CN112030598A - Coated powder tobacco forming paper and preparation method thereof - Google Patents

Coated powder tobacco forming paper and preparation method thereof Download PDF

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Publication number
CN112030598A
CN112030598A CN202010931240.9A CN202010931240A CN112030598A CN 112030598 A CN112030598 A CN 112030598A CN 202010931240 A CN202010931240 A CN 202010931240A CN 112030598 A CN112030598 A CN 112030598A
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China
Prior art keywords
tobacco
powder
forming paper
coating liquid
coating
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Pending
Application number
CN202010931240.9A
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Chinese (zh)
Inventor
王小平
肖翠翠
罗振静
黄启志
陈泽亮
彭满朝
陈文吉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Tobacco Mauduit Jiangmen Paper Industry Co ltd
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China Tobacco Mauduit Jiangmen Paper Industry Co ltd
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Publication date
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Priority to CN202010931240.9A priority Critical patent/CN112030598A/en
Publication of CN112030598A publication Critical patent/CN112030598A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/84Paper comprising more than one coating on both sides of the substrate
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/02Material of vegetable origin
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/25Cellulose
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/28Starch
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/28Starch
    • D21H17/29Starch cationic
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/31Gums
    • D21H17/32Guar or other polygalactomannan gum
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/46Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/55Polyamides; Polyaminoamides; Polyester-amides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/66Salts, e.g. alums

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)

Abstract

The invention discloses powder-coated tobacco forming paper which is characterized by comprising the following steps of 1) coating the front surface, the back surface or both surfaces of the forming paper, wherein the weight content of powder in coating liquid is 5-20%, and the coating weight is 1.0-5 g/square meter in terms of dry matter; 2) the forming paper has the quantitative weight of 20-50 g/square meter and the air permeability of 50-40000 CU; 3) the powder is one or more of tobacco stem sticks, tobacco stems, tobacco leaves, tea dust, dried orange peels and plums, and is crushed by a mechanical crusher. The invention directly uses the tobacco powder waste material in the coating material of the forming paper, thereby not only realizing the recycling of the tobacco powder, but also improving the cigarette fragrance and promoting the natural sensory quality of the cigarette because the prepared forming paper keeps the original fragrance characteristics of the raw material powder. The invention realizes the powder benefit, and provides novel color cigarette forming paper which has the function of identifying the binary composite filter stick and can directly identify the filter stick from the forming paper wrapping the filter stick.

Description

Coated powder tobacco forming paper and preparation method thereof
Technical Field
The invention relates to the technical field of cigarette forming paper.
Background
Tobacco powder is a by-product of the tobacco industry and is also a valuable tobacco material. The tobacco powder is not fully and deeply used due to the limitation of tobacco market and processing technology in China. At present, the tobacco powder is mainly used for manufacturing tobacco sheets, extracting nicotine and the like, and the use amount of the tobacco sheets, the nicotine extraction and the like is limited, so a large amount of the tobacco powder still becomes tobacco waste. How to utilize the tobacco powder to make it exert greater economic benefits becomes one of the popular subjects of the research in the tobacco industry.
Patent CN102619134 discloses a method for improving aroma of filter stick forming paper, which improves cigarette smoke by coating aroma components on high-permeability forming paper. Patent CN107447574 discloses a filter stick forming paper with natural extracts coated on both sides to enhance the fragrance of cigarettes and improve the fragrance and style characteristics of cigarettes.
In all of the above patents, the extract is added to the filter plug paper to improve the smoking quality of cigarettes, but the increase of aroma is limited due to the small amount of coating. In addition, the coating components are all tobacco extracts, the source of the coating material is narrow, the components are volatile, and the extracts destroy the composite aroma of the tobacco.
Whether the powder utilization can be increased and the environmental pollution can be reduced through technical improvement under the existing cigarette filter stick and forming paper production line; meanwhile, the cigarette smoking quality is improved, and the method is one of the most valuable research methods in the field of cigarette auxiliary materials.
Disclosure of Invention
The present invention is directed to solving one or more of the above problems and to providing a coated powdered tobacco forming paper and a method for making the same.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
a powder coated tobacco forming paper is characterized in that 1) the front surface, the back surface or both surfaces of the forming paper are coated, the weight content of the powder in the coating liquid is 5-20%, and the coating weight is 1.0-5 g/m calculated by dry matter2
2) The basis weight of the formed paper is 20 to 50g/m2The air permeability of the forming paper is 50-40000 CU;
3) the powder is one or more of tobacco stem sticks, tobacco stems, tobacco leaves, tea dust, dried orange peels and plums, and is crushed by a mechanical crusher.
The front side, the back side or both sides of the formed paper can be coated, and the powder content in the coating liquid of the front side and the back side can be the same or different.
The coating liquid is composed of coating materials except powder used for conventional filter stick forming paper, and preferably contains one or more of oxidized starch, cationic starch, polyvinyl alcohol, guar gum, polyacrylamide, sodium alginate and carboxymethyl cellulose.
The powder is preferably tobacco powder of tobacco stem sticks, tobacco stems and tobacco leaves. The particle size of the powder is preferably 500-10000 meshes.
The invention also provides the application of the tobacco powder.
The invention also provides a coating liquid of the forming paper, which is characterized by containing 5-20% of tobacco powder by weight and having the viscosity of 500-5000 mpa.s. The powder is one or a mixture of more of tobacco stem sticks, tobacco stems, tobacco leaves, tea dust, dried orange peels and plums, and is crushed by a mechanical crusher; preferably the powder of tobacco stem sticks, tobacco stems and tobacco leaves. The particle size of the powder is preferably 500-10000 meshes. Preferably, the coating liquid contains one or more of oxidized starch, cationic starch, polyvinyl alcohol, guar gum, polyacrylamide, sodium alginate and carboxymethyl cellulose.
A method of making a coated powdered tobacco forming paper comprising:
1) one or more of tobacco stem sticks, tobacco stems, tobacco leaves, tea dust, dried orange peel and plums are crushed by a mechanical crusher to obtain powder with the average particle size of 500 plus 10000 meshes;
2) pouring the powder in the step 1) into the conventional solution for coating the formed paper, stirring, and preparing a coating liquid with proper concentration and viscosity;
3) coating the coating liquid on the front surface, the back surface or both surfaces of the formed paper by a coating machine, wherein the total coating weight of the coating liquid is 1.0-5 g/m in terms of dry matter2
4) Drying and rolling to obtain the forming paper coated with the powder, wherein the forming paper has a basis weight of 20-50 g/m2
The powder in the step 1) is preferably tobacco powder such as tobacco stem sticks, tobacco stems, tobacco leaves and the like.
The content of the powder in the coating liquid in the step 2) is preferably 5-20% of the total weight. The solution for forming paper preferably contains one or more of oxidized starch, cationic starch, polyvinyl alcohol, guar gum, polyacrylamide, sodium alginate and carboxymethyl cellulose, and more preferably contains polyvinyl alcohol. The viscosity of the coating liquid is preferably 500-5000 mpa.s. The coating liquid mass concentration is preferably 8 to 15%.
And 3) when the coating machine works, the temperature of the coating liquid is preferably 50-95 ℃. Coating the coating liquid on the front, back or both sides of the forming paper by a coating machine, wherein the powder content in the coating liquid on the front and back sides can be the same or different.
And 4) coating the powder coating liquid on the forming paper by using a coating machine, and drying by adopting one or two of infrared drying and hot cylinder drying. The infrared drying power is 5-20 kW, and the temperature of the hot cylinder is 80-110 ℃. And controlling the air permeability of the finished powder forming paper product to be 50-40000 CU.
The invention has the beneficial effects that:
1. the invention directly uses the tobacco powder waste material in the coating material of the forming paper, thereby not only realizing the recycling of the tobacco powder, but also improving the cigarette fragrance and promoting the natural sensory quality of the cigarette because the prepared forming paper keeps the original fragrance characteristics of the raw material powder.
2. The invention realizes the powder benefit, and provides novel color cigarette forming paper which has the function of identifying the binary composite filter stick and can directly identify the filter stick from the forming paper wrapping the filter stick.
3. The front side, the back side or the double sides can be coated for one time or multiple times by adopting the coating mode of the invention, the mode is flexible and changeable, the adaptability is strong, and the possibility is provided for adjustment.
In conclusion, the method and the product provided by the invention only need to improve the process on the original production line, and have the advantages of simple method and low cost; not only solves the waste treatment problem of the tobacco powder, but also creates new forming paper and application, and has practical application prospect and economic benefit.
Detailed Description
The following examples are given to illustrate the practice of the present invention in detail. The technical parameters or auxiliary agents and the like which are not mentioned in the examples can be selected by a person skilled in the art by combining the prior art; the preparation steps which are not mentioned are all the prior art of forming paper by using cigarette paper.
The powder raw material adopted in the following examples is a dried product of a mixture waste of tobacco stem sticks, tobacco stems and tobacco leaves provided by a certain reconstituted tobacco limited of Zhongyan, and the water content is 10%. And (4) after primary impurity removal, mechanically crushing, and screening by a 2500-mesh sieve to obtain tobacco powder.
Example 1: preparation of coating liquid
Mixing the tobacco powder with polyvinyl alcohol according to the weight ratio of 4: 1, pouring the mixture into a charging bucket with a stirring function, adding water and stirring, and keeping the temperature of the charging bucket at 60 +/-5 ℃. The mass concentration of the powder is controlled to be 15 percent, and the viscosity of the coating liquid is 1500 mpa.s.
Example 2: preparation of coating liquid
Mixing the tobacco powder with polyvinyl alcohol according to the weight ratio of 5: 2, pouring the mixture into a charging bucket with a stirring function, adding water and stirring, and keeping the temperature of the charging bucket at 60 +/-5 ℃. The mass concentration of the powder is controlled to be 10 percent, and the viscosity of the coating liquid is 2000 mpa.s.
Example 3: preparation of coating liquid
Mixing the tobacco powder with cationic starch and polyvinyl alcohol according to the weight ratio of 2: 0.5: pouring the mixture into a feeding tank with a stirring function in a proportion of 0.5, adding water and stirring, and keeping the temperature of the feeding tank at 60 +/-5 ℃. The mass concentration of the powder is controlled to be 10 percent, and the viscosity of the coating liquid is 2500 mpa.s.
Example 4:
the coating solution obtained in example 1 was applied once to the front surface of the base paper of the conventional plug wrap paper by a coater in an amount of 1.7g/m in terms of dry matter2(ii) a Drying in a 95 ℃ drying cylinder, and rolling to obtain the forming paper coated with the powder. Quantitative determination of 26.85g/m2. Air permeability 10000 CU.
Example 5:
the coating liquid obtained in example 1 was applied to the front and back sides of the base paper of the conventional plug wrap paper by a coater in an amount of 1.7g/m on a dry matter basis at one time2(ii) a And (5) drying by flooding in a 95 ℃ drying cylinder, and rolling to obtain the forming paper coated with the powder. Quantitative determination of 28.6g/m2. Air permeability 3800 CU.
Example 6:
the coating liquid obtained in example 2 was applied to the reverse side of the base paper of the conventional filter plug wrap paper by a coater in an amount of 3.5g/m in dry matter2(ii) a Drying in a 95 ℃ drying cylinder, and rolling to obtain the forming paper coated with the powder. Quantitative determination of 27.1g/m2. Air permeability 4000 CU.
The finished formed paper test results for examples 4-5 are shown in table 1 below:
TABLE 1
Figure BDA0002670311620000051
Description of conventional technical physical parameters for functional identification of filter plug wrap: the paper sheets of the formed papers of examples 4-6 were coated uniformly in the longitudinal and transverse directions, and the physical properties of the formed papers were stable. The appearance is light yellow, and the fragrance is the same as the natural fragrance of the tobacco.
The filter stick forming paper belongs to the important component of cigarette auxiliary material, and is mainly used for wrapping filter stick tows to form filter sticks. The forming paper is positioned between the inner tow and the outer tipping paper in the cigarette filter stick structure, mainly comprises fibers, high polymer materials and the like, and does not have the function of identifying the composite filter stick. The powder-coated tobacco forming paper prepared in the embodiments 4-6 can directly and macroscopically see whether the filter stick is a binary composite filter stick or not from the appearance of the forming paper wrapping the filter stick.

Claims (12)

1. The powder-coated tobacco forming paper is characterized by 1) coating the front surface, the back surface or both surfaces of the forming paper, wherein the weight content of the powder in the coating liquid is 5-20%, and the coating amount is 1.0-5 g/square meter in terms of dry matter; 2) the forming paper has the quantitative weight of 20-50 g/square meter and the air permeability of 50-40000 CU; 3) the powder is one or more of tobacco stem sticks, tobacco stems, tobacco leaves, tea dust, dried orange peels and plums, and is crushed by a mechanical crusher.
2. The coated powdered tobacco forming paper as claimed in claim 1, wherein the coating liquid contains one or more of oxidized starch, cationic starch, polyvinyl alcohol, guar gum, polyacrylamide, sodium alginate, and carboxymethyl cellulose.
3. The coated powdered tobacco forming paper according to claim 1, wherein the coating liquid is a mixed solution of powder and polyvinyl alcohol.
4. The coated powder tobacco forming paper as claimed in claim 1, wherein the powder has a particle size of 500-10000 mesh.
5. The coated powder tobacco forming paper of claim 1, wherein the powder is a mixture of one or more of tobacco stem, and tobacco leaf.
6. The coating liquid for the cigarette forming paper is characterized by comprising 5-20 wt% of tobacco powder, wherein the tobacco powder is a mixture of one or more of tobacco stem sticks, tobacco stems, tobacco leaves, tea dust, dried orange peels and plums and is formed by crushing the mixture through a mechanical crusher; the particle size of the tobacco powder is 500-10000 meshes.
7. The coating liquid for cigarette-forming paper according to claim 6, wherein the viscosity of the coating liquid is 500 to 5000mpa.s, and the mass concentration of the coating liquid is 8 to 15%.
8. The coating liquid for cigarette forming paper according to claim 6, wherein the coating liquid contains one or more of oxidized starch, cationic starch, polyvinyl alcohol, guar gum, polyacrylamide, sodium alginate and carboxymethyl cellulose.
9. A method of making a coated powdered tobacco forming paper comprising:
1) respectively coating the coating liquid of any one of claims 6 to 8 on the front surface, the back surface or both surfaces of the formed paper by using a coating machine, wherein the total coating weight of the coating liquid is 1.0 to 5g per square meter on the basis of dry matters;
2) drying and rolling to obtain the powder-coated forming paper, wherein the forming paper has a quantitative of 20-50 g/square meter.
10. The method of manufacturing coated powdered tobacco forming paper according to claim 9, characterized in that: when the coating machine works, the temperature of the coating liquid is 50-95 ℃.
11. The method of manufacturing coated powdered tobacco forming paper according to claim 9, characterized in that: and 2) drying by adopting one or two of infrared drying and hot cylinder drying, wherein the infrared drying power is 5-20 kW, and the hot cylinder temperature is 80-110 ℃.
12. The tobacco powder is used for producing a coating liquid for cigarette-forming paper or a tobacco-forming paper.
CN202010931240.9A 2020-09-07 2020-09-07 Coated powder tobacco forming paper and preparation method thereof Pending CN112030598A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115637608A (en) * 2022-09-13 2023-01-24 云南中烟工业有限责任公司 White cardboard coated with tobacco stem powder, preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120125354A1 (en) * 2010-11-18 2012-05-24 R.J. Reynolds Tobacco Company Fire-Cured Tobacco Extract and Tobacco Products Made Therefrom
CN107361400A (en) * 2017-07-31 2017-11-21 云南中烟新材料科技有限公司 A kind of preparation method for being used to prepare the forming paper and its cigarette core that heat the cigarette cigarette core that do not burn
CN107447574A (en) * 2017-10-11 2017-12-08 云南中烟新材料科技有限公司 A kind of forming paper of double spread natural plant extracts and preparation method thereof
CN107663808A (en) * 2017-10-11 2018-02-06 云南中烟新材料科技有限公司 A kind of functional plants particle cigarette coating formation paper and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120125354A1 (en) * 2010-11-18 2012-05-24 R.J. Reynolds Tobacco Company Fire-Cured Tobacco Extract and Tobacco Products Made Therefrom
CN107361400A (en) * 2017-07-31 2017-11-21 云南中烟新材料科技有限公司 A kind of preparation method for being used to prepare the forming paper and its cigarette core that heat the cigarette cigarette core that do not burn
CN107447574A (en) * 2017-10-11 2017-12-08 云南中烟新材料科技有限公司 A kind of forming paper of double spread natural plant extracts and preparation method thereof
CN107663808A (en) * 2017-10-11 2018-02-06 云南中烟新材料科技有限公司 A kind of functional plants particle cigarette coating formation paper and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115637608A (en) * 2022-09-13 2023-01-24 云南中烟工业有限责任公司 White cardboard coated with tobacco stem powder, preparation method and application thereof
CN115637608B (en) * 2022-09-13 2023-11-03 云南中烟工业有限责任公司 White cardboard coated with tobacco stem powder, preparation method and application thereof

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