CN112646491A - Odorless environment-friendly non-cured rubber asphalt waterproof coating and preparation method thereof - Google Patents
Odorless environment-friendly non-cured rubber asphalt waterproof coating and preparation method thereof Download PDFInfo
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Abstract
An odor-free environment-friendly non-cured rubber asphalt waterproof coating and a preparation method thereof, belonging to the technical field of building waterproof materials. The composition is characterized by comprising the following raw materials in parts by weight: 40-60 parts of petroleum asphalt, 10-30 parts of a compatilizer, 3-10 parts of a modifier, 5-20 parts of a tackifier, 5-20 parts of waste rubber powder, 5-25 parts of an adsorbent and 0.5-2.5 parts of a deodorant; the deodorant is a mixture of zinc ricinoleate and zinc oxide in a weight ratio of 1: 0.5-5. The preparation method comprises the following steps: 1) heating and mixing the modifier and the compatilizer; 2) adding petroleum asphalt, heating and mixing; 3) adding tackifying resin, waste rubber powder, adsorbent and deodorant, and heating and mixing. The odorless environment-friendly non-cured rubber asphalt waterproof coating has no odor and no harmful gas release in the heating application process, and has good extensibility and heat resistance.
Description
Technical Field
The invention particularly relates to a smell-free environment-friendly non-cured rubber asphalt waterproof coating and a preparation method thereof, belonging to the technical field of building waterproof materials.
Background
The rubber powder is one of the components of the non-cured rubber asphalt waterproof coating, and mainly comes from rubber products such as waste tires, waste rubber shoes and the like. The rubber powder is added into the asphalt, so that the waste rubber can be reasonably utilized, the pressure of the waste rubber on the environment is relieved, the high-temperature stability and the low-temperature crack resistance of the asphalt can be improved, the waste rubber can be recycled, and the environment can be protected. The rubber powder is added into the non-cured rubber asphalt, so that the production cost can be reduced, and the performance of the non-cured rubber asphalt can be improved, thereby having economic, social and environmental benefits.
In recent years, the non-cured rubber asphalt waterproof coating is greatly popularized and applied in the field of building waterproofing, but the preparation temperature of the non-cured rubber asphalt waterproof coating is mostly 180 ℃ or above, the temperature is high, the rubber powder is partially decomposed at high temperature, harmful gases such as hydrogen sulfide, sulfur dioxide, organic amine and the like are easily generated, the taste is extremely unpleasant, certain pollution is caused to the environment, and certain influence is also caused to the health of production and construction personnel. The production of harmful gas in the preparation process of the non-cured rubber asphalt waterproof coating is reduced, the environmental protection is improved, and the development trend of the non-cured rubber asphalt waterproof coating is shown.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: aiming at the defects in the prior art, the odorless environment-friendly non-cured rubber asphalt waterproof coating and the preparation method thereof are provided, and the waterproof coating has no odor and no harmful gas release in the heating application process.
The invention is realized by the following technical scheme: the odorless environment-friendly non-cured rubber asphalt waterproof coating is prepared from the following raw materials in parts by weight: 40-60 parts of petroleum asphalt, 10-30 parts of a compatilizer, 3-10 parts of a modifier, 5-20 parts of a tackifier, 5-20 parts of waste rubber powder, 5-25 parts of an adsorbent and 0.5-2.5 parts of a deodorant; the deodorant is a mixture of zinc ricinoleate and zinc oxide in a weight ratio of 1: 0.5-5.
The odorless environment-friendly non-cured rubber asphalt waterproof coating is prepared from the following raw materials in parts by weight: 40-50 parts of petroleum asphalt, 20-25 parts of a compatilizer, 6-7 parts of a modifier, 7-12 parts of a tackifier, 8-14 parts of waste rubber powder, 10-15 parts of an adsorbent and 1-2 parts of a deodorant; the deodorant is a mixture of zinc ricinoleate and zinc oxide in a weight ratio of 1: 1-4.
The petroleum asphalt is one or a mixture of more of No. 110 road petroleum asphalt, No. 70 road petroleum asphalt and No. 90 road petroleum asphalt.
The compatilizer is one or a mixture of more of aromatic oil, naphthenic oil and reduced line oil. Preferably, the compatibilizer is naphthenic oil.
The modifier is SBS (chemical name is styrene-butadiene-styrene block copolymer) or the mixture of SBS and SIS (chemical name is polystyrene-polyisoprene-polystyrene block copolymer). When the mixture of SBS and SIS is adopted, preferably, SBS and SIS are mixed according to the mass ratio of 3-4: 1.
The SBS is linear, and the block ratio is S/B = 30-40/60-70; the SIS is linear, and the block ratio is S/I = 15-30/70-85. Preferably, the SBS molecular weight is within 10 million and the SIS molecular weight is within 50 million.
The tackifier is one or a mixture of more of coumarone resin, terpene resin, rosin resin, carbon five petroleum resin and carbon nine petroleum resin. Preferably, the tackifier is a terpene resin.
The waste rubber powder is 60-120 meshes of waste tire rubber powder. Preferably, the waste rubber powder is 80-mesh waste tire rubber powder.
The adsorbent is one or a mixture of more of zeolite powder, diatomite and activated clay. The raw materials are nontoxic and nonirritant, have strong adsorbability, can improve the heat resistance of the non-cured rubber asphalt waterproof coating, reduce the production cost, and can adsorb pungent smell generated in the production process, especially the pungent smell generated by heating waste rubber powder.
The preparation method of the odorless environment-friendly non-cured rubber asphalt waterproof coating comprises the following steps:
1) weighing the modifier and the compatilizer according to the parts by weight, mixing, heating to 120-150 ℃, stirring for 20-30 min by a medium-speed stirrer at the rotating speed of 300-500 r/min to obtain a mixture;
2) adding petroleum asphalt into the mixture obtained in the step 1) according to the weight part, heating to 160-180 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
3) adding tackifying resin, waste rubber powder, an adsorbent and a deodorant into the mixed material obtained in the step 2) in sequence according to parts by weight, maintaining the temperature at 160-180 ℃, stirring with a medium-speed stirrer for 30-60 min at a rotating speed of 600-1000 r/min, and then cooling to obtain the adhesive.
According to the invention, a mixture of zinc ricinoleate and zinc oxide in a weight ratio of 1: 0.5-5 is used as a deodorant, and the deodorant can radically and rapidly eliminate odor through a chemical reaction with harmful gases in the coating. Wherein zinc ricinoleate is used as a main deodorant and reacts with sulfur-containing compounds, amino nitrogen and the like; the zinc oxide can react with hydrogen sulfide and sulfur dioxide to remove odor, and can promote the crosslinking of sulfur in rubber powder and SBS, so that the non-cured rubber asphalt waterproof coating system is more stable. Preferably, the smell removing agent is a mixture of zinc ricinoleate and zinc oxide in a weight ratio of 1: 1-4, and the smell removing effect is better under the mixture ratio.
Compared with the prior art, the odorless environment-friendly non-cured rubber asphalt waterproof coating and the preparation method thereof have the beneficial effects that:
1. the odor-free environment-friendly non-cured rubber asphalt waterproof coating has no odor and no harmful gas release in the application process. The non-cured rubber asphalt waterproof coating material preferably takes a non-toxic and non-irritant odor-free raw material with strong adsorption capacity as a filler, and absorbs part of irritant gases through physical adsorption; the smell removing agent is adopted, and the generation of harmful gas is rapidly eliminated through chemical reaction. The dual functions of the physical adsorbent and the chemical reaction inhibit the generation of harmful gas in the production process of the non-cured rubber asphalt waterproof coating, remove odor, reduce pollution to the environment, and simultaneously release no harmful gas in the application process of product heating construction, thereby being beneficial to the health of production and constructors.
2. The odorless environment-friendly non-cured rubber asphalt waterproof coating has good extensibility and heat resistance. The applicant adds specific SBS in the formula of the invention or the specific SBS is matched with SIS to be used as a modifier, thus obviously improving the heat resistance, low temperature flexibility and extensibility of the odor-free environment-friendly non-cured rubber asphalt waterproof coating.
Detailed Description
Embodiments 1 to 5 are specific embodiments of the odorless environment-friendly non-curable rubber asphalt waterproof coating and the preparation method thereof. Of these, example 2 is the most preferred example. Comparative examples 1 to 4 are comparative examples designed by the applicant.
The resins and auxiliaries used in the examples and comparative examples are as follows:
the No. 110 road petroleum asphalt is produced by Liaohe petrochemical industry, and has a softening point of 40-50 ℃.
No. 70 road petroleum asphalt, manufactured by the Chinese petro-chemical Qilu division, has a softening point of 44-54 ℃.
No. 90 road petroleum asphalt, produced by the Kimura chemical, has a softening point of 42-52 ℃.
The waste tire rubber powder is produced by Qingdao commercial rubber Co., Ltd, and the particle size is 80 meshes.
The coumarone resin is prepared by Shanghai Bao Steel chemical industry Co., Ltd, and has a softening point of 80-100 ℃.
The terpene resin is produced by Jiangxi Jinlin chemical Limited company, and has a mark number of JL-T100 and a softening point of 80-120 ℃.
The rosin resin is produced by chemical industry Co., Ltd, daily forest products in Guangxi Wuzhou, and the softening point is more than or equal to 85 ℃.
The carbon five petroleum resin is produced by Shandong Qigong chemical Co., Ltd, and has a softening point of 90-110 ℃.
The carbon-nine petroleum resin is produced by Shandong Qigong chemical Co., Ltd, and has a softening point of 90-120 ℃.
Zinc ricinoleate is produced by Jinnan chemical plant of Hejian city and has a particle size of 200 meshes.
Zinc oxide, produced by Nippon Zinc barium industries, Inc., is in nanometer level.
Zeolite powder, produced by processing plants of Jiayuan mineral products in Lingshu county, with particle size of 325 mesh.
Diatomaceous earth, produced by Shunfo mineral processing plant of Lingshou county, with particle size of 325 mesh.
The particle size of the activated clay, Zichuan Yangxianghua bentonite processing plant is 200 meshes.
Aromatic oil is produced by China petrochemical Ministry of Ministry, the flash point is more than 230 ℃, and the aniline point is 40-50 ℃.
Naphthenic oil KN4008, produced by the company Clarity, medium petroleum, having a flash point greater than 200 ℃ and an aniline point greater than 100 ℃.
Reduced four-line oil, produced by the China petrochemical Minn division company, has a flash point of greater than 230 ℃ and an aniline point of less than 50 ℃.
SBS1301, produced by the mesopetro-chemical barlin division, linear, with a block ratio S/B = 30/70.
SBS1401, produced by the petrochemical holy division, linear, with block ratio S/B = 40/60.
SBS4303, manufactured by the medium petrochemical yanshan division, star-shaped, with a block ratio S/B = 40/60.
SIS1209, produced by the petrochemical holy division, with a block ratio S/I = 25/75.
Example 1
The non-cured rubber asphalt waterproof coating comprises the following raw materials in parts by weight: 60 parts of No. 70 road petroleum asphalt, 10 parts of naphthenic oil, 130110 parts of SBS, 20 parts of terpene resin, 20 parts of 80-mesh waste tire rubber powder, 25 parts of zeolite powder, 1 part of zinc ricinoleate and 1 part of zinc oxide;
the preparation method comprises the following steps:
1) weighing SBS1301 and naphthenic oil according to parts by weight, mixing, heating to 120-150 ℃, stirring for 20-30 min by using a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
2) adding No. 70 road petroleum asphalt into the mixture obtained in the step 1) according to weight, heating to 160-180 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
3) adding terpene resin, 80-mesh waste tire rubber powder, zeolite powder, zinc ricinoleate and zinc oxide into the mixture obtained in the step 2) in sequence according to parts by weight, maintaining the temperature at 160-180 ℃, stirring with a high-speed stirrer for 30-60 min at the rotating speed of 600-1000 r/min, and then cooling to obtain the material.
Example 2
The non-cured rubber asphalt waterproof coating comprises the following raw materials in parts by weight: 40 parts of No. 110 road petroleum asphalt, 20 parts of naphthenic oil, 43036 parts of SBS, 12 parts of coumarone resin, 14 parts of 100-mesh waste tire rubber powder, 15 parts of diatomite, 0.5 part of zinc ricinoleate and 1.5 parts of zinc oxide;
the preparation method comprises the following steps:
1) weighing SBS4303 and naphthenic oil according to parts by weight, mixing, heating to 120-150 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
2) adding No. 110 road petroleum asphalt into the mixture obtained in the step 1) according to the weight part, heating to 160-180 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
3) adding coumarone resin, 100-mesh waste tire rubber powder, diatomite, zinc ricinoleate and zinc oxide into the mixed material obtained in the step 2) in sequence according to parts by weight, maintaining the temperature at 160-180 ℃, stirring for 30-60 min by using a high-speed stirrer at the rotating speed of 600-1000 r/min, and then cooling to obtain the product.
Example 3
The non-cured rubber asphalt waterproof coating comprises the following raw materials in parts by weight: 50 parts of No. 90 road petroleum asphalt, 30 parts of naphthenic oil, 13017 parts of SBS, 5 parts of terpene resin, 5 parts of 120-mesh waste tire rubber powder, 5 parts of activated clay, 0.3 part of zinc ricinoleate and 1.0 part of zinc oxide;
the preparation method comprises the following steps:
1) weighing SBS1301 and naphthenic oil according to parts by weight, mixing, heating to 120-150 ℃, stirring for 20-30 min by using a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
2) adding No. 90 road petroleum asphalt into the mixture obtained in the step 1) according to parts by weight, heating to 160-180 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
3) sequentially adding terpene resin, 120-mesh waste tire rubber powder, activated clay, zinc ricinoleate and zinc oxide into the mixed material obtained in the step 2) according to the weight part, maintaining the temperature at 160-180 ℃, stirring for 30-60 min by a high-speed stirrer at the rotating speed of 600-1000 r/min, and then cooling to obtain the material.
Example 4
The non-cured rubber asphalt waterproof coating comprises the following raw materials in parts by weight: 53 parts of No. 110 road petroleum asphalt, 22 parts of aromatic oil, 14013 parts of SBS, 8 parts of carbon-nine petroleum resin, 10 parts of 60-mesh waste tire rubber powder, 10 parts of zeolite powder, 0.4 part of zinc ricinoleate and 1.6 parts of zinc oxide;
the preparation method comprises the following steps:
1) weighing SBS1401 and aromatic oil according to parts by weight, mixing, heating to 120-150 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
2) adding No. 110 road petroleum asphalt into the mixture obtained in the step 1) according to the weight part, heating to 160-180 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
3) sequentially adding carbon-nine petroleum resin, 60-mesh waste tire rubber powder, zeolite powder, zinc ricinoleate and zinc oxide into the mixed material obtained in the step 2) according to parts by weight, maintaining the temperature at 160-180 ℃, stirring for 30-60 min by using a high-speed stirrer at the rotating speed of 600-1000 r/min, and then cooling to obtain the catalyst.
Example 5
The non-cured rubber asphalt waterproof coating comprises the following raw materials in parts by weight: 55 parts of No. 70 road petroleum asphalt, 25 parts of minus line oil, 6 parts of a mixture of SBS1301 and SIS according to the mass ratio of 2:1, 8 parts of carbon five petroleum resin, 16 parts of 70-mesh waste tire rubber powder, 10 parts of zeolite powder, 0.3 part of zinc ricinoleate and 1.5 parts of zinc oxide;
the preparation method comprises the following steps:
1) weighing a mixture of SBS1301 and SIS in a mass ratio of 2:1 and reduced line oil in parts by weight, mixing, heating to 120-150 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
2) adding No. 90 road petroleum asphalt into the mixture obtained in the step 1) according to parts by weight, heating to 160-180 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
3) adding carbon five petroleum resin, 70-mesh waste tire rubber powder, zeolite powder, zinc ricinoleate and zinc oxide into the mixed material obtained in the step 2) in sequence according to parts by weight, maintaining the temperature at 160-180 ℃, stirring for 30-60 min by using a high-speed stirrer at the rotating speed of 600-1000 r/min, and then cooling to obtain the catalyst.
Example 6
The non-cured rubber asphalt waterproof coating comprises the following raw materials in parts by weight: 48 parts of No. 90 road petroleum asphalt, 20 parts of aromatic oil, SBS1301 and SIS in a mass ratio of 4:1, 10 parts of mixture, 8 parts of rosin resin, 12 parts of 100-mesh waste tire rubber powder, zeolite powder and diatomite according to a mass ratio of 1:1 mixture of 16 parts, 1 part of zinc ricinoleate and 0.5 part of zinc oxide;
the preparation method comprises the following steps:
1) weighing SBS1401 and naphthenic oil according to parts by weight, mixing, heating to 120-150 ℃, stirring for 20-30 min by a medium-speed stirrer at the rotating speed of 300-500 r/min to obtain a mixture;
2) adding No. 90 road petroleum asphalt into the mixture obtained in the step 1) according to parts by weight, heating to 160-180 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
3) sequentially adding rosin resin, 100-mesh waste tire rubber powder, zeolite powder and diatomite into the mixed material obtained in the step 2) according to the weight ratio of 1:1, maintaining the temperature of 160-180 ℃, stirring for 30-60 min by a high-speed stirrer at the rotating speed of 600-1000 r/min, and then cooling to obtain the zinc ricinoleate zinc oxide zinc castor oil.
Example 7
The non-cured rubber asphalt waterproof coating comprises the following raw materials in parts by weight: 50 parts of No. 90 road petroleum asphalt, 10 parts of naphthenic oil, 14015 parts of SBS, 8 parts of mixture of terpene resin and coumarone resin according to the mass ratio of 1:1, 15 parts of 110-mesh waste tire rubber powder, 10 parts of zeolite powder, 0.6 part of zinc ricinoleate and 1.4 parts of zinc oxide;
the preparation method comprises the following steps:
1) weighing SBS1401 and naphthenic oil according to parts by weight, mixing, heating to 120-150 ℃, stirring for 20-30 min by a medium-speed stirrer at the rotating speed of 300-500 r/min to obtain a mixture;
2) adding No. 90 road petroleum asphalt into the mixture obtained in the step 1) according to parts by weight, heating to 160-180 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
3) sequentially adding a mixture of terpene resin and coumarone resin, 110-mesh waste tire rubber powder, zeolite powder, zinc ricinoleate and zinc oxide into the mixed material obtained in the step 2) according to the mass ratio of 1:1, maintaining the temperature at 160-180 ℃, stirring for 30-60 min by a high-speed stirrer at the rotating speed of 600-1000 r/min, and then cooling to obtain the product.
Example 8
The non-cured rubber asphalt waterproof coating comprises the following raw materials in parts by weight: 45 parts of No. 110 road petroleum asphalt, 10 parts of naphthenic oil, 8 parts of a mixture of SBS1401 and SIS according to a mass ratio of 3:1, 8 parts of a mixture of terpene resin and carbon five petroleum resin according to a mass ratio of 2:1, 14 parts of 90-mesh waste tire rubber powder, 10 parts of a mixture of zeolite powder and diatomite according to a mass ratio of 1:1, 0.5 part of zinc ricinoleate and 1.0 part of zinc oxide;
the preparation method comprises the following steps:
1) weighing a mixture of SBS1401 and SIS in a mass ratio of 2:1 and naphthenic oil in parts by weight, mixing, heating to 120-150 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
2) adding No. 110 road petroleum asphalt into the mixture obtained in the step 1) according to the weight part, heating to 160-180 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
3) sequentially adding terpene resin and carbon five petroleum resin mixture according to the mass ratio of 2:1, 90-mesh waste tire rubber powder, zeolite powder and diatomite mixture according to the mass ratio of 1:1, zinc ricinoleate and zinc oxide into the mixed material obtained in the step 2), maintaining the temperature at 160-180 ℃, stirring with a high-speed stirrer for 30-60 min at the rotating speed of 600-1000 r/min, and then cooling to obtain the material.
Comparative example 1
The waterproof coating of the comparative example has the same raw material composition ratio and preparation method as those of example 1, and is different from the following steps: no zinc oxide was added.
Comparative example 2
The waterproof coating of the comparative example has the same raw material composition ratio and preparation method as those of example 1, and is different from the following steps: no zinc ricinoleate was added.
Comparative example 3
The waterproof coating of the comparative example is prepared from the following raw materials in the same proportion as in example 1, and has the following difference:
the preparation method comprises the following steps:
weighing No. 70 road petroleum asphalt, naphthenic oil, SBS1301, terpene resin, 80-mesh waste tire rubber powder, zeolite powder, zinc ricinoleate and zinc oxide in parts by weight, adding into a high-speed stirrer, stirring and mixing, maintaining the temperature at 160-180 ℃, stirring for 60min at the rotating speed of 600-1000 r/min, and then cooling to obtain the road petroleum asphalt.
Comparative example 4
The waterproof coating of the comparative example has the same raw material composition ratio and preparation method as those of example 1, and is different from the following steps: replacing zeolite powder with calcium carbonate.
Performance testing
The coatings obtained in the examples and the comparative examples are detected according to the non-cured rubber asphalt coating industry standard JCT2428-2017, and the detection data is recorded in the table below.
Table 1 examples 1-4 test results
Table 2 results of tests in examples 5 to 8
TABLE 3 test results of comparative examples 1 to 4
The test results of the above examples and comparative examples show that: the odor-free environment-friendly non-cured rubber asphalt waterproof coating prepared by the invention has good heat resistance, low-temperature flexibility and extensibility which reach the quality standard, and good waterproof effect, and simultaneously removes harmful gases in the production and use processes, thereby being beneficial to environmental protection.
While the invention has been described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. However, any simple modification, equivalent change and modification of the above embodiments according to the technical essence of the present invention are within the protection scope of the technical solution of the present invention.
Claims (10)
1. The odorless environment-friendly non-cured rubber asphalt waterproof coating is characterized by comprising the following raw materials in parts by weight: 40-60 parts of petroleum asphalt, 10-30 parts of a compatilizer, 3-10 parts of a modifier, 5-20 parts of a tackifier, 5-20 parts of waste rubber powder, 5-25 parts of an adsorbent and 0.5-2.5 parts of a deodorant; the deodorant is a mixture of zinc ricinoleate and zinc oxide in a weight ratio of 1: 0.5-5.
2. The odor-free environment-friendly non-cured rubber asphalt waterproof coating material as claimed in claim 1, which is characterized by comprising the following raw materials in parts by weight: 40-50 parts of petroleum asphalt, 20-25 parts of a compatilizer, 6-7 parts of a modifier, 7-12 parts of a tackifier, 8-14 parts of waste rubber powder, 10-15 parts of an adsorbent and 1-2 parts of a deodorant; the deodorant is a mixture of zinc ricinoleate and zinc oxide in a weight ratio of 1: 1-4.
3. The odor-free environment-friendly non-curing rubber asphalt waterproof coating material as claimed in claim 1, which is characterized in that: the petroleum asphalt is one or a mixture of more of No. 110 road petroleum asphalt, No. 70 road petroleum asphalt and No. 90 road petroleum asphalt.
4. The odor-free environment-friendly non-curing rubber asphalt waterproof coating material as claimed in claim 1, which is characterized in that: the compatilizer is one or a mixture of more of aromatic oil, naphthenic oil and reduced line oil.
5. The odor-free environment-friendly non-curing rubber asphalt waterproof coating material as claimed in claim 1, which is characterized in that: the modifier is SBS or the mixture of SBS and SIS.
6. The odor-free environment-friendly non-curing rubber asphalt waterproof coating material as claimed in claim 5, which is characterized in that: the SBS is linear, and the block ratio is S/B = 30-40/60-70; the SIS is linear, and the block ratio is S/I = 15-30/70-85.
7. The odor-free environment-friendly non-curing rubber asphalt waterproof coating material as claimed in claim 1, which is characterized in that: the tackifier is one or a mixture of more of coumarone resin, terpene resin, rosin resin, carbon five petroleum resin and carbon nine petroleum resin.
8. The odor-free environment-friendly non-curing rubber asphalt waterproof coating material as claimed in claim 1, which is characterized in that: the waste rubber powder is 60-120 meshes of waste tire rubber powder.
9. The odor-free environment-friendly non-curing rubber asphalt waterproof coating material as claimed in claim 1, which is characterized in that: the adsorbent is one or a mixture of more of zeolite powder, diatomite and activated clay.
10. The preparation method of the odorless environment-friendly non-curable rubber asphalt waterproof coating material as claimed in any one of claims 1 to 9, which is characterized by comprising the following steps:
1) weighing the modifier and the compatilizer according to the parts by weight, mixing, heating to 120-150 ℃, stirring for 20-30 min by a medium-speed stirrer at the rotating speed of 300-500 r/min to obtain a mixture;
2) adding petroleum asphalt into the mixture obtained in the step 1) according to the weight part, heating to 160-180 ℃, stirring for 20-30 min by a medium-speed stirrer at a rotating speed of 300-500 r/min to obtain a mixture;
3) adding tackifying resin, waste rubber powder, an adsorbent and a deodorant into the mixture obtained in the step 2) in sequence according to parts by weight, maintaining the temperature at 160-180 ℃, stirring for 30-60 min by using a medium-speed stirrer at the rotating speed of 600-1000 r/min, and then cooling to obtain the adhesive.
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