CN112480999A - 一种多功能导轨油 - Google Patents
一种多功能导轨油 Download PDFInfo
- Publication number
- CN112480999A CN112480999A CN202011357609.6A CN202011357609A CN112480999A CN 112480999 A CN112480999 A CN 112480999A CN 202011357609 A CN202011357609 A CN 202011357609A CN 112480999 A CN112480999 A CN 112480999A
- Authority
- CN
- China
- Prior art keywords
- oil
- parts
- multifunctional
- polyether polyol
- rail oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003921 oil Substances 0.000 claims abstract description 96
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 90
- 229920000570 polyether Polymers 0.000 claims abstract description 90
- 229920005862 polyol Polymers 0.000 claims abstract description 59
- 150000003077 polyols Chemical class 0.000 claims abstract description 59
- 239000002199 base oil Substances 0.000 claims abstract description 31
- 239000002994 raw material Substances 0.000 claims abstract description 28
- 238000005260 corrosion Methods 0.000 claims abstract description 21
- 230000007797 corrosion Effects 0.000 claims abstract description 21
- 239000003112 inhibitor Substances 0.000 claims abstract description 20
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 19
- 239000003899 bactericide agent Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
- -1 CWT-03 Substances 0.000 claims description 11
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 8
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 7
- 239000012964 benzotriazole Substances 0.000 claims description 7
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 6
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 6
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 6
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- NNRAOBUKHNZQFX-UHFFFAOYSA-N 2H-benzotriazole-4-thiol Chemical compound SC1=CC=CC2=C1NN=N2 NNRAOBUKHNZQFX-UHFFFAOYSA-N 0.000 claims description 3
- LXKCHCXZBPLTAE-UHFFFAOYSA-N 3,4-dimethyl-1H-pyrazole phosphate Chemical compound OP(O)(O)=O.CC1=CNN=C1C LXKCHCXZBPLTAE-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 235000010265 sodium sulphite Nutrition 0.000 claims description 3
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 claims description 2
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical group C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical group C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000003367 polycyclic group Chemical group 0.000 claims description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
- 235000010234 sodium benzoate Nutrition 0.000 claims description 2
- 239000004299 sodium benzoate Substances 0.000 claims description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims 1
- 125000005609 naphthenate group Chemical group 0.000 claims 1
- 239000003002 pH adjusting agent Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 1
- 239000010730 cutting oil Substances 0.000 abstract description 5
- 238000005299 abrasion Methods 0.000 abstract description 4
- 239000000654 additive Substances 0.000 abstract description 4
- 238000004945 emulsification Methods 0.000 abstract description 4
- 125000002947 alkylene group Chemical group 0.000 description 26
- 239000003999 initiator Substances 0.000 description 26
- 239000003054 catalyst Substances 0.000 description 14
- 230000032683 aging Effects 0.000 description 13
- 230000000903 blocking effect Effects 0.000 description 13
- 239000003153 chemical reaction reagent Substances 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 13
- 239000002808 molecular sieve Substances 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 13
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 13
- 238000003756 stirring Methods 0.000 description 13
- 238000005303 weighing Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 238000005520 cutting process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- ZBHSAYWIYAVUOP-UHFFFAOYSA-N 2-(benzylamino)-1-[3-(trifluoromethyl)phenyl]ethanol Chemical group C=1C=CC(C(F)(F)F)=CC=1C(O)CNCC1=CC=CC=C1 ZBHSAYWIYAVUOP-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002173 cutting fluid Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/32—Heterocyclic sulfur, selenium or tellurium compounds
- C10M135/34—Heterocyclic sulfur, selenium or tellurium compounds the ring containing sulfur and carbon only
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- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/12—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/12—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M149/14—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds a condensation reaction being involved
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C10M173/00—Lubricating compositions containing more than 10% water
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
- C10M2215/226—Morpholines
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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Abstract
本发明公开了一种多功能导轨油，导轨油包括以下重量份数的原料：所述基础油40～60份、pH调节剂4～14份、聚醚多元醇衍生物5‑10份、缓蚀剂0.5～3.5份、杀菌剂1～5份、水2～10份。本发明的多功能导轨油同时能起到极压抗磨、减磨、抗乳化和消泡的功能，消除了传统导轨油和切削油由于添加剂不同而导致不能混用问题。
Description
技术领域
本发明属于化工技术领域，涉及一种导轨油，尤其涉及一种多功能导轨油。
背景技术
一般而言，导轨油主要应用于加工机床的导轨，要求具有良好的抗磨性和粘附性。在使用过程中，由于机床的往复切割而容易与切削油混合，形成污染，从而导致导轨油与切削油的功能失效，产生增加成本、降低生产效率等问题。
发明内容
本发明要解决的技术问题在于，针对现有技术的缺陷，提供一种同时能起到极压抗磨、减磨、抗乳化和消泡的功能，消除了传统导轨油和切削油由于添加剂不同而导致不能混用问题的多功能导轨油。
本发明解决其技术问题所采用的技术方案是：
一种多功能导轨油，其特征在于，包括以下重量份数的原料：
基础油 40～60
pH调节剂 4～14
聚醚多元醇衍生物 5～10
缓蚀剂 0.1～3.5
杀菌剂 1～5
水 2～10；
所述基础油为白油与油溶性聚醚的混合物、白油与2cSt的混合物或白油与4cSt的混合物；
所述聚醚多元醇衍生物的结构为
其中，R1为C1～C20的烷烃；R2为C1～C10的烷烃；R3为含氯化合物、含硫化合物或含磷化合物中的任意一种；n为1～100。
所述的多功能导轨油中，优选R1为C1～C9的烷烃；R2为C1～C3的烷烃。
所述的多功能导轨油中，优选白油在40摄氏度的温度下的运动粘度为23-32mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为23-32mm2/s。
所述的多功能导轨油中，优选所述pH调节剂为乙醇胺、二乙醇胺、三乙醇胺、AMP-95、CWT-03、氢氧化钾、氢氧化钠、吗啉、N-甲基吗啉、吡啶或碳酸钠。
所述的多功能导轨油中，优选所述缓蚀剂为苯骈三氮唑及其衍生物、甲基苯并三氮唑及其衍生物、巯基苯并三氮唑及其衍生物、烷基磷酸酯缓蚀剂、烷基磺酸盐、烷基琥珀酸盐、烷基羟乙基咪唑啉、羟基乙叉二膦酸、3,4-二甲基吡唑磷酸盐、亚硫酸钠、苯甲酸钠、环烷酸咪唑啉季铵盐、壬基酚聚氧乙烯醚中的一种或其复配物。
所述的多功能导轨油中，优选所述杀菌剂为MBM、BIT、BK、IPBC、893MW、LD14中的一种或其复配物。
所述的多功能导轨油中，优选所述含硫化合物为
其中R为噻唑或苯并噻唑类基团；或
其中R'为芳基基团。
所述的多功能导轨油中，优选所述含氯化合物为
其中Cl在苯环或多环上的任意取代位。
所述的多功能导轨油中，优选所述含磷化合物为
其中R4为苯或多芳环基团，R5为C1～C20烷基链、苯、多芳环基团。
一种聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃40-70份、起始剂40-50份，封端基团40-70份、4A分子筛催化剂，催化剂加入量为制得产物的20～40ppm(质量比)；
B、将环氧烷烃加入到反应釜中，保持温度50-60℃温度下，以0.1～2mL/分钟的速率加入起始剂，添加完成后继续搅拌20-60min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至60-100℃，老化0.5～3小时，得到聚醚多元醇衍生物。
本发明采用油溶性聚醚作为基础油的主要成分，聚醚多元醇衍生物作为主添加剂具有三方面优势：一、聚醚多元醇衍生物起到极压抗磨、减磨、抗乳化和消泡的功能，消除了传统产品中需要单独添加抗磨剂、减磨剂、抗乳化机以及消泡剂，降低了产品成本，提高了调和效率；二、油溶性聚醚与聚醚衍生物的结构相似，具有很好的相容性，不存在其他产品中会出现的分层、浑浊等现象；三、本发明产品既可以用于导轨润滑，又可以用于金属切割，消除了传统导轨油和切削油由于添加剂不同而导致不能混用的问题，减少油品污染带来的损失。还可以节约成本、提高生产效率。
具体实施方式
为了对本发明的技术特征、目的和效果有更加清楚的理解，现详细说明本发明的具体实施方式。
实施例1一种多功能导轨油，包括以下重量份数的原料：
所述基础油50份、pH调节剂乙醇胺4份、聚醚多元醇衍生物5份、缓蚀剂苯骈三氮唑0.5份、杀菌剂MBM 5份、水2份。
基础油为白油与油溶性聚醚的混合物；其中选择工业白油30份，油溶性聚醚20份，白油在40摄氏度的温度下的运动粘度为26.2mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为25.0mm2/s。
聚醚多元醇衍生物
中，R1为CH2CH3；R2为CH3；R3为
n为5。
多功能导轨油制备方法与现有导轨油制备方法基本相同。以下实施例不再赘述。
具体为：将基础油50份、pH调节剂乙醇胺4份、聚醚多元醇衍生物5份、缓蚀剂苯骈三氮唑0.5份、杀菌剂MBM 5份、水2份混合搅拌均匀，即得多功能导轨油。
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃40份、起始剂40份，封端基团40份、4A分子筛催化剂0.0024份；
B、将环氧烷烃加入到反应釜中，保持温度50℃温度下，以0.1mL/分钟的速率加入起始剂，添加完成后继续搅拌20min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至60℃，老化0.5小时，得到聚醚多元醇衍生物。
实施例2、一种多功能导轨油，包括以下重量份数的原料：
所述基础油50份、pH调节剂二乙醇胺2份、聚醚多元醇衍生物7份、烷基磷酸酯缓蚀剂3.5份、杀菌剂MBM 4份、水2份。
基础油为白油与油溶性聚醚的混合物；其中选择工业白油30份，油溶性聚醚20份，白油在40摄氏度的温度下的运动粘度为25.2mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为27.0mm2/s。
聚醚多元醇衍生物
中，R1为
R2为CH2CH3；R3为
n为20；
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃70份、起始剂50份，封端基团70份、4A分子筛催化剂0.0076份；
B、将环氧烷烃加入到反应釜中，保持温度60℃温度下，以2mL/分钟的速率加入起始剂，添加完成后继续搅拌60min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至100℃，老化3小时，得到聚醚多元醇衍生物。
实施例3、一种多功能导轨油，包括以下重量份数的原料：
所述基础油50份、pH调节剂AMP-95 4份、聚醚多元醇衍生物10份、缓蚀剂甲基苯并三氮唑衍生物1.5份、杀菌剂IPBC 5份、水10份。
基础油为白油与油溶性聚醚的混合物；其中选择工业白油30份，油溶性聚醚20份，白油在40摄氏度的温度下的运动粘度为26.6mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为30.0mm2/s。
聚醚多元醇衍生物
中，R1为
R2为CH2CH3；R3为
n为50。
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃50份、起始剂50份，封端基团50份、4A分子筛催化剂0.0045份；
B、将环氧烷烃加入到反应釜中，保持温度55℃温度下，以1mL/分钟的速率加入起始剂，添加完成后继续搅拌30min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至70℃，老化2.5小时，得到聚醚多元醇衍生物。
实施例4、一种多功能导轨油，包括以下重量份数的原料：
所述基础油50份、pH调节剂(乙醇胺2份、二乙醇胺1份)、聚醚多元醇衍生物10份、缓蚀剂1.5份(苯骈三氮唑：甲基苯并三氮唑衍生物质量比为2:1)、杀菌剂BIT 4份、水8.5份。
基础油为白油与油溶性聚醚的混合物；其中选择工业白油30份，油溶性聚醚20份，白油在40摄氏度的温度下的运动粘度为26.4mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为27.1mm2/s。
聚醚多元醇衍生物
中，R1为
R2为CH2CH3；R3为
n为100。
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃55份、起始剂50份，封端基团55份、4A分子筛催化剂0.0048份；
B、将环氧烷烃加入到反应釜中，保持温度55℃温度下，以0.5mL/分钟的速率加入起始剂，添加完成后继续搅拌40min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至70℃，老化2.3小时，得到聚醚多元醇衍生物。
实施例5、一种多功能导轨油，包括以下重量份数的原料：
所述基础油50份、pH调节剂二乙醇胺3.5份、聚醚多元醇衍生物10份、缓蚀剂1.5份(苯骈三氮唑：甲基苯并三氮唑衍生物质量比为2:1)、杀菌剂BIT 2份、水8.5份。
基础油为白油与油溶性聚醚的混合物；其中选择工业白油30份，油溶性聚醚20份，白油在40摄氏度的温度下的运动粘度为27.2mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为29.6mm2/s。
聚醚多元醇衍生物
中，R1为
R2为CH3；R3为
n为80。
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃45份、起始剂45份，封端基团45份、4A分子筛催化剂0.0027份；
B、将环氧烷烃加入到反应釜中，保持温度60℃温度下，以1.5mL/分钟的速率加入起始剂，添加完成后继续搅拌30min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至60℃，老化3小时，得到聚醚多元醇衍生物。
实施例6、一种多功能导轨油，包括以下重量份数的原料：
所述基础油50份、pH调节剂二乙醇胺1.5份、聚醚多元醇衍生物10份、缓蚀剂1.5份(苯骈三氮唑：甲基苯并三氮唑衍生物质量比为2:1)、杀菌剂BIT 3份、水6份。
基础油为白油与油溶性聚醚的混合物；其中选择工业白油30份，油溶性聚醚20份，白油在40摄氏度的温度下的运动粘度为26.4mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为27.1mm2/s。
聚醚多元醇衍生物
中，R1为
R2为CH2CH(CH3)CH3；R3为
n为100。
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃40份、起始剂40份，封端基团40份、4A分子筛催化剂0.0048份；
B、将环氧烷烃加入到反应釜中，保持温度70℃温度下，以1mL/分钟的速率加入起始剂，添加完成后继续搅拌40min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至50℃，老化2.5小时，得到聚醚多元醇衍生物。
实施例7、一种多功能导轨油，包括以下重量份数的原料：
所述基础油60份、pH调节剂氢氧化钾14份、聚醚多元醇衍生物6份、缓蚀剂3,4-二甲基吡唑磷酸盐3.5份、杀菌剂LD14 3份、水5份。
基础油为白油与2cSt的混合物；其中选择工业白油40份，2cSt 20份，白油在40摄氏度的温度下的运动粘度为26.4mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为7.4mm2/s。
聚醚多元醇衍生物
中，R1为
R2为CH3；R3为
n为20。
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃55份、起始剂50份，封端基团55份、4A分子筛催化剂0.0048份；
B、将环氧烷烃加入到反应釜中，保持温度60℃温度下，以1.1mL/分钟的速率加入起始剂，添加完成后继续搅拌50min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至65℃，老化2.3小时，得到聚醚多元醇衍生物。
实施例8、一种多功能导轨油，包括以下重量份数的原料：
所述基础油40份、pH调节剂吗啉10份、聚醚多元醇衍生物10份、缓蚀剂巯基苯并三氮唑0.2份、杀菌剂893MW 2.5份、水8份。
基础油为白油与4cSt的混合物；其中选择工业白油30份，4cSt 10份，白油在40摄氏度的温度下的运动粘度为26.4mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为19.3mm2/s。
聚醚多元醇衍生物
中，R1为
R2为CH2(CH2)6CH(CH3)2；R3为
n为40。
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃50份、起始剂50份，封端基团50份、4A分子筛催化剂0.0082份；
B、将环氧烷烃加入到反应釜中，保持温度60℃温度下，以1.6mL/分钟的速率加入起始剂，添加完成后继续搅拌55min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至70℃，老化1.6小时，得到聚醚多元醇衍生物。
实施例9、一种多功能导轨油，包括以下重量份数的原料：
所述基础油40份、pH调节剂N-甲基吗啉11份、聚醚多元醇衍生物7份、缓蚀剂亚硫酸钠3.2份、杀菌剂893MW 2.7份、水6份。
基础油为白油与4cSt的混合物；其中选择工业白油25份，4cSt 15份，白油在40摄氏度的温度下的运动粘度为26.4mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为19.3mm2/s。
聚醚多元醇衍生物
中，R1为
R2为C(CH3)2CH2CH2CH2CH3；
R3为
n为82。
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃60份、起始剂50份，封端基团60份、4A分子筛催化剂0.0034份；
B、将环氧烷烃加入到反应釜中，保持温度80℃温度下，以0.9mL/分钟的速率加入起始剂，添加完成后继续搅拌30min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至70℃，老化3小时，得到聚醚多元醇衍生物。
实施例10、一种多功能导轨油，包括以下重量份数的原料：
所述基础油45份、pH调节剂碳酸钠13份、聚醚多元醇衍生物5份、缓蚀剂环烷酸咪唑啉季铵盐2.9份、杀菌剂IPBC 3份、水2份。
基础油为白油与4cSt的混合物；其中选择工业白油40份，4cSt 5份，白油在40摄氏度的温度下的运动粘度为26.4mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为19.3mm2/s。
聚醚多元醇衍生物
中，R1为
R2为CH2CH(CH3)2；
R3为
n为65。
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃45份、起始剂45份，封端基团45份、4A分子筛催化剂0.0045份；
B、将环氧烷烃加入到反应釜中，保持温度55℃温度下，以2mL/分钟的速率加入起始剂，添加完成后继续搅拌30min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至60℃，老化2.5小时，得到聚醚多元醇衍生物。
实施例11、一种多功能导轨油，包括以下重量份数的原料：
所述基础油50份、pH调节剂吡啶7份、聚醚多元醇衍生物7份、缓蚀剂烷基羟乙基咪唑啉2.6份、杀菌剂IPBC 3份、水6份。
基础油为白油与4cSt的混合物；其中选择工业白油35份，4cSt 15份，白油在40摄氏度的温度下的运动粘度为26.4mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为19.3mm2/s。
聚醚多元醇衍生物
中，R1为
R2为CH2CH3；R3为
n为34。
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃55份、起始剂50份，封端基团55份、4A分子筛催化剂0.0039份；
B、将环氧烷烃加入到反应釜中，保持温度70℃温度下，以2mL/分钟的速率加入起始剂，添加完成后继续搅拌50min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至65℃，老化1小时，得到聚醚多元醇衍生物。
实施例12、一种多功能导轨油，包括以下重量份数的原料：
所述基础油60份、pH调节剂CWT-03 12份、聚醚多元醇衍生物8份、缓蚀剂壬基酚聚氧乙烯醚3.4份、杀菌剂BK 4份、水8份。
基础油为白油与4cSt的混合物；其中选择工业白油35份，4cSt 25份，白油在40摄氏度的温度下的运动粘度为26.4mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为19.3mm2/s。
聚醚多元醇衍生物
中，R1为
R2为CH2(CH2)5CH3；R3为
n为73。
本实施例的聚醚多元醇衍生物的制备方法，包括以下步骤：
A、称取原料：环氧烷烃60份、起始剂50份，封端基团60份、4A分子筛催化剂0.0068份；
B、将环氧烷烃加入到反应釜中，保持温度40℃温度下，以0.6mL/分钟的速率加入起始剂，添加完成后继续搅拌60min；
C、待压力达到常压时，将封端试剂添加到反应釜中，升温至88℃，老化1.5小时，得到聚醚多元醇衍生物。
对比实验：
对比例1：
水溶性切削液：市售某著名品牌水溶液；
对比例2：
导轨油：市售某著名品牌ISO VG 68#导轨油；
将实施例1-12、对比例1、对比例2加水配制成5％稀释液，性能如表1、表2所示。
表1实施例与对比例应用效果对比(切削性能)
从表1可以看出：相比于对比例，实施例产品对铜片、铝片、铁片和T3铜片具有优异的防腐蚀性能，具有较高的PB值，摩擦系数优异，磨斑直径较小，说明了本发明产品中的聚醚多元醇衍生物发挥了作用。
在导轨油的应用方面，本实施例产品与对比产品的性能进行比较，结果发现，本发明实施例产品与对比例产品在相同的加工时间内，没有发现有表面浮油，经过培养后的菌落数较低，且机台工作表面清洁，体现出本发明产品的抗菌性好、溶解性强以及易于清洁等特点。
表2实施例与对比例应用效果对比(导轨性能)
Claims (9)
1.一种多功能导轨油，其特征在于，包括以下重量份数的原料：
基础油40～60
pH调节剂4～14
聚醚多元醇衍生物5～10
缓蚀剂0.1～3.5
杀菌剂1～5
水2～10；
所述基础油为白油与油溶性聚醚的混合物、白油与2cSt的混合物或白油与4cSt的混合物；
所述聚醚多元醇衍生物的结构为
其中，R1为C1～C20的烷烃；R2为C1～C10的烷烃；R3为含氯化合物、含硫化合物或含磷化合物中的任意一种；n为1～100。
2.根据权利要求1所述的多功能导轨油，其特征在于，R1为C1～C9的烷烃；R2为C1～C3的烷烃。
3.根据权利要求1所述的多功能导轨油，其特征在于，白油在40摄氏度的温度下的运动粘度为23-32mm2/s；油溶性聚醚在40摄氏度的温度下的运动粘度为23-32mm2/s。
4.根据权利要求1所述的多功能导轨油，其特征在于，所述pH调节剂为乙醇胺、二乙醇胺、三乙醇胺、AMP-95、CWT-03、氢氧化钾、氢氧化钠、吗啉、N-甲基吗啉、吡啶或碳酸钠。
5.根据权利要求1所述的多功能导轨油，其特征在于，所述缓蚀剂为苯骈三氮唑及其衍生物、甲基苯并三氮唑及其衍生物、巯基苯并三氮唑及其衍生物烷基、磷酸酯缓蚀剂、烷基磺酸盐、烷基琥珀酸盐、烷基羟乙基咪唑啉、羟基乙叉二膦酸、3,4-二甲基吡唑磷酸盐、亚硫酸钠、苯甲酸钠、环烷酸咪唑啉季铵盐、壬基酚聚氧乙烯醚中的一种或其复配物。
6.根据权利要求1所述的多功能导轨油，其特征在于，所述杀菌剂为MBM、BIT、BK、IPBC、893MW、LD14中的一种或其复配物。
7.根据权利要求1所述的多功能导轨油，其特征在于，所述含硫化合物为
其中R为噻唑或苯并噻唑类基团；或
其中R'为芳基基团。
8.根据权利要求1所述的多功能导轨油，其特征在于，所述含氯化合物为
其中Cl在苯环或多环上的任意取代位。
9.根据权利要求1所述的多功能导轨油，其特征在于，所述含磷化合物为
其中R4为苯或多芳环基团，R5为C1～C20烷基链、苯、多芳环基团。
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|---|---|---|---|---|
| US3211651A (en) * | 1960-12-19 | 1965-10-12 | Castrol Ltd | Lubricating compositions containing polyether derivatives |
| US5143640A (en) * | 1988-07-21 | 1992-09-01 | Bp Chemicals Limited | Polyether lubricants |
| US5652204A (en) * | 1991-12-24 | 1997-07-29 | Oecanfloor Limited | Lubricating oil compositions containing specified end-capped polyethers |
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| US3211651A (en) * | 1960-12-19 | 1965-10-12 | Castrol Ltd | Lubricating compositions containing polyether derivatives |
| US5143640A (en) * | 1988-07-21 | 1992-09-01 | Bp Chemicals Limited | Polyether lubricants |
| US5652204A (en) * | 1991-12-24 | 1997-07-29 | Oecanfloor Limited | Lubricating oil compositions containing specified end-capped polyethers |
| US20100120639A1 (en) * | 2007-04-25 | 2010-05-13 | Thoen Johan A | Lubricant blend composition |
| WO2011071492A1 (en) * | 2009-12-09 | 2011-06-16 | Dow Global Technologies Llc | Polyether derivatives of secondary hydroxy fatty acids and derivatives thereof |
| US20130204047A1 (en) * | 2010-03-13 | 2013-08-08 | Bayer Intellectual Property Gmbh | Method for producing polyther polyols |
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