CN107936814B - POSS (polyhedral oligomeric silsesquioxane) modified high-hardness polyurethane odor-free wood lacquer - Google Patents
POSS (polyhedral oligomeric silsesquioxane) modified high-hardness polyurethane odor-free wood lacquer Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to POSS modified high-hardness polyurethane odorless wood lacquer which is composed of A, B two components, wherein the weight ratio of A, B components is 1.4-1.8: 1; the component A consists of hydroxyl-containing odorless resin, various auxiliaries and solvents; the component B is a POSS modified low free monomer polyurethane curing agent; the invention also provides a preparation method of the POSS modified low-free monomer polyurethane curing agent. The POSS modified high-hardness polyurethane odorless wood lacquer disclosed by the invention has the advantages that the coating film has excellent adhesive force, fullness, high hardness, water resistance, flexibility, transparency, wear resistance, heat resistance, stain resistance and flame retardance; does not contain aromatic ketone and heavy metal, has odor-removing effect after being coated into a film for 48 hours, and is environment-friendly polyurethane odor-removing wood lacquer.
Description
Technical Field
The invention relates to polyurethane wood paint, in particular to POSS (polyhedral oligomeric silsesquioxane) modified high-hardness polyurethane odorless wood paint, and belongs to the technical field of wood paint.
Background
Along with the improvement of the living standard of people's material culture, the requirement of consumers on the coating effect of furniture is higher and higher, thereby driving the rapid growth of the domestic woodware coating. American coated furniture occupies a larger market share in the furniture coating market, most of domestic furniture industries use color concentrates (a metal complex dye, the dye has the defects of serious standard exceeding of heavy metal, containing pathogenic substances, temperature resistance, sun resistance and poor migration resistance, commonly called as glaze) to carry out wood grain coloring and finishing coloring, most of resins for coloring are common alkyd resin and linseed oil, and the furniture still has peculiar smell after being coated for a long time; the requirements of the current huge woodware paint market on paint products are higher and higher, the woodware Polyurethane (PU) paint has excellent comprehensive performance and wide use by consumers, but the products have a plurality of defects, such as blushing, foaming, delaminating, scratch resistance, ghost shadow, fingerprint disappearance difficulty and the like.
Chinese patent CN104099000A discloses a benzene-free odor-free scratch-resistant PU matte varnish, which consists of a component A resin paint and a component B curing agent, wherein the weight ratio of the component A to the component B is 1: 0.5; the component A resin paint consists of benzene-free odorless scratch-resistant alkyd resin without vegetable oil (fatty acid), aldehyde ketone resin, flatting powder, an auxiliary agent and a solvent; the component B consists of curing agent and solvent. The benzene-free odor-free scratch-resistant PU matt varnish prepared by the method does not contain aromatic hydrocarbon, ketone, heavy metal and vegetable oil (fatty acid), does not have uncomfortable odor after being coated into a film for 48 hours, and is an environment-friendly odor-free PU wood lacquer.
However, the existing polyurethane wood lacquer has the defects of poor crosslinking density, poor hydrophobicity, poor heat resistance, low flame retardant property and the like between resin and a curing agent.
Disclosure of Invention
The invention aims to provide POSS modified high-hardness polyurethane odor-free wood lacquer.
POSS is also called cage type polysilsesquioxane, is an inorganic inner core consisting of a silicon-oxygen framework in alternate connection with Si-O, is shaped like a cage, and belongs to a nano compound. The diversity, high reactivity and better polymer compatibility of POSS groups allows them to be incorporated into polymeric materials by both physical blending and chemical copolymerization.
The invention adopts the curing agent POSS modified low free monomer polyurethane curing agent, and the curing agent and the hydroxyl-containing resin are subjected to high crosslinking curing, and the paint film has high fullness, high wear resistance, heat resistance, water resistance and pollution resistance.
In order to overcome the defects and shortcomings of the prior art, the POSS modified high-hardness polyurethane odorless wood lacquer disclosed by the invention is composed of A, B two components, wherein the weight ratio of A, B components is 1.4-1.8: 1; the component A comprises the following components in percentage by weight: 50.0-85.0% of hydroxyl-containing odorless resin, 0.2-2.0% of wetting dispersant, 0.1-1.0% of flatting agent, 0.3-5.0% of rheological additive, 0.1-0.5% of defoaming agent, 0-6.0% of functional additive and 12.0-40.0% of solvent; the component B is a POSS modified low free monomer polyurethane curing agent.
The POSS modified low-free monomer polyurethane curing agent takes cage type polysilsesquioxane as a center, contains 16 isocyanate groups, and has a molecular structural formula shown as follows:
the POSS modified low-free monomer polyurethane curing agent comprises the following preparation steps:
a) isocyanate trimer synthesis: in N2Under protection, adding 100.0 parts of isocyanate monomer, 0.05-0.1 part of catalyst and 30.0-60.0 parts of solvent into a reaction kettle, starting stirring to uniformly stir the materials, heating to 50-80 ℃ for reaction for 2-4 h, dropwise adding 5.0 parts of mixed solution containing the catalyst, the accelerator and the solvent, after 0.5h of dropwise adding, keeping at 50-80 ℃ for continuous reaction, detecting the NCO value once every 0.5h, immediately adding a polymerization inhibitor accounting for 0.1-0.5% of the mass of the isocyanate monomer when the detected NCO value is 10-7%, and cooling to 20 ℃ to obtain the isocyanate trimer;
b) and the synthesis of the POSS modified low-free monomer polyurethane curing agent: and (2) dropwise adding a mixed solution of 15.0-40.0 parts of octaaminophenyl POSS and 30.0 parts of solvent into the isocyanate tripolymer at normal temperature, and continuously reacting for 2-3 hours after dropwise adding is finished for 0.5-1 hour to obtain the POSS modified low-free monomer polyurethane curing agent.
Wherein, the isocyanate monomer is at least one of TDI, MDI, NDI, TODI, HDI, TMDI, XDI, IPDI, HMDI and HTDI.
The mixed solution containing the catalyst, the accelerant and the solvent comprises the following components: 2.0-10.0 percent of catalyst, 2.0-10.0 percent of accelerant and 80.0-96.0 percent of solvent.
The catalyst is at least one of dibutyltin dilaurate, lithium acetate, tri-n-butylphosphor, stannous octoate, tin naphthenate, lead naphthenate, cobalt naphthenate, dibutyltin maleate, dibutyltin diacetate, triethylamine, K-1000 and benzyl glycidyl ether.
The accelerator is at least one of N, N-dimethyl-p-toluidine, N-methylpyrrole, triethanolamine and N, N-dimethyl-p-toluenesulfonyl chloride.
The hydroxyl-containing odor-free resin is odor-free alkyd resin, odor-free polyester resin or hydroxyl acrylic resin.
The wetting dispersant is at least one of an amino derivative-containing polycarboxylic acid high molecular polymer, a high molecular polyether compound containing pigment affinity groups, a polycarboxylic acid amide salt and a polycarboxylic acid organic amine electrically neutral salt.
The leveling agent is at least one of titanate modified organic silicon leveling agent, titanate modified polyacrylate leveling agent, organic silicon modified acrylic acid leveling agent, fluorine modified acrylic acid leveling agent and silica polymer leveling agent.
The rheological additive is at least one of nano-scale fumed silica, modified urea polymer and polyamide wax.
The solvent is at least one of ethyl acetate, butyl acetate, sec-butyl acetate, 120 white oil, D40 dearomatization solvent, diethylene glycol butyl ether, propylene glycol methyl ether, propylene glycol butyl ether, dipropylene glycol butyl ether and methyl 3-methoxypropionate.
The functional auxiliary agent is a delustering agent, a hardening agent, an anti-scratching agent, an anti-blocking agent, an anti-wear agent and an ultraviolet absorbent.
The defoaming agent is at least one of modified siloxane defoaming agent and polyacrylate defoaming agent.
Compared with other technologies in the field, the POSS modified high-hardness polyurethane odorless wood lacquer has the following advantages: (1) because a single molecule of the adopted curing agent contains 16 isocyanate groups, the curing agent has high crosslinking density when being cured with-OH in resin molecules, and a coating film has high adhesive force, high fullness, high hardness and high water resistance; (2) because the curing agent contains POSS groups, the coating film can obtain excellent hydrophobicity, flexibility, transparency, wear resistance, heat resistance, stain resistance and flame retardance. (2) The odor-free resin and the low-free monomer polyurethane curing agent are adopted, aromatic ketone and heavy metal are not contained, and the odor-free effect is achieved after 48 hours of film coating, so that the environment-friendly polyurethane odor-free wood lacquer is environment-friendly.
Detailed Description
The POSS modified high hardness polyurethane odorless wood lacquer of the present invention is further described below with reference to the examples. It is to be understood that the specific embodiments described herein are merely illustrative of the relevant invention and not restrictive of the invention.
Example 1
A POSS modified low free monomer polyurethane curing agent A is prepared by the following steps:
a) isocyanate trimer synthesis: in N2Under protection, adding 100.0 parts of IPDI monomer, 0.1 part of tri-N-butyl phosphorus and 30.0 parts of ethyl acetate into a reaction kettle, starting stirring to stir the materials uniformly, heating to 80 ℃ for reaction for 2 hours, dropwise adding 5.0 parts of ethyl acetate solution containing 2% of tri-N-butyl phosphorus and 2% of N-methylpyrrole, after the dropwise adding is completed within 0.5 hour, keeping at 80 ℃ for continuous reaction, detecting the NCO value once every 0.5 hour, immediately adding a polymerization inhibitor accounting for 0.5% of the mass of the isocyanate monomer when the detected NCO value is 9.0 +/-0.5%, and cooling to 20 ℃ to obtain an isocyanate trimer;
b) and the synthesis of the POSS modified low-free monomer polyurethane curing agent: at normal temperature, 19.2 parts of octaaminophenyl POSS and 30.0 parts of ethyl acetate solution are dropwise added into the isocyanate tripolymer, and after the dropwise addition is finished for 1h, the reaction is continued for 2h, so that the POSS modified low-free monomer polyurethane curing agent A is obtained.
Example 2
A POSS modified low free monomer polyurethane curing agent B is prepared by the following steps:
a) isocyanate trimer synthesis:in N2Under protection, adding 100.0 parts of HDI monomer, 0.1 part of K-1000 and 60.0 parts of isopropyl acetate into a reaction kettle, starting stirring to uniformly stir the materials, heating to 80 ℃ for reaction for 4 hours, dropwise adding 5.0 parts of isopropyl acetate solution containing 10% of K-1000 and 6% of triethanolamine, keeping the temperature at 80 ℃ for continuous reaction after the dropwise adding is completed within 0.5 hour, detecting the NCO value once every 0.5 hour, immediately adding a polymerization inhibitor accounting for 0.3% of the mass of the isocyanate monomer when the detected NCO value is 8.0 +/-0.5%, and cooling to 20 ℃ to obtain an isocyanate trimer;
b) and the synthesis of the POSS modified low-free monomer polyurethane curing agent: at normal temperature, 21.6 parts of octaaminophenyl POSS and 30.0 parts of isopropyl acetate solution are dropwise added into the isocyanate tripolymer, and after the dropwise addition is finished for 1h, the reaction is continued for 3h, so that the POSS modified low-free monomer polyurethane curing agent B is obtained.
Example 3
POSS modified high-hardness polyurethane odorless wood lacquer is composed of A, B two components, wherein the weight ratio of A, B components is 1.8: 1; the component A comprises the following components: 75.0 parts of saturated polyester resin, 0.5 part of amino derivative polycarboxylic acid polymer dispersant, 0.3 part of organic silicon modified acrylic acid leveling agent, 3.0 parts of nano-scale fumed silica, 21.0 parts of ethyl acetate and 0.2 part of modified siloxane defoamer; the component B comprises the following components: 55.0 parts of POSS modified low free monomer polyurethane curing agent A.
Example 4
POSS modified high-hardness polyurethane odorless wood lacquer is composed of A, B two components, wherein the weight ratio of A, B components is 1.67: 1; the component A comprises the following components: 70.0 parts of odor purifying alkyd resin, 1.0 part of macromolecular wetting dispersant, 0.4 part of fluorine modified acrylic acid leveling agent, 3.0 parts of modified urea polymer rheological additive, 18.0 parts of ethyl acetate, 5.0 parts of propylene glycol butyl ether, 2.5 parts of flatting agent and 0.1 part of modified siloxane defoaming agent; the component B is 60.0 parts of POSS modified low free monomer polyurethane curing agent B.
Example 5
POSS modified high-hardness polyurethane odorless wood lacquer is composed of A, B two components, wherein the weight ratio of A, B components is 1.75: 1; the component A comprises the following components: 80.0 parts of hydroxy acrylic resin, 0.5 part of macromolecular wetting dispersant, 0.3 part of silicone polymer flatting agent, 1.5 parts of polyamide wax, 14.0 parts of butyl acetate, 3.6 parts of methyl 3-methoxypropionate and 0.1 part of polyacrylate defoamer; the component B comprises the following components: 57.0 parts of POSS modified low free monomer polyurethane curing agent B.
The two-component polyurethane woodware coating in the embodiments 3, 4 and 5 and the odorless two-component polyurethane woodware coating (comparative example) on the market are sprayed on the surface of woodware according to the construction requirements, and after drying for 24 hours, the detection is carried out according to the relevant standards, and the test data is shown in table 1:
TABLE 1 technical index of polyurethane woodenware paint performance
Although the present invention has been described in detail and with reference to exemplary embodiments thereof, it will be apparent to one skilled in the art that various changes, modifications and variations can be made therein without departing from the spirit and scope of the invention as defined in the appended claims.
Claims (9)
1. The POSS modified high-hardness polyurethane odor-free wood lacquer is characterized in that: the POSS modified high-hardness polyurethane odorless wood lacquer consists of A, B two components, wherein the weight ratio of A, B components is 1.4-1.8: 1; the component A comprises the following components in percentage by weight: 50.0-85.0% of hydroxyl-containing odorless resin, 0.2-2.0% of wetting dispersant, 0.1-1.0% of flatting agent, 0.3-5.0% of rheological additive, 0.1-0.5% of defoaming agent, 0-6.0% of functional additive and 12.0-40.0% of solvent; the component B is a POSS modified low free monomer polyurethane curing agent;
the POSS modified low-free monomer polyurethane curing agent takes cage type polysilsesquioxane as a center, contains 16 isocyanate groups, and has a molecular structural formula shown as follows:
the preparation method comprises the following steps:
a) isocyanate trimer synthesis: in N2Under protection, adding 100.0 parts of isocyanate monomer, 0.05-0.1 part of catalyst and 30.0-60.0 parts of solvent into a reaction kettle, starting stirring to uniformly stir the materials, heating to 50-80 ℃ for reaction for 2-4 h, dropwise adding 5.0 parts of mixed solution containing the catalyst, the accelerator and the solvent, after 0.5h of dropwise adding, keeping at 50-80 ℃ for continuous reaction, detecting the NCO value once every 0.5h, immediately adding a polymerization inhibitor accounting for 0.1-0.5% of the mass of the isocyanate monomer when the detected NCO value is 10-7%, and cooling to 20 ℃ to obtain the isocyanate trimer;
b) and the synthesis of the POSS modified low-free monomer polyurethane curing agent: dropwise adding a mixed solution of 15.0-40.0 parts of octaaminophenyl POSS and 30.0 parts of solvent into the isocyanate tripolymer at normal temperature, and continuously reacting for 2-3 hours after the dropwise adding is finished for 0.5-1 hour to obtain the POSS modified low-free monomer polyurethane curing agent;
the free monomer content of the POSS modified low free monomer polyurethane curing agent is less than 0.5 percent.
2. The POSS modified high hardness polyurethane odor-free wood lacquer of claim 1, wherein: the hydroxyl-containing odor-free resin is odor-free alkyd resin, odor-free polyester resin or hydroxyl acrylic resin.
3. The POSS modified high hardness polyurethane odor-free wood lacquer of claim 1, wherein: the isocyanate monomer is at least one of TDI, MDI, NDI, TODI, HDI, TMDI, XDI, IPDI, HMDI or HTDI.
4. The POSS modified high hardness polyurethane odor-free wood lacquer of claim 1, wherein: the mixed solution containing the catalyst, the accelerant and the solvent comprises the following components in percentage by mass: 2.0-10.0 percent of catalyst, 2.0-10.0 percent of accelerant and 80.0-96.0 percent of solvent.
5. The POSS modified high hardness polyurethane odor-free wood lacquer of claim 1, wherein: the catalyst is at least one of dibutyltin dilaurate, lithium acetate, tri-n-butylphosphorus, stannous octoate, tin naphthenate, lead naphthenate, cobalt naphthenate, dibutyltin maleate, dibutyltin diacetate, triethylamine or benzyl glycidyl ether.
6. The POSS modified high hardness polyurethane odor-free wood lacquer of claim 1, wherein: the accelerator is at least one of N, N-dimethyl-p-toluidine, N-methylpyrrole or triethanolamine.
7. The POSS modified high hardness polyurethane odor-free wood lacquer of claim 1, wherein: the wetting dispersant is at least one of an amino derivative polycarboxylic acid high molecular polymer, a high molecular polyether compound containing pigment affinity groups, a polycarboxylic acid amide salt or a polycarboxylic acid organic amine charge neutral salt; the leveling agent is at least one of a titanate modified organic silicon leveling agent, a titanate modified polyacrylate leveling agent, an organic silicon modified acrylic acid leveling agent, a fluorine modified acrylic acid leveling agent or a silicon-oxygen polymer leveling agent; the rheological additive is at least one of nano-scale fumed silica, modified urea polymer or polyamide wax; the defoaming agent is at least one of modified siloxane defoaming agent or polyacrylate defoaming agent.
8. The POSS modified high hardness polyurethane odor-free wood lacquer of claim 1, wherein: the functional auxiliary agent is a delustering agent, a hardening agent, an anti-scratching agent, an anti-blocking agent, an anti-wear agent or an ultraviolet absorbent.
9. The POSS modified high hardness polyurethane odor-free wood lacquer of claim 1 or 4, wherein: the solvent is at least one of ethyl acetate, butyl acetate, sec-butyl acetate, 120 white oil, D40 dearomatization solvent, diethylene glycol butyl ether, propylene glycol methyl ether, propylene glycol butyl ether, dipropylene glycol butyl ether and methyl 3-methoxypropionate.
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| CN201711064341.5A CN107936814B (en) | 2017-11-02 | 2017-11-02 | POSS (polyhedral oligomeric silsesquioxane) modified high-hardness polyurethane odor-free wood lacquer |
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| CN201711064341.5A CN107936814B (en) | 2017-11-02 | 2017-11-02 | POSS (polyhedral oligomeric silsesquioxane) modified high-hardness polyurethane odor-free wood lacquer |
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| CN109321104A (en) * | 2018-09-28 | 2019-02-12 | 韶关市合众化工有限公司 | A kind of polyether-ether-ketone modified polyurethane two-component ordor removing woodcare paint |
| CN114806379A (en) * | 2019-12-31 | 2022-07-29 | 江西贝特利新材料有限公司 | High-flexibility coating applied to ethylene propylene diene monomer and preparation method thereof |
| CN112827220B (en) * | 2021-01-09 | 2023-08-15 | 湖北英采化学有限公司 | High-temperature-resistant delayed coking defoamer and preparation method thereof |
| CN113717371B (en) * | 2021-08-30 | 2023-11-10 | 山东一诺威新材料有限公司 | Preparation method of low-viscosity reactive flame-retardant polyether polyol, reactive flame-retardant heat-conducting polyurethane electronic pouring sealant and preparation method thereof |
| CN115124719B (en) * | 2022-09-02 | 2022-12-02 | 广东腐蚀科学与技术创新研究院 | Terminated POSS-containing polyisocyanate curing agent and weather-resistant anti-fouling anticorrosive polyurethane powder coating |
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| US20080108773A1 (en) * | 2006-11-06 | 2008-05-08 | Wicks Douglas A | Polyurethane dispersions containing POSS nanoparticles |
| WO2009065873A2 (en) * | 2007-11-21 | 2009-05-28 | Basf Se | Polyhedral oligomeric stannasilsesquioxanes as catalyst for polyurethane curing |
| CN101250375B (en) * | 2008-04-03 | 2010-09-22 | 同济大学 | POSS/polyurethane aqueous composite paint and preparation method thereof |
| CN102827340B (en) * | 2011-06-13 | 2014-04-02 | 中国科学院化学研究所 | Organosilicon-modified waterborne polyurethane composite material and applications thereof |
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Application publication date: 20180420 Assignee: Guangdong Yaoda Financial Leasing Co., Ltd Assignor: UNION (FOSHAN) CHEMICAL Co.,Ltd. Contract record no.: X2021980004392 Denomination of invention: A POS modified high hardness polyurethane finish for wood Granted publication date: 20200320 License type: Exclusive License Record date: 20210604 |
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Denomination of invention: A POS modified high hardness polyurethane finish for wood Effective date of registration: 20210607 Granted publication date: 20200320 Pledgee: Guangdong Yaoda Financial Leasing Co., Ltd Pledgor: UNION (FOSHAN) CHEMICAL Co.,Ltd. Registration number: Y2021980004467 |
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