CN1119827A - 非气溶胶型剃须凝胶 - Google Patents

非气溶胶型剃须凝胶 Download PDF

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Publication number
CN1119827A
CN1119827A CN94191598A CN94191598A CN1119827A CN 1119827 A CN1119827 A CN 1119827A CN 94191598 A CN94191598 A CN 94191598A CN 94191598 A CN94191598 A CN 94191598A CN 1119827 A CN1119827 A CN 1119827A
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Prior art keywords
peg
distearate
aerosol type
oleth
sorbitol
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W·R·格雷斯
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Gillette Co LLC
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Gillette Co LLC
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/042Gels
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q9/00Preparations for removing hair or for aiding hair removal
    • A61Q9/02Shaving preparations

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Medicinal Preparation (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Thermotherapy And Cooling Therapy Devices (AREA)

Abstract

本发明包括清澈凝胶形式的非气溶胶型剃须组合物,它包含(重量百分数):(a)大约15-20%肉豆蔻酸钾和棕榈酸钾的混合物,其中肉豆蔻酸与棕榈酸之比是大约2∶1,(b)大约2-4%Oleth-20;(c)大约1-5%月桂酰肌氨酸钠;和(d)大约1-2%羟乙基纤维素,大约1-3%山梨糖醇和大约1-2%PEG-150二硬脂酸酯;以及余量的水。与其它非气溶胶型剃须用制品相比,本组合物能获得优异的剃须效果。

Description

非气溶胶型剃须凝胶
本发明涉及新型的、非气溶胶剃须凝胶组合物。
几十年来非气溶胶型剃须组合物以各种形式出现,这些形式包括棒形制品、杆形制品、霜剂和洗剂,且一般具有两种类型—起沫型,通常用刷施用,和非起沫型,通常用手指涂抹。起沫型主要是皂利,非起沫型是水包油型乳液剂。
本发明的目的是提供一种非气溶胶剃须组合物,它是透明的或清澈的凝胶体并能通过刷子、海绵或其它施用器具或者通过手指施用来获得泡沫,本发明进一步的目的是提供一种非气溶胶型剃须凝胶组合物,它具有优异的起沫性质和皮肤和须毛调理性能,与其它非气溶胶型剃须  产品相比,它能获得优异的剃须效果。
本发明包括清澈凝胶形式的非气溶胶剃须组合物,它包含(按重量百分数):
(a)大约15-20%的肉豆蔻酸钾和棕榈酸钾的混合物,其中肉豆蔻酸与棕榈酸之比是大约2∶1;
(b)大约2-4%Oleth-20;
(c)大约1-5%月桂酰肌氨酸钠;和
(d)大约1-2%羟乙基纤维素,大约1-3%山梨糖醇,和大约1-2%PEG-150二硬脂酸酯;
以及余量的水。
在以上配方中,为了保持低温透明性,使游离脂肪酸的量低于大约0.1%的水平是优选的。
包括在本发明中的并且具有优异的剃须性能的剃须组合物的特定实例可以具有以下配方,其中百分数是按重量计的:
成分                 实例1                实例2
肉豆蔻酸             10.40                9.5
棕榈酸               5.15                 4.7
氢氧化钾             3.66                 3.3
O)leth-20            3.00                 3.0
月桂酰肌氨酸钠       2.25                 2.0
羟乙基纤维素         1.47                 1.3
山梨糖醇             1.50                 1.3
PEG-150二硬脂酸酯    1.38                 1.3
余量的水
如果认为必要或需要,还可以向上述配方中加入香料、染料和防腐剂。另外,可加入大约1.0%芦芸胶,以使过敏性皮肤不感到难受。在上述配方中引入大约0.0005~0.1%的氟化表面活性剂也是有利的,如可从杜邦购得的Zonyl FSK,Zonyl FSA或ZonylFSN氟化表面活性剂。
本技术领域的熟练人员很容易明白,上述配方中的一种或多种特定的组分可以用同类物质代替。例如,Oleth-20可用其它已知的润肤剂如Oleth-10或Laureth-23代替。月桂酰肌氨酸钠可被相当的肉豆蔻酰或cocoyl肌氨酸盐代替。山梨糖醇可被其它已知的保湿剂如甘油、丙二醇或Glycereth-26所代替。羟乙基纤维素可被其它已知的胶凝剂如瓜尔豆胶、十六烷基羟乙基纤维素,羟丙基纤维素或聚羟乙烯制剂所代替。PEG-150二硬脂酸酯可被其它已知的增稠剂如PEG-8二硬脂酸酯或PEG-120甲基葡萄糖二油酸酯所代替。
本发明的剃须凝胶组合物通过以下操作过程来制备。在一搅拌混合器中将羟乙基纤维素分散在水中,并升温至大约80-85℃。当溶液温度达到65℃时,添加肉豆蔻酸、棕榈酸、PEG-150二硬脂酸酯和Oleth-20。在80-85℃下,当脂肪酸熔化并呈现均相时,将氢氧化钾水溶液缓慢加入,混合溶液直到均匀为止(大约30-60分钟),从溶液取样检测游离脂肪酸,如果需要,用KOH调节,使游离脂肪酸水平降至0.1%或0.1%以下,或者,如果有游离碱,用肉豆蔻酸/棕榈酸(2∶1)调节。将溶液冷至35℃,在大约45℃时添加月桂酰肌氨酸钠(一起还可以有染料、香水和芦芸酸),收集清澈凝胶形式的产物。

Claims (6)

1.一种清澈凝胶形式的非气溶胶型剃须组合物,它包括(按重量百分数):
(a)大约15-20%的肉豆蔻酸钾和棕榈酸钾的混合物,其中肉豆蔻酸与棕榈酸之比是大约2∶1。
(b)大约2-4%Oleth-20;
(c)大约1-5%月桂酰肌氨酸钠;和
(d)大约1-2%的羟乙基纤维素,大约1-3%山梨糖醇,和大约1-2%PEG-150二硬脂酸酯;
以及余量的水。
2.根据权利要求1的非气溶胶型剃须组合物,其中游离脂肪酸的量低于大约0.1%。
3.根据权利要求2的非气溶胶型剃须组合物,它包括大约10.40%肉豆蔻酸,大约5.15%棕榈酸,大约3.66%氢氧化钾,大约3.00%Oleth-20大约2.25%月桂酰肌氨酸钠,大约1.50%山梨糖醇,大约1.47%羟乙基纤维素和大约1.38%PEG-150二硬脂酸酯。
4.根据权利要求3的非气溶胶型剃须组合物,进一步包括大约1.0%芦芸胶。
5.根据权利要求1的非气溶胶型剃须组合物,包括大约9.5%肉豆蔻酸,大约4.7%棕榈酸,大约3.3%氢氧化钾,大约3.0%Oleth-20,大约2.0%月桂酰肌氨酸钠,大约1.3%羟乙基纤维素,大约1.3%山梨糖醇和大约1.3%PEG-150二硬脂酸酯。
6.根据权利要求2的非气溶胶型剃须组合物,进一步包括大约0.0005~0.1%的氟化表面活性剂。
CN94191598A 1993-03-26 1994-03-16 非气溶胶型剃须凝胶 Pending CN1119827A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/037,958 US5340571A (en) 1993-03-26 1993-03-26 Non-aerosol shaving gel
US08/037,958 1993-03-26

Publications (1)

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CN1119827A true CN1119827A (zh) 1996-04-03

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US (1) US5340571A (zh)
EP (1) EP0693918B1 (zh)
JP (1) JP3656757B2 (zh)
CN (1) CN1119827A (zh)
AT (1) ATE230588T1 (zh)
AU (1) AU671736B2 (zh)
BR (1) BR9406025A (zh)
CA (1) CA2159013C (zh)
DE (1) DE69431987D1 (zh)
MY (1) MY110380A (zh)
NO (1) NO953787D0 (zh)
NZ (1) NZ263687A (zh)
PL (1) PL173654B1 (zh)
TR (1) TR27740A (zh)
TW (1) TW295547B (zh)
WO (1) WO1994022415A1 (zh)
ZA (1) ZA941901B (zh)

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US5500211A (en) * 1994-09-22 1996-03-19 The Gillette Company Soap-free self-foaming shave gel composition
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US5853710A (en) * 1997-09-26 1998-12-29 Colgate-Palmolive Co. Shave gel composition
US5902779A (en) * 1997-10-10 1999-05-11 Avon Products, Inc. Shower and shave body wash
IL122776A (en) 1997-12-28 2004-07-25 Dead Sea Lab Ltd Gel composition for skin care and protection and a method for preparation thereof
DE10057925A1 (de) * 2000-11-22 2002-05-23 Beiersdorf Ag Kosmetische Zubereitungen für die Rasur mittels eines Rasiergerätes
US6627185B2 (en) 2001-07-26 2003-09-30 The Gillette Company Non-aerosol Shaving gel free of thickening and gelling agents
DE10221813A1 (de) * 2002-05-16 2003-11-27 Beiersdorf Ag Stark schäumendes Reinigungsgel
CA2559045C (en) * 2004-03-12 2012-10-09 The Gillette Company Shave gel products
FR2911269B1 (fr) * 2007-01-17 2011-07-29 Oreal Mousse a raser sans savon a base de n-acylsarcosinate et d'acide gras sature lineaire libre; procede de rasage
US20100008883A1 (en) * 2008-02-11 2010-01-14 Ali Abdelaziz Alwattari Film forming personal care compositions
US20100021409A1 (en) * 2008-02-11 2010-01-28 Ali Abdelaziz Alwattari Film Forming Personal Care Compositions
FR2931666B1 (fr) 2008-06-02 2010-05-28 Oreal Gel auto-moussant sans savon a base de n-acylsarcosine ; procede de rasage ; procede de nettoyage
JP2015124219A (ja) * 2013-12-25 2015-07-06 シバタ化成株式会社 ゲル状洗浄剤の製造方法、及び液体洗浄剤用のゲル化剤
JP2015124383A (ja) * 2013-12-25 2015-07-06 シバタ化成株式会社 ゲル状洗浄剤組成物、及び液状洗浄剤のゲル化方法
WO2016154275A1 (en) 2015-03-23 2016-09-29 Edgewell Personal Care Brands Llc Non-aerosol shaving compositions
DE102020202019A1 (de) 2020-02-18 2021-08-19 Beiersdorf Aktiengesellschaft Rasierhilfsmittel enthaltend Hydroxyalkylcellulosen
EP4133048A1 (en) 2020-04-10 2023-02-15 The Procter & Gamble Company Cleaning implement with a rheological solid composition
JP2023518022A (ja) * 2020-04-10 2023-04-27 ザ プロクター アンド ギャンブル カンパニー 剃毛に使用するための流動性固体組成物
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US5034220A (en) * 1990-06-20 1991-07-23 Gaf Chemicals Corporation Non-aerosol shaving gel

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US5340571A (en) 1994-08-23
NZ263687A (en) 1996-08-27
NO953787L (no) 1995-09-25
AU6446994A (en) 1994-10-24
JPH08508730A (ja) 1996-09-17
TR27740A (tr) 1995-07-07
DE69431987D1 (de) 2003-02-13
JP3656757B2 (ja) 2005-06-08
TW295547B (zh) 1997-01-11
CA2159013A1 (en) 1994-10-13
CA2159013C (en) 1998-10-27
EP0693918A4 (en) 1999-05-19
ATE230588T1 (de) 2003-01-15
AU671736B2 (en) 1996-09-05
EP0693918B1 (en) 2003-01-08
MY110380A (en) 1998-04-30
ZA941901B (en) 1995-01-13
EP0693918A1 (en) 1996-01-31
BR9406025A (pt) 1995-12-26
WO1994022415A1 (en) 1994-10-13
PL173654B1 (pl) 1998-04-30
PL310776A1 (en) 1996-01-08
NO953787D0 (no) 1995-09-25

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