CN115093783B - Extremely-matt thin transparent matt varnish for solid wood furniture and preparation method thereof - Google Patents
Extremely-matt thin transparent matt varnish for solid wood furniture and preparation method thereof Download PDFInfo
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- CN115093783B CN115093783B CN202210726289.XA CN202210726289A CN115093783B CN 115093783 B CN115093783 B CN 115093783B CN 202210726289 A CN202210726289 A CN 202210726289A CN 115093783 B CN115093783 B CN 115093783B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4081—Mixtures of compounds of group C08G18/64 with other macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
- C08G18/6484—Polysaccharides and derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
Abstract
The invention belongs to the technical field of chemical coating, and particularly relates to a very-matt and thin transparent matt clear finish paint for solid wood furniture and a preparation method thereof. The preparation raw materials of the matte varnish comprise a component A, a component B and a component C, wherein: the component A comprises self-extinction hydroxy acrylic resin and cellulose acetate butyrate; the component B comprises an HDI type curing agent; the component C is a solvent. The self-extinction hydroxy acrylic resin is used as a main agent component, extinction and film forming can be achieved without adding extinction powder, high transparency of a paint film is ensured, and meanwhile, a macromolecular material cellulose acetate butyrate is added, so that the paint film is spread easily; the self-extinction hydroxy acrylic resin can react with-NCO of polyisocyanate serving as an HDI type curing agent to form a very matt paint film, so that the glossiness is lower than 3 degrees. The macromolecular cellulose acetate butyrate makes the paint film thinner and softer, and the glossiness is very uniform no matter seen from the plane or the side, thereby achieving the effects of thinness, extreme dumb and penetration.
Description
Technical Field
The invention belongs to the technical field of chemical coating, and particularly relates to a very-matt and thin transparent matt clear finish paint for solid wood furniture and a preparation method thereof.
Background
Along with the continuous improvement of the external opening level and the living standard of people, the demands for high-end solid wood furniture are also continuously increased. The high-end solid wood is a precious material, has beautiful textures and soft visual effects, is a continuous pursuit of researchers how to deeply excavate the value, and has the defects of easy water absorption, dirt resistance, easy mildew, aging, color change and the like. The common solid wood furniture mainly aims at protecting effect and practical effect, and the high-end solid wood furniture is required to have protecting and practical effects and is more attractive. Therefore, extremely dumb (glossiness lower than 3 °), thin, transparent effects are produced. The paint film is thin, transparent and very dumb, has a film like no film, can fully show the original taste and flavor of wood, and gives people natural comfort. The extremely matt and thin penetration of a paint film are a pair of contradictory properties, and in general, the lower the gloss (matt), the poorer the transparency.
The traditional extinction method is to add extinction powder, and the extinction powder is usually fumed silica, but the fumed silica has larger refractive index difference with matrix resin, and the compatibility is poor, so that the transparency is affected. Therefore, the gloss is less than 3 ° and the penetration effect cannot be achieved only by adding the matting powder. In addition, the common polyurethane matte varnish solid wood furniture has the defects of uneven gloss, bloom and the like in side view.
Therefore, there is a need to develop a clear top-coat paint for solid wood, which can achieve the effects of thinness, transparency and extreme dumb at the same time, and has uniform glossiness of the paint film and no defects of bloom.
Disclosure of Invention
Aiming at the technical problems that clear finish paint in the prior art cannot be simultaneously thin and transparent and very dumb, uneven gloss and bloom are caused by extinction through fumed silica, the invention aims at solving at least one of the technical problems in the prior art. Therefore, the invention provides the matte varnish for the solid wood furniture, which not only has the properties of good adhesive force, flexibility, hardness, leveling property, chemical resistance, durability and the like of the polyurethane matte varnish, but also solves the contradiction between extreme matte and thin penetration. The paint film prepared by the invention has the characteristics of thinness, high transparency and extreme dumb, is film-like and film-free, can fully show the original taste and flavor of solid wood, gives people natural comfort, is softer, and has uniform glossiness no matter seen from the plane or the side.
The first aspect of the invention provides a matte top-coat paint.
Specifically, the matte top-coat paint is prepared from a component A, a component B and a component C, wherein the component A comprises self-extinction hydroxy acrylic resin and cellulose acetate butyrate; the component B comprises an HDI type curing agent; the component C is a solvent.
According to the invention, the self-extinction hydroxy acrylic resin is used as a main agent component, extinction and film formation can be achieved without adding extinction powder, and meanwhile, a macromolecular material cellulose acetate butyrate is added, so that a paint film is spread easily; the self-extinction hydroxy acrylic resin adopts an HDI type curing agent, and can react with-NCO of the polyisocyanate of the HDI type curing agent due to the hydroxyl, so that a very matt paint film is formed, and the glossiness is lower than 3 degrees. The main agent component of the invention does not comprise matting powder, thus ensuring the high transparency of a paint film, and the macromolecular cellulose acetate butyrate also contains hydroxyl, and can react with-NCO of the HDI type curing agent polyisocyanate to make the paint film thinner and softer, and the glossiness is uniform no matter the paint film is seen from a plane or a side surface, thereby achieving the effects of thinness, extreme dumb and transparency. In addition, the extinction hydroxy acrylic resin, the macromolecular cellulose acetate butyrate and the HDI type curing agent react to provide good adhesive force, flexibility, high hardness, chemical resistance and durability for a paint film.
As a further improvement of the above scheme, the mass ratio of the component a, the component B and the component C is 1: (0.2-0.3): (1-1.5).
Preferably, the mass ratio of the component A to the component B to the component C is 1:0.25: (1-1.5).
Specifically, by adjusting the component A, the component B and the component C in proper ranges, the paint film can have the effects of thinness and extreme dumb on the premise of ensuring that the paint film has the same basic performance as polyurethane matte top-coat paint.
As a further improvement of the above-mentioned scheme, the particle size of the self-extinction hydroxy acrylic resin is 5-15 μm.
Specifically, by controlling the particle size of the self-extinction hydroxy acrylic resin to be in a micron level, the micron-level particles are uniformly distributed in a paint film, the effect is similar to that of extinction powder, the surface is rugged after film formation, diffuse reflection is formed, extinction effect is achieved, and a very-matte coating is formed; the particle size of the common hydroxy acrylic resin is nano-scale, and the extinction effect cannot be realized.
Preferably, the self-extinction hydroxy acrylic resin has non-volatile matter 48-52wt%, viscosity 4000-10000Cp at 25+ -1deg.C, acid value 15-35mg KOH/g, and hydroxyl value 35-40mg KOH/g.
More preferably, the self-extinction hydroxy acrylic resin is selected from H-MT-2350 from Hamming corporation.
As a further improvement of the scheme, the cellulose acetate butyrate has an acetate group content of 12.5-14.5wt%, a butyrate group content of 37-39wt%, a hydroxyl group content of 1.2-1.4%, a viscosity of 7.5-7.7poise and an average molecular weight of 35000-45000. The above properties of cellulose acetate butyrate allow for thinner and smoother paint films.
As a further improvement of the scheme, the component A also comprises at least one of dispersing agent, anti-settling agent, propylene glycol methyl ether acetate, wax powder, leveling agent, drier, defoaming agent and butyl acetate.
Preferably, the component A comprises the following components in parts by weight:
as a further improvement of the above scheme, the cellulose acetate butyrate solution comprises, by weight:
preferably, the cellulose acetate butyrate is selected from CAB381-2 of the company Isman.
As a further improvement of the above scheme, the anti-settling slurry comprises, by weight:
65-75 parts of dimethylbenzene;
25-35 parts of anti-settling agent.
In particular, wax powders are used to provide better hand feel; the leveling agent makes the paint film smoother and better in hand feeling; the anti-settling agent ensures that the wax powder and the self-extinction hydroxy acrylic resin do not generate sediment in the storage and use processes; defoamers can defoaming faster during preparation and use; the drier is used for promoting the actual drying; the solvent can adjust the viscosity and the volatilization rate, is convenient for processing, use, leveling, drying time adjustment and the like; the dispersing agent is favorable for dispersing the raw materials and does not agglomerate. The raw materials of the component A are matched with an HDI curing agent and a solvent in a specific proportion, and are sprayed on solid wood furniture according to a process, so that the adhesive has the characteristics of good adhesive force, good flexibility resistance, high hardness, good leveling property, good chemical resistance, durability and the like, and the adhesive has the characteristics of thinness and extreme dumb.
Preferably, the dispersing agent is a modified polyurethane dispersing agent; more preferably, the dispersant is selected from EFKA4010.
Preferably, the anti-settling agent is polyamide wax anti-settling agent; more preferably, the anti-settling agent is selected from 6900-20X of Disparlon corporation.
Preferably, the wax powder is modified polyethylene wax powder; more preferably, the wax powder is selected from 1400SF from Lubrizol corporation.
Preferably, the leveling agent is an organosilicon leveling agent; more preferably, the leveling agent is selected from BYK333 of BYK corporation in germany.
Preferably, the drier is an organotin drier; more preferably, the drier is selected from the group consisting of T-12 from America gas company.
Preferably, the defoaming agent is an organosilicon defoaming agent; more preferably, the defoamer is selected from BYK141 of BYK corporation, germany.
As a further improvement of the above scheme, the component B further comprises propylene glycol methyl ether acetate and/or butyl acetate.
Preferably, the component B comprises the following components in parts by weight:
5-15 parts of propylene glycol methyl ether acetate;
35-55 parts of butyl acetate;
and 35-45 parts of HDI type curing agent.
Preferably, the HDI-type curing agent is an aliphatic polyisocyanate comprising hexamethylene diisocyanate trimer; more preferably, the HDI-type curing agent is selected from N3390 of kechuang.
As a further improvement of the above scheme, the C component includes, in parts by weight:
the second aspect of the invention provides a preparation method of a matte varnish.
Specifically, the preparation method of the matte varnish is used for preparing the matte varnish, and comprises the following steps of:
(1) Dispersing the self-extinction hydroxy acrylic resin, adding other raw materials for preparing the component A, and mixing to obtain the component A;
(2) And (3) adding the component B and the component C into the component A prepared in the step (1) and mixing to obtain the matte varnish.
The self-extinction hydroxy acrylic resin is gelatinous, has high viscosity and is difficult to disperse, so that other raw materials for preparing the component A, such as wax powder, can be added until the self-extinction hydroxy acrylic resin is fully dispersed until the particle diameter is 5-15 mu m, otherwise, the wax powder cannot be dispersed, the self-extinction hydroxy acrylic resin cannot be uniformly dispersed, and the effect of thinness cannot be achieved because the paint film is full of particles with the size of a plate.
As a further improvement of the above scheme, the preparation method of the a component comprises the following steps:
(1) Adding self-extinction hydroxy acrylic resin, a dispersing agent and part of propylene glycol methyl ether acetate into a paint making cylinder, and dispersing at a low speed (the rotating speed is 600-800 rpm) for 5-10 minutes;
(2) Slowly adding wax powder under low-speed dispersion, and dispersing at high speed of 1000-1300 rpm for 20-30 min until fineness is less than or equal to 30 μm;
(3) Slowly adding anti-settling slurry, cellulose acetate butyrate liquid, a leveling agent, a drier, a defoaming agent, the rest propylene glycol methyl ether acetate and butyl acetate under low-speed dispersion, adopting the low-speed dispersion at the rotating speed of 600-800 rpm for 5-10 minutes, stopping dispersion, standing for 10-100 minutes, and obtaining the component A after defoaming.
Specifically, the solvent propylene glycol methyl ether acetate is added in two steps, and the propylene glycol methyl ether acetate added in the step (1) is mainly used for dispersing self-extinction hydroxy acrylic resin; the propylene glycol methyl ether acetate added in the step (3) is mainly used for adjusting the viscosity and the volatilization rate.
Preferably, the mass ratio of the propylene glycol methyl ether acetate added in the step (1) and the step (3) is (1-10): (1-15).
As a further improvement of the above scheme, the preparation method of the cellulose acetate butyrate liquid comprises the following steps:
(1) Dispersing xylene, butyl acetate and cyclohexanone at a low speed of 600-800 rpm for 5-10 min;
(2) Slowly adding cellulose acetate butyrate under low-speed dispersion, and dispersing at low speed for 5-10 min until the cellulose acetate butyrate is completely dissolved to obtain the cellulose acetate butyrate liquid.
As a further improvement of the scheme, the preparation method of the anti-settling slurry comprises the following steps: firstly adding dimethylbenzene, slowly adding an anti-settling agent under low-speed dispersion, and dispersing at the low speed of 600-800 rpm for 5-10 minutes until the anti-settling agent is uniformly dispersed, thus obtaining the anti-settling slurry.
As a further improvement of the above scheme, the preparation method of the B component comprises the following steps:
(1) Propylene glycol methyl ether acetate, butyl acetate and HDI curing agent are put into a special production cylinder of the curing agent, and are stirred for 10-15 minutes to be uniform at a low speed with the rotating speed of 200-400 rpm;
(2) Stopping stirring, standing for 5-10 min, sampling and detecting NCO (7-8wt%) and solid content (33.5-35.5wt%) and obtaining the component B after passing.
As a further improvement of the above scheme, the preparation method of the C component comprises the following steps:
(1) Putting xylene, butyl acetate, cyclohexanone and propylene glycol methyl ether acetate into a special production cylinder for solvent, and stirring at a low speed for 10-15 minutes at a rotating speed of 200-400 rpm until the mixture is uniform;
(2) Stopping stirring, standing for 5-10 min, sampling, detecting chromatogram (for standard sample), and obtaining component C.
The third aspect of the invention provides an application of the matte varnish.
Specifically, the matte varnish disclosed by the invention is applied to the field of solid wood furniture.
Compared with the prior art, the technical scheme of the invention has at least the following technical effects or advantages:
(1) The matte varnish disclosed by the invention consists of a component A, a component B and a component C, wherein: the component A is a main agent comprising self-extinction hydroxy acrylic resin and cellulose acetate butyrate; the component B is a curing agent, comprising an HDI type curing agent; the component C is a solvent. The self-extinction hydroxy acrylic resin is used as a main agent component, extinction and film formation can be achieved without adding extinction powder, and meanwhile, a macromolecular material cellulose acetate butyrate is added, so that a paint film is spread easily; the self-extinction hydroxy acrylic resin can react with-NCO of the HDI type curing agent polyisocyanate to form a very matt paint film, so that the glossiness is lower than 3 degrees and can reach 1-2.5 degrees. Because no extinction powder is included, the high transparency of the paint film is ensured, and the macromolecular cellulose acetate butyrate is assisted with hydroxyl, so that the paint film can react with-NCO of the HDI curing agent polyisocyanate, is thinner and softer, has uniform glossiness from the plane or from the side, and achieves the effects of thinness, extreme dumb and transparency.
(2) The self-extinction hydroxyl acrylic resin, the macromolecular cellulose acetate butyrate and the HDI type curing agent react to provide good adhesive force, flexibility, high hardness, chemical resistance and durability for a paint film, the defects of uneven gloss and bloom caused by fumed silica extinction powder are avoided, the coated furniture is odorless and has good yellowing resistance, the requirements of high-end solid wood furniture are met, and the performance is superior to that of similar foreign products.
Detailed Description
The present invention is described in detail below with reference to examples to facilitate understanding of the present invention by those skilled in the art. It is specifically pointed out that the examples are given solely for the purpose of illustration of the invention and are not to be construed as limiting the scope of the invention, since numerous insubstantial modifications and variations of the invention will be within the scope of the invention, as described above, will become apparent to those skilled in the art. Meanwhile, the raw materials mentioned below are not specified, and are all commercial products; the process steps or preparation methods not mentioned in detail are those known to the person skilled in the art.
The raw materials used in the examples and comparative examples of the present invention are specifically selected from the following raw materials:
self-extinction hydroxy acrylic resin: H-MT-2350 (average particle diameter 10 μm, nonvolatile matter 48-52wt%, viscosity 4000-10000Cp at 25+ -1deg.C, acid value 15-35mg KOH/g, hydroxyl value 38.61mg KOH/g) of Haimin company;
dispersing agent: EFKA4010;
anti-settling agent: disparlon 6900-20X;
wax powder: lubrizol 1400SF;
cellulose acetate butyrate: CAB381-2 (13.5% by weight acetate, 38% by weight butyrate, 1.3% by weight hydroxyl, 7.6poise viscosity, 40000 average molecular weight) from Isman;
leveling agent: BYK333 of BYK corporation, germany;
drier: t-12 of America gas company;
defoaming agent: BYK141, BYK Corp;
HDI-type curing agent: n3390 of kesi corporation.
Example 1
A matte varnish is prepared from a component A, a component B and a component C.
Wherein: the component A comprises the following components in parts by weight:
the cellulose acetate butyrate liquid comprises the following components in parts by weight:
the anti-settling slurry comprises the following components in parts by weight:
70 parts of dimethylbenzene;
30 parts of anti-settling agent.
The component B comprises the following components in parts by weight:
12 parts of propylene glycol methyl ether acetate;
50 parts of butyl acetate;
38 parts of HDI type curing agent.
The component C comprises the following components in parts by weight:
a preparation method of a matte varnish comprises the following steps:
and (3) preparation of the component A:
(1) The self-extinction hydroxy acrylic resin, the dispersing agent and part of propylene glycol methyl ether acetate (4 parts) are put into a paint making cylinder, and low-speed dispersion (the rotating speed is 600 revolutions per minute) is adopted for 10 minutes;
(2) Slowly adding wax powder under low-speed dispersion (the rotating speed is 600 rpm), and dispersing at high speed of 1000 rpm for 3 minutes until the fineness is less than or equal to 30 mu m;
(3) Under the condition of low-speed dispersion (the rotating speed is 600 revolutions per minute), anti-settling slurry, cellulose acetate butyrate liquid, flatting agent, drier, defoamer, the rest propylene glycol methyl ether acetate (6 parts) and butyl acetate are slowly added, the low-speed dispersion with the rotating speed of 600 revolutions per minute is adopted for 10 minutes, the dispersion is stopped, and the standing is carried out for 30 minutes, and the component A is obtained after defoaming.
Wherein: the preparation method of the cellulose acetate butyrate liquid comprises the following steps:
(1) Dispersing xylene, butyl acetate and cyclohexanone at a low speed of 600 rpm for 10 minutes;
(2) And slowly adding cellulose acetate butyrate at a low speed (rotating speed is 600 rpm) for dispersing for 10 minutes until the cellulose acetate butyrate is completely dissolved, so as to obtain cellulose acetate butyrate liquid.
The preparation method of the anti-settling slurry comprises the following steps: firstly, adding dimethylbenzene, slowly adding an anti-settling agent under low-speed dispersion (the rotating speed is 600 rpm), and dispersing for 10 minutes at the low speed of 600 rpm until the anti-settling agent is uniformly dispersed, thus obtaining the anti-settling slurry.
And (3) preparation of a component B:
(1) Propylene glycol methyl ether acetate, butyl acetate and HDI curing agent are put into a special production cylinder of the curing agent, and are stirred for 15 minutes to be uniform at a low speed with the rotating speed of 200 rpm;
(2) Stopping stirring, standing for 10 min, sampling and detecting NCO (7-8wt%) and solid content (33.5-35.5wt%) and obtaining component B after passing.
And (3) preparation of a component C:
(1) Putting xylene, butyl acetate, cyclohexanone and propylene glycol methyl ether acetate into a special production cylinder for solvent, and stirring at a low speed for 15 minutes at a rotating speed of 200 rpm until the mixture is uniform;
(2) Stopping stirring, standing for 10 min, sampling, detecting chromatogram (for standard sample), and obtaining component C.
The weight ratio of the component A to the component B to the component C is 1:0.2:1, and mixing to obtain the matte varnish of the embodiment.
Example 2
A matte varnish is prepared from a component A, a component B and a component C.
Wherein: the component A comprises the following components in parts by weight:
the cellulose acetate butyrate liquid comprises the following components in parts by weight:
the anti-settling slurry comprises the following components in parts by weight:
70 parts of dimethylbenzene;
30 parts of anti-settling agent.
The component B comprises the following components in parts by weight:
10 parts of propylene glycol methyl ether acetate;
52 parts of butyl acetate;
38 parts of HDI type curing agent.
The component C comprises the following components in parts by weight:
a preparation method of a matte varnish comprises the following steps:
and (3) preparation of the component A:
(1) Adding self-extinction hydroxy acrylic resin, a dispersing agent and part of propylene glycol methyl ether acetate (4 parts) into a paint making cylinder, and dispersing at a low speed (the rotating speed is 700 rpm) for 8 minutes;
(2) Slowly adding wax powder under low-speed dispersion (the rotating speed is 700 rpm), and adopting high-speed dispersion of 1100 rpm for 25 minutes until the fineness is less than or equal to 30 mu m;
(3) Under the condition of low-speed dispersion (the rotating speed is 700 revolutions per minute), anti-settling slurry, cellulose acetate butyrate liquid, flatting agent, drier, defoaming agent, the rest propylene glycol methyl ether acetate (10 parts) and butyl acetate are slowly added, the low-speed dispersion at the rotating speed of 700 revolutions per minute is adopted for 8 minutes, the dispersion is stopped, the standing is carried out for 50 minutes, and the component A is obtained after defoaming.
Wherein: the preparation method of the cellulose acetate butyrate liquid comprises the following steps:
(1) Dispersing xylene, butyl acetate and cyclohexanone at a low speed of 700 rpm for 8 minutes;
(2) And slowly adding cellulose acetate butyrate at a low speed (rotating speed is 700 rpm) and dispersing for 8 minutes at a low speed until the cellulose acetate butyrate is completely dissolved, so as to obtain the cellulose acetate butyrate solution.
The preparation method of the anti-settling slurry comprises the following steps: firstly, adding dimethylbenzene, slowly adding an anti-settling agent under low-speed dispersion, and dispersing for 8 minutes at a low speed of 700 revolutions per minute until the anti-settling agent is uniformly dispersed, thus obtaining the anti-settling slurry.
And (3) preparation of a component B:
(1) Propylene glycol methyl ether acetate, butyl acetate and HDI curing agent are put into a special production cylinder of the curing agent, and the mixture is stirred for 12 minutes to be uniform at a low speed with the rotating speed of 300 rpm;
(2) Stopping stirring, standing for 8 min, sampling and detecting NCO (7-8wt%) and solid content (33.5-35.5wt%) and obtaining component B after passing.
And (3) preparation of a component C:
(1) Putting xylene, butyl acetate, cyclohexanone and propylene glycol methyl ether acetate into a special production cylinder for solvent, and stirring at a low speed for 10-15 minutes at a rotating speed of 300 rpm until the mixture is uniform;
(2) Stopping stirring, standing for 8 min, sampling, detecting chromatogram (for standard sample), and obtaining component C.
The weight ratio of the component A to the component B to the component C is 1:0.25:1, and mixing to obtain the matte varnish of the embodiment.
Example 3
A matte varnish is prepared from a component A, a component B and a component C.
Wherein: the component A comprises the following components in parts by weight:
the cellulose acetate butyrate liquid comprises the following components in parts by weight:
the anti-settling slurry comprises the following components in parts by weight:
70 parts of dimethylbenzene;
30 parts of anti-settling agent.
The component B comprises the following components in parts by weight:
14 parts of propylene glycol methyl ether acetate;
51 parts of butyl acetate;
and 35 parts of HDI type curing agent.
The component C comprises the following components in parts by weight:
a preparation method of a matte varnish comprises the following steps:
and (3) preparation of the component A:
(1) Adding self-extinction hydroxy acrylic resin, a dispersing agent and part of propylene glycol methyl ether acetate (4 parts) into a paint making cylinder, and dispersing at a low speed (the rotating speed is 800 rpm) for 5-10 minutes;
(2) Slowly adding wax powder under low-speed dispersion (the rotating speed is 800 rpm), and dispersing at high speed of 1200 rpm for 25 minutes until the fineness is less than or equal to 30 mu m;
(3) Under the condition of low-speed dispersion (the rotating speed is 800 rpm), anti-settling slurry, cellulose acetate butyrate liquid, flatting agent, drier, defoamer, the rest propylene glycol methyl ether acetate (6 parts) and butyl acetate are slowly added, the low-speed dispersion with the rotating speed of 800 rpm is adopted for 5 minutes, the dispersion is stopped, and the standing is carried out for 20 minutes, and the component A is obtained after defoaming.
Wherein: the preparation method of the cellulose acetate butyrate liquid comprises the following steps:
(1) Dispersing xylene, butyl acetate and cyclohexanone at a low speed of 800 rpm for 5 minutes;
(2) And slowly adding cellulose acetate butyrate at a low speed (the rotating speed is 800 rpm) for 5 minutes until the cellulose acetate butyrate is completely dissolved, so as to obtain the cellulose acetate butyrate solution.
The preparation method of the anti-settling slurry comprises the following steps: firstly, adding dimethylbenzene, slowly adding an anti-settling agent under low-speed dispersion, and dispersing for 5 minutes at a low speed of 800 revolutions per minute until the anti-settling agent is uniformly dispersed, thus obtaining the anti-settling slurry.
And (3) preparation of a component B:
(1) Propylene glycol methyl ether acetate, butyl acetate and HDI curing agent are put into a special production cylinder of the curing agent, and the mixture is stirred for 10 minutes to uniformity at a low speed with the rotating speed of 400 rpm;
(2) Stopping stirring, standing for 5 min, sampling and detecting NCO (7-8wt%) and solid content (33.5-35.5wt%) and obtaining component B after passing.
And (3) preparation of a component C:
(1) Putting xylene, butyl acetate, cyclohexanone and propylene glycol methyl ether acetate into a special production cylinder for solvent, and stirring at a low speed for 10 minutes at a rotating speed of 400 rpm until the mixture is uniform;
(2) Stopping stirring, standing for 5 min, sampling, detecting chromatogram (for standard sample), and obtaining component C.
The weight ratio of the component A to the component B to the component C is 1:0.3:1, and mixing to obtain the matte varnish of the embodiment.
Example 4
A matte varnish is prepared from a component A, a component B and a component C.
Wherein: the component A comprises the following components in parts by weight:
the cellulose acetate butyrate liquid comprises the following components in parts by weight:
the anti-settling slurry comprises the following components in parts by weight:
70 parts of dimethylbenzene;
30 parts of anti-settling agent.
The component B comprises the following components in parts by weight:
7 parts of propylene glycol methyl ether acetate;
53 parts of butyl acetate;
40 parts of HDI type curing agent.
The component C comprises the following components in parts by weight:
a preparation method of a matte varnish comprises the following steps:
and (3) preparation of the component A:
(1) The self-extinction hydroxy acrylic resin, the dispersing agent and part of propylene glycol methyl ether acetate (4 parts) are put into a paint making cylinder, and low-speed dispersion (the rotating speed is 600 revolutions per minute) is adopted for 10 minutes;
(2) Slowly adding wax powder under low-speed dispersion (the rotating speed is 600 rpm), and dispersing at high speed of 1000 rpm for 3 minutes until the fineness is less than or equal to 30 mu m;
(3) Under the condition of low-speed dispersion (the rotating speed is 600 revolutions per minute), anti-settling slurry, cellulose acetate butyrate liquid, flatting agent, drier, defoamer, the rest propylene glycol methyl ether acetate (6 parts) and butyl acetate are slowly added, the low-speed dispersion with the rotating speed of 600 revolutions per minute is adopted for 10 minutes, the dispersion is stopped, and the standing is carried out for 30 minutes, and the component A is obtained after defoaming.
Wherein: the preparation method of the cellulose acetate butyrate liquid comprises the following steps:
(1) Dispersing xylene, butyl acetate and cyclohexanone at a low speed of 600 rpm for 10 minutes;
(2) And slowly adding cellulose acetate butyrate at a low speed (rotating speed is 600 rpm) for dispersing for 10 minutes until the cellulose acetate butyrate is completely dissolved, so as to obtain cellulose acetate butyrate liquid.
The preparation method of the anti-settling slurry comprises the following steps: firstly, adding dimethylbenzene, slowly adding an anti-settling agent under low-speed dispersion (the rotating speed is 600 rpm), and dispersing for 10 minutes at the low speed of 600 rpm until the anti-settling agent is uniformly dispersed, thus obtaining the anti-settling slurry.
And (3) preparation of a component B:
(1) Propylene glycol methyl ether acetate, butyl acetate and HDI curing agent are put into a special production cylinder of the curing agent, and are stirred for 15 minutes to be uniform at a low speed with the rotating speed of 200 rpm;
(2) Stopping stirring, standing for 10 min, sampling and detecting NCO (7-8wt%) and solid content (33.5-35.5wt%) and obtaining component B after passing.
And (3) preparation of a component C:
(1) Putting xylene, butyl acetate, cyclohexanone and propylene glycol methyl ether acetate into a special production cylinder for solvent, and stirring at a low speed for 15 minutes at a rotating speed of 200 rpm until the mixture is uniform;
(2) Stopping stirring, standing for 10 min, sampling, detecting chromatogram (for standard sample), and obtaining component C.
The weight ratio of the component A to the component B to the component C is 1:0.25:1.25, and obtaining the matte varnish of the embodiment.
Example 5
A matte varnish is prepared from a component A, a component B and a component C.
Wherein: the component A comprises the following components in parts by weight:
the cellulose acetate butyrate liquid comprises the following components in parts by weight:
the anti-settling slurry comprises the following components in parts by weight:
70 parts of dimethylbenzene;
30 parts of anti-settling agent.
The component B comprises the following components in parts by weight:
9 parts of propylene glycol methyl ether acetate;
46 parts of butyl acetate;
45 parts of HDI type curing agent.
The component C comprises the following components in parts by weight:
a preparation method of a matte varnish comprises the following steps:
and (3) preparation of the component A:
(1) Adding self-extinction hydroxy acrylic resin, a dispersing agent and part of propylene glycol methyl ether acetate (4 parts) into a paint making cylinder, and dispersing at a low speed (the rotating speed is 700 rpm) for 8 minutes;
(2) Slowly adding wax powder under low-speed dispersion (the rotating speed is 700 rpm), and adopting high-speed dispersion of 1100 rpm for 25 minutes until the fineness is less than or equal to 30 mu m;
(3) Under the condition of low-speed dispersion (the rotating speed is 700 revolutions per minute), anti-settling slurry, cellulose acetate butyrate liquid, flatting agent, drier, defoaming agent, the rest propylene glycol methyl ether acetate (10 parts) and butyl acetate are slowly added, the low-speed dispersion at the rotating speed of 700 revolutions per minute is adopted for 8 minutes, the dispersion is stopped, the standing is carried out for 50 minutes, and the component A is obtained after defoaming.
Wherein: the preparation method of the cellulose acetate butyrate liquid comprises the following steps:
(1) Dispersing xylene, butyl acetate and cyclohexanone at a low speed of 700 rpm for 8 minutes;
(2) And slowly adding cellulose acetate butyrate at a low speed (rotating speed is 700 rpm) and dispersing for 8 minutes at a low speed until the cellulose acetate butyrate is completely dissolved, so as to obtain the cellulose acetate butyrate solution.
The preparation method of the anti-settling slurry comprises the following steps: firstly, adding dimethylbenzene, slowly adding an anti-settling agent under low-speed dispersion, and dispersing for 8 minutes at a low speed of 700 revolutions per minute until the anti-settling agent is uniformly dispersed, thus obtaining the anti-settling slurry.
And (3) preparation of a component B:
(1) Propylene glycol methyl ether acetate, butyl acetate and HDI curing agent are put into a special production cylinder of the curing agent, and the mixture is stirred for 12 minutes to be uniform at a low speed with the rotating speed of 300 rpm;
(2) Stopping stirring, standing for 8 min, sampling and detecting NCO (7-8wt%) and solid content (33.5-35.5wt%) and obtaining component B after passing.
And (3) preparation of a component C:
(1) Putting xylene, butyl acetate, cyclohexanone and propylene glycol methyl ether acetate into a special production cylinder for solvent, and stirring at a low speed for 10-15 minutes at a rotating speed of 300 rpm until the mixture is uniform;
(2) Stopping stirring, standing for 8 min, sampling, detecting chromatogram (for standard sample), and obtaining component C.
The weight ratio of the component A to the component B to the component C is 1:0.25:1.5, mixing to obtain the matte varnish of the embodiment.
Example 6
A matte varnish is prepared from a component A, a component B and a component C.
Wherein: the component A comprises the following components in parts by weight:
the cellulose acetate butyrate liquid comprises the following components in parts by weight:
the anti-settling slurry comprises the following components in parts by weight:
70 parts of dimethylbenzene;
30 parts of anti-settling agent.
The component B comprises the following components in parts by weight:
12 parts of propylene glycol methyl ether acetate;
46 parts of butyl acetate;
42 parts of HDI type curing agent.
The component C comprises the following components in parts by weight:
a preparation method of a matte varnish comprises the following steps:
and (3) preparation of the component A:
(1) Adding self-extinction hydroxy acrylic resin, a dispersing agent and part of propylene glycol methyl ether acetate (4 parts) into a paint making cylinder, and dispersing at a low speed (the rotating speed is 800 rpm) for 5-10 minutes;
(2) Slowly adding wax powder under low-speed dispersion (the rotating speed is 800 rpm), and dispersing at high speed of 1200 rpm for 25 minutes until the fineness is less than or equal to 30 mu m;
(3) Under the condition of low-speed dispersion (the rotating speed is 800 rpm), anti-settling slurry, cellulose acetate butyrate liquid, flatting agent, drier, defoamer, the rest propylene glycol methyl ether acetate (6 parts) and butyl acetate are slowly added, the low-speed dispersion with the rotating speed of 800 rpm is adopted for 5 minutes, the dispersion is stopped, and the standing is carried out for 20 minutes, and the component A is obtained after defoaming.
Wherein: the preparation method of the cellulose acetate butyrate liquid comprises the following steps:
(1) Dispersing xylene, butyl acetate and cyclohexanone at a low speed of 800 rpm for 5 minutes;
(2) And slowly adding cellulose acetate butyrate at a low speed (the rotating speed is 800 rpm) for 5 minutes until the cellulose acetate butyrate is completely dissolved, so as to obtain the cellulose acetate butyrate solution.
The preparation method of the anti-settling slurry comprises the following steps: firstly, adding dimethylbenzene, slowly adding an anti-settling agent under low-speed dispersion, and dispersing for 5 minutes at a low speed of 800 revolutions per minute until the anti-settling agent is uniformly dispersed, thus obtaining the anti-settling slurry.
And (3) preparation of a component B:
(1) Propylene glycol methyl ether acetate, butyl acetate and HDI curing agent are put into a special production cylinder of the curing agent, and the mixture is stirred for 10 minutes to uniformity at a low speed with the rotating speed of 400 rpm;
(2) Stopping stirring, standing for 5 min, sampling and detecting NCO (7-8wt%) and solid content (33.5-35.5wt%) and obtaining component B after passing.
And (3) preparation of a component C:
(1) Putting xylene, butyl acetate, cyclohexanone and propylene glycol methyl ether acetate into a special production cylinder for solvent, and stirring at a low speed for 10 minutes at a rotating speed of 400 rpm until the mixture is uniform;
(2) Stopping stirring, standing for 5 min, sampling, detecting chromatogram (for standard sample), and obtaining component C.
The weight ratio of the component A to the component B to the component C is 1:0.25:1, and mixing to obtain the matte varnish of the embodiment.
Example 7
A matte varnish is prepared from a component A, a component B and a component C.
Wherein: the component A comprises the following components in parts by weight:
the cellulose acetate butyrate liquid comprises the following components in parts by weight:
the anti-settling slurry comprises the following components in parts by weight:
70 parts of dimethylbenzene;
30 parts of anti-settling agent.
The component B comprises the following components in parts by weight:
12 parts of propylene glycol methyl ether acetate;
50 parts of butyl acetate;
38 parts of HDI type curing agent.
The component C comprises the following components in parts by weight:
a preparation method of a matte varnish comprises the following steps:
and (3) preparation of the component A:
(1) The self-extinction hydroxy acrylic resin, the dispersing agent and part of propylene glycol methyl ether acetate (4 parts) are put into a paint making cylinder, and low-speed dispersion (the rotating speed is 600 revolutions per minute) is adopted for 10 minutes;
(2) Slowly adding wax powder under low-speed dispersion (the rotating speed is 600 rpm), and dispersing at high speed of 1000 rpm for 3 minutes until the fineness is less than or equal to 30 mu m;
(3) Under the condition of low-speed dispersion (the rotating speed is 600 revolutions per minute), anti-settling slurry, cellulose acetate butyrate liquid, flatting agent, drier, defoamer, the rest propylene glycol methyl ether acetate (6 parts) and butyl acetate are slowly added, the low-speed dispersion with the rotating speed of 600 revolutions per minute is adopted for 10 minutes, the dispersion is stopped, and the standing is carried out for 30 minutes, and the component A is obtained after defoaming.
Wherein: the preparation method of the cellulose acetate butyrate liquid comprises the following steps:
(1) Dispersing xylene, butyl acetate and cyclohexanone at a low speed of 600 rpm for 10 minutes;
(2) And slowly adding cellulose acetate butyrate at a low speed (rotating speed is 600 rpm) for dispersing for 10 minutes until the cellulose acetate butyrate is completely dissolved, so as to obtain cellulose acetate butyrate liquid.
The preparation method of the anti-settling slurry comprises the following steps: firstly, adding dimethylbenzene, slowly adding an anti-settling agent under low-speed dispersion (the rotating speed is 600 rpm), and dispersing for 10 minutes at the low speed of 600 rpm until the anti-settling agent is uniformly dispersed, thus obtaining the anti-settling slurry.
And (3) preparation of a component B:
(1) Propylene glycol methyl ether acetate, butyl acetate and HDI curing agent are put into a special production cylinder of the curing agent, and are stirred for 15 minutes to be uniform at a low speed with the rotating speed of 200 rpm;
(2) Stopping stirring, standing for 10 min, sampling and detecting NCO (7-8wt%) and solid content (33.5-35.5wt%) and obtaining component B after passing.
And (3) preparation of a component C:
(1) Putting xylene, butyl acetate, cyclohexanone and propylene glycol methyl ether acetate into a special production cylinder for solvent, and stirring at a low speed for 15 minutes at a rotating speed of 200 rpm until the mixture is uniform;
(2) Stopping stirring, standing for 10 min, sampling, detecting chromatogram (for standard sample), and obtaining component C.
The weight ratio of the component A to the component B to the component C is 1:0.3:1.5, mixing to obtain the matte varnish of the embodiment.
Comparative example 1
A clear finishing paint is prepared from a component A, a component B and a component C.
Wherein: the component A comprises the following components in parts by weight:
comparative example 1 differs from example 1 in that the a component of the clear topcoat of comparative example 1 employs a hydroxy acrylic resin instead of a self-extinction hydroxy acrylic resin, and the types, amounts and preparation methods of other raw materials are the same as example 1.
Comparative example 2
A clear finishing paint is prepared from a component A, a component B and a component C.
Wherein: the component A comprises the following components in parts by weight:
comparative example 2 differs from example 1 in that the component a of the clear top coat of comparative example 2 uses a hydroxy acrylic resin instead of cellulose acetate butyrate, and the types, amounts and preparation methods of other raw materials are the same as in example 1.
Comparative example 3
A clear finishing paint is prepared from a component A, a component B and a component C.
Wherein: the component A comprises the following components in parts by weight:
comparative example 3 differs from example 1 in that matting powder was added to the a component of the clear top coat of comparative example 3, and a hydroxy acrylic resin was used instead of a self-matting hydroxy acrylic resin, and at the same time, the amount of the hydroxy acrylic resin was adaptively reduced, and the kinds, amounts and preparation methods of other raw materials were the same as example 1.
Performance testing
The state and storage stability of the clear coats prepared in examples 1 to 7 and comparative examples 1 to 3 in a container were observed, and at the same time, the prepared clear coats were applied to solid wood furniture, and the properties of the paint films were observed and examined, as shown in tables 1 and 2.
Wherein: the process of applying the varnish to the solid wood furniture comprises the following steps:
(1) Polishing the solid wood furniture by 240 # abrasive paper, and wiping the solid wood furniture with filler overnight;
(2) After polishing by using No. 320 sand paper, coating two crosses (firstly, transversely coating, then vertically coating, then transversely coating, then vertically coating) by adopting an odor-removing collapse-resistant anti-swelling high-transparency transparent primer;
(3) Then polishing with 320 # abrasive paper, and coating two crosses (firstly, transversely coating, then vertically coating, then transversely coating, then vertically coating) with the odor-removing collapse-resistant swelling-preventing high-transparency transparent primer over night;
(4) Polishing with 400 # abrasive paper and 600 # abrasive paper successively, performing color correction, and then respectively coating the clear top coats of examples 1-7 and comparative examples 1-3 overnight to obtain the paint film to be tested.
The filler used in the test process can be a commercially available filler for common solid wood furniture, and the transparent primer can be a commercially available transparent primer for common solid wood furniture.
Table 1: performance test results table of the matte top coats and paint films of examples 1 to 7
Table 2: performance test results table of top coats and paint films of comparative examples 1 to 3
As can be seen from tables 1 and 2, the matte top-coat paint prepared in examples 1 to 7 has good stability, and when applied to solid wood furniture, the paint film has good adhesive force, good flexibility, high hardness, good leveling property, good chemical resistance, durability and other properties, and the paint film has good transparency, uniform side gloss, no bloom phenomenon and glossiness of 1 to 2.5 degrees. In comparative examples 1 to 3, however, the appearance, fullness, uniformity and scratch resistance of the paint film were inferior to examples 1 to 7 and extremely matt gloss could not be achieved due to the use of ordinary hydroxyacrylic resin or the absence of cellulose acetate butyrate.
It will be apparent to those skilled in the art that several simple deductions or substitutions may be made without departing from the inventive concept. Accordingly, it is intended that all such modifications as would be within the scope of this invention be included within the scope of this invention. The above embodiments are preferred embodiments of the present invention, and all similar processes and equivalent modifications are intended to fall within the scope of the present invention.
Claims (6)
1. The matte varnish is characterized by containing no matting powder, and the preparation raw materials of the matte varnish comprise a component A, a component B and a component C, wherein the component A comprises self-matting hydroxy acrylic resin and cellulose acetate butyrate; the component B comprises an HDI type curing agent; the component C is a solvent;
the particle size of the self-extinction hydroxy acrylic resin is 5-15 mu m;
the non-volatile matter of the self-extinction hydroxy acrylic resin is 48-52wt%, the viscosity at 25+/-1 ℃ is 4000-10000cP, the acid value is 15-35mg KOH/g, and the hydroxyl value is 35-40mg KOH/g;
the cellulose acetate butyrate has an acetate group content of 12.5-14.5wt%, a butyrate group content of 37-39wt%, a hydroxyl group content of 1.2-1.4%, a viscosity of 7.5-7.7poise and an average molecular weight of 35000-45000;
the mass ratio of the component A to the component B to the component C is 1: (0.2-0.3): (1-1.5).
2. The matte top-coat paint according to claim 1, wherein the a component further comprises a dispersant, an anti-settling agent, propylene glycol methyl ether acetate, wax powder, a leveling agent, a drier, a defoaming agent and butyl acetate;
the component A comprises the following components in parts by weight:
30-60 parts of self-extinction hydroxy acrylic resin;
0.1-1 part of dispersing agent;
1-4 parts of anti-settling slurry;
2-25 parts of propylene glycol methyl ether acetate;
0.2-1 part of wax powder;
15-40 parts of cellulose acetate butyrate liquid;
0.2-1 part of leveling agent;
0.01-0.2 part of drier;
0.1-0.5 part of defoaming agent;
5-25 parts of butyl acetate;
the cellulose acetate butyrate liquid comprises the following components in parts by weight:
15-22 parts of dimethylbenzene;
40-50 parts of butyl acetate;
15-22 parts of cyclohexanone;
19-21 parts of cellulose acetate butyrate;
the anti-settling slurry comprises the following components in parts by weight:
65-75 parts of dimethylbenzene;
25-35 parts of anti-settling agent.
3. The matte top coat of claim 1 wherein the B component further comprises propylene glycol methyl ether acetate and butyl acetate; the component B comprises the following components in parts by weight:
5-15 parts of propylene glycol methyl ether acetate;
35-55 parts of butyl acetate;
and 35-45 parts of HDI type curing agent.
4. The matte top coat of claim 1 wherein the C component comprises, in parts by weight:
15-25 parts of dimethylbenzene;
30-50 parts of butyl acetate;
1-10 parts of cyclohexanone;
25-50 parts of propylene glycol methyl ether acetate.
5. A method for preparing a matte top-coat paint, characterized in that the method is used for preparing the matte top-coat paint according to any one of claims 1 to 4, and comprises the following steps:
(1) Dispersing the self-extinction hydroxy acrylic resin, adding other raw materials for preparing the component A, and mixing to obtain the component A;
(2) And (3) adding the component B and the component C into the component A prepared in the step (1) and mixing to obtain the matte varnish.
6. Use of the matte top-coat paint according to any one of claims 1 to 4 in the field of solid wood furniture.
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| CN103305120A (en) * | 2013-06-28 | 2013-09-18 | 江苏海田技术有限公司 | Ultraviolet (UV)-natural matte finishing paint |
| CN112646467A (en) * | 2020-11-30 | 2021-04-13 | 澳达树熊涂料(惠州)有限公司 | Wear-resistant high-transparency super-smooth PU open matte top-coat paint and preparation method thereof |
| CN113278350A (en) * | 2021-04-14 | 2021-08-20 | 上海嘉宝莉涂料有限公司 | Matte varnish and application thereof |
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| CN113980567B (en) * | 2021-11-16 | 2022-05-03 | 湘江涂料科技有限公司 | Surface gloss treating agent and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103305120A (en) * | 2013-06-28 | 2013-09-18 | 江苏海田技术有限公司 | Ultraviolet (UV)-natural matte finishing paint |
| CN112646467A (en) * | 2020-11-30 | 2021-04-13 | 澳达树熊涂料(惠州)有限公司 | Wear-resistant high-transparency super-smooth PU open matte top-coat paint and preparation method thereof |
| CN113278350A (en) * | 2021-04-14 | 2021-08-20 | 上海嘉宝莉涂料有限公司 | Matte varnish and application thereof |
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