CN112794713A - 湿敏多孔陶瓷、雾化芯及其制备方法 - Google Patents

湿敏多孔陶瓷、雾化芯及其制备方法 Download PDF

Info

Publication number
CN112794713A
CN112794713A CN202110025723.7A CN202110025723A CN112794713A CN 112794713 A CN112794713 A CN 112794713A CN 202110025723 A CN202110025723 A CN 202110025723A CN 112794713 A CN112794713 A CN 112794713A
Authority
CN
China
Prior art keywords
porous ceramic
humidity
parts
sensitive
sensitive porous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110025723.7A
Other languages
English (en)
Inventor
林光榕
秦飞
刘卫丽
郑贤彬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huizhou Happy Vaping Technology Ltd
Original Assignee
Shenzhen Happy Vaping Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Happy Vaping Technology Ltd filed Critical Shenzhen Happy Vaping Technology Ltd
Priority to CN202110025723.7A priority Critical patent/CN112794713A/zh
Publication of CN112794713A publication Critical patent/CN112794713A/zh
Priority to PCT/CN2021/131623 priority patent/WO2022148144A1/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/453—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zinc, tin, or bismuth oxides or solid solutions thereof with other oxides, e.g. zincates, stannates or bismuthates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B15/00—Details of spraying plant or spraying apparatus not otherwise provided for; Accessories
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063—Preparing or treating the raw materials individually or as batches
    • C04B38/0635—Compounding ingredients
    • C04B38/0645—Burnable, meltable, sublimable materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063—Preparing or treating the raw materials individually or as batches
    • C04B38/0635—Compounding ingredients
    • C04B38/0645—Burnable, meltable, sublimable materials
    • C04B38/067—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063—Preparing or treating the raw materials individually or as batches
    • C04B38/0635—Compounding ingredients
    • C04B38/0645—Burnable, meltable, sublimable materials
    • C04B38/068—Carbonaceous materials, e.g. coal, carbon, graphite, hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
    • C04B2235/3203—Lithium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3241—Chromium oxides, chromates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3409—Boron oxide, borates, boric acids, or oxide forming salts thereof, e.g. borax
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5445—Particle size related information expressed by the size of the particles or aggregates thereof submicron sized, i.e. from 0,1 to 1 micron
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562—Heating rate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567—Treatment time
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/658—Atmosphere during thermal treatment
    • C04B2235/6582—Hydrogen containing atmosphere

Abstract

本发明的湿敏多孔陶瓷、雾化芯及其制备方法，湿敏多孔陶瓷由湿敏陶瓷材料制成，所述湿敏陶瓷材料按重量份包括如下组分：1‑30份ZnCr2O4，1‑10份ZnO，1‑50份造孔剂，1‑10份烧结助剂；雾化芯包括导液体和发热元件，导液体由湿敏多孔陶瓷制成；制备方法包括步骤：⑴将ZnO与Cr2O3按照摩尔比1:1混合，放入研磨装置中研磨，然后烘干，预烧制成ZnCr2O4；⑵将ZnCr2O4与ZnO、造孔剂、烧结助剂混合，研磨干燥得到混合粉料；⑶将石蜡加热，边搅拌边加入混合粉料，得到石蜡浆料；⑷将石蜡浆料注入模具中，成型后得到蜡模；⑸进行除蜡得到除蜡样；⑹将除蜡样放入炉中并在保护气氛中进行烧结得到湿敏多孔陶瓷。

Description

湿敏多孔陶瓷、雾化芯及其制备方法
技术领域
本发明属于湿敏多孔陶瓷、湿敏多孔瓷制造的雾化芯技术领域，特别涉及一种湿敏多孔陶瓷、雾化芯及其制备方法。
背景技术
电子雾化器包括储液装置和雾化芯，储液装置中灌装有待雾化液，待雾化液即待雾化的液体可以是烟液或含有药物的溶液，雾化芯一般包括导液体和发热元件，导液体接收、渗透、传导储液装置中的待雾化液，发热元件通电后发热，雾化芯用于将待雾化液进行加热、蒸发、雾化成气溶胶或蒸汽、汽雾，以便用户吸食，用于健康医疗之用途。雾化芯是电子雾化器的关键部件，其性能优劣直接决定了电子雾化器的雾化效果，加热效率及使用体验。
目前市场上的雾化芯通常由导液棉加发热电阻丝、或陶瓷导液体和加热电阻丝组成，电阻丝与陶瓷导液体的结合方式有植入式、印刷式、贴片式等，不同的结合方式在传热效率上带来了一定程度的提升。现有的雾化芯，在待雾化液即将用完或传导不顺畅时，雾化芯的温度就会急剧升高，导致雾化芯发生干烧，雾化芯容易被烧损和产生烧焦的味道，给用户造成不良的使用体验。现有雾化芯的防止干烧的方法一般是检测温度，在温度升高到设定的阈值时，则关断供电电源停止使用。此种检测温度的方法由于是在待雾化液缺乏发生之后温度上升到一定程度才被检测到，具有一定的滞后性，不免还是有一定程度的干烧发生。
发明内容
本发明所要解决的技术问题是克服现有雾化芯防干烧不及时的问题，提供一种湿敏多孔陶瓷、雾化芯及其制备方法。
本发明的技术解决方案是，一种湿敏多孔陶瓷，由湿敏陶瓷材料制成，所述湿敏陶瓷材料按重量份包括如下组分：1-30份ZnCr2O4，1-10份ZnO，1-50份造孔剂，1-10份烧结助剂。
优选地，所述湿敏陶瓷材料按重量份包括如下组分：1-30份ZnCr2O4，1-5份ZnO，1-30份造孔剂，1-10份烧结助剂。
优选地，所述造孔剂为石墨、淀粉、面粉、豆粉、聚苯乙烯微球、聚甲基丙烯酸甲酯微球、碳酸盐、铵盐、蔗糖、纤维中的至少一种，所述造孔剂粒径为1～200微米。
优选地，所述烧结助剂为氧化硼、硼酸、油酸、硬脂酸、硅酸钠、氧化钙，氧化铝、氧化锂，氧化钾，氧化钠、碳酸钙、氧化镁、氧化铁中的一种或多种。
优选地，所述湿敏陶瓷材料按重量份还包括如下组分：纳米氧化硅1～40份。
优选地，所述纳米氧化硅为纳米二氧化硅，所述纳米二氧化硅为胶体状的纳米二氧化硅或粉体状的纳米二氧化硅。
优选地，所述湿敏多孔陶瓷的孔隙率是30～70％。
本发明的另一技术解决方案是，一种雾化芯，包括用于传导待雾化液的导液体和设于导液体上的发热元件，所述导液体由权利要求1～7任一项所述的湿敏多孔陶瓷制成。
本发明的又一技术解决方案是，一种湿敏多孔陶瓷的制备方法，包括以下步骤：
⑴将ZnO与Cr2O3按照摩尔比1:1混合，放入研磨装置中研磨，然后烘干，预烧制成ZnCr2O4；
⑵将步骤⑴中得到的ZnCr2O4与ZnO、造孔剂、烧结助剂混合，放入研磨装置中研磨，然后烘烤干燥，得到混合粉料；
⑶将石蜡加热至融化状态，边搅拌边加入所述混合粉料，加入完毕后继续搅拌1～8h，得到石蜡浆料；
⑷将所述石蜡浆料注入预先准备的模具中，冷却成型，脱模后得到蜡模；
⑸将所述蜡模放入炉中进行预加热进行除蜡，得到除蜡样；
⑹将所述除蜡样放入炉中并在保护气氛中进行烧结，烧结过程包括升温、保温、降温，冷却后得到湿敏多孔陶瓷。
优选地，所述步骤⑴中的预烧结温度为700-950℃。
优选地，所述步骤⑵中，ZnCr2O4与ZnO的摩尔比为10:1-10：30，烧结助剂为Al2O3、Li2O，K2O，Na2O、CaCO3、MgO、Fe2O3中的一种或多种，烧结助剂的重量含量为1-15％。
优选地，所述步骤⑴、⑵中，球磨装置的转速设为150～350rpm，球磨时间为1～12h，磨料直径为1～20mm。
优选地，所述步骤⑵中，烘烤干燥的温度为60～120℃，烘烤干燥的时间为2～12h。
优选地，所述步骤⑶中，所述石蜡的熔点为50～110℃，所述石蜡的重量为所述混合粉料重量的10～60％。
优选地，所述步骤⑸中，除蜡的温度为400～800℃，除蜡的时间为2～12h。
优选地，所述步骤⑹中，烧结的温度为1000-1500℃，升温速度1～5℃/min，烧结的保温时间为2～12h；烧结时的保护气氛为还原性气氛，还原性气氛包括氢气与氩气、氮气、氦气等气体的混合，其中氢气在混合气体中占比1-20％。
与现有技术相比，本发明的有益效果:
本发明利用湿敏材料在待雾化液的干湿度不同时具有不同电阻阻值的特性，将湿敏材料加入陶瓷基体材料中和多孔陶瓷做成一体式的湿敏多孔陶瓷，作为雾化芯的导液体，该导液体可传导待雾化液并具有对湿度敏感的电阻阻值，通过检测其电阻可测定其湿度，这样在导液体内缺乏待雾化液时其湿度减小并可被迅速检测到，从而及时减小功率或关停电源，可迅速、无延时地防止雾化芯发生干烧。
附图说明
图1是本发明的雾化芯的结构示意图。
具体实施方式
本发明中的湿敏材料是指材料的电阻值随所处环境的湿度变化而变化的功能材料，它是在电绝缘物质中渗入容易吸潮的物质，如氧化镁、氧化铬等加工而成。它能将湿度的变化通过电阻值转换成电的信号。湿敏材料可以实现湿度的自动指示、自动记录、自动控制与调节。
本发明的一种湿敏多孔陶瓷，由湿敏陶瓷材料制成，湿敏陶瓷材料按重量份包括如下组分：1-30份ZnCr2O4，1-10份ZnO，1-50份造孔剂，1-10份烧结助剂。
优选的，湿敏陶瓷材料按重量份包括如下组分：1-30份ZnCr2O4，1-5份ZnO，1-30份造孔剂，1-10份烧结助剂。
其中，造孔剂为石墨、淀粉、面粉、豆粉、聚苯乙烯微球、聚甲基丙烯酸甲酯微球、碳酸盐、铵盐、蔗糖、纤维中的至少一种，造孔剂粒径为1～200微米。
烧结助剂为氧化硼、硼酸、油酸、硬脂酸、硅酸钠、氧化钙，氧化铝、氧化锂，氧化钾，氧化钠、碳酸钙、氧化镁、氧化铁中的一种或多种。
湿敏陶瓷材料按重量份还包括如下组分：纳米氧化硅1～40份。纳米氧化硅为纳米二氧化硅，纳米二氧化硅为胶体状的纳米二氧化硅或粉体状的纳米二氧化硅。
湿敏多孔陶瓷的孔隙率是30～70％。
本发明的一种雾化芯，包括用于传导待雾化液的导液体和设于导液体上的发热元件，导液体由上述湿敏多孔陶瓷制成。
本发明的一种湿敏多孔陶瓷的制备方法，包括以下步骤：
⑴将ZnO与Cr2O3按照摩尔比1:1混合，放入研磨装置中研磨，然后烘干，预烧制成ZnCr2O4；
⑵将步骤⑴中得到的ZnCr2O4与ZnO、造孔剂、烧结助剂混合，放入研磨装置中研磨，然后烘烤干燥，得到混合粉料；
⑶将石蜡加热至融化状态，边搅拌边加入混合粉料，加入完毕后继续搅拌1～8h，得到石蜡浆料；
⑷将石蜡浆料注入预先准备的模具中，冷却成型，脱模后得到蜡模；
⑸将蜡模放入炉中进行预加热进行除蜡，得到除蜡样；
⑹将除蜡样放入炉中并在保护气氛中进行烧结，烧结过程包括升温、保温、降温，冷却后得到湿敏多孔陶瓷。
其中，步骤⑴中的预烧结温度为700-950℃。
步骤⑵中，ZnCr2O4与ZnO的摩尔比为10:1-10：30，烧结助剂为Al2O3、Li2O，K2O，Na2O、CaCO3、MgO、Fe2O3中的一种或多种，烧结助剂的重量含量为1-15％。
步骤⑴、⑵中，球磨装置的转速设为150～350rpm，球磨时间为1～12h，磨料直径为1～20mm。
步骤⑵中，烘烤干燥的温度为60～120℃，烘烤干燥的时间为2～12h。
步骤⑶中，石蜡的熔点为50～110℃，石蜡的重量为混合粉料重量的10～60％。
步骤⑸中，除蜡的温度为400～800℃，除蜡的时间为2～12h。
步骤⑹中，烧结的温度为1000-1500℃，升温速度1～5℃/min，烧结的保温时间为2～12h；烧结时的保护气氛为还原性气氛，还原性气氛包括氢气与氩气、氮气、氦气等气体的混合，其中氢气在混合气体中占比1-20％。
本发明下面将结合实施例作进一步详述：
实施例一
本发明实施例的湿敏多孔陶瓷，由湿敏陶瓷材料烧结制成，湿敏陶瓷材料按重量配比包括如下原料组分：20份ZnCr2O4，3份ZnO，30份造孔剂，7份烧结助剂。
实施例二
本发明实施例的湿敏多孔陶瓷，由湿敏陶瓷材料烧结制成，湿敏陶瓷材料按重量配比包括如下原料组分：20份ZnCr2O4，3份ZnO，30份造孔剂，7份烧结助剂，30份纳米二氧化硅，该纳米二氧化硅为粒径150nm的硅溶胶，硅溶胶的纳米二氧化硅的量以其中固体份二氧化硅计。
实施例三
本发明实施例的雾化芯，如图1所示，该雾化芯包括导液体1、发热元件(图中未示)、设于发热元件两端的正负电极2、与湿敏材料连接的湿度检测电极3，发热元件设于导液体1的内部，导液体1用于传导待雾化液，导液体1由前面实施例所述的湿敏多孔陶瓷制成，待雾化液自上而下流动到导液体1，导液液体1可传导、渗透待雾化液。导液体1内包括湿敏材料，湿敏材料具有一定的导电性和电阻，其电阻随湿度不同而变化，与湿敏材料连接设有湿度检测电极3，通过湿度检测电极3可检测导液体1内的湿度。
导液体1的湿度是指相对湿度，当导液体1完全吸收、渗透、及最大量地贮存待雾化液时，其湿度为100％，导液体1没有吸收待雾化液即完全干燥时，其湿度为0％。湿敏元件13可通过阻值变化感应导液体1的湿度。
实施例四
本发明实施例的湿敏多孔陶瓷的制备方法，包括以下步骤：
⑴将ZnO与Cr2O3按照摩尔比1:1混合，放入研磨装置中研磨，然后烘干，预烧形成ZnCr2O4；
⑵将步骤1中得到的ZnCr2O4与ZnO、湿敏陶瓷助剂、造孔剂混合，放入研磨装置中研磨，然后烘烤干燥，得到混合粉料；
⑶将石蜡加热至融化状态，边搅拌边加入所述混合粉料，加入完毕后继续搅拌1～8h，得到石蜡浆料；
⑷将所述石蜡浆料注入预先准备的模具中，冷却成型，脱模后得到蜡模；
⑸将所述蜡模放入炉中进行预加热进行除蜡，得到除蜡样；
⑹将所述除蜡样放入炉中并在保护气氛中进行烧结，烧结过程包括升温、保温、降温，得到湿敏多孔陶瓷。
其中，步骤⑴中的预烧结温度为800℃，步骤⑵中，ZnCr2O4与ZnO的摩尔比为10：20，烧结助剂包括Al2O3、Li2O，K2O，Fe2O3，烧结助剂的重量含量为10％。步骤⑴、⑵中，球磨装置的转速设为300rpm，球磨时间为10h，磨料直径为20mm。步骤⑵中，烘烤干燥的温度为100℃，烘烤干燥的时间为8h。步骤⑶中，石蜡的熔点为60℃，石蜡的重量为混合粉料重量的40％。步骤⑸中，除蜡的温度为600℃，除蜡的时间为12h。步骤⑹中，烧结的温度为1200℃，升温速度5℃/min，烧结的保温时间为10h；烧结时的保护气氛为还原性气氛，还原性气氛包括氢气与氩气的混合，其中氢气在混合气体中占比20％。
以上所述仅为本发明的较佳实施例，凡依本发明权利要求范围所做的均等变化与修饰，皆应属本发明权利要求的涵盖范围。

Claims (16)

1.一种湿敏多孔陶瓷，其特征在于，由湿敏陶瓷材料制成，所述湿敏陶瓷材料按重量份包括如下组分：1-30份ZnCr2O4，1-10份ZnO，1-50份造孔剂，1-10份烧结助剂。
2.根据权利要求1所述的湿敏多孔陶瓷，其特征在于，所述湿敏陶瓷材料按重量份包括如下组分：1-30份ZnCr2O4，1-5份ZnO，1-30份造孔剂，1-10份烧结助剂。
3.根据权利要求1所述的湿敏多孔陶瓷，其特征在于，所述造孔剂为石墨、淀粉、面粉、豆粉、聚苯乙烯微球、聚甲基丙烯酸甲酯微球、碳酸盐、铵盐、蔗糖、纤维中的至少一种，所述造孔剂粒径为1～200微米。
4.根据权利要求1所述的湿敏多孔陶瓷，其特征在于，所述烧结助剂为氧化硼、硼酸、油酸、硬脂酸、硅酸钠、氧化钙，氧化铝、氧化锂，氧化钾，氧化钠、碳酸钙、氧化镁、氧化铁中的一种或多种。
5.根据权利要求1所述的湿敏多孔陶瓷，其特征在于，所述湿敏陶瓷材料按重量份还包括如下组分：纳米氧化硅1～40份。
6.根据权利要求5所述的湿敏多孔陶瓷，其特征在于，所述纳米氧化硅为纳米二氧化硅，所述纳米二氧化硅为胶体状的纳米二氧化硅或粉体状的纳米二氧化硅。
7.根据权利要求1所述的湿敏多孔陶瓷，其特征在于，所述湿敏多孔陶瓷的孔隙率是30～70％。
8.一种雾化芯，其特征在于，包括用于传导待雾化液的导液体和设于导液体上的发热元件，所述导液体由权利要求1～7任一项所述的湿敏多孔陶瓷制成。
9.一种湿敏多孔陶瓷的制备方法，其特征在于，包括以下步骤：
⑴将ZnO与Cr2O3按照摩尔比1:1混合，放入研磨装置中研磨，然后烘干，预烧制成ZnCr2O4；
⑵将步骤⑴中得到的ZnCr2O4与ZnO、造孔剂、烧结助剂混合，放入研磨装置中研磨，然后烘烤干燥，得到混合粉料；
⑶将石蜡加热至融化状态，边搅拌边加入所述混合粉料，加入完毕后继续搅拌1～8h，得到石蜡浆料；
⑷将所述石蜡浆料注入预先准备的模具中，冷却成型，脱模后得到蜡模；
⑸将所述蜡模放入炉中进行预加热进行除蜡，得到除蜡样；
⑹将所述除蜡样放入炉中并在保护气氛中进行烧结，烧结过程包括升温、保温、降温，冷却后得到湿敏多孔陶瓷。
10.根据权利要求9所述的湿敏多孔陶瓷的制备方法，其特征在于，所述步骤⑴中的预烧结温度为700-950℃。
11.根据权利要求9所述的湿敏多孔陶瓷的制备方法，其特征在于，所述步骤⑵中，ZnCr2O4与ZnO的摩尔比为10:1-10：30，烧结助剂为Al2O3、Li2O，K2O，Na2O、CaCO3、MgO、Fe2O3中的一种或多种，烧结助剂的重量含量为1-15％。
12.根据权利要求9所述的湿敏多孔陶瓷的制备方法，其特征在于，所述步骤⑴、⑵中，球磨装置的转速设为150～350rpm，球磨时间为1～12h，磨料直径为1～20mm。
13.根据权利要求9所述的湿敏多孔陶瓷的制备方法，其特征在于，所述步骤⑵中，烘烤干燥的温度为60～120℃，烘烤干燥的时间为2～12h。
14.根据权利要求9所述的湿敏多孔陶瓷的制备方法，其特征在于，所述步骤⑶中，所述石蜡的熔点为50～110℃，所述石蜡的重量为所述混合粉料重量的10～60％。
15.根据权利要求9所述的湿敏多孔陶瓷的制备方法，其特征在于，所述步骤⑸中，除蜡的温度为400～800℃，除蜡的时间为2～12h。
16.根据权利要求9所述的湿敏多孔陶瓷的制备方法，其特征在于，所述步骤⑹中，烧结的温度为1000-1500℃，升温速度1～5℃/min，烧结的保温时间为2～12h；烧结时的保护气氛为还原性气氛，还原性气氛包括氢气与氩气、氮气、氦气等气体的混合，其中氢气在混合气体中占比1-20％。
CN202110025723.7A 2021-01-08 2021-01-08 湿敏多孔陶瓷、雾化芯及其制备方法 Pending CN112794713A (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202110025723.7A CN112794713A (zh) 2021-01-08 2021-01-08 湿敏多孔陶瓷、雾化芯及其制备方法
PCT/CN2021/131623 WO2022148144A1 (zh) 2021-01-08 2021-11-19 湿敏多孔陶瓷、雾化芯及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110025723.7A CN112794713A (zh) 2021-01-08 2021-01-08 湿敏多孔陶瓷、雾化芯及其制备方法

Publications (1)

Publication Number Publication Date
CN112794713A true CN112794713A (zh) 2021-05-14

Family

ID=75809483

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110025723.7A Pending CN112794713A (zh) 2021-01-08 2021-01-08 湿敏多孔陶瓷、雾化芯及其制备方法

Country Status (2)

Country Link
CN (1) CN112794713A (zh)
WO (1) WO2022148144A1 (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022148139A1 (zh) * 2021-01-08 2022-07-14 惠州市新泓威科技有限公司 具有湿敏元件的电子雾化设备及其防干烧控制方法
WO2022148144A1 (zh) * 2021-01-08 2022-07-14 惠州市新泓威科技有限公司 湿敏多孔陶瓷、雾化芯及其制备方法
CN115947619A (zh) * 2022-12-30 2023-04-11 深圳市爱斯强科技有限公司 一种湿敏发热浆料及其制备方法、雾化芯

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114956783B (zh) * 2022-08-02 2022-10-25 河北洁城新型建材有限公司 一种垃圾烧结砖及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1101453A (zh) * 1993-10-08 1995-04-12 北京新奇材料研究所 一种陶瓷湿敏元件的制作方法
JPH08327577A (ja) * 1995-05-31 1996-12-13 Ngk Spark Plug Co Ltd 感湿素子及びその製造方法
CN103653261A (zh) * 2013-12-13 2014-03-26 上海烟草集团有限责任公司 一种智能电子烟

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63194307A (ja) * 1987-02-09 1988-08-11 株式会社村田製作所 感湿セラミツク
CN103880410B (zh) * 2014-02-14 2015-06-17 江西理工大学 熔盐法合成ZnO-Cr2O3-Fe2O3系湿敏陶瓷烧结粉体方法
CN110713379B (zh) * 2019-12-02 2023-01-24 湖南福美来电子陶瓷有限公司 一种多孔陶瓷雾化芯及其制备方法
CN111205104A (zh) * 2020-01-14 2020-05-29 东莞市陶陶新材料科技有限公司 电子烟用多孔陶瓷及其制备方法
CN111792922A (zh) * 2020-07-10 2020-10-20 湖南云天雾化科技有限公司 一种高还原多孔陶瓷雾化芯及其制备方法
CN112794713A (zh) * 2021-01-08 2021-05-14 深圳市康泓威科技有限公司 湿敏多孔陶瓷、雾化芯及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1101453A (zh) * 1993-10-08 1995-04-12 北京新奇材料研究所 一种陶瓷湿敏元件的制作方法
JPH08327577A (ja) * 1995-05-31 1996-12-13 Ngk Spark Plug Co Ltd 感湿素子及びその製造方法
CN103653261A (zh) * 2013-12-13 2014-03-26 上海烟草集团有限责任公司 一种智能电子烟

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
张玉龙: "《纳米复合材料手册》", 31 July 2005 *
黄勇等: "敏感陶瓷材料的制备及展望", 《佛山陶瓷》 *
黄平等: "ZnCr2O4湿敏陶瓷工艺研究", 《太原理工大学学报》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022148139A1 (zh) * 2021-01-08 2022-07-14 惠州市新泓威科技有限公司 具有湿敏元件的电子雾化设备及其防干烧控制方法
WO2022148144A1 (zh) * 2021-01-08 2022-07-14 惠州市新泓威科技有限公司 湿敏多孔陶瓷、雾化芯及其制备方法
CN115947619A (zh) * 2022-12-30 2023-04-11 深圳市爱斯强科技有限公司 一种湿敏发热浆料及其制备方法、雾化芯
CN115947619B (zh) * 2022-12-30 2023-09-05 深圳市爱斯强科技有限公司 一种湿敏发热浆料及其制备方法、雾化芯

Also Published As

Publication number Publication date
WO2022148144A1 (zh) 2022-07-14

Similar Documents

Publication Publication Date Title
CN112794713A (zh) 湿敏多孔陶瓷、雾化芯及其制备方法
CN112830773A (zh) 湿敏多孔陶瓷、雾化芯及其制备方法
CN105294140B (zh) 多孔陶瓷的制备方法、多孔陶瓷及其应用
EP3162778B1 (en) Method for preparing porous ceramics
WO2022134889A1 (zh) 可发热的石墨烯多孔陶瓷、雾化芯及其制备方法
CN112811925A (zh) 湿敏多孔陶瓷、雾化芯及其制备方法
CN110467441A (zh) 用于雾化器的多孔陶瓷基板及其制作方法
CN111138175B (zh) 多孔陶瓷基板及其制备方法、雾化芯
KR20190040323A (ko) 서셉터 어셈블리 및 이를 포함하는 에어로졸 발생 물품
CN112790445A (zh) 除重金属多孔陶瓷的制备方法、除重金属的多孔陶瓷及雾化芯
CN105817569B (zh) 耐高温铸造砂及其制备方法
CN113429217A (zh) 多孔陶瓷基体的制备方法及雾化芯、雾化器、电子烟
CN113387572A (zh) 一种含空心玻璃粉的多孔材料及其制备方法与应用
CN110655379A (zh) 一种纳米复合隔热板及其制备方法
WO2023142359A1 (zh) 一种具有感应加热堵头的加热卷烟烟支及其适配烟具
CN210726703U (zh) 具有多孔隔热层的发热体及低温烟具
CN215066312U (zh) 具有湿敏元件的雾化芯
CN112489906B (zh) 一种ntc热敏电阻芯片及其制备方法
CN109892689A (zh) 一种吸附型降温滤嘴棒的生产工艺
CN104198564A (zh) 一种氧传感器保护层及其制备方法
CN218354690U (zh) 一种雾化结构以及雾化器
CN114956857A (zh) 一种加热植物型电子烟过滤器多孔陶瓷滤芯材料的制备方法
KR20230151446A (ko) 가열식 흡연 물품
Vinnik et al. Ceramic humidity sensors based on zirconium dioxide
CN117981922A (zh) 雾化芯及其制备方法和电子雾化器

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20211105

Address after: 516000 the fourth and fifth floors of No.1 Workshop of Zhonghai Technology (Huizhou) Co., Ltd. in Dayawan West District, Huizhou City, Guangdong Province

Applicant after: HUIZHOU HAPPY VAPING TECHNOLOGY Ltd.

Address before: 518104 building A1, sha'er Industrial Park, Ditang Road, Shajing street, Bao'an District, Shenzhen City, Guangdong Province

Applicant before: SHENZHEN HAPPY VAPING TECHNOLOGY Ltd.

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20210514