Corrosion-inhibition fog inhibitor
Technical Field
The invention relates to the technical field of metal surface treatment, in particular to a corrosion and fog inhibitor.
Background
Ordinary carbon steel is easy to rust, and an oil stain layer and a corrosion layer on the surface of the ordinary carbon steel need to be removed before processing and use. The most common method in industry is to dissolve and remove the rust layer and the oil stain layer by using acid liquor and other additives as rust removers, and the method has the advantages of lowest cost and simple operation. In the hydrochloric acid pickling process, on one hand, the hydrochloric acid has certain volatility and is directly volatilized into the atmosphere to generate acid mist; on the other hand, hydrogen is generated on the surface of the steel through oxidation-reduction reaction and gradually forms bubbles, when the bubbles gradually increase to be more than about 0.3mm in diameter, the buoyancy of the bubbles exceeds the interfacial tension, the bubbles are separated from the metal surface and are accelerated to rise from hydrochloric acid until the acid liquid and the air interface burst, and the generated splash liquid drops are sprayed into the atmosphere at the speed of 10m/s, so that a large amount of acid liquid enters the atmosphere in the form of tiny liquid drops and is stably suspended in the air to form acid mist.
After the formation of acid mist, the following serious hazards will occur: firstly, the conditions of a working site are worsened, and the physical health of workers is seriously injured; secondly, serious pollution is caused to the atmosphere and the surrounding environment; thirdly, production facilities and equipment are seriously corroded, and the service life of the equipment is greatly shortened; and fourthly, the acid liquor is excessively lost, so that unnecessary waste is caused. Various problems caused by hydrochloric acid mist are increasingly prominent, and the harmfulness is increased, so that an efficient and economic method is urgently needed to solve the problem of the hydrochloric acid mist.
In order to reduce or slow down the volatilization of acid mist, a corrosion-inhibiting fog inhibitor is usually added into the acid liquor to inhibit the generation of the volatilization of the acid mist, simultaneously promote the removal of various oil stains in the metal pickling process, slow down or inhibit the corrosion of acid to metal, has good synergistic effect with the acid, and is suitable for acid use at various temperatures. The existing corrosion and fog inhibition agent needs to be fully stirred after acid liquor is added in use, so that the acid washing efficiency is influenced, the use cost is increased, and in addition, the acid fog isolation effect of the existing corrosion and fog inhibition agent is not good and needs to be improved.
Disclosure of Invention
1. Technical problem to be solved
Aiming at the problems in the prior art, the invention aims to provide a corrosion and fog inhibitor, wherein a corrosion and fog inhibitor with corrosion and fog inhibition effects is filled in a corrosion and fog inhibitor filling ring, so that the slow release of the corrosion and fog inhibitor is realized, the corrosion and fog inhibitor can be fully contacted with acid liquor while the corrosion and fog inhibitor is slowly released, oil stains generated in the acid pickling process can be adsorbed by an oil absorption fiber net, and when a plurality of regular hexagonal annular shells are combined together, an oil stain isolation layer which is not easy to break can be formed on the surface of the acid liquor, so that the overflow of acid fog is effectively inhibited.
2. Technical scheme
In order to solve the above problems, the present invention adopts the following technical solutions.
The corrosion and fog inhibition agent comprises a corrosion and fog inhibition component and a corrosion and fog inhibition filling ring, wherein the corrosion and fog inhibition component is filled in the corrosion and fog inhibition filling ring, and the corrosion and fog inhibition component comprises the following components in parts by weight: 10-15% of ethanol, 5-10% of isopropanol, 5-9% of accelerator, 5-10% of corrosion inhibitor, 15-20% of surfactant, 3-5% of foam stabilizer and the balance of deionized water.
Furthermore, the corrosion-inhibition and fog-inhibition filling ring comprises a regular hexagon annular shell, an oil-absorbing fiber mesh matched with the regular hexagon annular shell is fixed on the inner side wall of the regular hexagon annular shell, hemispherical clamping grooves are formed in the center positions of the side walls of three sides of the regular hexagon annular shell, hemispherical clamping blocks matched with the hemispherical clamping grooves are fixed in the center positions of the side walls of the other three sides of the regular hexagon annular shell, the hemispherical clamping grooves and the hemispherical clamping blocks are arranged at intervals, mounting grooves are formed in the centers of six sides of the regular hexagon annular shell, a first magnet block and a second magnet block are mounted in the mounting grooves, the first magnet block and the second magnet block are perpendicular to the side wall of the regular hexagon annular shell, the magnetic pole arrangement directions of the first magnet block and the second magnet block are arranged, and the first magnet block and the hemispherical clamping grooves are arranged correspondingly, the second magnet block and the hemispherical clamping block are arranged correspondingly, a corrosion and fog inhibitor filling groove is formed in the outer side wall of the regular hexagonal annular shell along the tangential direction of the side where the second magnet block is located, six corrosion and fog inhibitor filling grooves are distributed in an annular array mode with the geometric center of the regular hexagonal annular shell, a sealing protective layer is arranged at an opening of each corrosion and fog inhibitor filling groove, the corrosion and fog inhibitor filling grooves are filled with the corrosion and fog inhibitor, the regular hexagonal annular shell integrally sinks to the bottom of acid liquor when the corrosion and fog inhibitor filling grooves are filled with the corrosion and fog inhibitor, and the regular hexagonal annular shell integrally floats on the surface of the acid liquor when the corrosion and fog inhibitor filling grooves are not filled with the corrosion and fog inhibitor. When in use, the plurality of corrosion and fog inhibition filling rings are sequentially placed into the acid liquor according to the placing amount, when in an initial state, the regular hexagonal annular shell is integrally sunk to the bottom of the acid liquor, the sealing protective layer begins to be decomposed after contacting with the acid liquor, the corrosion and fog inhibition components gradually seep out, the slow release of the corrosion and fog inhibition components is realized, the regular hexagonal annular shell gradually floats upwards while the corrosion and fog inhibition components gradually seep out, the full contact between the corrosion and fog inhibition components and the acid liquor is realized, and the regular hexagonal annular shell floats upwards to the liquid level surface after the fog inhibition components are fully seeped out, because the plurality of first magnet blocks and the plurality of second magnet blocks are arranged, the plurality of regular hexagonal annular shells are adsorbed together, and because the hemispherical clamping grooves and the hemispherical clamping blocks are arranged, the clamping combination of the plurality of regular hexagonal annular shells is realized, the combination is firmer, the oil absorption fiber net is arranged on the oil absorption fiber net and can absorb oil stains generated in the pickling process, and when the regular hexagonal annular shells are combined together, an oil stain isolation layer which is not easy to break can be formed on the surface of acid liquor, so that the overflow of acid mist is effectively inhibited.
Further, the oil absorption fiber net is a net structure woven by oil absorption fibers, and the oil absorption fibers are chemically synthesized oil absorption fibers, specifically one of polypropylene, polyurethane and alkyl ethylene polymer. The oil absorption fiber is woven into a net structure, the oil absorption effect is effectively improved, the strength of an oil pollution isolation layer is reinforced, the chemically synthesized oil absorption fiber is adopted, the hydrophobic and oleophylic characteristics of the oil absorption fiber and gaps among polymer molecules are utilized to conceal oil absorption, the oil absorption speed is high, the oil absorption rate is high, the overall performance is good, and the use and the recovery are convenient.
Furthermore, the sealing protective layer is a sealing film decomposed in the presence of acid or a sealing protective layer made of a material decomposed in the presence of acid.
Furthermore, a positioning rod is fixed inside the corrosion and fog inhibitor filling groove and is perpendicular to the bottom in the regular hexagon annular shell, a plurality of acid decomposition protective films are fixed on the positioning rod and are spherical films which are decomposed when meeting acids, and a sodium bicarbonate reactant is filled inside the acid decomposition protective films. The acid-resistant corrosion-inhibiting agent filling groove is formed in six edges of the regular hexagonal annular shell, so that acting forces are exerted on the six edges along the tangential direction of the regular hexagonal annular shell, the regular hexagonal annular shell rotates in the acid liquor, the full mixing of the corrosion-inhibiting fog-inhibiting components and the acid liquor can be accelerated, the acid liquor does not need to be stirred when the acid liquor is added, stirring equipment is omitted, the acid pickling efficiency is improved, and the use cost is reduced.
Further, the accelerator is bromopyridine or disodium hydrogen phosphate.
Further, the corrosion inhibitor is a sodium salt corrosion inhibitor or an ammonium salt corrosion inhibitor, the sodium salt corrosion inhibitor is one of sodium benzoate, trisodium phosphate, sodium tripolyphosphate, sodium molybdate, sodium silicate and trisodium citrate, and the ammonium salt corrosion inhibitor is one of triammonium citrate, ammonium phosphomolybdate, ammonium acetate and ammonium sulfate.
Further, the surfactant is a nonionic surfactant, and the nonionic surfactant is one of octyl phenol polyoxyethylene ether, cocoyl diethanol amine, fatty alcohol polyoxyethylene ether 7, alkylphenol polyoxyethylene ether, end-capping polyether, fatty acid polyoxyethylene methyl ether, fatty alcohol polyoxyethylene ether 9, stearamidopropyl dimethylamine, coconut oil fatty acid monoethanolamide and nonylphenol polyoxyethylene ether.
Further, the foam stabilizer is dodecyl dimethyl amine oxide or alkylolamide.
Further, the preparation method of the corrosion-inhibition fog-suppression component comprises the following steps:
s1, taking the components of the corrosion-inhibition fog-suppression component raw material according to the component proportion;
s2, adding ethanol, isopropanol and an accelerant into a stirring device, and fully stirring to obtain a mixture A;
s3, adding a corrosion inhibitor and deionized water into the mixture A, and fully stirring to obtain a mixture B;
s3, adding the foam stabilizer and the surfactant into the mixture A, and fully stirring to obtain the corrosion-inhibiting and fog-inhibiting component.
3. Advantageous effects
Compared with the prior art, the invention has the advantages that:
(1) the corrosion and fog inhibitor comprises a corrosion and fog inhibitor component and a corrosion and fog inhibitor filling ring, wherein the corrosion and fog inhibitor component is filled in the corrosion and fog inhibitor filling ring, and comprises ethanol, isopropanol, an accelerator, a corrosion inhibitor, a surfactant, a foam stabilizer, deionized water and the like, so that the corrosion and fog inhibitor has an obvious effect of inhibiting acid fog, obviously improves the working environment of a production workshop, reduces the damage of the acid fog to plants, equipment, workers and the surrounding environment, has a good corrosion inhibition effect, can effectively control the acid fog brought out by hydrogen precipitation with a proper corrosion inhibition rate, does not influence the pickling speed of a pickling production line of a large-scale steel plant, and ensures the yield of pickling products.
(2) When in use, the plurality of corrosion and fog inhibition filling rings are sequentially placed into the acid liquor according to the placing amount, when in an initial state, the regular hexagonal annular shell is integrally sunk to the bottom of the acid liquor, the sealing protective layer begins to be decomposed after contacting with the acid liquor, the corrosion and fog inhibition components gradually seep out, the slow release of the corrosion and fog inhibition components is realized, the regular hexagonal annular shell gradually floats upwards while the corrosion and fog inhibition components gradually seep out, the full contact between the corrosion and fog inhibition components and the acid liquor is realized, and the regular hexagonal annular shell floats upwards to the liquid level surface after the fog inhibition components are fully seeped out, because the plurality of first magnet blocks and the plurality of second magnet blocks are arranged, the plurality of regular hexagonal annular shells are adsorbed together, and because the hemispherical clamping grooves and the hemispherical clamping blocks are arranged, the clamping combination of the plurality of regular hexagonal annular shells is realized, the combination is firmer, the oil absorption fiber net is arranged on the oil absorption fiber net and can absorb oil stains generated in the pickling process, and when the regular hexagonal annular shells are combined together, an oil stain isolation layer which is not easy to break can be formed on the surface of acid liquor, so that the overflow of acid mist is effectively inhibited.
(3) The oil absorption fiber is woven into a net structure, the oil absorption effect is effectively improved, the strength of an oil pollution isolation layer is reinforced, the chemically synthesized oil absorption fiber is adopted, the hydrophobic and oleophylic characteristics of the oil absorption fiber and gaps among polymer molecules are utilized to conceal oil absorption, the oil absorption speed is high, the oil absorption rate is high, the overall performance is good, and the use and the recovery are convenient.
(4) The acid-resistant corrosion-inhibiting agent filling groove is formed in six edges of the regular hexagonal annular shell, so that acting forces are exerted on the six edges along the tangential direction of the regular hexagonal annular shell, the regular hexagonal annular shell rotates in the acid liquor, the full mixing of the corrosion-inhibiting fog-inhibiting components and the acid liquor can be accelerated, the acid liquor does not need to be stirred when the acid liquor is added, stirring equipment is omitted, the acid pickling efficiency is improved, and the use cost is reduced.
Drawings
FIG. 1 is a front view of the present invention;
FIG. 2 is an enlarged schematic view of the structure at A in FIG. 1;
FIG. 3 is a schematic view of the present invention in the state of being placed in an acid solution;
FIG. 4 is a schematic view of the protective layer after being decomposed in acid solution when the protective layer is decomposed in the presence of acid;
FIG. 5 is a schematic view showing the ejection direction of carbon dioxide put into the acid solution according to the present invention;
FIG. 6 is a diagram showing the combination of a plurality of corrosion-inhibiting mist-suppressing filled rings floating on the surface of an acid solution according to the present invention.
The reference numbers in the figures illustrate:
the device comprises a regular hexagon annular shell, a 2 oil absorption fiber net, a 3 hemispherical clamping groove, a 4 hemispherical clamping block, a 5 first magnet block, a 6 second magnet block, a 7 corrosion inhibition and fog inhibitor filling groove, an 8 sealing protective layer, a 9 positioning rod, a 10 acid decomposition protective film and a 11 sodium bicarbonate reactant.
Detailed Description
The drawings in the embodiments of the invention will be combined; the technical scheme in the embodiment of the invention is clearly and completely described; obviously; the described embodiments are only some of the embodiments of the invention; but not all embodiments, are based on the embodiments of the invention; all other embodiments obtained by a person skilled in the art without making any inventive step; all fall within the scope of protection of the present invention.
In the description of the present invention, it should be noted that the terms "upper", "lower", "inner", "outer", "top/bottom", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of description and simplification of description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus should not be construed as limiting the present invention. Furthermore, the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the present invention, it should be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "disposed," "sleeved/connected," "connected," and the like are to be construed broadly, e.g., "connected," which may be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
Example 1:
referring to fig. 1, a corrosion and fog inhibitor includes a corrosion and fog inhibitor component and a corrosion and fog inhibitor filling ring, wherein the corrosion and fog inhibitor component is filled in the corrosion and fog inhibitor filling ring, and the corrosion and fog inhibitor component includes the following components in parts by weight: 10-15% of ethanol, 5-10% of isopropanol, 5-9% of accelerator, 5-10% of corrosion inhibitor, 15-20% of surfactant, 3-5% of foam stabilizer and the balance of deionized water.
Wherein the accelerator is pyridine bromide or disodium hydrogen phosphate.
The corrosion inhibitor is a sodium salt corrosion inhibitor or an ammonium salt corrosion inhibitor, the sodium salt corrosion inhibitor is one of sodium benzoate, trisodium phosphate, sodium tripolyphosphate, sodium molybdate, sodium silicate and trisodium citrate, and the ammonium salt corrosion inhibitor is one of triammonium citrate, ammonium phosphomolybdate, ammonium acetate and ammonium sulfate.
The surfactant is nonionic surfactant, and the nonionic surfactant is one of octyl phenol polyoxyethylene ether, cocoyl diethanol amine, fatty alcohol polyoxyethylene ether 7, alkylphenol polyoxyethylene ether, end capping polyether, fatty acid polyoxyethylene methyl ether, fatty alcohol polyoxyethylene ether 9, stearamidopropyl dimethylamine, coconut oil fatty acid monoethanolamide and nonyl phenol polyoxyethylene ether.
The foam stabilizer is dodecyl dimethyl amine oxide or alkylolamide.
The preparation method of the corrosion-inhibition fog-suppression component comprises the following steps:
s1, taking the components of the corrosion-inhibition fog-suppression component raw material according to the component proportion;
s2, adding ethanol, isopropanol and an accelerant into a stirring device, and fully stirring to obtain a mixture A;
s3, adding a corrosion inhibitor and deionized water into the mixture A, and fully stirring to obtain a mixture B;
s3, adding the foam stabilizer and the surfactant into the mixture A, and fully stirring to obtain the corrosion-inhibiting and fog-inhibiting component.
Referring to fig. 1-2, the corrosion-inhibiting and fog-inhibiting packing ring comprises a regular hexagonal annular housing 1, an oil-absorbing fiber net 2 matched with the regular hexagonal annular housing 1 is fixed on the inner side wall of the regular hexagonal annular housing 1, hemispherical clamping grooves 3 are respectively formed in the center positions of the side walls of three sides of the regular hexagonal annular housing 1, hemispherical clamping blocks 4 matched with the hemispherical clamping grooves 3 are respectively fixed in the center positions of the side walls of the other three sides, the hemispherical clamping grooves 3 and the hemispherical clamping blocks 4 are arranged at intervals, mounting grooves are respectively formed in the centers of six sides of the regular hexagonal annular housing 1, a first magnet block 5 and a second magnet block 6 are mounted in the mounting grooves, the first magnet block 5 and the second magnet block 6 are arranged perpendicular to the side wall of the regular hexagonal annular housing 1, and the arrangement directions of the magnetic poles of the first magnet block 5 and the second magnet block 6 are arranged, the first magnet block 5 is arranged corresponding to the hemispherical clamping groove 3, the second magnet block 6 is arranged corresponding to the hemispherical clamping block 4, a corrosion and fog inhibitor filling groove 7 is formed in the outer side wall of the regular hexagonal annular shell 1 along the tangential direction of the side where the magnetic block is located, the six corrosion and fog inhibitor filling grooves 7 are distributed in an annular array mode by the geometric center of the regular hexagonal annular shell 1, a sealing protection layer 8 is arranged at the opening of the corrosion and fog inhibitor filling groove 7, the corrosion and fog inhibitor is filled in the corrosion and fog inhibitor filling groove 7, the regular hexagonal annular shell 1 integrally sinks to the bottom of acid liquor when the corrosion and fog inhibitor filling groove 7 is filled with corrosion and fog inhibitor components, and the regular hexagonal annular shell 1 integrally floats on the surface of the acid liquor when the corrosion and fog inhibitor filling groove 7 is not filled with the corrosion and fog inhibitor components.
Referring to fig. 3-6, when in use, a plurality of corrosion and fog inhibition filling rings are sequentially placed into the acid solution according to the placing amount, when in an initial state, the regular hexagonal annular shell 1 is integrally sunk to the bottom of the acid solution, the sealing protective layer 8 begins to decompose after contacting with the acid solution, the corrosion and fog inhibition components gradually seep out, the slow release of the corrosion and fog inhibition components is realized, the regular hexagonal annular shell 1 gradually floats upwards while the corrosion and fog inhibition components gradually seep out, the full contact between the corrosion and fog inhibition components and the acid solution is realized, and after the corrosion and fog inhibition components completely seep out, the regular hexagonal annular shell 1 floats upwards to the liquid level surface, due to the arrangement of the plurality of first magnet blocks 5 and the second magnet blocks 6, the magnetic attraction effect among each other is realized, the plurality of regular hexagonal annular shells 1 are adsorbed together, and due to the arrangement of the hemispherical clamping grooves 3 and the hemispherical clamping blocks 4, the clamping combination of the plurality of, the combination is more firm, sets up and to adsorb the greasy dirt that the pickling process produced at oil absorption fiber web 2, when a plurality of regular hexagon annular casings 1 were made up together, can form the not easy cracked greasy dirt isolated layer of one deck on the acidizing fluid surface to effectively restrain overflowing of acid mist.
Referring to fig. 1-2, the oil absorbing fiber web 2 is a net structure woven by oil absorbing fibers, and the oil absorbing fibers are chemically synthesized oil absorbing fibers, specifically, one of polypropylene, polyurethane, and alkyl ethylene polymer. Referring to fig. 6, the oil absorption fiber is woven into a net structure, so that the oil absorption effect is effectively improved, the strength of the oil isolation layer is reinforced, and the chemical synthesis oil absorption fiber is adopted, so that the oil absorption is concealed by utilizing the hydrophobic and oleophilic characteristics of the chemical synthesis oil absorption fiber and the gaps among polymer molecules, and the oil absorption device has the advantages of high oil absorption speed, high oil absorption rate, good overall performance, and convenience in use and recovery.
Referring to fig. 1-2, the sealing protective layer 8 is a sealing film or a sealing protective layer made of a material that decomposes in the presence of acid.
Referring to fig. 1-2, a positioning rod 9 is fixed inside the corrosion and fog inhibitor filling tank 7, the positioning rod 9 is disposed perpendicular to the bottom of the regular hexagonal annular housing 1, a plurality of acid-decomposing protective films 10 are fixed on the positioning rod 9, the acid-decomposing protective film 10 is a spherical film that is decomposed by acid, and the sodium bicarbonate reactant 11 is filled inside the acid-decomposing protective film 10. The acid-resistant decomposition protective film 10 is arranged inside the positioning rod 9, when the acid-resistant decomposition protective film 10 is decomposed by acid liquor, the sodium bicarbonate reactant 11 wrapped inside the sodium bicarbonate reactant is decomposed by acid, a large amount of carbon dioxide is generated, the carbon dioxide can apply acting force in the opposite direction to the regular hexagonal annular shell 1 when being discharged from the inside of the corrosion-resistant fog inhibitor filling groove 7, and the corrosion-resistant fog inhibitor filling grooves 7 are formed in six edges of the regular hexagonal annular shell 1, so that the acting force is applied to the six edges along the tangential direction of the six edges, the regular hexagonal annular shell 1 rotates inside the acid liquor, the full mixing of the corrosion-resistant fog inhibitor component and the acid liquor can be accelerated, the acid liquor does not need to be stirred when being added, stirring equipment is omitted, the acid washing efficiency is improved, and the use cost is reduced.
The above; but are merely preferred embodiments of the invention; the scope of the invention is not limited thereto; any person skilled in the art is within the technical scope of the present disclosure; the technical scheme and the improved concept of the invention are equally replaced or changed; are intended to be covered by the scope of the present invention.