high recovery cost.
At present, the sludge is mainly treated in a stockpiling mode, occupies a large amount of land resources, and if the sludge is not treated properly, heavy metal components in the sludge enter soil, so that immeasurable damage is caused to the surrounding ecological environment.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a method for the cooperative treatment of waste incineration fly ash and copper-containing sludge so as to realize the cooperative treatment of the waste incineration fly ash and the copper-containing sludge.
A method for the cooperative treatment of waste incineration fly ash and copper-containing sludge comprises the following steps:
s1, uniformly mixing the waste incineration fly ash and the copper-containing sludge, and pelletizing to obtain a pellet material;
wherein, in the ball material, the chlorine content is 1-20 wt%, the total content of copper and nickel is 1-10 wt%, and the water content is less than 30 wt%;
s2, mixing the ball material obtained in the S1, a fluxing agent and fuel to obtain a mixture;
wherein in the mixed material, SiO is2The mass ratio of Fe is 0.5-1.5: 1, SiO2The mass ratio of CaO to CaO is 0.5-1.5: 1; adding fuel with 1000-3000 kcal of heat into every 1kg of ball material; the fuel comprises coke; optionally, the coke addition in the fuel is 12-30wt% of the pellets;
s3, carrying out smelting treatment on the mixture obtained in the step S2 to obtain molten slag and flue gas; optionally, combustible gas such as natural gas can be filled into the smelting furnace as auxiliary fuel when the smelting furnace is used as required;
s4, when the chlorine content in the ball material is 5-20 wt% (marking the ball material as a high-chlorine material), performing water quenching on the molten slag to obtain vitreous body tailings; collecting soot in the flue gas, sequentially carrying out water washing and solid-liquid separation on the soot to obtain supernatant, and adding alkali into the supernatant to obtain a precipitate rich in copper and nickel;
when the chlorine content in the ball material is less than 5wt% (the ball material is marked as a low-chlorine material), carrying out depletion treatment on the molten slag to obtain a slag phase and matte, and then carrying out water quenching on the slag phase to obtain vitreous body tailings.
Further, in S1, the mass ratio of the waste incineration fly ash to the copper-containing sludge is 1-8: 1-8.
Further, in S1, in the waste incineration fly ash, the chlorine content is 1-30 wt%, the water content is 1-20 wt%, and the copper and nickel contents are both lower than 3 wt%; in the copper-containing sludge, the content of Cu is 1-10 wt%, the content of Ni is 1-10 wt%, the content of water is 30-70 wt%, and the content of chlorine is less than 1 wt%.
Further, in S2, SiO is contained in the mixture2The mass ratio of Fe is 0.6-1.2: 1, SiO2And the mass ratio of CaO is 0.7-1.0: 1.
Further, in S2, the flux includes one or more of iron ore, steel ash, blast furnace ash, limestone, papermaking white mud, carbide slag, and quartz stone.
Further, in S2, the fuel includes one or more of carbon, waste activated carbon, oil sludge, and resin.
Further, in S2, fuel with 1200-2000 kcal of heat is added for every 1kg of pellet material.
Further, in S3, oxygen-enriched air is adopted for combustion supporting during smelting, the oxygen content in the oxygen-enriched air is 40-80 vol%, preferably 50-60vol%, and the molar ratio of the introduction amount of the oxygen-enriched air to the addition amount of coke is 0.7-1.3: 1.
further, in S3, the smelting temperature is controlled to be 1200-1500 ℃, preferably 1250-1450 ℃.
Further, in S4, depletion is performed in an electrothermal pre-bed.
Furthermore, the flue gas can be discharged after reaching standards after waste heat utilization, semi-dry dechlorination, cloth bag dust removal, wet desulphurization and catalytic denitration.
After the low-chlorine material is smelted, most metals cannot generate chloride to enter flue gas due to the low chlorine content in the mixed material. After the mixture is melted at high temperature, the metal oxide is reduced into simple substance or sulfide, calcium, silicon, iron and the like form low-melting-point silicate, the mixed melt can be transferred to an electric heating forehearth through a chute for sedimentation and delamination, a slag discharge port and a matte port are arranged in the electric heating forehearth, and the delaminated slag phase and the matte are respectively discharged from the ports. The low-chlorine high-copper-nickel material has lower copper content and large slag content compared with the conventional copper-containing material, the smelting area of a common side-blown furnace has small volume, the retention time of the material in the furnace chamber is short, an obvious copper matte layer is difficult to obtain, and the cost is high and the project is complicated when the furnace chamber is arranged too large. In order to solve the problem, the copper matte can be transferred into an electric heating fore-bed for sedimentation, so that the sedimentation time of the copper matte is prolonged, and the amount of the copper matte in the fore-bed is increased to ensure that an obvious copper matte layer is generated, namely the aim of slag matte layering is fulfilled.
The main reactions in the smelting process of the low-chlorine mixed material are as follows:
(1) oxidation-reduction reaction:
2CuO+C=Cu2O+CO
Cu2O+C=2Cu+CO
PbO+C=Pb+CO
NiO+C=Ni+CO
2CO+O2=2CO2
(2) slagging reaction
Fe2O3+CO=2FeO+CO2
Na2O+SiO2=Na2O·SiO2
CaO+SiO2=CaO·SiO2
FeO+SiO2=FeO·SiO2
After the high-chlorine mixed material is smelted, because the chlorine content in the mixed material is high and the boiling point of the metal chloride is low, most metal elements of the mixed material are converted into chloride after high-temperature melting and are volatilized into smoke gas, and the chloride is enriched in smoke dust. Sulfur dioxide and hydrogen fluoride are generated by sulfur, fluorine and other substances in a reducing atmosphere and enter the flue gas. At the moment, most harmful substances are removed from the slag, and the molten slag can be directly quenched by water and cooled to generate vitreous body tailings.
The main reactions in the smelting process of the high-chlorine mixed material are as follows:
(1) chlorination and volatilization reaction:
CaCl2 + SiO2 + H2O = CaSiO3 + 2HCl(g)
2CaCl2 + 2SiO2 + O2(g) = 2CaSiO3 + 2Cl2(g)
CuO+2HCl(g)=CuCl2↑+H2O
2CuO+2Cl2(g)=2CuCl2↑+O2(g)
NiO+2HCl(g)=NiCl2↑+H2O
2NiO+2Cl2(g)=2NiCl2↑+O2(g)
Na2O+2HCl (g) =2NaCl(g)+H2O(g)
Na2O+2Cl2(g) =2NaCl(g)+H2O(g)
K2O+2HCl (g) =2KCl(g)+H2O(g)
K2O+2Cl2(g) =2KCl(g)+H2O(g)
2PbO+C=2Pb(g) +CO2(g)
2ZnO+C=2Zn(g) +CO2(g)
(2) slagging reaction
Fe2O3+CO=2FeO+CO2
CaO+SiO2=CaO·SiO2
FeO+SiO2=FeO·SiO2
The flue dust collected in S4 can be actually considered as secondary fly ash, which contains, in addition to metal chlorides, components such as silica, iron oxide, etc. carried along with the gas stream. The secondary fly ash can be used for precipitating impurities insoluble in water by first-step water washing, the precipitates comprise flying dust such as silicon dioxide and ferric oxide and metal components such as Pb and Zn which are reduced and volatilized, the precipitates can be directly sold when the Pb and Zn contents are high, otherwise, the precipitates can be returned for secondary smelting, and the supernatant of the water washing is mainly CuCl2、NiCl2Combination of NaCl, KCl, CaCl and the like which are easily dissolved in waterA compound (I) is provided. And adding alkali to the washing supernatant for precipitation, wherein hydroxides of metals such as copper, nickel, calcium and the like which are insoluble in water are enriched in the alkali washing slag, and the slag has high content of valuable metals and can be directly sold. And (4) separating salt from the clear liquid after the alkali washing through triple effect evaporation to obtain products such as NaCl, KCl and the like.
The main reactions in this process are as follows:
CuCl2 + 2NaOH = Cu(OH)2+2NaCl
NiCl2 + 2NaOH = Ni (OH)2+2NaCl
CaCl2 + 2NaOH = Ca (OH)2+2NaCl
when the chlorine content in the ball material is high, the molten slag is directly water quenched, and is cooled to generate vitreous tailings, while metal components in the material generate chlorides which are volatilized into flue gas and are enriched in the flue gas, and products such as heavy metal alkali slag, potassium chloride, sodium chloride and the like are obtained through processes such as water washing, alkali precipitation, salt separation and the like. When the chlorine content in the ball material is low, metals such as copper, nickel and the like can not generate chloride to volatilize, the material is diluted after melting, a metal phase and a slag phase are generated through precipitation and stratification, and the slag phase is further quenched and cooled by water to generate vitreous body tailings. The invention successfully solves the problem of difficult disposal of the chlorine-containing fly ash, not only achieves the aim of harmless disposal, but also effectively enriches valuable metals in the fly ash and the copper-containing sludge, and further recycles resources.
The method utilizes the characteristics of low water content, high chlorine content, high water content of heavy metal-containing sludge and high heavy metal-containing sludge of the waste incineration fly ash to match the waste incineration fly ash and the copper-containing sludge, selects different smelting processes according to the chlorine content of the mixed material, and realizes harmless and resource treatment of the waste incineration fly ash and the copper-containing sludge through one-stage smelting or two-stage smelting and dilution. The invention has the obvious advantages of strong raw material adaptability, high harmless degree, high resource recovery efficiency and the like.
Compared with the prior art, the invention has the advantages that:
1) by the synergistic treatment method, the waste incineration fly ash is treated without adding an additional binder for pelletizing, the copper-containing sludge is treated without additionally adding drying equipment, and the two materials are treated in a synergistic manner, so that the process flow and the investment cost are greatly reduced.
2) The invention successfully solves the problem that the incineration fly ash is difficult to treat, and can effectively enrich heavy metal elements in the incineration fly ash, so that resources are recycled.
3) The stable state vitreous substance generated by the slag has certain economic value, belongs to an environment-friendly raw material, and can be directly used as roadbed materials, concrete aggregates and the like.
4) The raw material adaptability is strong, a proper process route can be selected according to different raw material sources, the high-chlorine mixed material can be directly smelted by a single furnace, and the low-chlorine mixed material can enter an electric heating forehearth for clarification and layering to obtain a product.
5) The waste heat utilization can be effectively carried out, the corrosion of a boiler is prevented, the synthesis of dioxin can be effectively avoided by adopting lime milk spraying of the quench tower, and hydrogen chloride in the dioxin can be removed.
6) By further processing the smoke dust, valuable metal components in the smoke dust can be effectively collected, different chlorine salt products are obtained by triple effect evaporation and fractionation, and environment-friendly production is successfully realized.
Optionally, the smelting system used in the smelting process comprises a smelting furnace and an electric heating forehearth, wherein the smelting furnace is provided with a slag discharge port, the electric heating forehearth is provided with a slag tap and a siphon tap which are distributed up and down, and the slag discharge port is communicated with the electric heating forehearth; the slag discharge port is also communicated with a water quenching tank; the slag tap is communicated with the water quenching tank. Therefore, the molten slag can be discharged to an electric heating fore-bed or a water quenching tank according to requirements, the molten slag of a metal phase needing to be settled and separated and the molten slag of the metal phase not needing to be settled and separated are subjected to differential treatment, and the universality of the system on raw materials is improved.
Furthermore, the slag discharge port is communicated with a three-way valve, one outlet of the three-way valve is communicated with the electric heating forehearth, and the other outlet of the three-way valve is communicated with a water quenching pool. Thus, the flow direction of the molten slag can be controlled by the three-way valve, the molten slag is discharged to an electric heating front bed or a water quenching tank, and when the smelted material is a high-chlorine mixed material, the molten slag can be directly discharged into the water quenching tank to be water-quenched to generate glass body tailings; when the smelted material is a low-chlorine mixed material, the molten slag can be discharged into an electric heating forehearth firstly, so that a metal phase and a slag phase are layered in the electric heating forehearth, and after slag-liquid separation is realized, the slag phase is discharged into a water quenching tank for water quenching treatment. Therefore, the smelting system has wide application range to materials, is suitable for smelting materials with different copper and chlorine contents, and improves the applicability of equipment to raw materials.
Further, the three-way valve is communicated with the electric heating fore-bed through a first chute. Further, the three-way valve is communicated with the water quenching tank through a second chute. Further, the slag tap is communicated with the water quenching tank through a third chute.
As another scheme, a first valve is arranged between the slag discharge port and the electric heating fore bed; and a second valve is arranged between the slag discharging port and the water quenching tank. The flow direction of the molten slag is controlled through the selective opening and closing of the first valve and the second valve, so that the molten slag of different materials is treated.
Further, the smelting furnace is a side-blown furnace.
Further, the smelting furnace comprises a furnace base, a furnace hearth and a furnace top from bottom to top in sequence, and the slag discharge port is arranged at the bottom side of the furnace hearth.
Optionally, the inner wall of the furnace top is provided with an insulating layer. Optionally, the furnace roof is made of a heat insulating material. The furnace top is made of heat-insulating materials or the inner wall of the furnace top is provided with the heat-insulating layer, so that the temperature of flue gas generated after smelting of hazardous waste materials containing copper and nickel can reach more than 850 ℃ in the inner cavity of the furnace top, the inner cavity of the furnace top forms a place for decomposing dioxin, the full decomposition of the flue gas is ensured, the subsequent flue gas treatment pressure is reduced, and the environmental protection performance of the system is favorably improved.
The smelting system has strong adaptability to raw materials, can reasonably control the flow direction of the molten slag according to the difference of the copper and chlorine contents of the raw materials, and realizes the high-efficiency and low-energy-consumption treatment of the molten slag. By improving the heat insulation performance of the furnace top, the dioxin is decomposed in the smelting furnace, and the environmental protection performance of the system is improved. Can be directly improved on the basis of the existing smelting equipment, and has good popularization and application values.
Furthermore, the smelting system can form a co-processing system of fly ash incineration and copper-containing sludge together with other equipment, and is applied to co-processing of fly ash incineration and copper-containing sludge.
Therefore, the copper-containing sludge and the waste incineration fly ash can be mixed through the first mixing mechanism, then granulation is carried out through the granulator, the ball material, the fluxing agent, the fuel and the like are uniformly mixed in the second mixing mechanism, then the mixture is input into the smelting furnace for smelting, and then the molten slag generated by the smelting furnace is discharged into an electric heating front bed for settlement separation or is directly discharged into a water quenching tank for water quenching according to the relative content of copper and chlorine in the ball material.
The system further comprises a flue gas treatment unit, wherein the flue gas treatment unit comprises an SNCR (selective non-catalytic reduction) denitration mechanism, a waste heat boiler, a quench tower and a dust collection mechanism which are sequentially communicated; and a spraying mechanism is arranged on a pipeline between the quenching tower and the dust collecting mechanism.
Flue gas that the smelting furnace produced gets into exhaust-heat boiler and carries out waste heat utilization after SNCR denitration (can urea solution medium), and is optional, and exhaust-heat boiler's whole diaphragm type wall carries out build-up welding nickel alloy and handles to effectual boiler corrosion prevention. Flue gas after the waste heat utilization gets into quench tower dechlorination and rapid cooling avoids the dioxin synthesis interval, and the quench tower internal medicine adopts lime milk to spray, and the purpose lies in that chlorine content is too high in this flue gas, singly leans on the wet process mechanism that drops, and dechlorination effect is difficult to up to standard. The pipeline between the outlet of the quenching tower and the dust collecting mechanism is provided with the injection mechanism which can inject active carbon and slaked lime, absorb dioxin which is possibly synthesized and remove hydrogen chloride and sulfur dioxide which are not completely removed in the front-stage working procedure. The treated flue gas is discharged after reaching standards through dust collection, wet desulphurization and catalytic denitration.
Further, the flue gas treatment unit also comprises a water washing mechanism, an alkali washing mechanism and a triple-effect evaporator which are sequentially communicated, wherein the water washing mechanism is communicated with a discharge hole of the dust collecting mechanism.
Further, the flue gas treatment unit further comprises a wet deacidification mechanism, a flue gas-flue gas reheater (GGH device), a steam-flue gas heat exchanger (SGH device), a hot blast stove and an SCR denitration mechanism which are sequentially communicated, wherein a gas inlet of the wet deacidification mechanism is communicated with a gas outlet of the dust collection mechanism; the flue gas-flue gas reheater is provided with a first flue gas inlet, a first flue gas outlet, a second flue gas inlet and a second flue gas outlet which are mutually communicated, the wet deacidification mechanism is communicated with the first flue gas inlet, the first flue gas outlet is communicated with the steam-flue gas heat exchanger, the gas outlet of the SCR denitration mechanism is communicated with the second flue gas inlet, and the second flue gas outlet is communicated with a chimney. The wet deacidification mechanism can deacidify by taking lime milk as a medium.
Further, an induced draft fan is arranged at an air outlet of the dust collecting mechanism.
Further, the dust collecting mechanism is a cloth bag dust collector.
The co-processing system for the incineration fly ash and the copper-containing sludge can realize simultaneous processing of the incineration fly ash and the copper-containing sludge, and enrich valuable metals in the incineration fly ash and the copper-containing sludge, so that resources are recycled. The applicability to raw materials is strong, the proper material flow direction can be selected according to the difference of the source quantity of the raw materials, the high-chlorine mixed material can be directly smelted by a single furnace, and the low-chlorine mixed material can enter an electric heating forehearth for clarification and layering to obtain a product. By further processing the smoke dust, valuable metal components in the smoke dust can be effectively collected, different chlorine salt products are obtained by triple effect evaporation and fractionation, and environment-friendly production is successfully realized.
Drawings
FIG. 1 is a schematic view of a co-processing system of a co-processing method of fly ash from waste incineration and sludge containing copper of the present invention.
FIG. 2 is a top view of a smelting system for use in the present invention.
Fig. 3 is a front view of a smelting system for use in the present invention.
In the figure, 1-smelting furnace, 2-second chute, 3-first chute, 4-electric heating fore bed, 5-third chute, 6-slag tap, 7-siphon tap, 8-copper mold, 9-secondary tuyere, 10-primary tuyere, 11-hearth, 12-hearth, 13-furnace top, 14-electrode, 15-slag tap, 16-three-way valve, 17-water quenching tank, 18-first mixing mechanism, 19-granulator, 20-second mixing mechanism, 21-water treatment station, 22-alkaline washing system, 23-triple effect evaporator, 24-SNCR denitration mechanism, 25-waste heat boiler, 26-quench tower, 27-jet system, 28-dust collection mechanism, 29-induced draft fan, 30-wet deacidification mechanism, 31-a flue gas-flue gas reheater, 32-a steam-flue gas heat exchanger, 33-a hot blast stove, 34-an SCR denitration mechanism, 35-a chimney and 36-a water washing mechanism.
Detailed Description
The present invention will be described in detail below with reference to the embodiments with reference to the attached drawings. It should be noted that the embodiments and features of the embodiments may be combined with each other without conflict. For convenience of description, the words "upper", "lower", "left" and "right" in the following description are used only to indicate the correspondence between the upper, lower, left and right directions of the drawings themselves, and do not limit the structure.
Example 1
The method for the cooperative treatment of the waste incineration fly ash and the copper-containing sludge comprises the following steps:
s1, uniformly mixing the waste incineration fly ash and the copper-containing sludge according to the mass ratio of 5:1, and pelletizing to obtain a pellet material (a high-chlorine low-copper-nickel mixed material);
wherein, the waste incineration fly ash contains 18wt% of chlorine and 3wt% of water, and the contents of copper and nickel are lower than 1 wt%; the copper-containing sludge contains 3.4wt% of copper, 1.2wt% of nickel and 60wt% of water, and the content of chlorine is less than 1 wt%;
s2, mixing the ball material obtained in the S1, a fluxing agent and fuel to obtain a mixture;
wherein in the mixed material, SiO is2The mass ratio of Fe is 0.7: 1, SiO2The mass ratio of CaO is 0.9: 1; adding fuel with 1600kcal of heat into every 1kg of ball material; the addition amount of the coke is 21wt% of the ball material;
s3, carrying out smelting treatment on the mixture obtained in the step S2 to obtain molten slag and flue gas;
during the period, the smelting temperature is controlled to be 1450 ℃; during smelting, oxygen-enriched air is used for supporting combustion, the oxygen content in the oxygen-enriched air is 40-80 vol%, and the molar ratio of the introduction amount of the oxygen-enriched air to the addition amount of coke is 0.9.
S4, performing water quenching on the molten slag to obtain vitreous body tailings; collecting soot in the flue gas, sequentially washing the soot and carrying out solid-liquid separation to obtain supernatant, adding alkali into the supernatant, reacting, and carrying out solid-liquid separation to obtain residual solution and precipitate rich in copper and nickel; and (5) performing effective evaporation on the residual solution to obtain sodium chloride and potassium chloride.
S2, the fluxing agent is composed of iron ore, limestone and quartz stone, wherein the iron content in the iron ore is more than 50wt%, and SiO in the quartz stone2The content is more than 85wt%, and the CaO content in the limestone is more than 45 wt%.
In S2, the fuel includes one or more of carbon essence, waste activated carbon, oil sludge and resin.
In this example, the recovery rates of Cu, Ni, Na, K, Cl, Pb, and Zn were 90%, 85%, 94%, 96%, 99%, 90%, and 93%, respectively. Discharging the molten slag into a water quenching slag pool, and cooling to form glass body tailings, wherein the content of the glass body is 92 wt%. The flue gas is discharged through a tail gas treatment system after reaching the standard.
Example 2
The method for the cooperative treatment of the waste incineration fly ash and the copper-containing sludge comprises the following steps:
s1, uniformly mixing the waste incineration fly ash and the copper-containing sludge according to the mass ratio of 3:1, and pelletizing to obtain a pellet material (a high-chlorine low-copper-nickel mixed material);
wherein, the waste incineration fly ash contains 21wt% of chlorine and 2wt% of water, and the contents of copper and nickel are lower than 1 wt%; the copper-containing sludge contains 2.7wt% of copper, 0.6wt% of nickel and 50wt% of water, and the content of chlorine is less than 1 wt%;
s2, mixing the ball material obtained in the S1, a fluxing agent and fuel to obtain a mixture;
wherein in the mixed material, SiO is2The mass ratio of Fe is 0.75: 1, SiO2The mass ratio of CaO is 0.85: 1; adding fuel with 1200kcal of heat into every 1kg of ball material; the fuel contains coke; the addition amount of the coke is 21wt% of the ball material;
s3, carrying out smelting treatment on the mixture obtained in the step S2 to obtain molten slag and flue gas;
during the period, the smelting temperature is controlled to be 1300 ℃; during smelting, oxygen-enriched air is used for supporting combustion, the oxygen content in the oxygen-enriched air is 40-80 vol%, and the molar ratio of the introduction amount of the oxygen-enriched air to the addition amount of coke is 1.1.
S4, performing water quenching on the molten slag to obtain vitreous body tailings; collecting soot in the flue gas, sequentially washing the soot and carrying out solid-liquid separation to obtain supernatant, adding alkali into the supernatant, reacting, and carrying out solid-liquid separation to obtain residual solution and precipitate rich in copper and nickel; and (5) performing effective evaporation on the residual solution to obtain sodium chloride and potassium chloride.
S2, the fluxing agent is composed of iron ore, limestone and quartz stone, wherein the iron content in the iron ore is more than 50wt%, and SiO in the quartz stone2The content is more than 85wt%, and the CaO content in the limestone is more than 45 wt%.
In S2, the fuel includes one or more of carbon essence, waste activated carbon, oil sludge and resin.
In this example, the recovery rates of Cu, Ni, Na, K, Cl, Pb, and Zn were 91%, 87%, 96%, 98%, 99%, 93%, and 96%, respectively. Discharging the molten slag into a water quenching slag pool, and cooling to form glass body tailings, wherein the content of the glass body is 91 wt%. The flue gas is discharged through a tail gas treatment system after reaching the standard.
Example 3
The method for the cooperative treatment of the waste incineration fly ash and the copper-containing sludge comprises the following steps:
s1, uniformly mixing the waste incineration fly ash and the copper-containing sludge according to the mass ratio of 2:5, and pelletizing to obtain a pellet material (a low-chlorine high-copper-nickel mixed material);
wherein, the waste incineration fly ash contains 6wt% of chlorine and 2wt% of water, and the contents of copper and nickel are lower than 1 wt%; the copper-containing sludge contains 4.1wt% of copper, 1.3wt% of nickel and 30wt% of water, and the content of chlorine is less than 1 wt%;
s2, mixing the ball material obtained in the S1, a fluxing agent and fuel to obtain a mixture;
wherein in the mixed material, SiO is2The mass ratio of Fe is 0.8: 1, SiO2The mass ratio of CaO is 1: 1; adding fuel with 1400kcal of heat into every 1kg of ball material; the fuel contains coke; the addition amount of the coke is 21wt% of the ball material;
s3, carrying out smelting treatment on the mixture obtained in the step S2 to obtain molten slag and flue gas;
during the period, the smelting temperature is controlled to be 1400 ℃; during smelting, oxygen-enriched air is used for supporting combustion, the oxygen content in the oxygen-enriched air is 40-80 vol%, and the molar ratio of the introduction amount of the oxygen-enriched air to the addition amount of coke is 1.2.
And S4, discharging the molten slag to an electric heating forehearth for settling and layering to obtain a slag phase and copper matte, and then performing water quenching on the slag phase to obtain vitreous body tailings.
S2, the fluxing agent is composed of iron ore, limestone and quartz stone, wherein the iron content in the iron ore is more than 50wt%, and SiO in the quartz stone2The content is more than 85wt%, and the CaO content in the limestone is more than 45 wt%.
In S2, the fuel includes one or more of carbon essence, waste activated carbon, oil sludge and resin.
In this example, the recovery rates of Cu, Ni, Cl, Pb and Zn were 94%, 91%, 99%, 84% and 88%, respectively. Discharging the molten slag into a water quenching slag pool, and cooling to form glass body tailings, wherein the content of the glass body is 93 wt%. The flue gas is discharged through a tail gas treatment system after reaching the standard.
Example 4
The method for the cooperative treatment of the waste incineration fly ash and the copper-containing sludge comprises the following steps:
s1, uniformly mixing the waste incineration fly ash and the copper-containing sludge according to the mass ratio of 1:5, and pelletizing to obtain a pellet material (a low-chlorine high-copper-nickel mixed material);
wherein, the waste incineration fly ash contains 4wt% of chlorine and 5wt% of water, and the contents of copper and nickel are lower than 1 wt%; the copper-containing sludge contains 3.7wt% of copper, 1.4wt% of nickel and 40wt% of water, and the chlorine content is less than 1 wt%;
s2, mixing the ball material obtained in the S1, a fluxing agent and fuel to obtain a mixture;
wherein in the mixed material, SiO is2The mass ratio of Fe is 0.75: 1, SiO2The mass ratio of CaO is 0.85: 1; adding tools for every 1kg of ball materialA fuel having 1400kcal of heat; the fuel contains coke; the addition amount of the coke is 21wt% of the ball material;
s3, carrying out smelting treatment on the mixture obtained in the step S2 to obtain molten slag and flue gas;
during the period, the smelting temperature is controlled to be 1400 ℃; during smelting, oxygen-enriched air is used for supporting combustion, the oxygen content in the oxygen-enriched air is 40-80 vol%, and the molar ratio of the introduction amount of the oxygen-enriched air to the addition amount of coke is 0.8. .
And S4, discharging the molten slag to an electric heating forehearth for settling and layering to obtain a slag phase and copper matte, and then performing water quenching on the slag phase to obtain vitreous body tailings.
S2, the fluxing agent is composed of iron ore, limestone and quartz stone, wherein the iron content in the iron ore is more than 50wt%, and SiO in the quartz stone2The content is more than 85wt%, and the CaO content in the limestone is more than 45 wt%.
In S2, the fuel includes one or more of carbon essence, waste activated carbon, oil sludge and resin.
In this example, the recovery rates of Cu, Ni, Cl, Pb and Zn were 95%, 92%, 99%, 85% and 90%, respectively. Discharging the molten slag into a water quenching slag pool, and cooling to form glass body tailings, wherein the content of the glass body is 95 wt%. The flue gas is discharged through a tail gas treatment system after reaching the standard.
The above embodiments are carried out by utilizing a co-processing system of incineration fly ash and copper-containing sludge, the system comprises a first mixing mechanism 18, a granulator 19, a second mixing mechanism 20 and a smelting furnace 1 which are sequentially communicated, a slag discharge port 15 of the smelting furnace 1 is connected with an electric heating forehearth 4 and a water quenching tank 17 in parallel, and a slag discharge port of the electric heating forehearth 4 is communicated with the water quenching tank 17. The device also comprises a flue gas treatment unit, wherein the flue gas treatment unit comprises an SNCR (selective non-catalytic reduction) denitration mechanism 24, a waste heat boiler 25, a quench tower 26 and a dust collection mechanism 28 which are sequentially communicated; and a spraying mechanism 27 is arranged on a pipeline between the quenching tower 26 and the dust collecting mechanism 28.
The flue gas treatment unit also comprises a water washing mechanism 36, an alkaline washing mechanism 22 and a triple-effect evaporator 23 which are sequentially communicated, wherein the water washing mechanism 36 is communicated with a discharge hole of the dust collecting mechanism 28. The flue gas treatment unit further comprises a wet deacidification mechanism 30, a flue gas-flue gas reheater 31, a steam-flue gas heat exchanger 32, a hot blast stove 33 and an SCR denitration mechanism 34 which are sequentially communicated, wherein a gas inlet of the wet deacidification mechanism 30 is communicated with a gas outlet of the dust collection mechanism 28; the flue gas-flue gas reheater 31 is provided with a first flue gas inlet, a first flue gas outlet, a second flue gas inlet and a second flue gas outlet which are communicated with each other, the wet deacidification mechanism 30 is communicated with the first flue gas inlet, the first flue gas outlet is communicated with the steam-flue gas heat exchanger 32, the gas outlet of the SCR denitration mechanism 34 is communicated with the second flue gas inlet, and the second flue gas outlet is communicated with a chimney 35. The wet deacidification mechanism 30 is a two-stage wet deacidification mechanism, the produced gypsum can be sold, and the produced deacidification wastewater can be recycled or discharged after being treated by the water treatment station 21 to reach the standard.
And an induced draft fan 29 is arranged at an air outlet of the dust collecting mechanism 28. The dust collecting mechanism 28 is a cloth bag dust collector.
The smelting furnace comprises a hearth 12, a hearth 11 and a furnace top 13 from bottom to top in sequence, and the slag discharge port 15 is arranged at the bottom side of the hearth 11. The slag discharge port is communicated with a three-way valve 16, one outlet of the three-way valve 16 is communicated with the electric heating fore-bed 4, and the other outlet of the three-way valve 16 is communicated with a water quenching tank 17. An insulating layer 1301 is arranged on the inner wall of the furnace top 13; alternatively, the furnace ceiling 13 is made of a heat insulating material. An electrode 14 for heating molten slag is arranged on the electric heating forebed 4, a slag tap 6 and a siphon tap 7 which are distributed up and down are arranged on the electric heating forebed 4, and the siphon tap is used for discharging copper matte to the copper mold 8; the slag discharge port 15 is communicated with a three-way valve 16, one outlet of the three-way valve 16 is communicated with the electric heating fore-bed 4, and the other outlet of the three-way valve 16 is communicated with a water quenching pool 17; the slag tap 6 is communicated with a water quenching tank 17. The three-way valve 16 is communicated with the electric heating fore bed 4 through the first chute 3. The three-way valve 16 is communicated with a water quenching tank 17 through a second chute 2. And the slag tap 6 is communicated with a water quenching tank 17 through a third chute 5. Optionally, 2 valves may be used to replace the three- way valve 16, and 1 valve is disposed on the first chute, and the other 1 valve is disposed on the second chute, which may also play a role in controlling the flow direction of the molten slag; preferably, the valve is located as close as possible to the inlet end of the chute. The smelting furnace is a side-blown furnace. The smelting furnace is provided with a primary air port 10 and a secondary air port 9 which are communicated with the furnace hearth, and the primary air port 10 is positioned below the secondary air port 9. During operation, according to the content of copper and chlorine in the treated materials, the molten slag generated by smelting in the smelting furnace is directly discharged into a water quenching tank or into an electric heating fore-hearth, and the materials with different copper and chlorine contents can be treated by a set of smelting system.
The foregoing examples are set forth to illustrate the present invention more clearly and are not to be construed as limiting the scope of the invention, which is defined in the appended claims to which the invention pertains, as modified in all equivalent forms, by those skilled in the art after reading the present invention.
Claims (9)
1. A method for the cooperative treatment of waste incineration fly ash and copper-containing sludge is characterized by comprising the following steps:
s1, uniformly mixing the waste incineration fly ash and the copper-containing sludge, and pelletizing to obtain a pellet material;
wherein, in the ball material, the chlorine content is 1-20 wt%, the total content of copper and nickel is 1-15 wt%, and the water content is less than 30 wt%;
s2, mixing the ball material obtained in the S1, a fluxing agent and fuel to obtain a mixture;
wherein in the mixed material, SiO is2The mass ratio of Fe is 0.5-1.5: 1, SiO2The mass ratio of CaO to CaO is 0.5-1.5: 1; adding fuel with 1000-3000 kcal of heat into every 1kg of ball material; the fuel comprises coke;
s3, carrying out smelting treatment on the mixture obtained in the step S2 to obtain molten slag and flue gas;
s4, when the chlorine content in the ball material is 5-20 wt%, performing water quenching on the molten slag to obtain vitreous body tailings; collecting soot in the flue gas, sequentially carrying out water washing and solid-liquid separation on the soot to obtain supernatant, and adding alkali into the supernatant to obtain a precipitate rich in copper and nickel;
and when the chlorine content in the ball material is less than 5wt%, carrying out depletion treatment on the molten slag to obtain a slag phase and matte, and then carrying out water quenching on the slag phase to obtain vitreous body tailings.
2. The synergistic treatment method according to claim 1, wherein in S1, the mass ratio of the waste incineration fly ash to the copper-containing sludge is 1-8: 1-8.
3. The synergistic treatment method as claimed in claim 1, wherein in S1, the fly ash from waste incineration contains 1-30 wt% of chlorine, 1-20 wt% of water and less than 3wt% of copper and nickel; in the copper-containing sludge, the content of Cu is 1-10 wt%, the content of Ni is 1-10 wt%, the content of water is 30-70 wt%, and the content of chlorine is less than 1 wt%.
4. The co-processing method according to claim 1, wherein in S2, SiO is contained in the mixture2The mass ratio of Fe is 0.6-1.2: 1, SiO2And the mass ratio of CaO is 0.7-1.0: 1.
5. the co-processing method according to claim 1, wherein in S2, the flux comprises one or more of iron ore, steel ash, blast furnace ash, limestone, papermaking white mud and carbide slag.
6. The co-processing method according to claim 1, wherein in S2, the fuel further comprises one or more of carbon, waste activated carbon, sludge, and resin.
7. The co-processing method according to claim 1, wherein in S2, fuel having 1200 to 2000kcal of heat is blended per 1kg of pellet.
8. The cooperative processing method according to claim 1, wherein in S3, oxygen-enriched air is used for combustion supporting during smelting, the oxygen content in the oxygen-enriched air is 40-80 vol%, and the molar ratio of the introduced amount of the oxygen-enriched air to the added amount of coke is 0.7-1.3: 1.
9. The co-processing method according to claim 1, wherein in S3, the melting temperature is controlled to be 1200 to 1500 ℃, preferably 1250 to 1450 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011567386.6A CN112795776B (en) | 2020-12-25 | 2020-12-25 | Method for co-processing waste incineration fly ash and copper-containing sludge |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011567386.6A CN112795776B (en) | 2020-12-25 | 2020-12-25 | Method for co-processing waste incineration fly ash and copper-containing sludge |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112795776A true CN112795776A (en) | 2021-05-14 |
| CN112795776B CN112795776B (en) | 2022-04-29 |
Family
ID=75804149
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011567386.6A Active CN112795776B (en) | 2020-12-25 | 2020-12-25 | Method for co-processing waste incineration fly ash and copper-containing sludge |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112795776B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113564381A (en) * | 2021-07-26 | 2021-10-29 | 广东飞南资源利用股份有限公司 | Synergistic copper smelting method and building material |
| CN113666687A (en) * | 2021-07-16 | 2021-11-19 | 中国科学院武汉岩土力学研究所 | Method for preparing baking-free floor tile by using household garbage incineration fly ash composite material |
| CN113667827A (en) * | 2021-08-24 | 2021-11-19 | 上海康恒环境股份有限公司 | Method for co-processing waste incineration fly ash and copper-containing sludge |
| CN113774227A (en) * | 2021-08-31 | 2021-12-10 | 中国恩菲工程技术有限公司 | Smelting treatment method of incineration fly ash |
| CN114438336A (en) * | 2021-12-30 | 2022-05-06 | 荆门格林循环电子废弃物处置有限公司 | Method for treating wet impurity-removing slag and copper-containing hazardous waste |
| CN114836630A (en) * | 2022-03-29 | 2022-08-02 | 中国恩菲工程技术有限公司 | Method and system for cooperatively treating hazardous waste containing copper by copper concentrate |
| CN116375452A (en) * | 2023-03-30 | 2023-07-04 | 中国科学院城市环境研究所 | Sludge incineration ash and waste incineration fly ash synergetic detoxification and resource utilization method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106082646A (en) * | 2016-06-15 | 2016-11-09 | 上海大学 | Electroplating sludge and domestic garbage incineration flyash is utilized to work in coordination with the melted method preparing glass sand |
| CN108687106A (en) * | 2018-05-02 | 2018-10-23 | 中国恩菲工程技术有限公司 | The cooperative processing method of flying dust and sludge |
-
2020
- 2020-12-25 CN CN202011567386.6A patent/CN112795776B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106082646A (en) * | 2016-06-15 | 2016-11-09 | 上海大学 | Electroplating sludge and domestic garbage incineration flyash is utilized to work in coordination with the melted method preparing glass sand |
| CN108687106A (en) * | 2018-05-02 | 2018-10-23 | 中国恩菲工程技术有限公司 | The cooperative processing method of flying dust and sludge |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113666687A (en) * | 2021-07-16 | 2021-11-19 | 中国科学院武汉岩土力学研究所 | Method for preparing baking-free floor tile by using household garbage incineration fly ash composite material |
| CN113564381A (en) * | 2021-07-26 | 2021-10-29 | 广东飞南资源利用股份有限公司 | Synergistic copper smelting method and building material |
| CN113667827A (en) * | 2021-08-24 | 2021-11-19 | 上海康恒环境股份有限公司 | Method for co-processing waste incineration fly ash and copper-containing sludge |
| CN113774227A (en) * | 2021-08-31 | 2021-12-10 | 中国恩菲工程技术有限公司 | Smelting treatment method of incineration fly ash |
| CN114438336A (en) * | 2021-12-30 | 2022-05-06 | 荆门格林循环电子废弃物处置有限公司 | Method for treating wet impurity-removing slag and copper-containing hazardous waste |
| CN114836630A (en) * | 2022-03-29 | 2022-08-02 | 中国恩菲工程技术有限公司 | Method and system for cooperatively treating hazardous waste containing copper by copper concentrate |
| CN116375452A (en) * | 2023-03-30 | 2023-07-04 | 中国科学院城市环境研究所 | Sludge incineration ash and waste incineration fly ash synergetic detoxification and resource utilization method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN112795776B (en) | 2022-04-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112795776B (en) | Method for co-processing waste incineration fly ash and copper-containing sludge | |
| CN211247720U (en) | Plasma fusion vitrification device and waste incineration fly ash treatment system | |
| CN112442589B (en) | Method and system for co-processing waste incineration fly ash and zinc-containing dust and mud of iron and steel plant | |
| CN101062783B (en) | Environment-friendly type technique for vanadium extraction of stone coal | |
| CN112808746B (en) | Resource treatment method for incineration slag and fly ash | |
| CN102321806A (en) | Smelting method for processing zinc leaching residue by oxygen-enriched side-blowing furnace | |
| CN115121590A (en) | High-temperature melting treatment method for household garbage incineration fly ash by cooperating with sludge and aluminum ash | |
| CN114672643B (en) | Method for synergistically utilizing high-iron red mud and molten steel slag | |
| CN102776309A (en) | Treatment method of zinc-bearing dust for steel works | |
| CN106480310A (en) | A kind of alkali-metal method in removing metallurgical dust sludge | |
| CN107338358A (en) | Heavy metal in flying ash is Ji the removal methods of bioxin | |
| CN111676373A (en) | Copper-based organic solid waste recycling, reducing and harmless treatment device and treatment method | |
| CN110093471A (en) | A kind of efficient low-consume red mud method of comprehensive utilization | |
| CN111826526A (en) | Method and device for environment-friendly recovery of precious metals in waste circuit board through combined smelting of waste circuit board, copper concentrate and desulfurized gypsum | |
| CN113714246B (en) | Waste incineration fly ash treatment system and method | |
| CN112441759A (en) | Method and device for treating waste incineration fly ash with low energy consumption, resource utilization and environmental protection | |
| CN112063848B (en) | Metallurgical furnace for treating copper-containing sludge and treatment method thereof | |
| CN214244234U (en) | Incineration fly ash and copper-containing sludge co-treatment system | |
| CN214115666U (en) | Smelting system | |
| EP0819183B1 (en) | Treatment of fly ash | |
| CN114558440B (en) | High-efficiency zinc extraction coupling pulp flue gas desulfurization carbon fixation process by high-chlorine zinc gray ammonia-ammonium sulfate method | |
| CN113502401B (en) | Method for degrading dioxin in waste incineration fly ash and recycling zinc, indium and lead elements | |
| CN113860365B (en) | Method for treating arsenic-containing gypsum slag by using tin-smelting fuming furnace | |
| CN113667827A (en) | Method for co-processing waste incineration fly ash and copper-containing sludge | |
| CN215745469U (en) | Waste incineration fly ash treatment system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A Synergistic Treatment Method of MSW Incineration Fly Ash and Copper containing Sludge Effective date of registration: 20221028 Granted publication date: 20220429 Pledgee: Hunan Xiangjiang Zhongying Investment Management Co.,Ltd. Pledgor: HUNAN RUIYI ZIHUAN TECHNOLOGY CO.,LTD. Registration number: Y2022980020202 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CB03 | Change of inventor or designer information |
Inventor after: Peng Hongkui Inventor after: Zhou Jiajia Inventor after: Gu Jiashun Inventor after: Zhang Lipan Inventor after: Zhang Li Inventor after: Li Chen Inventor after: Liang Chao Inventor after: Han Xu Inventor after: Xie Longchen Inventor after: Luo Jian Inventor after: Long Sen Inventor before: Peng Hongkui Inventor before: Zhou Jiajia Inventor before: Gu Jiashun Inventor before: Zhang Lipan Inventor before: Zhang Li Inventor before: Li Chen Inventor before: Liang Chao Inventor before: Han Xu Inventor before: Xie Longchen Inventor before: Luo Jian Inventor before: Long Sen |
|
| CB03 | Change of inventor or designer information |