CN112745687A - 一种生物质重油改性沥青材料及其制备方法 - Google Patents
一种生物质重油改性沥青材料及其制备方法 Download PDFInfo
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- CN112745687A CN112745687A CN201911040853.7A CN201911040853A CN112745687A CN 112745687 A CN112745687 A CN 112745687A CN 201911040853 A CN201911040853 A CN 201911040853A CN 112745687 A CN112745687 A CN 112745687A
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- Prior art keywords
- asphalt
- parts
- heavy oil
- oil
- modified asphalt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000010426 asphalt Substances 0.000 title claims abstract description 158
- 239000000463 material Substances 0.000 title claims abstract description 109
- 239000002028 Biomass Substances 0.000 title claims abstract description 76
- 239000000295 fuel oil Substances 0.000 title claims abstract description 57
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- XPVIQPQOGTVMSU-UHFFFAOYSA-N (4-acetamidophenyl)arsenic Chemical compound CC(=O)NC1=CC=C([As])C=C1 XPVIQPQOGTVMSU-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229920013640 amorphous poly alpha olefin Polymers 0.000 claims abstract description 34
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 239000011159 matrix material Substances 0.000 claims abstract description 8
- 239000003208 petroleum Substances 0.000 claims description 32
- 238000003756 stirring Methods 0.000 claims description 24
- 239000012075 bio-oil Substances 0.000 claims description 20
- 239000003921 oil Substances 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 16
- 230000035515 penetration Effects 0.000 claims description 15
- 238000010008 shearing Methods 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 238000000197 pyrolysis Methods 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 8
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000004711 α-olefin Substances 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000012423 maintenance Methods 0.000 claims description 3
- 238000005292 vacuum distillation Methods 0.000 claims description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 2
- 239000002199 base oil Substances 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 238000004821 distillation Methods 0.000 claims description 2
- -1 ethylene, propylene, 1-butene Chemical class 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- 238000007670 refining Methods 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims 1
- 230000007547 defect Effects 0.000 abstract description 6
- 239000002023 wood Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 10
- 235000011613 Pinus brutia Nutrition 0.000 description 10
- 241000018646 Pinus brutia Species 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 239000002131 composite material Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229920005604 random copolymer Polymers 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000002557 mineral fiber Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 239000010909 process residue Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000974 shear rheometry Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
项目 | 生物质重油 | 石油基质沥青 | APAO | DOA | 相容剂 | 沥青材料 |
实施例1 | 6 | 100 | 5 | 2 | 3 | A1 |
实施例2 | 12 | 100 | 10 | 3 | 5 | A2 |
实施例3 | 18 | 100 | 15 | 4 | 8 | A3 |
比较例1 | 6 | 100 | - | 2 | 3 | A4 |
比较例2 | - | 100 | 5 | 2 | 3 | A5 |
比较例3 | 6 | 100 | 7 | - | 3 | A6 |
沥青材料 | 基质沥青 | A1 | A2 | A3 | A4 | A5 | A6 | I-C类技术要求 |
针入度25℃/0.1mm | 61 | 65 | 66 | 67 | 74 | 63 | 70 | 60~80 |
针入度指数PI | -1.1 | 0.8 | 0.5 | 0.4 | -0.1 | 0.9 | 0.2 | ≥-0.4 |
软化点/℃ | 47.7 | 86.5 | 85.8 | 85.2 | 56.2 | 87.0 | 79.1 | ≥55 |
延度5℃/cm | - | 35 | 36 | 38 | 44 | 26 | 37 | ≥30 |
延度10℃/cm | 45 | - | - | - | - | - | - | - |
135℃运动粘度/(Pa·s) | 0.8 | 2.2 | 2.0 | 1.9 | 1.6 | 2.5 | 1.8 | ≤3 |
储存稳定性,48h软化点差/℃ | - | 1.4 | 1.5 | 1.6 | 0.1 | 5.1 | 1.5 | ≤2.5 |
TFOT后针入度比(25℃) | 65.8 | 76.2 | 75.4 | 76.0 | 68.8 | 75.0 | 74.1 | ≥60 |
温度/℃ | 基质沥青 | A1 | A2 | A3 | A4 | A5 | A6 |
64 | 3.62 | 7.91 | 7.73 | 7.82 | 5.90 | 5.96 | 5.81 |
70 | 1.95 | 4.02 | 3.86 | 4.01 | 2.02 | 2.31 | 3.55 |
76 | 0.91 | 1.62 | 1.53 | 1.60 | 1.02 | 0.98 | 1.51 |
82 | 0.65 | 0.97 | 0.95 | 0.97 | 0.71 | 0.77 | 0.88 |
Claims (13)
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CN112745687A true CN112745687A (zh) | 2021-05-04 |
CN112745687B CN112745687B (zh) | 2023-05-05 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113717687A (zh) * | 2021-09-09 | 2021-11-30 | 昆山科顺防水材料有限公司 | 环保型改性沥青自粘涂盖料组合物、环保型改性沥青自粘涂盖料及其制备方法和应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3068079B1 (ja) * | 1999-02-08 | 2000-07-24 | 日進化成株式会社 | 道路舗装用改質アスファルト、その製造方法、並びに道路舗装用改質アスファルトにおける相分離抑制方法 |
CN105038832A (zh) * | 2015-07-31 | 2015-11-11 | 长安大学 | 一种道路用生物沥青及其制备装置和制备方法 |
CN105482475A (zh) * | 2016-01-13 | 2016-04-13 | 河海大学 | 一种复合改性硬质沥青及其制备方法 |
-
2019
- 2019-10-30 CN CN201911040853.7A patent/CN112745687B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3068079B1 (ja) * | 1999-02-08 | 2000-07-24 | 日進化成株式会社 | 道路舗装用改質アスファルト、その製造方法、並びに道路舗装用改質アスファルトにおける相分離抑制方法 |
CN105038832A (zh) * | 2015-07-31 | 2015-11-11 | 长安大学 | 一种道路用生物沥青及其制备装置和制备方法 |
CN105482475A (zh) * | 2016-01-13 | 2016-04-13 | 河海大学 | 一种复合改性硬质沥青及其制备方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113717687A (zh) * | 2021-09-09 | 2021-11-30 | 昆山科顺防水材料有限公司 | 环保型改性沥青自粘涂盖料组合物、环保型改性沥青自粘涂盖料及其制备方法和应用 |
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Effective date of registration: 20231114 Address after: 100728 No. 22 North Main Street, Chaoyang District, Beijing, Chaoyangmen Patentee after: CHINA PETROLEUM & CHEMICAL Corp. Patentee after: Sinopec (Dalian) Petrochemical Research Institute Co.,Ltd. Address before: 100728 No. 22 North Main Street, Chaoyang District, Beijing, Chaoyangmen Patentee before: CHINA PETROLEUM & CHEMICAL Corp. Patentee before: DALIAN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC Corp. |