CN112095346A - Softening agent for yarns - Google Patents

Softening agent for yarns Download PDF

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Publication number
CN112095346A
CN112095346A CN202011093568.4A CN202011093568A CN112095346A CN 112095346 A CN112095346 A CN 112095346A CN 202011093568 A CN202011093568 A CN 202011093568A CN 112095346 A CN112095346 A CN 112095346A
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CN
China
Prior art keywords
parts
glass fiber
yarn
water
mixing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011093568.4A
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Chinese (zh)
Inventor
王道印
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanxian Avenue Glass Fiber Co ltd
Original Assignee
Shanxian Avenue Glass Fiber Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanxian Avenue Glass Fiber Co ltd filed Critical Shanxian Avenue Glass Fiber Co ltd
Priority to CN202011093568.4A priority Critical patent/CN112095346A/en
Priority to PCT/CN2020/126813 priority patent/WO2022077644A1/en
Publication of CN112095346A publication Critical patent/CN112095346A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55Epoxy resins
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Woven Fabrics (AREA)

Abstract

The invention discloses a softening agent for yarns, which relates to the field of glass fiber mesh cloth and is prepared from the following raw materials in parts by weight: 1.5-2.5 parts of peregal, 0.7-1 part of stearic acid, 5-6 parts of white oil, 3-4.5 parts of a color fixing agent, 6812-3 parts of epoxy resin, SR-11-2 parts of polyester resin and 80-90 parts of water; the invention selects peregal, stearic acid, white oil, color fixing agent, epoxy resin 681, polyester resin SR-1, water as main raw materials, the raw materials selected are few, the proportion is simple, the softening agent is used for softening the glass fiber alkali-free yarn and medium-alkali yarn, the fiber yarn produced can replace 98% starch yarn, 100% paraffin type yarn, and the tensile resistance of the yarn produced is 2 times of starch yarn and paraffin type yarn, the tensile resistance is strong, the application range is wide, can be matched with high-speed rapier loom and air jet loom, can help the glass fiber weaving enterprises to eliminate the ordinary rapier loom and upgrade and change the type.

Description

Softening agent for yarns
Technical Field
The invention relates to the field of glass fiber mesh cloth, in particular to a softening agent for yarns.
Background
At present, in the glass fiber textile industry, the produced glass fiber alkali-free yarns and medium-alkali yarns can not replace starch yarns and paraffin type yarns, the tensile resistance of the starch yarns and the paraffin type yarns is weak, the application range of the glass fiber alkali-free yarns and medium-alkali yarns is narrow, the glass fiber alkali-free yarns and the medium-alkali yarns can not be matched with a high-speed rapier loom and an air jet loom for use, and the glass fiber textile enterprises can not be helped to eliminate common rapier looms so as to upgrade and change types.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: the softening agent for the yarns solves the problems that the existing glass fiber alkali-free yarns and medium alkali yarns can not replace starch yarns and paraffin type yarns, the application range of the glass fiber alkali-free yarns and medium alkali yarns is narrow, the glass fiber alkali-free yarns and medium alkali yarns can not be matched with a high-speed rapier loom and an air jet loom for use, and the glass fiber weaving enterprises can not be helped to eliminate common rapier looms so as to upgrade and transform.
The technical scheme adopted by the invention for solving the problems is as follows:
a softening agent for yarns, characterized in that: the feed is prepared from the following raw materials in parts by weight:
1.5-2.5 parts of peregal, 0.7-1 part of stearic acid, 5-6 parts of white oil, 3-4.5 parts of a color fixing agent, 6812-3 parts of epoxy resin, SR-11-2 parts of polyester resin and 80-90 parts of water;
the preparation method comprises the following steps:
(1) adding peregal, stearic acid and white oil into a reaction kettle, heating to 95-96 ℃, preserving heat, mixing for 30min, and mixing uniformly to obtain a material I;
(2) independently heating the color fixing agent, the epoxy resin 681 and the polyester resin SR-1 to 55-60 ℃, sequentially adding the color fixing agent, the epoxy resin 681 and the polyester resin SR-1 into the material I prepared in the step 1, mixing for 25min, and uniformly mixing to obtain a material II;
(3) heating 10-15 parts of water to 95-100 ℃, adding the heated water into the material II prepared in the step (2), mixing for 10min, and uniformly mixing to obtain a material III;
(4) adding the rest water into the material III prepared in the step 3, mixing for 5min, and uniformly mixing to obtain a softening agent;
the water is deionized water, so that impurities in the water are prevented from affecting the quality of the softening agent;
the water temperature in the step 4 is normal temperature, so that the production cost of the softener is reduced;
and (4) adding the softening agent prepared in the step (4) into an infiltration groove on a wire drawing machine, infiltrating the glass fiber drawn out from the wire drawing furnace by the softening agent in the infiltration groove, winding the drawn glass fiber on a wire drawing cylinder by a winding machine, twisting the glass fiber on the wire drawing cylinder into glass fiber wires by a twisting machine, and weaving the glass fiber wires into glass fiber mesh cloth by a weaving machine.
The invention has the beneficial effects that: the invention selects peregal, stearic acid, white oil, color fixing agent, epoxy resin 681, polyester resin SR-1, water as main raw materials, the raw materials selected are few, the proportion is simple, the softening agent is used for softening the glass fiber alkali-free yarn and medium-alkali yarn, the fiber yarn produced can replace 98% starch yarn, 100% paraffin type yarn, and the tensile resistance of the yarn produced is 2 times of starch yarn and paraffin type yarn, the tensile resistance is strong, the application range is wide, can be matched with high-speed rapier loom and air jet loom, can help the glass fiber weaving enterprises to eliminate the ordinary rapier loom and upgrade and change the type.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. The specific embodiments described herein are merely illustrative of the invention and do not delimit the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
a softening agent for yarns, characterized in that: the feed is prepared from the following raw materials in parts by weight:
1.5 parts of peregal, 0.7 part of stearic acid, 5 parts of white oil, 3 parts of a color fixing agent, 6812 parts of epoxy resin, SR-11 parts of polyester resin and 80 parts of water;
the preparation method comprises the following steps:
(1) adding peregal, stearic acid and white oil into a reaction kettle, heating to 95-96 ℃, preserving heat, mixing for 30min, and mixing uniformly to obtain a material I;
(2) independently heating the color fixing agent, the epoxy resin 681 and the polyester resin SR-1 to 55-60 ℃, sequentially adding the color fixing agent, the epoxy resin 681 and the polyester resin SR-1 into the material I prepared in the step 1, mixing for 25min, and uniformly mixing to obtain a material II;
(3) heating 10 parts of water to 95-100 ℃, adding the heated water into the material II prepared in the step (2), mixing for 10min, and uniformly mixing to obtain a material III;
(4) adding the rest water into the material III prepared in the step 3, mixing for 5min, and uniformly mixing to obtain a softening agent;
the water is deionized water, so that impurities in the water are prevented from affecting the quality of the softening agent;
the water temperature in the step 4 is normal temperature, so that the production cost of the softener is reduced;
and (4) adding the softening agent prepared in the step (4) into an infiltration groove on a wire drawing machine, infiltrating the glass fiber drawn out from the wire drawing furnace by the softening agent in the infiltration groove, winding the drawn glass fiber on a wire drawing cylinder by a winding machine, twisting the glass fiber on the wire drawing cylinder into glass fiber wires by a twisting machine, and weaving the glass fiber wires into glass fiber mesh cloth by a weaving machine.
Example 2:
a softening agent for yarns, characterized in that: the feed is prepared from the following raw materials in parts by weight:
2 parts of peregal, 0.8 part of stearic acid, 5.5 parts of white oil, 4 parts of a color fixing agent, 6812.5 parts of epoxy resin, SR-11.5 parts of polyester resin and 85 parts of water;
the preparation method comprises the following steps:
(1) adding peregal, stearic acid and white oil into a reaction kettle, heating to 95-96 ℃, preserving heat, mixing for 30min, and mixing uniformly to obtain a material I;
(2) independently heating the color fixing agent, the epoxy resin 681 and the polyester resin SR-1 to 55-60 ℃, sequentially adding the color fixing agent, the epoxy resin 681 and the polyester resin SR-1 into the material I prepared in the step 1, mixing for 25min, and uniformly mixing to obtain a material II;
(3) heating 12 parts of water to 95-100 ℃, adding the heated water into the material II prepared in the step (2), mixing for 10min, and uniformly mixing to obtain a material III;
(4) adding the rest water into the material III prepared in the step 3, mixing for 5min, and uniformly mixing to obtain a softening agent;
the water is deionized water, so that impurities in the water are prevented from affecting the quality of the softening agent;
the water temperature in the step 4 is normal temperature, so that the production cost of the softener is reduced;
and (4) adding the softening agent prepared in the step (4) into an infiltration groove on a wire drawing machine, infiltrating the glass fiber drawn out from the wire drawing furnace by the softening agent in the infiltration groove, winding the drawn glass fiber on a wire drawing cylinder by a winding machine, twisting the glass fiber on the wire drawing cylinder into glass fiber wires by a twisting machine, and weaving the glass fiber wires into glass fiber mesh cloth by a weaving machine.
Example 3:
a softening agent for yarns, characterized in that: the feed is prepared from the following raw materials in parts by weight:
2.5 parts of peregal, 1 part of stearic acid, 6 parts of white oil, 4.5 parts of a color fixing agent, 6813 parts of epoxy resin, SR-12 parts of polyester resin and 90 parts of water;
the preparation method comprises the following steps:
(1) adding peregal, stearic acid and white oil into a reaction kettle, heating to 95-96 ℃, preserving heat, mixing for 30min, and mixing uniformly to obtain a material I;
(2) independently heating the color fixing agent, the epoxy resin 681 and the polyester resin SR-1 to 55-60 ℃, sequentially adding the color fixing agent, the epoxy resin 681 and the polyester resin SR-1 into the material I prepared in the step 1, mixing for 25min, and uniformly mixing to obtain a material II;
(3) heating 15 parts of water to 95-100 ℃, adding the heated water into the material II prepared in the step (2), mixing for 10min, and uniformly mixing to obtain a material III;
(4) adding the rest water into the material III prepared in the step 3, mixing for 5min, and uniformly mixing to obtain a softening agent;
the water is deionized water, so that impurities in the water are prevented from affecting the quality of the softening agent;
the water temperature in the step 4 is normal temperature, so that the production cost of the softener is reduced;
and (4) adding the softening agent prepared in the step (4) into an infiltration groove on a wire drawing machine, infiltrating the glass fiber drawn out from the wire drawing furnace by the softening agent in the infiltration groove, winding the drawn glass fiber on a wire drawing cylinder by a winding machine, twisting the glass fiber on the wire drawing cylinder into glass fiber wires by a twisting machine, and weaving the glass fiber wires into glass fiber mesh cloth by a weaving machine.
Similarly, it should be appreciated that in the foregoing description of exemplary embodiments of the invention, for the purposes of streamlining the disclosure and aiding in the understanding of one or more of the various inventive aspects, however, the disclosed method should not be construed as reflecting the intent: that the invention as claimed requires more features than are expressly recited in each claim. Rather, as the following claims reflect, inventive aspects lie in less than all features of a single foregoing disclosed embodiment. Thus, the claims following the detailed description are hereby expressly incorporated into this detailed description, with each claim standing on its own as a separate embodiment of this invention.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments or portions thereof without departing from the spirit and scope of the invention.

Claims (4)

1. A softening agent for yarns, characterized in that: the feed is prepared from the following raw materials in parts by weight:
1.5-2.5 parts of peregal, 0.7-1 part of stearic acid, 5-6 parts of white oil, 3-4.5 parts of a color fixing agent, 6812-3 parts of epoxy resin, SR-11-2 parts of polyester resin and 80-90 parts of water;
the preparation method comprises the following steps:
(1) adding peregal, stearic acid and white oil into a reaction kettle, heating to 95-96 ℃, preserving heat, mixing for 30min, and mixing uniformly to obtain a material I;
(2) independently heating the color fixing agent, the epoxy resin 681 and the polyester resin SR-1 to 55-60 ℃, sequentially adding the color fixing agent, the epoxy resin 681 and the polyester resin SR-1 into the material I prepared in the step 1, mixing for 25min, and uniformly mixing to obtain a material II;
(3) heating 10-15 parts of water to 95-100 ℃, adding the heated water into the material II prepared in the step (2), mixing for 10min, and uniformly mixing to obtain a material III;
(4) and (4) adding the rest water into the material III prepared in the step (3), mixing for 5min, and uniformly mixing to obtain the softener.
2. A yarn softener according to claim 1, wherein: the water is deionized water.
3. A yarn softener according to claim 1, wherein: the water temperature in the step 4 is normal temperature.
4. A method of making a yarn softener according to claim 3, characterized by:
and (4) adding the softening agent prepared in the step (4) into an infiltration groove on a wire drawing machine, infiltrating the glass fiber drawn out from the wire drawing furnace by the softening agent in the infiltration groove, winding the drawn glass fiber on a wire drawing cylinder by a winding machine, twisting the glass fiber on the wire drawing cylinder into glass fiber wires by a twisting machine, and weaving the glass fiber wires into glass fiber mesh cloth by a weaving machine.
CN202011093568.4A 2020-10-14 2020-10-14 Softening agent for yarns Pending CN112095346A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202011093568.4A CN112095346A (en) 2020-10-14 2020-10-14 Softening agent for yarns
PCT/CN2020/126813 WO2022077644A1 (en) 2020-10-14 2020-11-05 Softening agent for yarn

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011093568.4A CN112095346A (en) 2020-10-14 2020-10-14 Softening agent for yarns

Publications (1)

Publication Number Publication Date
CN112095346A true CN112095346A (en) 2020-12-18

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Country Status (2)

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CN (1) CN112095346A (en)
WO (1) WO2022077644A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114605091A (en) * 2022-04-27 2022-06-10 单县大道玻纤有限公司 Glass fiber impregnating compound

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009091176A (en) * 2007-10-04 2009-04-30 Nitto Boseki Co Ltd Epoxy resin-containing binder for glass fiber
WO2009062137A1 (en) * 2007-11-08 2009-05-14 Ppg Industries Ohio, Inc. Sizing composition for glass fibers, sized glass fibers, and reinforced products comprising the same
CN102603213A (en) * 2011-12-06 2012-07-25 巨石攀登电子基材有限公司 Formula and production method of impregnating agent for low-cost electronic-grade glass fiber yarns
CN107601923A (en) * 2017-10-31 2018-01-19 安徽丹凤电子材料股份有限公司 A kind of high-performance glass fiber size and preparation method thereof
CN109279789A (en) * 2018-10-18 2019-01-29 山东兴国大成特种纤维科技有限公司 A kind of electronics cloth warp thread sizing agent special and its preparation process
CN110885198A (en) * 2019-11-23 2020-03-17 单县大道玻纤有限公司 Medium-alkali wax-free glass fiber yarn

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101503280B (en) * 2009-03-06 2011-05-18 陕西科技大学 Inorfil softening intensifier and preparation thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009091176A (en) * 2007-10-04 2009-04-30 Nitto Boseki Co Ltd Epoxy resin-containing binder for glass fiber
WO2009062137A1 (en) * 2007-11-08 2009-05-14 Ppg Industries Ohio, Inc. Sizing composition for glass fibers, sized glass fibers, and reinforced products comprising the same
CN102603213A (en) * 2011-12-06 2012-07-25 巨石攀登电子基材有限公司 Formula and production method of impregnating agent for low-cost electronic-grade glass fiber yarns
CN107601923A (en) * 2017-10-31 2018-01-19 安徽丹凤电子材料股份有限公司 A kind of high-performance glass fiber size and preparation method thereof
CN109279789A (en) * 2018-10-18 2019-01-29 山东兴国大成特种纤维科技有限公司 A kind of electronics cloth warp thread sizing agent special and its preparation process
CN110885198A (en) * 2019-11-23 2020-03-17 单县大道玻纤有限公司 Medium-alkali wax-free glass fiber yarn

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114605091A (en) * 2022-04-27 2022-06-10 单县大道玻纤有限公司 Glass fiber impregnating compound
CN114605091B (en) * 2022-04-27 2024-04-19 单县大道玻纤有限公司 Glass fiber impregnating compound

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Application publication date: 20201218