CN112646467A - Wear-resistant high-transparency super-smooth PU open matte top-coat paint and preparation method thereof - Google Patents
Wear-resistant high-transparency super-smooth PU open matte top-coat paint and preparation method thereof Download PDFInfo
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
- C08G18/725—Combination of polyisocyanates of C08G18/78 with other polyisocyanates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/795—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of mixtures of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates with aromatic isocyanates or isothiocyanates
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention belongs to the technical field of coatings. A wear-resistant high-transparency super-smooth PU open matte top-coat paint comprises a component A, a component B and a diluent, wherein the mass ratio of the component A to the component B is 10: 5-6; the component A comprises: hydroxyl acrylic resin, a wetting dispersant, polyamide anti-settling slurry, an antioxidant, an ultraviolet light absorber, aldehyde ketone resin, wax powder, glass powder, extinction powder, CAB cellulose, ether ester solvents, a defoaming agent, a leveling agent and a drier; the component B comprises: n-butyl acetate, a dehydrating agent, aromatic polyisocyanate and aliphatic polyisocyanate. The paint film has high hardness, good yellowing resistance, chemical resistance, scratch resistance and wear resistance, good solid wood texture and high transparency when being applied to the surface of technical wood, and the paint film is clear, not bloated and good in matte effect.
Description
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to a wear-resistant high-transmittance super-smooth PU open type matte top-coat paint and a preparation method thereof.
Background
Along with the improvement of the physical living and cultural living standard of people, the living environment and the home taste are improved, and the selection of furniture materials is more diversified. In recent years, the scientific and technological veneer sheets are well favored by vast furniture manufacturers, occupy an indispensable position in home production, and are also favored by vast consumers. The scientific and technological veneer which is beautified and processed by adopting scientific and technological means to the log is taken as a novel wood to meet the demand of people on the lean and refinement of the use of the wood. The technical wood veneer is also called as beautifying board, technical board, composite board and artificial wood veneer, can be made to be very thin, is easy to stick, has low cost, can replace natural original wood veneer, is more environment-friendly, and is widely applied to the fields of furniture, cabinets, display racks, indoor and outdoor decoration, house decoration, product decoration and the like. However, the technical wood veneer is very easy to turn yellow after being processed by a technical means or other technical means, the surface effect is poor and the wood veneer is free of hand feeling, and the easy yellowing of the original technical wood veneer also brings troubles to furniture manufacturers and home decoration construction teams: the paint film is relatively bloated, has no solid wood texture, has too high luster, poor original wood texture, poor transparency, one layer of surface fog, is not scratch-resistant and has low hardness.
Disclosure of Invention
The invention aims to solve the technical problem of providing the wear-resistant high-transparency super-smooth PU open type matte top-coat paint which has high film hardness, good yellowing resistance, chemical resistance, scraping resistance and wear resistance, good solid wood texture, high transparency, non-swelling film clearness and good matte effect when being applied to the surface of technical wood.
The technical scheme of the invention is as follows:
a wear-resistant high-transparency super-smooth PU open matte top-coat paint comprises a component A, a component B and a diluent, wherein the mass ratio of the component A to the component B is 10: 5-6;
the component A comprises the following components in percentage by mass: 35-55% of hydroxyl acrylic resin, 0.5-1% of wetting dispersant, 0.5-1.5% of polyamide anti-settling slurry, 0.1-0.5% of antioxidant, 0.3-0.5% of ultraviolet absorber, 5-8% of aldehyde ketone resin, 0.5-3% of wax powder, 3-5% of glass powder, 2-3.5% of matting powder, 18-28% of CAB cellulose, 5-10% of ether ester solvent, 1-5% of ester solvent, 0.1-0.5% of defoaming agent, 0.55-1.6% of flatting agent and 0.05-0.1% of drier, wherein the sum of the components is 100%;
the component B comprises the following components in percentage by mass: 25-45% of n-butyl acetate, 0.1-0.3% of dehydrating agent, 20-50% of aromatic polyisocyanate TDI and 10-20% of aliphatic polyisocyanate HDI, wherein the sum of the components is 100%.
Furthermore, the fineness of the hydroxyl acrylic resin is 3-10 μm, the viscosity is 2500-5000CPS, and the hydroxyl value is 2-3.5. Preferably DE modest FS-3060, same German ACR 6503B.
Further, the ester solvent is n-Butyl Acetate (BAC) and/or Ethyl Acetate (EAC); the ether solvent is propylene glycol methyl ether acetate (PMA).
Further, the wetting dispersant is modified polyurethane polymer; the wax powder is fluorine modified wax powder, preferably Kelain 9615A or Austen source 628 FE; the fineness of the glass powder is less than or equal to 3 mu m; the defoaming agent is modified polysiloxane, preferably moderate 5300, 5400 or BYK-141; the leveling agent comprises 0.05-0.1% of polyacrylate leveling agent and 0.5-1.5% of polyether modified polydimethylsiloxane, the polyacrylate leveling agent is preferably BYK-358N, EFKA3600, and the polyether modified polydimethylsiloxane is preferably BYK-323, BYK-300 and BYK-333; the drier is an organic tin drier, preferably T-12 of American gas company.
Further, the polyamide anti-settling is preferably teschong 868 or des (292); the antioxidant is preferably Ciba 1010; the ultraviolet light absorber is preferably Ciba UV-531 and UV-2; the aldehyde ketone resin is preferably Basf A81, and has the advantages of light stability, quick curing, high hardness and high adhesion; the glass powder is preferably VX-SP of Channel in Japan; the extinction powder is preferably Grace ED-2 or Tosoh 1011; the CAB cellulose is preferably American Isyman CAB-381-0.5.
Further, the aromatic polyisocyanate TDI is low molecular weight toluene diisocyanate trimer, has good compatibility with acrylic resin, and is preferably selected from AC-510 of Sabium Italy, D-262T of Mitsui Japan or L1451 of Bayer of Germany; the aliphatic polyisocyanate HDI is hexamethylene diisocyanate trimer, preferably N3390 and BasebasfHI 190B/S of Bayer in Germany.
Further, the dehydrating agent is monofunctional isocyanate, preferably Bayer TI and Ciba BF-5.
Further, the diluent comprises 8-28% of xylene, 5-10% of cyclohexanone, 15-35% of propylene glycol methyl ether acetate and 25-55% of n-butyl acetate.
A preparation method of the wear-resistant high-transparency super-smooth PU open type matte top-coat paint comprises the following steps:
A. preparation of the A component
a. Hydroxyl acrylic resin, wetting dispersant and polyamide anti-settling slurry are mixed and dispersed for 5-10min to be uniform at the rotating speed of 400-500 r/min;
b. adding antioxidant, ultraviolet absorbent, aldehyde ketone resin and wax powder, and dispersing at the rotating speed of 800-;
c. adding glass powder and matting powder, and dispersing at a rotation speed of 1000-1500r/min for at least 10min until the fineness is less than or equal to 25 μm;
d. adding CAB cellulose, ether ester solvent and ester solvent, and dispersing at the rotation speed of 800-;
e. adding a defoaming agent, a drier and a flatting agent, dispersing for 5-10min at the rotating speed of 500-800r/min, and sieving with a 200-mesh sieve;
B. preparation of component B
f. Mixing a dehydrating agent and n-butyl acetate, and dehydrating for at least 1 h;
adding aromatic polyisocyanate and aliphatic polyisocyanate, and dispersing at the rotating speed of 500-800r/min for 5-10 min.
The invention has the following beneficial effects:
1. the hydroxyl acrylic resin is selected as a film forming substance, so that the hardness and the yellowing resistance of a paint film can be improved, the hardness of the paint film can be obviously improved by matching with the aldehyde ketone resin, the solid content is increased, the permeability of the paint film is improved, the paint film is easy to dull, the use amount of an organic solvent in the paint is reduced due to the low viscosity characteristic of the aldehyde ketone resin, the VOC content in the paint is low, and the paint is safer and more environment-friendly. The paint film has good flexibility, high adhesive force and excellent scratch resistance and wear resistance.
2. The polyether modified polydimethylsiloxane is selected to improve the scratch resistance of the paint film. The organic silicon auxiliary agent can be uniformly distributed in the paint film and on the surface of the paint film, and the polyacrylate high polymer leveling agent can improve the flatness of the paint film so as to improve the performance of the paint film. The matching of the antioxidant and the ultraviolet absorber can improve the weather resistance of the paint film.
3. The glass powder with the grain size less than or equal to 3 microns is selected, has high hardness, can be uniformly distributed in the paint film, and does not influence the scratch resistance of the paint film. The fluorine modified polytetrafluoroethylene wax is matched, and the wax powder is polytetrafluoroethylene ultrafine powder, so that the paint film has good heat resistance, cold resistance, low friction, non-stickiness, chemical stability and electrical insulation performance, is endowed with a fine and smooth hand feeling, and improves the scratch resistance and wear resistance of the paint film.
4. The CAB cellulose selected can improve the viscosity, the smoothness, the ultraviolet light resistance stability and the solvent corrosion resistance of a paint film, improve the leveling property and shorten the drying time, thereby improving the smoothness and the wear resistance of the paint film.
5. The TDI trimer curing agent with low molecular weight in the component B is matched with HDI hexamethylene diisocyanate polymer, so that the curing time can be reasonably controlled in the surface drying and actual drying processes of a paint film, the internal and external reactions of the paint film are stable, the paint film has high hardness and high toughness, and the aims of improving the adhesive force and resisting scratches of the paint film are fulfilled.
Detailed Description
The present invention will be described in detail with reference to examples, which are only preferred embodiments of the present invention and are not intended to limit the present invention.
In the embodiment and the comparative example of the invention, the used hydroxy acrylic resin is squat FS-4660, the wetting dispersant is EFKA-4010, the polyamide anti-sediment foam DE squat 292, the antioxidant is 1010, the ultraviolet light absorber is UV-531, the aldehyde ketone resin is A81, the polytetrafluoroethylene wax powder is Kelaien 9615A, the glass powder is Japanese chanel VX-SP, the extinction powder is ED-2, the CAB cellulose is CAB-381-0.5, the ether ester solvent is PMA, the ester solvent is BCA, the drier is T-12, the leveling agent is EF360KA 0, BYK323, the acetate is N-butyl acetate, the dehydrating agent is TI, the aliphatic polyisocyanate HDI is N3390, and the aromatic polyisocyanate TDI is D262-262 BACT.
A component
The following table shows the formula (unit:%) of 5 examples and 4 comparative examples of the component A in the wear-resistant high-transparency super-smooth PU open type matte clear finishing coat of the invention:
component B
The following table shows the formula (unit:%) of 5 examples and 1 comparative example of component B in the wear-resistant high-transparency super-smooth PU open type matte clear finishing coat of the invention:
a preparation method of the wear-resistant high-transparency super-smooth PU open type matte top-coat paint comprises the following steps:
A. preparation of the A component
a. Hydroxyl acrylic resin, wetting dispersant and polyamide anti-settling slurry are mixed and dispersed for 5-10min to be uniform at the rotating speed of 400-500 r/min;
b. adding antioxidant, ultraviolet absorbent, aldehyde ketone resin and wax powder, and dispersing at the rotating speed of 800-;
c. adding glass powder and matting powder, and dispersing at a rotation speed of 1000-1500r/min for at least 10min until the fineness is less than or equal to 25 μm;
d. adding CAB cellulose, ether ester solvent and ester solvent, and dispersing at the rotation speed of 800-;
e. adding a defoaming agent, a drier and a flatting agent, dispersing for 5-10min at the rotating speed of 500-800r/min, and sieving with a 200-mesh sieve;
B. preparation of component B
f. Mixing a dehydrating agent and n-butyl acetate, and dehydrating for at least 1 h;
adding aromatic polyisocyanate and aliphatic polyisocyanate, and dispersing at the rotating speed of 500-800r/min for 5-10 min.
The component A and the component B in each example and each comparative example are mixed according to the mass ratio of 100:50, and are subjected to spray coating test after being adjusted to corresponding construction viscosity with a proper amount of diluent, wherein the diluent comprises 28% of dimethylbenzene, 10% of cyclohexanone, 35% of propylene glycol methyl ether acetate and 27% of n-butyl acetate.
The paint film performance is tested according to GB-18581-2009 standard and GB/T23997-2009 standard, and the test results are shown in tables 1-3:
TABLE 1
TABLE 2
TABLE 3
Therefore, the coating disclosed by the invention is safe and environment-friendly, good in construction performance, high in curing speed, good in hand feeling of a paint film, high in hardness, good in adhesive force, and good in scratch resistance, wear resistance, cold and hot cycle resistance and yellowing resistance.
The wear-resistant high-transparency super-smooth PU open type matte top-coat paint disclosed by the invention has the advantages of high paint film hardness, good yellowing resistance, chemical resistance, scratch resistance and wear resistance, good solid wood texture, high transparency, transparent and non-swelling paint film and good matte effect when being applied to the surface of technical wood.
Claims (8)
1. A wear-resistant high-transparency super-smooth PU open type matte top-coat paint is characterized by comprising a component A, a component B and a diluent, wherein the mass ratio of the component A to the component B is 10: 5-6;
the component A comprises the following components in percentage by mass: 35-55% of hydroxyl acrylic resin, 0.5-1% of wetting dispersant, 0.5-1.5% of polyamide anti-settling slurry, 0.1-0.5% of antioxidant, 0.3-0.5% of ultraviolet absorber, 5-8% of aldehyde ketone resin, 0.5-3% of wax powder, 3-5% of glass powder, 2-3.5% of matting powder, 18-28% of CAB cellulose, 5-10% of ether ester solvent, 1-5% of ester solvent, 0.1-0.5% of defoaming agent, 0.55-1.6% of flatting agent and 0.05-0.1% of drier, wherein the sum of the components is 100%;
the component B comprises the following components in percentage by mass: 25-45% of n-butyl acetate, 0.1-0.3% of dehydrating agent, 20-50% of aromatic polyisocyanate TDI and 10-20% of aliphatic polyisocyanate HDI, wherein the sum of the components is 100%.
2. The wear-resistant high-transparency super-smooth PU open type matte top-coat paint is characterized in that the fineness of the hydroxyl acrylic resin is 3-10 mu m, the viscosity is 2500-.
3. A wear-resistant high-transparency super-smooth PU open type matte top-coat paint is characterized in that the ester solvent is n-Butyl Acetate (BAC) and/or Ethyl Acetate (EAC); the ether solvent is propylene glycol methyl ether acetate (PMA).
4. A wear-resistant high-transparency super-smooth PU open type matte top-coat paint is characterized in that the wetting dispersant is modified polyurethane high polymer; the wax powder is fluorine modified wax powder; the fineness of the glass powder is less than or equal to 3 mu m; the defoaming agent is modified polysiloxane; the leveling agent comprises 0.05-0.1% of polyacrylate leveling agent and 0.5-1.5% of polyether modified polydimethylsiloxane; the drier is an organic tin drier.
5. The wear-resistant high-transparency super-smooth PU open type matte top-coat paint is characterized in that the aromatic polyisocyanate TDI is low-molecular-weight toluene diisocyanate trimer; the aliphatic polyisocyanate HDI is hexamethylene diisocyanate trimer.
6. The wear-resistant high-transparency super-smooth PU open type matte top-coat paint is characterized in that the dehydrating agent is isocyanate with a single functional group.
7. The wear-resistant high-transparency super-smooth PU open matte top-coat paint is characterized in that a diluent comprises 8-28% of dimethylbenzene, 5-10% of cyclohexanone, 15-35% of propylene glycol methyl ether acetate and 25-55% of n-butyl acetate.
8. A method for preparing the wear-resistant high-transparency ultra-smooth PU open matte clear finish paint according to any one of claims 1 to 7, which is characterized by comprising the following steps:
A. preparation of the A component
a. Hydroxyl acrylic resin, wetting dispersant and polyamide anti-settling slurry are mixed and dispersed for 5-10min to be uniform at the rotating speed of 400-500 r/min;
b. adding antioxidant, ultraviolet absorbent, aldehyde ketone resin and wax powder, and dispersing at the rotating speed of 800-;
c. adding glass powder and matting powder, and dispersing at a rotation speed of 1000-1500r/min for at least 10min until the fineness is less than or equal to 25 μm;
d. adding CAB cellulose, ether ester solvent and ester solvent, and dispersing at the rotation speed of 800-;
e. adding a defoaming agent, a drier and a flatting agent, dispersing for 5-10min at the rotating speed of 500-800r/min, and sieving with a 200-mesh sieve;
B. preparation of component B
f. Mixing a dehydrating agent and n-butyl acetate, and dehydrating for at least 1 h;
g. adding aromatic polyisocyanate TDI and aliphatic polyisocyanate HDI, and dispersing at the rotating speed of 500-800r/min for 5-10 min.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113278349A (en) * | 2021-04-14 | 2021-08-20 | 上海嘉宝莉涂料有限公司 | Matte white finish and application thereof |
| CN113278350A (en) * | 2021-04-14 | 2021-08-20 | 上海嘉宝莉涂料有限公司 | Matte varnish and application thereof |
| CN113480927A (en) * | 2021-06-07 | 2021-10-08 | 君子兰涂料（天津）有限公司 | High-temperature-resistant PU (polyurethane) wood coating and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002311A (en) * | 2009-09-03 | 2011-04-06 | 澳达树熊涂料(惠州)有限公司 | Super-yellowing resistant solvent type bicomponent polyurethane (PU) white-topcoat wood lacquer |
| CN104559727A (en) * | 2014-12-08 | 2015-04-29 | 澳达树熊涂料(惠州)有限公司 | Double-component polyurethane white glass finishing varnish and preparation method thereof |
| CN110951366A (en) * | 2019-12-05 | 2020-04-03 | 澳达树熊涂料(惠州)有限公司 | Full-odor-free bi-component matte top-coat paint and preparation method thereof |
| CN111978848A (en) * | 2020-09-17 | 2020-11-24 | 福州展辰新材料有限公司 | Yellowing-resistant dull odor-free PU polyurethane clear finish and preparation method thereof |
| CN111995940A (en) * | 2020-09-17 | 2020-11-27 | 福州展辰新材料有限公司 | Super-matte PU odor-free clear finishing coat and preparation method thereof |
-
2020
- 2020-11-30 CN CN202011374668.4A patent/CN112646467A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002311A (en) * | 2009-09-03 | 2011-04-06 | 澳达树熊涂料(惠州)有限公司 | Super-yellowing resistant solvent type bicomponent polyurethane (PU) white-topcoat wood lacquer |
| CN104559727A (en) * | 2014-12-08 | 2015-04-29 | 澳达树熊涂料(惠州)有限公司 | Double-component polyurethane white glass finishing varnish and preparation method thereof |
| CN110951366A (en) * | 2019-12-05 | 2020-04-03 | 澳达树熊涂料(惠州)有限公司 | Full-odor-free bi-component matte top-coat paint and preparation method thereof |
| CN111978848A (en) * | 2020-09-17 | 2020-11-24 | 福州展辰新材料有限公司 | Yellowing-resistant dull odor-free PU polyurethane clear finish and preparation method thereof |
| CN111995940A (en) * | 2020-09-17 | 2020-11-27 | 福州展辰新材料有限公司 | Super-matte PU odor-free clear finishing coat and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张永芬: "《有机化学》", 31 December 2012, 北京理工大学出版社 * |
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