CN101042013A - Antistatic pseudo-classic ecological brick - Google Patents

Antistatic pseudo-classic ecological brick Download PDF

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Publication number
CN101042013A
CN101042013A CN 200710014609 CN200710014609A CN101042013A CN 101042013 A CN101042013 A CN 101042013A CN 200710014609 CN200710014609 CN 200710014609 CN 200710014609 A CN200710014609 A CN 200710014609A CN 101042013 A CN101042013 A CN 101042013A
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CN
China
Prior art keywords
antistatic
classic
pseudo
ecological brick
glaze
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Application number
CN 200710014609
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Chinese (zh)
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CN100422481C (en
Inventor
袁国梁
张建斌
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Shandong Electric Shield Polytron Technologies Inc
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Baoding Chint Technology Co Ltd
ZIBO TONGYI CERAM CO Ltd
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Application filed by Baoding Chint Technology Co Ltd, ZIBO TONGYI CERAM CO Ltd filed Critical Baoding Chint Technology Co Ltd
Priority to CNB2007100146094A priority Critical patent/CN100422481C/en
Publication of CN101042013A publication Critical patent/CN101042013A/en
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Publication of CN100422481C publication Critical patent/CN100422481C/en
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Abstract

An antistatic archaize ecological brick comprises the blank and the glaze surface, with the blank made of 35-38% feldspar, 28-32% clay, 7-10% flint clay, 1-3% talc, 6-12% quartz, 5-14% conductive powder, with the glaze surface made of potash feldspar 29-32%,albite porphyrite 15-18%, calcite 6-10%, sintering talc 5-8%, zinc bloom,barium carbonate 3-6% , alumina 4-7%, clinker clew 8-13%, calcinations dust 15- 20%, China clay 3-7% and conductive powder 13-18%.it not only enjoys the fine features of ceramic tile, but also having the ability of eliminating electrostatic, with surface electro resistance and leak electro resistance being 1X106-1X109omega.cm, conforming to the standard of <=1X109omega.cm, being healthy and environment friendly.

Description

Antistatic pseudo-classic ecological brick
Technical field
The present invention relates to a kind of antistatic pseudo-classic ecological brick, be floor tile, belong to the architectural pottery technical field.
Background technology
In daily life, especially in the north dry winter, indoor have " " everywhere, touches door handle and can be shocked by electricity, and touches water pipe and can be shocked by electricity, and goes home to hold a baby in one's arms and also can be shocked by electricity, even unblank to touch keyhole, also can be shocked by electricity.Discover that these electric shock phenomenons bring very big harm can for people's body ﹠ mind, influence the physiological equilibrium of personal human body, cause all illness subtlely, quicken human senescence.Particularly some working environment must not require and had static, as machine room of high technology equipment etc.Therefore need to eliminate static.
Summary of the invention
The object of the present invention is to provide a kind of antistatic pseudo-classic ecological brick, can eliminate static, promote health, protection live and work environment.
Antistatic pseudo-classic ecological brick of the present invention comprises base substrate and glaze layer, it is characterized in that:
The ingredients by weight percentage composition of base substrate is: feldspar 35~38%, clay 28~32%, flint clay 7~10%, talcum 1~3%, quartz 6~12% and conducting powder 5~14%;
The ingredients by weight percentage composition of glaze layer is: potassic feldspar 29~32%, albite 15~18%, calcite 6~10%, burning talcum 5~8%, zinc oxide 4~7%, brium carbonate 3~6%, alumina 4~7%, frit 8~13%, calcined earth 15~20% and kaolin 3~7% add conducting powder 13~18%;
Wherein:
The ingredients by weight percentage composition of conducting powder is: alumina 55~60%, calcium oxide 16~23% and zinc oxide 20~27%;
The weight percent of frit consists of: R 2O 4.07%, CaO 8.2%, BaO 1.5%, ZnO 6.2%, PbO 0.47%, Al 2O 38.7%, B 2O 32.67%, SiO 267.38% and ZrO 20.81%, R wherein 2O is Na 2O and K 2O and, also be written as KnaO.
The present invention has determined suitable base substrate batching and glaze layer batching and has formed, and added conducting powder therein, thereby obtained antistatic pseudo-classic ecological brick by a large amount of development tests.By laying antistatic pseudo-classic ecological brick of the present invention, static can be drawn and let out in the earth, change the normal current potential of body surface, make between human body and the earth and form equipotential, avoided the electric shock phenomenon, eliminated the discomfort that electric shock is brought, promote healthy.Eliminate static, also satisfied the requirement that must not there be static in the working environment requirement; Eliminate static, also help environmental protection, meet ecological requirement.
Many times, also need on the glaze layer, execute printing glaze, improve decorative effect, as pseudo-classic effect, suitable printing glaze ingredients by weight percentage composition is: potassic feldspar 20~25%, albite 15~18%, calcite 10~15%, zinc oxide 6~8%, alumina 4~8%, quartz 8~12%, frit 15~20% and kaolin 6~10% add conducting powder 5~9%.
According to above-mentioned batching requirement, utilize common floor tile production technology, can production antistatic pseudo-classic ecological brick of the present invention.General activities is as follows:
Body preparation:
Each is prepared burden grinds into mud into barreling, and powdered granule is made in oven dry then, through forcing press compression moulding, after the oven dry semiproduct---base substrate.
Glaze preparation and glazing:
Each is prepared burden grinds into glaze slip into barreling, dries after glazing on the base substrate.
In the time of need applying printing glaze, equally prepare printing glaze, apply printing glaze with the glaze preparation.Printing glaze adds corresponding toner according to the requirement difference of pattern, requires operation to get final product according to routine.
Product burns till: firing period 50~90 minutes, 1180~1210 ℃ of firing temperatures get product after burning till.
Antistatic pseudo-classic ecological brick of the present invention not only has the excellent properties of floor tile, and is ornamental strong, durable, and, also have antistatic characteristic, after testing, sheet resistance and bleeder resistance are: 1 * 10 6~1 * 10 9Ω cm meets standard≤1 * 10 9The requirement of Ω cm can be eliminated static, promotes health protection live and work environment.
The specific embodiment
The invention will be further described below in conjunction with embodiment.
Raw materials used chemical weight percentage composition sees the following form
SiO 2 Al 2O 3 Fe 2O 3 TiO 2 CaO MgO K 2O Na 2O Burn and lose
Potassic feldspar 65.33 19.66 0.02 0.06 0.04 10.80 3.32 0.68
Albite 72.33 15.38 0.07 0.69 0.13 2.01 8.77 0.38
Calcite 56.03 18.00 25.50
Burn talcum 64.30 34.06
Calcined earth 56.40 42.80
Kaolin 52.50 38.23 8.40
Feldspar 70.01 16.43 0.37 0.52 0.35 2.77 8.10 0.39
Clay 71.42 14.91 0.70 0.06 1.77 3.18 1.22 0.55 6.19
Flint clay 44.69 39.27 0.50 0.08 0.17 0.38 13.96
Talcum 59.56 1.51 0.38 0.11 0.40 32.37 0.02 0.05 5.59
Quartzy 99.20 0.09 0.70
The composition deficiency of raw material in the table, surplus is conventional dirt, ore deposit, ground raw material is kept away carrying secretly of unavoidable dirt, thinks pure also not pure.
Other raw material is a technical pure chemical industry raw material.
The weight percent of frit consists of: R 2O 4.07%, CaO 8.2%, BaO 1.5%, ZnO 6.2%, PbO 0.47%, Al 2O 38.7%, B 2O 32.67%, SiO 267.38% and ZrO 20.81%.
Antistatic pseudo-classic ecological brick of the present invention comprises base substrate and glaze layer, and its ingredients by weight percentage composition sees the following form:
Raw material Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8 Embodiment 9
Base substrate Feldspar 38 38 37 36 36 35 35 38 37
Clay 32 30 30 30 32 29 32 32 31
Flint clay 8 8 10 8 7 10 8 10 10
Talcum 2 2 3 2 3 3 2 2 2
Quartzy 10 12 10 10 10 12 12 6 6
Conducting powder 10 10 10 14 12 11 11 12 14
The glaze layer Potassic feldspar 30 28 29 28 29 29 30 32 30
Albite 15 15 15 15 15 15 15 15 16
Calcite 7 7 7 6 6 7 7 6 6
Burn talcum 7 7 7 6 6 6 7 6 5
Zinc oxide 4 6 6 6 6 5 6 4 5
Brium carbonate 5 5 5 5 5 4 5 5 4
Alumina 5 5 4 7 6 4 7 5 4
Frit 8 8 8 8 8 8 9 8 8
Calcined earth 15 15 15 15 15 15 15 15 15
Kaolin 4 4 4 4 4 7 3 4 7
Conducting powder 15 14 18 14 15 18 17 17 18
Printing glaze Potassic feldspar 20 23 21 20 25 20 20 21 20
Albite 18 16 18 18 18 16 18 17 18
Calcite 13 12 13 13 13 15 13 13 13
Zinc oxide 8 8 7 8 6 8 8 8 8
Alumina 7 7 7 8 4 7 6 7 7
Quartzy 10 11 12 9 10 9 11 11 10
Frit 16 15 15 15 16 15 16 15 15
Kaolin 8 8 7 9 8 10 8 8 9
Conducting powder 8 9 8 5 9 7 6 8 9
Conducting powder Alumina 58 55 58 57 56 60 59 60 60
Calcium oxide 17 18 20 16 21 16 18 20 19
Zinc oxide 25 27 22 27 23 24 23 20 21
Firing temperature (℃) 1190 1200 1208 1205 1206 1208 1210 1203 1210
Firing period (min) 80 85 83 89 83 89 88 86 85
Sheet resistance (1 * 10 9Ω·cm) 1×10 7 1×10 8 1×10 8 1×10 7 1×10 7 1×10 8 1×10 9 1×10 9 1×10 8
Bleeder resistance (1 * 10 9Ω·cm) 1×10 7 1×10 8 1×10 8 1×10 7 1×10 7 1×10 8 1×10 9 1×10 9 1×10 8
Prepare according to common process.

Claims (2)

1, a kind of antistatic pseudo-classic ecological brick comprises base substrate and glaze layer, it is characterized in that:
The ingredients by weight percentage composition of base substrate is: feldspar 35~38%, clay 28~32%, flint clay 7~10%, talcum 1~3%, quartz 6~12% and conducting powder 5~14%;
The ingredients by weight percentage composition of glaze layer is: potassic feldspar 29~32%, albite 15~18%, calcite 6~10%, burning talcum 5~8%, zinc oxide 4~7%, brium carbonate 3~6%, alumina 4~7%, frit 8~13%, calcined earth 15~20% and kaolin 3~7% add conducting powder 13~18%;
Wherein:
The ingredients by weight percentage composition of conducting powder is: alumina 55~60%, calcium oxide 16~23% and zinc oxide 20~27%;
The weight percent of frit consists of: R 2O 4.07%, CaO 8.2%, BaO 1.5%, ZnO 6.2%, PbO 0.47%, Al 2O 38.7%, B 2O 32.67%, SiO 267.38% and ZrO 20.81%.
2, antistatic pseudo-classic ecological brick according to claim 1, it is characterized in that having executed printing glaze on the glaze layer, the ingredients by weight percentage composition of printing glaze is: potassic feldspar 20~25%, albite 15~18%, calcite 10~15%, zinc oxide 6~8%, alumina 4~8%, quartz 8~12%, frit 15~20% and kaolin 6~10% add conducting powder 5~9%.
CNB2007100146094A 2007-04-21 2007-04-21 Antistatic pseudo-classic ecological brick Active CN100422481C (en)

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Application Number Priority Date Filing Date Title
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CN101042013A true CN101042013A (en) 2007-09-26
CN100422481C CN100422481C (en) 2008-10-01

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Cited By (19)

* Cited by examiner, † Cited by third party
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CN101314540A (en) * 2008-05-15 2008-12-03 郑兰斌 Porcelain high-strength abrasion-proof brick of sidewalk for the blind
CN101973757A (en) * 2010-08-24 2011-02-16 霍镰泉 Formula and production process of shell stone imitation ceramic tile
CN102030519A (en) * 2010-11-30 2011-04-27 广东特地陶瓷有限公司 Anti-static ceramic brick and production method thereof
CN102086111A (en) * 2010-11-23 2011-06-08 江苏瑞诚非金属材料有限公司 Acid-resistant high-temperature-resistant high-pressure-resistant ceramic tile and preparation method thereof
CN101708988B (en) * 2009-11-24 2011-09-14 袁国梁 Compound conductive powder for anti-static ceramic tile
CN102543247A (en) * 2012-01-14 2012-07-04 佛山市中国科学院上海硅酸盐研究所陶瓷研发中心 Composite conductive powder
CN102561656A (en) * 2012-02-15 2012-07-11 山东电盾科技有限公司 Anti-static ceramic-wood composite floor
CN103086498A (en) * 2013-01-30 2013-05-08 广州市大禹环保科技有限公司 Ecological brick for purifying water
CN103467137A (en) * 2013-08-30 2013-12-25 李惠成 Anti-static negative-ion eco-ceramic tile and preparation method thereof
CN105000865A (en) * 2015-07-08 2015-10-28 福建省晋江市丹豪陶瓷有限公司 Preparation method for large-sized ceramic tile
CN105036704A (en) * 2015-07-30 2015-11-11 李政伟 Wall corner ceramic tile and manufacturing method thereof
CN105064638A (en) * 2015-08-07 2015-11-18 东莞市唯美陶瓷工业园有限公司 Antistatic ceramic tile and manufacturing method thereof
CN106082658A (en) * 2016-06-16 2016-11-09 福建冠福实业有限公司 The magnesia glaze of environment-friendly type of a kind of high brightness and preparation technology thereof
CN106430966A (en) * 2016-08-18 2017-02-22 佛山欧神诺陶瓷股份有限公司 Transparent glaze with anti-electrostatic function and preparation method for ceramic tiles of transparent glaze
CN108585884A (en) * 2018-05-10 2018-09-28 山西安晟科技发展有限公司 Energy-saving fire proof foamed ceramics glaze Side fascia
CN111205069A (en) * 2020-03-09 2020-05-29 上海孚士德建筑科技有限公司 Preparation method of anti-static ceramic tile
CN112321156A (en) * 2020-10-29 2021-02-05 佛山昕通新型材料有限公司 Random color anti-static ceramic tile and preparation method thereof
CN114773033A (en) * 2022-05-07 2022-07-22 福建省德化县宝瑞陶瓷有限公司 Domestic ceramic product of transparent glaze and preparation method thereof
CN115433003A (en) * 2022-09-05 2022-12-06 罗毕诚 Anti-static ceramic tile and preparation method thereof

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SU1477719A1 (en) * 1987-06-17 1989-05-07 Томский политехнический институт им.С.М.Кирова Composition for making electric ceramic articles
CN2125628U (en) * 1992-07-15 1992-12-23 林文荻 Anti-static floor tile
CN2251000Y (en) * 1996-02-12 1997-04-02 李惠成 Antistatic filed floor
KR100417910B1 (en) * 2001-03-19 2004-02-14 이문수 Method product and tile for protecting static electricity
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DE20318290U1 (en) * 2003-11-26 2004-04-01 M. Kaindl Antistatic paper and panel
CN1693294B (en) * 2004-12-28 2010-07-14 华南理工大学 Electrostatic-proof ceramics wall floor tile and preparation method thereof
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CN101314540A (en) * 2008-05-15 2008-12-03 郑兰斌 Porcelain high-strength abrasion-proof brick of sidewalk for the blind
CN101708988B (en) * 2009-11-24 2011-09-14 袁国梁 Compound conductive powder for anti-static ceramic tile
CN101973757A (en) * 2010-08-24 2011-02-16 霍镰泉 Formula and production process of shell stone imitation ceramic tile
CN101973757B (en) * 2010-08-24 2012-07-25 霍镰泉 Formula and production process of shell stone imitation ceramic tile
CN102086111B (en) * 2010-11-23 2012-07-04 江苏瑞诚非金属材料有限公司 Acid-resistant high-temperature-resistant high-pressure-resistant ceramic tile and preparation method thereof
CN102086111A (en) * 2010-11-23 2011-06-08 江苏瑞诚非金属材料有限公司 Acid-resistant high-temperature-resistant high-pressure-resistant ceramic tile and preparation method thereof
CN102030519B (en) * 2010-11-30 2013-02-13 广东特地陶瓷有限公司 Anti-static ceramic brick and production method thereof
CN102030519A (en) * 2010-11-30 2011-04-27 广东特地陶瓷有限公司 Anti-static ceramic brick and production method thereof
CN102543247A (en) * 2012-01-14 2012-07-04 佛山市中国科学院上海硅酸盐研究所陶瓷研发中心 Composite conductive powder
CN102543247B (en) * 2012-01-14 2015-12-09 佛山市中国科学院上海硅酸盐研究所陶瓷研发中心 A kind of composite conductive powder
CN102561656A (en) * 2012-02-15 2012-07-11 山东电盾科技有限公司 Anti-static ceramic-wood composite floor
CN102561656B (en) * 2012-02-15 2014-01-08 山东电盾科技有限公司 Anti-static ceramic-wood composite floor
CN103086498A (en) * 2013-01-30 2013-05-08 广州市大禹环保科技有限公司 Ecological brick for purifying water
CN103467137A (en) * 2013-08-30 2013-12-25 李惠成 Anti-static negative-ion eco-ceramic tile and preparation method thereof
CN103467137B (en) * 2013-08-30 2015-04-15 李惠成 Anti-static negative-ion eco-ceramic tile and preparation method thereof
CN105000865A (en) * 2015-07-08 2015-10-28 福建省晋江市丹豪陶瓷有限公司 Preparation method for large-sized ceramic tile
CN105036704A (en) * 2015-07-30 2015-11-11 李政伟 Wall corner ceramic tile and manufacturing method thereof
CN105064638A (en) * 2015-08-07 2015-11-18 东莞市唯美陶瓷工业园有限公司 Antistatic ceramic tile and manufacturing method thereof
CN105064638B (en) * 2015-08-07 2018-06-22 东莞市唯美陶瓷工业园有限公司 Anti-static ceramic tile and preparation method thereof
CN106082658B (en) * 2016-06-16 2018-09-28 福建冠福实业有限公司 A kind of magnesia glaze of the environment-friendly type of high brightness and its preparation process
CN106082658A (en) * 2016-06-16 2016-11-09 福建冠福实业有限公司 The magnesia glaze of environment-friendly type of a kind of high brightness and preparation technology thereof
CN106430966A (en) * 2016-08-18 2017-02-22 佛山欧神诺陶瓷股份有限公司 Transparent glaze with anti-electrostatic function and preparation method for ceramic tiles of transparent glaze
CN106430966B (en) * 2016-08-18 2019-04-12 佛山欧神诺陶瓷有限公司 A kind of preparation method of clear frit and its ceramic tile with anti-static function
CN108585884A (en) * 2018-05-10 2018-09-28 山西安晟科技发展有限公司 Energy-saving fire proof foamed ceramics glaze Side fascia
CN108585884B (en) * 2018-05-10 2021-07-23 山西安晟科技发展有限公司 Energy-saving fireproof foamed ceramic glazed external wall panel
CN111205069A (en) * 2020-03-09 2020-05-29 上海孚士德建筑科技有限公司 Preparation method of anti-static ceramic tile
CN112321156A (en) * 2020-10-29 2021-02-05 佛山昕通新型材料有限公司 Random color anti-static ceramic tile and preparation method thereof
CN114773033A (en) * 2022-05-07 2022-07-22 福建省德化县宝瑞陶瓷有限公司 Domestic ceramic product of transparent glaze and preparation method thereof
CN114773033B (en) * 2022-05-07 2023-10-20 福建省德化县宝瑞陶瓷有限公司 Daily ceramic product with transparent glaze and preparation method thereof
CN115433003A (en) * 2022-09-05 2022-12-06 罗毕诚 Anti-static ceramic tile and preparation method thereof

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