CN112321156A - Random color anti-static ceramic tile and preparation method thereof - Google Patents
Random color anti-static ceramic tile and preparation method thereof Download PDFInfo
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- CN112321156A CN112321156A CN202011175827.8A CN202011175827A CN112321156A CN 112321156 A CN112321156 A CN 112321156A CN 202011175827 A CN202011175827 A CN 202011175827A CN 112321156 A CN112321156 A CN 112321156A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention discloses an anti-static tile with random color and a preparation method thereof, wherein the anti-static tile is prepared from the following raw materials in parts by weight: 10-13 parts of barium carbonate, 12-14 parts of zinc oxide, 3-5 parts of quartz, 14-15 parts of dolomite, 10-11 parts of washing soil, 46-49 parts of feldspar, 5-7 parts of talc, 30-34 parts of conductive powder and 0.1-0.3 part of coloring material. The invention changes the condition that the color of the ceramic tile is changed to be single, also keeps good conductivity of the ceramic tile, forms a stable conductive network, minimizes the influence of metal oxides and realizes sustainable production.
Description
The technical field is as follows:
the invention relates to a ceramic tile glaze, in particular to an anti-static ceramic tile with random color and a preparation method thereof, and belongs to the technical field of ceramic glazes.
Background art:
the different static ceramic tiles in market, static brick ubiquitous problem are, the colour is single, and the colour can only make the ceramic tile of similar beige white and light colour, and this kind of colour is the original colour of frit in fact, if make the frit of pattern or other dark colours (similar black), the ceramic tile is fired out and will lose electric conductivity, and this is the ubiquitous problem in market, and temporary unable way is solved, can not satisfy the different fancy of consumer's electrically conductive ceramic tile and colour requirement.
The invention content is as follows:
the technical problem to be solved by the invention is as follows: the antistatic ceramic tile with random color and the preparation method thereof are provided, the problem of single color of the tile is solved by adding coloring materials, and the conductivity of the tile is not lost by adding elements with good conductivity.
The technical scheme adopted by the invention for solving the technical problem is as follows:
the utility model provides an arbitrary colour prevents static ceramic tile which characterized in that: the feed is prepared from the following raw materials in parts by weight: 10-13 parts of barium carbonate, 12-14 parts of zinc oxide, 3-5 parts of quartz, 14-15 parts of dolomite, 10-11 parts of washing soil, 46-49 parts of feldspar, 5-7 parts of talc, 30-34 parts of conductive powder and 0.1-0.3 part of coloring material.
The coloring material is metal oxide, and the metal oxide can be zirconium oxide, ferric oxide and chromium oxide, and can also be vanadium pentoxide, zirconium silicate and aluminum oxide.
The weight ratio of the zirconium oxide to the ferric oxide to the chromium oxide is 25% to 35% to 40%.
The weight ratio of the vanadium pentoxide to the zirconium silicate to the aluminum oxide is 25% to 60% to 15%.
The preparation method of the antistatic ceramic tile glaze is characterized by comprising the following steps: the method comprises the following steps:
(1) weighing barium carbonate, zinc oxide, quartz, dolomite, washing soil, feldspar, talc, conductive powder and coloring material according to a proportion, and sending the materials into a ball mill for grinding to obtain mixed powder A;
(2) adding 0.4% of blank methyl, 0.45% of sodium tripolyphosphate and 46% of water into the mixed powder A, and mixing and stirring for 25-40 minutes to obtain mixed glaze slurry B;
(3) detecting the mixed glaze slurry B after stirring, and requiring that: the specific gravity of the glaze slip is 0.2%, and the fineness of the glaze slip is less than or equal to 0.3;
(4) feeding the mixed glaze slurry B after being stirred to be qualified into a vibrating screen, and vibrating for 20 minutes, wherein the used vibrating screen is 140 meshes;
(5) and feeding the ceramic blank, and firing after the feeding is finished.
When feeding, the surface temperature of the ceramic blank is 85-90 ℃, and the strength of the blank is 1.0 MPA.
When the blank body is fired, the kiln speed is 25-40 cycles, the firing time is 40-60 minutes, the firing temperature is 1150-1160 ℃, and the holding time at the highest temperature is 10-20 minutes.
The invention has the following positive beneficial effects:
the invention not only changes the problem of single color of the ceramic tile, but also can keep the conductivity of the ceramic tile while adding metal oxide as coloring material in the glaze by adjusting the formula of the glaze, so that the resistance value is always in a stable range, and the requirement of consumers is met.
2. The glaze formula introduces the conductive-assisting element to form a stable conductive network, so that the influence of metal oxide is minimized, and sustainable production is realized, wherein the performances of the raw materials are as follows:
firstly, zinc oxide: as an important component of a glaze raw material, the high-temperature viscosity and the surface tension of a glaze melt are reduced, so that an electrostatic glaze layer can be easily spread on a blank body, and a high-quality glaze surface is obtained; in addition, the zinc oxide can improve the glossiness and the chemical corrosion resistance of the glaze surface.
② barium carbonate: the main substances for generating the celsian crystals are high-temperature fluxing agents with very stable chemical properties, and the glazed surfaces can be smooth; the celsian crystals formed in the glaze, which are present themselves in a network structure, allow the electrostatic layer to be spread evenly to the local corners.
③ dolomite: the main raw materials of the matt glaze are high in surface tension, and the ductility, namely surface smoothness, of the glaze can be improved by adding dolomite, and the hand feeling of the glaze is directly improved, so that the matt glaze is soft and smooth.
Fourthly, talc: the stable high-temperature strong fluxing agent has the strongest fluxing effect in a high-temperature state. Has irreplaceable effect on stabilizing the glaze firing temperature.
Fifth, kaolin: the raw materials are added, so that the glaze suspension effect is realized in the glaze, and the function of homogenizing the glaze liquid is realized in the mass production; in the absence of kaolin or glazes with poor kaolin performance, precipitation often occurs, which can seriously affect the uniformity of the chemical composition of the upper and lower layers of the glaze liquid.
Sixthly, quartz: a certain amount of barium carbonate is introduced, so that the amount of barium feldspar crystals generated by barium carbonate is increased, and the conductive network tissue is indirectly promoted; and is also an important component raw material for improving the glossiness and the chemical resistance.
And seventhly, feldspar: raw materials are added, the chemical stability is good, and a structural basic unit of a glaze formula is formed; in essence, the electrostatic glaze is a feldspar based glaze.
The specific implementation mode is as follows:
the invention will be further explained and illustrated by means of specific embodiments:
example 1, an antistatic tile glaze is prepared from the following raw materials in parts by weight: 10 parts of barium carbonate, 12 parts of zinc oxide, 3 parts of quartz, 14 parts of dolomite, 10 parts of washing soil, 46 parts of feldspar, 5 parts of talcum, 30 parts of conductive powder and 0.1 part of coloring material; wherein: the coloring material is metal oxide, and the metal oxide can be zirconium oxide, ferric oxide and chromium oxide, and can also be vanadium pentoxide, zirconium silicate and aluminum oxide; the weight ratio of the zirconium oxide to the ferric oxide to the chromium oxide is 25 percent to 35 percent to 40 percent. (ii) a The weight ratio of the vanadium pentoxide to the zirconium silicate to the aluminum oxide is 25 percent to 60 percent to 15 percent.
The preparation method of the antistatic ceramic tile glaze comprises the following steps:
(1) weighing barium carbonate, zinc oxide, quartz, dolomite, washing soil, feldspar, talc, conductive powder and coloring material according to a proportion, and sending the materials into a ball mill for grinding to obtain mixed powder A;
(2) adding 0.4% of blank methyl, 0.45% of sodium tripolyphosphate and 46% of water into the mixed powder A, and mixing and stirring for 25-40 minutes to obtain mixed glaze slurry B;
(3) detecting the mixed glaze slurry B after stirring, and requiring that: the specific gravity of the glaze slip is 0.2%, and the fineness of the glaze slip is less than or equal to 0.3;
(4) feeding the mixed glaze slurry B after being stirred to be qualified into a vibrating screen, and vibrating for 20 minutes, wherein the used vibrating screen is 140 meshes;
(5) and feeding the ceramic blank, and firing after the feeding is finished.
When feeding, the surface temperature of the ceramic blank is 85-90 ℃, and the strength of the blank is 1.0 MPA.
When the blank is fired, the kiln speed is 25-40 cycles, the firing time is 40-60 minutes, the firing temperature is 1150-1160 ℃, and the holding time at the highest temperature is 10-20 minutes.
Embodiment 2, an antistatic tile glaze is prepared from the following raw materials in parts by weight: 13 parts of barium carbonate, 14 parts of zinc oxide, 5 parts of quartz, 15 parts of dolomite, 11 parts of washing soil, 49 parts of feldspar, 7 parts of talc, 34 parts of conductive powder and 0.3 part of coloring material; the coloring material is a metal oxide, and the metal oxide can be zirconium oxide, ferric oxide and chromium oxide, and can also be vanadium pentoxide, zirconium silicate and aluminum oxide; the weight ratio of the zirconium oxide to the ferric oxide to the chromium oxide is 25 percent to 35 percent to 40 percent. (ii) a The weight ratio of the vanadium pentoxide to the zirconium silicate to the aluminum oxide is 25 percent to 60 percent to 15 percent. .
The preparation method of the antistatic ceramic tile glaze comprises the following steps:
(1) weighing barium carbonate, zinc oxide, quartz, dolomite, washing soil, feldspar, talc, conductive powder and coloring material according to a proportion, and sending the materials into a ball mill for grinding to obtain mixed powder A;
(2) adding 0.4% of blank methyl, 0.45% of sodium tripolyphosphate and 46% of water into the mixed powder A, and mixing and stirring for 25-40 minutes to obtain mixed glaze slurry B;
(3) detecting the mixed glaze slurry B after stirring, and requiring that: the specific gravity of the glaze slip is 0.2%, and the fineness of the glaze slip is less than or equal to 0.3;
(4) feeding the mixed glaze slurry B after being stirred to be qualified into a vibrating screen, and vibrating for 20 minutes, wherein the used vibrating screen is 140 meshes;
(5) and feeding the ceramic blank, and firing after the feeding is finished.
When feeding, the surface temperature of the ceramic blank is 85-90 ℃, and the strength of the blank is 1.0 MPA.
When the blank is fired, the kiln speed is 25-40 cycles, the firing time is 40-60 minutes, the firing temperature is 1150-1160 ℃, and the holding time at the highest temperature is 10-20 minutes.
Example 3, an antistatic tile glaze is prepared from the following raw materials in parts by weight: 10 parts of barium carbonate, 12 parts of zinc oxide, 3 parts of quartz, 14 parts of dolomite, 10 parts of washing soil, 46 parts of feldspar, 5 parts of talcum, 30 parts of conductive powder and 0.1 part of coloring material; wherein: the coloring material is metal oxide, the metal oxide can be zirconium oxide, ferric oxide and chromium oxide, and the weight ratio of the zirconium oxide, the ferric oxide and the chromium oxide is 25 percent to 35 percent to 40 percent. .
The preparation method of the antistatic ceramic tile glaze comprises the following steps:
(1) weighing barium carbonate, zinc oxide, quartz, dolomite, washing soil, feldspar, talc, conductive powder and coloring material according to a proportion, and sending the materials into a ball mill for grinding to obtain mixed powder A;
(2) adding 0.4% of blank methyl, 0.45% of sodium tripolyphosphate and 46% of water into the mixed powder A, and mixing and stirring for 25-40 minutes to obtain mixed glaze slurry B;
(3) detecting the mixed glaze slurry B after stirring, and requiring that: the specific gravity of the glaze slip is 0.2%, and the fineness of the glaze slip is less than or equal to 0.3;
(4) feeding the mixed glaze slurry B after being stirred to be qualified into a vibrating screen, and vibrating for 20 minutes, wherein the used vibrating screen is 140 meshes;
(5) and feeding the ceramic blank, and firing after the feeding is finished.
When the ceramic blank is loaded, the surface temperature of the ceramic blank is 85 ℃, and the strength of the blank is 1.0 MPA.
When the blank body is fired, the kiln speed is 25-40 cycles, the firing time is 40-60 minutes, the firing temperature is 1150-1160 ℃, and the heat preservation time at the highest temperature is 10-20 minutes;
the coloring material mainly comprises cobalt oxide and ferric oxide, and is a pure black antique brick on the market; the conductivity of the cobalt oxide is poor, the ferric oxide can be oxidized to react, part of the ferroferric oxide solid particles are converted, and the ferroferric oxide solid has certain conductivity and can not react with other components of the glaze melt; therefore, the combination of the cobalt oxide and the ferric oxide has little influence on the resistance, but the resistance is increased along with the increase of the coloring material amount, so that the stability of the electric conduction is ensured by introducing the quartz and the conductive powder.
Example 4, an antistatic tile glaze is prepared from the following raw materials in parts by weight: 13 parts of barium carbonate, 14 parts of zinc oxide, 5 parts of quartz, 15 parts of dolomite, 11 parts of washing soil, 49 parts of feldspar, 7 parts of talc, 34 parts of conductive powder and 0.3 part of coloring material; wherein: the coloring material is metal oxide, and the metal oxide can be vanadium pentoxide, zirconium silicate and aluminum oxide; the weight ratio of the vanadium pentoxide to the zirconium silicate to the aluminum oxide is 25 percent to 60 percent to 15 percent. .
The preparation method of the antistatic ceramic tile glaze is characterized by comprising the following steps: the method comprises the following steps:
(1) weighing barium carbonate, zinc oxide, quartz, dolomite, washing soil, feldspar, talc, conductive powder and coloring material according to a proportion, and sending the materials into a ball mill for grinding to obtain mixed powder A;
(2) adding 0.4% of blank methyl, 0.45% of sodium tripolyphosphate and 46% of water into the mixed powder A, and mixing and stirring for 25-40 minutes to obtain mixed glaze slurry B;
(3) detecting the mixed glaze slurry B after stirring, and requiring that: the specific gravity of the glaze slip is 0.2%, and the fineness of the glaze slip is less than or equal to 0.3;
(4) feeding the mixed glaze slurry B after being stirred to be qualified into a vibrating screen, and vibrating for 20 minutes, wherein the used vibrating screen is 140 meshes;
(5) and feeding the ceramic blank, and firing after the feeding is finished.
When feeding, the surface temperature of the ceramic blank is 85-90 ℃, and the strength of the blank is 1.0 MPA.
When the blank body is fired, the kiln speed is 25-40 cycles, the firing time is 40-60 minutes, the firing temperature is 1150-1160 ℃, and the holding time at the highest temperature is 10-20 minutes.
The coloring material mainly comprises vanadium pentoxide, zirconium silicate and aluminum oxide, and is an ivory white anti-static ceramic tile on the market, wherein zirconium silicate can greatly dissolve a conductive network formed on a glaze surface, the conductivity of vanadium pentoxide is poor, and the introduction of metal ions can easily neutralize the conductivity of the electrostatic glaze; therefore, the introduction of 0.1% into the 8 th-power glaze with a normal resistance value of 10 directly results in the loss of the resistance value; therefore, it is absolutely necessary to introduce quartz and conductive powder to form a stable network conductive layer, which can resist the destructive effect of metal oxides and other oxides in the pigment.
We understand the influence of the kiln temperature profile and key raw materials by the following experimental data:
A. a high-temperature fast-firing system: the kiln length is 250-300 m, the average kiln speed is 35 cycles, and the total firing time is 35 minutes. The actual maximum glaze firing temperature is 1155 ℃, and the holding time at the maximum temperature is more than 6 minutes, so that under the firing curve, the ideal resistance range can be achieved. (normal value is 10 to the power of 8.)
B. High-temperature slow firing degree: the kiln length is 250-300 m, the average kiln speed is 24 cycles, and the total firing time is 1 hour; the maximum glaze firing temperature is 1160 ℃, and when the heat preservation time at the maximum temperature reaches more than 15 minutes, the ideal resistance range can be reached. (normal value is 10 to the power of 8.)
C. The average kiln speed is 35 cycles, the total firing period of the kiln is 1 hour with 300 meters. The maximum glaze firing temperature is 1150 ℃, the holding time of the maximum temperature is less than 5 minutes, the resistance value is in a higher value, and under the condition that the holding time is less than 5 minutes, the data is only 9 to 10 times of 10; 8 th power of normal data well above 10. The problem of the firing system is that the holding time is too short, crystals in the glaze are just formed, the crystals do not grow and develop for a certain time, and the line construction of the conductive network is tiny, so the conductivity is poor.
D. The average kiln speed is 35 cycles, the total firing period of the kiln with 300 meters is still 1 hour. The maximum glaze firing temperature is 1140 ℃, the maximum temperature holding time is 10 minutes, and the resistance value is 10 to the power of 10. The firing system is caused by that the temperature is too low, the solid phase reaction is not complete enough, the crystal phase glass phase reaction in the glaze melt is not complete enough, and the glaze melt does not form a sufficiently homogenized conductive network.
E. The feed is prepared from the following raw materials in parts by weight: 13 parts of barium carbonate, 15 parts of dolomite, 11 parts of washing soil, 49 parts of feldspar, 7 parts of talc, 34 parts of conductive powder and 0.3 part of coloring material; wherein: the coloring material is metal oxide, the metal oxide is vanadium pentoxide, zirconium silicate and aluminum oxide, the component ratio of the vanadium pentoxide to the zirconium silicate to the aluminum oxide is 25% to 60% to 15%, and the generated ceramic tile is detected to be 10 times of the resistance value of 10.
From the above cases, it is known that: the three decisive factors for determining the resistance value and the glaze quality are a total firing period, a maximum glaze firing temperature and a maximum temperature holding time, wherein the total firing period only most influences the glaze effect, but not the final conductivity; the maximum glaze firing temperature and the maximum temperature heat preservation time can directly influence the resistance value, key raw materials are lacked in the raw materials, the ceramic tile can not form a stable conductive network,
therefore, in order to ensure that the pure-color electrostatic bricks obtain excellent glaze quality and stable resistance value, certain requirements are imposed on the kiln curve, the kiln curve is formulated to 1150 ℃ according to the maximum firing, and the temperature is kept for more than 10 minutes in a high-temperature area, which is most suitable.
According to the invention, by adjusting the formula of the glaze, the conductivity of the ceramic tile can be kept while the metal oxide is added into the glaze as a coloring material, so that the resistance value is always in a stable range, a stable conductive network is formed, the influence of the metal oxide is minimized, and sustainable production is realized.
Claims (7)
1. An anti-static tile with random colors and a preparation method thereof are characterized in that: the feed is prepared from the following raw materials in parts by weight: 10-13 parts of barium carbonate, 12-14 parts of zinc oxide, 3-5 parts of quartz, 14-15 parts of dolomite, 10-11 parts of washing soil, 46-49 parts of feldspar, 5-7 parts of talc, 30-34 parts of conductive powder and 0.1-0.3 part of coloring material.
2. The free color antistatic tile and the preparation method thereof according to claim 1, wherein: the coloring material is metal oxide, and the metal oxide can be zirconia, ferric oxide and oxide complex, and can also be vanadium pentoxide, zirconium silicate and alumina.
3. The free color antistatic tile and the preparation method thereof according to claim 2, wherein: the weight ratio of the zirconium oxide to the ferric oxide to the chromium oxide is 25% to 35% to 40%.
4. The free color antistatic tile and the preparation method thereof according to claim 2, wherein: the weight ratio of the vanadium pentoxide to the zirconium silicate to the aluminum oxide is 25% to 60% to 15%.
5. An arbitrary color antistatic tile and a method for preparing the same according to claim 1 or 2, wherein: the method comprises the following steps:
weighing barium carbonate, zinc oxide, quartz, dolomite, washing soil, feldspar, talc, conductive powder and coloring material according to a proportion, and feeding the materials into a ball mill for grinding to obtain mixed powder A;
secondly, adding 0.4% of blank methyl, 0.45% of sodium tripolyphosphate and 46% of water into the mixed powder A, and mixing and stirring for 25-40 minutes to obtain mixed glaze slurry B;
detecting the stirred mixed glaze slurry B, and requiring that: the specific gravity of the glaze slip is 0.2%, and the fineness of the glaze slip is less than or equal to 0.3;
fourthly, feeding the mixed glaze slurry B after being stirred to be qualified into a vibrating screen, and vibrating for 20 minutes, wherein the used vibrating screen is 140 meshes;
and fifthly, feeding the ceramic blank body, and firing after the feeding is finished.
6. The free color antistatic tile and the preparation method thereof according to claim 4, wherein: when feeding, the surface temperature of the ceramic blank is 85-90 ℃, and the strength of the blank is 1.0 MPA.
7. The free color antistatic tile and the preparation method thereof according to claim 4, wherein: when the blank is fired, the kiln speed is 25-40 cycles, the firing time is 40-60 minutes, the firing temperature is 1150-1160 ℃, and the holding time at the highest temperature is 10-20 minutes.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN117430405A (en) * | 2023-10-09 | 2024-01-23 | 山东亮剑陶瓷有限公司 | Antistatic ceramic tile and preparation method thereof |
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| CN101042013A (en) * | 2007-04-21 | 2007-09-26 | 淄博统一陶瓷有限公司 | Antistatic pseudo-classic ecological brick |
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| CN117430405A (en) * | 2023-10-09 | 2024-01-23 | 山东亮剑陶瓷有限公司 | Antistatic ceramic tile and preparation method thereof |
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