CN112512487A - 毛发化妆品 - Google Patents
毛发化妆品 Download PDFInfo
- Publication number
- CN112512487A CN112512487A CN201980049409.3A CN201980049409A CN112512487A CN 112512487 A CN112512487 A CN 112512487A CN 201980049409 A CN201980049409 A CN 201980049409A CN 112512487 A CN112512487 A CN 112512487A
- Authority
- CN
- China
- Prior art keywords
- amount
- hair
- nonionic surfactant
- oil
- hair cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000004209 hair Anatomy 0.000 title claims abstract description 66
- 239000002537 cosmetic Substances 0.000 title claims abstract description 44
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 35
- 239000003921 oil Substances 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 229920000642 polymer Polymers 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000010696 ester oil Substances 0.000 claims abstract description 10
- 229920005862 polyol Polymers 0.000 claims abstract description 9
- 150000003077 polyols Chemical class 0.000 claims abstract description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 7
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 7
- -1 methacryloyloxyethyl Chemical group 0.000 claims description 31
- 229920001577 copolymer Polymers 0.000 claims description 18
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 238000005406 washing Methods 0.000 abstract description 9
- 210000001061 forehead Anatomy 0.000 abstract description 4
- 238000007665 sagging Methods 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 26
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 16
- 235000014113 dietary fatty acids Nutrition 0.000 description 14
- 239000000194 fatty acid Substances 0.000 description 14
- 229930195729 fatty acid Natural products 0.000 description 14
- 239000004359 castor oil Substances 0.000 description 10
- 235000019438 castor oil Nutrition 0.000 description 10
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 150000005215 alkyl ethers Chemical class 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 4
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 3
- 240000000912 Macadamia tetraphylla Species 0.000 description 3
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 description 3
- 239000010466 nut oil Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 235000013772 propylene glycol Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- NMGPHUOPSWFUEB-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCCNCCOC(=O)C(C)=C NMGPHUOPSWFUEB-UHFFFAOYSA-N 0.000 description 2
- AVBJHQDHVYGQLS-UHFFFAOYSA-N 2-(dodecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCC(=O)NC(C(O)=O)CCC(O)=O AVBJHQDHVYGQLS-UHFFFAOYSA-N 0.000 description 2
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 229920006322 acrylamide copolymer Polymers 0.000 description 2
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000003676 hair preparation Substances 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- WFXHUBZUIFLWCV-UHFFFAOYSA-N (2,2-dimethyl-3-octanoyloxypropyl) octanoate Chemical compound CCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCC WFXHUBZUIFLWCV-UHFFFAOYSA-N 0.000 description 1
- KFYRJJBUHYILSO-YFKPBYRVSA-N (2s)-2-amino-3-dimethylarsanylsulfanyl-3-methylbutanoic acid Chemical compound C[As](C)SC(C)(C)[C@@H](N)C(O)=O KFYRJJBUHYILSO-YFKPBYRVSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- WAYINTBTZWQNSN-UHFFFAOYSA-N 11-methyldodecyl 3,5,5-trimethylhexanoate Chemical compound CC(C)CCCCCCCCCCOC(=O)CC(C)CC(C)(C)C WAYINTBTZWQNSN-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- RKJGFHYCZPZJPE-UHFFFAOYSA-N 2,2-bis(16-methylheptadecanoyloxymethyl)butyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C RKJGFHYCZPZJPE-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 description 1
- NFIHXTUNNGIYRF-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)OC(=O)CCCCCCCCC NFIHXTUNNGIYRF-UHFFFAOYSA-N 0.000 description 1
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 1
- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- MXRGSJAOLKBZLU-UHFFFAOYSA-N 3-ethenylazepan-2-one Chemical compound C=CC1CCCCNC1=O MXRGSJAOLKBZLU-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 description 1
- BRORPGSJXSLXKN-UHFFFAOYSA-N 6-methylheptyl 3,5,5-trimethylhexanoate Chemical compound CC(C)CCCCCOC(=O)CC(C)CC(C)(C)C BRORPGSJXSLXKN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
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- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- LDDUCKDUDZVHLN-UHFFFAOYSA-N [2-hydroxy-3-[2-hydroxy-3-(16-methylheptadecanoyloxy)propoxy]propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COC(=O)CCCCCCCCCCCCCCC(C)C LDDUCKDUDZVHLN-UHFFFAOYSA-N 0.000 description 1
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- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- ZPWFUIUNWDIYCJ-UHFFFAOYSA-N propan-2-yl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(C)C ZPWFUIUNWDIYCJ-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明的目的在于,提供一种含有油分的膏脂状的毛发化妆品,其能够无额前头发的垂落地保持发型,并且冲洗性(洗发性)优异。本发明涉及一种毛发化妆品,其特征在于,含有:(A)(A‑1)HLB为1~6的非离子性表面活性剂及(A‑2)HLB为7~20的非离子性表面活性剂;(B)包含选自酯油及烃油中的至少1种的油剂;(C)多元醇;(D)聚合物;和(E)水,上述(A‑1)的配合量相对于(A‑2)的配合量的比率(A‑1)/(A‑2)为0.01~0.2的范围内。
Description
技术领域
本发明涉及毛发化妆品。更详细而言,本发明涉及一种组合具有特定范围的不同HLB(Hydrophile Lipophile Balance,亲水亲油平衡)值的2种以上的非离子性表面活性剂而配合的膏脂状的毛发化妆品。
背景技术
毛发整饰用化妆品中,尤其是作为重视整发性的头发造型剂(整发剂),已知有膏脂状的整发剂(称为毛发润滑脂或润发脂(pomade)者),操作性或对毛发的光泽赋予等性能优异。膏脂状整发剂呈现流动性低于凝胶状的整发剂的固体状或膏状,通常填充至罐容器等中,以手指取适量使用。
在膏脂状整发剂中存在使用液状油及固体油的油性类型、向水中配合多元醇、皮膜形成聚合物及增稠剂而成的水性类型。以往的油性膏脂状整发剂由于利用液状油分来压住毛发,光泽虽然优异,但有时因头发造型后的头部的动作等使额前头发垂落。
专利文献1中,指出在油性的膏脂状整发剂中存在油独特的粘腻感的问题,认为通过在不含油分的水性类型的膏脂状整发剂中,组合两种特定结构的聚氧乙烯烷基醚而进行配合,从而改善粘腻感的抑制、涂抹容易性、整发力、稳定性。
作为包含油分的化妆品,专利文献2中公开有一种含有非离子性表面活性剂、液状高级醇、液状油及水的凝胶状化妆品。认为该凝胶状化妆品具有适度的粘性,经时稳定性良好,作为整发剂、清洁料而对皮肤、毛发较温和。
然而,专利文献1中的两种聚氧乙烯烷基醚、专利文献2中记载的非离子性表面活性剂是HLB为10以上的亲水性表面活性剂,就粘腻感抑制、改善洗发性的方面而言不充分。
现有技术文献
专利文献
专利文献1:日本专利特开2017-186296号公报
专利文献2:日本专利特开2001-335425号公报
发明内容
发明要解决的问题
本发明是鉴于上述以往技术的缺点而成者,其目的在于,提供一种含有油分的膏脂状的毛发化妆品,其能够无额前头发的垂落地保持发型,并且冲洗性(洗发性)优异。
用于解决问题的方案
本发明人为了解决上述课题而反复进行努力研究,结果发现,通过制成组合具有低HLB值与高HLB的两种非离子性表面活性剂而使用,并且配合有聚合物的油性的膏脂状毛发化妆品,水溶合性良好,洗发性良好,也不易产生额前头发的垂落,从而完成本发明。
即,本发明提供一种毛发化妆品,其特征在于,含有:
(A)非离子性表面活性剂,其包含(A-1)HLB为1~6的非离子性表面活性剂及(A-2)HLB为7~20的非离子性表面活性剂;
(B)油剂,其包含选自酯油及烃油中的至少1种;
(C)多元醇;
(D)聚合物;和
(E)水,
上述(A-1)的配合量相对于(A-2)的配合量的比率(A-1)/(A-2)为0.01~0.2的范围内。
发明的效果
本发明的毛发化妆品由于组合HLB值不同的两种非离子性表面活性剂而进行配合,故而水溶合性良好,容易冲洗。另外,由于配合有聚合物,故而可长时间保持期望的发型,抑制额前头发的垂落。
具体实施方式
以下,对本发明的毛发化妆品详细地进行说明。
(A)非离子性表面活性剂
配合至本发明的毛发化妆品中的(A)非离子性表面活性剂包含(A-1)HLB为1~6的非离子性表面活性剂与(A-2)HLB为7~20的非离子性表面活性剂。
(A-1)HLB为1~6的非离子性表面活性剂是具有HLB为1~6、优选为2~6、更优选为3~5的相对亲油性的性质的表面活性剂,只要是化妆品等中所使用者,则并没有特别限定。
例如,可选自二异硬脂酸聚甘油-2酯、聚氧乙烯脂肪酸甘油酯、聚氧乙烯-甲基聚硅氧烷共聚物、失水山梨醇脂肪酸酯、聚氧乙烯失水山梨醇脂肪酸酯、聚氧乙烯烷基醚、聚二醇脂肪酸酯、烷醇二乙醇酰胺、脂肪酸异丙醇酰胺等。具体例包含自乳化型硬脂酸聚乙二醇酯(硬脂酸PG(SE))、油醇聚醚-2、PEG-5氢化蓖麻油、鲸蜡醇聚醚-2、硬脂醇聚醚-2、硬脂醇聚醚-3、三硬脂酸PEG-10甘油酯、异硬脂酸PEG-5氢化蓖麻油等。
(A-2)HLB为7~20的非离子性表面活性剂是具有HLB为7~20、优选为8~19、更优选为10~18的相对亲水性的性质的表面活性剂,只要是化妆品等中所使用者,则并没有特别限定。
例如,可选自甘油或聚甘油脂肪酸酯类、丙二醇脂肪酸酯类、POE失水山梨醇脂肪酸酯类、POE山梨醇脂肪酸酯类、POE甘油脂肪酸酯类、POE脂肪酸酯类、POE烷基醚类、POE烷基苯醚类、POE/POP烷基醚类、POE蓖麻油或氢化蓖麻油衍生物、POE蜂蜡/羊毛脂衍生物、烷醇酰胺类、POE丙二醇脂肪酸酯类、POE烷基胺、POE脂肪酰胺等。此处,“POE”是指,聚氧乙烯,“POP”是指,聚氧丙烯。具体例包含PEG-40氢化蓖麻油、PEG-50氢化蓖麻油、PEG-60氢化蓖麻油、琥珀酸PEG-50氢化蓖麻油等氢化蓖麻油衍生物、异硬脂酸PEG-60甘油酯、鲸蜡醇聚醚-25等。
本发明的毛发化妆品中的(A)非离子性表面活性剂的配合量优选设为15~45质量%,更优选为20~45质量%,进而优选为25~40质量%。
本发明中,上述(A-1)HLB为1~6的非离子性表面活性剂的配合量相对于(A-2)HLB为7~20的非离子性表面活性剂的配合量的比率(A-1)/(A-2)通过设为0.01~0.2的范围内,可发挥优异的洗发性等本发明的效果。在该比率(A-1)/(A-2)不足0.01的情况下,或在超过0.2的情况下,无法达成所需的定型力及洗发性。
(B)油剂
本发明的毛发化妆品含有(B)选自酯油及烃油中的至少1种油剂。本发明中的(B)油剂为在常温下液状的油(液状油),只要含有酯油或烃油中的任一种即可,可含有两者,两者中优选含有酯油。
作为酯油,并没有特别限定,例如可列举:2-乙基己酸鲸蜡酯、棕榈酸-2-乙基己酯、棕榈酸异丙酯、肉豆蔻酸异丙酯、硬脂酸异丙酯、硬脂酸异丁酯、硬脂酸-2-乙基己酯、异硬脂酸异丙酯、异硬脂酸丁酯、异硬脂酸癸酯、异硬脂酸月桂酯、异癸酸异癸酯、异壬酸异癸酯、异壬酸异十三烷基酯、异壬酸异壬酯、二辛酸新戊二醇酯、三-2-乙基己酸甘油酯、二癸酸丙二醇酯、辛酸/癸酸三甘油酯、三异硬脂酸三羟甲基丙烷、四-2-乙基己酸季戊四醇酯、二季戊四醇脂肪酸酯等。
作为烃油,例如可列举:矿物油、液体石蜡、角鲨烷、角鲨烯、凡士林、聚丁烯、聚异丁烯等。
作为除酯油及/或烃油以外可配合的其他液状油,可列举:小麦胚芽油、米胚芽油、白芒花籽油、迷迭香油、橄榄油、蓖麻油、霍霍巴油、澳洲坚果油、红花油等植物油;单异硬脂酸二甘油酯、二异硬脂酸二甘油酯、三异硬脂酸二甘油酯等脂肪酸二甘油酯;羊毛脂;甲基聚硅氧烷、甲基苯基聚硅氧烷等硅油、异硬脂醇等液状高级醇、N-月桂酰-L-谷氨酸二(胆甾醇/山萮基/辛基十二烷基)酯、12-羟基硬脂酸胆甾醇酯、澳洲坚果油脂肪酸胆甾醇酯等胆甾醇衍生物、N-月桂酰-L-谷氨酸二(植物甾醇/山萮基/辛基十二烷基)酯、澳洲坚果油脂肪酸植物甾醇酯等植物甾醇衍生物,但并不限定于这些。
本发明的毛发化妆品中的(B)油剂的配合量优选设为1~30质量%,更优选为3~25质量%,进而优选为5~20质量%。
另外,优选将(B)油剂的全部配合量中所占的酯油的配合量的比率设为50质量%以上,更优选为60质量%以上,进而优选为70质量%以上。
另外,本发明中,优选将上述(A)非离子性表面活性剂的配合量(即,包含(A-1)与(A-2)的非离子性表面活性剂的合计配合量)与上述(B)油剂的配合量的比率A/B设为2~5的范围内。若该比率不足2,则存在无法稳定地进行乳化的情况。
(C)多元醇
本发明中所使用的(C)多元醇只要是化妆品等中所使用者,则并没有特别限定。作为具体例,可例示:乙二醇、一缩二丙二醇、丙二醇、1,3-丁二醇、甘油、二甘油等2~4元醇、或山梨醇、甘露醇等5~6元醇。另外,可使用在多元醇上加成环氧烷而成的衍生物。
本发明的毛发化妆品中的(C)多元醇的配合量优选设为10~40质量%,更优选为13~35质量%,进而优选为15~30质量%。
另外,本发明中,优选将上述(A)非离子性表面活性剂的配合量(即,包含(A-1)与(A-2)的非离子性表面活性剂的合计配合量)与上述(C)多元醇的配合量的比率A/C设为1~3的范围内。若该比率超过3,则存在产生粘腻感而导致定型力的降低的情况。
(D)聚合物
配合至本发明的毛发化妆品中的(D)聚合物可选自由一直以来配合至毛发化妆品(整发剂)中的水溶性高分子或相当于皮膜形成剂的高分子树脂(也称为毛发定型用聚合物)。本发明中的“毛发定型用聚合物”例如可选自日本专利特开2011-140500号公报中所记载的毛发定型树脂。
本发明中优选使用的聚合物的具体例包含以下者。
作为非离子性(nonionic)聚合物,存在聚乙烯吡咯烷酮、乙烯基甲醚/马来酸烷基酯共聚物、乙烯基吡咯烷酮/甲基丙烯酰胺/乙烯基咪唑共聚物、聚乙烯基己内酰胺、(辛基丙烯酰胺/丙烯酸羟基丙酯/甲基丙烯酸丁基氨基乙酯)共聚物、(丙烯酸烷基酯/辛基丙烯酰胺)共聚物、(乙酸乙烯酯/巴豆酸/新癸酸乙烯酯)共聚物、(PVP/乙烯基己内酰胺/丙烯酸DMAPA)共聚物、(乙烯基吡咯烷酮/丙烯酸DMAPA)共聚物、(乙烯基吡咯烷酮/乙烯醇)共聚物[也记载为(VP/VA)共聚物]、聚丙烯酸酯交联聚合物-3、聚氨基甲酸酯-24、聚氨基甲酸酯-10葡聚糖等。
作为两性聚合物,可列举:(甲基丙烯酰氧乙基羧基甜菜碱/甲基丙烯酸烷基酯)共聚物、(丙烯酸(酯)类/丙烯酸月桂酯/丙烯酸硬脂酯/甲基丙烯酸乙基氧化胺)共聚物、(辛基丙烯酰胺/丙烯酸羟基丙酯/甲基丙烯酸丁基氨基乙酯)共聚物、(二甲基二烯丙基氯化铵/丙烯酸)共聚物、(二甲基二烯丙基氯化铵/丙烯酰胺/丙烯酸)共聚物等。
作为阴离子性(anionic)聚合物,可列举:丙烯酸烷基酯/二丙酮丙烯酰胺共聚物、丙烯酸烷基酯/辛基丙烯酰胺共聚物、乙酸乙烯酯/巴豆酸/新癸酸乙烯酯共聚物、丙烯酸/丙烯酰胺/丙烯酸乙酯共聚物等。
本发明中,尤其优选使用选自由(VP/VA)共聚物、聚丙烯酸酯交联聚合物-3及(甲基丙烯酰氧乙基羧基甜菜碱/甲基丙烯酸烷基酯)共聚物组成的组中的1种或2种以上。
本发明的毛发化妆品中的(D)聚合物的配合量优选设为0.5~5质量%,更优选为0.8~4质量%,进而优选为1~3质量%。
(E)水
配合至本发明的毛发化妆品中的水并没有特别限定,优选设为化妆品的20~40质量%,更优选为22~38质量%,进而优选为24~35质量%。
本发明中,优选将上述(A)表面活性剂的配合量(即,包含(A-1)与(A-2)的非离子性表面活性剂的合计配合量)与上述(E)水的配合量的比率A/E设为0.5~2的范围内。若该比率超过2,则有化妆品的操作性或定型力降低的倾向。
本发明的毛发化妆品中,除上述必须成分(A)~(E)以外,可在不有损本发明的效果的范围内适当配合整发剂等毛发化妆品中通常配合的其他任意成分。作为其他任意成分,可列举:在常温下为固体的高级醇(山萮醇等)、碳数6以下的低级醇(乙醇等)、粉末、保湿剂((C)多元醇除外)、分散剂、防腐剂、抗氧化剂、各种药剂、紫外线吸收剂、增稠剂、香料等。
本发明的毛发化妆品可依据自一直以来用于膏脂状化妆品的制造方法而制造。
本发明的毛发化妆品可尤其适宜地用作膏脂或润发脂等剂型的整发剂(头发造型剂),另外,也可用作梳理眉毛或胡须流的制剂。
以下列举实施例,对本发明更详细地进行说明,但本发明并不因此受到任何限定。需要说明的是,配合量只要未特别记载,则以质量%表示。
实施例
以下述表1~3中所公开的组成制备毛发化妆品,并实施对于各例的化妆品的实际使用试验。试验方法是由专业官能检查员5名使用各例的化妆品,对基于下述评价分数基准进行的各人的评价分数进行合计,并基于下述基准对合计分进行评价。评价项目设为“涂展容易性”、“剂的取用容易性”、“无粘腻感”、“定型力”、“光泽感”及“洗发性”。
(评价分数基准)
5分:非常优异。
4分:优异。
3分:普通。
2分:较差。
1分:非常差。
(评价基准)
a*:合计分为20分以上。
a:合计分为15分以上且不足20分。
b:合计分为10分以上且不足15分。
c:合计分不足10分。
另一方面,通过目测观察各例的化妆品的状态,如下所述那样对其结果进行评价。
a:为相当透明的状态。
b:为透明的状态(略微混浊)。
c:已乳化(不透明)、或者未乳化而进行了分离。
[表1]
[表2]
[表3]
表1~表3的脚注:
*1:NIKKOL PMS-SE(Nikko Chemicals公司制造)
*2:Emalex 502(Nihon Emulsion公司制造)
*3:NIKKOL HCO-5(Nikko Chemicals公司制造)
*4:NIKKOL HCO-40(Nikko Chemicals公司制造)
*5:COSMOL 50(Nikko Chemicals公司制造)
*6:NIKKOL HCO-50(Nikko Chemicals公司制造)
*7:NIKKOL HCO-60(Nikko Chemicals公司制造)
*8:Emalex 125(Nihon Emulsion公司制造)
*9:Emalex GWIS-160(Nihon Emulsion公司制造)
*10:NIKKOL CIO(Nikko Chemicals公司制造)
*11:NIKKOL IPM(Nikko Chemicals公司制造)
如表1所示,作为本发明的毛发化妆品的实施例1~5在评价的所有特性方面均可充分地令人满意。与此相对,未配合(A-1)HLB为1~6的非离子性表面活性剂的比较例1略微产生粘腻感,洗发性也降低。另外,HLB不同的表面活性剂的配合量比率(A-1)/(A-2)超过0.2的比较例2的粘腻感及洗发性进而恶化。另外,未配合油剂的比较例3无法乳化而进行分离(表2)。
表3所示的结果中,配合量的比率A/B成为不足2的比较例5及6、配合量的比率A/C超过3的比较例5及7、配合量的比率A/E超过2的比较例4显示在所评价的任一种特性方面均超出使用上可容许的范围而降低。
Claims (7)
1.一种毛发化妆品,其特征在于,含有:
(A)非离子性表面活性剂,其包含(A-1)HLB为1~6的非离子性表面活性剂及(A-2)HLB为7~20的非离子性表面活性剂;
(B)油剂,其包含选自酯油及烃油中的至少1种;
(C)多元醇;
(D)聚合物;和
(E)水,
所述(A-1)的配合量相对于(A-2)的配合量的比率(A-1)/(A-2)为0.01~0.2的范围内。
2.根据权利要求1所述的毛发化妆品,其中,所述(A)非离子性表面活性剂的配合量((A-1)与(A-2)的合计配合量)与所述(B)油剂的配合量的比率A/B为2~5的范围内。
3.根据权利要求1或2所述的毛发化妆品,其中,所述(A)非离子性表面活性剂的配合量((A-1)与(A-2)的合计配合量)与所述(C)多元醇的配合量的比率A/C为1~3的范围内。
4.根据权利要求1至3中任一项所述的毛发化妆品,其中,所述(A)非离子性表面活性剂的配合量((A-1)与(A-2)的合计配合量)与所述(E)水的配合量的比率A/E为0.5~2的范围内。
5.根据权利要求1至4中任一项所述的毛发化妆品,其中,所述(B)油剂为酯油。
6.根据权利要求1至5中任一项所述的毛发化妆品,其中,所述(D)聚合物为毛发定型用聚合物。
7.根据权利要求6所述的毛发化妆品,其中,所述(D)聚合物为选自由(VP/VA)共聚物、聚丙烯酸酯交联聚合物-3及(甲基丙烯酰氧乙基羧基甜菜碱/甲基丙烯酸烷基酯)共聚物组成的组中的至少1种。
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