CN112609458A - 一种纺织品阻燃耐高温涂层胶的制备方法 - Google Patents

一种纺织品阻燃耐高温涂层胶的制备方法 Download PDF

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CN112609458A
CN112609458A CN202011374557.3A CN202011374557A CN112609458A CN 112609458 A CN112609458 A CN 112609458A CN 202011374557 A CN202011374557 A CN 202011374557A CN 112609458 A CN112609458 A CN 112609458A
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李小军
曹虹
李阳
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Suzhou Winnings Chemical Co ltd
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Abstract

本发明公开了一种纺织品阻燃耐高温涂层胶的配方及其制备，包括以下成分（按质量百分比）：聚四氟乙烯：15～20％、聚氨酯：20～25％、磷氮阻燃剂：25～30%、丙烯酸树脂：20～25％、磷酸酯阻燃剂：12～18％、溶剂：3～5％、交联剂：2～4％、气相二氧化硅：0.5～1%、增稠剂：0.2～0.6、柔软剂：0.2～0.5。本发明还公开了一种纺织品阻燃耐高温涂层胶对织物进行涂层整理,遇火后在纺织品表面形成一层碳层,有效地隔绝火焰,可以通B1级阻燃测试标准。

Description

一种纺织品阻燃耐高温涂层胶的制备方法
技术领域
本发明涉及化工新材料领域,具体说是一种纺织品阻燃耐高温涂层胶的配方及其制备。
背景技术
随着经济的不断发展,工业和民用纺织品迅速增长,但同时由纺织品引起的火灾也不断增加,时刻威胁着人类的生命和财产安全。因此,对纺织品进行阻燃耐高温处理,延缓火灾蔓延速度,对减少生命财产损失非常有意义。目前工业发达国家和地区制定了相应的纺织
品阻燃标准及测试方法，比如家纺织物的BS-5852:2006阻燃测试标、遮阳材料NTA8825:2010阻燃测试标准、B1级：难燃性建筑材料：难燃类材料有较好的阻燃作用。其在空气中遇明火或在高温作用下难起火，不易很快发生蔓延，且当火源移开后燃烧立即停止。还出台相关法律进行强制执行。这促进了各国工业部门和研究部门对纺织品阻燃的研究,因此推动了耐高温阻燃涂层胶的发展。
现有的阻燃涂层胶几乎都是采用复配技术,阻燃机理方面主要以气相阻燃机理和膨胀性阻燃剂两种。气相阻燃机理缺乏耐高温能力,不能对火源进行有效的隔绝，遇火织物直接被烧开,点燃后无法自熄。
膨胀性阻燃剂受热时,表面生成一层起到隔热、隔氧和抑烟,并能防止
产生熔滴,具有一定厚度的均匀碳层,该碳层具有良好的阻燃性能,很好的弥补了气相阻燃剂的缺陷,单独采用膨胀型阻燃剂应用于涂层,虽然能成碳阻燃,但在抑制续燃和阻燃方面仍有不足,其在阻燃过程中产生更多的黑烟和更大的烟毒。因此，发明一种纺织品阻燃耐高温
涂层胶的制备方法来解决上述问题很有必要。
发明内容
本发明所要解决的技术问题是克服上述现有技术存在的缺陷，提供一种在空气中遇明火或在高温作用下难起火，不易很快发生蔓延，表面生成碳层,以有效的隔绝火焰，且当火源移开后燃烧立即停止；
为实现上述目的，本发明提供如下技术方案：一种纺织品阻燃耐高温涂层胶的配方及其制备，其包括以下成分(按质量百分比)：聚四氟乙烯 ：15～20％、聚氨酯：20～25％、磷氮阻燃剂：25～30%、丙烯酸树脂：20～25％、磷酸酯阻燃剂：12～18％、溶剂：3～5％、交联剂 ： 2～4％、气相二氧化硅 ：0.5～1%、增稠剂：0.2～0.6、柔软剂：0.2～0.5。
所述的纺织品阻燃耐高温涂层胶,其特征在于,所述的聚氨酯、丙烯酸树脂均为水性。
进一步，所述的纺织品阻燃耐高温涂层胶,其特征在于,所述聚四氟乙烯作为防火、耐高温、耐强酸强碱、绝缘材料。
所述的纺织品阻燃耐高温涂层胶,其特征在于,所述交联剂为甲苯二异氰酸酷。
进一步，所述的纺织品阻燃耐高温涂层胶,其特征在于,所述柔软剂为有机硅树脂。
进一步，所述的纺织品阻燃耐高温涂层胶,其特征在于,所述气相二氧化硅为分散剂。
进一步，所述纺织品阻燃耐高温涂层胶的制备方法,包括如下步骤：
步骤一：在搅拌釜中加入聚氨酯树脂、丙烯酸树脂、有机硅树脂，加适量水充分搅拌，温度控制在75～85℃，然后搅拌一小时后静置，即为树脂溶液。
步骤二：在搅拌釜中依次加入树脂溶液、聚四氟乙烯、磷氮阻燃剂、磷酸酯阻燃剂、交联剂、气相二氧化硅、增稠剂，开启搅拌，加热至85～105℃，搅拌30min，然后冷却至常温。
步骤三：,对上述混合物进行研磨处理,使其混合胶粒子直径小于8微米，然后加入增稠剂,充分搅拌,过滤后即得纺织品阻燃耐高温涂层胶。
本发明的技术效果和优点：本发明采用了磷氮阻燃剂和磷酸酯，这两个阻燃剂配合其他原料可显著提高本发明的阻燃性能；本发明采用了气相二氧化硅作为分散剂，使得本发明具有优异的分散性和防流挂；本发明采用聚四氟乙烯、聚氨酯、丙烯酸树脂及其他原料，在高温200度下可以形成一层保护膜，保护膜可耐300度高温；本发明中的聚四氟乙烯具有良好的耐高温性、绝缘性、抗腐蚀性和阻燃性；本发明阻燃胶附着力强，色泽鲜亮、干燥快，耐高温性和阻燃性好，遇火成碳,同时还可以提高织物的静水压、撕破强力。使用过程中不释放甲醛、挥发性溶剂等有毒物质,使用寿命长。安全环保,具有广阔的市场前景。
附图说明
图1为本发明实施例4与对比例,涤纶织物检测照片。
图2为本发明实施例4与对比例,检测结果。
具体实施方式
下面结合具体实施方式和说明书附图对本发明作进一步说明，
实施例1：一种纺织品阻燃耐高温涂层胶的配方及其制备，其包括以下成分(按质量百分比)：
成分 聚四氟乙烯 聚氨酯 磷氮阻燃剂 丙烯酸树脂 磷酸酯阻燃剂 溶剂 交联剂 气相二氧化硅 增稠剂 柔软剂
质量% 15 20 25 20 12 5 2 0.5 0.2 0.2
实施例1：所述一种纺织品阻燃耐高温涂层胶的制备方法,包括如下步骤：
步骤一：在搅拌釜中加入聚氨酯树脂、丙烯酸树脂、有机硅树脂，加适量水充分搅拌，温度控制在75～85℃，然后搅拌一小时后静置，即为树脂溶液。
步骤二：在搅拌釜中依次加入树脂溶液、聚四氟乙烯、磷氮阻燃剂、磷酸酯阻燃剂、交联剂、气相二氧化硅、增稠剂，开启搅拌，加热至85～105℃，搅拌30min，然后冷却至常温。
步骤三：,对上述混合物进行研磨处理,使其混合胶粒子直径小于8微米，然后加入增稠剂,充分搅拌,过滤后即得纺织品阻燃耐高温涂层胶。
实施例2：一种纺织品阻燃耐高温涂层胶的配方及其制备，其包括以下成分(按质量百分比)：
成分 聚四氟乙烯 聚氨酯 磷氮阻燃剂 丙烯酸树脂 磷酸酯阻燃剂 溶剂 交联剂 气相二氧化硅 增稠剂 柔软剂
质量% 14 21 24 21 12 5 2 0.5 0.2 0.2
实施例2：所述一种纺织品阻燃耐高温涂层胶的制备方法,包括如下步骤：
步骤一：在搅拌釜中加入聚氨酯树脂、丙烯酸树脂、有机硅树脂，加适量水充分搅拌，温度控制在75～85℃，然后搅拌一小时后静置，即为树脂溶液。
步骤二：在搅拌釜中依次加入树脂溶液、聚四氟乙烯、磷氮阻燃剂、磷酸酯阻燃剂、交联剂、气相二氧化硅、增稠剂，开启搅拌，加热至85～105℃，搅拌30min，然后冷却至常温。
步骤三：,对上述混合物进行研磨处理,使其混合胶粒子直径小于8微米，然后加入增稠剂,充分搅拌,过滤后即得纺织品阻燃耐高温涂层胶。
实施例3：一种纺织品阻燃耐高温涂层胶的配方及其制备，其包括以下成分(按质量百分比)：
成分 聚四氟乙烯 聚氨酯 磷氮阻燃剂 丙烯酸树脂 磷酸酯阻燃剂 溶剂 交联剂 气相二氧化硅 增稠剂 柔软剂
质量% 16 19 24 21 12 5 2 0.5 0.2 0.2
实施例3：所述一种纺织品阻燃耐高温涂层胶的制备方法,包括如下步骤：
步骤一：在搅拌釜中加入聚氨酯树脂、丙烯酸树脂、有机硅树脂，加适量水充分搅拌，温度控制在75～85℃，然后搅拌一小时后静置，即为树脂溶液。
步骤二：在搅拌釜中依次加入树脂溶液、聚四氟乙烯、磷氮阻燃剂、磷酸酯阻燃剂、交联剂、气相二氧化硅、增稠剂，开启搅拌，加热至85～105℃，搅拌30min，然后冷却至常温。
步骤三：,对上述混合物进行研磨处理,使其混合胶粒子直径小于8微米，然后加入增稠剂,充分搅拌,过滤后即得纺织品阻燃耐高温涂层胶。
表一配方对比列
实施例1 实施例2 实施例3
聚四氟乙烯 15 14 16
聚氨酯 20 21 19
磷氮阻燃剂 25 24 24
丙烯酸树脂 20 20 20
磷酸酯阻燃剂 12 12 12
溶剂 5 5 5
交联剂 2 2 2
气相二氧化硅 0.5 0.5 0.5
增稠剂 0.2 0.2 0.2
柔软剂 0.2 0.2 0.2
通过以上三组实施例均可以制得阻燃耐高温涂层胶的配方，其中第二组实施例制得的阻燃耐高温涂层胶的配方效果最好，本发明采用磷氮阻燃剂和磷酸酯，这两个阻燃剂配合其他原料可显著提高本发明的阻燃性能；本发明采用了气相二氧化硅作为分散剂，使得本发明具有优异的分散性和防流挂；本发明采用聚四氟乙烯、聚氨酯、丙烯酸树脂及其他原料，在高温200度下可以形成一层保护膜，保护膜可耐300度高温；本发明中的聚四氟乙烯具有良好的耐高温性、绝缘性、抗腐蚀性和阻燃性；本发明阻燃胶附着力强，色泽鲜亮、干燥快，耐高温性和阻燃性好，遇火成碳,同时还可以提高织物的静水压、撕破强力。
最后应说明的是：以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (7)

1.一种纺织品阻燃耐高温涂层胶的配方及其制备，其特征在于，包括以下成分(按质量百分比)：聚四氟乙烯 ：15～20％、聚氨酯：20～25％、磷氮阻燃剂：25～30%、丙烯酸树脂：20～25％、磷酸酯阻燃剂：12～18％、溶剂：3～5％、交联剂： 2～4％、气相二氧化硅：0.5～1%、增稠剂： 0.2-0.6、柔软剂：0.2-0.5。
2.根据权利要求1所述的纺织品阻燃耐高温涂层胶,其特征在于,所述的聚氨酷、丙烯酸树脂均为水性。
3.根据权利要求1所述的纺织品阻燃耐高温涂层胶,其特征在于,所述聚四氟乙烯作为防火、耐高温、耐强酸强碱、绝缘材料。
4.根据权利要求1所述的纺织品阻燃耐高温涂层胶,其特征在于,所述交联剂为甲苯二异氰酸酷。
5.根据权利要求1所述的纺织品阻燃耐高温涂层胶,其特征在于,所述柔软剂为有机硅树脂。
6.根据权利要求1所述的纺织品阻燃耐高温涂层胶,其特征在于,所述气相二氧化硅为分散剂。
7.权利要求1-6一任一项所述一种纺织品阻燃耐高温涂层胶的制备方法,包括如下步骤：
步骤一：在搅拌釜中加入聚氨酯树脂、丙烯酸树脂、有机硅树脂，加适量水充分搅拌，温度控制在75～85℃，然后搅拌一小时后静置，即为树脂溶液；
步骤二：在搅拌釜中依次加入树脂溶液、聚四氟乙烯、磷氮阻燃剂、磷酸酯阻燃剂、交联剂、气相二氧化硅、增稠剂，开启搅拌，加热至85～105℃，搅拌30min，然后冷却至常温；
步骤三：,对上述混合物进行研磨处理,使其混合胶粒子直径小于8微米，然后加入增稠剂,充分搅拌,过滤后即得纺织品阻燃耐高温涂层胶。
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