CN112321850A - Hydrogel bait and preparation method thereof - Google Patents
Hydrogel bait and preparation method thereof Download PDFInfo
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- CN112321850A CN112321850A CN202011082358.5A CN202011082358A CN112321850A CN 112321850 A CN112321850 A CN 112321850A CN 202011082358 A CN202011082358 A CN 202011082358A CN 112321850 A CN112321850 A CN 112321850A
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- 238000002360 preparation method Methods 0.000 title abstract description 7
- 241000251468 Actinopterygii Species 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 13
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 claims abstract description 12
- 102000002322 Egg Proteins Human genes 0.000 claims abstract description 12
- 108010000912 Egg Proteins Proteins 0.000 claims abstract description 12
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 12
- 235000014103 egg white Nutrition 0.000 claims abstract description 12
- 210000000969 egg white Anatomy 0.000 claims abstract description 12
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 12
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- 240000004922 Vigna radiata Species 0.000 claims abstract description 10
- 235000010721 Vigna radiata var radiata Nutrition 0.000 claims abstract description 10
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- 150000001768 cations Chemical class 0.000 claims abstract description 7
- 239000003755 preservative agent Substances 0.000 claims abstract description 7
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- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 150000001450 anions Chemical class 0.000 claims abstract description 5
- UKHXPHLUQGMQOF-UHFFFAOYSA-N 2-carboxyethyl(dimethyl)sulfanium;bromide Chemical group [Br-].C[S+](C)CCC(O)=O UKHXPHLUQGMQOF-UHFFFAOYSA-N 0.000 claims description 24
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 16
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 16
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical group CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 13
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- 239000000661 sodium alginate Substances 0.000 claims description 13
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical group [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 6
- 229920006318 anionic polymer Polymers 0.000 claims description 6
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- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
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- 235000012141 vanillin Nutrition 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/075—Macromolecular gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K85/00—Artificial bait for fishing
- A01K85/01—Artificial bait for fishing with light emission, sound emission, scent dispersal or the like
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2403/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
- C08J2403/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2405/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2401/00 or C08J2403/00
- C08J2405/04—Alginic acid; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2489/00—Characterised by the use of proteins; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Environmental Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Marine Sciences & Fisheries (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Health & Medical Sciences (AREA)
- Fodder In General (AREA)
Abstract
The invention discloses a hydrogel bait and a preparation method thereof, wherein the hydrogel bait is prepared from 5-8% of polyvinyl alcohol; 0.85-1.5% of egg white powder; 1.5 to 3 percent of anion high polymer; 0.5 to 1 percent of cation fish luring agent; 0.2 to 0.5 percent of preservative; 0.5-1% of mung bean starch; 88-95% deionized water. According to the invention, the anion high polymer, the polyvinyl alcohol, the egg white powder, the cation fish luring agent, the preservative and the mung bean starch are mixed to prepare the hydrogel bait, the anion high polymer is combined with the cation fish luring agent, the polyvinyl alcohol can form hydrogen bonds with carbonyl of the egg white powder through hydroxyl groups to prepare the bait with the fish luring agent close to the first-order release rate, and the xerogel expands in volume after absorbing water to release the loaded fish luring agent, so that the effect of effective and continuous release can be achieved.
Description
Technical Field
The invention relates to hydrogel bait and a preparation method thereof.
Background
The bait, i.e., food eaten by fish, is food for attracting fish to get up during fishing, and further is all usable substances capable of gathering fish or attracting fish to get up during fishing. Li Meng Jie uses corn stalk, mica powder and active carbon as bionic bait filler, which is environment-friendly and degradable, avoids the pollution to water quality, then carries out hydroxylation treatment on the bionic bait filler, and then carries out esterification reaction with acrylic acid, thus achieving the purpose of grafting acrylic acid on the surface of the bionic bait filler, and improving the problems of weak acting force and poor interface binding force of the traditional bionic bait filler and a substrate. The main material of the bait of the invention has natural and pure cereal fragrance, vanillin is added, the olfactory organ of fish can be stimulated, and the bait has rich animal and plant protein and amino acid, and food attractant component is added, so that the taste of the bait is improved, the fish can be promoted to eat first, and the fish can be bitten. (Yangbang-a fragrant bait and its preparation method: China 201810907456.4[ P ].2020-02-21.)
However, the bait of the invention can not continuously lure fish, and the bait with the approximate first-order release rate can be prepared by mixing anionic high polymer, polyvinyl alcohol, egg white powder, cationic fish luring agent (2-carboxyethyl) dimethyl sulfonium bromide, preservative and mung bean starch. The hydrogel is a gel in which water is used as a dispersion medium. Hydrogels are excellent vehicles because hydrogels do not readily dissolve; has water swelling property, and the swelling process is the drug release process. The anionic polymer is sodium alginate and sodium polyacrylate. The (2-carboxyethyl) dimethyl sulfonium bromide can receive stimulation of low-concentration chemical substances in a water body through the smell of aquatic animals, can distinguish the chemical substances, is extremely sensitive, and can increase the contact area between the (2-carboxyethyl) dimethyl sulfonium bromide and an external water environment through folds in the smell speak in a low voice so as to improve the sensitivity of the smell. Therefore, the fish, the shrimp and the crab have strong feeding physiological mechanism to the peculiar smell of the (2-carboxyethyl) dimethyl sulfonium bromide. Compared with the fish luring agent of the common bait, the time for releasing the fish luring agent of the bait is obviously prolonged, and the fish luring agent can be continuously released in water, so that the fish biting times are improved, and the fishing effect is good.
The invention aims to provide hydrogel bait and a preparation method thereof, and the hydrogel bait with the first-level release rate of the fish luring agent is obtained, and the bait can effectively and continuously release the fish luring agent to achieve the purpose of long-acting fish luring and bait swallowing.
Therefore, the technical scheme adopted by the invention is as follows:
the hydrogel bait consists of the following effective components in percentage by mass: 5-8% of polyvinyl alcohol; 0.85-1.5% of egg white powder; 1.5 to 3 percent of anion high polymer; 0.5 to 1 percent of cation fish luring agent; 0.2 to 0.5 percent of preservative; 0.5-1% of mung bean starch; 88-95% of deionized water.
Further, the anionic polymer is sodium alginate and sodium polyacrylate, and the mass ratio of the sodium alginate to the sodium polyacrylate is 1: 0.5-2.
Sodium alginate and sodium polyacrylate are mixed by monomers with different molecular weights, wherein: molecular weight 3000 sodium polyacrylate mass: mass of sodium polyacrylate with molecular weight of 12000: the mass of 800 ten thousand sodium polyacrylate with molecular weight is 1: 0.5-3: 0.3 to 2; mass of sodium alginate with molecular weight of 3700: the mass of the sodium alginate with the molecular weight of 64000 is 1: 0.5-2.
The cation fish luring agent is (2-carboxyethyl) dimethyl sulfonium bromide.
(2-carboxyethyl) dimethylsulfonium bromide has the following structural formula:
the preservative is potassium sorbate.
The invention also adopts the following technical scheme:
weighing the components according to a set proportion, dissolving an anionic polymer in deionized water, slowly adding polyvinyl alcohol, egg white powder, (2-carboxyethyl) dimethyl sulfonium bromide, potassium sorbate and mung bean starch, magnetically stirring for 40 minutes at room temperature, stirring for 2.5 hours at a constant temperature of 95 ℃ in an oil bath kettle, completely mixing the system to obtain a clear and transparent viscous solution, pouring the solution into a mold, standing for 1.5 hours to remove bubbles, freezing for 20 hours at-25 ℃, taking out the solution, thawing for 4.5 hours, circulating for 3 times in a freezing-thawing manner, pouring the hydrogel out of the mold, and placing the hydrogel in pure water to remove unreacted monomers to obtain the hydrogel bait.
Compared with the prior art, the invention has the following beneficial effects: the method comprises the following steps of mixing anionic high polymer, polyvinyl alcohol, egg white powder, a cationic fish luring agent, an antiseptic and mung bean starch to prepare the hydrogel bait, combining the anionic high polymer and the cationic fish luring agent, enabling the polyvinyl alcohol to form hydrogen bonds with carbonyl groups of the egg white powder through hydroxyl groups to prepare the bait with the fish luring agent close to the first-level release rate, and enabling the xerogel to expand in volume after water absorption to release the loaded fish luring agent, so that the effect of effective and continuous release can be achieved.
Drawings
The following detailed description is made with reference to the accompanying drawings and embodiments of the present invention
Fig. 1 shows the sustained release speed of the hydrogel bait.
Detailed Description
The invention will be further described with reference to specific examples, but the scope of the invention is not limited thereto:
it is to be understood that these examples are preferred embodiments of the invention and are intended only for purposes of illustration. From the above discussion and these examples, one skilled in the art can ascertain the essential characteristics of this invention, and without departing from the spirit and technical scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.
Example 1
1) Hydrogel preparation
1.0g of sodium polyacrylate with the molecular weight of 3000, 0.5g of sodium polyacrylate with the molecular weight of 12000, 1.5g of sodium polyacrylate with the molecular weight of 800 ten thousand, 1.5g of sodium alginate with the molecular weight of 3700 and 1.5g of sodium alginate with the molecular weight of 64000 are dissolved in 300ml of deionized water, 22.0g of polyvinyl alcohol 1788, 3.0g of egg white powder, (2-carboxyethyl) dimethyl sulfonium bromide, 0.9g of potassium sorbate and 2.0g of mung bean starch are slowly added, magnetic stirring is carried out for 40 minutes at room temperature, an oil bath kettle is stirred for 2.5 hours at the constant temperature of 95 ℃, after complete solutions of anionic high polymer, polyvinyl alcohol, egg white powder, mung bean starch, (2-carboxyethyl) dimethyl sulfonium bromide and potassium sorbate are mixed uniformly, clear and transparent viscous solution is poured into a mold to stand for 1.5 hours to remove air bubbles, then is placed in a freezing layer for 20 hours at the temperature of-25 ℃, then is unfrozen at the temperature of 25 ℃ for 4.5 hours, and (3) circulating the freeze-thaw times for 3 times, pouring the hydrogel out of the mold, and placing the hydrogel into pure water to remove unreacted monomers to obtain the hydrogel bait.
2) Drawing of (2-carboxyethyl) dimethyl sulfonium bromide standard curve
Precisely weighing 1.0g of (2-carboxyethyl) dimethyl sulfonium bromide, dissolving the (2-carboxyethyl) dimethyl sulfonium bromide in (phosphate buffer solution with pH of 7.4), fixing the volume to 1L, shaking the solution uniformly to serve as stock solution, weighing 5mL of the stock solution, fixing the volume to 100mL to obtain 50mg/L of (2-carboxyethyl) dimethyl sulfonium bromide solution, and diluting the solution to 5mg/L, 10mg/L, 15mg/L, 20mg/L, 25mg/L and 30 mg/L. The absorbance Abs of each solution was measured at the maximum absorption wavelength 208 by zeroing with a phosphate buffer solution at pH 7.4, according to lambert-beer's law with the (2-carboxyethyl) dimethylsulfonium bromide concentration (mg/L) as the abscissa and the absorbance Abs (a) as the ordinate.
3) Research on slow release performance of hydrogel bait to (2-carboxyethyl) dimethyl sulfonium bromide
The hydrogel bait prepared in example 1 was placed in a 50mL beaker containing a release medium (phosphate buffer solution having a pH of 7.4) and stored in a sealed manner, 5mL of the solution was taken out at regular intervals while 5mL of the release medium was replenished in the beaker, the absorbance of the taken-out solution at the maximum absorption wavelength was measured by an ultraviolet spectrophotometer, the absorbance was substituted into a standard curve to determine the concentration of (2-carboxyethyl) dimethylsulfonium bromide in the solution, and the cumulative release amount of (2-carboxyethyl) dimethylsulfonium bromide was calculated.
Cumulative release rate of (2-carboxyethyl) dimethylsulfonium bromide: q (%) - (C)n×50+Cn-1×5+……+C1×5)/(1000×Wo)]×100％
In the formula: cnDetermining the concentration (mg/L) of (2-carboxyethyl) dimethylsulfonium bromide in the delivery system for the nth sample; cn-1The concentration (mg/L) of (2-carboxyethyl) dimethylsulfonium bromide in the delivery system was determined for the (n-1) th sampling;
W0the mass (mg) of (2-carboxyethyl) dimethylsulfonium bromide in the hydrogel bait sample was used.
4) Hydrogel bait strength test
The hydrogel bait samples were cut into dumbbell-shaped sample strips, the compression strength was measured with a universal tester, the compression rate was 20mm/min, 3 samples per group were tested, and the average value was taken.
The procedure of example 1 was otherwise the same as that of example 2 to example 4 in Table 1 except that anionic polymers having different molecular weights were added to the control group without adding any anionic polymer.
Table 1 composite hydrogel bait formulation composition
TABLE 2 compression Strength and Water content of hydrogel bait
As can be seen from Table 1 and FIG. 1, the rate of releasing the fish luring agent from the hydrogel bait prepared by the present invention is close to the first-order release rate, and compared with the prior art, the fish luring agent in the bait can be released continuously, and the release time of the fish luring agent is prolonged obviously.
The above description is only a preferred embodiment of the present invention and should not be taken as limiting the invention, and any modification, replacement, or improvement made on the principle of the present invention should be included in the protection scope of the present invention.
Claims (6)
1. The hydrogel bait is characterized in that: the composition comprises the following effective components in percentage by mass: the composition comprises the following effective components in percentage by mass: 5-8% of polyvinyl alcohol; 0.85-1.5% of egg white powder; 1.5 to 3 percent of anion high polymer; 0.5 to 1 percent of cation fish luring agent; 0.2 to 0.5 percent of preservative; 0.5-1% of mung bean starch; 88-95% of deionized water.
2. The hydrogel fishing lure according to claim 1, wherein: the anionic polymer is sodium alginate and sodium polyacrylate, and the mass ratio of the sodium alginate to the sodium polyacrylate is 1: 0.5-2.
3. The hydrogel fishing lure according to claim 1, wherein: sodium alginate and sodium polyacrylate are mixed by monomers with different molecular weights, wherein: molecular weight 3000 sodium polyacrylate mass: mass of sodium polyacrylate with molecular weight of 12000: the mass of 800 ten thousand sodium polyacrylate with molecular weight is 1: 0.5-3: 0.3 to 2; mass of sodium alginate with molecular weight of 3700: the mass of the sodium alginate with the molecular weight of 64000 is 1: 0.5-2.
4. The hydrogel fishing lure according to claim 1, wherein: the cation fish luring agent is (2-carboxyethyl) dimethyl sulfonium bromide, and the (2-carboxyethyl) dimethyl sulfonium bromide has the following structural formula:
5. the hydrogel fishing lure according to claim 1, wherein: the preservative is potassium sorbate.
6. A method for preparing hydrogel bait according to any one of claims 1 to 5, which is characterized in that: weighing the components according to a set proportion, dissolving an anionic high polymer in deionized water, slowly adding polyvinyl alcohol, egg white powder, (2-carboxyethyl) dimethyl sulfonium bromide, potassium sorbate and mung bean starch, magnetically stirring for 40 minutes at room temperature, stirring for 2.5 hours at a constant temperature of 95 ℃ in an oil bath kettle, completely mixing the system to obtain a clear and transparent viscous solution, pouring the solution into a mold, standing for 1.5 hours to remove bubbles, freezing for 20 hours at-25 ℃, taking out and thawing for 4.5 hours, performing freeze-thaw cycle for 3 times, pouring the hydrogel out of the mold, and placing the hydrogel in pure water to remove unreacted monomers to obtain the hydrogel bait.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202011082358.5A CN112321850B (en) | 2020-10-12 | 2020-10-12 | Hydrogel bait and preparation method thereof |
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| CN202011082358.5A CN112321850B (en) | 2020-10-12 | 2020-10-12 | Hydrogel bait and preparation method thereof |
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| CN112321850A true CN112321850A (en) | 2021-02-05 |
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Cited By (1)
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| CN113331147A (en) * | 2021-06-04 | 2021-09-03 | 浙江师范大学 | Novel quick-adhesion type fishing bait and preparation method thereof |
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| CN113331147A (en) * | 2021-06-04 | 2021-09-03 | 浙江师范大学 | Novel quick-adhesion type fishing bait and preparation method thereof |
| CN113331147B (en) * | 2021-06-04 | 2023-02-24 | 浙江师范大学 | Preparation method of quick-adhesion fishing bait |
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| CN112321850B (en) | 2022-06-14 |
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