CN112251298A - 一种超浓缩洗衣液及其稀释液制备方法 - Google Patents
一种超浓缩洗衣液及其稀释液制备方法 Download PDFInfo
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- CN112251298A CN112251298A CN202011141125.8A CN202011141125A CN112251298A CN 112251298 A CN112251298 A CN 112251298A CN 202011141125 A CN202011141125 A CN 202011141125A CN 112251298 A CN112251298 A CN 112251298A
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- Prior art keywords
- laundry detergent
- super
- concentrated laundry
- preparing
- grease ethoxylate
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- 239000003599 detergent Substances 0.000 title claims abstract description 51
- 239000003085 diluting agent Substances 0.000 title claims description 12
- 238000002360 preparation method Methods 0.000 title claims description 11
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- 238000003756 stirring Methods 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 15
- 239000003755 preservative agent Substances 0.000 claims abstract description 15
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- 238000010438 heat treatment Methods 0.000 claims abstract description 12
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 12
- 239000006184 cosolvent Substances 0.000 claims abstract description 11
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 10
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 10
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims abstract description 7
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims abstract description 7
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- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000008103 glucose Substances 0.000 claims abstract description 5
- 229930182470 glycoside Natural products 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 5
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 5
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- -1 alkyl glucoside Chemical class 0.000 claims description 6
- 229940088598 enzyme Drugs 0.000 claims description 6
- 239000002562 thickening agent Substances 0.000 claims description 6
- 239000006260 foam Substances 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 238000007046 ethoxylation reaction Methods 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
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- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical compound C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 claims description 2
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- 108010059892 Cellulase Proteins 0.000 claims description 2
- 102000004882 Lipase Human genes 0.000 claims description 2
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- 108090001060 Lipase Proteins 0.000 claims description 2
- 108091005804 Peptidases Proteins 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
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- 125000000129 anionic group Chemical group 0.000 claims description 2
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 2
- 229940106157 cellulase Drugs 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 150000002338 glycosides Chemical class 0.000 claims description 2
- 239000008233 hard water Substances 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 2
- 235000019421 lipase Nutrition 0.000 claims description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 235000019419 proteases Nutrition 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000001509 sodium citrate Substances 0.000 claims description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 238000006277 sulfonation reaction Methods 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 238000012360 testing method Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
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- 238000005202 decontamination Methods 0.000 description 1
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- 238000013112 stability test Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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Abstract
本发明公开了一种超浓缩洗衣液，液碱4％、十二烷基苯磺酸10％、三乙醇胺3％、C8‑C10烷基糖苷7％、C8异构醇醚10％、改性油脂乙氧化物12％、高碳油脂乙氧化物10％、改性油脂乙氧化物磺酸盐5％、脂肪醇聚氧乙烯醚硫酸钠29％、乙醇2％、甲基异噻唑啉酮1.5％、去离子水6.5％；S1、分别将液碱、十二烷基苯磺酸、异构聚氧乙烯醚、烷基葡糖、改性油脂乙氧基化物磺酸盐SNS‑80、高碳酸油脂乙氧基化物、改性油脂乙氧基化物和助溶剂加入去离子水中，加热搅拌均匀；S2、向步骤S1得到的物料中加入防腐剂，加热搅拌均匀；S1中，搅拌温度为25‑60℃。本发明通过适量阴离子表面活性剂、非离子表面活性剂、中和剂、助溶剂制得一种具有优良洗涤性能的超浓缩洗衣液。
Description
技术领域
本发明涉及洗涤剂技术领域，具体为一种超浓缩洗衣液及其稀释液制备方法。
背景技术
超浓缩洗衣液是指活性成分含量高的液体衣物洗涤剂，不仅具有生产过程节水、减少废物排放的优点，而且有助于减少包装材料，节约成本，便于贮存运输，与普通洗衣液相比具有极高的市场竞争优势，已经成为洗涤剂领域技术创新的主流。其稀释液可以根据市场变化，调整各种参数，灵活应对市场变化。
发明内容
本发明的目的在于提供一种超浓缩洗衣液及其稀释液制备方法，解决了背景技术提出的问题。
为实现上述目的，本发明提供如下技术方案：一种超浓缩洗衣液的制备方法，超浓缩洗衣液按质量百分比计，包括下述原料：异构醇醚5-32％、烷基葡糖苷1-10％、改性油脂乙氧基化物磺酸盐SNS-805-15％、十二烷基苯磺酸1-15％、液碱1-10％、高碳酸油脂乙氧基化物SOE10-30％、改性油脂乙氧基化物10-40％、脂肪醇聚氧乙烯醚硫酸钠10-30％、助溶剂4-10％、防腐剂0-1％、溶剂1-10％和去离子水1-40％。
优选的，改性油脂乙氧基化物磺酸盐SNS-80，其由天然油脂乙氧化再磺化制得，具有很高的水溶性，溶解过程中不产生凝胶相、溶解速度快、耐硬水、泡沫低、有很好的生物降解性。
优选的，高碳酸油脂乙氧基化物SOE，其由天然油脂乙氧化制得，其具有较好的低温流动性和稳定性，较低的泡沫，易于其他非离子、阴离子、两性表面活性剂复配。
优选的，异构醇醚碳链数为C8-C12，其中碳链可为直链或具有支链的碳链，聚氧乙烯的聚合度为n:7-10。
优选的，烷基葡糖苷碳链数为C8-C14，其中碳链可为直链或具有支链的碳链，可以为单一或多种糖苷的混合物。
优选的，所述助溶剂为乙醇、乙二醇、丙三醇中的至少一种。
优选的，所述防腐剂为卡松或者甲基异噻唑啉酮或苯并异噻唑林的单一物或混合物。
优选的，包括下述步骤：
S1、分别将液碱、十二烷基苯磺酸、异构聚氧乙烯醚、烷基葡糖、改性油脂乙氧基化物磺酸盐SNS-80、高碳酸油脂乙氧基化物、改性油脂乙氧基化物和助溶剂加入去离子水中，加热搅拌均匀。
S2、向步骤S1得到的物料中加入防腐剂，加热搅拌均匀。
优选的，所述步骤S1中，搅拌温度为25-60℃；所述步骤S2中，搅拌温度为30-40℃。
一种超浓缩洗衣液稀释液的制备方法，稀释液按照质量百分比计，包括下述原料：超浓缩洗衣液20-50％、酶0.1-0.4％、防腐剂0.1-0.3％、洗涤助剂0.1-1.0％、香精0.1-0.5％、色素0.0001-0.001％和增稠剂0.1-1％。
优选的，所述酶包括脂肪酶、蛋白酶、淀粉酶、纤维素酶的一种或几种的混合物。
优选的，所述防腐剂包括异噻唑林酮、苯并异噻唑林酮的单一物或混合物。
优选的，所述洗涤剂包括柠檬酸钠、低分子量的聚丙烯酸钠或共聚物钠。
优选的，所述增稠剂包括高分子的有机物、无机物。
优选的，S3分别将超浓缩洗衣液、洗涤助剂、香精、防腐剂、色素、增稠剂加入去离子水中，加热搅拌均匀。
优选的，所述步骤S3中，搅拌温度为25-40℃。
与现有技术相比，本发明的有益效果如下：本发明通过适量阴离子表面活性剂、非离子表面活性剂、中和剂、助溶剂制得一种具有优良洗涤性能的超浓缩洗衣液；本发明制得的浓缩洗衣液具有高浓缩倍数，其稀释倍数可达1/4-1/8，在高浓缩倍数下能够保持良好的稳定性，且具有低泡沫、去污能力强的作用，是一种高附加值的浓缩洗衣液产品。其稀释液能够随市场变化添加助剂后，形成各具特色的洗涤产品。
附图说明
图1为本发明去污能力测试图。
具体实施方式
下面参照附图说明，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1
一种超浓缩洗衣液，按质量百分比计，包括下述原料：液碱4％、十二烷基苯磺酸10％、三乙醇胺3％、C8-C10烷基糖苷7％、C8异构醇醚10％、改性油脂乙氧化物12％、高碳油脂乙氧化物10％、改性油脂乙氧化物磺酸盐5％、脂肪醇聚氧乙烯醚硫酸钠29％、乙醇2％、甲基异噻唑啉酮1.5％、去离子水6.5％。
上述超浓缩洗衣液的制备方法，包括下述步骤：
S1、分别将液碱、十二烷基苯磺酸、异构聚氧乙烯醚、烷基葡糖、改性油脂乙氧基化物磺酸盐SNS-80、高碳酸油脂乙氧基化物、改性油脂乙氧基化物和助溶剂加入去离子水中，加热搅拌均匀；
S2、向步骤S1得到的物料中加入防腐剂，加热搅拌均匀；S1中，搅拌温度为25-60℃；所述步骤S2中，搅拌温度为30-40℃。
实施例2
一种超浓缩洗衣液，按质量百分比计，包括下述原料：十二烷基苯磺酸8％、三乙醇胺3％、C8-C10烷基糖苷10％、C8异构醇醚5％、改性油脂乙氧化物16％、高碳油脂乙氧化物13％、改性油脂乙氧化物磺酸盐8％、脂肪醇聚氧乙烯醚硫酸钠20％、甲基异噻唑啉酮1.0％、去离子水14％。
上述超浓缩洗衣液的制备方法，包括下述步骤：
S1、分别将液碱、十二烷基苯磺酸、异构聚氧乙烯醚、烷基葡糖、改性油脂乙氧基化物磺酸盐SNS-80、高碳酸油脂乙氧基化物、改性油脂乙氧基化物和助溶剂加入去离子水中，加热搅拌均匀；
S2、向步骤S1得到的物料中加入防腐剂，加热搅拌均匀；S1中，搅拌温度为25-60℃；所述步骤S2中，搅拌温度为30-40℃。
实施例3
一种浓缩洗衣液稀释液，按质量百分比计，包括下述原料：去离子水70％、超浓缩洗衣液20％、甲基异噻唑啉酮0.12％、香精0.5％、酶0.2％、氯化钠3％超浓缩洗衣液稀释液的制备工艺：在30-40℃，按照次序和质量比加入去离子水、超浓缩洗衣液、甲基异噻唑啉酮、香精、氯化钠、酶对制得的超浓缩洗衣液和稀释液进行检验，结果如下：
(1)稳定性
耐寒稳定性：于(-5±2)℃的冰箱内放置24h，然后取出恢复至室温，观察，以不分层、无沉淀、产品透明不浑浊为合格；耐热稳定性：(40±2)℃的保温箱内房子24h，然后取出恢复至室温，观察，以不分层、无沉淀、产品透明不浑浊为合格。结果如表1所示：
表1稳定性测试结果
(2)去污能力测试:见附图1由此可见：
本发明制得的超浓缩洗衣液不仅相比于常规洗衣液具有更强的去污能力，而且具有高稳定性。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。
Claims (16)
1.一种超浓缩洗衣液的制备方法，其特征在于，超浓缩洗衣液按质量百分比计，包括下述原料：异构醇醚5-32％、烷基葡糖苷1-10％、改性油脂乙氧基化物磺酸盐SNS-805-15％、十二烷基苯磺酸1-15％、液碱1-10％、高碳酸油脂乙氧基化物SOE10-30％、改性油脂乙氧基化物10-40％、脂肪醇聚氧乙烯醚硫酸钠10-30％、助溶剂4-10％、防腐剂0-1％、溶剂1-10％和去离子水1-40％。
2.根据权利要求1所述超浓缩洗衣液的制备方法，其特征在于：改性油脂乙氧基化物磺酸盐SNS-80，其由天然油脂乙氧化再磺化制得，具有很高的水溶性，溶解过程中不产生凝胶相、溶解速度快、耐硬水、泡沫低、有很好的生物降解性。
3.根据权利要求1所述的超浓缩洗衣液的制备方法，其特征在于：高碳酸油脂乙氧基化物SOE，其由天然油脂乙氧化制得，其具有较好的低温流动性和稳定性，较低的泡沫，易于其他非离子、阴离子、两性表面活性剂复配。
4.根据权利要求1所述的超浓缩洗衣液的制备方法，其特征在于：异构醇醚碳链数为C8-C12，其中碳链可为直链或具有支链的碳链，聚氧乙烯的聚合度为n:7-10。
5.根据权利要求1所述的超浓缩洗衣液的制备方法，其特征在于：烷基葡糖苷碳链数为C8-C14，其中碳链可为直链或具有支链的碳链，可以为单一或多种糖苷的混合物。
6.根据权利要求1所述的超浓缩洗衣液的制备方法，其特征在于：所述助溶剂为乙醇、乙二醇、丙三醇中的至少一种。
7.根据权利要求1所述的超浓缩洗衣液，其特征在于：所述防腐剂为卡松或者甲基异噻唑啉酮或苯并异噻唑林的单一物或混合物。
8.一种如权利要求1-7任一项所述的超浓缩洗衣液的制备方法，其特征在于：包括下述步骤：
S1、分别将液碱、十二烷基苯磺酸、异构聚氧乙烯醚、烷基葡糖、改性油脂乙氧基化物磺酸盐SNS-80、高碳酸油脂乙氧基化物、改性油脂乙氧基化物和助溶剂加入去离子水中，加热搅拌均匀；
S2、向步骤S1得到的物料中加入防腐剂，加热搅拌均匀。
9.根据权利要求8所述的超浓缩洗衣液的制备方法，其特征在于：所述步骤S1中，搅拌温度为25-60℃；所述步骤S2中，搅拌温度为30-40℃。
10.一种超浓缩洗衣液稀释液的制备方法，其特征在于：稀释液按照质量百分比计，包括下述原料：超浓缩洗衣液20-50％、酶0.1-0.4％、防腐剂0.1-0.3％、洗涤助剂0.1-1.0％、香精0.1-0.5％、色素0.0001-0.001％和增稠剂0.1-1％。
11.根据权利要求10所述超浓缩洗衣液稀释液的制备方法，其特征在于：所述酶包括脂肪酶、蛋白酶、淀粉酶、纤维素酶的一种或几种的混合物。
12.根据权利要求10所述超浓缩洗衣液稀释液的制备方法，其特征在于：所述洗涤剂包括柠檬酸钠、低分子量的聚丙烯酸钠或共聚物钠。
13.根据权利要求10所述超浓缩洗衣液稀释液的制备方法，其特征在于：所述增稠剂包括高分子的有机物、无机物。
14.根据权利要求10所述超浓缩洗衣液稀释液的制备方法，其特征在于：所述防腐剂包括异噻唑林酮、苯并异噻唑林酮的单一物或混合物。
15.一种如权利要求10-14任一项所述的超浓缩洗衣液稀释液的制备方法，其特征在于，包括下述步骤：S3分别将超浓缩洗衣液、洗涤助剂、香精、防腐剂、色素、增稠剂加入去离子水中，加热搅拌均匀。
16.根据权利要求10-14所述的超浓缩洗衣液稀释液的制备方法，其特征在于，所述步骤S3中，搅拌温度为25-40℃。
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113088407A (zh) * | 2021-03-30 | 2021-07-09 | 中国日用化学研究院有限公司 | 一种含改性油脂基乙氧基化物磺酸盐的洗衣粉及其制备方法 |
| CN117720969A (zh) * | 2023-12-13 | 2024-03-19 | 广东欧蝶兰高新科技日用品有限公司 | 一种运动衣物洗涤使用的洗衣液及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107937171A (zh) * | 2017-11-29 | 2018-04-20 | 黑龙江省科学院高技术研究院 | 一种低泡绿色cip杀菌浓缩型清洗剂 |
| CN109181894A (zh) * | 2018-09-30 | 2019-01-11 | 北京洛娃日化有限公司 | 一种超浓缩洗洁精及制备方法 |
| CN109971561A (zh) * | 2017-12-27 | 2019-07-05 | 北京绿伞化学股份有限公司 | 一种改性油脂阴离子表面活性剂为主的浓缩洗涤剂及其制备方法 |
| CN110331049A (zh) * | 2019-06-24 | 2019-10-15 | 上海发凯化工有限公司 | 含烷基糖苷的表面活性剂组合物及其制备方法 |
| CN111139144A (zh) * | 2019-12-26 | 2020-05-12 | 中国日用化学研究院有限公司 | 一种低温易漂洗超浓缩液体洗涤剂及其制备方法 |
-
2020
- 2020-10-22 CN CN202011141125.8A patent/CN112251298A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107937171A (zh) * | 2017-11-29 | 2018-04-20 | 黑龙江省科学院高技术研究院 | 一种低泡绿色cip杀菌浓缩型清洗剂 |
| CN109971561A (zh) * | 2017-12-27 | 2019-07-05 | 北京绿伞化学股份有限公司 | 一种改性油脂阴离子表面活性剂为主的浓缩洗涤剂及其制备方法 |
| CN109181894A (zh) * | 2018-09-30 | 2019-01-11 | 北京洛娃日化有限公司 | 一种超浓缩洗洁精及制备方法 |
| CN110331049A (zh) * | 2019-06-24 | 2019-10-15 | 上海发凯化工有限公司 | 含烷基糖苷的表面活性剂组合物及其制备方法 |
| CN111139144A (zh) * | 2019-12-26 | 2020-05-12 | 中国日用化学研究院有限公司 | 一种低温易漂洗超浓缩液体洗涤剂及其制备方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113088407A (zh) * | 2021-03-30 | 2021-07-09 | 中国日用化学研究院有限公司 | 一种含改性油脂基乙氧基化物磺酸盐的洗衣粉及其制备方法 |
| CN117720969A (zh) * | 2023-12-13 | 2024-03-19 | 广东欧蝶兰高新科技日用品有限公司 | 一种运动衣物洗涤使用的洗衣液及其制备方法 |
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Application publication date: 20210122 |