CN112074555B - 水性涂料组合物 - Google Patents
水性涂料组合物 Download PDFInfo
- Publication number
- CN112074555B CN112074555B CN201880093187.0A CN201880093187A CN112074555B CN 112074555 B CN112074555 B CN 112074555B CN 201880093187 A CN201880093187 A CN 201880093187A CN 112074555 B CN112074555 B CN 112074555B
- Authority
- CN
- China
- Prior art keywords
- coating composition
- aqueous coating
- weight
- solids
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000008199 coating composition Substances 0.000 title claims abstract description 103
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 43
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 43
- 239000004815 dispersion polymer Substances 0.000 claims abstract description 20
- 239000007787 solid Substances 0.000 claims description 85
- -1 2-ethoxyethyl toluate Chemical compound 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 44
- 239000002904 solvent Substances 0.000 claims description 31
- 239000006224 matting agent Substances 0.000 claims description 28
- 229920000058 polyacrylate Polymers 0.000 claims description 28
- 229920002635 polyurethane Polymers 0.000 claims description 21
- 239000004814 polyurethane Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000006185 dispersion Substances 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 13
- 239000002562 thickening agent Substances 0.000 claims description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 229920003009 polyurethane dispersion Polymers 0.000 claims description 9
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 239000003607 modifier Substances 0.000 claims description 7
- 239000000049 pigment Substances 0.000 claims description 7
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 5
- 229920001519 homopolymer Polymers 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- NMBQBIACXMPEQB-UHFFFAOYSA-N 2-butoxyethyl benzoate Chemical compound CCCCOCCOC(=O)C1=CC=CC=C1 NMBQBIACXMPEQB-UHFFFAOYSA-N 0.000 claims description 3
- OALFAAFIQJBHRZ-UHFFFAOYSA-N 2-propoxyethyl benzoate Chemical compound CCCOCCOC(=O)C1=CC=CC=C1 OALFAAFIQJBHRZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000010985 leather Substances 0.000 abstract description 28
- 239000000178 monomer Substances 0.000 description 24
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 22
- 229920005862 polyol Polymers 0.000 description 18
- 150000003077 polyols Chemical class 0.000 description 17
- 239000000126 substance Substances 0.000 description 15
- BHXIWUJLHYHGSJ-UHFFFAOYSA-N ethyl 3-ethoxypropanoate Chemical compound CCOCCC(=O)OCC BHXIWUJLHYHGSJ-UHFFFAOYSA-N 0.000 description 14
- 239000012948 isocyanate Substances 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 239000012855 volatile organic compound Substances 0.000 description 10
- 239000004971 Cross linker Substances 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 238000007720 emulsion polymerization reaction Methods 0.000 description 8
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 7
- 229920002125 Sokalan® Polymers 0.000 description 7
- UYAAVKFHBMJOJZ-UHFFFAOYSA-N diimidazo[1,3-b:1',3'-e]pyrazine-5,10-dione Chemical compound O=C1C2=CN=CN2C(=O)C2=CN=CN12 UYAAVKFHBMJOJZ-UHFFFAOYSA-N 0.000 description 7
- 229940116423 propylene glycol diacetate Drugs 0.000 description 7
- 239000004721 Polyphenylene oxide Substances 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229920005906 polyester polyol Polymers 0.000 description 6
- 229920000570 polyether Polymers 0.000 description 6
- 235000002639 sodium chloride Nutrition 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 239000004606 Fillers/Extenders Substances 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 150000002009 diols Chemical class 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 239000005058 Isophorone diisocyanate Substances 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 238000000113 differential scanning calorimetry Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 229920002396 Polyurea Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 238000007655 standard test method Methods 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- OINMNSFDYTYXEQ-UHFFFAOYSA-M 2-bromoethyl(trimethyl)azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCBr OINMNSFDYTYXEQ-UHFFFAOYSA-M 0.000 description 2
- QENRKQYUEGJNNZ-UHFFFAOYSA-N 2-methyl-1-(prop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(C)C(S(O)(=O)=O)NC(=O)C=C QENRKQYUEGJNNZ-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000001530 fumaric acid Chemical class 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 2
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000002649 leather substitute Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 2
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 150000003673 urethanes Chemical class 0.000 description 2
- 125000000391 vinyl group Chemical class [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- DJKGDNKYTKCJKD-BPOCMEKLSA-N (1s,4r,5s,6r)-1,2,3,4,7,7-hexachlorobicyclo[2.2.1]hept-2-ene-5,6-dicarboxylic acid Chemical compound ClC1=C(Cl)[C@]2(Cl)[C@H](C(=O)O)[C@H](C(O)=O)[C@@]1(Cl)C2(Cl)Cl DJKGDNKYTKCJKD-BPOCMEKLSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N -2,3-Dihydroxypropanoic acid Natural products OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 1
- XSCLFFBWRKTMTE-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1CCCC(CN=C=O)C1 XSCLFFBWRKTMTE-UHFFFAOYSA-N 0.000 description 1
- AGJCSCSSMFRMFQ-UHFFFAOYSA-N 1,4-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=C(C(C)(C)N=C=O)C=C1 AGJCSCSSMFRMFQ-UHFFFAOYSA-N 0.000 description 1
- OHLKMGYGBHFODF-UHFFFAOYSA-N 1,4-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=C(CN=C=O)C=C1 OHLKMGYGBHFODF-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- FWWWRCRHNMOYQY-UHFFFAOYSA-N 1,5-diisocyanato-2,4-dimethylbenzene Chemical compound CC1=CC(C)=C(N=C=O)C=C1N=C=O FWWWRCRHNMOYQY-UHFFFAOYSA-N 0.000 description 1
- QGLRLXLDMZCFBP-UHFFFAOYSA-N 1,6-diisocyanato-2,4,4-trimethylhexane Chemical compound O=C=NCC(C)CC(C)(C)CCN=C=O QGLRLXLDMZCFBP-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- DDHUNHGZUHZNKB-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diamine Chemical compound NCC(C)(C)CN DDHUNHGZUHZNKB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
- BPGIOCZAQDIBPI-UHFFFAOYSA-N 2-ethoxyethanamine Chemical compound CCOCCN BPGIOCZAQDIBPI-UHFFFAOYSA-N 0.000 description 1
- DETXZQGDWUJKMO-UHFFFAOYSA-N 2-hydroxymethanesulfonic acid Chemical compound OCS(O)(=O)=O DETXZQGDWUJKMO-UHFFFAOYSA-N 0.000 description 1
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 description 1
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 1
- IBZKBSXREAQDTO-UHFFFAOYSA-N 2-methoxy-n-(2-methoxyethyl)ethanamine Chemical compound COCCNCCOC IBZKBSXREAQDTO-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- YOOSAIJKYCBPFW-UHFFFAOYSA-N 3-[4-(3-aminopropoxy)butoxy]propan-1-amine Chemical compound NCCCOCCCCOCCCN YOOSAIJKYCBPFW-UHFFFAOYSA-N 0.000 description 1
- SOYBEXQHNURCGE-UHFFFAOYSA-N 3-ethoxypropan-1-amine Chemical compound CCOCCCN SOYBEXQHNURCGE-UHFFFAOYSA-N 0.000 description 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 1
- VATRWWPJWVCZTA-UHFFFAOYSA-N 3-oxo-n-[2-(trifluoromethyl)phenyl]butanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C(F)(F)F VATRWWPJWVCZTA-UHFFFAOYSA-N 0.000 description 1
- NYYSPVRERVXMLJ-UHFFFAOYSA-N 4,4-difluorocyclohexan-1-one Chemical compound FC1(F)CCC(=O)CC1 NYYSPVRERVXMLJ-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RBNPOMFGQQGHHO-UWTATZPHSA-N D-glyceric acid Chemical compound OC[C@@H](O)C(O)=O RBNPOMFGQQGHHO-UWTATZPHSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Chemical class 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Chemical class C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- MLHOXUWWKVQEJB-UHFFFAOYSA-N Propyleneglycol diacetate Chemical compound CC(=O)OC(C)COC(C)=O MLHOXUWWKVQEJB-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- KXBFLNPZHXDQLV-UHFFFAOYSA-N [cyclohexyl(diisocyanato)methyl]cyclohexane Chemical compound C1CCCCC1C(N=C=O)(N=C=O)C1CCCCC1 KXBFLNPZHXDQLV-UHFFFAOYSA-N 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-M acetoacetate Chemical compound CC(=O)CC([O-])=O WDJHALXBUFZDSR-UHFFFAOYSA-M 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- LOGBRYZYTBQBTB-UHFFFAOYSA-N butane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(C(O)=O)CC(O)=O LOGBRYZYTBQBTB-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical class CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- MGFFVSDRCRVHLC-UHFFFAOYSA-N butyl 3-sulfanylpropanoate Chemical compound CCCCOC(=O)CCS MGFFVSDRCRVHLC-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Chemical class 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-L dioxidosulfate(2-) Chemical compound [O-]S[O-] HRKQOINLCJTGBK-UHFFFAOYSA-L 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000010350 erythorbic acid Nutrition 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- FZWBABZIGXEXES-UHFFFAOYSA-N ethane-1,2-diol;hexanedioic acid Chemical compound OCCO.OC(=O)CCCCC(O)=O FZWBABZIGXEXES-UHFFFAOYSA-N 0.000 description 1
- ZEYMDLYHRCTNEE-UHFFFAOYSA-N ethenyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OC=C ZEYMDLYHRCTNEE-UHFFFAOYSA-N 0.000 description 1
- 229940012017 ethylenediamine Drugs 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical compound O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-M hydrosulfide Chemical compound [SH-] RWSOTUBLDIXVET-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 229920013819 hydroxyethyl ethylcellulose Polymers 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229940026239 isoascorbic acid Drugs 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical class [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- LDTLDBDUBGAEDT-UHFFFAOYSA-N methyl 3-sulfanylpropanoate Chemical compound COC(=O)CCS LDTLDBDUBGAEDT-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229940113083 morpholine Drugs 0.000 description 1
- UDGSVBYJWHOHNN-UHFFFAOYSA-N n',n'-diethylethane-1,2-diamine Chemical compound CCN(CC)CCN UDGSVBYJWHOHNN-UHFFFAOYSA-N 0.000 description 1
- YRVUCYWJQFRCOB-UHFFFAOYSA-N n-butylprop-2-enamide Chemical compound CCCCNC(=O)C=C YRVUCYWJQFRCOB-UHFFFAOYSA-N 0.000 description 1
- JKZQBSUPPNQHTK-UHFFFAOYSA-N n-ethyl-2-methylideneoctanamide Chemical compound CCCCCCC(=C)C(=O)NCC JKZQBSUPPNQHTK-UHFFFAOYSA-N 0.000 description 1
- SWPMNMYLORDLJE-UHFFFAOYSA-N n-ethylprop-2-enamide Chemical compound CCNC(=O)C=C SWPMNMYLORDLJE-UHFFFAOYSA-N 0.000 description 1
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 1
- QNILTEGFHQSKFF-UHFFFAOYSA-N n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C=C QNILTEGFHQSKFF-UHFFFAOYSA-N 0.000 description 1
- XFHJDMUEHUHAJW-UHFFFAOYSA-N n-tert-butylprop-2-enamide Chemical compound CC(C)(C)NC(=O)C=C XFHJDMUEHUHAJW-UHFFFAOYSA-N 0.000 description 1
- 239000010434 nepheline Substances 0.000 description 1
- 229910052664 nepheline Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920005787 opaque polymer Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- MOOYVEVEDVVKGD-UHFFFAOYSA-N oxaldehydic acid;hydrate Chemical compound O.OC(=O)C=O MOOYVEVEDVVKGD-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000003921 particle size analysis Methods 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-N peroxydisulfuric acid Chemical class OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000002743 phosphorus functional group Chemical group 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- ARJOQCYCJMAIFR-UHFFFAOYSA-N prop-2-enoyl prop-2-enoate Chemical compound C=CC(=O)OC(=O)C=C ARJOQCYCJMAIFR-UHFFFAOYSA-N 0.000 description 1
- AXLMPTNTPOWPLT-UHFFFAOYSA-N prop-2-enyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCC=C AXLMPTNTPOWPLT-UHFFFAOYSA-N 0.000 description 1
- VSVCAMGKPRPGQR-UHFFFAOYSA-N propan-2-one;sulfurous acid Chemical compound CC(C)=O.OS(O)=O VSVCAMGKPRPGQR-UHFFFAOYSA-N 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000010435 syenite Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical group CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920001567 vinyl ester resin Chemical class 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
- C14C11/003—Surface finishing of leather using macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
- C14C11/003—Surface finishing of leather using macromolecular compounds
- C14C11/006—Surface finishing of leather using macromolecular compounds using polymeric products of isocyanates (or isothiocyanates) with compounds having active hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
一种适于制备皮革面漆的水性涂料组合物，其包含水性聚合物分散体、水分散性多异氰酸酯和特定的醚‑酯化合物。与含EEP的涂料组合物相比，所述水性涂料组合物具有更少的气味和更低的VOC含量。所述水性涂料组合物还具有可接受的适用期。
Description
技术领域
本发明涉及水性涂料组合物和其制备方法。
背景技术
更加注重环保意识仍然是汽车皮革行业强劲的消费者主导市场驱动力，反过来又导致对最小化气味和挥发性有机化合物(VOC)的产品的需求增加。
汽车皮革饰面材料用面漆组合物表面处理，所述面漆组合物通常包含水性聚合物粘结剂、水分散性聚异氰酸酯交联剂、消光剂和任选地颜料和手感改性剂。在面漆组合物中气味和VOC的一个主要来源为多异氰酸酯交联剂。供应水分散性多异氰酸酯交联剂，其通常溶解在有机溶剂中，如3-乙氧基丙酸乙酯(EEP)。溶解在EEP中的水分散性聚异氰酸酯在施用前与水性聚合物粘结剂共混时可提供可接受的适用期，例如，所得涂料组合物在室温(20℃-25℃)下可使用约4小时。然而，EEP可引起强烈的令人不愉快的气味，并且导致VOC。一种可能的解决方案是用气味较小但仍被归类为VOC的替代溶剂(如碳酸亚丙酯)代替EEP。此外，使用碳酸亚丙酯可导致适用期缩短。
仍然需要适用于汽车皮革表面处理面漆的水性涂料组合物，与含EEP的涂料组合物相比，所述涂料组合物具有更少的气味和更低的VOC含量，并具有可接受的适用期。
发明内容
本发明提供适于制备皮革面漆的水性涂料组合物，其包含水性聚合物分散体、水分散性多异氰酸酯和特定的醚-酯化合物。与含EEP的涂料组合物相比，本发明的水性涂料组合物具有更少的气味和更低的VOC含量。水性涂料组合物还具有可接受的适用期，如由根据在下文实例部分中描述的测试方法的△粘度小于10秒指示。
在第一方面，本发明为水性涂料组合物，其包含，
(a)以水性涂料组合物的所述固体重量计，20固体重量％到80固体重量％的包含Tg小于0℃的聚合物的水性聚合物分散体；
(b)以水性涂料组合物的固体重量计，5固体重量％到50固体重量％的水分散性多异氰酸酯；
(c)溶剂，以所述溶剂的总重量计，其包含30重量％或更多的具有式(I)结构的醚-酯化合物，
其中R1表示氢或C1-C4烷基，R2表示氢或甲基，R3表示C1-C4烷基，并且n为1或2；和
其中以水分散性多异氰酸酯的固体重量计，溶剂的存在量为45重量％到300重量％；和
(d)以水性涂料组合物的固体重量计，2固体重量％到30固体重量％的消光剂。
在第二方面，本发明为制备第一方面的水性涂料组合物的方法。方法包含：
(i)提供水分散性多异氰酸酯在溶剂中的溶液，其中以溶剂的总重量计，溶剂包含30重量％或更多的具有式(I)结构的醚-酯化合物，
其中R1表示氢或C1-C4烷基，R2表示氢或甲基，R3表示C1-C4烷基，并且n为1或2；
其中以水分散性多异氰酸酯的固体重量计，溶剂的存在量为45重量％到300重量％；和
(ii)将水分散性多异氰酸酯溶液与包含Tg小于0℃的聚合物的水性聚合物分散体和消光剂混合，以形成水性涂料组合物；
其中以水性涂料组合物的固体重量计，水性涂料组合物包含5固体重量％到50固体重量％的水分散性多异氰酸酯、20固体重量％到80固体重量％的水性聚合物分散体，和2固体重量％到30固体重量％的消光剂。
具体实施方式
本发明中的“丙烯酸”包括(甲基)丙烯酸、(甲基)丙烯酸烷基酯、(甲基)丙烯酰胺、(甲基)丙烯腈以及其改性形式，如(甲基)丙烯酸羟基烷基酯。在整篇文件中，词语片段“(甲基)丙烯酰基”是指“甲基丙烯酰基”和“丙烯酰基”。举例来说，(甲基)丙烯酸是指甲基丙烯酸和丙烯酸，并且(甲基)丙烯酸甲酯是指甲基丙烯酸甲酯和丙烯酸甲酯。
如本文所用，术语指定单体的结构单元(也被称为聚合单元)是指在聚合之后单体的残余物，或呈聚合形式的单体。举例来说，甲基丙烯酸甲酯的结构单元如下所示：
其中虚线表示结构单元与聚合物主链的附接点。
本文中的“水性”组合物或分散体是指分散在水性介质中的颗粒。本文中通过“水性介质”意指水和以介质的重量计，0到30重量％的(一种或多种)水可混溶化合物，例如醇、二元醇、二醇醚、二醇酯等。
本发明的水性涂料组合物包含用作交联剂的一种或多种水分散性多异氰酸酯。水分散性多异氰酸酯可包含多异氰酸酯和改性的多异氰酸酯，所述改性的多异氰酸酯包含至少一个阴离子基团、至少一个聚氧化乙烯链段，或阴离子基团和聚氧化乙烯链段两者。如本文所用，阴离子基团为带有负电荷的化学基团。负电荷可为-1、-2或-3。具有阴离子性基团的化合物与一种或多种阳离子缔合。缔合的阳离子可为金属阳离子或具有阳离子基团的有机化合物、具有+1、+2或+3价正电荷的基团。优选的阴离子基团为磺酸根、羧酸根、羧酸基、膦酸根或其混合物。如本文所用，本文中的多异氰酸酯是指异氰酸酯化合物的聚合物、异氰酸酯化合物的加合物或其混合物。本文中的加合物是指通过使至少一种异氰酸酯化合物与具有至少两个对异氰酸酯基具有反应性的氢原子的化合物反应制备的产物。适用于本发明的加合物可为异氰酸酯化合物与一种或多种多元醇(包括例如三羟甲基丙烷、丙二醇、二丙二醇和其混合物)的加合物。
适用于本发明的异氰酸酯化合物可包括脂肪族、环脂族或芳香族异氰酸酯化合物和其混合物。合适的脂肪族异氰酸酯化合物可包括例如具有5到20个碳原子的ω-亚烷基二异氰酸酯，如六亚甲基-1,6-二异氰酸酯(HDI)、1,12-十二烷二异氰酸酯、2,2,4-三甲基-六亚甲基二异氰酸酯、2,4,4-三甲基-六亚甲基二异氰酸酯、2-甲基-1,5-五亚甲基二异氰酸酯，其异构体和其混合物。合适的环脂族异氰酸酯化合物的实例包括二环己基甲烷二异氰酸酯、异佛尔酮二异氰酸酯、1,4-环己烷二异氰酸酯、1,3-双-(异氰酸基甲基)环己烷，其异构体和其混合物。合适的芳香族异氰酸酯化合物的实例包括间四甲基二甲苯基二异氰酸酯、对四甲基二甲苯基二异氰酸酯、1,4-二甲苯基二异氰酸酯、1,3-二甲苯基二异氰酸酯、4,4'-二苯亚甲基二异氰酸酯、甲苯二异氰酸酯；其异构体；和其混合物。
适用于本发明的多异氰酸酯每分子可平均具有两个或更多个异氰酸酯(NCO)基，优选地两个到四个异氰酸酯基。多异氰酸酯通常包含5到60个碳原子、10到50个碳原子或15到40个碳原子。多异氰酸酯优选地为脂肪族或环脂族多异氰酸酯。更优选地，多异氰酸酯为六亚甲基二异氰酸酯均聚物、六亚甲基二异氰酸酯加合物、异佛尔酮二异氰酸酯均聚物、异佛尔酮二异氰酸酯加合物或其混合物。
适合的市售水分散性异氰酸酯可包括例如可购自科思创(Covestro)的基于六亚甲基二异氰酸酯的BAYHYDUR XP2655亲水性脂肪族多异氰酸酯。以水性涂料组合物的总固体重量计，在水性涂料组合物中的水分散性多异氰酸酯的存在量可为5固体重量(即，干重)％或更多、10固体重量％或更多、15固体重量％或更多、20固体重量％或更多、25固体重量％或更多，或甚至30固体重量％或更多，并且同时50固体重量％或更少、45固体重量％或更少、40固体重量％或更少，或甚至35固体重量％或更少。
本发明的水性涂料组合物另外包含一种或多种包含一种或多种具有式(I)的结构的醚-酯化合物的溶剂，
其中R1表示氢或C1-C4烷基(即，具有1到4个碳原子的烷基)，优选地氢或甲基；R2表示氢或甲基；R3表示C1-C4烷基；并且n为1或2。醚-酯化合物的沸点可为250℃或更高、260℃或更高、270℃或更高、280℃或更高，或甚至290℃或更高。合适的醚-酯化合物的实例包括苯甲酸2-丁氧基乙酯、苯甲酸2-丙氧基乙酯、苯甲酸2-乙氧基乙酯、甲苯甲酸2-乙氧基乙酯、甲苯甲酸2-丙氧基乙酯、甲苯甲酸2-丁氧基乙酯和其混合物。除了醚-酯化合物之外，在水性涂料组合物中的溶剂可另外包含一种或多种与醚-酯化合物不同的额外的溶剂。合适的额外的溶剂的实例包括碳酸亚丙酯、丙二醇二乙酸酯、3-乙氧基丙酸乙酯、二丙二醇二甲醚、乙二醇丁醚醋酸酯和其混合物。以溶剂的总重量计，醚-酯化合物可存在30重量％或更多、35重量％或更多、40重量％或更多、45重量％或更多、50％或更多、55重量％或更多、60重量％或更多、65重量％或更多、70重量％或更多、75重量％或更多、80重量％或更多、85重量％或更多、90重量％或更多、95重量％或更多或甚至100重量％。以水分散性多异氰酸酯的固体重量计，在水性涂料组合物中的所有溶剂可以45重量％或更多、48重量％或更多、50重量％或更多、52重量％或更多、55重量％或更多、58重量％或更多、60重量％或更多，或甚至65重量％或更多，并且同时，300重量％或更少、250％或更少、200重量％或更少、150重量％或更少、100重量％或更少、90重量％或更少、80重量％或更少，或甚至70重量％或更少的组合量存在。
本发明的水性涂料组合物另外包含一种或多种包括丙烯酸聚合物分散体、聚氨基甲酸酯分散体、丙烯酸聚合物/聚氨基甲酸酯杂合分散体和其混合物的水性聚合物分散体。水性聚合物分散体可用作粘结剂。
可通过使一种或多种多元醇与一种或多种异氰酸酯化合物反应制备适用于本发明的聚氨基甲酸酯分散体。“多元醇”是指每分子具有两个或更多个羟基的任何产品。适用于制备聚氨基甲酸酯的多元醇可包括聚醚二醇、聚酯二醇、多官能多元醇和其混合物。多元醇可选自由以下组成的群组：聚醚多元醇、聚酯多元醇和聚碳酸酯多元醇。适用于制备聚氨基甲酸酯的聚醚多元醇可含有-C-O-C-基团。它们可通过使含有反应性氢原子的起始化合物(如水或二醇)与环氧烷(如环氧乙烷、环氧丙烷、环氧丁烷、环氧苯乙烷、四氢呋喃、表氯醇或其混合物)反应获得。优选的聚醚多元醇包括分子量为400到3,000的聚(丙二醇)、聚四氢呋喃和聚(乙二醇)与聚(丙二醇)的共聚物。适用于制备聚醚多元醇的二醇可包括亚烷基二醇，优选地乙二醇、二乙二醇和丁二醇，和其混合物。适用于制备聚氨基甲酸酯的聚酯多元醇通常为通过使有机聚羧酸或其酸酐与化学计算量过量的(一种或多种)二醇反应来制备的酯化产物。适用于制备聚氨基甲酸酯的合适的聚酯多元醇的实例包括聚(乙二醇己二酸酯)、聚(对苯二甲酸乙二酯)多元醇、聚己内酯多元醇、醇酸多元醇、邻苯二甲酸多元醇、磺化和膦酸化多元醇和其混合物。适用于制备聚酯多元醇的二醇包括上文对于制备聚醚多元醇描述的那些。适用于制备聚酯多元醇的合适的羧酸包括二羧酸和三羧酸和酸酐，例如马来酸、马来酸酐、琥珀酸、戊二酸、戊二酸酐、己二酸、辛二酸、庚二酸、壬二酸、癸二酸、氯桥酸、1,2,4-丁烷-三羧酸、邻苯二甲酸邻苯二甲酸的异构体、邻苯二甲酸酐、富马酸、二聚脂肪酸，如油酸等，和其混合物。适用于制备聚酯多元醇的优选的多元羧酸包括脂肪族和芳香族二元酸。适用于制备聚氨基甲酸酯的异氰酸酯化合物可包括在上文水分散性多异氰酸酯部分中描述的那些。具体实例包括六亚甲基-1,6-二异氰酸酯、1,12-十二烷二异氰酸酯、异佛尔酮二异氰酸酯和其混合物。
适用于本发明的聚氨基甲酸酯的数均分子量可为2,000或更多、5,000或更多、10,000或更多、20,000或更多、50,000或更多，或甚至100,000或更多，如通过凝胶渗透色谱法(GPC)在聚苯乙烯标准物下测量。聚氨基甲酸酯分散体可通过所属领域中已知的技术制备，例如首先任选地在催化剂、溶剂和其混合物存在下，通过使上文所描述的至少一种多元醇和至少一种异氰酸酯化合物反应来制备聚氨基甲酸酯；通常在存在表面活性剂的情况下，将获得的聚氨基甲酸酯分散在水中；和任选地在将聚氨基甲酸酯分散在水中之前、期间和/在之后期间和/之后添加多胺。合适的市售聚氨基甲酸酯分散体可包括例如可购自陶氏化学公司(available from The Dow Chemical Company)PRIMALTM粘结剂U-91聚氨基甲酸酯分散体(PRIMAL为陶氏化学公司的商标)。
适用于本发明的丙烯酸聚合物分散体包含一种或多种丙烯酸聚合物。丙烯酸聚合物可包含具有一个或多个官能团的一种或多种烯系不饱和单体的结构单元。官能团可为羧基、酰胺、磺酸酯基、乙酰乙酸基、羰基、脲基、酰亚胺基、氨基或磷基或其组合。含这类官能团的烯系不饱和单体的实例包括α,β-烯系不饱和羧酸，包括带有酸的单体，如甲基丙烯酸、丙烯酸、衣康酸、马来酸、巴豆酸、酰氧基丙酸，或富马酸；带有产生或随后可转化成的此类酸基的酸形成基团的单体(如酸酐、(甲基)丙烯酸酸酐或马来酸酸酐)；丙烯酰胺、甲基丙烯酰胺、N-甲基丙烯酰胺、N-乙基丙烯酰胺、N-异丙基丙烯酰胺、N-丁基丙烯酰胺、N-叔丁基丙烯酰胺、N-2-乙基己基丙烯酰胺、N,N-二甲基丙烯酰胺、N,N-二乙基丙烯酰胺和双丙酮丙烯酰胺；磺酸盐单体，如苯乙烯磺酸钠(SSS)和乙烯基磺酸钠(SVS)；丙烯酰胺基-2-甲基丙磺酸(AMPS)、其盐；(甲基)丙烯酸磷酸烷基酯，如(甲基)丙烯酸磷酸乙酯、(甲基)丙烯酸磷酸丙酯、(甲基)丙烯酸磷酸丁酯、其盐；二丙酮丙烯酰胺(DAAM)、(甲基)丙烯酸乙酰乙酰氧基乙酯、(甲基)丙烯酸乙酰乙酰氧基丙酯、(甲基)丙烯酸乙酰乙酰氧基丁酯、(甲基)丙烯酸2,3-二(乙酰乙酰氧基)丙酯、乙酰乙酸烯丙酯，或乙酰乙酸乙烯基酯；和其混合物。优选的含官能团的烯系不饱和单体选自由以下组成的组：丙烯酸、甲基丙烯酸、丙烯酰胺和甲基丙烯酰胺。以丙烯酸聚合物的重量计，丙烯酸聚合物可包含零或更多、0.1重量％或更多、0.3重量％或更多、0.5重量％或更多，或甚至1重量％或更多，并且同时，20重量％或更少、15重量％或更少、10重量％或更少、8重量％或更少，或甚至5重量％或更少的含官能团的烯系不饱和单体的结构单元。本发明中的丙烯酸聚合物的重量是指丙烯酸聚合物的干重或固体重量。
适用于本发明的丙烯酸聚合物还可包含一种或多种与含官能团的烯系不饱和单体不同的烯系不饱和非离子单体的结构单元。如本文所用，术语“非离子单体”是指在pH＝1-14之间不带有离子电荷的单体。合适的烯系不饱和非离子单体可包括例如(甲基)丙烯酸的烷基酯、乙烯基芳香族单体，如苯乙烯和被取代的苯乙烯、羧酸的乙烯基酯、烯系不饱和腈，或其混合物。优选地，烯系不饱和非离子单体包括(甲基)丙烯酸的C1-C18、C1-C10或C1-C6烷基酯，例如丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸乙酯、(甲基)丙烯酸丁酯、丙烯酸2-乙基己酯、(甲基)丙烯酸己酯、(甲基)丙烯酸月桂酯、(甲基)丙烯酸硬脂酯、(甲基)丙烯酸环己酯、(甲基)丙烯酸苯甲酯、(甲基)丙烯酸油酯、(甲基)丙烯酸棕榈酯、(甲基)丙烯酸壬酯、(甲基)丙烯酸癸酯、(甲基)丙烯酸十二烷基酯、(甲基)丙烯酸十五烷基酯、(甲基)丙烯酸十六烷基酯、(甲基)丙烯酸十八烷基酯、丙烯酸2-羟乙酯、甲基丙烯酸2-羟基乙酯、丙烯酸2-羟丙酯、甲基丙烯酸2-羟丙酯、丙烯酸3-羟丙酯和甲基丙烯酸3-羟丙酯和其混合物。以丙烯酸聚合物的重量计，丙烯酸聚合物可包含80重量％到100重量％、85重量％到99.7重量％、90重量％到99.5重量％或95重量％到99重量％的烯系不饱和非离子单体的结构单元。
适用于本发明的水性聚合物分散体可为丙烯酸聚合物/聚氨基甲酸酯杂合分散体。杂合分散体可通过在存在聚氨基甲酸酯的情况下上文所描述的适用于制备丙烯酸聚合物的单体在水性介质中的乳液聚合制备，例如首先提供聚氨基甲酸酯，优选地聚氨基甲酸酯分散体，并且然后装载用于制备丙烯酸聚合物的单体并且使其聚合，由此获得杂合分散体。在丙烯酸聚合物/聚氨基甲酸酯杂合分散体中的聚氨基甲酸酯包括在上文聚氨基甲酸酯分散体部分中描述的那些。在丙烯酸聚合物/聚氨基甲酸酯杂合分散体中，聚氨基甲酸酯与丙烯酸聚合物的重量比可为20/80到99/1、35/65到75/25，或40/60到60/40。
丙烯酸聚合物分散体和/或丙烯酸聚合物/聚氨基甲酸酯杂合分散体可通过自由基聚合，优选地乳液聚合制备。适合于乳液聚合的温度可低于100℃、在15℃到95℃范围内或在30℃到90℃范围内。
在乳液聚合中，可使用自由基引发剂。乳液聚合方法可为热引发的或氧化还原引发的乳液聚合。合适的自由基引发剂的实例包括过氧化氢、叔丁基过氧化氢、过氧化氢异丙苯、过硫酸铵和/或碱金属过硫酸盐、过硼酸钠、过磷酸和其盐、高锰酸钾，和过二硫酸的铵或碱金属盐。以单体的总重量计，自由基引发剂通常可以0.01重量％到3.0重量％的水平使用。可在聚合方法中使用包含上文所描述引发剂外加合适的还原剂的氧化还原系统。适合的还原剂的实例包括甲醛次硫酸钠、抗坏血酸、异抗坏血酸、含硫的酸的碱金属盐和铵盐(如亚硫酸钠、亚硫酸氢盐、硫代硫酸盐、次硫酸盐、硫化物、硫氢化物或连二亚硫酸盐)、甲脒亚磺酸、羟甲基磺酸、丙酮亚硫酸氢盐、乙醇酸、乙醛酸水合物、乳酸、甘油酸、苹果酸、酒石酸和前述酸的盐。铁、铜、锰、银、铂、钒、镍、铬、钯或钴的金属盐可用于催化氧化还原反应。可任选地使用金属的螯合剂。
在乳液聚合中，可使用表面活性剂。表面活性剂可在单体聚合之前或期间或其组合添加。一部分表面活性剂也可在聚合之后添加。这些表面活性剂可包括阴离子和/或非离子乳化剂。合适的表面活性剂的实例包括烷基、芳基或烷基芳基硫酸酯、磺酸酯或磷酸酯的碱金属或铵盐；烷基磺酸；磺基琥珀酸盐；脂肪酸；可聚合表面活性剂；和乙氧基化醇或酚。以总单体计重量重量，使用的表面活性剂通常为0.1重量％到6重量％或0.3重量％到1.5重量％。
在乳液聚合中，可使用链转移剂。合适的链转移剂的实例包括3-巯基丙酸、十二烷基硫醇、3-巯基丙酸甲酯、3-巯基丙酸丁酯、苯硫酚、壬二酸烷基硫醇，或其混合物。链转移剂可以控制聚合物的分子量的有效量使用，例如，以单体的总重量计，0到2.5重量％、0.03重量％到1重量％，或0.05重量％到0.5重量％。
在完成聚合物的聚合之后，获得的聚合物分散体可通过一种或多种碱作为中和剂中和到例如至少6、6到10或7到9的pH值。碱可导致聚合物的离子或潜在离子基团的部分或完全中和。合适的碱的实例包括氨水；碱金属或碱土金属化合物，如氢氧化钠、氢氧化钾、氢氧化钙、氧化锌、氧化镁、碳酸钠；伯胺、仲胺和叔胺，如三乙胺、乙胺、丙胺、单异丙胺、单丁胺、己胺、乙醇胺、二乙胺、二甲胺、二正丙胺、三丁胺、三乙醇胺、二甲氧基乙胺、2-乙氧基乙胺、3-乙氧基丙胺、二甲基乙醇胺、二异丙醇胺、吗啉、乙二胺、2-二乙氨基乙胺、2,3-二氨基丙烷、1,2-丙二胺、新戊二胺、二甲基氨基丙胺、己二胺、4,9-二氧杂十二烷-1,12-二胺、聚乙烯亚胺或聚乙烯胺；氢氧化铝；和其混合物。
在水性聚合物分散体中的聚合物的玻璃化转变温度(Tg)可小于0℃，例如-100℃到0℃、-70℃到-5℃、-65℃到-10℃、-60℃到-15℃或-60℃到-20℃。本文报道的特定Tg值为根据ASTM D3418-12(2012)(通过差示扫描量热法进行聚合物的融合和结晶转变温度和焓的标准测试方法)通过差示扫描量热法(DSC)测量的那些。在装配有自动进样器的TAInstrument DSC Q2000上，在氮气氛围下，在敞口铝盘中分析5到10毫克(mg)样品。通过DSC的Tg测量在-90℃到150℃，20℃/min；2个循环下。使用半高法在第2循环中获得的拐折的中点处测量Tg。
在水性聚合物分散体中的聚合物颗粒的数均粒径可为30纳米(nm)或更大、40nm或更大、50nm或更大或甚至60nm或更大，并且同时，500nm或更小、300nm或更小、200nm或更小、150nm或更小，或甚至120nm或更小，如通过Brookhaven BI-90粒径分析仪测量。
以水性涂料组合物的固体重量计，本发明的水性涂料组合物可包含20固体重量％或更多、25固体重量％或更多、30固体重量％或更多或甚至35固体重量％或更多，并且同时80固体重量％或更少、70固体重量％或更少、60固体重量％或更少、50固体重量％或更少或甚至40固体重量％的水性聚合物分散体。
本发明的水性涂料组合物可另外包含一种或多种消光剂。本文中的“消光剂”是指提供消光效果的任何无机或有机颗粒。根据ASTM E2651-10(2010)粉末粒径分析的标准指南，通常消光剂的平均粒径为3.5微米或更大。适用于本发明的合适的消光剂可包括二氧化硅消光剂、聚脲消光剂、聚丙烯酸酯消光剂、聚乙烯消光剂、聚四氟乙烯消光剂和其混合物。优选的消光剂为二氧化硅消光剂、聚丙烯酸酯消光剂、聚脲消光剂和其混合物。适合的市售消光剂包括例如均可购自赢创(Evonik)的ACEMATT TS-100和OK520二氧化硅消光剂；可购自杜特兰(Deuteron)的DEUTERON MK聚脲消光剂、可购自格雷斯戴维森(Grace Davison)的SYLOID Silica 7000消光剂、可购自陶氏化学公司(The Dow Chemical Company)的基于聚丙烯酸酯的PARALOIDTM PRD 137B乳液(PARALOID为陶氏化学公司的商标)；均可购自肯阿迪技术公司(Keim-Additec)的基于HDPE/塑料的ULTRALUBE D277乳液、基于褐煤/PE/塑料的ULTRALUBE D818乳液和基于PE/酯消光剂的ULTRALUBE D860乳液；和其混合物。以水性涂料组合物的固体重量计，消光剂存在量可为2固体重量％或更多、3固体重量％或更多、4固体重量％或更多或甚至5固体重量％或更多，并且同时30固体重量％或更少、25固体重量％或更少、20固体重量％或更少、15固体重量％或更少或甚至10固体重量％或更少。
本发明的水性涂料组合物可另外包含一种或多种增稠剂，也被称为“流变改性剂”。合适的增稠剂的实例包括碱可溶胀的乳液(ASE)；疏水改性的碱可溶胀乳液(HASE)；缔合增稠剂，如疏水改性的乙氧基化氨酯(HEUR)；和纤维素增稠剂，如甲基纤维素醚、羟基甲基纤维素(HMC)、羟基乙基纤维素(HEC)、疏水改性的羟乙基纤维素(HMHEC)、羧甲基纤维素钠(SCMC)、羧基甲基2-羟乙基纤维素钠、2-羟丙基甲基纤维素、2-羟乙基甲基纤维素、2-羟丁基甲基纤维素、2-羟乙基乙基纤维素和2-羟丙基纤维素。优选的增稠剂为HEUR、HASE或ASE。以水性涂料组合物的总固体重量计，增稠剂的存在量可为0到7固体重量％、0.2固体重量％到6固体重量％、0.5固体重量％到5固体重量％或0.8固体重量％到4固体重量％。
本发明的水性涂料组合物还可包含一种或多种调平剂。“调平剂”是指使得能够涂料组合物更均匀地润湿基材并且减少表面缺陷的化学物质。合适的调平剂的实例包括聚二甲基硅氧烷、改性的聚二甲基硅氧烷、聚丙烯酸酯、碳氟化合物表面活性剂和其混合物。以涂料组合物的总固体重量计，调平剂可存在0到15重量％、0到10重量％、0.3重量％到7重量％、0.5重量％到6重量％或0.7重量％到5重量％。
本发明的水性涂料组合物还可包含一种或多种手感改性剂。“手感改性剂”是指添加到涂料配制物中目的为赋予由其制备的干燥膜令人愉快的手感的化学品。合适的手感改性剂的实例包括硅酮、蜡乳液、聚丙烯酸聚合物和其混合物。以涂料组合物的总固体重量计，手感改性剂可存在0到40固体重量％、2固体重量％到30固体重量％、4固体重量％到25固体重量％或6固体重量％到20固体重量％。
本发明的水性涂料组合物可另外包含颜料和/或增量剂。本文中的“颜料”是指能够实质上有助于涂料的不透明性或遮盖能力的颗粒状无机材料。这类材料的折射率通常大于1.8。无机颜料可包括例如二氧化钛(TiO2)、氧化锌、氧化铁、硫化锌、硫酸钡、碳酸钡或其混合物。在优选的实施例中，用于本发明的颜料TiO2。TiO2通常以两种晶体形式存在，锐钛矿和金红石。TiO2还可以浓缩分散体的形式获得。水性涂料组合物还可包含一种或多种增量剂。本文中的“增量剂”是指折射率小于或等于1.8并且大于1.3的颗粒状材料。合适的增量剂的实例包括碳酸钙、粘土、硫酸钙、铝硅酸盐、硅酸盐、沸石、云母、硅藻土、实心或中空玻璃、瓷珠、霞石正长岩、长石、硅藻土、煅烧硅藻土、滑石(水合硅酸镁)、二氧化硅、氧化铝、高岭土、叶蜡石、珍珠岩、重晶石、硅灰石、不透明聚合物(例如可购自陶氏化学公司的ROPAQUETMUltra E(ROPAQUE为陶氏化学公司的商标)或其混合物。以涂料组合物的总固体重量计，颜料和/或增量剂可以0到30重量％、2重量％到25重量％或4重量％到20重量％的组合量存在。
以涂料组合物的重量计，水性涂料组合物的固体含量可在10重量％到60重量％、15重量％到50重量％或25重量％到45重量％的范围内。
除上文所描述的组分之外，本发明的水性涂料组合物可另外包含以下添加剂中的任一种或组合：缓冲剂、中和剂、冻/融添加剂、保湿剂、防霉剂、杀生物剂、防结皮剂、着色剂、流动剂、抗氧化剂、塑化剂、触变剂、粘合促进剂和研磨媒剂。以水性涂料组合物的固体重量计，这些添加剂可以0到10固体重量％、0.3固体重量％到5固体重量％或0.5固体重量％到3固体重量％的组合量存在。
本发明的水性涂料组合物可通过以下制备：提供在溶剂中的水分散性多异氰酸酯的溶液，其可通过将水分散性多异氰酸酯溶解在溶剂中制备；将所得的水分散性多异氰酸酯溶液、水性聚合物分散体和消光剂混合以形成水性涂料组合物。可以任何顺序将水性涂料组合物中的组分混合以提供本发明的水性涂料组合物。还可将上述任选的组分中的任一种在混合期间或之前添加到组合物，以形成水性涂料组合物。
与含EEP的涂料组合物相比，本发明的水性涂料组合物具有更低的VOC含量和更少的气味。水性涂料组合物可具有100克(g)或更少的VOC每升(L)所述水性涂料组合物、50g/L或更少、30g/L或更少，或甚至10g/L或更少，如通过GB 18582-2008(室内装饰和装修材料标准-内部建筑涂料的有害物质限值)(中国)测量。水性涂料组合物还具有与含EEP的涂料组合物相当的可接受的适用期，例如，如由△粘度小于10秒、小于9秒或甚至小于8秒所指示，如根据在下文实例部分中描述的测试方法测量。与含丙二醇二乙酸酯(PGDA)使涂料组合物相比，水性涂料组合物还可提供相当的特性，包括例如bally柔韧性、湿摩擦坚牢度和/或Gakushin擦坚牢度，根据在下文实例部分中描述测试方法。
本发明还涉及使用水性涂料组合物的方法，其包含形成水性涂料组合物，将水性涂料组合物施用到基材，和干燥，任选地固化施用的涂料组合物。本发明还涉及制备涂料的方法，其包含形成本发明的水性涂料组合物，将水性涂料组合物施用到基材，和干燥施用的水性涂料组合物或使其干燥以形成涂层。可使用已知方式进行干燥，例如在将不破坏基材的温度(例如150℃或更低，或120℃或更低，例如50℃到100℃)下空气干燥或热干燥。
本发明的水性涂料组合物可通过任何已知的方法(例如刷涂、浸渍、滚涂和喷涂)施用到建筑基材或工业基材，包括例如包括皮革(例如天然皮革、人造革、合成革和乙烯基皮革)的柔性基材，如皮革饰面材料，例如汽车饰面材料、金属、塑料、泡沫、石头、弹性体基材、织物、混凝土或似水泥的基材。涂料组合物特别适于汽车皮革表面处理。水性涂料组合物可施用到未表面处理的或底涂层表面处理的皮革，例如矿物鞣制或植物鞣制的皮革，包括全粒面皮革、抛光或校正粒面皮革和分开的皮革；或纸；通过幕涂机和喷涂方法，例如通过辊涂或刮涂进行的空气雾化喷涂、空气辅助喷涂、无气喷涂、高容量低压喷涂和空气辅助无气喷涂。水性涂料组合物可直接施用到皮革上或间接涂布在底漆层上。底漆可为常规底漆，其包含(甲基)丙烯酸聚合物、聚氨基甲酸酯、聚丙烯腈、聚丁二烯、聚苯乙烯、聚氯乙烯、聚偏二氯乙烯、聚乙酸乙烯酯和其组合。
实例
现在将在以下实例中描述本发明的一些实施例，除非另外说明，否则其中所有份数和百分比均按重量计。在实例中使用以下材料：
3-乙氧基丙酸乙酯(EEP)、1,2-丙二醇、二乙酸酯(PGDA)和苯甲酸2-丁氧基乙酯(BCB)均可购自陶氏化学公司。
碳酸亚丙酯(PC)可购自Lixing化学(Lixing Chemical)。
可购自朗盛(Lanxess)的AQUADERM流体H(100％固体)为聚酯改性的聚硅氧烷调平剂。
可购自陶氏化学公司的OPTI-MATTTM UD-4基于聚氨基甲酸酯的去光剂(25％固体)包含作为粘结剂的聚氨基甲酸酯分散体(Tg：约-54±2℃)和作为消光剂的无机物二氧化硅和有机丙烯酸珠粒的混合物。
可购自朗盛的EUDERM Black BN颜料分散体(23％固体)包含碳和丙烯酸粘结剂。
可购自陶氏化学公司的HYDRHOLACTM CL-20乳液(36％固体)为作为粘结剂的丙烯酸聚合物分散体(Tg：约-52±2℃)。
可购自陶氏化学公司的ROSILKTM2229手感改性剂(60％固体)为水性硅酮乳液(ROSILK为陶氏化学公司的商标)。
可购自陶氏化学公司的ACRYSOLTM RM-819W增稠剂(18％固体)为疏水改性的乙氧基化氨基甲酸酯。
可购自科思创的水分散性多异氰酸酯(100％固体)包含六亚甲基二异氰酸酯的均聚物、嵌段的己烷、1,6-二异氰酸基均聚物。
OPTI-MATT、HYDRHOLAC和ACRYSOL为陶氏化学公司的商标。
在实例中使用以下标准分析设备和方法。
适用期
水分散性多异氰酸酯(100％固体)溶解在不同溶剂中以形成具有不同固体含量的交联剂溶液。然后每种交联剂溶液与除了ACRYSOL RM-819增稠剂以外的在涂料组合物中的其它组分混合以形成混合物。
然后，将ACRYSOL RM-819增稠剂作为增稠剂添加到混合物，其量为将所得涂料组合物的粘度调节到理想地20～21秒。通过使用Zahn2#粘度杯以秒为单位测量粘度。在形成涂料组合物之后二十分钟和210分钟，将粘度分别记录为初始和最终粘度。在初始粘度和最终粘度之间的△粘度用于评估适用期。最大可接受△粘度为10秒。否则，如果涂料组合物胶凝或△粘度大于10秒，那么涂料组合物具有差的适用期。粘度改变越高表示适用期越短。
气味评估
根据嗅觉进行气味评估。对于每个样品，为八位气味小组成员分别提供每种溶剂样品的“盲”样品，并且然后闻样品。小组成员按照1到3的等级评分，其中1代表强烈气味，2代表中等气味，并且3代表低气味。气味等级通过平均所有小组成员给出的分数来确定。气味等级为2.0或更高为可接受的，或代表低气味。等级越高表示气味越少。
光泽度
使用光泽度仪(BYK Gardner USA MICRO-TRI-GLOSS仪，目录号4520)测量皮革表面的光泽度(60°)。最大可接受光泽度(60°)为1.5。
Bally柔韧性
根据ASTM D6182-00(2010)(表面处理的皮革的柔韧性和粘附性的标准测试方法)测量Bally柔韧性，所述方法在引用的循环次数和温度下反复弯曲皮革标本，具体来说，分别在20℃下循环100,000次，在-10℃下循环30,000次。在弯曲之后，使用立体镜(10×放大倍数)评估皮革以评估对涂饰层的损坏。涂饰层示出没有开裂或白色裂纹被评定为“合格”。否则，开裂或白色裂纹被评定为“不合格”。
湿摩擦坚牢度测试
润摩擦坚牢度根据ASTM D 5053-03(2009)(耐摩擦皮革的色牢度的标准测试方法)确定。使用摩擦坚牢度(Satra Footware技术中心型号STM421)进行润摩擦坚牢度测试。从表面处理的外皮中取出11.5cm×3.5cm的样片。为了确定表面涂层皮革的涂饰层坚牢度，将1.5cm×1.5cm的毛毡摩擦垫用水浸透，并放在设备摩擦头上(摩擦头的总重量为1千克)。为了完成测试，将皮革样片插入摩擦坚牢度测试仪中并再拉伸10％，将水饱和的毛毡垫施用到表面处理的表面，分别完成1,000次摩擦循环和2,000次摩擦循环。通过将其与对照毛毡垫(未使用的毛毡垫)进行比较，目测评估整涂饰层的损坏，并目测评估用于测试的毛毡垫的颜料转移。使用灰度图评估毛毡垫之间的色差。
Gakushin测试方法
如下进行Gakushin测试：将研磨布(#6导管布)固定到压板并且将一条皮革固定到头部。将布和皮革接触在一起，并且现场将皮革上方的总头部重量设置为1千克(kg)。启动测试，并且以30循环每分钟的速率来回移动压板，使得导管布能够在施用的1kg压力下在皮革样片的表面上摩擦。当皮革涂层被磨损到可见赤褐色的程度或20,000个循环(以先到者为准)时，测试完成。记录测试循环数，其中8,000个循环或更多被评定为“合格”，并且少于8,000个循环被评定为“不合格”。
涂料组合物
基于在表1中给出的配方制备涂料组合物。将水分散性多异氰酸酯和溶剂混合在一起并搅拌几分钟以首先形成透明的交联剂溶液。在搅动(200转/分钟(rpm))下将除了ACRYSOL RM-819增稠剂和交联剂溶液以外的在表1中列出的其它材料依次添加到容器中。然后在搅动(200rpm)下将交联剂溶液添加到容器以形成混合物。然后将ACRYSOL RM-819增稠剂添加到混合物以调节粘度，理想地目标为20～21秒，如通过使用Zahn2#粘度杯测量，由此形成涂料组合物。根据上文所描述的测试方法评估这些涂料组合物并且在表1和2中给出特性。
如表1所示，以总溶剂的重量计，不包含BCB的涂料组合物(比较实例A和B)或仅含有25重量％的BCB(比较实例C)均展示差的适用期，如通过示出凝胶或△粘度高于10秒所指示。包含固体含量分别为70％和75％的在BCB中的水分散性多异氰酸酯的溶液的比较实例D和E的涂料组合物均示出不合期望地短适用期。相比之下，实例1-4的涂料组合物均出人意料地表现出长的多的适用期，如由△粘度小于10秒所指示。
此外，气味评估结果示出EEP、BCB、PGDA和PC的气味等级分别为1.5、2.9、1.9和2.5。EEP、PGDA、PC和BCB的沸点分别为170℃、191℃、240℃和292℃。这表明，与添加EEP、PGDA或PC相比，向涂料组合物中添加BCB产生的气味更少并且VOC含量更低。
表1.皮革面漆的配方和性能
根据上文所描述的测试方法进一步评估实例2的水性涂料组合物。如在表2中所示，实例2的水性涂料组合物还提供用于皮革应用的可接受的特性。
表2.性能评价结果
Claims (10)
1.一种水性涂料组合物，其包含：
(a)以所述水性涂料组合物的固体重量计，20固体重量％到80固体重量％的包含Tg小于0℃的聚合物的水性聚合物分散体；
(b)以所述水性涂料组合物的固体重量计，5固体重量％到50固体重量％的水分散性多异氰酸酯；
(c)溶剂，以所述溶剂的总重量计，其包含40重量％或更多的具有式(I)结构的醚-酯化合物，
其中R1表示氢或C1-C4烷基，R2表示氢或甲基，R3表示C1-C4烷基，并且n为1或2；和
其中以所述水分散性多异氰酸酯的固体重量计，所述溶剂的存在量为50重量％到300重量％；和
(d)以所述水性涂料组合物的固体重量计，2固体重量％到30固体重量％的消光剂。
2.根据权利要求1所述的水性涂料组合物，其中所述水性聚合物分散体为丙烯酸聚合物分散体、聚氨基甲酸酯分散体、丙烯酸聚合物/聚氨酯杂合分散体或其混合物。
3.根据权利要求1所述的水性涂料组合物，其中所述醚-酯化合物选自由以下组成的组：苯甲酸2-丁氧基乙酯、苯甲酸2-丙氧基乙酯、苯甲酸2-乙氧基乙酯、甲苯甲酸2-乙氧基乙酯、甲苯甲酸2-丙氧基乙酯和甲苯甲酸2-丁氧基乙酯。
4.根据权利要求1所述的水性涂料组合物，其中将所述水分散性多异氰酸酯溶解在所述溶剂中以形成溶液，然后与所述水性聚合物分散体和所述消光剂混合。
5.根据权利要求1所述的水性涂料组合物，其中以所述水分散性多异氰酸酯的固体重量计，所述溶剂的存在量为50重量％到150重量％。
6.根据权利要求1所述的水性涂料组合物，其中以所述溶剂的总重量计，所述溶剂包含40重量％到100重量％的所述醚-酯化合物。
7.根据权利要求1所述的水性涂料组合物，其中所述水分散性多异氰酸酯包含六亚甲基二异氰酸酯的均聚物。
8.根据权利要求1所述的水性涂料组合物，其以所述水性涂料组合物的固体重量计，包含15固体重量％到35固体重量％的所述水分散性多异氰酸酯。
9.根据权利要求1所述的水性涂料组合物，其另外包含调平剂、手感改性剂、增稠剂、颜料或其混合物。
10.一种制备水性涂料组合物的方法，其包含：
(i)提供水分散性多异氰酸酯在溶剂中的溶液，其中以所述溶剂的总重量计，所述溶剂包含40重量％或更多的具有所述式(I)结构的醚-酯化合物，
其中R1表示氢或C1-C4烷基，R2表示氢或甲基，R3表示C1-C4烷基，并且n为1或2；
其中以所述水分散性多异氰酸酯的固体重量计，所述溶剂的存在量为50重量％到300重量％；和
(ii)将所述水分散性多异氰酸酯溶液与包含Tg小于0℃的聚合物的水性聚合物分散体和消光剂混合，以形成所述水性涂料组合物；
其中以所述水性涂料组合物的固体重量计，所述水性涂料组合物包含5固体重量％到50固体重量％的所述水分散性多异氰酸酯、20固体重量％到80固体重量％的所述水性聚合物分散体，和2固体重量％到30固体重量％的所述消光剂。
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2018/090042 WO2019232704A1 (en) | 2018-06-06 | 2018-06-06 | Aqueous coating composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112074555A CN112074555A (zh) | 2020-12-11 |
| CN112074555B true CN112074555B (zh) | 2022-08-30 |
Family
ID=68769151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201880093187.0A Expired - Fee Related CN112074555B (zh) | 2018-06-06 | 2018-06-06 | 水性涂料组合物 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20210087425A1 (zh) |
| EP (1) | EP3802658A4 (zh) |
| KR (1) | KR20210018299A (zh) |
| CN (1) | CN112074555B (zh) |
| AU (1) | AU2018426345A1 (zh) |
| BR (1) | BR112020021099A2 (zh) |
| MX (1) | MX2020012096A (zh) |
| WO (1) | WO2019232704A1 (zh) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102324995B1 (ko) * | 2021-03-03 | 2021-11-10 | 김준현 | 우수한 방수성능 및 접착성능을 갖는 프라이머 조성물 및 이를 이용한 콘크리트 구조물의 방수 시공방법 |
| WO2024011580A1 (en) * | 2022-07-15 | 2024-01-18 | Dow Global Technologies Llc | Multi-layer synthetic leather products |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5414041A (en) * | 1994-04-08 | 1995-05-09 | Rohm And Haas Company | Waterborne coating composition |
| JP3957018B2 (ja) * | 1997-09-22 | 2007-08-08 | 株式会社Ａｄｅｋａ | 水系ポリウレタン樹脂組成物 |
| JP2003064244A (ja) * | 2001-08-27 | 2003-03-05 | Asahi Denka Kogyo Kk | 熱可塑性ポリエステル系樹脂組成物 |
| DE102004049591A1 (de) * | 2004-10-12 | 2006-04-13 | Bayer Materialscience Ag | Wässrige Schaumbeschichtung mit Softfeel-Effekt |
| EP2170971B1 (de) * | 2007-07-19 | 2011-02-02 | Basf Se | Wasserdispergierbare polyisocyanate |
| CN102395612B (zh) * | 2009-04-16 | 2014-05-28 | 巴斯夫欧洲公司 | 球形颗粒及其用途 |
| DE102009033194A1 (de) * | 2009-07-14 | 2011-01-20 | Mankiewicz Gebr. & Co. (Gmbh & Co. Kg) | Beschichtungsstoffzusammensetzung und deren Verwendung |
| EP2681278B1 (en) * | 2011-03-02 | 2020-04-22 | Dow Global Technologies LLC | A coating composition and articles made therefrom |
| EP3178891B1 (en) * | 2011-04-08 | 2020-10-21 | Rohm And Haas Company | Low/zero voc glycol ether-esters as coalescents for aqueous polymeric dispersions |
| CA2771697C (en) * | 2011-04-08 | 2014-07-08 | Dow Global Technologies Llc | Low/zero voc glycol ether-esters and use as clean-up solvents and paint thinners |
| RU2665923C2 (ru) * | 2012-09-28 | 2018-09-05 | Басф Се | Вододиспергируемые полиизоцианаты |
| ES2705759T3 (es) * | 2014-06-24 | 2019-03-26 | Dow Global Technologies Llc | Procedimiento para producir éter-ésteres de glicol con bajo nivel de COV |
| JP2016084400A (ja) * | 2014-10-24 | 2016-05-19 | Dic株式会社 | 水性樹脂組成物、水性表面処理剤及びそれを用いた物品 |
| CA3018968A1 (en) * | 2016-03-28 | 2017-10-05 | Dow Global Technologies Llc | Compositions, aqueous coating compositions, and methods for improving the freeze/thaw stability of aqueous coating compositions |
| CN108779349A (zh) * | 2016-03-28 | 2018-11-09 | 陶氏环球技术有限责任公司 | 组合物、水性涂料组合物以及改进水性涂料组合物的冻融稳定性的方法 |
| ES2776903T3 (es) * | 2016-10-17 | 2020-08-03 | Dsm Ip Assets Bv | Dispersión acuosa y usos de la misma |
| EP3532534A1 (en) * | 2016-10-28 | 2019-09-04 | Solvay Specialty Polymers Italy S.p.A. | Coating composition |
| CN106947048A (zh) * | 2017-04-13 | 2017-07-14 | 合肥科天水性科技有限责任公司 | 一种用于水性服装革贝斯的水性聚氨酯树脂及其制备方法 |
| CN108084396A (zh) * | 2017-12-29 | 2018-05-29 | 襄阳点元素软装科技有限公司 | 一种耐高温的水性聚氨酯皮革软包面料 |
-
2018
- 2018-06-06 EP EP18921429.9A patent/EP3802658A4/en not_active Withdrawn
- 2018-06-06 KR KR1020207036251A patent/KR20210018299A/ko active IP Right Grant
- 2018-06-06 WO PCT/CN2018/090042 patent/WO2019232704A1/en unknown
- 2018-06-06 CN CN201880093187.0A patent/CN112074555B/zh not_active Expired - Fee Related
- 2018-06-06 US US17/053,197 patent/US20210087425A1/en not_active Abandoned
- 2018-06-06 AU AU2018426345A patent/AU2018426345A1/en not_active Abandoned
- 2018-06-06 BR BR112020021099-4A patent/BR112020021099A2/pt not_active Application Discontinuation
- 2018-06-06 MX MX2020012096A patent/MX2020012096A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN112074555A (zh) | 2020-12-11 |
| WO2019232704A1 (en) | 2019-12-12 |
| KR20210018299A (ko) | 2021-02-17 |
| AU2018426345A1 (en) | 2021-01-21 |
| EP3802658A4 (en) | 2022-01-12 |
| BR112020021099A2 (pt) | 2021-02-23 |
| EP3802658A1 (en) | 2021-04-14 |
| MX2020012096A (es) | 2021-01-29 |
| US20210087425A1 (en) | 2021-03-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1161477B1 (en) | Aqueous coating composition and a polyol for such a composition | |
| EP2834283B1 (en) | Polyurethane/acrylic hybrid dispersions for roof coatings and their preparation | |
| CN106479298B (zh) | 用于皮革上衣的水性多段共聚物组合物 | |
| EP2534215B1 (en) | Manganese complex drier for coating compositions | |
| EP1833869B1 (en) | Water borne coating composition containing thiol functional compounds | |
| JP5116678B2 (ja) | コーティングに関連した多成分の水媒介性コーティング組成物、および方法 | |
| US7569636B2 (en) | Aqueous pigmented coating composition with improved open time comprising crosslinkable oligomer(s) and dispersed polymer(s) | |
| JPH093400A (ja) | 二成分の水に担持された架橋可能なポリウレタン／アクリレート混成系 | |
| US8461256B2 (en) | Low VOC aqueous compositions of acrylic-urethane block copolymers | |
| US10745583B2 (en) | Aqueous coating composition and method of preparing the same | |
| JP2013545836A (ja) | ソフトな感触特性を有する水性配合物 | |
| CN112074555B (zh) | 水性涂料组合物 | |
| CA2144151C (en) | Mixer system for the production of water-thinnable coating compositions | |
| CA2957558A1 (en) | Coating compositions capable of producing surfaces with dry-erase properties | |
| CN112424246A (zh) | 耐污涂料组合物 | |
| TW202104277A (zh) | 聚合物粒子之水性分散液及其製備方法 | |
| CN111410902A (zh) | 水性多组分聚氨酯涂料组合物 | |
| JP7383461B2 (ja) | 複層塗膜形成方法 | |
| CA3209687A1 (en) | Stain resistant coating composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20220830 |