CN112209830B - 醋酸乙烯酯的生产方法 - Google Patents

醋酸乙烯酯的生产方法 Download PDF

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Publication number
CN112209830B
CN112209830B CN202011127390.0A CN202011127390A CN112209830B CN 112209830 B CN112209830 B CN 112209830B CN 202011127390 A CN202011127390 A CN 202011127390A CN 112209830 B CN112209830 B CN 112209830B
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China
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tower
ethyl acetate
acetic acid
vinyl acetate
phase
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Chinese (zh)
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CN112209830A (zh
Inventor
张敏华
耿中峰
董贺
龚浩
余英哲
钱胜华
董秀芹
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Tianjin University
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Tianjin University
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Priority to CN202011127390.0A priority Critical patent/CN112209830B/zh
Publication of CN112209830A publication Critical patent/CN112209830A/zh
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Publication of CN112209830B publication Critical patent/CN112209830B/zh
Priority to JP2022576527A priority patent/JP7486847B2/ja
Priority to PCT/CN2021/119874 priority patent/WO2022083396A1/zh
Priority to EP21881815.1A priority patent/EP4144716B1/en
Priority to US18/023,300 priority patent/US11939286B2/en
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/58—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • C07C69/145—Acetic acid esters of monohydroxylic compounds of unsaturated alcohols
    • C07C69/15—Vinyl acetate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN202011127390.0A 2020-10-20 2020-10-20 醋酸乙烯酯的生产方法 Active CN112209830B (zh)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN202011127390.0A CN112209830B (zh) 2020-10-20 2020-10-20 醋酸乙烯酯的生产方法
JP2022576527A JP7486847B2 (ja) 2020-10-20 2021-09-23 エチレンアセタートの製造方法
PCT/CN2021/119874 WO2022083396A1 (zh) 2020-10-20 2021-09-23 醋酸乙烯酯的生产方法
EP21881815.1A EP4144716B1 (en) 2020-10-20 2021-09-23 Method for producing vinyl acetate
US18/023,300 US11939286B2 (en) 2020-10-20 2021-09-23 Method for producing vinyl acetate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011127390.0A CN112209830B (zh) 2020-10-20 2020-10-20 醋酸乙烯酯的生产方法

Publications (2)

Publication Number Publication Date
CN112209830A CN112209830A (zh) 2021-01-12
CN112209830B true CN112209830B (zh) 2021-08-27

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US (1) US11939286B2 (https=)
EP (1) EP4144716B1 (https=)
JP (1) JP7486847B2 (https=)
CN (1) CN112209830B (https=)
WO (1) WO2022083396A1 (https=)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112299989B (zh) * 2020-10-20 2021-08-31 天津大学 醋酸乙烯生产工艺及装置
CN112209830B (zh) * 2020-10-20 2021-08-27 天津大学 醋酸乙烯酯的生产方法
CN113861026B (zh) * 2021-10-29 2022-09-06 天津大学 一种乙炔法合成的醋酸乙烯及醋酸的精制方法
CN117959746A (zh) * 2022-10-25 2024-05-03 中国石油化工股份有限公司 一种醋酸乙烯制备过程中脱除醋酸乙酯的系统及方法
CN115745794B (zh) * 2022-11-16 2023-06-20 天津大学 乙烯法醋酸乙烯生产工艺及装置
CN116651016B (zh) * 2023-06-13 2025-11-21 山东中盛药化设备有限公司 一种用于聚醚醚酮的分离提纯系统及工艺
CN116924877A (zh) * 2023-07-26 2023-10-24 天津大学 醋酸乙烯合成过程循环气精制工艺及装置
CN119751195B (zh) * 2025-03-10 2025-07-01 华东理工大学 一种含密封油的乙烯气体中的乙烯的回收方法和回收装置

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1248855A (en) * 1968-10-25 1971-10-06 Du Pont Purification of vinyl acetate
CN1769259A (zh) * 2004-11-04 2006-05-10 塞拉尼斯化学品欧洲有限公司 制备醋酸乙烯酯的方法
WO2008019873A1 (en) * 2006-08-17 2008-02-21 Celanese Chemicals Europe Gmbh Process for working up vinyl acetate

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3905875A (en) * 1968-05-10 1975-09-16 Bayer Ag Process for the purification of crude liquid vinyl acetate
GB1305367A (https=) * 1970-07-01 1973-01-31
US4897161A (en) * 1989-03-20 1990-01-30 Lloyd Berg Separation of vinyl acetate from ethyl acetate by extractive distillation
DE19825254C1 (de) * 1998-06-05 1999-11-11 Celanese Gmbh Verfahren zur Aufarbeitung von rohem, flüssigem Vinylacetat
CN104718182B (zh) * 2012-08-30 2016-08-31 国际人造丝公司 具有用于预脱水塔的侧线式反应器的乙酸乙烯酯制造方法
CN102936198B (zh) * 2012-10-12 2016-05-25 天津大学 生产醋酸乙烯的方法
CN112209830B (zh) * 2020-10-20 2021-08-27 天津大学 醋酸乙烯酯的生产方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1248855A (en) * 1968-10-25 1971-10-06 Du Pont Purification of vinyl acetate
CN1769259A (zh) * 2004-11-04 2006-05-10 塞拉尼斯化学品欧洲有限公司 制备醋酸乙烯酯的方法
WO2008019873A1 (en) * 2006-08-17 2008-02-21 Celanese Chemicals Europe Gmbh Process for working up vinyl acetate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
醋酸乙烯精馏装置的工艺流程模拟与优化;罗静;《中国优秀硕士学位论文工程科技Ⅰ辑》;20180815;全文 *

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Publication number Publication date
US11939286B2 (en) 2024-03-26
JP7486847B2 (ja) 2024-05-20
JP2023531171A (ja) 2023-07-21
US20230312452A1 (en) 2023-10-05
EP4144716C0 (en) 2025-05-14
CN112209830A (zh) 2021-01-12
EP4144716A1 (en) 2023-03-08
WO2022083396A1 (zh) 2022-04-28
EP4144716B1 (en) 2025-05-14
EP4144716A4 (en) 2024-06-19

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