CN112120025A - Spray type dog repellent and preparation method thereof - Google Patents
Spray type dog repellent and preparation method thereof Download PDFInfo
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- CN112120025A CN112120025A CN202010975125.1A CN202010975125A CN112120025A CN 112120025 A CN112120025 A CN 112120025A CN 202010975125 A CN202010975125 A CN 202010975125A CN 112120025 A CN112120025 A CN 112120025A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/38—Solanaceae [Potato family], e.g. nightshade, tomato, tobacco or chilli pepper
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Abstract
The invention relates to a spray type dog repellent and a preparation method thereof, wherein the dog repellent comprises the following components in parts by mass: 0-10.1 parts of camphor, 2.0-4.1 parts of four-bit muscone, 0-2.3 parts of chili oil, 0-11.3 parts of DMF, 0-9.0 parts of mint oil, 0-3.3 parts of glycerol, 10.0-30.9 parts of ethylene glycol, 0-56.2 parts of ethanol and 0-61.6 parts of isopropanol, wherein the content of the chili oil, the DMF, the mint oil and the glycerol is not 0 at the same time. Compared with the prior art, the dog repellent has a good repelling effect on dogs, can keep a certain distance from infants, dog terrorists and dog prohibition places, and effectively avoids the dogs from injuring the infants or the corresponding articles.
Description
Technical Field
The invention relates to the field of sprays, in particular to a spray type dog repellent and a preparation method thereof.
Background
As more and more people are raising dogs, the dogs are causing more and more inconvenience or injury to them, for example, the dogs sometimes destroy our furniture or defecate in unfavorable occasions. And the number of wandering dogs in cities is increased, the number of dog biting events of the wandering dogs is increased, and a plurality of dog biting children events can be seen even in news. The best way to prevent such events is to drive them apart when they are not intended to be close.
The existing dog expelling method comprises an ultrasonic dog expelling method and the like. The ultrasonic dog-driving method is a method for driving a dog by using the Doppler effect of ultrasonic waves, and also is a method for driving the dog away by using a substance with a special smell by using the characteristic that the smell of the dog is sensitive. However, the ultrasonic dog-driving machine requires a power supply, an ultrasonic generator and the like, so that the cost is high and the use is not very convenient. The dog repelling spray has the characteristics of simple and convenient use, low cost and the like, and is a promising dog repelling method. At present, the main component of the dog repellent is camphor, which has unique aromatic odor, and dogs are sensitive to the odor and can avoid the odor immediately after smelling the odor. But the camphor itself has relatively great harm to human body and environment.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a spray type dog repellent which has a good effect of repelling dogs and has little harm to human bodies and environment and a preparation method thereof.
The purpose of the invention can be realized by the following technical scheme:
in the present invention, it is necessary to reduce or avoid the use of camphor. The four-position muscone is a by-product in the industrial production of artificial musk, namely 4-methylcyclopentadecanone. It is essentially disposed of as waste, as it is not of much practical value. This brings great environmental protection pressure and environmental protection cost to the manufacturing enterprises. If the environment-friendly plastic can be utilized, the environment-friendly plastic can not only solve the environmental protection problem for enterprises, but also bring certain economic benefits for the enterprises. The quandazidone has certain medicinal effect, basically has no harm to human bodies through research, and has unique smell. Based on the situation, the four-digit muscone and the camphor are combined, and the special smells of the two are utilized to achieve the effect of expelling the dog. The amount of camphor can be reduced to some extent by using the tetra-musk ketone. In addition, the synergic action of the four-position muscone and other auxiliary materials can be utilized to enhance the dog expelling effect and reduce the harm to human bodies and the environment, and the specific scheme is as follows:
a spray type dog repellent comprises the following components in parts by mass: 0-10.1 parts of camphor, 2.0-4.1 parts of four-bit muscone, 0-2.3 parts of chili oil, 0-11.3 parts of DMF, 0-9.0 parts of mint oil, 0-3.3 parts of glycerol, 10.0-30.9 parts of ethylene glycol, 0-56.2 parts of ethanol and 0-61.6 parts of isopropanol, wherein the content of the chili oil, the DMF, the mint oil and the glycerol is not 0 at the same time.
Further, the dog repellent comprises the following components in parts by mass: 4-6 parts of camphor, 2.0-4.1 parts of four-bit muscone, 2-2.3 parts of chili oil, 0-11.3 parts of DMF, 2-9.0 parts of peppermint oil, 0-3.3 parts of glycerol, 10.0-30.9 parts of ethylene glycol, 0-56.2 parts of ethanol and 0-61.6 parts of isopropanol.
Further, the dog repellent comprises the following components in parts by mass: 4.5 parts of camphor, 2.3 parts of four-bit muscone, 2.3 parts of chili oil, 8.0 parts of DMF, 9 parts of peppermint oil, 3.3 parts of glycerol, 11.3 parts of ethylene glycol and 56.2 parts of ethanol.
Further, the dog repellent comprises the following components in parts by mass: 6-10.1 parts of camphor, 2.0-4.1 parts of four-bit muscone, 2-2.3 parts of chili oil, 0-11.3 parts of DMF, 1-2.0 parts of peppermint oil, 0-3.3 parts of glycerol, 10.0-30.9 parts of ethylene glycol, 0-56.2 parts of ethanol and 0-61.6 parts of isopropanol.
Further, the dog repellent comprises the following components in parts by mass: 10.1 parts of camphor, 2.0 parts of four-bit muscone, 2.0 parts of chili oil, 2.0 parts of peppermint oil, 3.0 parts of glycerol, 30.3 parts of ethylene glycol and 50.5 parts of ethanol.
A method of preparing a spray-type dog repellent as described above, the method comprising the steps of:
(1) one or more of ethanol, isopropanol or ethylene glycol are put into a container according to the parts by mass and stirred;
(2) according to the parts by mass, adding the four-position muscone under the stirring state;
(3) adding one or more of chili oil, DMF, peppermint oil or glycerol according to parts by mass under the stirring state;
(4) stirring to obtain spray type dog repellent;
(5) the obtained spray type dog repellent is filled into spray bottle for use.
Further, camphor is added in the step (1) according to the mass portion.
Further, the camphor is powder with 100-200 meshes.
Further, the stirring time in the step (1) is 25-35 min.
Further, the stirring time in the step (4) is 40-60 min.
Compared with the prior art, the dog repellent has a good repelling effect on dogs, can keep a certain distance from infants, dog terrorists and dog prohibition places, and effectively avoids the dogs from injuring the infants or the corresponding articles.
Drawings
FIG. 1 is a graph of the effect of camphor content on dog repelling effect;
FIG. 2 is a graph of the effect of muscone content on dog repelling effect;
FIG. 3 is a graph showing the effect of capsicum oil content on dog repelling effect;
figure 4 is a graph of the effect of peppermint oil content on dog repelling.
Detailed Description
The influence curves of camphor, muscone, capsicol and peppermint oil on dog expelling effect are shown in figures 1-4, wherein the rest is solvent except for effective components.
As can be analyzed from fig. 1, although the increase of the camphor content can improve the dog repelling effect, the increase effect reaches a bottleneck when the content reaches about 10%, and at this time, only 9 levels of dog repelling effect are obtained, and it is known that when the camphor content exceeds 10.1%, a strong uncomfortable feeling is generated to a human body or an animal, and even a small animal is killed, which means that, from the viewpoint of health benefits, if the camphor content is about 10%, the dog repelling effect is at most 9 levels, and if the camphor content is about 5%, the dog repelling effect is at most 7 levels. Similarly, as shown in fig. 2, although the increase of the content of the muscone can improve the dog-driving effect, the increase effect reaches the bottleneck when the content reaches about 8%, at the moment, only 9-grade dog-driving effect is achieved, and more remarkably, the increase of the dog-driving effect is obvious when the content of the muscone is increased from 1% to 2%, so that the content of the muscone is mainly 2.0-4.1%, and is better at 2%, and excessive increase is not needed. Then, as shown in fig. 3-4, with the content of the capsicum oil or the peppermint oil increasing to about 10%, the dog repelling effect can only reach 5 levels, and the improving effect is not obvious.
The invention can reduce the using amount of camphor to a certain extent by using a small amount of four-digit muscone. In addition, the synergistic effect of the four-digit muscone and the capsicum oil or the peppermint oil can be utilized to enhance the dog expelling effect, and the dog expelling effect can be stably improved to 9-10 grade when the mass content of the four-digit muscone is 2.0-4.1% under the condition that the using amount of camphor is not more than 10.1%, and the human body and the environment are not harmed.
The invention is described in detail below with reference to the figures and specific embodiments.
Example 1
A method for preparing a spray-type dog repellent, the method comprising the steps of:
(1) 1.0g of camphor (5.2%) was thoroughly ground to 100 mesh.
(2) The milled camphor was added to a beaker with 11.8g isopropanol (61.6%) with rapid stirring and stirring was continued for 30 minutes.
(3) 0.745g of tetra musk ketone (3.9%) was added to the beaker with rapid stirring.
(4) 5.6g of ethylene glycol (29.3%) were added to the beaker with rapid stirring and stirring was continued for 40 minutes.
(5) The prepared dog repellent is filled into a spray bottle for use.
Example 2
A method for preparing a spray-type dog repellent, the method comprising the steps of:
(1) 4.8g of isopropanol (57.4%) were added to the beaker and stirred.
(2) 2.58g of ethylene glycol (30.9%) was added to the beaker with rapid stirring.
(3) 0.34g of quadtyridone (4.1%) was added to a beaker containing the mixed solvent with rapid stirring.
(4) 0.18g peppermint oil (2.2%) was added to the beaker with rapid stirring. Finally, 0.46g of glycerol (5.5%) was added and stirring was continued for 50 minutes at ambient temperature.
(5) The prepared dog repellent is filled into a spray bottle for use.
Comparative example 1
The difference from example 2 is that, in step (1), 1.64g of camphor was added so that the mass content thereof became 16.4%.
Example 3
A method for preparing a spray-type dog repellent, the method comprising the steps of:
(1) 1.0g of camphor (10.1%) was thoroughly ground to 150 mesh.
(2) The ground camphor was added to a beaker with 5g ethanol (50.5%) with rapid stirring and stirring was continued for 30 minutes.
(3) 0.2g of quadtree muscone (2.0%) was added to the beaker with rapid stirring.
(4) To the beaker was added 3g of ethylene glycol (30.3%) with stirring.
(5) 0.2g peppermint oil (2.0%) was added to the beaker with rapid stirring.
(6) To the beaker were added 0.2g of chili oil (2.0%), 0.3g of glycerin (3.0%) in that order with stirring, and stirring was continued for 40 minutes.
(7) The prepared dog repellent is filled into a spray bottle for use.
Example 4
A method for preparing a spray-type dog repellent, the method comprising the steps of:
(1) 0.45g of camphor (4.5%) was thoroughly ground to 200 mesh.
(2) The milled camphor was added to a beaker with 5.62g ethanol (56.2%) with rapid stirring and stirring was continued for an additional 30 minutes.
(4) 0.225g of tetra musk ketone (2.3%) was added to the beaker with rapid stirring.
(5) To the beaker was added 11.25g of ethylene glycol (11.3%) with rapid stirring.
(6) 0.9g peppermint oil (9.0%) was added to the beaker with rapid stirring.
(7) 0.225g of capsicum oil (2.3%), 0.33g of glycerol (3.3%), 1.125g of DMF (11.3%) were added to the beaker in this order with stirring. Then, stirring was continued for 60 minutes
(8) The prepared dog repellent is filled into a spray bottle for use.
Example 5
A method for preparing a spray-type dog repellent, the method comprising the steps of:
(1) 0.45g of camphor (4.5%) was thoroughly ground to 200 mesh.
(2) The milled camphor was added to a beaker with 5.62g ethanol (56.2%) with rapid stirring and stirring was continued for an additional 30 minutes.
(3) 0.23g of quadtetrakis muscone (2.3%) by mass are added to the beaker with rapid stirring.
(4) 0.73g of isopropanol (7.3%) and 1.13g of ethylene glycol (11.3%) were added to the beaker in succession with stirring.
(5) 0.68g of peppermint oil (6.8%), 0.11g of chili oil (1.1%), 0.25g of glycerol (2.5%), 0.8g of DMF (8.0%) were added to the beaker in this order with rapid stirring.
(6) Stirring was continued for 40 minutes.
(7) The prepared dog repellent is filled into a spray bottle for use.
Example 6
A method for preparing a spray-type dog repellent, the method comprising the steps of:
(1) 0.6g of camphor (6%) was thoroughly ground to 200 mesh.
(2) The ground camphor was added to a beaker containing 5.0g ethanol (50.0%) with rapid stirring and stirring was continued for 30 minutes.
(3) 0.3g of quadtree muscone (3.0%) was added to the beaker with rapid stirring.
(4) 1.9g of isopropanol (19%) and 1.0g of ethylene glycol (10.0%) were added successively with stirring.
(5) 0.2g peppermint oil (2%), 0.2g chili oil (2.0%), 0.3g glycerin (3.0%) and 0.5g DMF (5.0%) were added to the beaker in this order with rapid stirring.
(6) Stirring was continued for 40 minutes.
(7) The prepared dog repellent is filled into a spray bottle for use.
To evaluate the effectiveness of the dog repellent, the dog was sprayed 2-3 times with the wind in the same direction within 0.5-1.5 m from the dog, and the reaction was observed.
According to the reaction of the dog, the dog repelling effect of the dog repelling agent is divided into 10 grades which are gradually increased from 1 grade to 10 grades,
level 1: the dogs did not respond to the reaction and,
and 2, stage: the dogs had hardly any reaction and had no adverse effect,
and 3, level: has certain dog expelling effect, the dog has aversion to feeling and moves the position,
4, level: dogs have increased aversion and will be 5-10 meters away from the site.
And 5, stage: dogs, which showed a strong aversion, were immediately 10-20 meters away from the site,
and 6, level: dogs have a strong aversive response and will turn around to escape 20-30 meters.
And 7, stage: the aversion of dogs continues to increase and sneezing may occur, rapidly escaping to 30-50 meters.
And 8, stage: dogs exhibit a strong aversion to the dog, and, with sneezing, rapidly escape 50-80 meters,
and 9, stage: the dog showed a strong aversion to the stomach, with sneezing, rapidly escaped to over 80 meters,
10 level: the body turns to escape, and the body rapidly escapes from the sight along with sneezing.
TABLE 1 evaluation of dog repelling Effect of examples 1-6 and comparative example 1
The foregoing is directed to preferred embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow. However, any simple modification, equivalent change and modification of the above embodiments according to the technical essence of the present invention are within the protection scope of the technical solution of the present invention.
Claims (10)
1. The spray type dog repellent is characterized by comprising the following components in parts by mass: 0-10.1 parts of camphor, 2.0-4.1 parts of four-bit muscone, 0-2.3 parts of chili oil, 0-11.3 parts of DMF, 0-9.0 parts of mint oil, 0-3.3 parts of glycerol, 10.0-30.9 parts of ethylene glycol, 0-56.2 parts of ethanol and 0-61.6 parts of isopropanol, wherein the content of the chili oil, the DMF, the mint oil and the glycerol is not 0 at the same time.
2. The spray type dog repellent according to claim 1, which is characterized by comprising the following components in parts by mass: 4-6 parts of camphor, 2.0-4.1 parts of four-bit muscone, 2-2.3 parts of chili oil, 0-11.3 parts of DMF, 2-9.0 parts of peppermint oil, 0-3.3 parts of glycerol, 10.0-30.9 parts of ethylene glycol, 0-56.2 parts of ethanol and 0-61.6 parts of isopropanol.
3. The spray type dog repellent according to claim 1, which is characterized by comprising the following components in parts by mass: 4.5 parts of camphor, 2.3 parts of four-bit muscone, 2.3 parts of chili oil, 8.0 parts of DMF, 9 parts of peppermint oil, 3.3 parts of glycerol, 11.3 parts of ethylene glycol and 56.2 parts of ethanol.
4. The spray type dog repellent according to claim 1, which is characterized by comprising the following components in parts by mass: 6-10.1 parts of camphor, 2.0-4.1 parts of four-bit muscone, 2-2.3 parts of chili oil, 0-11.3 parts of DMF, 1-2.0 parts of peppermint oil, 0-3.3 parts of glycerol, 10.0-30.9 parts of ethylene glycol, 0-56.2 parts of ethanol and 0-61.6 parts of isopropanol.
5. The spray type dog repellent according to claim 1, which is characterized by comprising the following components in parts by mass: 10.1 parts of camphor, 2.0 parts of four-bit muscone, 2.0 parts of chili oil, 2.0 parts of peppermint oil, 3.0 parts of glycerol, 30.3 parts of ethylene glycol and 50.5 parts of ethanol.
6. A process for preparing the spray-on dog repellent according to claim 1, comprising the steps of:
(1) one or more of ethanol, isopropanol or ethylene glycol are put into a container according to the parts by mass and stirred;
(2) according to the parts by mass, adding the four-position muscone under the stirring state;
(3) adding one or more of chili oil, DMF, peppermint oil or glycerol according to parts by mass under the stirring state;
(4) stirring to obtain spray type dog repellent;
(5) the obtained spray type dog repellent is filled into spray bottle for use.
7. The method for preparing a spray type dog repellent according to claim 6, wherein camphor is added in the step (1) in parts by mass.
8. The method as claimed in claim 7, wherein the camphor is powder of 100-200 mesh.
9. The method for preparing a spray-type dog repellent according to claim 6 or 7, wherein the stirring time in step (1) is 25-35 min.
10. The method for preparing a spray-type dog repellent according to claim 6 or 7, wherein the stirring time in the step (4) is 40-60 min.
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| CN202010975125.1A CN112120025A (en) | 2020-09-16 | 2020-09-16 | Spray type dog repellent and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03170403A (en) * | 1989-11-29 | 1991-07-24 | Shiseido Co Ltd | Animal repellent |
| CN103004895A (en) * | 2012-12-25 | 2013-04-03 | 杨继新 | Dog repellent and preparation method thereof |
| CN103891791A (en) * | 2012-12-31 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Pet repellent |
| CN108633871A (en) * | 2018-07-25 | 2018-10-12 | 胥开理 | Drive dog baste |
-
2020
- 2020-09-16 CN CN202010975125.1A patent/CN112120025A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03170403A (en) * | 1989-11-29 | 1991-07-24 | Shiseido Co Ltd | Animal repellent |
| CN103004895A (en) * | 2012-12-25 | 2013-04-03 | 杨继新 | Dog repellent and preparation method thereof |
| CN103891791A (en) * | 2012-12-31 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Pet repellent |
| CN108633871A (en) * | 2018-07-25 | 2018-10-12 | 胥开理 | Drive dog baste |
Non-Patent Citations (1)
| Title |
|---|
| 张玲 等: "dl-麝香酮与异构体4-甲基环十五烷酮检定方法的研究", 《齐鲁药事》 * |
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